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Seven novel lanthanide coordination polymers were prepared. These coordination polymers exhibit several 2D and 3D framework topologies that are dictated by the choice of metal salts and carboxyl­ate ligands. The heteronuclear compounds [EuxTb1−x(STP)(1,2-bdc)]n [STP is 2-(2,2′:6′,2′′-terpyridin-4′-yl)benzenesulfonate and (1,2-bdc)2− is benzene-1,2-dicarboxylate] (0 ≤ x ≤ 1) have potential use as efficient luminescent tags.
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