A heterobimetallic zinc(II)/uranium(IV) complex with the Schiff base 2-amino-N,N′-bis­(3-hydroxy­salicyl­idene)benzyl­amine

The title complex, [μ-2-amino-N,N′-bis­(3-hydroxy­salicyl­idene)benzyl­amine­(4−)]bis­(pentane-2,4-dionato)(pyridine)zinc(II)uranium(IV) tetrahydrofuran solvate, [UZn(C₂₁H₁₄N₂O₄)(C₅H₇O₂)₂(C₅H₅N)]·C₄H₈O, is a novel example of a dinuclear complex including one 3d and one 5f metal ions. The U atom is located in the O₄ site of the Schiff base ligand 2-amino-N,N′-bis­(3-hydroxy­salicyl­idene)benzyl­amine (L¹) and is further bound to two acetyl­acetonate groups, which gives an octa­coordinated dodeca­hedral environment. The Zn atom is in the inner N₂O₂ site. Its bonding to an axial pyridine mol­ecule results in a penta­coordinated square-pyramidal environment.

Key indicators

• Single-crystal X-ray study
• T = 100 K
• Mean [sigma](C-C) = 0.012 Å
• R factor = 0.048
• wR factor = 0.083
• Data-to-parameter ratio = 14.5

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         12
PLAT432_ALERT_2_C Short Inter X...Y Contact  O9     ..  C15     ..       2.92 Ang.
PLAT764_ALERT_4_C Overcomplete CIF Bond List Detected (Rep/Expd) .       1.11 Ratio

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   3 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: KappaCCD Server Software (Nonius, 1997); cell refinement: HKL-2000 (Otwinowski & Minor, 1997); data reduction: HKL-2000; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1999); software used to prepare material for publication: SHELXTL and PLATON (Spek, 2003).

A heterobimetallic zinc(II)/uranium(IV) complex with the Schiff base 2-amino-N,N'-bis(3-hydroxysalicylidene)benzylamine tetrahydrofuran solvate

Crystal data

[UZn(C21H14N2O4)(C5H7O2)2(C5H5N)]·C4H8O	F(000) = 3968
Mr = 1011.16	Dx = 1.789 Mg m^−3
Orthorhombic, Pbca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 49102 reflections
a = 16.6996 (8) Å	θ = 2.6–25.7°
b = 19.5711 (6) Å	µ = 5.01 mm^−1
c = 22.9680 (11) Å	T = 100 K
V = 7506.6 (6) Å^3	Platelet, translucent light yellow
Z = 8	0.15 × 0.10 × 0.03 mm

Data collection

Nonius KappaCCD diffractometer	7106 independent reflections
Radiation source: fine-focus sealed tube	3665 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.081
φ scans	θmax = 25.7°, θmin = 2.6°
Absorption correction: part of the refinement model (ΔF) (DELABS in PLATON; Spek, 2003)	h = −20→20
Tmin = 0.438, Tmax = 0.860	k = −23→23
49102 measured reflections	l = −27→27

Refinement

Refinement on F^2	Primary atom site location: patter
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.048	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.083	H-atom parameters constrained
S = 1.03	w = 1/[σ^2(Fo^2) + 27.6914P] where P = (Fo^2 + 2Fc^2)/3
7103 reflections	(Δ/σ)max = 0.001
491 parameters	Δρmax = 0.60 e Å^−3
0 restraints	Δρmin = −0.75 e Å^−3

Special details

Experimental. crystal-to-detector distance 28 mm

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Structure solved by Patterson map interpretation and subsequent Fourier-difference synthesis. All non-hydrogen atoms were refined with anisotropic displacement parameters. The H atoms were introduced at calculated positions as riding atoms with an isotropic displacement parameter equal to 1.2 (CH, CH2) or 1.5 (CH3) times that of the parent atom. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
U	0.74929 (3)	0.093970 (12)	0.462215 (11)	0.01989 (7)
Zn	0.74730 (8)	−0.04382 (4)	0.57256 (3)	0.02057 (18)
O1	0.6988 (3)	0.0326 (2)	0.3875 (2)	0.0204 (12)
O2	0.7129 (3)	−0.0212 (2)	0.4891 (2)	0.0202 (12)
O3	0.7814 (3)	0.0530 (2)	0.5607 (2)	0.0207 (12)
O4	0.8022 (3)	0.1747 (3)	0.5207 (2)	0.0246 (14)
O5	0.8643 (3)	0.0223 (3)	0.4540 (3)	0.0285 (14)
O6	0.8394 (3)	0.1416 (3)	0.3940 (3)	0.0253 (14)
O7	0.6749 (3)	0.1823 (3)	0.4171 (3)	0.0235 (13)
O8	0.6277 (3)	0.1126 (3)	0.5141 (3)	0.0267 (14)
N1	0.7816 (4)	−0.1385 (3)	0.5468 (3)	0.0218 (16)
N2	0.8185 (4)	−0.0462 (3)	0.6482 (3)	0.0207 (15)
N3	0.6321 (4)	−0.0602 (3)	0.6040 (3)	0.0220 (16)
C1	0.6926 (5)	−0.0365 (4)	0.3899 (4)	0.0216 (18)
C2	0.7064 (5)	−0.0655 (4)	0.4450 (4)	0.0200 (19)
C3	0.7160 (5)	−0.1372 (4)	0.4510 (4)	0.0201 (18)
C4	0.7010 (5)	−0.1791 (4)	0.4018 (4)	0.026 (2)
H4	0.7052	−0.2264	0.4050	0.031*
C5	0.6801 (5)	−0.1501 (4)	0.3491 (4)	0.0269 (19)
H5	0.6671	−0.1780	0.3177	0.032*
C6	0.6785 (5)	−0.0779 (4)	0.3425 (4)	0.025 (2)
H6	0.6679	−0.0587	0.3063	0.030*
C7	0.7556 (7)	−0.1685 (3)	0.5005 (3)	0.0247 (17)
H7	0.7632	−0.2155	0.4987	0.030*
C8	0.8381 (5)	−0.1761 (4)	0.5848 (4)	0.024 (2)
H8A	0.8916	−0.1586	0.5779	0.029*
H8B	0.8378	−0.2238	0.5734	0.029*
C9	0.8211 (5)	−0.1719 (4)	0.6486 (4)	0.0219 (19)
C10	0.8135 (5)	−0.2316 (4)	0.6801 (4)	0.028 (2)
H10	0.8183	−0.2729	0.6604	0.034*
C11	0.7992 (5)	−0.2331 (4)	0.7389 (4)	0.035 (2)
H11	0.7923	−0.2745	0.7581	0.042*
C12	0.7952 (5)	−0.1722 (4)	0.7692 (4)	0.028 (2)
H12	0.7877	−0.1724	0.8093	0.033*
C13	0.8024 (5)	−0.1099 (4)	0.7391 (4)	0.0235 (19)
H13	0.7980	−0.0688	0.7593	0.028*
C14	0.8159 (5)	−0.1094 (4)	0.6799 (4)	0.0218 (19)
C15	0.8477 (4)	0.0073 (4)	0.6736 (4)	0.0192 (18)
H15	0.8705	0.0003	0.7100	0.023*
C16	0.8489 (4)	0.0768 (4)	0.6517 (4)	0.0188 (18)
C17	0.8182 (4)	0.0955 (4)	0.5961 (3)	0.0199 (17)
C18	0.8285 (4)	0.1632 (4)	0.5751 (4)	0.0220 (18)
C19	0.8629 (5)	0.2114 (4)	0.6108 (4)	0.027 (2)
H19	0.8672	0.2563	0.5979	0.032*
C20	0.8916 (5)	0.1944 (4)	0.6664 (4)	0.031 (2)
H20	0.9153	0.2276	0.6897	0.037*
C21	0.8843 (5)	0.1280 (4)	0.6862 (4)	0.024 (2)
H21	0.9032	0.1170	0.7231	0.029*
C22	0.9838 (5)	−0.0393 (4)	0.4373 (4)	0.033 (2)
H22A	0.9667	−0.0627	0.4719	0.049*
H22B	1.0384	−0.0249	0.4418	0.049*
H22C	0.9797	−0.0695	0.4045	0.049*
C23	0.9316 (5)	0.0221 (5)	0.4274 (4)	0.030 (2)
C24	0.9571 (5)	0.0756 (4)	0.3905 (4)	0.027 (2)
H24	1.0089	0.0739	0.3756	0.032*
C25	0.9093 (5)	0.1303 (4)	0.3753 (4)	0.026 (2)
C26	0.9419 (5)	0.1827 (4)	0.3325 (4)	0.030 (2)
H26A	0.9085	0.1838	0.2985	0.045*
H26B	0.9954	0.1703	0.3214	0.045*
H26C	0.9424	0.2269	0.3504	0.045*
C27	0.5946 (5)	0.2730 (4)	0.3827 (4)	0.032 (2)
H27A	0.6360	0.3070	0.3848	0.047*
H27B	0.5438	0.2937	0.3914	0.047*
H27C	0.5931	0.2540	0.3442	0.047*
C28	0.6116 (5)	0.2169 (4)	0.4263 (4)	0.0230 (19)
C29	0.5603 (5)	0.2077 (4)	0.4740 (4)	0.027 (2)
H29	0.5173	0.2375	0.4780	0.032*
C30	0.5699 (5)	0.1567 (4)	0.5156 (4)	0.028 (2)
C31	0.5104 (5)	0.1508 (5)	0.5643 (4)	0.041 (2)
H31A	0.4763	0.1121	0.5576	0.062*
H31B	0.4785	0.1916	0.5659	0.062*
H31C	0.5383	0.1451	0.6005	0.062*
C32	0.5700 (5)	−0.0310 (4)	0.5770 (4)	0.028 (2)
H32	0.5801	−0.0027	0.5453	0.033*
C33	0.4920 (5)	−0.0408 (4)	0.5937 (4)	0.029 (2)
H33	0.4507	−0.0197	0.5734	0.035*
C34	0.4752 (5)	−0.0819 (4)	0.6409 (4)	0.026 (2)
H34	0.4227	−0.0885	0.6534	0.031*
C35	0.5379 (5)	−0.1127 (4)	0.6689 (4)	0.029 (2)
H35	0.5283	−0.1415	0.7003	0.035*
C36	0.6154 (5)	−0.1009 (4)	0.6504 (4)	0.029 (2)
H36	0.6575	−0.1214	0.6703	0.035*
O9	0.6890 (4)	0.0195 (3)	0.7262 (3)	0.0391 (17)
C37	0.6405 (5)	0.0040 (5)	0.7761 (4)	0.035 (2)
H37A	0.6741	−0.0037	0.8100	0.042*
H37B	0.6091	−0.0369	0.7691	0.042*
C38	0.5866 (6)	0.0642 (5)	0.7859 (5)	0.054 (3)
H38A	0.6110	0.0971	0.8119	0.065*
H38B	0.5354	0.0500	0.8018	0.065*
C39	0.5770 (6)	0.0933 (5)	0.7250 (5)	0.049 (3)
H39A	0.5358	0.0694	0.7033	0.059*
H39B	0.5646	0.1417	0.7261	0.059*
C40	0.6592 (5)	0.0804 (4)	0.6998 (5)	0.036 (2)
H40A	0.6559	0.0747	0.6579	0.043*
H40B	0.6945	0.1185	0.7081	0.043*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
U	0.02012 (12)	0.01899 (12)	0.02056 (12)	0.0011 (2)	0.0002 (3)	0.00084 (12)
Zn	0.0213 (4)	0.0207 (4)	0.0197 (4)	0.0011 (6)	0.0000 (7)	0.0006 (3)
O1	0.026 (3)	0.017 (3)	0.018 (3)	−0.001 (2)	−0.004 (2)	0.002 (2)
O2	0.026 (3)	0.021 (3)	0.013 (3)	0.003 (2)	0.001 (2)	0.001 (2)
O3	0.026 (3)	0.020 (3)	0.016 (3)	−0.006 (2)	−0.002 (2)	−0.001 (2)
O4	0.029 (3)	0.021 (3)	0.024 (4)	0.000 (2)	−0.006 (3)	−0.003 (2)
O5	0.023 (3)	0.027 (3)	0.036 (4)	0.008 (3)	−0.003 (3)	0.004 (3)
O6	0.021 (3)	0.024 (3)	0.031 (4)	−0.004 (2)	0.002 (3)	−0.001 (3)
O7	0.027 (3)	0.021 (3)	0.022 (3)	0.006 (3)	−0.001 (3)	0.003 (3)
O8	0.024 (3)	0.024 (3)	0.032 (4)	0.003 (2)	0.004 (3)	0.003 (2)
N1	0.023 (3)	0.019 (3)	0.023 (4)	0.003 (3)	0.002 (3)	0.002 (3)
N2	0.024 (4)	0.022 (4)	0.016 (4)	0.002 (3)	0.003 (3)	0.001 (3)
N3	0.026 (4)	0.023 (4)	0.018 (4)	0.002 (3)	0.004 (3)	−0.002 (3)
C1	0.016 (4)	0.025 (4)	0.024 (5)	−0.002 (3)	0.005 (4)	−0.005 (4)
C2	0.015 (4)	0.020 (4)	0.025 (5)	0.002 (3)	−0.001 (3)	−0.002 (3)
C3	0.020 (4)	0.021 (4)	0.019 (5)	−0.002 (3)	0.000 (3)	−0.001 (3)
C4	0.025 (5)	0.021 (4)	0.031 (6)	−0.001 (4)	−0.004 (4)	−0.005 (4)
C5	0.028 (5)	0.028 (5)	0.025 (5)	−0.002 (4)	−0.006 (4)	0.000 (4)
C6	0.017 (4)	0.038 (5)	0.020 (5)	0.004 (4)	−0.005 (4)	0.000 (4)
C7	0.023 (4)	0.022 (4)	0.029 (4)	−0.001 (5)	0.002 (6)	0.002 (3)
C8	0.032 (5)	0.017 (4)	0.024 (5)	0.002 (4)	0.000 (4)	−0.002 (3)
C9	0.017 (4)	0.025 (5)	0.024 (5)	0.002 (3)	0.001 (4)	0.003 (4)
C10	0.036 (5)	0.021 (4)	0.027 (6)	−0.001 (4)	−0.007 (4)	0.006 (4)
C11	0.040 (6)	0.027 (5)	0.038 (6)	0.000 (4)	−0.005 (5)	0.013 (4)
C12	0.027 (5)	0.042 (5)	0.015 (5)	−0.003 (4)	0.000 (4)	0.007 (4)
C13	0.022 (4)	0.026 (4)	0.023 (5)	0.005 (4)	−0.003 (4)	0.003 (4)
C14	0.016 (4)	0.023 (4)	0.026 (5)	0.002 (3)	−0.005 (4)	−0.006 (4)
C15	0.018 (4)	0.025 (4)	0.015 (5)	0.003 (3)	0.001 (3)	−0.007 (3)
C16	0.017 (4)	0.026 (4)	0.014 (5)	−0.003 (3)	0.006 (3)	−0.003 (3)
C17	0.017 (4)	0.026 (4)	0.017 (4)	−0.003 (4)	0.005 (3)	−0.004 (4)
C18	0.016 (4)	0.030 (5)	0.020 (5)	−0.003 (4)	0.003 (3)	−0.009 (4)
C19	0.030 (5)	0.020 (4)	0.031 (6)	0.003 (4)	0.002 (4)	−0.003 (4)
C20	0.030 (5)	0.036 (5)	0.027 (6)	−0.013 (4)	0.003 (4)	−0.011 (4)
C21	0.013 (4)	0.036 (5)	0.024 (5)	−0.011 (4)	0.006 (4)	−0.008 (4)
C22	0.029 (5)	0.030 (5)	0.039 (6)	0.011 (4)	0.003 (4)	0.000 (4)
C23	0.025 (5)	0.039 (5)	0.025 (6)	0.004 (4)	−0.010 (4)	−0.012 (4)
C24	0.020 (5)	0.032 (5)	0.028 (6)	−0.005 (4)	0.005 (4)	−0.002 (4)
C25	0.028 (5)	0.031 (5)	0.020 (5)	−0.010 (4)	0.002 (4)	−0.001 (4)
C26	0.029 (5)	0.032 (5)	0.030 (6)	−0.001 (4)	0.011 (4)	−0.001 (4)
C27	0.038 (5)	0.025 (5)	0.032 (6)	0.009 (4)	−0.006 (4)	0.002 (4)
C28	0.030 (5)	0.013 (4)	0.027 (5)	−0.002 (4)	−0.004 (4)	0.000 (4)
C29	0.026 (4)	0.023 (4)	0.031 (6)	0.008 (4)	0.002 (4)	−0.004 (4)
C30	0.027 (4)	0.021 (4)	0.036 (5)	0.004 (4)	−0.004 (4)	−0.014 (4)
C31	0.040 (5)	0.056 (6)	0.027 (5)	0.002 (5)	0.008 (4)	−0.009 (5)
C32	0.024 (5)	0.029 (5)	0.030 (6)	−0.007 (4)	−0.002 (4)	0.003 (4)
C33	0.032 (5)	0.029 (5)	0.027 (6)	0.001 (4)	−0.006 (4)	0.002 (4)
C34	0.017 (4)	0.033 (5)	0.028 (6)	0.002 (4)	0.002 (4)	−0.003 (4)
C35	0.036 (5)	0.032 (5)	0.019 (5)	−0.007 (4)	0.008 (4)	0.002 (4)
C36	0.021 (4)	0.034 (5)	0.031 (5)	0.002 (4)	−0.001 (4)	−0.005 (4)
O9	0.035 (4)	0.036 (4)	0.046 (5)	0.003 (3)	0.012 (3)	0.005 (3)
C37	0.038 (5)	0.039 (5)	0.027 (6)	−0.002 (5)	0.003 (4)	0.007 (4)
C38	0.048 (7)	0.071 (7)	0.044 (7)	0.022 (6)	0.031 (6)	0.014 (6)
C39	0.043 (6)	0.050 (6)	0.054 (7)	0.014 (6)	0.015 (5)	0.011 (6)
C40	0.032 (5)	0.029 (5)	0.047 (7)	0.002 (4)	0.002 (5)	−0.003 (4)

Geometric parameters (Å, º)

U—O1	2.258 (5)	C13—H13	0.9300
U—O2	2.415 (5)	C15—C16	1.451 (10)
U—O3	2.459 (5)	C15—H15	0.9300
U—O4	2.255 (5)	C16—C21	1.407 (10)
U—O5	2.385 (5)	C16—C17	1.424 (11)
U—O6	2.364 (6)	C17—C18	1.419 (11)
U—O7	2.368 (5)	C18—C19	1.377 (11)
U—O8	2.383 (5)	C19—C20	1.403 (12)
Zn—O2	2.049 (5)	C19—H19	0.9300
Zn—O3	1.997 (5)	C20—C21	1.383 (11)
Zn—N1	2.027 (6)	C20—H20	0.9300
Zn—N2	2.105 (7)	C21—H21	0.9300
Zn—N3	2.080 (7)	C22—C23	1.503 (11)
U—Zn	3.7009 (8)	C22—H22A	0.9600
O1—C1	1.356 (9)	C22—H22B	0.9600
O1—O2	2.571 (8)	C22—H22C	0.9600
O2—C2	1.338 (9)	C23—C24	1.413 (12)
O2—O3	2.473 (7)	C24—C25	1.379 (12)
O2—N1	2.888 (8)	C24—H24	0.9300
O3—C17	1.317 (9)	C25—C26	1.522 (11)
O3—O4	2.576 (7)	C26—H26A	0.9600
O3—N2	2.862 (8)	C26—H26B	0.9600
O4—C18	1.343 (9)	C26—H26C	0.9600
O5—C23	1.280 (10)	C27—C28	1.515 (11)
O6—C25	1.265 (10)	C27—H27A	0.9600
O7—C28	1.272 (9)	C27—H27B	0.9600
O8—C30	1.295 (9)	C27—H27C	0.9600
N1—C7	1.290 (10)	C28—C29	1.401 (11)
N1—C8	1.480 (10)	C29—C30	1.391 (11)
N1—N2	3.010 (9)	C29—H29	0.9300
N2—C15	1.293 (9)	C30—C31	1.500 (12)
N2—C14	1.437 (10)	C31—H31A	0.9600
N3—C32	1.336 (10)	C31—H31B	0.9600
N3—C36	1.359 (10)	C31—H31C	0.9600
C1—C6	1.378 (11)	C32—C33	1.371 (12)
C1—C2	1.406 (11)	C32—H32	0.9300
C2—C3	1.419 (10)	C33—C34	1.379 (12)
C3—C4	1.419 (11)	C33—H33	0.9300
C3—C7	1.451 (11)	C34—C35	1.368 (12)
C4—C5	1.382 (11)	C34—H34	0.9300
C4—H4	0.9300	C35—C36	1.382 (11)
C5—C6	1.421 (11)	C35—H35	0.9300
C5—H5	0.9300	C36—H36	0.9300
C6—H6	0.9300	O9—C40	1.426 (10)
C7—H7	0.9300	O9—C37	1.435 (10)
C8—C9	1.495 (11)	C37—C38	1.500 (12)
C8—H8A	0.9700	C37—H37A	0.9700
C8—H8B	0.9700	C37—H37B	0.9700
C9—C10	1.380 (10)	C38—C39	1.518 (14)
C9—C14	1.422 (10)	C38—H38A	0.9700
C10—C11	1.371 (12)	C38—H38B	0.9700
C10—H10	0.9300	C39—C40	1.512 (12)
C11—C12	1.382 (12)	C39—H39A	0.9700
C11—H11	0.9300	C39—H39B	0.9700
C12—C13	1.406 (11)	C40—H40A	0.9700
C12—H12	0.9300	C40—H40B	0.9700
C13—C14	1.380 (11)
O1—U—O2	66.66 (18)	N2—C15—C16	127.5 (8)
O2—U—O3	60.99 (17)	N2—C15—H15	116.3
O3—U—O4	66.10 (17)	C16—C15—H15	116.3
O4—U—O1	166.46 (19)	C21—C16—C17	118.2 (7)
O5—U—O6	70.57 (19)	C21—C16—C15	118.7 (8)
O6—U—O7	75.89 (19)	C17—C16—C15	123.1 (7)
O7—U—O8	70.09 (19)	O3—C17—C18	115.9 (7)
O8—U—O5	144.65 (19)	O3—C17—C16	124.0 (7)
O4—U—O6	82.5 (2)	C18—C17—C16	120.1 (7)
O1—U—O6	86.77 (19)	O4—C18—C19	125.1 (8)
O4—U—O7	87.40 (19)	O4—C18—C17	115.7 (7)
O1—U—O7	81.97 (19)	C19—C18—C17	119.2 (8)
O4—U—O8	85.92 (19)	C18—C19—C20	121.5 (8)
O1—U—O8	98.21 (19)	C18—C19—H19	119.3
O6—U—O8	144.45 (18)	C20—C19—H19	119.3
O4—U—O5	98.3 (2)	C21—C20—C19	119.5 (8)
O1—U—O5	85.86 (19)	C21—C20—H20	120.2
O7—U—O5	144.8 (2)	C19—C20—H20	120.2
O4—U—O2	126.88 (19)	C20—C21—C16	121.4 (8)
O6—U—O2	134.25 (18)	C20—C21—H21	119.3
O7—U—O2	131.41 (18)	C16—C21—H21	119.3
O8—U—O2	78.49 (17)	C23—C22—H22A	109.5
O5—U—O2	70.96 (18)	C23—C22—H22B	109.5
O1—U—O3	127.36 (17)	H22A—C22—H22B	109.5
O6—U—O3	126.85 (18)	C23—C22—H22C	109.5
O7—U—O3	139.01 (18)	H22A—C22—H22C	109.5
O8—U—O3	77.05 (18)	H22B—C22—H22C	109.5
O5—U—O3	72.87 (19)	O5—C23—C24	123.3 (8)
O2—Zn—N1	90.2 (2)	O5—C23—C22	116.1 (8)
N1—Zn—N2	93.5 (3)	C24—C23—C22	120.6 (8)
N2—Zn—O3	88.4 (2)	C25—C24—C23	123.5 (8)
O2—Zn—O3	75.3 (2)	C25—C24—H24	118.2
O2—Zn—N3	95.7 (2)	C23—C24—H24	118.2
O3—Zn—N3	117.2 (2)	O6—C25—C24	125.8 (8)
N1—Zn—N3	102.8 (3)	O6—C25—C26	115.6 (8)
N2—Zn—N3	103.4 (3)	C24—C25—C26	118.6 (8)
O3—Zn—N1	138.3 (2)	C25—C26—H26A	109.5
O2—Zn—N2	159.2 (2)	C25—C26—H26B	109.5
C1—O1—U	121.9 (5)	H26A—C26—H26B	109.5
C2—O2—Zn	126.2 (5)	C25—C26—H26C	109.5
C2—O2—U	115.6 (5)	H26A—C26—H26C	109.5
Zn—O2—U	111.8 (2)	H26B—C26—H26C	109.5
C17—O3—Zn	130.4 (5)	C28—C27—H27A	109.5
C17—O3—U	117.6 (4)	C28—C27—H27B	109.5
Zn—O3—U	111.9 (2)	H27A—C27—H27B	109.5
C18—O4—U	124.4 (5)	C28—C27—H27C	109.5
C23—O5—U	138.3 (6)	H27A—C27—H27C	109.5
C25—O6—U	138.1 (5)	H27B—C27—H27C	109.5
C28—O7—U	138.7 (5)	O7—C28—C29	124.7 (8)
C30—O8—U	138.6 (5)	O7—C28—C27	115.6 (8)
C7—N1—C8	118.3 (6)	C29—C28—C27	119.7 (7)
C7—N1—Zn	124.1 (6)	C30—C29—C28	124.0 (7)
C8—N1—Zn	117.6 (5)	C30—C29—H29	118.0
C15—N2—C14	118.7 (7)	C28—C29—H29	118.0
C15—N2—Zn	124.6 (6)	O8—C30—C29	123.0 (8)
C14—N2—Zn	114.8 (5)	O8—C30—C31	117.6 (8)
C32—N3—C36	117.1 (7)	C29—C30—C31	119.4 (8)
C32—N3—Zn	119.4 (5)	C30—C31—H31A	109.5
C36—N3—Zn	123.5 (5)	C30—C31—H31B	109.5
O1—C1—C6	124.6 (8)	H31A—C31—H31B	109.5
O1—C1—C2	115.3 (7)	C30—C31—H31C	109.5
C6—C1—C2	120.1 (7)	H31A—C31—H31C	109.5
O2—C2—C1	115.6 (7)	H31B—C31—H31C	109.5
O2—C2—C3	123.9 (8)	N3—C32—C33	123.2 (8)
C1—C2—C3	120.4 (7)	N3—C32—H32	118.4
C2—C3—C4	118.3 (8)	C33—C32—H32	118.4
C2—C3—C7	123.0 (7)	C32—C33—C34	119.7 (8)
C4—C3—C7	117.5 (7)	C32—C33—H33	120.1
C5—C4—C3	120.3 (8)	C34—C33—H33	120.1
C5—C4—H4	119.9	C35—C34—C33	118.0 (8)
C3—C4—H4	119.9	C35—C34—H34	121.0
C4—C5—C6	120.5 (8)	C33—C34—H34	121.0
C4—C5—H5	119.7	C34—C35—C36	120.0 (8)
C6—C5—H5	119.7	C34—C35—H35	120.0
C1—C6—C5	119.8 (8)	C36—C35—H35	120.0
C1—C6—H6	120.1	N3—C36—C35	122.0 (8)
C5—C6—H6	120.1	N3—C36—H36	119.0
N1—C7—C3	127.4 (7)	C35—C36—H36	119.0
N1—C7—H7	116.3	C40—O9—C37	108.7 (7)
C3—C7—H7	116.3	O9—C37—C38	107.0 (7)
N1—C8—C9	115.4 (7)	O9—C37—H37A	110.3
N1—C8—H8A	108.4	C38—C37—H37A	110.3
C9—C8—H8A	108.4	O9—C37—H37B	110.3
N1—C8—H8B	108.4	C38—C37—H37B	110.3
C9—C8—H8B	108.4	H37A—C37—H37B	108.6
H8A—C8—H8B	107.5	C37—C38—C39	102.7 (8)
C10—C9—C14	117.2 (8)	C37—C38—H38A	111.2
C10—C9—C8	119.1 (7)	C39—C38—H38A	111.2
C14—C9—C8	123.7 (7)	C37—C38—H38B	111.2
C11—C10—C9	123.5 (8)	C39—C38—H38B	111.2
C11—C10—H10	118.3	H38A—C38—H38B	109.1
C9—C10—H10	118.3	C40—C39—C38	101.3 (8)
C10—C11—C12	119.0 (8)	C40—C39—H39A	111.5
C10—C11—H11	120.5	C38—C39—H39A	111.5
C12—C11—H11	120.5	C40—C39—H39B	111.5
C11—C12—C13	119.8 (8)	C38—C39—H39B	111.5
C11—C12—H12	120.1	H39A—C39—H39B	109.3
C13—C12—H12	120.1	O9—C40—C39	107.0 (8)
C14—C13—C12	120.3 (8)	O9—C40—H40A	110.3
C14—C13—H13	119.9	C39—C40—H40A	110.3
C12—C13—H13	119.9	O9—C40—H40B	110.3
C13—C14—C9	120.2 (7)	C39—C40—H40B	110.3
C13—C14—N2	120.7 (7)	H40A—C40—H40B	108.6
C9—C14—N2	118.9 (7)