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The reactions of a flexible ligand hexakis(3-pyridyloxy)cyclotriphosphazene (HPCP) with a variety of silver(I) salts (AgX; X = NO3, PF6, ClO4, CH3PhSO3, BF4 and CF3SO3) afforded six silver(I) coordination polymers, namely {[Ag2(HPCP)]·(NO3)2·H2O}n (1), {[Ag2(HPCP)(CH3CN)]·(PF6)2}n (2), {[Ag2(HPCP)(CH3CN)]·(ClO4)2}n (3), [Ag3(HPCP)(CH3PhSO3)3]n (4), [Ag2(HPCP)(CH3CN)(BF4)2]n (5) and {[Ag(HPCP)]·(CF3SO3)}n (6). All of the isolated crystalline compounds were structurally determined by X-ray crystallography. Changing the counteranions in the reactions, which were conducted under similar conditions of M/L ratio (1:1), temperature and solvent, resulted in structures with different types of topologies. In complexes (1)–(6), the ligand HPCP shows different coordination modes with AgI ions giving two-dimensional layered structures and three-dimensional frameworks with different topologies. Complex (1) displays a new three-dimensional framework adopting a (3,3,6)-connected 3-nodal net with point symbol {4.62}2{42.610.83}. Complexes (2) and (3) are isomorphous and have a two-dimensional layered structure showing the same 3,6L60 topology with point symbol {4.26}2{48.66.8}. Complex (4) is a two-dimensional structure incorporating short Ag...Ag argentophilic interactions and has a uninodal 4-connected sql/Shubnikov tetragonal plane net with {44.62} topology. Complex (5) exhibits a novel three-dimensional framework and more suprisingly contains twofold interpenetrated honeycomb-like networks, in which the single net has a trinodal (2,3,5)-connected 3-nodal net with point symbol {63.86.12}{63}{8}. Complex (6) crystallizes in a trigonal crystal system with the space group R\bar 3 and possesses a three-dimensional polymeric structure showing a binodal (4,6)-connected fsh net with the point symbol (43.63)2.(46.66.83). The effect of the counteranions on the formation of coordination polymers is discussed in this study.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S2052520616002663/xk5028sup1.cif
Contains datablocks ActaB, CCDC1422432, CCDC1422433, CCDC1422434, CCDC1422435, CCDC1422430, CCDC1422431, CCDC1422436

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520616002663/xk5028CCDC1422430sup2.hkl
Contains datablock CCDC1422430

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520616002663/xk5028CCDC1422431sup3.hkl
Contains datablock CCDC1422431

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520616002663/xk5028CCDC1422432sup4.hkl
Contains datablock CCDC1422432

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520616002663/xk5028CCDC1422433sup5.hkl
Contains datablock CCDC1422433

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520616002663/xk5028CCDC1422434sup6.hkl
Contains datablock CCDC1422434

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520616002663/xk5028CCDC1422435sup7.hkl
Contains datablock CCDC1422435

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520616002663/xk5028CCDC1422436sup8.hkl
Contains datablock CCDC1422436

pdf

Portable Document Format (PDF) file https://doi.org/10.1107/S2052520616002663/xk5028sup9.pdf
Supporting tables and figures including the intermolecular interactions and IR spectra of complexes 1-6; IR, 1H NMR, 31P NMR spectrum of HPCP

CCDC references: 1422430; 1422431; 1422432; 1422433; 1422434; 1422435; 1422436

Computing details top

For all compounds, data collection: APEX2 (Bruker AXS); cell refinement: APEX2 (Bruker AXS). Data reduction: SAINT (Bruker AXS, 2009) for CCDC1422432; SAINT (Bruker AXS) for CCDC1422433, CCDC1422434, CCDC1422435, CCDC1422430, CCDC1422436; SAINT V8.27B (Bruker AXS) for CCDC1422431. For all compounds, program(s) used to solve structure: SHELXTL V6.14 (Bruker AXS); program(s) used to refine structure: SHELXTL V6.14 (Bruker AXS); molecular graphics: Mercury (Macrae et al., 2006); software used to prepare material for publication: PLATON V1.16 (Spek, 2009), SHELXTL V6.14 (Bruker AXS).

(CCDC1422432) top
Crystal data top
C32H27Ag2N10O6P3·2(F6P)Z = 2
Mr = 1246.23F(000) = 1228
Triclinic, P1Dx = 1.890 Mg m3
a = 12.6372 (4) ÅMo Kα radiation, λ = 0.71073 Å
b = 12.9850 (4) ÅCell parameters from 128 reflections
c = 14.7076 (4) Åθ = 6.3–28.9°
α = 77.680 (1)°µ = 1.18 mm1
β = 68.355 (1)°T = 150 K
γ = 87.319 (1)°Plate, clear colourless
V = 2190.24 (11) Å30.40 × 0.24 × 0.08 mm
Data collection top
Bruker APEX II Quazar three-circle
diffractometer
7707 independent reflections
Radiation source: microfocus sealed tube7107 reflections with I > 2σ(I)
Multilayer quazar mirrors monochromatorRint = 0.047
Detector resolution: 8.3333 pixels mm-1θmax = 25.0°, θmin = 1.5°
φ and ω scansh = 1515
Absorption correction: multi-scan
SADABS (Bruker AXS)
k = 1514
Tmin = 0.650, Tmax = 0.913l = 1716
32889 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.038Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.099H-atom parameters constrained
S = 1.01 w = 1/[σ2(Fo2) + (0.0431P)2 + 6.3238P]
where P = (Fo2 + 2Fc2)/3
7707 reflections(Δ/σ)max = 0.002
605 parametersΔρmax = 1.37 e Å3
0 restraintsΔρmin = 0.81 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.70364 (2)0.36935 (3)0.70554 (2)0.03503 (10)
Ag20.66611 (3)0.15202 (2)0.34833 (2)0.03458 (10)
C10.1552 (3)0.2756 (3)0.8475 (3)0.0225 (7)
H10.11610.24490.79150.027*
C20.1364 (3)0.2392 (3)0.9352 (3)0.0188 (7)
C30.1933 (3)0.2803 (3)1.0186 (3)0.0236 (7)
H30.18140.25511.07950.028*
C40.2683 (3)0.3596 (3)1.0103 (3)0.0276 (8)
H40.30940.39041.06580.033*
C50.2824 (3)0.3932 (3)0.9200 (3)0.0291 (8)
H50.33410.44770.91480.035*
C60.2270 (3)0.0206 (3)0.8157 (3)0.0214 (7)
H60.17050.01640.78690.026*
C70.2085 (3)0.0251 (2)0.8963 (2)0.0192 (7)
C80.2873 (3)0.0196 (3)0.9410 (3)0.0269 (8)
H80.27400.04890.99810.032*
C90.3872 (3)0.0306 (3)0.8992 (3)0.0331 (9)
H90.44520.03450.92620.040*
C100.4023 (3)0.0747 (3)0.8184 (3)0.0307 (8)
H100.47120.10910.79090.037*
C110.1668 (3)0.6308 (3)0.7795 (3)0.0227 (7)
H110.23750.59810.77210.027*
C120.0666 (3)0.5728 (3)0.8380 (2)0.0198 (7)
C130.0370 (3)0.6177 (3)0.8485 (3)0.0277 (8)
H130.10640.57890.88830.033*
C140.0365 (3)0.7210 (3)0.7991 (3)0.0348 (9)
H140.10610.75450.80350.042*
C150.0663 (3)0.7749 (3)0.7434 (3)0.0307 (8)
H150.06560.84630.71070.037*
C160.1743 (3)0.4877 (3)0.5017 (3)0.0224 (7)
H160.22910.43940.47360.027*
C170.0910 (3)0.4543 (3)0.5941 (2)0.0187 (7)
C180.0083 (3)0.5214 (3)0.6353 (3)0.0242 (7)
H180.05140.49800.69820.029*
C190.0148 (3)0.6236 (3)0.5826 (3)0.0302 (8)
H190.04020.67250.60890.036*
C200.1020 (3)0.6543 (3)0.4909 (3)0.0273 (8)
H200.10700.72550.45570.033*
C210.5211 (3)0.2455 (3)0.9026 (3)0.0255 (8)
H210.58480.20400.90350.031*
C220.4213 (3)0.2258 (3)0.9850 (3)0.0284 (8)
H220.41720.17281.04200.034*
C230.3276 (3)0.2838 (3)0.9841 (3)0.0274 (8)
H230.25750.27171.03980.033*
C240.3389 (3)0.3598 (3)0.8998 (3)0.0197 (7)
C250.4410 (3)0.3773 (3)0.8199 (3)0.0224 (7)
H250.44700.43060.76270.027*
C260.5778 (3)0.1458 (3)0.5760 (3)0.0284 (8)
H260.64960.11470.56670.034*
C270.5120 (3)0.1623 (3)0.6693 (3)0.0253 (7)
H270.53830.14260.72320.030*
C280.4069 (3)0.2078 (3)0.6844 (3)0.0212 (7)
H280.35980.22040.74810.025*
C290.3738 (3)0.2340 (2)0.6033 (2)0.0181 (7)
C300.4438 (3)0.2149 (3)0.5117 (3)0.0250 (7)
H300.41910.23300.45680.030*
C310.8287 (4)0.0526 (3)0.4471 (3)0.0346 (9)
C320.8946 (4)0.1332 (4)0.4837 (4)0.0478 (11)
H32A0.91950.18280.43880.072*
H32B0.84770.17110.55100.072*
H32C0.96150.10030.48610.072*
F10.5003 (4)0.6975 (4)0.7383 (3)0.1052 (16)
F20.7307 (3)0.6029 (4)0.7527 (3)0.127 (2)
F30.6111 (3)0.5734 (2)0.6814 (2)0.0700 (9)
F40.5460 (2)0.5713 (2)0.8461 (2)0.0613 (8)
F50.6216 (7)0.7316 (4)0.8102 (4)0.170 (3)
F60.6880 (4)0.7311 (3)0.6460 (3)0.1099 (17)
F70.6925 (4)0.0607 (4)0.8354 (3)0.1185 (18)
F80.8831 (3)0.0315 (4)0.6694 (3)0.0969 (13)
F90.7727 (3)0.0938 (2)0.8238 (2)0.0691 (9)
F100.6949 (3)0.0154 (3)0.7133 (4)0.0954 (14)
F110.7969 (4)0.1306 (3)0.6822 (3)0.1082 (15)
F120.8802 (4)0.0505 (3)0.7849 (4)0.1188 (19)
N10.1026 (2)0.2736 (2)0.93085 (19)0.0173 (6)
N20.2056 (2)0.3897 (2)0.7441 (2)0.0175 (6)
N30.1135 (2)0.1958 (2)0.7721 (2)0.0175 (6)
N40.2265 (2)0.3526 (3)0.8390 (2)0.0285 (7)
N50.3229 (2)0.0709 (2)0.7770 (2)0.0253 (6)
N60.5450 (3)0.1718 (3)0.4976 (2)0.0277 (7)
N70.1799 (2)0.5873 (2)0.4500 (2)0.0251 (6)
N80.1669 (3)0.7310 (2)0.7333 (2)0.0251 (6)
N90.5321 (2)0.3208 (2)0.8210 (2)0.0248 (6)
N100.7780 (4)0.0104 (3)0.4170 (3)0.0508 (10)
O10.24810 (19)0.42395 (17)0.89527 (17)0.0199 (5)
O20.06235 (19)0.46913 (18)0.89021 (17)0.0206 (5)
O30.10442 (19)0.07092 (18)0.93818 (17)0.0214 (5)
O40.06339 (18)0.15625 (17)0.94144 (17)0.0199 (5)
O50.27246 (18)0.28164 (18)0.60444 (16)0.0198 (5)
O60.08385 (18)0.34899 (17)0.64455 (16)0.0183 (5)
P10.15470 (7)0.38271 (6)0.86127 (6)0.01496 (17)
P20.16905 (7)0.30287 (6)0.69935 (6)0.01487 (17)
P30.06979 (7)0.18092 (6)0.88994 (6)0.01538 (17)
P40.61491 (12)0.65333 (9)0.74735 (9)0.0466 (3)
P50.78766 (9)0.01775 (8)0.74983 (8)0.0325 (2)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.02111 (16)0.0480 (2)0.02274 (16)0.00383 (12)0.00044 (12)0.00413 (13)
Ag20.03466 (18)0.03822 (18)0.02299 (16)0.01460 (13)0.00018 (13)0.01252 (13)
C10.0127 (16)0.0328 (19)0.0201 (17)0.0014 (13)0.0028 (13)0.0079 (14)
C20.0134 (15)0.0178 (16)0.0231 (17)0.0021 (12)0.0041 (13)0.0041 (13)
C30.0229 (18)0.0262 (18)0.0207 (17)0.0020 (14)0.0059 (14)0.0068 (14)
C40.0240 (18)0.0273 (19)0.032 (2)0.0052 (15)0.0068 (16)0.0143 (16)
C50.0195 (18)0.0297 (19)0.038 (2)0.0061 (15)0.0115 (16)0.0062 (16)
C60.0195 (17)0.0184 (16)0.0235 (18)0.0019 (13)0.0059 (14)0.0022 (13)
C70.0178 (16)0.0148 (15)0.0187 (16)0.0046 (12)0.0008 (13)0.0022 (13)
C80.032 (2)0.0234 (18)0.0274 (19)0.0064 (15)0.0136 (16)0.0052 (15)
C90.029 (2)0.033 (2)0.042 (2)0.0091 (16)0.0191 (18)0.0081 (18)
C100.0222 (18)0.0263 (19)0.039 (2)0.0096 (15)0.0073 (16)0.0068 (16)
C110.0212 (17)0.0219 (17)0.0269 (18)0.0067 (13)0.0103 (15)0.0083 (14)
C120.0263 (18)0.0172 (16)0.0187 (17)0.0070 (13)0.0092 (14)0.0089 (13)
C130.0210 (18)0.0298 (19)0.0253 (19)0.0099 (15)0.0011 (15)0.0065 (15)
C140.028 (2)0.033 (2)0.034 (2)0.0181 (16)0.0045 (17)0.0041 (17)
C150.037 (2)0.0226 (18)0.029 (2)0.0124 (16)0.0093 (17)0.0054 (15)
C160.0193 (17)0.0269 (18)0.0201 (17)0.0071 (14)0.0066 (14)0.0056 (14)
C170.0189 (16)0.0234 (17)0.0176 (16)0.0030 (13)0.0108 (14)0.0052 (13)
C180.0214 (17)0.0314 (19)0.0159 (17)0.0065 (14)0.0033 (14)0.0046 (14)
C190.034 (2)0.031 (2)0.0239 (19)0.0142 (16)0.0088 (16)0.0075 (15)
C200.031 (2)0.0243 (18)0.0255 (19)0.0056 (15)0.0120 (16)0.0017 (15)
C210.0220 (18)0.0261 (18)0.030 (2)0.0049 (14)0.0119 (16)0.0064 (15)
C220.0256 (19)0.031 (2)0.0224 (18)0.0040 (15)0.0063 (15)0.0026 (15)
C230.0234 (18)0.034 (2)0.0195 (18)0.0039 (15)0.0041 (15)0.0025 (15)
C240.0190 (16)0.0222 (17)0.0234 (17)0.0038 (13)0.0109 (14)0.0111 (14)
C250.0204 (17)0.0257 (18)0.0231 (18)0.0023 (14)0.0107 (14)0.0036 (14)
C260.0193 (18)0.035 (2)0.029 (2)0.0111 (15)0.0061 (15)0.0099 (16)
C270.0246 (18)0.0306 (19)0.0228 (18)0.0071 (15)0.0109 (15)0.0078 (15)
C280.0213 (17)0.0235 (17)0.0176 (17)0.0032 (13)0.0041 (14)0.0084 (14)
C290.0156 (16)0.0174 (16)0.0196 (17)0.0035 (12)0.0044 (13)0.0046 (13)
C300.0234 (18)0.035 (2)0.0164 (17)0.0083 (15)0.0064 (14)0.0079 (14)
C310.036 (2)0.032 (2)0.030 (2)0.0084 (18)0.0067 (18)0.0058 (17)
C320.053 (3)0.036 (2)0.060 (3)0.014 (2)0.031 (2)0.007 (2)
F10.130 (3)0.134 (3)0.051 (2)0.093 (3)0.037 (2)0.028 (2)
F20.057 (2)0.178 (5)0.111 (3)0.023 (3)0.040 (2)0.067 (3)
F30.080 (2)0.0592 (19)0.0559 (19)0.0076 (16)0.0026 (16)0.0313 (15)
F40.0532 (17)0.072 (2)0.0435 (16)0.0108 (14)0.0106 (13)0.0048 (14)
F50.383 (10)0.077 (3)0.116 (4)0.019 (4)0.160 (6)0.028 (3)
F60.153 (4)0.097 (3)0.087 (3)0.073 (3)0.082 (3)0.049 (2)
F70.131 (4)0.111 (3)0.073 (3)0.080 (3)0.003 (2)0.026 (2)
F80.090 (3)0.120 (3)0.054 (2)0.019 (2)0.0109 (19)0.035 (2)
F90.065 (2)0.0518 (17)0.067 (2)0.0171 (15)0.0120 (16)0.0107 (15)
F100.096 (3)0.067 (2)0.165 (4)0.0062 (19)0.101 (3)0.017 (2)
F110.147 (4)0.055 (2)0.116 (3)0.025 (2)0.069 (3)0.040 (2)
F120.125 (4)0.081 (3)0.229 (6)0.022 (2)0.138 (4)0.069 (3)
N10.0177 (13)0.0195 (14)0.0131 (13)0.0019 (11)0.0034 (11)0.0050 (11)
N20.0147 (13)0.0187 (14)0.0169 (14)0.0002 (10)0.0033 (11)0.0035 (11)
N30.0196 (14)0.0166 (13)0.0165 (14)0.0029 (11)0.0052 (11)0.0072 (11)
N40.0185 (15)0.0404 (18)0.0268 (17)0.0044 (13)0.0098 (13)0.0054 (14)
N50.0224 (15)0.0212 (15)0.0279 (16)0.0052 (12)0.0024 (13)0.0093 (12)
N60.0224 (15)0.0386 (18)0.0204 (15)0.0114 (13)0.0035 (13)0.0126 (13)
N70.0215 (15)0.0311 (16)0.0176 (15)0.0018 (12)0.0047 (12)0.0009 (12)
N80.0286 (16)0.0215 (15)0.0246 (16)0.0048 (12)0.0089 (13)0.0062 (12)
N90.0176 (14)0.0333 (17)0.0224 (15)0.0001 (12)0.0070 (12)0.0038 (13)
N100.052 (2)0.050 (2)0.039 (2)0.021 (2)0.0099 (19)0.0012 (18)
O10.0194 (12)0.0184 (11)0.0264 (13)0.0044 (9)0.0116 (10)0.0089 (10)
O20.0177 (11)0.0197 (12)0.0212 (12)0.0055 (9)0.0030 (10)0.0060 (9)
O30.0210 (12)0.0182 (11)0.0173 (12)0.0053 (9)0.0000 (9)0.0014 (9)
O40.0150 (11)0.0175 (11)0.0232 (12)0.0014 (9)0.0034 (10)0.0029 (9)
O50.0153 (11)0.0274 (12)0.0142 (11)0.0061 (9)0.0025 (9)0.0055 (9)
O60.0159 (11)0.0199 (11)0.0186 (12)0.0018 (9)0.0068 (9)0.0028 (9)
P10.0136 (4)0.0157 (4)0.0157 (4)0.0030 (3)0.0046 (3)0.0054 (3)
P20.0135 (4)0.0170 (4)0.0128 (4)0.0031 (3)0.0028 (3)0.0044 (3)
P30.0144 (4)0.0143 (4)0.0144 (4)0.0025 (3)0.0017 (3)0.0037 (3)
P40.0748 (9)0.0301 (6)0.0391 (7)0.0015 (5)0.0279 (6)0.0033 (5)
P50.0317 (5)0.0316 (5)0.0330 (6)0.0031 (4)0.0112 (4)0.0057 (4)
Geometric parameters (Å, º) top
Ag1—N7i2.182 (3)C21—H210.9500
Ag1—N92.222 (3)C22—C231.376 (5)
Ag1—N4ii2.400 (3)C22—H220.9500
Ag2—N62.226 (3)C23—C241.376 (5)
Ag2—N5iii2.270 (3)C23—H230.9500
Ag2—N8i2.419 (3)C24—C251.376 (5)
Ag2—N102.534 (4)C24—O11.399 (4)
C1—N41.331 (5)C25—N91.340 (4)
C1—C21.378 (5)C25—H250.9500
C1—H10.9500C26—N61.338 (5)
C2—C31.378 (5)C26—C271.374 (5)
C2—O41.395 (4)C26—H260.9500
C3—C41.384 (5)C27—C281.389 (5)
C3—H30.9500C27—H270.9500
C4—C51.381 (5)C28—C291.377 (5)
C4—H40.9500C28—H280.9500
C5—N41.345 (5)C29—C301.379 (5)
C5—H50.9500C29—O51.392 (4)
C6—N51.340 (4)C30—N61.332 (5)
C6—C71.378 (5)C30—H300.9500
C6—H60.9500C31—N101.131 (5)
C7—C81.374 (5)C31—C321.445 (6)
C7—O31.395 (4)C32—H32A0.9800
C8—C91.384 (5)C32—H32B0.9800
C8—H80.9500C32—H32C0.9800
C9—C101.374 (6)F1—P41.574 (4)
C9—H90.9500F2—P41.597 (4)
C10—N51.347 (5)F3—P41.578 (3)
C10—H100.9500F4—P41.580 (3)
C11—N81.334 (4)F5—P41.537 (4)
C11—C121.385 (5)F6—P41.589 (4)
C11—H110.9500F7—P51.569 (3)
C12—C131.376 (5)F8—P51.568 (3)
C12—O21.393 (4)F9—P51.587 (3)
C13—C141.382 (5)F10—P51.568 (3)
C13—H130.9500F11—P51.568 (3)
C14—C151.380 (6)F12—P51.549 (3)
C14—H140.9500N1—P11.568 (3)
C15—N81.339 (5)N1—P31.588 (3)
C15—H150.9500N2—P21.583 (3)
C16—N71.343 (5)N2—P11.586 (3)
C16—C171.371 (5)N3—P21.572 (3)
C16—H160.9500N3—P31.583 (3)
C17—C181.376 (5)N4—Ag1iv2.400 (3)
C17—O61.399 (4)N5—Ag2iii2.270 (3)
C18—C191.375 (5)N7—Ag1i2.182 (3)
C18—H180.9500N8—Ag2i2.419 (3)
C19—C201.380 (5)O1—P11.593 (2)
C19—H190.9500O2—P11.587 (2)
C20—N71.340 (5)O3—P31.573 (2)
C20—H200.9500O4—P31.586 (2)
C21—N91.344 (5)O5—P21.587 (2)
C21—C221.377 (5)O6—P21.594 (2)
N7i—Ag1—N9151.70 (11)C29—C28—H28121.4
N7i—Ag1—N4ii120.33 (11)C27—C28—H28121.4
N9—Ag1—N4ii87.91 (10)C28—C29—C30120.2 (3)
N6—Ag2—N5iii140.42 (11)C28—C29—O5125.0 (3)
N6—Ag2—N8i117.99 (11)C30—C29—O5114.8 (3)
N5iii—Ag2—N8i100.61 (10)N6—C30—C29122.2 (3)
N6—Ag2—N1095.13 (12)N6—C30—H30118.9
N5iii—Ag2—N1092.23 (12)C29—C30—H30118.9
N8i—Ag2—N1091.34 (12)N10—C31—C32179.0 (5)
N4—C1—C2121.9 (3)C31—C32—H32A109.5
N4—C1—H1119.1C31—C32—H32B109.5
C2—C1—H1119.1H32A—C32—H32B109.5
C1—C2—C3120.7 (3)C31—C32—H32C109.5
C1—C2—O4119.8 (3)H32A—C32—H32C109.5
C3—C2—O4119.4 (3)H32B—C32—H32C109.5
C2—C3—C4117.6 (3)P1—N1—P3122.44 (17)
C2—C3—H3121.2P2—N2—P1119.57 (17)
C4—C3—H3121.2P2—N3—P3122.29 (17)
C5—C4—C3118.8 (3)C1—N4—C5117.9 (3)
C5—C4—H4120.6C1—N4—Ag1iv117.6 (2)
C3—C4—H4120.6C5—N4—Ag1iv121.1 (2)
N4—C5—C4123.1 (3)C6—N5—C10118.2 (3)
N4—C5—H5118.4C6—N5—Ag2iii116.8 (2)
C4—C5—H5118.4C10—N5—Ag2iii124.9 (2)
N5—C6—C7121.5 (3)C30—N6—C26118.1 (3)
N5—C6—H6119.3C30—N6—Ag2123.1 (2)
C7—C6—H6119.3C26—N6—Ag2118.6 (2)
C8—C7—C6121.1 (3)C20—N7—C16118.5 (3)
C8—C7—O3119.2 (3)C20—N7—Ag1i120.8 (2)
C6—C7—O3119.6 (3)C16—N7—Ag1i120.0 (2)
C7—C8—C9117.0 (3)C11—N8—C15118.0 (3)
C7—C8—H8121.5C11—N8—Ag2i124.8 (2)
C9—C8—H8121.5C15—N8—Ag2i116.6 (2)
C10—C9—C8120.0 (3)C25—N9—C21118.1 (3)
C10—C9—H9120.0C25—N9—Ag1120.8 (2)
C8—C9—H9120.0C21—N9—Ag1120.1 (2)
N5—C10—C9122.3 (3)C31—N10—Ag2179.5 (4)
N5—C10—H10118.9C24—O1—P1119.08 (19)
C9—C10—H10118.9C12—O2—P1126.9 (2)
N8—C11—C12121.9 (3)C7—O3—P3124.1 (2)
N8—C11—H11119.0C2—O4—P3118.23 (19)
C12—C11—H11119.0C29—O5—P2127.1 (2)
C13—C12—C11120.2 (3)C17—O6—P2122.26 (19)
C13—C12—O2115.9 (3)N1—P1—N2117.77 (14)
C11—C12—O2123.9 (3)N1—P1—O2108.03 (13)
C12—C13—C14117.7 (3)N2—P1—O2111.35 (14)
C12—C13—H13121.1N1—P1—O1109.39 (13)
C14—C13—H13121.1N2—P1—O1109.72 (14)
C15—C14—C13119.3 (3)O2—P1—O198.93 (12)
C15—C14—H14120.4N3—P2—N2118.27 (14)
C13—C14—H14120.4N3—P2—O5110.56 (13)
N8—C15—C14122.9 (3)N2—P2—O5109.97 (13)
N8—C15—H15118.6N3—P2—O6106.92 (13)
C14—C15—H15118.6N2—P2—O6111.01 (13)
N7—C16—C17121.3 (3)O5—P2—O698.22 (12)
N7—C16—H16119.3O3—P3—N3110.58 (13)
C17—C16—H16119.3O3—P3—O495.37 (12)
C16—C17—C18120.7 (3)N3—P3—O4112.18 (14)
C16—C17—O6120.3 (3)O3—P3—N1111.36 (14)
C18—C17—O6118.9 (3)N3—P3—N1116.16 (14)
C19—C18—C17117.8 (3)O4—P3—N1109.29 (13)
C19—C18—H18121.1F5—P4—F193.4 (3)
C17—C18—H18121.1F5—P4—F3178.7 (4)
C18—C19—C20119.4 (3)F1—P4—F387.6 (2)
C18—C19—H19120.3F5—P4—F490.1 (3)
C20—C19—H19120.3F1—P4—F490.5 (2)
N7—C20—C19122.2 (3)F3—P4—F490.74 (18)
N7—C20—H20118.9F5—P4—F691.9 (3)
C19—C20—H20118.9F1—P4—F691.5 (2)
N9—C21—C22122.8 (3)F3—P4—F687.2 (2)
N9—C21—H21118.6F4—P4—F6177.1 (3)
C22—C21—H21118.6F5—P4—F290.3 (4)
C23—C22—C21119.3 (3)F1—P4—F2176.3 (3)
C23—C22—H22120.4F3—P4—F288.7 (3)
C21—C22—H22120.4F4—P4—F289.33 (18)
C24—C23—C22117.7 (3)F6—P4—F288.6 (2)
C24—C23—H23121.1F12—P5—F10179.5 (3)
C22—C23—H23121.1F12—P5—F888.6 (3)
C25—C24—C23120.7 (3)F10—P5—F890.9 (3)
C25—C24—O1118.6 (3)F12—P5—F1190.2 (3)
C23—C24—O1120.6 (3)F10—P5—F1189.7 (2)
N9—C25—C24121.4 (3)F8—P5—F1196.2 (3)
N9—C25—H25119.3F12—P5—F790.6 (3)
C24—C25—H25119.3F10—P5—F789.9 (3)
N6—C26—C27122.7 (3)F8—P5—F7176.4 (2)
N6—C26—H26118.7F11—P5—F787.3 (3)
C27—C26—H26118.7F12—P5—F989.7 (2)
C26—C27—C28119.6 (3)F10—P5—F990.5 (2)
C26—C27—H27120.2F8—P5—F987.2 (2)
C28—C27—H27120.2F11—P5—F9176.5 (2)
C29—C28—C27117.2 (3)F7—P5—F989.2 (2)
N4—C1—C2—C31.4 (5)C14—C15—N8—Ag2i171.6 (3)
N4—C1—C2—O4178.1 (3)C24—C25—N9—C210.4 (5)
C1—C2—C3—C40.7 (5)C24—C25—N9—Ag1168.2 (2)
O4—C2—C3—C4177.5 (3)C22—C21—N9—C251.3 (5)
C2—C3—C4—C50.1 (5)C22—C21—N9—Ag1167.4 (3)
C3—C4—C5—N40.0 (6)N7i—Ag1—N9—C2554.1 (4)
N5—C6—C7—C80.9 (5)N4ii—Ag1—N9—C25129.6 (3)
N5—C6—C7—O3176.0 (3)N7i—Ag1—N9—C21137.5 (3)
C6—C7—C8—C92.2 (5)N4ii—Ag1—N9—C2138.8 (3)
O3—C7—C8—C9177.3 (3)C32—C31—N10—Ag22E1 (8)
C7—C8—C9—C101.9 (6)N6—Ag2—N10—C3116E1 (5)
C8—C9—C10—N50.3 (6)N5iii—Ag2—N10—C316E1 (5)
N8—C11—C12—C131.2 (5)N8i—Ag2—N10—C314E1 (5)
N8—C11—C12—O2177.8 (3)C25—C24—O1—P197.1 (3)
C11—C12—C13—C140.0 (5)C23—C24—O1—P185.6 (4)
O2—C12—C13—C14179.0 (3)C13—C12—O2—P1152.4 (3)
C12—C13—C14—C151.1 (6)C11—C12—O2—P128.6 (4)
C13—C14—C15—N81.1 (6)C8—C7—O3—P3108.7 (3)
N7—C16—C17—C182.1 (5)C6—C7—O3—P376.1 (4)
N7—C16—C17—O6177.1 (3)C1—C2—O4—P377.0 (3)
C16—C17—C18—C192.5 (5)C3—C2—O4—P3106.2 (3)
O6—C17—C18—C19177.6 (3)C28—C29—O5—P27.9 (5)
C17—C18—C19—C200.8 (5)C30—C29—O5—P2173.1 (2)
C18—C19—C20—N71.5 (6)C16—C17—O6—P276.3 (3)
N9—C21—C22—C231.3 (6)C18—C17—O6—P2108.6 (3)
C21—C22—C23—C240.3 (6)P3—N1—P1—N216.3 (3)
C22—C23—C24—C250.6 (5)P3—N1—P1—O2110.88 (19)
C22—C23—C24—O1177.8 (3)P3—N1—P1—O1142.40 (18)
C23—C24—C25—N90.5 (5)P2—N2—P1—N119.4 (2)
O1—C24—C25—N9177.9 (3)P2—N2—P1—O2106.17 (19)
N6—C26—C27—C280.1 (6)P2—N2—P1—O1145.34 (17)
C26—C27—C28—C290.3 (5)C12—O2—P1—N1169.8 (3)
C27—C28—C29—C300.0 (5)C12—O2—P1—N239.0 (3)
C27—C28—C29—O5178.9 (3)C12—O2—P1—O176.3 (3)
C28—C29—C30—N60.5 (5)C24—O1—P1—N156.0 (3)
O5—C29—C30—N6178.5 (3)C24—O1—P1—N274.6 (3)
C2—C1—N4—C51.3 (5)C24—O1—P1—O2168.8 (2)
C2—C1—N4—Ag1iv160.7 (3)P3—N3—P2—N213.0 (3)
C4—C5—N4—C10.7 (5)P3—N3—P2—O5141.02 (18)
C4—C5—N4—Ag1iv159.2 (3)P3—N3—P2—O6113.09 (19)
C7—C6—N5—C100.7 (5)P1—N2—P2—N317.8 (2)
C7—C6—N5—Ag2iii175.6 (2)P1—N2—P2—O5146.13 (17)
C9—C10—N5—C61.0 (5)P1—N2—P2—O6106.26 (19)
C9—C10—N5—Ag2iii175.0 (3)C29—O5—P2—N364.0 (3)
C29—C30—N6—C260.7 (6)C29—O5—P2—N268.4 (3)
C29—C30—N6—Ag2174.8 (3)C29—O5—P2—O6175.6 (3)
C27—C26—N6—C300.4 (6)C17—O6—P2—N3163.5 (2)
C27—C26—N6—Ag2175.3 (3)C17—O6—P2—N233.2 (3)
N5iii—Ag2—N6—C3060.0 (4)C17—O6—P2—O581.9 (2)
N8i—Ag2—N6—C30105.9 (3)C7—O3—P3—N338.6 (3)
N10—Ag2—N6—C30159.8 (3)C7—O3—P3—O4154.7 (3)
N5iii—Ag2—N6—C26124.5 (3)C7—O3—P3—N192.1 (3)
N8i—Ag2—N6—C2669.5 (3)P2—N3—P3—O3137.55 (18)
N10—Ag2—N6—C2624.7 (3)P2—N3—P3—O4117.33 (19)
C19—C20—N7—C162.0 (5)P2—N3—P3—N19.4 (3)
C19—C20—N7—Ag1i168.6 (3)C2—O4—P3—O3169.4 (2)
C17—C16—N7—C200.2 (5)C2—O4—P3—N375.8 (3)
C17—C16—N7—Ag1i170.4 (2)C2—O4—P3—N154.5 (3)
C12—C11—N8—C151.2 (5)P1—N1—P3—O3138.90 (18)
C12—C11—N8—Ag2i169.7 (2)P1—N1—P3—N311.1 (3)
C14—C15—N8—C110.0 (6)P1—N1—P3—O4117.02 (19)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+1, y, z; (iii) x+1, y, z+1; (iv) x1, y, z.
(CCDC1422433) top
Crystal data top
C32H27Ag2Cl2N10O14P3Z = 2
Mr = 1155.18F(000) = 1148
Triclinic, P1Dx = 1.789 Mg m3
a = 12.7463 (4) ÅMo Kα radiation, λ = 0.71073 Å
b = 12.7843 (3) ÅCell parameters from 151 reflections
c = 14.4175 (4) Åθ = 2.9–29.4°
α = 69.521 (1)°µ = 1.23 mm1
β = 77.152 (1)°T = 150 K
γ = 87.168 (1)°Block, clear colourless
V = 2144.75 (10) Å30.20 × 0.19 × 0.08 mm
Data collection top
Bruker APEX II QUAZAR three-circle
diffractometer
7637 independent reflections
Multilayer QUAZAR mirrors monochromator6869 reflections with I > 2σ(I)
Detector resolution: 8.3333 pixels mm-1Rint = 0.038
φ and ω scansθmax = 25.1°, θmin = 1.5°
Absorption correction: multi-scan
SADABS (Bruker AXS)
h = 1515
Tmin = 0.79, Tmax = 0.91k = 1514
30873 measured reflectionsl = 1717
Refinement top
Refinement on F26 restraints
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.037H-atom parameters constrained
wR(F2) = 0.097 w = 1/[σ2(Fo2) + (0.0431P)2 + 5.4001P]
where P = (Fo2 + 2Fc2)/3
S = 1.02(Δ/σ)max = 0.001
7637 reflectionsΔρmax = 1.26 e Å3
524 parametersΔρmin = 1.14 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.36001 (3)0.69163 (2)0.20766 (2)0.03808 (10)
Ag20.84941 (2)0.34675 (2)0.15598 (2)0.03555 (10)
C10.7886 (3)0.0782 (3)0.2419 (3)0.0344 (9)
H10.86220.07930.20920.041*
C20.7387 (3)0.0236 (4)0.3025 (3)0.0416 (10)
H20.77740.09060.31190.05*
C30.6309 (3)0.0263 (3)0.3495 (3)0.0331 (9)
H30.59390.0950.39170.04*
C40.5793 (3)0.0730 (3)0.3334 (2)0.0232 (7)
C50.6347 (3)0.1724 (3)0.2714 (3)0.0262 (7)
H50.59760.24050.26040.031*
C60.3735 (3)0.4362 (3)0.3237 (3)0.0270 (7)
H60.42210.44040.2620.032*
C70.3625 (3)0.3381 (3)0.4051 (3)0.0225 (7)
C80.2946 (3)0.3296 (3)0.4961 (3)0.0320 (8)
H80.28780.26250.55320.038*
C90.2365 (3)0.4220 (3)0.5015 (3)0.0360 (9)
H90.18820.41950.56280.043*
C100.2492 (3)0.5179 (3)0.4170 (3)0.0278 (8)
H100.2080.58070.42120.033*
C110.6645 (3)0.1116 (3)0.0124 (3)0.0321 (8)
H110.73790.11860.04720.039*
C120.6328 (3)0.0247 (3)0.0782 (3)0.0354 (9)
H120.68370.02780.10440.043*
C130.5271 (3)0.0141 (3)0.1306 (3)0.0286 (8)
H130.5030.04570.19280.034*
C140.4575 (3)0.0939 (3)0.0891 (2)0.0211 (7)
C150.4929 (3)0.1774 (3)0.0027 (3)0.0256 (7)
H150.44310.230.03090.031*
C160.1428 (3)0.5719 (3)0.0748 (3)0.0300 (8)
H160.11190.6430.06590.036*
C170.1601 (3)0.5081 (3)0.1694 (3)0.0299 (8)
H170.14180.53530.22420.036*
C180.2046 (3)0.4040 (3)0.1833 (3)0.0258 (7)
H180.21730.35820.24740.031*
C190.2297 (3)0.3695 (3)0.1011 (2)0.0218 (7)
C200.2105 (3)0.4366 (3)0.0087 (3)0.0266 (7)
H200.2280.41080.0470.032*
C210.2751 (3)0.1529 (3)0.3445 (3)0.0296 (8)
H210.24230.11650.2890.036*
C220.2405 (3)0.1309 (3)0.4328 (3)0.0225 (7)
C230.2852 (3)0.1838 (3)0.5154 (3)0.0312 (8)
H230.26190.1690.57680.037*
C240.3644 (3)0.2583 (3)0.5059 (3)0.0339 (8)
H240.3960.29780.56160.041*
C250.3974 (3)0.2754 (3)0.4152 (3)0.0342 (9)
H250.45370.32570.40890.041*
C260.0237 (3)0.2324 (3)0.3228 (3)0.0242 (7)
H260.02160.17820.29110.029*
C270.0233 (2)0.2094 (3)0.4048 (2)0.0220 (7)
C280.0217 (3)0.2848 (3)0.4530 (3)0.0300 (8)
H280.05250.2690.51050.036*
C290.0270 (3)0.3855 (3)0.4139 (3)0.0332 (8)
H290.02860.44130.44360.04*
C300.0731 (3)0.4041 (3)0.3320 (3)0.0313 (8)
H300.10660.47310.30660.038*
C311.0562 (4)0.1827 (6)0.0471 (5)0.0749 (16)
C321.1295 (5)0.1166 (7)0.0001 (6)0.1019 (19)
H32A1.19560.16090.03940.153*
H32B1.09550.09440.04530.153*
H32C1.14720.04970.05250.153*
Cl10.03078 (8)0.76483 (10)0.24928 (8)0.0452 (3)
N10.1922 (2)0.1138 (2)0.2715 (2)0.0219 (6)
N20.2732 (2)0.1052 (2)0.4314 (2)0.0211 (6)
N30.3880 (2)0.2085 (2)0.2408 (2)0.0206 (6)
N40.7390 (2)0.1751 (3)0.2267 (2)0.0294 (7)
N50.3177 (2)0.5259 (2)0.3291 (2)0.0275 (6)
N60.0724 (2)0.3285 (2)0.2866 (2)0.0267 (6)
N70.3535 (3)0.2238 (3)0.3342 (3)0.0366 (8)
N80.1680 (2)0.5370 (2)0.0047 (2)0.0288 (7)
N90.5952 (2)0.1868 (2)0.0532 (2)0.0287 (7)
N101.0017 (3)0.2365 (3)0.0801 (3)0.0456 (9)
O10.27683 (19)0.26849 (19)0.10145 (17)0.0243 (5)
O20.34907 (18)0.08496 (18)0.14024 (17)0.0229 (5)
O40.15546 (17)0.05914 (19)0.44101 (17)0.0240 (5)
O50.47213 (18)0.06661 (19)0.38458 (17)0.0240 (5)
O60.42629 (18)0.24837 (19)0.39563 (17)0.0230 (5)
O80.0085 (9)0.7445 (11)0.1786 (8)0.274 (7)
O90.1331 (6)0.7768 (8)0.2082 (8)0.201 (4)
O100.0422 (9)0.6658 (6)0.3299 (5)0.196 (4)
O110.0149 (7)0.8409 (6)0.2876 (4)0.167 (4)
O120.06677 (18)0.10478 (19)0.44301 (17)0.0248 (5)
P10.30036 (6)0.16942 (7)0.19658 (6)0.01872 (18)
P20.17895 (6)0.07138 (7)0.39105 (6)0.01925 (18)
P30.38372 (6)0.15770 (7)0.35924 (6)0.01849 (18)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0476 (2)0.02513 (16)0.02605 (16)0.00634 (13)0.00819 (13)0.00058 (12)
Ag20.03369 (17)0.03801 (18)0.02685 (16)0.01167 (13)0.01067 (12)0.00034 (12)
C10.0218 (18)0.045 (2)0.0291 (19)0.0090 (16)0.0008 (15)0.0081 (17)
C20.029 (2)0.039 (2)0.040 (2)0.0171 (17)0.0006 (17)0.0010 (18)
C30.029 (2)0.0283 (19)0.0294 (19)0.0096 (16)0.0019 (15)0.0010 (15)
C40.0181 (16)0.0310 (18)0.0196 (16)0.0059 (14)0.0057 (13)0.0073 (14)
C50.0214 (17)0.0267 (18)0.0286 (18)0.0052 (14)0.0068 (14)0.0072 (15)
C60.0292 (19)0.0242 (17)0.0264 (18)0.0021 (14)0.0008 (14)0.0107 (14)
C70.0205 (17)0.0222 (17)0.0265 (17)0.0009 (13)0.0045 (14)0.0105 (14)
C80.036 (2)0.0261 (19)0.0259 (18)0.0010 (16)0.0000 (16)0.0031 (15)
C90.038 (2)0.033 (2)0.0287 (19)0.0044 (17)0.0072 (16)0.0109 (16)
C100.0271 (18)0.0229 (17)0.0327 (19)0.0017 (14)0.0020 (15)0.0116 (15)
C110.0225 (18)0.044 (2)0.0285 (19)0.0067 (16)0.0018 (15)0.0137 (17)
C120.033 (2)0.041 (2)0.0293 (19)0.0185 (17)0.0097 (16)0.0093 (17)
C130.0322 (19)0.0280 (18)0.0204 (17)0.0098 (15)0.0032 (14)0.0048 (14)
C140.0200 (16)0.0234 (17)0.0203 (16)0.0035 (13)0.0026 (13)0.0095 (13)
C150.0260 (18)0.0273 (18)0.0217 (17)0.0083 (14)0.0043 (14)0.0077 (14)
C160.032 (2)0.0244 (18)0.0318 (19)0.0094 (15)0.0089 (16)0.0078 (15)
C170.031 (2)0.0308 (19)0.0288 (19)0.0070 (16)0.0060 (15)0.0122 (16)
C180.0248 (18)0.0266 (18)0.0223 (17)0.0040 (14)0.0062 (14)0.0038 (14)
C190.0171 (16)0.0193 (16)0.0243 (17)0.0049 (13)0.0026 (13)0.0037 (13)
C200.0268 (18)0.0263 (18)0.0235 (17)0.0038 (14)0.0055 (14)0.0051 (14)
C210.038 (2)0.0183 (17)0.0281 (18)0.0021 (15)0.0064 (16)0.0034 (14)
C220.0198 (16)0.0182 (16)0.0268 (17)0.0025 (13)0.0031 (13)0.0053 (14)
C230.0254 (19)0.037 (2)0.0310 (19)0.0022 (16)0.0084 (15)0.0101 (16)
C240.029 (2)0.035 (2)0.039 (2)0.0029 (16)0.0155 (17)0.0102 (17)
C250.029 (2)0.0258 (19)0.049 (2)0.0049 (15)0.0095 (17)0.0139 (17)
C260.0186 (16)0.0252 (17)0.0265 (17)0.0033 (13)0.0037 (14)0.0074 (14)
C270.0133 (15)0.0249 (17)0.0220 (16)0.0024 (13)0.0012 (13)0.0046 (14)
C280.0209 (17)0.043 (2)0.0266 (18)0.0065 (15)0.0038 (14)0.0147 (16)
C290.031 (2)0.033 (2)0.040 (2)0.0086 (16)0.0060 (17)0.0201 (17)
C300.0259 (19)0.0264 (19)0.038 (2)0.0088 (15)0.0026 (16)0.0100 (16)
C310.041 (2)0.117 (4)0.113 (4)0.043 (3)0.037 (3)0.091 (4)
C320.066 (3)0.142 (5)0.141 (5)0.048 (3)0.038 (3)0.099 (4)
Cl10.0334 (5)0.0687 (7)0.0384 (5)0.0136 (5)0.0093 (4)0.0255 (5)
N10.0180 (14)0.0259 (15)0.0187 (14)0.0009 (11)0.0037 (11)0.0043 (11)
N20.0189 (14)0.0227 (14)0.0183 (13)0.0039 (11)0.0027 (11)0.0042 (11)
N30.0153 (13)0.0194 (13)0.0217 (14)0.0005 (11)0.0001 (11)0.0026 (11)
N40.0215 (15)0.0365 (17)0.0285 (16)0.0039 (13)0.0065 (12)0.0091 (13)
N50.0317 (16)0.0207 (14)0.0266 (15)0.0023 (12)0.0025 (13)0.0065 (12)
N60.0216 (15)0.0279 (15)0.0291 (16)0.0050 (12)0.0072 (12)0.0074 (13)
N70.048 (2)0.0224 (16)0.0385 (18)0.0076 (14)0.0066 (16)0.0125 (14)
N80.0334 (17)0.0250 (15)0.0245 (15)0.0072 (13)0.0104 (13)0.0027 (12)
N90.0290 (16)0.0298 (16)0.0215 (15)0.0044 (13)0.0015 (12)0.0066 (12)
N100.0357 (19)0.050 (2)0.043 (2)0.0098 (17)0.0028 (16)0.0114 (18)
O10.0291 (13)0.0214 (12)0.0181 (11)0.0075 (10)0.0038 (10)0.0032 (9)
O20.0202 (12)0.0224 (12)0.0226 (12)0.0010 (9)0.0005 (9)0.0066 (10)
O40.0164 (11)0.0206 (12)0.0272 (12)0.0007 (9)0.0008 (9)0.0022 (10)
O50.0173 (11)0.0229 (12)0.0277 (12)0.0062 (9)0.0054 (10)0.0043 (10)
O60.0195 (11)0.0220 (12)0.0285 (12)0.0046 (9)0.0072 (10)0.0094 (10)
O80.304 (12)0.442 (16)0.266 (10)0.250 (12)0.233 (10)0.283 (12)
O90.101 (5)0.226 (9)0.292 (11)0.062 (5)0.074 (6)0.174 (9)
O100.373 (13)0.128 (5)0.104 (5)0.138 (7)0.080 (7)0.060 (4)
O110.259 (8)0.165 (6)0.094 (4)0.163 (6)0.061 (5)0.072 (4)
O120.0173 (11)0.0270 (12)0.0209 (12)0.0041 (9)0.0003 (9)0.0001 (10)
P10.0169 (4)0.0188 (4)0.0166 (4)0.0034 (3)0.0020 (3)0.0030 (3)
P20.0147 (4)0.0202 (4)0.0180 (4)0.0025 (3)0.0013 (3)0.0024 (3)
P30.0155 (4)0.0177 (4)0.0198 (4)0.0029 (3)0.0034 (3)0.0041 (3)
Geometric parameters (Å, º) top
Ag1—N9i2.191 (3)C20—N81.335 (5)
Ag1—N52.223 (3)C20—H200.95
Ag1—N7ii2.410 (3)C21—N71.334 (5)
Ag2—N8i2.221 (3)C21—C221.371 (5)
Ag2—N6iii2.258 (3)C21—H210.95
Ag2—N42.436 (3)C22—C231.379 (5)
Ag2—N102.610 (4)C22—O41.397 (4)
C1—N41.333 (5)C23—C241.372 (5)
C1—C21.378 (6)C23—H230.95
C1—H10.95C24—C251.372 (6)
C2—C31.387 (5)C24—H240.95
C2—H20.95C25—N71.352 (5)
C3—C41.371 (5)C25—H250.95
C3—H30.95C26—N61.337 (4)
C4—C51.388 (5)C26—C271.378 (5)
C4—O51.391 (4)C26—H260.95
C5—N41.339 (4)C27—C281.368 (5)
C5—H50.95C27—O121.395 (4)
C6—N51.336 (4)C28—C291.389 (5)
C6—C71.372 (5)C28—H280.95
C6—H60.95C29—C301.376 (6)
C7—C81.375 (5)C29—H290.95
C7—O61.401 (4)C30—N61.341 (5)
C8—C91.378 (5)C30—H300.95
C8—H80.95C31—N101.103 (6)
C9—C101.378 (5)C31—C321.446 (7)
C9—H90.95C32—H32A0.98
C10—N51.344 (5)C32—H32B0.98
C10—H100.95C32—H32C0.98
C11—N91.342 (5)Cl1—O91.299 (6)
C11—C121.378 (5)Cl1—O111.330 (5)
C11—H110.95Cl1—O81.334 (7)
C12—C131.379 (5)Cl1—O101.415 (6)
C12—H120.95N1—P11.572 (3)
C13—C141.380 (5)N1—P21.587 (3)
C13—H130.95N2—P31.571 (3)
C14—C151.374 (5)N2—P21.584 (3)
C14—O21.404 (4)N3—P11.581 (3)
C15—N91.333 (4)N3—P31.590 (3)
C15—H150.95N6—Ag2iv2.258 (3)
C16—N81.340 (5)N7—Ag1v2.410 (3)
C16—C171.382 (5)N8—Ag2i2.221 (3)
C16—H160.95N9—Ag1i2.191 (3)
C17—C181.386 (5)O1—P11.583 (2)
C17—H170.95O2—P11.592 (2)
C18—C191.373 (5)O4—P21.583 (2)
C18—H180.95O5—P31.586 (2)
C19—C201.377 (5)O6—P31.590 (2)
C19—O11.396 (4)O12—P21.573 (2)
N9i—Ag1—N5157.77 (11)C25—C24—H24120.3
N9i—Ag1—N7ii112.04 (11)C23—C24—H24120.3
N5—Ag1—N7ii90.15 (11)N7—C25—C24122.9 (3)
N8i—Ag2—N6iii143.27 (11)N7—C25—H25118.5
N8i—Ag2—N4116.52 (11)C24—C25—H25118.5
N6iii—Ag2—N4100.00 (10)N6—C26—C27122.0 (3)
N8i—Ag2—N1093.57 (11)N6—C26—H26119.0
N6iii—Ag2—N1091.53 (11)C27—C26—H26119.0
N4—Ag2—N1087.71 (11)C28—C27—C26120.9 (3)
N4—C1—C2123.5 (3)C28—C27—O12119.8 (3)
N4—C1—H1118.3C26—C27—O12119.2 (3)
C2—C1—H1118.3C27—C28—C29117.0 (3)
C1—C2—C3118.7 (4)C27—C28—H28121.5
C1—C2—H2120.6C29—C28—H28121.5
C3—C2—H2120.6C30—C29—C28119.7 (3)
C4—C3—C2118.0 (4)C30—C29—H29120.1
C4—C3—H3121.0C28—C29—H29120.1
C2—C3—H3121.0N6—C30—C29122.6 (3)
C3—C4—C5120.1 (3)N6—C30—H30118.7
C3—C4—O5116.0 (3)C29—C30—H30118.7
C5—C4—O5123.9 (3)N10—C31—C32177.4 (9)
N4—C5—C4121.9 (3)C31—C32—H32A109.5
N4—C5—H5119.0C31—C32—H32B109.5
C4—C5—H5119.0H32A—C32—H32B109.5
N5—C6—C7121.7 (3)C31—C32—H32C109.5
N5—C6—H6119.1H32A—C32—H32C109.5
C7—C6—H6119.1H32B—C32—H32C109.5
C6—C7—C8120.8 (3)O9—Cl1—O11118.2 (5)
C6—C7—O6118.9 (3)O9—Cl1—O8101.3 (7)
C8—C7—O6120.3 (3)O11—Cl1—O8119.2 (5)
C7—C8—C9117.5 (3)O9—Cl1—O1094.1 (6)
C7—C8—H8121.2O11—Cl1—O10109.0 (4)
C9—C8—H8121.2O8—Cl1—O10112.3 (7)
C10—C9—C8119.4 (3)P1—N1—P2121.97 (18)
C10—C9—H9120.3P3—N2—P2122.34 (17)
C8—C9—H9120.3P1—N3—P3119.45 (17)
N5—C10—C9122.5 (3)C1—N4—C5117.8 (3)
N5—C10—H10118.8C1—N4—Ag2118.2 (2)
C9—C10—H10118.8C5—N4—Ag2122.2 (2)
N9—C11—C12122.3 (3)C6—N5—C10118.1 (3)
N9—C11—H11118.9C6—N5—Ag1120.5 (2)
C12—C11—H11118.9C10—N5—Ag1120.3 (2)
C11—C12—C13119.8 (3)C26—N6—C30117.8 (3)
C11—C12—H12120.1C26—N6—Ag2iv116.4 (2)
C13—C12—H12120.1C30—N6—Ag2iv125.8 (2)
C12—C13—C14117.3 (3)C21—N7—C25117.4 (3)
C12—C13—H13121.4C21—N7—Ag1v117.9 (3)
C14—C13—H13121.4C25—N7—Ag1v120.0 (2)
C15—C14—C13120.5 (3)C20—N8—C16118.5 (3)
C15—C14—O2120.8 (3)C20—N8—Ag2i122.4 (2)
C13—C14—O2118.6 (3)C16—N8—Ag2i118.9 (2)
N9—C15—C14121.9 (3)C15—N9—C11118.3 (3)
N9—C15—H15119.0C15—N9—Ag1i119.3 (2)
C14—C15—H15119.0C11—N9—Ag1i121.9 (2)
N8—C16—C17122.3 (3)C31—N10—Ag2171.4 (4)
N8—C16—H16118.9C19—O1—P1126.9 (2)
C17—C16—H16118.9C14—O2—P1121.2 (2)
C16—C17—C18119.3 (3)C22—O4—P2118.8 (2)
C16—C17—H17120.4C4—O5—P3127.3 (2)
C18—C17—H17120.4C7—O6—P3120.5 (2)
C19—C18—C17117.7 (3)C27—O12—P2123.0 (2)
C19—C18—H18121.2N1—P1—N3118.28 (15)
C17—C18—H18121.2N1—P1—O1110.62 (14)
C18—C19—C20120.5 (3)N3—P1—O1109.98 (14)
C18—C19—O1125.0 (3)N1—P1—O2106.77 (14)
C20—C19—O1114.5 (3)N3—P1—O2111.05 (13)
N8—C20—C19121.8 (3)O1—P1—O298.26 (12)
N8—C20—H20119.1O12—P2—O495.58 (12)
C19—C20—H20119.1O12—P2—N2110.86 (14)
N7—C21—C22122.1 (3)O4—P2—N2109.71 (14)
N7—C21—H21119.0O12—P2—N1110.51 (13)
C22—C21—H21119.0O4—P2—N1111.84 (14)
C21—C22—C23120.5 (3)N2—P2—N1116.41 (15)
C21—C22—O4119.9 (3)N2—P3—O5107.41 (13)
C23—C22—O4119.6 (3)N2—P3—N3117.46 (15)
C24—C23—C22117.7 (4)O5—P3—N3111.64 (14)
C24—C23—H23121.1N2—P3—O6109.51 (14)
C22—C23—H23121.1O5—P3—O699.20 (12)
C25—C24—C23119.3 (4)N3—P3—O6110.04 (14)
N4—C1—C2—C30.8 (7)C17—C16—N8—C200.6 (6)
C1—C2—C3—C40.2 (6)C17—C16—N8—Ag2i174.3 (3)
C2—C3—C4—C50.2 (6)C14—C15—N9—C110.2 (5)
C2—C3—C4—O5178.1 (3)C14—C15—N9—Ag1i172.0 (3)
C3—C4—C5—N40.7 (5)C12—C11—N9—C151.4 (6)
O5—C4—C5—N4177.3 (3)C12—C11—N9—Ag1i170.2 (3)
N5—C6—C7—C81.2 (6)C18—C19—O1—P16.4 (5)
N5—C6—C7—O6177.7 (3)C20—C19—O1—P1174.7 (2)
C6—C7—C8—C91.5 (6)C15—C14—O2—P174.2 (4)
O6—C7—C8—C9178.0 (3)C13—C14—O2—P1108.6 (3)
C7—C8—C9—C100.5 (6)C21—C22—O4—P279.4 (4)
C8—C9—C10—N51.0 (6)C23—C22—O4—P2104.1 (3)
N9—C11—C12—C131.0 (6)C3—C4—O5—P3161.5 (3)
C11—C12—C13—C140.8 (6)C5—C4—O5—P320.4 (5)
C12—C13—C14—C152.3 (5)C6—C7—O6—P391.7 (3)
C12—C13—C14—O2179.5 (3)C8—C7—O6—P391.7 (4)
C13—C14—C15—N92.1 (5)C28—C27—O12—P2106.4 (3)
O2—C14—C15—N9179.2 (3)C26—C27—O12—P277.8 (4)
N8—C16—C17—C180.4 (6)P2—N1—P1—N314.0 (3)
C16—C17—C18—C190.2 (5)P2—N1—P1—O1142.11 (18)
C17—C18—C19—C200.2 (5)P2—N1—P1—O2112.0 (2)
C17—C18—C19—O1178.6 (3)P3—N3—P1—N119.7 (3)
C18—C19—C20—N80.5 (5)P3—N3—P1—O1148.10 (17)
O1—C19—C20—N8178.5 (3)P3—N3—P1—O2104.22 (19)
N7—C21—C22—C231.1 (6)C19—O1—P1—N166.7 (3)
N7—C21—C22—O4177.6 (3)C19—O1—P1—N365.8 (3)
C21—C22—C23—C240.1 (5)C19—O1—P1—O2178.2 (3)
O4—C22—C23—C24176.4 (3)C14—O2—P1—N1162.7 (2)
C22—C23—C24—C251.5 (6)C14—O2—P1—N332.5 (3)
C23—C24—C25—N71.7 (6)C14—O2—P1—O182.7 (2)
N6—C26—C27—C280.2 (5)C27—O12—P2—O4158.4 (3)
N6—C26—C27—O12176.0 (3)C27—O12—P2—N288.0 (3)
C26—C27—C28—C291.4 (5)C27—O12—P2—N142.6 (3)
O12—C27—C28—C29177.2 (3)C22—O4—P2—O12168.7 (2)
C27—C28—C29—C301.6 (5)C22—O4—P2—N254.2 (3)
C28—C29—C30—N60.6 (6)C22—O4—P2—N176.5 (3)
C2—C1—N4—C51.4 (6)P3—N2—P2—O12138.77 (18)
C2—C1—N4—Ag2163.9 (3)P3—N2—P2—O4116.93 (19)
C4—C5—N4—C11.3 (5)P3—N2—P2—N111.3 (3)
C4—C5—N4—Ag2163.4 (3)P1—N1—P2—O12137.19 (19)
C7—C6—N5—C100.2 (5)P1—N1—P2—O4117.6 (2)
C7—C6—N5—Ag1168.0 (3)P1—N1—P2—N29.6 (3)
C9—C10—N5—C61.3 (6)P2—N2—P3—O5109.5 (2)
C9—C10—N5—Ag1166.9 (3)P2—N2—P3—N317.2 (3)
C27—C26—N6—C300.8 (5)P2—N2—P3—O6143.66 (18)
C27—C26—N6—Ag2iv177.4 (2)C4—O5—P3—N2173.8 (3)
C29—C30—N6—C260.6 (5)C4—O5—P3—N343.7 (3)
C29—C30—N6—Ag2iv177.5 (3)C4—O5—P3—O672.2 (3)
C22—C21—N7—C250.9 (5)P1—N3—P3—N221.2 (3)
C22—C21—N7—Ag1v156.8 (3)P1—N3—P3—O5103.52 (19)
C24—C25—N7—C210.5 (6)P1—N3—P3—O6147.34 (17)
C24—C25—N7—Ag1v154.8 (3)C7—O6—P3—N256.3 (3)
C19—C20—N8—C160.6 (5)C7—O6—P3—O5168.5 (2)
C19—C20—N8—Ag2i174.1 (3)C7—O6—P3—N374.3 (3)
Symmetry codes: (i) x+1, y+1, z; (ii) x, y+1, z; (iii) x+1, y, z; (iv) x1, y, z; (v) x, y1, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C1—H1···N100.952.633.367 (5)135
C5—H5···O60.952.613.171 (4)118
C11—H11···O9i0.952.503.311 (8)144
C16—H16···O80.952.623.382 (9)138
C24—H24···O6vi0.952.633.316 (4)129
Symmetry codes: (i) x+1, y+1, z; (vi) x+1, y, z+1.
(CCDC1422434) top
Crystal data top
C51H45Ag3N9O15P3S3Z = 2
Mr = 1536.66F(000) = 1536
Triclinic, P1Dx = 1.730 Mg m3
a = 13.1577 (10) ÅMo Kα radiation, λ = 0.71073 Å
b = 13.7793 (12) ÅCell parameters from 9901 reflections
c = 18.4731 (16) Åθ = 2.3–27.3°
α = 93.043 (5)°µ = 1.25 mm1
β = 104.723 (4)°T = 173 K
γ = 112.509 (4)°Block, colourless
V = 2949.8 (4) Å30.34 × 0.20 × 0.10 mm
Data collection top
Bruker APEX II QUAZAR three-circle
diffractometer
12997 independent reflections
Multilayer QUAZAR mirrors monochromator9286 reflections with I > 2σ(I)
Detector resolution: 8.3333 pixels mm-1Rint = 0.047
φ and ω scansθmax = 27.1°, θmin = 1.2°
Absorption correction: multi-scan
SADABS (Bruker AXS)
h = 1616
Tmin = 0.68, Tmax = 0.88k = 1713
49496 measured reflectionsl = 2323
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.039Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.083H atoms treated by a mixture of independent and constrained refinement
S = 1.06 w = 1/[σ2(Fo2) + (0.032P)2 + 0.7896P]
where P = (Fo2 + 2Fc2)/3
12997 reflections(Δ/σ)max = 0.001
760 parametersΔρmax = 0.73 e Å3
0 restraintsΔρmin = 0.98 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.86677 (2)0.10426 (2)0.463092 (16)0.03871 (9)
Ag20.58943 (2)0.56982 (2)0.574709 (16)0.03737 (8)
Ag30.34251 (2)0.44369 (2)0.183739 (18)0.04328 (9)
C10.7352 (2)0.0810 (2)0.63802 (18)0.0247 (7)
C20.6525 (2)0.1228 (3)0.6324 (2)0.0283 (8)
H20.62630.14750.58730.034*
C30.6090 (3)0.1282 (3)0.6922 (2)0.0352 (9)
H30.5530.15690.68780.042*
C40.6453 (3)0.0926 (3)0.7584 (2)0.0361 (9)
C50.7267 (3)0.0497 (3)0.7628 (2)0.0357 (9)
H50.75220.02410.80760.043*
C60.7710 (3)0.0437 (3)0.70286 (19)0.0300 (8)
H60.8260.01390.70670.036*
C70.5987 (3)0.1013 (3)0.8235 (2)0.0538 (11)
H7A0.64310.17250.85430.081*
H7B0.60490.04750.85490.081*
H7C0.51760.08950.80380.081*
C80.6745 (2)0.6809 (2)0.29135 (17)0.0220 (7)
C90.7802 (3)0.6772 (3)0.32031 (19)0.0278 (8)
H90.79660.65140.36660.033*
C100.8624 (3)0.7108 (3)0.2824 (2)0.0317 (8)
H100.93530.70880.30330.038*
C110.8397 (3)0.7475 (3)0.2141 (2)0.0302 (8)
C120.7329 (3)0.7503 (3)0.18590 (19)0.0350 (9)
H120.71560.77490.13920.042*
C130.6509 (3)0.7182 (3)0.22403 (19)0.0316 (8)
H130.57860.72190.2040.038*
C140.9284 (3)0.7862 (3)0.1724 (2)0.0475 (10)
H14A0.90370.73630.12510.071*
H14B1.00250.79060.20430.071*
H14C0.93680.85680.16050.071*
C150.2318 (3)0.1376 (2)0.08317 (17)0.0236 (7)
C160.3459 (3)0.1548 (3)0.11074 (19)0.0291 (8)
H160.38740.18610.16230.035*
C170.4005 (3)0.1266 (3)0.06363 (19)0.0316 (8)
H170.47930.1390.08340.038*
C180.3428 (3)0.0809 (3)0.0115 (2)0.0397 (9)
C190.2277 (3)0.0638 (4)0.0376 (2)0.0536 (12)
H190.18590.03230.08910.064*
C200.1717 (3)0.0910 (3)0.00856 (19)0.0402 (9)
H200.09260.07780.01090.048*
C210.4036 (4)0.0552 (4)0.0630 (2)0.0718 (15)
H21A0.48690.08840.03810.108*
H21B0.38590.08260.11040.108*
H21C0.37780.02230.07430.108*
C220.6475 (2)0.4272 (2)0.12852 (17)0.0178 (7)
C230.5741 (2)0.4424 (2)0.16451 (18)0.0228 (7)
H230.60090.46640.21780.027*
C240.4308 (3)0.3897 (3)0.0510 (2)0.0339 (9)
H240.3540.37590.0230.041*
C250.5008 (3)0.3734 (3)0.01274 (19)0.0378 (9)
H250.47270.34870.04050.045*
C260.6131 (3)0.3935 (3)0.05257 (18)0.0290 (8)
H260.66420.3840.02760.035*
C271.0095 (2)0.4575 (2)0.18151 (16)0.0184 (7)
C281.0308 (2)0.5633 (3)0.19394 (18)0.0249 (7)
H280.9710.58560.19420.03*
C291.1432 (2)0.6364 (3)0.20614 (18)0.0267 (8)
H291.1620.71070.21530.032*
C301.0968 (2)0.4264 (3)0.17936 (17)0.0219 (7)
H301.07960.35250.16950.026*
C311.2274 (2)0.6013 (3)0.20492 (17)0.0254 (7)
H311.30430.65250.21440.031*
C321.1424 (2)0.2823 (3)0.34733 (17)0.0237 (7)
H321.17740.28660.30780.028*
C331.1508 (2)0.2153 (3)0.39806 (18)0.0242 (7)
H331.19270.17380.39290.029*
C341.0433 (2)0.2637 (2)0.46162 (17)0.0215 (7)
H341.00730.25670.50080.026*
C351.0335 (2)0.3335 (2)0.41267 (16)0.0165 (6)
C361.0821 (2)0.3444 (2)0.35400 (17)0.0208 (7)
H361.07470.3920.31970.025*
C370.7640 (2)0.0080 (2)0.34312 (17)0.0232 (7)
H370.71080.00180.37140.028*
C380.8315 (2)0.0761 (2)0.23985 (17)0.0231 (7)
H380.82660.11280.19790.028*
C390.7555 (2)0.0590 (2)0.28185 (17)0.0180 (7)
C400.9155 (2)0.0376 (3)0.26145 (18)0.0254 (7)
H400.96950.04660.23380.031*
C410.9205 (3)0.0139 (3)0.32297 (19)0.0279 (8)
H410.97870.040.33710.033*
C420.7134 (2)0.4840 (2)0.48824 (17)0.0205 (7)
H420.69330.52620.45290.025*
C430.7861 (2)0.4385 (2)0.47759 (16)0.0179 (7)
C440.8163 (2)0.3764 (3)0.52711 (17)0.0235 (7)
H440.86530.34340.51980.028*
C450.7722 (2)0.3638 (3)0.58820 (18)0.0251 (7)
H450.7920.32250.62430.03*
C460.7001 (2)0.4106 (3)0.59667 (18)0.0252 (7)
H460.67030.40070.63880.03*
C470.4868 (2)0.2857 (2)0.34167 (17)0.0217 (7)
H470.48740.33330.30620.026*
C480.5235 (2)0.2066 (2)0.33056 (16)0.0177 (7)
C490.5249 (2)0.1375 (2)0.38088 (17)0.0215 (7)
H490.55280.08440.37440.026*
C500.4842 (2)0.1480 (3)0.44145 (18)0.0271 (8)
H500.4810.10.47670.033*
C510.4484 (2)0.2280 (3)0.45054 (18)0.0271 (8)
H510.42150.23480.49280.032*
N10.77060 (18)0.26846 (19)0.35335 (13)0.0168 (5)
N20.71883 (18)0.26278 (19)0.20177 (13)0.0175 (5)
N30.88471 (18)0.44020 (19)0.29702 (13)0.0190 (6)
N40.66990 (19)0.4705 (2)0.54705 (15)0.0244 (6)
N50.4651 (2)0.4242 (2)0.12602 (16)0.0279 (6)
N60.8469 (2)0.0287 (2)0.36397 (14)0.0257 (6)
N70.4501 (2)0.2967 (2)0.40185 (15)0.0255 (6)
N81.20544 (19)0.4975 (2)0.19085 (14)0.0252 (6)
N91.1031 (2)0.2049 (2)0.45489 (14)0.0240 (6)
O10.8309 (2)0.0059 (2)0.56636 (15)0.0502 (7)
O20.6994 (2)0.0602 (2)0.49362 (14)0.0529 (8)
O30.8857 (2)0.1825 (2)0.57315 (15)0.0518 (7)
O40.2494 (2)0.2530 (2)0.20466 (13)0.0428 (6)
O50.0869 (3)0.2149 (3)0.09551 (17)0.0961 (13)
O60.0978 (3)0.0774 (2)0.16685 (19)0.0736 (10)
O70.5104 (2)0.51953 (18)0.31525 (14)0.0382 (6)
O80.49068 (18)0.68632 (19)0.31286 (14)0.0387 (6)
O90.6277 (2)0.6634 (2)0.41936 (13)0.0409 (6)
O100.76150 (15)0.45413 (17)0.17082 (12)0.0261 (5)
O110.90078 (15)0.37489 (16)0.16955 (11)0.0201 (5)
O120.97751 (15)0.39769 (15)0.42712 (11)0.0180 (4)
O130.82933 (15)0.46465 (16)0.41622 (11)0.0189 (4)
O140.55964 (15)0.20175 (16)0.26559 (10)0.0178 (4)
O150.66361 (15)0.09075 (15)0.26215 (11)0.0184 (5)
P10.86125 (6)0.38790 (6)0.36816 (4)0.01610 (17)
P20.68599 (6)0.21243 (6)0.27196 (4)0.01555 (17)
P30.81316 (6)0.37967 (6)0.21388 (4)0.01585 (17)
S10.79247 (7)0.07898 (7)0.56073 (5)0.0282 (2)
S20.16059 (7)0.17369 (8)0.14203 (5)0.0354 (2)
S30.56755 (6)0.63516 (7)0.33881 (5)0.02575 (19)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.04902 (17)0.0465 (2)0.03586 (17)0.03304 (15)0.01404 (13)0.02035 (14)
Ag20.03027 (14)0.04377 (19)0.04484 (17)0.02369 (13)0.01167 (12)0.00589 (14)
Ag30.02330 (13)0.0461 (2)0.0722 (2)0.02035 (13)0.02361 (14)0.01282 (16)
C10.0234 (15)0.0190 (19)0.0313 (19)0.0066 (14)0.0106 (14)0.0041 (15)
C20.0233 (16)0.0200 (19)0.038 (2)0.0070 (14)0.0066 (15)0.0065 (16)
C30.0262 (17)0.021 (2)0.059 (3)0.0059 (15)0.0199 (17)0.0010 (18)
C40.0372 (19)0.019 (2)0.050 (2)0.0034 (16)0.0236 (18)0.0021 (18)
C50.041 (2)0.032 (2)0.035 (2)0.0104 (17)0.0169 (17)0.0124 (17)
C60.0284 (17)0.028 (2)0.038 (2)0.0137 (16)0.0127 (15)0.0112 (17)
C70.054 (2)0.042 (3)0.063 (3)0.007 (2)0.037 (2)0.002 (2)
C80.0200 (15)0.0204 (18)0.0250 (17)0.0083 (14)0.0063 (13)0.0023 (14)
C90.0247 (16)0.030 (2)0.0300 (19)0.0157 (15)0.0036 (14)0.0068 (16)
C100.0194 (16)0.028 (2)0.045 (2)0.0101 (15)0.0063 (15)0.0024 (17)
C110.0253 (16)0.022 (2)0.039 (2)0.0050 (15)0.0116 (15)0.0018 (16)
C120.0288 (18)0.043 (2)0.0278 (19)0.0083 (17)0.0080 (15)0.0116 (17)
C130.0222 (16)0.040 (2)0.032 (2)0.0129 (16)0.0065 (15)0.0083 (17)
C140.039 (2)0.040 (2)0.069 (3)0.0129 (19)0.030 (2)0.006 (2)
C150.0280 (16)0.0216 (19)0.0238 (17)0.0103 (14)0.0107 (14)0.0081 (15)
C160.0304 (17)0.030 (2)0.0250 (18)0.0140 (16)0.0021 (14)0.0045 (16)
C170.0260 (17)0.039 (2)0.035 (2)0.0174 (16)0.0102 (15)0.0153 (18)
C180.040 (2)0.060 (3)0.030 (2)0.028 (2)0.0158 (17)0.0117 (19)
C190.045 (2)0.094 (4)0.0186 (19)0.031 (2)0.0036 (17)0.009 (2)
C200.0260 (18)0.064 (3)0.028 (2)0.0189 (18)0.0053 (15)0.0009 (19)
C210.059 (3)0.137 (5)0.042 (3)0.059 (3)0.025 (2)0.010 (3)
C220.0117 (13)0.0161 (17)0.0265 (17)0.0075 (12)0.0039 (12)0.0070 (14)
C230.0216 (15)0.0234 (19)0.0259 (17)0.0114 (14)0.0072 (13)0.0069 (15)
C240.0185 (16)0.034 (2)0.043 (2)0.0088 (15)0.0004 (15)0.0129 (18)
C250.0347 (19)0.051 (3)0.0219 (18)0.0144 (18)0.0044 (15)0.0049 (17)
C260.0324 (18)0.036 (2)0.0272 (19)0.0182 (16)0.0160 (15)0.0083 (16)
C270.0145 (14)0.025 (2)0.0168 (16)0.0066 (13)0.0083 (12)0.0056 (14)
C280.0189 (15)0.029 (2)0.0343 (19)0.0145 (14)0.0125 (14)0.0107 (16)
C290.0221 (16)0.023 (2)0.037 (2)0.0089 (14)0.0124 (14)0.0100 (16)
C300.0182 (14)0.0225 (19)0.0258 (17)0.0070 (13)0.0098 (13)0.0047 (14)
C310.0180 (15)0.028 (2)0.0275 (18)0.0055 (14)0.0083 (13)0.0067 (16)
C320.0177 (15)0.027 (2)0.0240 (17)0.0063 (14)0.0079 (13)0.0007 (15)
C330.0213 (15)0.0234 (19)0.0293 (18)0.0099 (14)0.0085 (14)0.0042 (16)
C340.0176 (14)0.0261 (19)0.0215 (17)0.0091 (14)0.0065 (13)0.0053 (15)
C350.0092 (13)0.0166 (17)0.0208 (16)0.0040 (12)0.0026 (11)0.0009 (14)
C360.0179 (14)0.0253 (19)0.0204 (16)0.0093 (13)0.0064 (13)0.0076 (14)
C370.0229 (15)0.0250 (19)0.0256 (18)0.0118 (14)0.0106 (13)0.0036 (15)
C380.0274 (16)0.0207 (19)0.0229 (17)0.0090 (14)0.0113 (14)0.0051 (14)
C390.0162 (14)0.0140 (17)0.0217 (16)0.0056 (13)0.0035 (12)0.0006 (14)
C400.0239 (16)0.0235 (19)0.0335 (19)0.0107 (14)0.0149 (14)0.0029 (16)
C410.0232 (16)0.027 (2)0.035 (2)0.0143 (15)0.0066 (14)0.0009 (16)
C420.0185 (14)0.0220 (19)0.0223 (17)0.0099 (13)0.0057 (13)0.0034 (14)
C430.0153 (13)0.0170 (18)0.0185 (16)0.0034 (13)0.0058 (12)0.0002 (14)
C440.0229 (15)0.0248 (19)0.0275 (18)0.0119 (14)0.0119 (14)0.0067 (15)
C450.0271 (16)0.0232 (19)0.0247 (17)0.0083 (14)0.0098 (14)0.0074 (15)
C460.0275 (16)0.025 (2)0.0234 (17)0.0084 (15)0.0116 (14)0.0029 (15)
C470.0182 (14)0.0209 (19)0.0272 (18)0.0105 (13)0.0045 (13)0.0055 (14)
C480.0102 (13)0.0204 (18)0.0192 (16)0.0036 (12)0.0040 (12)0.0002 (14)
C490.0190 (15)0.0178 (18)0.0292 (18)0.0080 (13)0.0085 (13)0.0065 (15)
C500.0214 (15)0.028 (2)0.0300 (19)0.0047 (14)0.0112 (14)0.0122 (16)
C510.0197 (15)0.034 (2)0.0254 (18)0.0075 (15)0.0097 (13)0.0019 (16)
N10.0146 (11)0.0171 (14)0.0187 (13)0.0066 (10)0.0046 (10)0.0061 (11)
N20.0155 (11)0.0175 (14)0.0176 (13)0.0057 (11)0.0035 (10)0.0038 (11)
N30.0178 (12)0.0151 (14)0.0216 (14)0.0027 (11)0.0080 (11)0.0041 (11)
N40.0189 (13)0.0280 (17)0.0276 (15)0.0101 (12)0.0094 (11)0.0008 (13)
N50.0163 (13)0.0289 (17)0.0430 (18)0.0115 (12)0.0120 (12)0.0085 (14)
N60.0286 (14)0.0292 (17)0.0271 (15)0.0190 (13)0.0095 (12)0.0084 (13)
N70.0206 (13)0.0296 (17)0.0310 (16)0.0142 (12)0.0102 (12)0.0002 (14)
N80.0173 (12)0.0336 (18)0.0285 (15)0.0123 (12)0.0099 (11)0.0080 (13)
N90.0211 (13)0.0253 (16)0.0284 (15)0.0118 (12)0.0078 (11)0.0084 (13)
O10.0789 (19)0.0547 (18)0.0541 (17)0.0526 (16)0.0381 (15)0.0256 (15)
O20.0459 (15)0.095 (2)0.0318 (15)0.0422 (16)0.0123 (12)0.0165 (15)
O30.0514 (16)0.0449 (18)0.0592 (18)0.0067 (14)0.0364 (14)0.0119 (14)
O40.0478 (15)0.0427 (16)0.0298 (14)0.0090 (13)0.0152 (12)0.0032 (12)
O50.132 (3)0.142 (3)0.051 (2)0.121 (3)0.0082 (19)0.016 (2)
O60.0679 (19)0.0500 (19)0.105 (3)0.0002 (15)0.0702 (19)0.0038 (18)
O70.0465 (14)0.0248 (15)0.0478 (16)0.0102 (12)0.0275 (12)0.0112 (12)
O80.0305 (12)0.0485 (16)0.0559 (16)0.0281 (12)0.0217 (12)0.0261 (13)
O90.0464 (15)0.0612 (18)0.0244 (13)0.0311 (14)0.0121 (11)0.0036 (12)
O100.0130 (10)0.0250 (13)0.0389 (13)0.0087 (9)0.0023 (9)0.0132 (11)
O110.0172 (10)0.0206 (12)0.0249 (12)0.0076 (9)0.0108 (9)0.0021 (9)
O120.0139 (9)0.0191 (12)0.0196 (11)0.0064 (9)0.0035 (8)0.0015 (9)
O130.0227 (10)0.0191 (12)0.0205 (11)0.0116 (9)0.0105 (9)0.0059 (9)
O140.0146 (9)0.0254 (12)0.0174 (11)0.0112 (9)0.0066 (8)0.0038 (9)
O150.0165 (10)0.0134 (12)0.0248 (12)0.0058 (9)0.0055 (9)0.0039 (9)
P10.0132 (3)0.0180 (5)0.0174 (4)0.0066 (3)0.0049 (3)0.0028 (3)
P20.0122 (3)0.0164 (5)0.0186 (4)0.0063 (3)0.0047 (3)0.0032 (3)
P30.0131 (3)0.0194 (5)0.0178 (4)0.0083 (3)0.0064 (3)0.0047 (3)
S10.0269 (4)0.0322 (5)0.0323 (5)0.0164 (4)0.0122 (4)0.0119 (4)
S20.0355 (5)0.0427 (6)0.0341 (5)0.0241 (5)0.0093 (4)0.0012 (4)
S30.0260 (4)0.0300 (5)0.0290 (5)0.0170 (4)0.0115 (4)0.0090 (4)
Geometric parameters (Å, º) top
Ag1—N62.162 (3)C30—N81.341 (4)
Ag1—N9i2.171 (2)C30—H300.95
Ag1—O12.524 (2)C31—N81.342 (4)
Ag2—N42.136 (2)C31—H310.95
Ag2—N7ii2.146 (3)C32—C331.364 (4)
Ag2—Ag2ii3.0865 (6)C32—C361.390 (4)
Ag3—N8iii2.226 (2)C32—H320.95
Ag3—N52.233 (2)C33—N91.341 (4)
Ag3—O42.538 (2)C33—H330.95
C1—C61.373 (4)C34—N91.349 (4)
C1—C21.397 (4)C34—C351.374 (4)
C1—S11.780 (3)C34—H340.95
C2—C31.378 (4)C35—C361.380 (4)
C2—H20.95C35—O121.403 (3)
C3—C41.382 (5)C36—H360.95
C3—H30.95C37—N61.351 (4)
C4—C51.396 (5)C37—C391.367 (4)
C4—C71.502 (5)C37—H370.95
C5—C61.389 (4)C38—C391.376 (4)
C5—H50.95C38—C401.382 (4)
C6—H60.95C38—H380.95
C7—H7A0.98C39—O151.408 (3)
C7—H7B0.98C40—C411.372 (4)
C7—H7C0.98C40—H400.95
C8—C91.379 (4)C41—N61.339 (4)
C8—C131.379 (4)C41—H410.95
C8—S31.776 (3)C42—N41.341 (4)
C9—C101.383 (4)C42—C431.375 (4)
C9—H90.95C42—H420.95
C10—C111.389 (5)C43—C441.374 (4)
C10—H100.95C43—O131.397 (3)
C11—C121.385 (4)C44—C451.384 (4)
C11—C141.505 (4)C44—H440.95
C12—C131.382 (4)C45—C461.369 (4)
C12—H120.95C45—H450.95
C13—H130.95C46—N41.351 (4)
C14—H14A0.98C46—H460.95
C14—H14B0.98C47—N71.343 (4)
C14—H14C0.98C47—C481.377 (4)
C15—C161.377 (4)C47—H470.95
C15—C201.379 (4)C48—C491.367 (4)
C15—S21.768 (3)C48—O141.406 (3)
C16—C171.385 (4)C49—C501.381 (4)
C16—H160.95C49—H490.95
C17—C181.380 (5)C50—C511.371 (4)
C17—H170.95C50—H500.95
C18—C191.387 (5)C51—N71.338 (4)
C18—C211.497 (5)C51—H510.95
C19—C201.382 (5)N1—P21.570 (2)
C19—H190.95N1—P11.578 (2)
C20—H200.95N2—P31.573 (2)
C21—H21A0.98N2—P21.581 (2)
C21—H21B0.98N3—P31.571 (2)
C21—H21C0.98N3—P11.574 (2)
C22—C261.355 (4)N7—Ag2ii2.146 (3)
C22—C231.374 (4)N8—Ag3iv2.226 (2)
C22—O101.394 (3)N9—Ag1i2.171 (2)
C23—N51.347 (4)O1—S11.441 (2)
C23—H230.95O2—S11.434 (2)
C24—N51.341 (4)O3—S11.440 (3)
C24—C251.367 (5)O4—S21.448 (2)
C24—H240.95O5—S21.432 (3)
C25—C261.383 (4)O6—S21.440 (3)
C25—H250.95O7—S31.462 (2)
C26—H260.95O8—S31.444 (2)
C27—C281.370 (4)O9—S31.448 (2)
C27—C301.379 (4)O10—P31.579 (2)
C27—O111.399 (3)O11—P31.5926 (18)
C28—C291.385 (4)O12—P11.5887 (19)
C28—H280.95O13—P11.585 (2)
C29—C311.373 (4)O14—P21.5844 (17)
C29—H290.95O15—P21.579 (2)
N6—Ag1—N9i165.88 (9)N9—C34—H34119.5
N6—Ag1—O1108.18 (9)C35—C34—H34119.5
N9i—Ag1—O185.93 (9)C34—C35—C36121.4 (3)
N4—Ag2—N7ii164.12 (10)C34—C35—O12117.4 (2)
N4—Ag2—Ag2ii78.78 (7)C36—C35—O12121.1 (3)
N7ii—Ag2—Ag2ii107.84 (7)C35—C36—C32116.9 (3)
N8iii—Ag3—N5152.04 (10)C35—C36—H36121.6
N8iii—Ag3—O499.52 (9)C32—C36—H36121.6
N5—Ag3—O498.31 (9)N6—C37—C39120.9 (3)
C6—C1—C2119.6 (3)N6—C37—H37119.5
C6—C1—S1121.7 (2)C39—C37—H37119.5
C2—C1—S1118.8 (3)C39—C38—C40117.0 (3)
C3—C2—C1120.1 (3)C39—C38—H38121.5
C3—C2—H2120.0C40—C38—H38121.5
C1—C2—H2120.0C37—C39—C38121.5 (3)
C2—C3—C4121.2 (3)C37—C39—O15117.2 (2)
C2—C3—H3119.4C38—C39—O15121.3 (3)
C4—C3—H3119.4C41—C40—C38119.6 (3)
C3—C4—C5118.1 (3)C41—C40—H40120.2
C3—C4—C7120.4 (3)C38—C40—H40120.2
C5—C4—C7121.5 (4)N6—C41—C40122.7 (3)
C6—C5—C4121.2 (3)N6—C41—H41118.6
C6—C5—H5119.4C40—C41—H41118.6
C4—C5—H5119.4N4—C42—C43121.9 (3)
C1—C6—C5119.9 (3)N4—C42—H42119.1
C1—C6—H6120.1C43—C42—H42119.1
C5—C6—H6120.1C44—C43—C42120.7 (3)
C4—C7—H7A109.5C44—C43—O13124.1 (2)
C4—C7—H7B109.5C42—C43—O13115.2 (3)
H7A—C7—H7B109.5C43—C44—C45117.2 (3)
C4—C7—H7C109.5C43—C44—H44121.4
H7A—C7—H7C109.5C45—C44—H44121.4
H7B—C7—H7C109.5C46—C45—C44120.2 (3)
C9—C8—C13119.6 (3)C46—C45—H45119.9
C9—C8—S3120.6 (2)C44—C45—H45119.9
C13—C8—S3119.8 (2)N4—C46—C45122.1 (3)
C8—C9—C10120.4 (3)N4—C46—H46118.9
C8—C9—H9119.8C45—C46—H46118.9
C10—C9—H9119.8N7—C47—C48121.0 (3)
C9—C10—C11120.7 (3)N7—C47—H47119.5
C9—C10—H10119.6C48—C47—H47119.5
C11—C10—H10119.6C49—C48—C47121.0 (3)
C12—C11—C10117.9 (3)C49—C48—O14122.5 (3)
C12—C11—C14120.4 (3)C47—C48—O14116.4 (3)
C10—C11—C14121.7 (3)C48—C49—C50117.3 (3)
C13—C12—C11121.7 (3)C48—C49—H49121.3
C13—C12—H12119.1C50—C49—H49121.3
C11—C12—H12119.1C51—C50—C49119.8 (3)
C8—C13—C12119.6 (3)C51—C50—H50120.1
C8—C13—H13120.2C49—C50—H50120.1
C12—C13—H13120.2N7—C51—C50122.2 (3)
C11—C14—H14A109.5N7—C51—H51118.9
C11—C14—H14B109.5C50—C51—H51118.9
H14A—C14—H14B109.5P2—N1—P1121.12 (15)
C11—C14—H14C109.5P3—N2—P2120.29 (15)
H14A—C14—H14C109.5P3—N3—P1121.48 (15)
H14B—C14—H14C109.5C42—N4—C46118.0 (2)
C16—C15—C20119.6 (3)C42—N4—Ag2119.8 (2)
C16—C15—S2121.1 (2)C46—N4—Ag2120.69 (19)
C20—C15—S2119.3 (2)C24—N5—C23117.1 (3)
C15—C16—C17120.3 (3)C24—N5—Ag3120.6 (2)
C15—C16—H16119.9C23—N5—Ag3122.2 (2)
C17—C16—H16119.9C41—N6—C37118.2 (3)
C18—C17—C16121.3 (3)C41—N6—Ag1119.9 (2)
C18—C17—H17119.3C37—N6—Ag1121.8 (2)
C16—C17—H17119.3C51—N7—C47118.6 (3)
C17—C18—C19117.2 (3)C51—N7—Ag2ii120.5 (2)
C17—C18—C21121.1 (3)C47—N7—Ag2ii120.6 (2)
C19—C18—C21121.7 (3)C30—N8—C31117.8 (2)
C20—C19—C18122.3 (3)C30—N8—Ag3iv120.5 (2)
C20—C19—H19118.8C31—N8—Ag3iv121.64 (18)
C18—C19—H19118.8C33—N9—C34117.9 (3)
C15—C20—C19119.3 (3)C33—N9—Ag1i120.0 (2)
C15—C20—H20120.4C34—N9—Ag1i122.0 (2)
C19—C20—H20120.4S1—O1—Ag1127.66 (14)
C18—C21—H21A109.5S2—O4—Ag3119.01 (14)
C18—C21—H21B109.5C22—O10—P3127.51 (19)
H21A—C21—H21B109.5C27—O11—P3122.93 (18)
C18—C21—H21C109.5C35—O12—P1121.03 (17)
H21A—C21—H21C109.5C43—O13—P1124.04 (18)
H21B—C21—H21C109.5C48—O14—P2121.30 (16)
C26—C22—C23121.2 (3)C39—O15—P2121.13 (17)
C26—C22—O10120.0 (2)N3—P1—N1117.65 (13)
C23—C22—O10118.6 (3)N3—P1—O13106.62 (12)
N5—C23—C22121.5 (3)N1—P1—O13111.85 (11)
N5—C23—H23119.2N3—P1—O12111.26 (11)
C22—C23—H23119.2N1—P1—O12108.26 (11)
N5—C24—C25123.4 (3)O13—P1—O1299.76 (10)
N5—C24—H24118.3N1—P2—O15108.54 (12)
C25—C24—H24118.3N1—P2—N2117.78 (12)
C24—C25—C26119.1 (3)O15—P2—N2110.78 (12)
C24—C25—H25120.4N1—P2—O14111.26 (11)
C26—C25—H25120.4O15—P2—O1499.74 (10)
C22—C26—C25117.6 (3)N2—P2—O14107.25 (11)
C22—C26—H26121.2N3—P3—N2119.04 (13)
C25—C26—H26121.2N3—P3—O10107.63 (13)
C28—C27—C30120.6 (3)N2—P3—O10111.44 (11)
C28—C27—O11123.6 (2)N3—P3—O11108.26 (11)
C30—C27—O11115.8 (3)N2—P3—O11106.84 (11)
C27—C28—C29117.3 (3)O10—P3—O11102.31 (11)
C27—C28—H28121.4O2—S1—O3113.12 (17)
C29—C28—H28121.4O2—S1—O1113.63 (17)
C31—C29—C28119.8 (3)O3—S1—O1112.88 (16)
C31—C29—H29120.1O2—S1—C1105.63 (14)
C28—C29—H29120.1O3—S1—C1105.12 (15)
N8—C30—C27121.8 (3)O1—S1—C1105.47 (15)
N8—C30—H30119.1O5—S2—O6112.9 (2)
C27—C30—H30119.1O5—S2—O4112.70 (19)
N8—C31—C29122.6 (3)O6—S2—O4112.09 (18)
N8—C31—H31118.7O5—S2—C15105.99 (17)
C29—C31—H31118.7O6—S2—C15105.86 (15)
C33—C32—C36119.3 (3)O4—S2—C15106.68 (14)
C33—C32—H32120.3O8—S3—O9114.56 (15)
C36—C32—H32120.3O8—S3—O7112.14 (15)
N9—C33—C32123.5 (3)O9—S3—O7111.11 (15)
N9—C33—H33118.2O8—S3—C8105.85 (14)
C32—C33—H33118.2O9—S3—C8106.56 (14)
N9—C34—C35121.0 (3)O7—S3—C8105.93 (14)
C6—C1—C2—C31.2 (5)O1—Ag1—N6—C3738.9 (3)
S1—C1—C2—C3178.1 (2)C50—C51—N7—C470.8 (4)
C1—C2—C3—C40.2 (5)C50—C51—N7—Ag2ii173.3 (2)
C2—C3—C4—C50.7 (5)C48—C47—N7—C510.9 (4)
C2—C3—C4—C7178.7 (3)C48—C47—N7—Ag2ii173.3 (2)
C3—C4—C5—C60.6 (5)C27—C30—N8—C310.2 (4)
C7—C4—C5—C6178.8 (3)C27—C30—N8—Ag3iv178.3 (2)
C2—C1—C6—C51.3 (5)C29—C31—N8—C301.5 (5)
S1—C1—C6—C5178.0 (3)C29—C31—N8—Ag3iv177.0 (2)
C4—C5—C6—C10.4 (5)C32—C33—N9—C340.4 (4)
C13—C8—C9—C100.1 (5)C32—C33—N9—Ag1i175.5 (2)
S3—C8—C9—C10178.7 (3)C35—C34—N9—C331.2 (4)
C8—C9—C10—C110.9 (5)C35—C34—N9—Ag1i174.5 (2)
C9—C10—C11—C120.7 (5)N6—Ag1—O1—S15.8 (2)
C9—C10—C11—C14179.0 (3)N9i—Ag1—O1—S1174.6 (2)
C10—C11—C12—C130.2 (5)N8iii—Ag3—O4—S278.74 (16)
C14—C11—C12—C13178.1 (3)N5—Ag3—O4—S279.65 (16)
C9—C8—C13—C120.8 (5)C26—C22—O10—P393.0 (3)
S3—C8—C13—C12177.8 (3)C23—C22—O10—P391.4 (3)
C11—C12—C13—C81.0 (5)C28—C27—O11—P338.3 (4)
C20—C15—C16—C170.7 (5)C30—C27—O11—P3142.4 (2)
S2—C15—C16—C17179.6 (3)C34—C35—O12—P1117.0 (2)
C15—C16—C17—C180.0 (5)C36—C35—O12—P166.5 (3)
C16—C17—C18—C190.4 (6)C44—C43—O13—P133.7 (4)
C16—C17—C18—C21177.2 (4)C42—C43—O13—P1149.3 (2)
C17—C18—C19—C200.2 (6)C49—C48—O14—P258.5 (3)
C21—C18—C19—C20177.4 (4)C47—C48—O14—P2121.1 (2)
C16—C15—C20—C190.9 (5)C37—C39—O15—P2111.7 (3)
S2—C15—C20—C19179.4 (3)C38—C39—O15—P270.1 (3)
C18—C19—C20—C150.5 (6)P3—N3—P1—N15.2 (2)
C26—C22—C23—N50.3 (5)P3—N3—P1—O13121.29 (16)
O10—C22—C23—N5175.9 (3)P3—N3—P1—O12130.90 (15)
N5—C24—C25—C260.2 (6)P2—N1—P1—N314.2 (2)
C23—C22—C26—C251.0 (5)P2—N1—P1—O13109.72 (16)
O10—C22—C26—C25176.5 (3)P2—N1—P1—O12141.34 (14)
C24—C25—C26—C221.0 (5)C43—O13—P1—N3170.1 (2)
C30—C27—C28—C291.7 (4)C43—O13—P1—N140.2 (2)
O11—C27—C28—C29179.0 (3)C43—O13—P1—O1274.1 (2)
C27—C28—C29—C310.4 (5)C35—O12—P1—N374.5 (2)
C28—C27—C30—N81.5 (5)C35—O12—P1—N156.2 (2)
O11—C27—C30—N8179.2 (2)C35—O12—P1—O13173.2 (2)
C28—C29—C31—N81.2 (5)P1—N1—P2—O15146.38 (14)
C36—C32—C33—N90.4 (5)P1—N1—P2—N219.5 (2)
N9—C34—C35—C361.4 (4)P1—N1—P2—O14104.83 (16)
N9—C34—C35—O12175.1 (2)C39—O15—P2—N147.9 (2)
C34—C35—C36—C320.7 (4)C39—O15—P2—N282.9 (2)
O12—C35—C36—C32175.7 (2)C39—O15—P2—O14164.4 (2)
C33—C32—C36—C350.2 (4)P3—N2—P2—N116.0 (2)
N6—C37—C39—C380.8 (5)P3—N2—P2—O15141.73 (14)
N6—C37—C39—O15177.4 (3)P3—N2—P2—O14110.37 (15)
C40—C38—C39—C371.2 (4)C48—O14—P2—N120.8 (2)
C40—C38—C39—O15177.0 (3)C48—O14—P2—O1593.5 (2)
C39—C38—C40—C410.8 (5)C48—O14—P2—N2151.0 (2)
C38—C40—C41—N60.1 (5)P1—N3—P3—N22.0 (2)
N4—C42—C43—C440.5 (4)P1—N3—P3—O10125.93 (16)
N4—C42—C43—O13176.6 (2)P1—N3—P3—O11124.16 (16)
C42—C43—C44—C451.2 (4)P2—N2—P3—N37.5 (2)
O13—C43—C44—C45175.6 (3)P2—N2—P3—O10118.69 (16)
C43—C44—C45—C461.2 (5)P2—N2—P3—O11130.32 (15)
C44—C45—C46—N40.4 (5)C22—O10—P3—N3130.2 (2)
N7—C47—C48—C490.7 (4)C22—O10—P3—N22.1 (3)
N7—C47—C48—O14179.7 (2)C22—O10—P3—O11115.9 (2)
C47—C48—C49—C502.3 (4)C27—O11—P3—N335.4 (2)
O14—C48—C49—C50178.2 (2)C27—O11—P3—N2164.7 (2)
C48—C49—C50—C512.3 (4)C27—O11—P3—O1078.1 (2)
C49—C50—C51—N70.8 (5)Ag1—O1—S1—O244.4 (2)
C43—C42—N4—C460.3 (4)Ag1—O1—S1—O386.1 (2)
C43—C42—N4—Ag2166.2 (2)Ag1—O1—S1—C1159.62 (17)
C45—C46—N4—C420.4 (4)C6—C1—S1—O2146.2 (3)
C45—C46—N4—Ag2166.2 (2)C2—C1—S1—O234.4 (3)
N7ii—Ag2—N4—C4245.5 (5)C6—C1—S1—O393.9 (3)
Ag2ii—Ag2—N4—C4270.9 (2)C2—C1—S1—O385.4 (3)
N7ii—Ag2—N4—C46120.1 (4)C6—C1—S1—O125.6 (3)
Ag2ii—Ag2—N4—C46123.5 (2)C2—C1—S1—O1155.1 (3)
C25—C24—N5—C230.5 (5)Ag3—O4—S2—O537.4 (2)
C25—C24—N5—Ag3178.2 (3)Ag3—O4—S2—O6166.04 (15)
C22—C23—N5—C240.5 (4)Ag3—O4—S2—C1578.53 (17)
C22—C23—N5—Ag3178.1 (2)C16—C15—S2—O5141.3 (3)
N8iii—Ag3—N5—C2444.5 (4)C20—C15—S2—O538.9 (3)
O4—Ag3—N5—C2484.7 (3)C16—C15—S2—O698.5 (3)
N8iii—Ag3—N5—C23137.9 (2)C20—C15—S2—O681.2 (3)
O4—Ag3—N5—C2392.9 (2)C16—C15—S2—O421.0 (3)
C40—C41—N6—C370.6 (5)C20—C15—S2—O4159.2 (3)
C40—C41—N6—Ag1177.1 (2)C9—C8—S3—O8158.2 (3)
C39—C37—N6—C410.1 (4)C13—C8—S3—O823.2 (3)
C39—C37—N6—Ag1177.6 (2)C9—C8—S3—O935.9 (3)
N9i—Ag1—N6—C4139.6 (5)C13—C8—S3—O9145.6 (3)
O1—Ag1—N6—C41138.7 (2)C9—C8—S3—O782.5 (3)
N9i—Ag1—N6—C37142.8 (3)C13—C8—S3—O796.0 (3)
Symmetry codes: (i) x+2, y, z+1; (ii) x+1, y+1, z+1; (iii) x1, y, z; (iv) x+1, y, z.
(CCDC1422435) top
Crystal data top
C32H27Ag2N10O6P3·2(BF4)V = 1025.10 (19) Å3
Mr = 1129.90Z = 1
Triclinic, P1F(000) = 558
a = 8.1432 (8) ÅDx = 1.830 Mg m3
b = 9.879 (1) ÅMo Kα radiation, λ = 0.71073 Å
c = 13.5670 (15) ŵ = 1.17 mm1
α = 99.386 (5)°T = 300 K
β = 99.515 (5)°Block, colorless
γ = 103.137 (5)°0.49 × 0.47 × 0.15 mm
Data collection top
Bruker APEX II QUAZAR three-circle
diffractometer
6792 independent reflections
Multilayer QUAZAR mirrors monochromator6089 reflections with I > 2σ(I)
Detector resolution: 8.3333 pixels mm-1Rint = 0.055
φ and ω scansθmax = 25.3°, θmin = 2.9°
Absorption correction: multi-scan
SADABS (Bruker AXS)
h = 99
Tmin = 0.60, Tmax = 0.85k = 1111
12958 measured reflectionsl = 1616
Refinement top
Refinement on F2Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: fullH-atom parameters constrained
R[F2 > 2σ(F2)] = 0.075 w = 1/[σ2(Fo2) + (0.1602P)2 + 0.0722P]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.217(Δ/σ)max = 0.001
S = 1.11Δρmax = 1.74 e Å3
6792 reflectionsΔρmin = 1.13 e Å3
569 parametersAbsolute structure: Flack x determined using 2307 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
69 restraintsAbsolute structure parameter: 0.12 (2)
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refined as a 2-component perfect inversion twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.84901 (13)1.17851 (9)0.91032 (8)0.0609 (4)
Ag20.43723 (15)0.02437 (13)0.39677 (10)0.0689 (5)
B10.415 (8)0.833 (6)0.121 (4)0.145 (4)
B20.438 (6)0.231 (6)0.701 (4)0.140 (4)
C10.1463 (16)0.1677 (13)0.4267 (9)0.038 (3)
H10.21560.19970.4920.045*
C20.0011 (15)0.2145 (10)0.4036 (9)0.030 (2)
C30.0980 (19)0.1763 (14)0.3077 (11)0.046 (3)
H30.19360.21130.29130.055*
C40.0539 (18)0.0847 (15)0.2354 (11)0.047 (3)
H40.12170.05460.16970.056*
C50.089 (2)0.0382 (15)0.2603 (11)0.047 (3)
H50.11970.02180.21040.056*
C60.0820 (19)0.4125 (13)0.1175 (10)0.041 (3)
H60.00590.36240.1420.05*
C70.0714 (17)0.5448 (13)0.1736 (9)0.036 (3)
C80.177 (2)0.6212 (17)0.1404 (10)0.051 (3)
H80.16730.71290.17520.061*
C90.307 (3)0.556 (2)0.0493 (11)0.069 (5)
H90.38640.60360.0250.082*
C100.311 (2)0.4236 (18)0.0014 (11)0.055 (4)
H100.39590.38040.05980.066*
C110.2626 (15)0.8759 (10)0.3971 (9)0.031 (2)
H110.31880.83960.32920.038*
C120.1134 (14)0.8434 (10)0.4318 (8)0.026 (2)
C130.0257 (19)0.8979 (15)0.5312 (10)0.045 (3)
H130.0790.87970.55560.054*
C140.1001 (19)0.9812 (14)0.5939 (9)0.040 (3)
H140.05061.01810.66280.048*
C150.2520 (19)1.0056 (13)0.5476 (12)0.043 (3)
H150.30011.06380.58860.052*
C160.5385 (16)0.3876 (13)0.4220 (11)0.039 (3)
H160.57660.38370.48970.047*
C170.4947 (14)0.5102 (12)0.4023 (9)0.031 (2)
C180.4464 (19)0.5253 (16)0.3040 (11)0.046 (3)
H180.41920.60720.28910.055*
C190.441 (2)0.4115 (18)0.2286 (12)0.056 (4)
H190.40780.41520.16040.067*
C200.483 (2)0.2930 (16)0.2533 (12)0.053 (3)
H200.47980.21880.20060.064*
C210.6070 (18)0.9191 (13)0.7552 (10)0.042 (3)
H210.56540.99340.73640.051*
C220.5405 (15)0.7823 (12)0.6951 (9)0.034 (2)
C230.597 (2)0.6709 (13)0.7238 (10)0.049 (3)
H230.55170.57890.68510.058*
C240.724 (3)0.6989 (17)0.8126 (11)0.067 (5)
H240.76490.62620.83480.08*
C250.788 (2)0.8387 (18)0.8669 (10)0.058 (4)
H250.87440.85810.92510.07*
C260.0679 (18)0.3762 (14)0.7330 (10)0.043 (3)
H260.15630.30440.6890.051*
C270.0011 (16)0.4936 (14)0.6978 (10)0.040 (3)
C280.130 (2)0.6009 (16)0.7591 (12)0.062 (4)
H280.17510.68340.73740.074*
C290.190 (2)0.581 (2)0.8557 (12)0.070 (5)
H290.28110.65040.90020.084*
C300.117 (2)0.4616 (19)0.8854 (11)0.058 (4)
H300.16180.44940.95010.07*
C311.228 (4)1.115 (3)0.972 (2)0.098 (4)
C321.347 (4)1.053 (3)0.924 (2)0.100 (4)
H32A1.4551.0730.97130.149*
H32B1.36511.09320.86520.149*
H32C1.29990.95210.90220.149*
F10.430 (4)0.866 (3)0.2156 (16)0.149 (4)
F20.375 (3)0.676 (3)0.1255 (17)0.148 (4)
F30.251 (3)0.840 (2)0.0780 (15)0.142 (4)
F40.510 (4)0.836 (3)0.0528 (17)0.145 (4)
F50.330 (3)0.309 (3)0.7099 (16)0.143 (4)
F60.555 (2)0.227 (2)0.7739 (14)0.134 (4)
F70.310 (3)0.099 (2)0.6773 (15)0.142 (4)
F80.486 (3)0.236 (3)0.6149 (16)0.142 (4)
N10.2257 (12)0.5139 (10)0.5418 (7)0.031 (2)
N20.2432 (12)0.7223 (9)0.4317 (7)0.0293 (19)
N30.0585 (13)0.5277 (10)0.4136 (8)0.034 (2)
N40.1942 (18)0.3532 (13)0.0308 (8)0.047 (3)
N50.3319 (13)0.9588 (10)0.4576 (8)0.036 (2)
N60.0154 (19)0.3600 (14)0.8259 (9)0.056 (3)
N70.1907 (13)0.0777 (10)0.3583 (9)0.039 (2)
N80.7310 (16)0.9450 (11)0.8403 (8)0.044 (3)
N90.5295 (15)0.2785 (12)0.3517 (10)0.048 (3)
N101.140 (3)1.159 (3)1.0065 (18)0.098 (4)
O10.0450 (10)0.2999 (8)0.4833 (7)0.0354 (18)
O20.0684 (12)0.5048 (9)0.5992 (7)0.0392 (19)
O30.4154 (12)0.7744 (9)0.6111 (7)0.043 (2)
O40.5083 (10)0.6218 (8)0.4842 (7)0.0342 (17)
O50.0627 (11)0.5996 (9)0.2582 (6)0.0380 (18)
O60.0502 (11)0.7663 (8)0.3562 (6)0.0329 (17)
P10.0212 (3)0.4678 (3)0.5051 (2)0.0278 (6)
P20.0503 (3)0.6496 (2)0.3728 (2)0.0266 (6)
P30.3360 (3)0.6502 (3)0.5132 (2)0.0279 (6)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0773 (8)0.0388 (6)0.0478 (6)0.0135 (5)0.0153 (5)0.0125 (4)
Ag20.0639 (7)0.0738 (8)0.0724 (8)0.0525 (6)0.0033 (6)0.0058 (6)
B10.187 (9)0.165 (9)0.105 (6)0.096 (8)0.021 (6)0.023 (6)
B20.115 (7)0.175 (9)0.113 (6)0.022 (6)0.017 (5)0.048 (6)
C10.035 (6)0.043 (7)0.030 (6)0.008 (5)0.000 (5)0.002 (5)
C20.039 (6)0.010 (4)0.035 (6)0.005 (4)0.004 (5)0.002 (4)
C30.051 (7)0.041 (7)0.046 (7)0.028 (6)0.002 (6)0.003 (6)
C40.050 (8)0.045 (7)0.041 (7)0.027 (6)0.011 (6)0.005 (5)
C50.056 (8)0.038 (7)0.043 (7)0.011 (6)0.013 (6)0.003 (5)
C60.056 (8)0.029 (6)0.034 (6)0.009 (5)0.005 (6)0.002 (5)
C70.046 (7)0.036 (6)0.026 (5)0.011 (5)0.009 (5)0.005 (5)
C80.076 (10)0.054 (8)0.031 (6)0.037 (7)0.004 (6)0.007 (6)
C90.087 (12)0.103 (13)0.030 (7)0.075 (11)0.004 (7)0.001 (7)
C100.077 (10)0.061 (9)0.030 (6)0.029 (8)0.006 (6)0.004 (6)
C110.034 (6)0.017 (5)0.037 (6)0.006 (4)0.004 (4)0.001 (4)
C120.038 (5)0.017 (4)0.024 (5)0.010 (4)0.008 (4)0.002 (4)
C130.051 (7)0.047 (7)0.032 (6)0.023 (6)0.011 (5)0.003 (5)
C140.055 (7)0.038 (6)0.025 (5)0.021 (5)0.000 (5)0.007 (4)
C150.047 (7)0.032 (6)0.060 (9)0.023 (5)0.014 (6)0.017 (6)
C160.036 (6)0.034 (6)0.045 (7)0.015 (5)0.002 (5)0.000 (5)
C170.025 (5)0.032 (5)0.032 (6)0.008 (4)0.005 (4)0.001 (4)
C180.051 (7)0.049 (7)0.038 (7)0.014 (6)0.013 (6)0.008 (6)
C190.071 (10)0.060 (9)0.043 (7)0.032 (7)0.015 (7)0.002 (6)
C200.057 (8)0.051 (8)0.043 (8)0.016 (6)0.003 (6)0.010 (6)
C210.053 (7)0.034 (6)0.030 (6)0.008 (5)0.000 (5)0.008 (5)
C220.040 (6)0.029 (5)0.028 (5)0.012 (4)0.002 (4)0.001 (4)
C230.076 (9)0.025 (6)0.040 (7)0.019 (6)0.001 (6)0.003 (5)
C240.119 (15)0.045 (8)0.037 (7)0.045 (9)0.011 (8)0.005 (6)
C250.082 (11)0.062 (9)0.026 (6)0.028 (8)0.008 (7)0.000 (6)
C260.048 (7)0.037 (6)0.034 (6)0.002 (5)0.015 (5)0.006 (5)
C270.036 (6)0.041 (6)0.044 (7)0.015 (5)0.012 (5)0.003 (5)
C280.081 (11)0.041 (8)0.048 (8)0.007 (7)0.027 (8)0.013 (6)
C290.058 (9)0.081 (12)0.042 (8)0.014 (9)0.003 (7)0.013 (8)
C300.062 (9)0.070 (10)0.029 (6)0.000 (8)0.009 (6)0.000 (6)
C310.105 (10)0.097 (9)0.091 (9)0.051 (7)0.002 (7)0.007 (7)
C320.108 (10)0.098 (9)0.092 (9)0.049 (7)0.000 (8)0.007 (8)
F10.189 (9)0.168 (9)0.108 (6)0.095 (8)0.020 (6)0.021 (6)
F20.189 (9)0.167 (9)0.108 (6)0.095 (8)0.022 (6)0.023 (6)
F30.185 (10)0.163 (9)0.100 (7)0.097 (8)0.020 (7)0.026 (6)
F40.186 (10)0.164 (9)0.105 (7)0.096 (8)0.023 (7)0.023 (7)
F50.118 (7)0.176 (10)0.119 (7)0.023 (6)0.014 (6)0.045 (7)
F60.111 (7)0.170 (10)0.108 (7)0.022 (6)0.019 (5)0.051 (7)
F70.116 (7)0.175 (10)0.116 (7)0.019 (6)0.020 (6)0.046 (7)
F80.117 (7)0.181 (10)0.113 (7)0.022 (6)0.015 (6)0.046 (7)
N10.035 (5)0.027 (4)0.029 (5)0.009 (4)0.003 (4)0.004 (4)
N20.033 (5)0.019 (4)0.033 (5)0.006 (3)0.002 (4)0.004 (3)
N30.027 (4)0.028 (4)0.042 (5)0.005 (3)0.004 (4)0.005 (4)
N40.067 (8)0.041 (6)0.029 (5)0.013 (5)0.004 (5)0.002 (4)
N50.040 (5)0.026 (4)0.044 (6)0.010 (4)0.016 (5)0.005 (4)
N60.070 (8)0.050 (7)0.035 (6)0.001 (6)0.001 (6)0.008 (5)
N70.037 (5)0.024 (5)0.050 (6)0.014 (4)0.003 (4)0.003 (4)
N80.062 (7)0.031 (5)0.028 (5)0.014 (5)0.015 (5)0.004 (4)
N90.046 (6)0.042 (6)0.059 (7)0.017 (5)0.012 (5)0.010 (5)
N100.105 (10)0.097 (9)0.091 (9)0.051 (7)0.002 (7)0.006 (7)
O10.040 (4)0.018 (3)0.046 (5)0.005 (3)0.014 (4)0.003 (3)
O20.044 (5)0.038 (4)0.040 (5)0.024 (4)0.011 (4)0.002 (4)
O30.049 (5)0.031 (4)0.038 (5)0.015 (3)0.016 (4)0.009 (3)
O40.030 (4)0.027 (4)0.043 (5)0.009 (3)0.006 (3)0.000 (3)
O50.043 (4)0.037 (4)0.025 (4)0.010 (3)0.006 (3)0.003 (3)
O60.047 (4)0.022 (3)0.029 (4)0.016 (3)0.001 (3)0.002 (3)
P10.0300 (13)0.0174 (12)0.0339 (14)0.0061 (9)0.0034 (10)0.0026 (10)
P20.0309 (13)0.0172 (11)0.0282 (13)0.0094 (10)0.0024 (10)0.0013 (9)
P30.0274 (12)0.0208 (12)0.0287 (13)0.0051 (9)0.0042 (10)0.0015 (10)
Geometric parameters (Å, º) top
Ag1—N82.264 (11)C17—C181.368 (19)
Ag1—N4i2.307 (13)C17—O41.402 (14)
Ag1—N6ii2.436 (12)C18—C191.38 (2)
Ag1—N102.57 (2)C18—H180.93
Ag2—N72.192 (10)C19—C201.37 (2)
Ag2—N5iii2.203 (11)C19—H190.93
B1—F11.24 (5)C20—N91.37 (2)
B1—F41.31 (6)C20—H200.93
B1—F31.39 (6)C21—N81.348 (17)
B1—F21.52 (6)C21—C221.395 (17)
B2—F61.27 (4)C21—H210.93
B2—F81.29 (5)C22—C231.374 (17)
B2—F51.30 (6)C22—O31.376 (14)
B2—F71.43 (5)C23—C241.39 (2)
C1—N71.330 (17)C23—H230.93
C1—C21.373 (18)C24—C251.39 (2)
C1—H10.93C24—H240.93
C2—C31.357 (18)C25—N81.316 (19)
C2—O11.414 (14)C25—H250.93
C3—C41.37 (2)C26—N61.309 (19)
C3—H30.93C26—C271.365 (19)
C4—C51.36 (2)C26—H260.93
C4—H40.93C27—C281.35 (2)
C5—N71.387 (19)C27—O21.396 (17)
C5—H50.93C28—C291.38 (3)
C6—N41.318 (18)C28—H280.93
C6—C71.378 (19)C29—C301.35 (3)
C6—H60.93C29—H290.93
C7—C81.340 (19)C30—N61.33 (2)
C7—O51.385 (15)C30—H300.93
C8—C91.43 (2)C31—N101.05 (3)
C8—H80.93C31—C321.45 (4)
C9—C101.37 (2)C32—H32A0.96
C9—H90.93C32—H32B0.96
C10—N41.35 (2)C32—H32C0.96
C10—H100.93N1—P31.583 (9)
C11—N51.344 (16)N1—P11.592 (10)
C11—C121.355 (16)N2—P21.583 (9)
C11—H110.93N2—P31.589 (9)
C12—C131.375 (17)N3—P21.561 (10)
C12—O61.412 (14)N3—P11.569 (10)
C13—C141.39 (2)N4—Ag1iv2.307 (13)
C13—H130.93N5—Ag2v2.203 (11)
C14—C151.38 (2)N6—Ag1vi2.436 (12)
C14—H140.93O1—P11.585 (7)
C15—N51.243 (19)O2—P11.604 (9)
C15—H150.93O3—P31.584 (8)
C16—N91.297 (19)O4—P31.590 (8)
C16—C171.392 (17)O5—P21.580 (9)
C16—H160.93O6—P21.582 (8)
N8—Ag1—N4i138.6 (5)N8—C21—H21119.6
N8—Ag1—N6ii126.8 (4)C22—C21—H21119.6
N4i—Ag1—N6ii89.8 (5)C23—C22—O3126.4 (11)
N8—Ag1—N1098.2 (6)C23—C22—C21120.1 (12)
N4i—Ag1—N1098.3 (6)O3—C22—C21113.5 (10)
N6ii—Ag1—N1093.2 (7)C22—C23—C24118.4 (12)
N7—Ag2—N5iii170.2 (4)C22—C23—H23120.8
F1—B1—F4140 (6)C24—C23—H23120.8
F1—B1—F3107 (4)C25—C24—C23118.2 (13)
F4—B1—F3109 (4)C25—C24—H24120.9
F1—B1—F291 (3)C23—C24—H24120.9
F4—B1—F2101 (3)N8—C25—C24123.4 (13)
F3—B1—F299 (4)N8—C25—H25118.3
F6—B2—F8115 (4)C24—C25—H25118.3
F6—B2—F5124 (5)N6—C26—C27123.0 (12)
F8—B2—F5109 (4)N6—C26—H26118.5
F6—B2—F7108 (4)C27—C26—H26118.5
F8—B2—F7102 (4)C28—C27—C26120.6 (14)
F5—B2—F795 (3)C28—C27—O2120.3 (13)
N7—C1—C2121.8 (11)C26—C27—O2119.1 (12)
N7—C1—H1119.1C27—C28—C29116.4 (15)
C2—C1—H1119.1C27—C28—H28121.8
C3—C2—C1120.8 (11)C29—C28—H28121.8
C3—C2—O1121.1 (11)C30—C29—C28119.9 (14)
C1—C2—O1118.1 (10)C30—C29—H29120.0
C2—C3—C4118.5 (12)C28—C29—H29120.0
C2—C3—H3120.8N6—C30—C29122.9 (15)
C4—C3—H3120.8N6—C30—H30118.6
C5—C4—C3119.7 (13)C29—C30—H30118.6
C5—C4—H4120.1N10—C31—C32179 (3)
C3—C4—H4120.1C31—C32—H32A109.5
C4—C5—N7121.8 (13)C31—C32—H32B109.5
C4—C5—H5119.1H32A—C32—H32B109.5
N7—C5—H5119.1C31—C32—H32C109.5
N4—C6—C7123.5 (13)H32A—C32—H32C109.5
N4—C6—H6118.3H32B—C32—H32C109.5
C7—C6—H6118.3P3—N1—P1120.1 (6)
C8—C7—C6120.2 (13)P2—N2—P3120.2 (5)
C8—C7—O5122.2 (12)P2—N3—P1122.1 (6)
C6—C7—O5117.3 (12)C6—N4—C10117.8 (13)
C7—C8—C9117.5 (14)C6—N4—Ag1iv122.5 (11)
C7—C8—H8121.2C10—N4—Ag1iv116.9 (9)
C9—C8—H8121.2C15—N5—C11116.8 (11)
C10—C9—C8118.7 (13)C15—N5—Ag2v121.4 (9)
C10—C9—H9120.6C11—N5—Ag2v121.5 (8)
C8—C9—H9120.6C26—N6—C30117.0 (13)
N4—C10—C9122.1 (14)C26—N6—Ag1vi127.4 (10)
N4—C10—H10119.0C30—N6—Ag1vi115.2 (10)
C9—C10—H10119.0C1—N7—C5117.3 (11)
N5—C11—C12122.2 (11)C1—N7—Ag2119.4 (8)
N5—C11—H11118.9C5—N7—Ag2122.6 (9)
C12—C11—H11118.9C25—N8—C21119.0 (12)
C11—C12—C13120.2 (11)C25—N8—Ag1126.0 (10)
C11—C12—O6114.9 (9)C21—N8—Ag1114.3 (8)
C13—C12—O6124.5 (11)C16—N9—C20115.7 (12)
C12—C13—C14117.3 (12)C31—N10—Ag1125 (2)
C12—C13—H13121.3C2—O1—P1120.7 (7)
C14—C13—H13121.3C27—O2—P1121.6 (8)
C15—C14—C13115.9 (12)C22—O3—P3129.3 (8)
C15—C14—H14122.1C17—O4—P3118.6 (7)
C13—C14—H14122.1C7—O5—P2127.8 (8)
N5—C15—C14127.7 (13)C12—O6—P2125.6 (6)
N5—C15—H15116.2N3—P1—O1110.9 (5)
C14—C15—H15116.2N3—P1—N1117.3 (5)
N9—C16—C17124.0 (13)O1—P1—N1109.3 (5)
N9—C16—H16118.0N3—P1—O2108.7 (5)
C17—C16—H16118.0O1—P1—O298.6 (5)
C18—C17—C16120.7 (12)N1—P1—O2110.5 (5)
C18—C17—O4119.9 (11)N3—P2—O5112.0 (5)
C16—C17—O4119.4 (10)N3—P2—O6111.0 (5)
C17—C18—C19115.8 (14)O5—P2—O698.1 (4)
C17—C18—H18122.1N3—P2—N2118.4 (5)
C19—C18—H18122.1O5—P2—N2104.8 (5)
C20—C19—C18120.6 (15)O6—P2—N2110.4 (5)
C20—C19—H19119.7N1—P3—O3111.0 (5)
C18—C19—H19119.7N1—P3—N2118.4 (5)
N9—C20—C19123.2 (14)O3—P3—N2104.4 (5)
N9—C20—H20118.4N1—P3—O4110.5 (5)
C19—C20—H20118.4O3—P3—O4100.0 (5)
N8—C21—C22120.9 (12)N2—P3—O4110.8 (5)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+1, y+1, z; (iii) x+1, y1, z; (iv) x1, y1, z1; (v) x1, y+1, z; (vi) x1, y1, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C1—H1···F80.932.453.30 (2)152
C5—H5···F3vii0.932.593.52 (3)171
C8—H8···O60.932.412.942 (16)117
C9—H9···F4viii0.932.613.42 (3)146
C10—H10···F6ix0.932.423.20 (3)142
C11—H11···F1viii0.932.443.18 (3)136
C13—H13···F7x0.932.623.13 (2)115
C16—H16···F80.932.513.26 (3)138
C18—H18···F20.932.423.09 (3)129
C21—H21···F6x0.932.303.14 (3)149
C21—H21···F7x0.932.603.44 (3)151
C32—H32B···F6ii0.962.433.30 (4)151
C32—H32B···F7ii0.962.533.42 (4)155
Symmetry codes: (ii) x+1, y+1, z; (vii) x, y1, z; (viii) x1, y, z; (ix) x1, y, z1; (x) x, y+1, z.
(CCDC1422430) top
Crystal data top
C30H24N9O6P3F(000) = 1440
Mr = 699.49Dx = 1.524 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 17.9886 (3) ÅCell parameters from 134 reflections
b = 22.4886 (4) Åθ = 2.4–27.6°
c = 7.5366 (1) ŵ = 0.26 mm1
β = 90.522 (1)°T = 150 K
V = 3048.72 (8) Å3Block, clear colourless
Z = 40.30 × 0.23 × 0.14 mm
Data collection top
Bruker APEX II QUAZAR three-circle
diffractometer
5366 independent reflections
Multilayer QUAZAR mirrors monochromator4680 reflections with I > 2σ(I)
Detector resolution: 8.3333 pixels mm-1Rint = 0.037
φ and ω scansθmax = 25.0°, θmin = 1.1°
Absorption correction: multi-scan
SADABS (Bruker AXS)
h = 2121
Tmin = 0.87, Tmax = 0.96k = 2626
39717 measured reflectionsl = 88
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.032Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.088H-atom parameters constrained
S = 1.05 w = 1/[σ2(Fo2) + (0.0417P)2 + 1.833P]
where P = (Fo2 + 2Fc2)/3
5366 reflections(Δ/σ)max = 0.001
433 parametersΔρmax = 0.27 e Å3
0 restraintsΔρmin = 0.47 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
C10.29111 (11)0.35622 (8)0.0709 (2)0.0292 (4)
H10.26170.37970.00750.035*
C20.35574 (10)0.38011 (8)0.1412 (2)0.0242 (4)
C30.40142 (11)0.34676 (9)0.2493 (3)0.0311 (4)
H30.44670.36240.29550.037*
C40.37861 (12)0.28932 (9)0.2881 (3)0.0371 (5)
H40.40820.26430.36170.045*
C50.31227 (12)0.26922 (9)0.2180 (3)0.0367 (5)
H50.29650.23020.24830.044*
C60.12800 (10)0.42073 (9)0.6978 (2)0.0313 (4)
H60.11580.45770.75130.038*
C70.19570 (10)0.41487 (8)0.6163 (2)0.0249 (4)
C80.21515 (11)0.36261 (9)0.5373 (3)0.0360 (5)
H80.26170.35810.48030.043*
C90.16445 (13)0.31649 (10)0.5433 (3)0.0454 (6)
H90.17540.27930.48950.054*
C100.09808 (12)0.32513 (10)0.6282 (3)0.0426 (5)
H100.0640.29290.63310.051*
C110.05773 (11)0.35574 (8)0.1736 (3)0.0309 (4)
H110.09340.33310.11050.037*
C120.06870 (10)0.41636 (8)0.1913 (2)0.0238 (4)
C130.01823 (10)0.45081 (8)0.2805 (3)0.0289 (4)
H130.02460.49260.29220.035*
C140.04245 (11)0.42175 (9)0.3529 (3)0.0332 (5)
H140.07880.44330.41710.04*
C150.04925 (11)0.36127 (9)0.3302 (3)0.0357 (5)
H150.0910.34210.3810.043*
C160.17387 (11)0.72065 (9)0.0709 (3)0.0355 (5)
H160.18630.76170.07590.043*
C170.11277 (11)0.70184 (9)0.1641 (3)0.0331 (4)
H170.08360.72940.22890.04*
C180.09446 (10)0.64190 (8)0.1618 (3)0.0279 (4)
H180.05290.6270.22470.033*
C190.13935 (9)0.60502 (8)0.0642 (2)0.0224 (4)
C200.19876 (11)0.62728 (8)0.0291 (2)0.0293 (4)
H200.22780.60070.09780.035*
C210.40270 (13)0.70419 (10)0.4893 (3)0.0463 (6)
H210.43540.73660.46840.056*
C220.33780 (13)0.70141 (9)0.3927 (3)0.0433 (5)
H220.3260.73140.30810.052*
C230.29002 (11)0.65459 (9)0.4202 (3)0.0340 (5)
H230.24480.65110.35510.041*
C240.31012 (10)0.61336 (8)0.5445 (2)0.0255 (4)
C250.37578 (12)0.61898 (10)0.6368 (3)0.0406 (5)
H250.38840.58960.72270.049*
C260.56178 (12)0.62692 (10)0.2686 (3)0.0394 (5)
H260.6040.64720.31480.047*
C270.55170 (11)0.56839 (10)0.3165 (3)0.0389 (5)
H270.58670.5490.3920.047*
C280.48981 (11)0.53807 (9)0.2529 (3)0.0337 (5)
H280.48110.49760.28270.04*
C290.44158 (10)0.56913 (8)0.1449 (2)0.0252 (4)
C300.45610 (11)0.62755 (8)0.1013 (3)0.0305 (4)
H300.42220.64780.02530.037*
N10.32721 (8)0.49694 (6)0.36274 (19)0.0230 (3)
N20.17849 (8)0.51282 (6)0.35753 (19)0.0226 (3)
N30.25182 (8)0.49351 (6)0.05206 (19)0.0220 (3)
N40.21692 (9)0.68504 (7)0.0261 (2)0.0360 (4)
N50.42250 (10)0.66400 (9)0.6108 (3)0.0522 (5)
N60.51577 (10)0.65673 (8)0.1614 (2)0.0382 (4)
N70.26871 (10)0.30117 (7)0.1099 (2)0.0362 (4)
N80.00072 (10)0.32780 (7)0.2413 (2)0.0373 (4)
N90.07902 (9)0.37641 (8)0.7042 (2)0.0397 (4)
O10.37806 (7)0.43799 (5)0.09514 (16)0.0253 (3)
O20.37689 (7)0.54492 (6)0.06953 (16)0.0271 (3)
O30.13279 (7)0.43825 (5)0.11068 (16)0.0265 (3)
O40.12198 (6)0.54397 (5)0.05537 (16)0.0238 (3)
O50.24507 (7)0.46282 (6)0.62468 (16)0.0328 (3)
O60.26368 (7)0.56576 (6)0.58976 (17)0.0335 (3)
P10.32885 (2)0.493246 (19)0.15298 (6)0.02028 (12)
P20.25349 (3)0.50897 (2)0.46842 (6)0.02227 (12)
P30.17570 (2)0.498073 (19)0.15261 (6)0.01990 (12)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.0345 (10)0.0248 (10)0.0282 (10)0.0037 (8)0.0017 (8)0.0042 (8)
C20.0280 (9)0.0220 (9)0.0227 (9)0.0018 (7)0.0081 (7)0.0030 (7)
C30.0282 (10)0.0354 (11)0.0296 (10)0.0069 (8)0.0022 (8)0.0026 (8)
C40.0469 (12)0.0309 (11)0.0335 (11)0.0135 (9)0.0014 (9)0.0025 (9)
C50.0524 (13)0.0231 (10)0.0346 (11)0.0025 (9)0.0051 (10)0.0023 (9)
C60.0300 (10)0.0381 (11)0.0257 (10)0.0031 (9)0.0034 (8)0.0031 (8)
C70.0230 (9)0.0324 (10)0.0194 (9)0.0018 (8)0.0005 (7)0.0087 (8)
C80.0269 (10)0.0401 (12)0.0410 (12)0.0082 (9)0.0052 (9)0.0034 (9)
C90.0460 (13)0.0295 (11)0.0605 (15)0.0049 (10)0.0011 (11)0.0033 (10)
C100.0380 (12)0.0389 (12)0.0507 (14)0.0101 (10)0.0050 (10)0.0176 (10)
C110.0353 (11)0.0253 (10)0.0320 (11)0.0036 (8)0.0001 (8)0.0004 (8)
C120.0233 (9)0.0252 (9)0.0228 (9)0.0055 (7)0.0034 (7)0.0017 (7)
C130.0277 (10)0.0261 (10)0.0329 (10)0.0030 (8)0.0006 (8)0.0015 (8)
C140.0245 (10)0.0413 (12)0.0336 (11)0.0040 (8)0.0000 (8)0.0002 (9)
C150.0311 (11)0.0413 (12)0.0346 (11)0.0131 (9)0.0046 (9)0.0084 (9)
C160.0383 (11)0.0235 (10)0.0447 (12)0.0014 (9)0.0027 (9)0.0059 (9)
C170.0332 (11)0.0266 (10)0.0395 (12)0.0081 (8)0.0041 (9)0.0007 (9)
C180.0220 (9)0.0301 (10)0.0316 (10)0.0030 (8)0.0018 (8)0.0034 (8)
C190.0226 (9)0.0233 (9)0.0213 (9)0.0007 (7)0.0039 (7)0.0027 (7)
C200.0322 (10)0.0286 (10)0.0272 (10)0.0025 (8)0.0064 (8)0.0014 (8)
C210.0408 (13)0.0288 (11)0.0696 (16)0.0080 (10)0.0148 (12)0.0125 (11)
C220.0515 (14)0.0296 (11)0.0490 (13)0.0073 (10)0.0078 (11)0.0015 (10)
C230.0301 (10)0.0355 (11)0.0363 (11)0.0056 (9)0.0040 (9)0.0043 (9)
C240.0246 (9)0.0271 (10)0.0249 (9)0.0024 (7)0.0033 (7)0.0104 (8)
C250.0398 (12)0.0375 (12)0.0441 (13)0.0020 (10)0.0143 (10)0.0015 (10)
C260.0328 (11)0.0555 (14)0.0300 (11)0.0177 (10)0.0059 (9)0.0094 (10)
C270.0251 (10)0.0580 (14)0.0336 (11)0.0037 (10)0.0005 (9)0.0030 (10)
C280.0289 (10)0.0367 (11)0.0354 (11)0.0047 (9)0.0020 (8)0.0068 (9)
C290.0216 (9)0.0315 (10)0.0225 (9)0.0056 (7)0.0053 (7)0.0020 (7)
C300.0348 (11)0.0293 (10)0.0275 (10)0.0052 (8)0.0038 (8)0.0023 (8)
N10.0231 (8)0.0268 (8)0.0191 (8)0.0008 (6)0.0010 (6)0.0004 (6)
N20.0238 (8)0.0241 (8)0.0199 (8)0.0003 (6)0.0029 (6)0.0014 (6)
N30.0249 (8)0.0246 (8)0.0164 (7)0.0014 (6)0.0011 (6)0.0006 (6)
N40.0384 (9)0.0280 (9)0.0416 (10)0.0003 (7)0.0108 (8)0.0066 (8)
N50.0349 (10)0.0464 (12)0.0750 (15)0.0090 (9)0.0143 (10)0.0085 (11)
N60.0427 (10)0.0386 (10)0.0335 (10)0.0157 (8)0.0055 (8)0.0070 (8)
N70.0445 (10)0.0255 (9)0.0386 (10)0.0008 (7)0.0005 (8)0.0051 (7)
N80.0409 (10)0.0304 (9)0.0406 (10)0.0114 (8)0.0013 (8)0.0040 (8)
N90.0271 (9)0.0524 (12)0.0398 (10)0.0043 (8)0.0060 (8)0.0106 (9)
O10.0227 (6)0.0270 (7)0.0261 (7)0.0003 (5)0.0070 (5)0.0007 (5)
O20.0262 (7)0.0301 (7)0.0250 (7)0.0076 (5)0.0006 (5)0.0052 (5)
O30.0266 (7)0.0234 (7)0.0295 (7)0.0064 (5)0.0053 (5)0.0046 (5)
O40.0230 (6)0.0231 (6)0.0253 (7)0.0020 (5)0.0031 (5)0.0000 (5)
O50.0341 (7)0.0442 (8)0.0200 (7)0.0130 (6)0.0034 (5)0.0074 (6)
O60.0373 (8)0.0386 (8)0.0248 (7)0.0125 (6)0.0093 (6)0.0121 (6)
P10.0211 (2)0.0214 (2)0.0184 (2)0.00187 (18)0.00235 (18)0.00014 (17)
P20.0247 (2)0.0257 (3)0.0164 (2)0.00448 (18)0.00163 (18)0.00168 (18)
P30.0213 (2)0.0194 (2)0.0190 (2)0.00199 (17)0.00053 (18)0.00115 (17)
Geometric parameters (Å, º) top
C1—N71.335 (2)C18—H180.95
C1—C21.382 (3)C19—C201.378 (3)
C1—H10.95C19—O41.410 (2)
C2—C31.375 (3)C20—N41.339 (2)
C2—O11.407 (2)C20—H200.95
C3—C41.387 (3)C21—N51.333 (3)
C3—H30.95C21—C221.372 (3)
C4—C51.377 (3)C21—H210.95
C4—H40.95C22—C231.376 (3)
C5—N71.335 (3)C22—H220.95
C5—H50.95C23—C241.365 (3)
C6—N91.332 (3)C23—H230.95
C6—C71.375 (3)C24—C251.371 (3)
C6—H60.95C24—O61.402 (2)
C7—C81.364 (3)C25—N51.331 (3)
C7—O51.398 (2)C25—H250.95
C8—C91.382 (3)C26—N61.332 (3)
C8—H80.95C26—C271.377 (3)
C9—C101.373 (3)C26—H260.95
C9—H90.95C27—C281.387 (3)
C10—N91.334 (3)C27—H270.95
C10—H100.95C28—C291.375 (3)
C11—N81.330 (3)C28—H280.95
C11—C121.384 (3)C29—C301.380 (3)
C11—H110.95C29—O21.401 (2)
C12—C131.374 (3)C30—N61.334 (2)
C12—O31.398 (2)C30—H300.95
C13—C141.388 (3)N1—P21.5765 (15)
C13—H130.95N1—P11.5836 (15)
C14—C151.376 (3)N2—P31.5800 (15)
C14—H140.95N2—P21.5829 (15)
C15—N81.337 (3)N3—P31.5744 (15)
C15—H150.95N3—P11.5746 (15)
C16—N41.336 (3)O1—P11.5890 (12)
C16—C171.376 (3)O2—P11.5821 (12)
C16—H160.95O3—P31.5816 (12)
C17—C181.388 (3)O4—P31.5884 (12)
C17—H170.95O5—P21.5779 (13)
C18—C191.375 (3)O6—P21.5806 (13)
N7—C1—C2122.05 (18)C22—C21—H21118.2
N7—C1—H1119.0C21—C22—C23119.0 (2)
C2—C1—H1119.0C21—C22—H22120.5
C3—C2—C1120.76 (17)C23—C22—H22120.5
C3—C2—O1118.73 (16)C24—C23—C22117.47 (19)
C1—C2—O1120.42 (16)C24—C23—H23121.3
C2—C3—C4117.16 (18)C22—C23—H23121.3
C2—C3—H3121.4C23—C24—C25120.49 (18)
C4—C3—H3121.4C23—C24—O6122.08 (16)
C5—C4—C3118.80 (19)C25—C24—O6117.35 (17)
C5—C4—H4120.6N5—C25—C24122.5 (2)
C3—C4—H4120.6N5—C25—H25118.8
N7—C5—C4124.01 (19)C24—C25—H25118.8
N7—C5—H5118.0N6—C26—C27123.86 (19)
C4—C5—H5118.0N6—C26—H26118.1
N9—C6—C7122.23 (19)C27—C26—H26118.1
N9—C6—H6118.9C26—C27—C28119.1 (2)
C7—C6—H6118.9C26—C27—H27120.4
C8—C7—C6120.61 (18)C28—C27—H27120.4
C8—C7—O5121.25 (17)C29—C28—C27117.04 (19)
C6—C7—O5118.06 (17)C29—C28—H28121.5
C7—C8—C9117.38 (19)C27—C28—H28121.5
C7—C8—H8121.3C28—C29—C30120.34 (17)
C9—C8—H8121.3C28—C29—O2124.06 (17)
C10—C9—C8119.1 (2)C30—C29—O2115.58 (16)
C10—C9—H9120.5N6—C30—C29122.76 (19)
C8—C9—H9120.5N6—C30—H30118.6
N9—C10—C9123.4 (2)C29—C30—H30118.6
N9—C10—H10118.3P2—N1—P1122.46 (9)
C9—C10—H10118.3P3—N2—P2121.60 (9)
N8—C11—C12122.73 (19)P3—N3—P1122.22 (9)
N8—C11—H11118.6C16—N4—C20116.59 (17)
C12—C11—H11118.6C25—N5—C21116.86 (19)
C13—C12—C11120.56 (17)C26—N6—C30116.86 (18)
C13—C12—O3124.43 (16)C5—N7—C1117.16 (18)
C11—C12—O3115.00 (16)C11—N8—C15116.63 (17)
C12—C13—C14116.89 (18)C6—N9—C10117.32 (18)
C12—C13—H13121.6C2—O1—P1119.66 (10)
C14—C13—H13121.6C29—O2—P1125.39 (11)
C15—C14—C13119.07 (19)C12—O3—P3128.01 (11)
C15—C14—H14120.5C19—O4—P3118.52 (10)
C13—C14—H14120.5C7—O5—P2122.60 (11)
N8—C15—C14124.11 (19)C24—O6—P2122.85 (11)
N8—C15—H15117.9N3—P1—O2106.66 (7)
C14—C15—H15117.9N3—P1—N1117.24 (8)
N4—C16—C17124.36 (18)O2—P1—N1111.93 (7)
N4—C16—H16117.8N3—P1—O1111.13 (7)
C17—C16—H16117.8O2—P1—O199.07 (7)
C16—C17—C18118.86 (18)N1—P1—O1109.29 (7)
C16—C17—H17120.6N1—P2—O5110.56 (8)
C18—C17—H17120.6N1—P2—O6109.71 (7)
C19—C18—C17116.87 (17)O5—P2—O696.38 (7)
C19—C18—H18121.6N1—P2—N2117.35 (8)
C17—C18—H18121.6O5—P2—N2110.05 (7)
C18—C19—C20121.02 (17)O6—P2—N2110.80 (8)
C18—C19—O4118.79 (16)N3—P3—N2117.65 (8)
C20—C19—O4120.15 (16)N3—P3—O3105.87 (7)
N4—C20—C19122.26 (18)N2—P3—O3112.64 (7)
N4—C20—H20118.9N3—P3—O4110.39 (7)
C19—C20—H20118.9N2—P3—O4109.17 (7)
N5—C21—C22123.7 (2)O3—P3—O499.60 (7)
N5—C21—H21118.2
N7—C1—C2—C32.7 (3)C3—C2—O1—P1118.00 (16)
N7—C1—C2—O1179.12 (16)C1—C2—O1—P165.5 (2)
C1—C2—C3—C41.8 (3)C28—C29—O2—P129.3 (2)
O1—C2—C3—C4178.30 (16)C30—C29—O2—P1152.01 (14)
C2—C3—C4—C50.3 (3)C13—C12—O3—P322.0 (2)
C3—C4—C5—N71.8 (3)C11—C12—O3—P3158.85 (14)
N9—C6—C7—C80.3 (3)C18—C19—O4—P3110.75 (16)
N9—C6—C7—O5176.60 (17)C20—C19—O4—P371.61 (19)
C6—C7—C8—C90.2 (3)C8—C7—O5—P284.8 (2)
O5—C7—C8—C9176.61 (17)C6—C7—O5—P298.37 (18)
C7—C8—C9—C100.4 (3)C23—C24—O6—P276.6 (2)
C8—C9—C10—N90.9 (3)C25—C24—O6—P2106.65 (18)
N8—C11—C12—C130.4 (3)P3—N3—P1—O2125.55 (10)
N8—C11—C12—O3179.54 (17)P3—N3—P1—N10.79 (14)
C11—C12—C13—C141.0 (3)P3—N3—P1—O1127.47 (10)
O3—C12—C13—C14179.94 (16)C29—O2—P1—N3164.55 (13)
C12—C13—C14—C150.7 (3)C29—O2—P1—N135.08 (16)
C13—C14—C15—N80.2 (3)C29—O2—P1—O180.06 (14)
N4—C16—C17—C181.3 (3)P2—N1—P1—N38.01 (14)
C16—C17—C18—C190.3 (3)P2—N1—P1—O2115.70 (10)
C17—C18—C19—C201.2 (3)P2—N1—P1—O1135.58 (10)
C17—C18—C19—O4178.80 (16)C2—O1—P1—N367.69 (14)
C18—C19—C20—N41.7 (3)C2—O1—P1—O2179.59 (12)
O4—C19—C20—N4179.32 (16)C2—O1—P1—N163.24 (14)
N5—C21—C22—C230.5 (3)P1—N1—P2—O5131.64 (10)
C21—C22—C23—C240.4 (3)P1—N1—P2—O6123.27 (10)
C22—C23—C24—C250.2 (3)P1—N1—P2—N24.32 (14)
C22—C23—C24—O6176.43 (17)C7—O5—P2—N1104.12 (15)
C23—C24—C25—N50.0 (3)C7—O5—P2—O6142.03 (14)
O6—C24—C25—N5176.81 (19)C7—O5—P2—N227.12 (16)
N6—C26—C27—C281.0 (3)C24—O6—P2—N130.59 (16)
C26—C27—C28—C290.3 (3)C24—O6—P2—O5145.13 (14)
C27—C28—C29—C301.1 (3)C24—O6—P2—N2100.57 (15)
C27—C28—C29—O2179.71 (17)P3—N2—P2—N16.78 (14)
C28—C29—C30—N60.7 (3)P3—N2—P2—O5120.78 (11)
O2—C29—C30—N6179.49 (17)P3—N2—P2—O6133.85 (10)
C17—C16—N4—C200.8 (3)P1—N3—P3—N29.62 (14)
C19—C20—N4—C160.7 (3)P1—N3—P3—O3117.30 (10)
C24—C25—N5—C210.0 (3)P1—N3—P3—O4135.80 (10)
C22—C21—N5—C250.2 (3)P2—N2—P3—N313.54 (14)
C27—C26—N6—C301.3 (3)P2—N2—P3—O3110.04 (11)
C29—C30—N6—C260.5 (3)P2—N2—P3—O4140.31 (10)
C4—C5—N7—C11.1 (3)C12—O3—P3—N3168.41 (14)
C2—C1—N7—C51.2 (3)C12—O3—P3—N238.51 (16)
C12—C11—N8—C150.5 (3)C12—O3—P3—O477.05 (15)
C14—C15—N8—C110.8 (3)C19—O4—P3—N370.60 (13)
C7—C6—N9—C100.2 (3)C19—O4—P3—N260.20 (14)
C9—C10—N9—C60.8 (3)C19—O4—P3—O3178.38 (12)
(CCDC1422431) top
Crystal data top
C30H26Ag2N10O10P3·NO3F(000) = 1052
Mr = 1057.27Dx = 1.899 Mg m3
Monoclinic, P21Mo Kα radiation, λ = 0.71073 Å
a = 8.2988 (2) ÅCell parameters from 117 reflections
b = 23.5144 (7) Åθ = 3.7–21.4°
c = 9.6730 (3) ŵ = 1.27 mm1
β = 101.610 (1)°T = 150 K
V = 1848.98 (9) Å3Block, clear colourless
Z = 20.14 × 0.11 × 0.05 mm
Data collection top
Bruker APEX II QUAZAR three-circle
diffractometer
6511 independent reflections
Multilayer QUAZAR mirrors monochromator6244 reflections with I > 2σ(I)
Detector resolution: 8.3333 pixels mm-1Rint = 0.048
φ and ω scansθmax = 25.0°, θmin = 1.7°
Absorption correction: multi-scan
SADABS (Bruker AXS)
h = 99
Tmin = 0.76, Tmax = 0.94k = 2727
24307 measured reflectionsl = 1111
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.028H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.066 w = 1/[σ2(Fo2) + (0.0298P)2 + 0.7573P]
where P = (Fo2 + 2Fc2)/3
S = 1.03(Δ/σ)max = 0.001
6511 reflectionsΔρmax = 0.45 e Å3
539 parametersΔρmin = 0.61 e Å3
4 restraintsAbsolute structure: Flack H D (1983), Acta Cryst. A39, 876-881
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.235 (17)
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.34021 (4)0.32038 (13)0.22564 (3)0.03003 (8)
Ag20.20589 (4)0.106008 (12)0.56158 (3)0.03209 (9)
C10.8395 (5)0.14828 (16)0.5282 (4)0.0260 (8)
H10.8740.1690.45490.031*
C20.6993 (4)0.16493 (15)0.5723 (4)0.0212 (8)
C30.6440 (5)0.13567 (17)0.6774 (4)0.0296 (9)
H30.54810.14720.70950.036*
C40.7348 (5)0.08867 (17)0.7340 (5)0.0329 (10)
H40.70010.06640.80450.039*
C50.8753 (5)0.07465 (17)0.6873 (5)0.0318 (10)
H50.93790.04290.72870.038*
C61.0081 (5)0.30656 (15)0.3242 (4)0.0219 (8)
H61.04220.26790.32880.026*
C70.8609 (4)0.32025 (17)0.3602 (3)0.0208 (7)
C80.8080 (5)0.37596 (17)0.3530 (5)0.0298 (9)
H80.70520.38610.3750.036*
C90.9093 (6)0.41643 (17)0.3128 (5)0.0360 (11)
H90.87810.45540.30830.043*
C101.0571 (5)0.39999 (18)0.2789 (5)0.0308 (9)
H101.12640.42830.25190.037*
C110.2579 (5)0.24308 (16)0.6142 (4)0.0234 (8)
H110.28010.24250.52160.028*
C120.2596 (4)0.29461 (15)0.6851 (4)0.0191 (8)
C130.2254 (5)0.29713 (16)0.8171 (4)0.0211 (8)
H130.22640.33230.86540.025*
C140.1896 (5)0.24711 (16)0.8781 (4)0.0255 (9)
H140.16340.24730.96930.031*
C150.1920 (5)0.19650 (16)0.8053 (4)0.0254 (9)
H150.16910.16210.84930.03*
C160.5352 (5)0.22074 (18)1.1195 (4)0.0313 (9)
H160.46770.19831.16670.038*
C170.6521 (6)0.19373 (18)1.0602 (5)0.0395 (11)
H170.66450.15361.0670.047*
C180.7520 (5)0.22594 (18)0.9902 (4)0.0324 (10)
H180.83450.20890.94870.039*
C190.7251 (5)0.28326 (16)0.9842 (4)0.0237 (8)
C200.6066 (4)0.30817 (16)1.0451 (4)0.0223 (8)
H200.59140.34821.03840.027*
C210.5741 (5)0.50349 (15)0.4992 (4)0.0215 (8)
H210.59670.48990.41250.026*
C220.4856 (4)0.46965 (15)0.5738 (4)0.0196 (8)
C230.4513 (5)0.48748 (16)0.7003 (4)0.0271 (9)
H230.39120.46440.75280.033*
C240.5089 (6)0.54079 (17)0.7472 (4)0.0322 (9)
H240.48950.5550.83430.039*
C250.5934 (6)0.57296 (17)0.6684 (4)0.0313 (9)
H250.62880.60980.70150.038*
C260.8861 (6)0.45095 (18)0.9289 (5)0.0349 (10)
H260.82980.42430.97570.042*
C270.9342 (5)0.43539 (17)0.8057 (4)0.0263 (9)
C281.0104 (6)0.47383 (19)0.7347 (5)0.0363 (10)
H281.04180.46370.64880.044*
C291.0405 (6)0.52687 (19)0.7897 (5)0.0426 (11)
H291.09310.55450.74230.051*
C300.9940 (6)0.54017 (18)0.9147 (5)0.0385 (11)
H301.01760.57710.95320.046*
N10.5155 (4)0.31435 (13)0.4813 (3)0.0195 (6)
N20.7964 (4)0.28475 (13)0.6634 (3)0.0230 (7)
N30.5967 (4)0.36499 (13)0.7365 (3)0.0220 (7)
N40.5122 (4)0.27717 (14)1.1138 (3)0.0254 (7)
N50.9176 (5)0.50343 (16)0.9838 (4)0.0419 (10)
N60.6289 (4)0.55502 (13)0.5461 (4)0.0257 (7)
N71.1052 (4)0.34590 (14)0.2828 (3)0.0251 (7)
N80.9285 (4)0.10381 (15)0.5854 (4)0.0294 (7)
N90.1256 (5)0.17570 (14)0.2225 (4)0.0306 (8)
N100.3957 (4)0.44769 (14)0.0805 (4)0.0290 (8)
N110.2252 (4)0.19384 (13)0.6752 (3)0.0239 (7)
O10.6065 (3)0.21109 (11)0.5083 (3)0.0240 (6)
O20.7685 (3)0.27422 (10)0.3927 (3)0.0210 (5)
O30.2909 (3)0.34550 (10)0.6181 (3)0.0211 (5)
O40.4330 (3)0.41726 (10)0.5130 (3)0.0235 (6)
O50.9131 (3)0.38058 (11)0.7490 (3)0.0264 (6)
O60.8277 (3)0.31915 (12)0.9221 (2)0.0229 (5)
O70.1232 (6)0.16508 (15)0.0984 (3)0.0582 (11)
O80.0152 (5)0.16013 (16)0.2802 (5)0.0700 (13)
O90.2464 (4)0.20221 (14)0.2933 (4)0.0471 (9)
O100.4545 (5)0.42822 (15)0.1996 (3)0.0552 (10)
O110.4210 (4)0.49775 (13)0.0515 (3)0.0371 (7)
O120.3117 (5)0.41592 (15)0.0061 (4)0.0629 (12)
O130.2745 (4)0.04496 (14)0.8083 (3)0.0409 (8)
P10.67216 (12)0.27431 (4)0.51900 (10)0.01870 (19)
P20.77315 (12)0.33639 (4)0.76099 (10)0.0203 (2)
P30.46961 (11)0.35810 (4)0.59232 (10)0.0184 (2)
H1W0.371 (3)0.0310 (17)0.834 (4)0.028*
H2W0.219 (4)0.0309 (17)0.864 (4)0.028*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.02455 (15)0.03687 (17)0.03186 (16)0.00170 (14)0.01327 (12)0.00140 (14)
Ag20.03070 (17)0.02298 (15)0.04540 (19)0.00665 (13)0.01440 (14)0.00558 (14)
C10.024 (2)0.0240 (19)0.031 (2)0.0015 (16)0.0100 (17)0.0019 (16)
C20.0184 (19)0.0173 (18)0.028 (2)0.0022 (15)0.0043 (16)0.0019 (15)
C30.024 (2)0.028 (2)0.038 (2)0.0010 (17)0.0100 (18)0.0031 (18)
C40.026 (2)0.030 (2)0.045 (3)0.0032 (17)0.011 (2)0.0109 (18)
C50.031 (2)0.022 (2)0.041 (2)0.0006 (17)0.0017 (19)0.0069 (18)
C60.0207 (19)0.022 (2)0.0233 (19)0.0018 (15)0.0059 (15)0.0006 (14)
C70.0245 (18)0.0203 (17)0.0175 (16)0.0016 (17)0.0039 (14)0.0003 (16)
C80.027 (2)0.028 (2)0.038 (2)0.0061 (17)0.0163 (19)0.0036 (17)
C90.043 (3)0.019 (2)0.051 (3)0.0053 (19)0.022 (2)0.0086 (19)
C100.032 (2)0.025 (2)0.038 (2)0.0020 (18)0.0132 (19)0.0069 (18)
C110.0196 (19)0.026 (2)0.0257 (19)0.0002 (16)0.0074 (16)0.0004 (16)
C120.0131 (17)0.0176 (17)0.027 (2)0.0023 (14)0.0053 (15)0.0041 (15)
C130.0198 (19)0.0186 (18)0.025 (2)0.0007 (15)0.0042 (16)0.0062 (15)
C140.027 (2)0.029 (2)0.0213 (19)0.0028 (17)0.0087 (17)0.0004 (16)
C150.028 (2)0.019 (2)0.030 (2)0.0007 (16)0.0086 (17)0.0050 (16)
C160.033 (2)0.032 (2)0.030 (2)0.0010 (19)0.0102 (19)0.0056 (18)
C170.048 (3)0.023 (2)0.051 (3)0.006 (2)0.017 (2)0.0070 (19)
C180.032 (2)0.032 (2)0.034 (2)0.0088 (18)0.0107 (19)0.0002 (18)
C190.021 (2)0.029 (2)0.0202 (19)0.0018 (16)0.0023 (16)0.0032 (15)
C200.0220 (19)0.023 (2)0.0218 (18)0.0003 (15)0.0040 (15)0.0028 (14)
C210.024 (2)0.0164 (18)0.025 (2)0.0011 (15)0.0064 (16)0.0003 (15)
C220.0186 (18)0.0113 (16)0.029 (2)0.0002 (14)0.0048 (16)0.0015 (15)
C230.030 (2)0.0207 (19)0.035 (2)0.0032 (17)0.0155 (19)0.0071 (16)
C240.044 (3)0.021 (2)0.035 (2)0.0025 (18)0.016 (2)0.0032 (17)
C250.041 (2)0.017 (2)0.038 (2)0.0040 (17)0.012 (2)0.0061 (17)
C260.043 (3)0.028 (2)0.036 (2)0.0067 (19)0.012 (2)0.0048 (18)
C270.024 (2)0.0217 (19)0.031 (2)0.0011 (17)0.0021 (18)0.0014 (17)
C280.035 (2)0.035 (2)0.039 (2)0.004 (2)0.009 (2)0.006 (2)
C290.047 (3)0.024 (2)0.055 (3)0.008 (2)0.007 (2)0.006 (2)
C300.038 (3)0.019 (2)0.055 (3)0.0037 (19)0.002 (2)0.0049 (19)
N10.0197 (15)0.0182 (15)0.0209 (14)0.0004 (13)0.0050 (12)0.0012 (13)
N20.0182 (16)0.0228 (17)0.0280 (17)0.0007 (13)0.0048 (14)0.0005 (13)
N30.0245 (17)0.0201 (16)0.0230 (16)0.0009 (13)0.0086 (14)0.0015 (13)
N40.0256 (17)0.0278 (17)0.0222 (16)0.0015 (14)0.0034 (14)0.0011 (14)
N50.047 (2)0.028 (2)0.051 (2)0.0027 (17)0.011 (2)0.0128 (18)
N60.0262 (17)0.0170 (16)0.0346 (18)0.0025 (13)0.0080 (15)0.0028 (13)
N70.0240 (17)0.0258 (17)0.0268 (17)0.0028 (14)0.0087 (14)0.0005 (14)
N80.0253 (17)0.0215 (16)0.0436 (19)0.0003 (16)0.0120 (15)0.0035 (17)
N90.044 (2)0.0169 (17)0.034 (2)0.0020 (16)0.0138 (18)0.0026 (14)
N100.0277 (19)0.0273 (19)0.033 (2)0.0001 (15)0.0085 (16)0.0058 (15)
N110.0245 (17)0.0188 (16)0.0303 (18)0.0018 (13)0.0095 (14)0.0011 (13)
O10.0212 (14)0.0197 (13)0.0315 (14)0.0014 (11)0.0061 (11)0.0013 (11)
O20.0221 (14)0.0196 (13)0.0242 (14)0.0027 (10)0.0115 (11)0.0031 (10)
O30.0200 (13)0.0163 (12)0.0285 (14)0.0022 (10)0.0088 (11)0.0020 (10)
O40.0296 (15)0.0146 (13)0.0264 (14)0.0044 (11)0.0061 (12)0.0021 (10)
O50.0251 (14)0.0225 (14)0.0336 (15)0.0050 (11)0.0108 (12)0.0043 (11)
O60.0212 (12)0.0275 (13)0.0215 (12)0.0013 (12)0.0077 (10)0.0016 (12)
O70.108 (3)0.043 (2)0.0275 (17)0.023 (2)0.0219 (19)0.0015 (15)
O80.081 (3)0.049 (2)0.101 (3)0.021 (2)0.068 (3)0.024 (2)
O90.043 (2)0.0420 (19)0.056 (2)0.0066 (16)0.0089 (17)0.0162 (16)
O100.081 (3)0.046 (2)0.0311 (18)0.017 (2)0.0055 (18)0.0069 (15)
O110.0419 (18)0.0283 (16)0.0423 (18)0.0021 (14)0.0117 (15)0.0046 (14)
O120.074 (3)0.039 (2)0.060 (2)0.0054 (19)0.024 (2)0.0110 (18)
O130.0394 (18)0.0401 (19)0.0442 (19)0.0084 (15)0.0106 (15)0.0143 (15)
P10.0184 (5)0.0165 (4)0.0225 (5)0.0003 (4)0.0073 (4)0.0002 (4)
P20.0189 (4)0.0208 (5)0.0219 (5)0.0010 (4)0.0059 (4)0.0007 (4)
P30.0190 (5)0.0147 (4)0.0227 (5)0.0010 (4)0.0075 (4)0.0011 (4)
Geometric parameters (Å, º) top
Ag1—N4i2.205 (3)C20—N41.340 (5)
Ag1—N7ii2.215 (3)C20—H200.95
Ag1—N12.608 (3)C21—N61.341 (5)
Ag2—N6iii2.231 (3)C21—C221.381 (5)
Ag2—N112.330 (3)C21—H210.95
Ag2—N8ii2.360 (3)C22—C231.376 (5)
C1—N81.334 (5)C22—O41.397 (4)
C1—C21.375 (5)C23—C241.385 (6)
C1—H10.95C23—H230.95
C2—C31.381 (6)C24—C251.364 (6)
C2—O11.401 (4)C24—H240.95
C3—C41.387 (6)C25—N61.343 (5)
C3—H30.95C25—H250.95
C4—C51.373 (6)C26—N51.348 (6)
C4—H40.95C26—C271.380 (6)
C5—N81.346 (5)C26—H260.95
C5—H50.95C27—C281.365 (6)
C6—N71.340 (5)C27—O51.398 (5)
C6—C71.374 (5)C28—C291.359 (6)
C6—H60.95C28—H280.95
C7—C81.379 (6)C29—C301.378 (7)
C7—O21.398 (5)C29—H290.95
C8—C91.376 (6)C30—N51.329 (6)
C8—H80.95C30—H300.95
C9—C101.387 (6)N1—P11.587 (3)
C9—H90.95N1—P31.588 (3)
C10—N71.331 (5)N2—P21.574 (3)
C10—H100.95N2—P11.580 (3)
C11—N111.351 (5)N3—P31.579 (3)
C11—C121.391 (5)N3—P21.585 (3)
C11—H110.95N4—Ag1iv2.205 (3)
C12—C131.364 (5)N6—Ag2v2.231 (3)
C12—O31.410 (4)N7—Ag1vi2.215 (3)
C13—C141.375 (5)N8—Ag2vi2.360 (3)
C13—H130.95N9—O81.221 (5)
C14—C151.385 (5)N9—O71.222 (4)
C14—H140.95N9—O91.259 (5)
C15—N111.343 (5)N10—O121.229 (5)
C15—H150.95N10—O111.238 (4)
C16—N41.340 (5)N10—O101.245 (5)
C16—C171.378 (6)O1—P11.579 (3)
C16—H160.95O2—P11.589 (3)
C17—C181.395 (6)O3—P31.580 (3)
C17—H170.95O4—P31.588 (3)
C18—C191.365 (6)O5—P21.580 (3)
C18—H180.95O6—P21.586 (2)
C19—C201.375 (5)O13—H1W0.852 (18)
C19—O61.416 (5)O13—H2W0.840 (18)
N4i—Ag1—N7ii159.55 (12)C24—C23—H23121.7
N4i—Ag1—N198.49 (10)C25—C24—C23120.1 (4)
N7ii—Ag1—N197.42 (11)C25—C24—H24120.0
N6iii—Ag2—N11134.93 (12)C23—C24—H24120.0
N6iii—Ag2—N8ii137.48 (12)N6—C25—C24123.1 (4)
N11—Ag2—N8ii87.09 (12)N6—C25—H25118.4
N8—C1—C2121.8 (4)C24—C25—H25118.4
N8—C1—H1119.1N5—C26—C27121.1 (4)
C2—C1—H1119.1N5—C26—H26119.5
C1—C2—C3121.0 (4)C27—C26—H26119.5
C1—C2—O1120.5 (3)C28—C27—C26120.2 (4)
C3—C2—O1118.5 (3)C28—C27—O5116.6 (4)
C2—C3—C4116.9 (4)C26—C27—O5123.2 (4)
C2—C3—H3121.5C29—C28—C27118.6 (4)
C4—C3—H3121.5C29—C28—H28120.7
C5—C4—C3119.5 (4)C27—C28—H28120.7
C5—C4—H4120.3C28—C29—C30119.3 (4)
C3—C4—H4120.3C28—C29—H29120.3
N8—C5—C4122.9 (4)C30—C29—H29120.3
N8—C5—H5118.5N5—C30—C29122.7 (4)
C4—C5—H5118.5N5—C30—H30118.7
N7—C6—C7122.2 (3)C29—C30—H30118.7
N7—C6—H6118.9P1—N1—P3121.72 (18)
C7—C6—H6118.9P1—N1—Ag1121.67 (15)
C6—C7—C8120.0 (4)P3—N1—Ag1116.23 (15)
C6—C7—O2115.6 (3)P2—N2—P1120.9 (2)
C8—C7—O2124.3 (3)P3—N3—P2121.4 (2)
C9—C8—C7117.7 (4)C16—N4—C20117.8 (3)
C9—C8—H8121.2C16—N4—Ag1iv122.5 (3)
C7—C8—H8121.2C20—N4—Ag1iv119.6 (3)
C8—C9—C10119.6 (4)C30—N5—C26118.1 (4)
C8—C9—H9120.2C21—N6—C25117.5 (3)
C10—C9—H9120.2C21—N6—Ag2v121.7 (3)
N7—C10—C9122.3 (4)C25—N6—Ag2v120.4 (3)
N7—C10—H10118.9C10—N7—C6118.3 (3)
C9—C10—H10118.9C10—N7—Ag1vi121.7 (3)
N11—C11—C12120.9 (4)C6—N7—Ag1vi120.0 (3)
N11—C11—H11119.5C1—N8—C5117.9 (4)
C12—C11—H11119.5C1—N8—Ag2vi114.3 (3)
C13—C12—C11121.1 (3)C5—N8—Ag2vi123.5 (3)
C13—C12—O3119.1 (3)O8—N9—O7121.5 (4)
C11—C12—O3119.8 (3)O8—N9—O9119.2 (4)
C12—C13—C14117.9 (3)O7—N9—O9119.3 (4)
C12—C13—H13121.0O12—N10—O11121.5 (4)
C14—C13—H13121.0O12—N10—O10118.0 (4)
C13—C14—C15119.4 (4)O11—N10—O10120.4 (3)
C13—C14—H14120.3C15—N11—C11117.8 (3)
C15—C14—H14120.3C15—N11—Ag2118.4 (2)
N11—C15—C14122.9 (3)C11—N11—Ag2123.7 (3)
N11—C15—H15118.6C2—O1—P1123.3 (2)
C14—C15—H15118.6C7—O2—P1123.7 (2)
N4—C16—C17123.1 (4)C12—O3—P3119.8 (2)
N4—C16—H16118.5C22—O4—P3123.8 (2)
C17—C16—H16118.5C27—O5—P2127.8 (3)
C16—C17—C18119.3 (4)C19—O6—P2119.5 (2)
C16—C17—H17120.4H1W—O13—H2W105 (3)
C18—C17—H17120.4O1—P1—N2111.07 (15)
C19—C18—C17116.6 (4)O1—P1—N1106.72 (16)
C19—C18—H18121.7N2—P1—N1118.03 (16)
C17—C18—H18121.7O1—P1—O299.71 (14)
C18—C19—C20121.8 (4)N2—P1—O2109.89 (16)
C18—C19—O6120.0 (4)N1—P1—O2109.84 (15)
C20—C19—O6118.1 (3)N2—P2—O5106.41 (16)
N4—C20—C19121.4 (3)N2—P2—N3117.32 (16)
N4—C20—H20119.3O5—P2—N3112.36 (16)
C19—C20—H20119.3N2—P2—O6110.31 (16)
N6—C21—C22121.6 (4)O5—P2—O699.89 (14)
N6—C21—H21119.2N3—P2—O6109.14 (15)
C22—C21—H21119.2N3—P3—O3111.19 (16)
C23—C22—C21121.1 (3)N3—P3—N1117.09 (16)
C23—C22—O4122.7 (3)O3—P3—N1110.22 (15)
C21—C22—O4116.2 (3)N3—P3—O4111.44 (15)
C22—C23—C24116.6 (4)O3—P3—O498.41 (14)
C22—C23—H23121.7N1—P3—O4106.82 (16)
N8—C1—C2—C30.7 (6)C12—C11—N11—C151.0 (5)
N8—C1—C2—O1178.7 (3)C12—C11—N11—Ag2176.7 (3)
C1—C2—C3—C40.9 (6)N6iii—Ag2—N11—C15128.5 (3)
O1—C2—C3—C4177.2 (3)N8ii—Ag2—N11—C1558.8 (3)
C2—C3—C4—C52.0 (6)N6iii—Ag2—N11—C1155.8 (4)
C3—C4—C5—N81.6 (7)N8ii—Ag2—N11—C11116.8 (3)
N7—C6—C7—C80.7 (6)C1—C2—O1—P166.1 (4)
N7—C6—C7—O2176.1 (3)C3—C2—O1—P1115.9 (3)
C6—C7—C8—C91.7 (6)C6—C7—O2—P1139.0 (3)
O2—C7—C8—C9176.8 (4)C8—C7—O2—P145.8 (5)
C7—C8—C9—C101.2 (7)C13—C12—O3—P3111.4 (3)
C8—C9—C10—N70.4 (7)C11—C12—O3—P371.0 (4)
N11—C11—C12—C131.2 (6)C23—C22—O4—P354.2 (5)
N11—C11—C12—O3178.8 (3)C21—C22—O4—P3126.3 (3)
C11—C12—C13—C140.1 (6)C28—C27—O5—P2151.4 (3)
O3—C12—C13—C14177.7 (3)C26—C27—O5—P230.3 (6)
C12—C13—C14—C151.0 (6)C18—C19—O6—P294.5 (4)
C13—C14—C15—N111.2 (6)C20—C19—O6—P289.5 (4)
N4—C16—C17—C180.2 (7)C2—O1—P1—N230.7 (3)
C16—C17—C18—C190.5 (7)C2—O1—P1—N1160.6 (3)
C17—C18—C19—C200.5 (6)C2—O1—P1—O285.1 (3)
C17—C18—C19—O6176.3 (4)P2—N2—P1—O1128.5 (2)
C18—C19—C20—N40.2 (6)P2—N2—P1—N14.9 (3)
O6—C19—C20—N4175.7 (3)P2—N2—P1—O2122.1 (2)
N6—C21—C22—C230.5 (6)P3—N1—P1—O1117.5 (2)
N6—C21—C22—O4179.0 (3)Ag1—N1—P1—O169.81 (19)
C21—C22—C23—C240.5 (6)P3—N1—P1—N28.3 (3)
O4—C22—C23—C24179.0 (3)Ag1—N1—P1—N2164.38 (16)
C22—C23—C24—C250.6 (6)P3—N1—P1—O2135.3 (2)
C23—C24—C25—N61.8 (7)Ag1—N1—P1—O237.4 (2)
N5—C26—C27—C282.1 (7)C7—O2—P1—O1175.9 (3)
N5—C26—C27—O5176.1 (4)C7—O2—P1—N259.2 (3)
C26—C27—C28—C291.4 (6)C7—O2—P1—N172.2 (3)
O5—C27—C28—C29177.0 (4)P1—N2—P2—O5107.7 (2)
C27—C28—C29—C300.2 (7)P1—N2—P2—N319.0 (3)
C28—C29—C30—N51.2 (7)P1—N2—P2—O6144.8 (2)
N4i—Ag1—N1—P113.3 (2)C27—O5—P2—N2173.5 (3)
N7ii—Ag1—N1—P1153.80 (19)C27—O5—P2—N343.9 (4)
N4i—Ag1—N1—P3159.75 (17)C27—O5—P2—O671.7 (3)
N7ii—Ag1—N1—P333.13 (19)P3—N3—P2—N221.0 (3)
C17—C16—N4—C200.9 (6)P3—N3—P2—O5102.8 (2)
C17—C16—N4—Ag1iv174.3 (3)P3—N3—P2—O6147.4 (2)
C19—C20—N4—C160.9 (5)C19—O6—P2—N274.4 (3)
C19—C20—N4—Ag1iv174.4 (3)C19—O6—P2—O5173.9 (3)
C29—C30—N5—C260.6 (7)C19—O6—P2—N355.9 (3)
C27—C26—N5—C301.1 (7)P2—N3—P3—O3136.4 (2)
C22—C21—N6—C250.6 (5)P2—N3—P3—N18.5 (3)
C22—C21—N6—Ag2v173.4 (3)P2—N3—P3—O4114.9 (2)
C24—C25—N6—C211.7 (6)C12—O3—P3—N364.6 (3)
C24—C25—N6—Ag2v172.3 (3)C12—O3—P3—N166.9 (3)
C9—C10—N7—C61.5 (6)C12—O3—P3—O4178.4 (2)
C9—C10—N7—Ag1vi179.2 (3)P1—N1—P3—N36.5 (3)
C7—C6—N7—C101.0 (5)Ag1—N1—P3—N3166.57 (15)
C7—C6—N7—Ag1vi179.7 (3)P1—N1—P3—O3121.9 (2)
C2—C1—N8—C51.1 (6)Ag1—N1—P3—O365.04 (18)
C2—C1—N8—Ag2vi156.5 (3)P1—N1—P3—O4132.2 (2)
C4—C5—N8—C10.0 (6)Ag1—N1—P3—O440.9 (2)
C4—C5—N8—Ag2vi155.5 (3)C22—O4—P3—N39.7 (3)
C14—C15—N11—C110.2 (6)C22—O4—P3—O3107.1 (3)
C14—C15—N11—Ag2175.8 (3)C22—O4—P3—N1138.7 (3)
Symmetry codes: (i) x, y, z1; (ii) x1, y, z; (iii) x+1, y1/2, z+1; (iv) x, y, z+1; (v) x+1, y+1/2, z+1; (vi) x+1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O13—H1W···O11iii0.85 (2)2.01 (2)2.842 (4)163 (4)
O13—H2W···N5vii0.84 (2)2.14 (2)2.972 (5)174 (4)
Symmetry codes: (iii) x+1, y1/2, z+1; (vii) x+1, y1/2, z+2.
(CCDC1422436) top
Crystal data top
C30H24AgN9O6P3·CF3SO3Dx = 1.822 Mg m3
Mr = 956.43Mo Kα radiation, λ = 0.71073 Å
Trigonal, R3Cell parameters from 126 reflections
a = 12.5705 (11) Åθ = 2.0–24.7°
c = 38.213 (6) ŵ = 0.86 mm1
V = 5229.3 (12) Å3T = 150 K
Z = 6Plate, colourless
F(000) = 28800.23 × 0.19 × 0.07 mm
Data collection top
Bruker APEX II QUAZAR three-circle
diffractometer
2067 independent reflections
Multilayer QUAZAR mirrors monochromator1901 reflections with I > 2σ(I)
Detector resolution: 8.3333 pixels mm-1Rint = 0.060
φ and ω scansθmax = 25.1°, θmin = 1.6°
Absorption correction: multi-scan
SADABS (Bruker AXS)
h = 1414
Tmin = 0.82, Tmax = 0.94k = 1414
22685 measured reflectionsl = 4545
Refinement top
Refinement on F20 restraints
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.025H-atom parameters constrained
wR(F2) = 0.068 w = 1/[σ2(Fo2) + (0.0281P)2 + 12.4135P]
where P = (Fo2 + 2Fc2)/3
S = 1.06(Δ/σ)max < 0.001
2067 reflectionsΔρmax = 0.30 e Å3
149 parametersΔρmin = 0.29 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.33330.66670.16670.03389 (13)
Ag20000.03704 (13)
P10.19676 (5)0.55597 (5)0.01204 (2)0.02602 (14)
O20.08475 (13)0.46469 (13)0.03560 (4)0.0298 (3)
O10.13571 (14)0.51171 (13)0.02530 (4)0.0311 (3)
N10.22408 (16)0.69205 (16)0.01723 (5)0.0287 (4)
N20.02707 (17)0.18288 (17)0.03716 (5)0.0356 (4)
N30.15963 (18)0.51644 (18)0.12871 (5)0.0368 (4)
C40.08824 (18)0.44391 (19)0.07127 (5)0.0281 (4)
C90.09255 (19)0.3960 (2)0.04012 (5)0.0292 (4)
C100.0729 (2)0.2932 (2)0.02177 (6)0.0325 (5)
H100.09230.30070.00250.039*
C30.0171 (2)0.3259 (2)0.08304 (6)0.0412 (6)
H30.0320.26080.06740.049*
C10.0925 (2)0.4010 (2)0.13997 (6)0.0398 (5)
H10.09560.38480.16410.048*
C60.0011 (2)0.1753 (2)0.07130 (7)0.0415 (6)
H60.03290.09730.08230.05*
C50.1555 (2)0.5370 (2)0.09458 (6)0.0329 (5)
H50.20060.61890.08610.039*
C20.0192 (2)0.3046 (2)0.11840 (6)0.0455 (6)
H20.02950.22420.12770.055*
C70.0210 (3)0.2744 (3)0.09122 (7)0.0474 (6)
H70.00250.26490.11550.057*
C80.0682 (2)0.3882 (2)0.07552 (6)0.0397 (6)
H80.08340.45860.08860.048*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.03709 (16)0.03709 (16)0.0275 (2)0.01855 (8)00
Ag20.03337 (16)0.03337 (16)0.0444 (3)0.01668 (8)00
P10.0242 (3)0.0250 (3)0.0276 (3)0.0114 (2)0.0004 (2)0.0007 (2)
O20.0253 (7)0.0304 (8)0.0295 (8)0.0106 (6)0.0005 (6)0.0001 (6)
O10.0349 (8)0.0296 (8)0.0291 (8)0.0163 (7)0.0049 (6)0.0018 (6)
N10.0260 (9)0.0291 (9)0.0318 (9)0.0143 (8)0.0005 (7)0.0000 (7)
N20.0325 (10)0.0319 (10)0.0403 (11)0.0144 (8)0.0006 (8)0.0065 (8)
N30.0358 (10)0.0368 (11)0.0328 (10)0.0145 (9)0.0010 (8)0.0015 (8)
C40.0237 (10)0.0309 (11)0.0302 (11)0.0139 (9)0.0028 (8)0.0004 (9)
C90.0254 (10)0.0314 (11)0.0309 (11)0.0143 (9)0.0024 (9)0.0043 (9)
C100.0320 (11)0.0343 (12)0.0302 (11)0.0158 (10)0.0003 (9)0.0031 (9)
C30.0395 (13)0.0308 (12)0.0399 (13)0.0076 (10)0.0005 (10)0.0015 (10)
C10.0370 (13)0.0445 (14)0.0332 (12)0.0167 (11)0.0038 (10)0.0051 (10)
C60.0381 (13)0.0424 (14)0.0475 (14)0.0229 (11)0.0120 (11)0.0178 (11)
C50.0323 (12)0.0300 (11)0.0328 (12)0.0128 (10)0.0025 (9)0.0009 (9)
C20.0473 (15)0.0350 (13)0.0395 (13)0.0095 (11)0.0039 (11)0.0073 (11)
C70.0596 (17)0.0602 (17)0.0372 (13)0.0410 (14)0.0201 (12)0.0172 (12)
C80.0499 (14)0.0471 (14)0.0332 (12)0.0327 (12)0.0090 (11)0.0048 (10)
Geometric parameters (Å, º) top
Ag1—N32.5128 (19)O2—C41.393 (3)
Ag1—N3i2.5129 (19)O1—C91.393 (3)
Ag1—N3ii2.5129 (19)N1—P1i1.5824 (18)
Ag1—N3iii2.5129 (19)N2—C61.337 (3)
Ag1—N3iv2.5129 (19)N2—C101.343 (3)
Ag1—N3v2.5129 (19)N3—C11.333 (3)
Ag2—N2vi2.576 (2)N3—C51.335 (3)
Ag2—N2vii2.576 (2)C4—C31.370 (3)
Ag2—N2viii2.576 (2)C4—C51.374 (3)
Ag2—N2ix2.576 (2)C9—C81.379 (3)
Ag2—N2x2.576 (2)C9—C101.380 (3)
Ag2—N22.576 (2)C3—C21.380 (3)
P1—O21.5792 (15)C1—C21.371 (4)
P1—N11.5797 (18)C6—C71.372 (4)
P1—N1ii1.5824 (18)C7—C81.382 (3)
P1—O11.5836 (15)
N3—Ag1—N3i90.01 (6)O2—P1—N1110.33 (9)
N3—Ag1—N3ii90.01 (6)O2—P1—N1ii109.99 (9)
N3i—Ag1—N3ii90.01 (6)N1—P1—N1ii117.11 (12)
N3—Ag1—N3iii89.99 (6)O2—P1—O199.14 (8)
N3i—Ag1—N3iii89.99 (6)N1—P1—O1107.35 (9)
N3ii—Ag1—N3iii180.0N1ii—P1—O1111.40 (9)
N3—Ag1—N3iv180.0C4—O2—P1126.43 (13)
N3i—Ag1—N3iv89.99 (6)C9—O1—P1126.91 (13)
N3ii—Ag1—N3iv89.99 (6)P1—N1—P1i119.80 (11)
N3iii—Ag1—N3iv90.01 (6)C6—N2—C10117.7 (2)
N3—Ag1—N3v89.99 (6)C6—N2—Ag2123.79 (15)
N3i—Ag1—N3v180.0C10—N2—Ag2118.54 (15)
N3ii—Ag1—N3v89.99 (6)C1—N3—C5117.5 (2)
N3iii—Ag1—N3v90.01 (6)C1—N3—Ag1118.09 (15)
N3iv—Ag1—N3v90.01 (6)C5—N3—Ag1121.44 (15)
N2vi—Ag2—N2vii92.54 (6)C3—C4—C5120.0 (2)
N2vi—Ag2—N2viii87.46 (6)C3—C4—O2117.36 (19)
N2vii—Ag2—N2viii180.00 (11)C5—C4—O2122.57 (19)
N2vi—Ag2—N2ix92.53 (6)C8—C9—C10120.1 (2)
N2vii—Ag2—N2ix92.53 (6)C8—C9—O1115.47 (19)
N2viii—Ag2—N2ix87.47 (6)C10—C9—O1124.40 (19)
N2vi—Ag2—N2x87.47 (6)N2—C10—C9121.9 (2)
N2vii—Ag2—N2x87.47 (6)C4—C3—C2117.8 (2)
N2viii—Ag2—N2x92.53 (6)N3—C1—C2123.2 (2)
N2ix—Ag2—N2x180.00 (9)N2—C6—C7123.4 (2)
N2vi—Ag2—N2180.0N3—C5—C4122.3 (2)
N2vii—Ag2—N287.47 (6)C1—C2—C3119.1 (2)
N2viii—Ag2—N292.53 (6)C6—C7—C8119.2 (2)
N2ix—Ag2—N287.47 (6)C9—C8—C7117.7 (2)
N2x—Ag2—N292.53 (6)
N1—P1—O2—C479.60 (18)C5—C4—C3—C22.1 (4)
N1ii—P1—O2—C451.09 (18)O2—C4—C3—C2179.5 (2)
O1—P1—O2—C4167.95 (16)C5—N3—C1—C21.0 (4)
O2—P1—O1—C962.66 (18)Ag1—N3—C1—C2161.6 (2)
N1—P1—O1—C9177.43 (16)C10—N2—C6—C71.2 (4)
N1ii—P1—O1—C953.13 (19)Ag2—N2—C6—C7176.96 (19)
O2—P1—N1—P1i151.32 (11)C1—N3—C5—C41.9 (3)
N1ii—P1—N1—P1i24.5 (2)Ag1—N3—C5—C4158.02 (16)
O1—P1—N1—P1i101.62 (13)C3—C4—C5—N33.5 (3)
P1—O2—C4—C3142.00 (18)O2—C4—C5—N3179.22 (19)
P1—O2—C4—C540.7 (3)N3—C1—C2—C32.3 (4)
P1—O1—C9—C8166.40 (16)C4—C3—C2—C10.7 (4)
P1—O1—C9—C1014.2 (3)N2—C6—C7—C81.2 (4)
C6—N2—C10—C90.3 (3)C10—C9—C8—C71.8 (3)
Ag2—N2—C10—C9178.57 (16)O1—C9—C8—C7177.7 (2)
C8—C9—C10—N21.8 (3)C6—C7—C8—C90.3 (4)
O1—C9—C10—N2177.64 (19)
Symmetry codes: (i) x+y, x+1, z; (ii) y+1, xy+1, z; (iii) y1/3, x+y+1/3, z+1/3; (iv) x+2/3, y+4/3, z+1/3; (v) xy+2/3, x+1/3, z+1/3; (vi) x, y, z; (vii) y, x+y, z; (viii) y, xy, z; (ix) xy, x, z; (x) x+y, x, z.
 

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