Bis(2-amino­pyrimidine)silver(I) tri­fluoro­methane­sulfonate hemihydrate

Zhu, H.-L.; Yang, S.; Ma, J.-L.; Qiu, X.-Y.; Sun, L.; Shao, S.-C.

doi:10.1107/S1600536803022141

Bis(2-aminopyrimidine)silver(I) trifluoromethanesulfonate hemihydrate

H.-L. Zhu, S. Yang, J.-L. Ma, X.-Y. Qiu, L. Sun and S.-C. Shao

In the title compound, [Ag(C₄H₅N₃)₂](CF₃O₃S)·0.5H₂O, there are two similar mononuclear Ag^I complex cations in the asymmetric unit. Each of the Ag atoms is coordinated by two imine N atoms from two 2-aminopyridine ligands and is in a distorted linear geometry. Numerous weak interactions connect the complexes to form a three-dimensional structure.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803022141/ww6119sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536803022141/ww6119Isup2.hkl Contains datablock I

CCDC reference: 226665

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.010 Å
R factor = 0.057
wR factor = 0.122
Data-to-parameter ratio = 13.5

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT029_ALERT_3_A _diffrn_measured_fraction_theta_full Low .......       0.97
PLAT732_ALERT_1_A Angle   Calc     116(10), Rep   117.0(10) ......       9.90 su-Rat
              H1WA -O1W  -H1WB    1.555   1.555   1.555
PLAT738_ALERT_1_A D-H..A  Calc     172(11), Rep   173.0(10) ......       9.90 su-Rat
              O1W  -H1WB -O1      1.555   1.555   1.555

Alert level C
CELLV02_ALERT_1_C  The supplied cell volume s.u. differs from that
            calculated from the cell parameter s.u.'s by > 2
            Calculated cell volume su =       8.10
            Cell volume su given      =       6.00
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.50 Ratio
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       3.41
PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent .....          ?
PLAT244_ALERT_4_C Low Solvent  U(eq) as Compared to Neighbors ....        C17
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         10
PLAT354_ALERT_3_C Short   O-H Bond (0.82A)   O1W    -   H1WA     =       0.71 Ang.
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          1
            N4  -AG1 -N1  -C4    102.80  1.70   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          2
            N4  -AG1 -N1  -C1    -73.90  1.90   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          3
            N1  -AG1 -N4  -C8     91.20  1.80   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          4
            N1  -AG1 -N4  -C5    -91.70  1.70   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          5
            N10 -AG2 -N7  -C12   -62.00  5.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          6
            N10 -AG2 -N7  -C9    118.00  4.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          7
            N7  -AG2 -N10 -C14  -120.00  4.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          8
            N7  -AG2 -N10 -C13    55.00  5.00   1.555   1.555   1.555   1.555
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          2
PLAT728_ALERT_1_C D-H..A  Calc      167.88, Rep      169.00, Dev.        1.12 Deg.
              N5   -H5B  -N3      1.555   1.555   1.455
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          4
              C F3 O3 S

   3 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  20 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   8 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
  11 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Siemens, 1996); cell refinement: SMART; data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 1997); software used to prepare material for publication: SHELXTL.

Bis(2-aminopyrimidine)silver(I) trifluoromethylsulfonate hemihydrate top

Crystal data top

[Ag(C₄H₅N₃)₂](CF₃O₃S)·0.5H₂O	Z = 4
M_r = 456.17	F(000) = 900
Triclinic, P1	D_x = 2.005 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.194 (2) Å	Cell parameters from 6425 reflections
b = 13.112 (3) Å	θ = 2.5–25.5°
c = 13.173 (3) Å	µ = 1.53 mm⁻¹
α = 113.67 (3)°	T = 293 K
β = 105.12 (3)°	Prism, colorless
γ = 96.20 (3)°	0.42 × 0.34 × 0.15 mm
V = 1511.1 (6) Å³

Data collection top

Siemens SMART CCD area-detector diffractometer	5758 independent reflections
Radiation source: fine-focus sealed tube	4440 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.025
φ and ω scans	θ_max = 26.0°, θ_min = 1.8°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −12→12
T_min = 0.541, T_max = 0.795	k = −16→16
6831 measured reflections	l = −16→10

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.057	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.122	H atoms treated by a mixture of independent and constrained refinement
S = 1.04	w = 1/[σ²(F_o²) + (0.0538P)²] where P = (F_o² + 2F_c²)/3
5758 reflections	(Δ/σ)_max = 0.001
425 parameters	Δρ_max = 2.12 e Å⁻³
0 restraints	Δρ_min = −0.62 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Ag1	0.58419 (5)	0.30062 (4)	0.44174 (5)	0.03512 (16)
Ag2	0.89936 (5)	0.86983 (4)	0.88621 (5)	0.03593 (16)
S1	0.68113 (16)	0.52030 (13)	0.75549 (16)	0.0318 (4)
S2	1.90310 (15)	0.88411 (13)	1.22778 (15)	0.0288 (4)
F1	0.5074 (5)	0.3515 (4)	0.7417 (4)	0.0843 (18)
F2	0.4665 (4)	0.5148 (4)	0.8267 (4)	0.0658 (13)
F3	0.6337 (4)	0.4683 (3)	0.9169 (4)	0.0542 (11)
F4	1.6677 (4)	0.7317 (4)	1.0922 (4)	0.0663 (13)
F5	1.7711 (5)	0.7157 (3)	1.2475 (4)	0.0580 (12)
F6	1.8495 (4)	0.6618 (3)	1.1039 (4)	0.0539 (11)
O1	0.7835 (5)	0.4532 (4)	0.7497 (5)	0.0556 (15)
O2	0.7344 (4)	0.6380 (3)	0.8421 (4)	0.0385 (11)
O3	0.5884 (5)	0.5025 (4)	0.6424 (4)	0.0461 (12)
O4	2.0316 (5)	0.8749 (4)	1.2961 (5)	0.0496 (13)
O5	1.8306 (5)	0.9565 (4)	1.2951 (4)	0.0421 (12)
O6	1.9110 (5)	0.9008 (4)	1.1279 (4)	0.0423 (12)
N1	0.7545 (5)	0.3715 (4)	0.4045 (4)	0.0292 (12)
N2	0.8902 (5)	0.2487 (4)	0.4332 (5)	0.0377 (14)
H2B	0.9663	0.2204	0.4299	0.080*
H2C	0.8271	0.2209	0.4582	0.080*
N3	0.9690 (5)	0.3703 (4)	0.3648 (5)	0.0317 (12)
N4	0.4083 (5)	0.2149 (4)	0.4598 (4)	0.0254 (11)
N5	0.2510 (6)	0.3071 (4)	0.3863 (5)	0.0383 (14)
H5A	0.3201	0.3436	0.3733	0.080*
H5B	0.1648	0.3196	0.3683	0.080*
N6	0.1675 (5)	0.1821 (4)	0.4494 (5)	0.0318 (12)
N7	0.7229 (5)	0.9380 (4)	0.8415 (4)	0.0262 (11)
N8	0.5750 (5)	0.8209 (4)	0.8810 (5)	0.0395 (15)
H8B	0.6447	0.7874	0.8978	0.080*
H8C	0.4913	0.7982	0.8859	0.080*
N9	0.4875 (5)	0.9505 (4)	0.8252 (5)	0.0320 (12)
N10	1.0750 (4)	0.7996 (4)	0.9240 (4)	0.0240 (11)
N11	1.2174 (5)	0.9027 (4)	0.8681 (5)	0.0298 (12)
H11B	1.1514	0.9412	0.8574	0.080*
H11C	1.2977	0.9183	0.8547	0.080*
N12	1.2983 (5)	0.7665 (4)	0.9175 (5)	0.0290 (12)
C1	0.8706 (6)	0.3314 (5)	0.4010 (5)	0.0276 (14)
C2	0.9535 (6)	0.4552 (6)	0.3366 (5)	0.0338 (15)
H2A	1.0243	0.4851	0.3132	0.080*
C3	0.8396 (6)	0.5040 (5)	0.3413 (6)	0.0369 (16)
H3A	0.8290	0.5653	0.3199	0.080*
C4	0.7418 (7)	0.4593 (5)	0.3772 (5)	0.0357 (16)
H4A	0.6629	0.4922	0.3835	0.080*
C5	0.2777 (6)	0.2331 (5)	0.4331 (5)	0.0289 (14)
C6	0.1922 (7)	0.1104 (5)	0.4952 (5)	0.0330 (15)
H6A	0.1164	0.0746	0.5095	0.080*
C7	0.3205 (7)	0.0833 (5)	0.5240 (6)	0.0338 (15)
H7A	0.3337	0.0283	0.5542	0.080*
C8	0.4268 (6)	0.1395 (5)	0.5059 (5)	0.0326 (15)
H8A	0.5180	0.1252	0.5270	0.080*
C9	0.5957 (6)	0.9043 (5)	0.8486 (5)	0.0281 (14)
C10	0.5047 (6)	1.0310 (5)	0.7902 (6)	0.0328 (15)
H10A	0.4280	1.0650	0.7735	0.080*
C11	0.6288 (6)	1.0679 (5)	0.7764 (5)	0.0297 (14)
H11A	0.6391	1.1247	0.7486	0.080*
C12	0.7360 (6)	1.0188 (5)	0.8043 (6)	0.0342 (16)
H12A	0.8240	1.0435	0.7974	0.080*
C13	1.1972 (6)	0.8228 (5)	0.9040 (5)	0.0257 (13)
C14	1.0610 (6)	0.7196 (5)	0.9630 (5)	0.0316 (15)
H14A	0.9767	0.7027	0.9789	0.080*
C15	1.1596 (7)	0.6620 (6)	0.9801 (6)	0.0390 (17)
H15A	1.1474	0.6056	1.0081	0.080*
C16	1.2810 (6)	0.6886 (5)	0.9559 (6)	0.0308 (15)
H16A	1.3536	0.6494	0.9671	0.080*
C17	0.5662 (7)	0.4597 (6)	0.8129 (6)	0.0384 (17)
C18	1.7926 (7)	0.7417 (6)	1.1645 (6)	0.0381 (16)
O1W	0.7656 (6)	0.2195 (6)	0.6053 (5)	0.0457 (14)
H1WA	0.794 (9)	0.184 (7)	0.630 (8)	0.07 (4)*
H1WB	0.772 (11)	0.291 (9)	0.656 (9)	0.12 (4)*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.0259 (3)	0.0405 (3)	0.0401 (3)	0.0035 (2)	0.0158 (2)	0.0174 (3)
Ag2	0.0219 (3)	0.0480 (3)	0.0434 (3)	0.0159 (2)	0.0144 (2)	0.0218 (3)
S1	0.0266 (8)	0.0289 (9)	0.0460 (11)	0.0082 (7)	0.0170 (8)	0.0193 (8)
S2	0.0260 (8)	0.0310 (9)	0.0386 (10)	0.0099 (7)	0.0136 (8)	0.0219 (8)
F1	0.102 (4)	0.052 (3)	0.069 (3)	−0.036 (3)	0.048 (3)	0.000 (2)
F2	0.048 (3)	0.116 (4)	0.075 (3)	0.045 (3)	0.041 (3)	0.063 (3)
F3	0.052 (3)	0.063 (3)	0.059 (3)	0.008 (2)	0.009 (2)	0.045 (2)
F4	0.034 (2)	0.066 (3)	0.070 (3)	−0.003 (2)	−0.002 (2)	0.019 (3)
F5	0.083 (3)	0.043 (2)	0.063 (3)	0.003 (2)	0.043 (3)	0.029 (2)
F6	0.067 (3)	0.036 (2)	0.057 (3)	0.013 (2)	0.030 (3)	0.013 (2)
O1	0.047 (3)	0.043 (3)	0.102 (5)	0.027 (2)	0.043 (3)	0.042 (3)
O2	0.040 (3)	0.025 (2)	0.048 (3)	0.004 (2)	0.009 (2)	0.019 (2)
O3	0.046 (3)	0.051 (3)	0.042 (3)	0.004 (2)	0.018 (3)	0.022 (3)
O4	0.036 (3)	0.044 (3)	0.067 (4)	0.011 (2)	0.000 (3)	0.033 (3)
O5	0.052 (3)	0.041 (3)	0.048 (3)	0.018 (2)	0.032 (3)	0.023 (2)
O6	0.052 (3)	0.047 (3)	0.053 (3)	0.023 (2)	0.034 (3)	0.034 (3)
N1	0.029 (3)	0.038 (3)	0.029 (3)	0.009 (2)	0.015 (2)	0.019 (3)
N2	0.039 (3)	0.041 (3)	0.051 (4)	0.015 (3)	0.025 (3)	0.031 (3)
N3	0.026 (3)	0.039 (3)	0.033 (3)	0.004 (2)	0.015 (3)	0.018 (3)
N4	0.021 (2)	0.026 (3)	0.030 (3)	0.004 (2)	0.009 (2)	0.013 (2)
N5	0.038 (3)	0.044 (3)	0.049 (4)	0.009 (3)	0.020 (3)	0.033 (3)
N6	0.030 (3)	0.035 (3)	0.038 (3)	0.005 (2)	0.016 (3)	0.021 (3)
N7	0.021 (2)	0.028 (3)	0.036 (3)	0.008 (2)	0.015 (2)	0.016 (2)
N8	0.022 (3)	0.038 (3)	0.076 (4)	0.014 (2)	0.020 (3)	0.038 (3)
N9	0.022 (3)	0.041 (3)	0.041 (3)	0.012 (2)	0.015 (3)	0.023 (3)
N10	0.015 (2)	0.029 (3)	0.030 (3)	0.008 (2)	0.010 (2)	0.013 (2)
N11	0.022 (3)	0.036 (3)	0.048 (3)	0.016 (2)	0.017 (3)	0.029 (3)
N12	0.023 (3)	0.033 (3)	0.038 (3)	0.011 (2)	0.015 (3)	0.018 (3)
C1	0.021 (3)	0.031 (4)	0.022 (3)	0.003 (3)	0.004 (3)	0.007 (3)
C2	0.029 (3)	0.046 (4)	0.026 (4)	0.005 (3)	0.010 (3)	0.017 (3)
C3	0.030 (4)	0.036 (4)	0.043 (4)	0.004 (3)	0.008 (3)	0.020 (3)
C4	0.031 (3)	0.040 (4)	0.025 (4)	0.007 (3)	0.004 (3)	0.008 (3)
C5	0.034 (3)	0.027 (3)	0.024 (3)	0.006 (3)	0.012 (3)	0.009 (3)
C6	0.036 (4)	0.031 (4)	0.029 (4)	0.001 (3)	0.014 (3)	0.010 (3)
C7	0.041 (4)	0.030 (4)	0.033 (4)	0.006 (3)	0.015 (3)	0.015 (3)
C8	0.028 (3)	0.039 (4)	0.026 (3)	0.011 (3)	0.008 (3)	0.010 (3)
C9	0.023 (3)	0.031 (3)	0.029 (4)	0.008 (3)	0.010 (3)	0.011 (3)
C10	0.027 (3)	0.037 (4)	0.040 (4)	0.012 (3)	0.009 (3)	0.023 (3)
C11	0.028 (3)	0.035 (4)	0.036 (4)	0.010 (3)	0.013 (3)	0.024 (3)
C12	0.030 (3)	0.038 (4)	0.031 (4)	0.004 (3)	0.016 (3)	0.010 (3)
C13	0.020 (3)	0.030 (3)	0.020 (3)	0.004 (3)	0.002 (3)	0.008 (3)
C14	0.029 (3)	0.032 (4)	0.029 (4)	0.001 (3)	0.011 (3)	0.011 (3)
C15	0.040 (4)	0.039 (4)	0.050 (5)	0.014 (3)	0.021 (4)	0.027 (4)
C16	0.027 (3)	0.036 (4)	0.039 (4)	0.016 (3)	0.017 (3)	0.021 (3)
C17	0.033 (4)	0.040 (4)	0.046 (4)	0.003 (3)	0.017 (4)	0.021 (4)
C18	0.033 (4)	0.041 (4)	0.043 (4)	0.008 (3)	0.016 (3)	0.019 (4)
O1W	0.047 (3)	0.049 (4)	0.054 (4)	0.025 (3)	0.016 (3)	0.032 (3)

Geometric parameters (Å, º) top

Ag1—N4	2.131 (4)	N8—C9	1.340 (7)
Ag1—N1	2.140 (4)	N8—H8B	0.9000
Ag2—N10	2.136 (4)	N8—H8C	0.9000
Ag2—N7	2.144 (5)	N9—C10	1.322 (7)
S1—O1	1.434 (4)	N9—C9	1.340 (7)
S1—O2	1.435 (4)	N10—C14	1.350 (7)
S1—O3	1.451 (5)	N10—C13	1.367 (7)
S1—C17	1.822 (6)	N11—C13	1.328 (7)
S2—O4	1.431 (5)	N11—H11B	0.9000
S2—O5	1.432 (4)	N11—H11C	0.9000
S2—O6	1.438 (4)	N12—C16	1.324 (7)
S2—C18	1.804 (7)	N12—C13	1.346 (7)
F1—C17	1.306 (7)	C2—C3	1.388 (8)
F2—C17	1.318 (7)	C2—H2A	0.9600
F3—C17	1.316 (8)	C3—C4	1.380 (8)
F4—C18	1.332 (7)	C3—H3A	0.9600
F5—C18	1.329 (7)	C4—H4A	0.9600
F6—C18	1.332 (7)	C6—C7	1.389 (8)
N1—C4	1.347 (8)	C6—H6A	0.9601
N1—C1	1.349 (7)	C7—C8	1.369 (8)
N2—C1	1.330 (7)	C7—H7A	0.9601
N2—H2B	0.9000	C8—H8A	0.9600
N2—H2C	0.9000	C10—C11	1.388 (8)
N3—C2	1.320 (8)	C10—H10A	0.9600
N3—C1	1.352 (7)	C11—C12	1.371 (8)
N4—C8	1.357 (7)	C11—H11A	0.9599
N4—C5	1.359 (7)	C12—H12A	0.9600
N5—C5	1.357 (7)	C14—C15	1.347 (8)
N5—H5A	0.8999	C14—H14A	0.9600
N5—H5B	0.9000	C15—C16	1.398 (8)
N6—C6	1.319 (8)	C15—H15A	0.9600
N6—C5	1.354 (7)	C16—H16A	0.9602
N7—C12	1.341 (7)	O1W—H1WA	0.71 (9)
N7—C9	1.364 (7)	O1W—H1WB	0.88 (10)

N4—Ag1—N1	173.68 (18)	N1—C4—H4A	119.1
N10—Ag2—N7	177.83 (18)	C3—C4—H4A	119.0
O1—S1—O2	114.4 (3)	N6—C5—N5	115.5 (5)
O1—S1—O3	114.9 (3)	N6—C5—N4	124.7 (5)
O2—S1—O3	115.0 (3)	N5—C5—N4	119.7 (5)
O1—S1—C17	103.0 (3)	N6—C6—C7	124.3 (6)
O2—S1—C17	103.8 (3)	N6—C6—H6A	117.7
O3—S1—C17	103.5 (3)	C7—C6—H6A	118.0
O4—S2—O5	114.8 (3)	C8—C7—C6	115.9 (6)
O4—S2—O6	114.3 (3)	C8—C7—H7A	122.1
O5—S2—O6	114.6 (3)	C6—C7—H7A	122.0
O4—S2—C18	102.7 (3)	N4—C8—C7	122.6 (6)
O5—S2—C18	104.1 (3)	N4—C8—H8A	118.8
O6—S2—C18	104.3 (3)	C7—C8—H8A	118.6
C4—N1—C1	117.5 (5)	N8—C9—N9	116.9 (5)
C4—N1—Ag1	117.4 (4)	N8—C9—N7	119.5 (5)
C1—N1—Ag1	125.0 (4)	N9—C9—N7	123.6 (5)
C1—N2—H2B	120.0	N9—C10—C11	122.6 (6)
C1—N2—H2C	120.0	N9—C10—H10A	118.6
H2B—N2—H2C	120.0	C11—C10—H10A	118.8
C2—N3—C1	118.1 (5)	C12—C11—C10	116.4 (5)
C8—N4—C5	116.4 (5)	C12—C11—H11A	121.7
C8—N4—Ag1	118.7 (4)	C10—C11—H11A	121.9
C5—N4—Ag1	124.9 (4)	N7—C12—C11	122.5 (5)
C5—N5—H5A	119.7	N7—C12—H12A	118.9
C5—N5—H5B	120.3	C11—C12—H12A	118.6
H5A—N5—H5B	120.0	N11—C13—N12	118.1 (5)
C6—N6—C5	116.1 (5)	N11—C13—N10	119.3 (5)
C12—N7—C9	116.9 (5)	N12—C13—N10	122.6 (5)
C12—N7—Ag2	119.2 (4)	C15—C14—N10	123.1 (6)
C9—N7—Ag2	123.8 (4)	C15—C14—H14A	118.4
C9—N8—H8B	120.1	N10—C14—H14A	118.5
C9—N8—H8C	119.9	C14—C15—C16	116.9 (6)
H8B—N8—H8C	120.0	C14—C15—H15A	121.5
C10—N9—C9	117.9 (5)	C16—C15—H15A	121.6
C14—N10—C13	116.9 (5)	N12—C16—C15	121.8 (6)
C14—N10—Ag2	117.6 (4)	N12—C16—H16A	118.9
C13—N10—Ag2	125.3 (4)	C15—C16—H16A	119.3
C13—N11—H11B	120.3	F1—C17—F3	108.3 (6)
C13—N11—H11C	119.7	F1—C17—F2	108.3 (6)
H11B—N11—H11C	120.0	F3—C17—F2	106.2 (6)
C16—N12—C13	118.7 (5)	F1—C17—S1	111.0 (5)
N2—C1—N1	119.2 (5)	F3—C17—S1	112.1 (5)
N2—C1—N3	117.5 (5)	F2—C17—S1	110.8 (5)
N1—C1—N3	123.3 (5)	F5—C18—F6	106.6 (5)
N3—C2—C3	122.4 (6)	F5—C18—F4	107.5 (5)
N3—C2—H2A	118.8	F6—C18—F4	107.7 (6)
C3—C2—H2A	118.8	F5—C18—S2	111.2 (5)
C4—C3—C2	116.7 (6)	F6—C18—S2	112.0 (4)
C4—C3—H3A	121.7	F4—C18—S2	111.6 (5)
C2—C3—H3A	121.7	H1WA—O1W—H1WB	117 (1)
N1—C4—C3	121.9 (6)

N4—Ag1—N1—C4	102.8 (17)	Ag2—N7—C9—N9	177.1 (4)
N4—Ag1—N1—C1	−73.9 (19)	C9—N9—C10—C11	0.5 (10)
N1—Ag1—N4—C8	91.2 (18)	N9—C10—C11—C12	−1.9 (10)
N1—Ag1—N4—C5	−91.7 (17)	C9—N7—C12—C11	1.2 (9)
N10—Ag2—N7—C12	−62 (5)	Ag2—N7—C12—C11	−178.7 (5)
N10—Ag2—N7—C9	118 (4)	C10—C11—C12—N7	1.0 (10)
N7—Ag2—N10—C14	−120 (4)	C16—N12—C13—N11	178.4 (5)
N7—Ag2—N10—C13	55 (5)	C16—N12—C13—N10	−2.6 (9)
C4—N1—C1—N2	176.6 (6)	C14—N10—C13—N11	−178.5 (5)
Ag1—N1—C1—N2	−6.7 (8)	Ag2—N10—C13—N11	6.5 (8)
C4—N1—C1—N3	−4.1 (9)	C14—N10—C13—N12	2.5 (8)
Ag1—N1—C1—N3	172.5 (4)	Ag2—N10—C13—N12	−172.5 (4)
C2—N3—C1—N2	−177.6 (6)	C13—N10—C14—C15	−1.2 (9)
C2—N3—C1—N1	3.2 (9)	Ag2—N10—C14—C15	174.1 (5)
C1—N3—C2—C3	−1.0 (9)	N10—C14—C15—C16	0.2 (10)
N3—C2—C3—C4	−0.1 (10)	C13—N12—C16—C15	1.4 (9)
C1—N1—C4—C3	3.0 (9)	C14—C15—C16—N12	−0.2 (10)
Ag1—N1—C4—C3	−173.9 (5)	O1—S1—C17—F1	−61.4 (6)
C2—C3—C4—N1	−1.0 (10)	O2—S1—C17—F1	179.1 (5)
C6—N6—C5—N5	−179.8 (5)	O3—S1—C17—F1	58.7 (6)
C6—N6—C5—N4	0.3 (9)	O1—S1—C17—F3	59.9 (5)
C8—N4—C5—N6	0.1 (9)	O2—S1—C17—F3	−59.7 (5)
Ag1—N4—C5—N6	−177.0 (4)	O3—S1—C17—F3	179.9 (5)
C8—N4—C5—N5	−179.8 (5)	O1—S1—C17—F2	178.3 (5)
Ag1—N4—C5—N5	3.1 (8)	O2—S1—C17—F2	58.8 (6)
C5—N6—C6—C7	−1.6 (9)	O3—S1—C17—F2	−61.6 (5)
N6—C6—C7—C8	2.2 (10)	O4—S2—C18—F5	62.9 (5)
C5—N4—C8—C7	0.6 (9)	O5—S2—C18—F5	−57.1 (5)
Ag1—N4—C8—C7	177.9 (5)	O6—S2—C18—F5	−177.6 (4)
C6—C7—C8—N4	−1.7 (9)	O4—S2—C18—F6	−56.3 (5)
C10—N9—C9—N8	−178.4 (6)	O5—S2—C18—F6	−176.3 (5)
C10—N9—C9—N7	1.9 (9)	O6—S2—C18—F6	63.3 (5)
C12—N7—C9—N8	177.5 (6)	O4—S2—C18—F4	−177.1 (5)
Ag2—N7—C9—N8	−2.5 (8)	O5—S2—C18—F4	62.9 (5)
C12—N7—C9—N9	−2.8 (9)	O6—S2—C18—F4	−57.6 (5)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2B···N6ⁱ	0.90	2.14	3.028 (7)	170
N2—H2C···O1W	0.90	2.19	2.999 (7)	149
N5—H5A···O3ⁱⁱ	0.90	2.24	3.042 (6)	148
N5—H5B···N3ⁱⁱⁱ	0.90	2.17	3.052 (7)	169
N8—H8B···O2	0.90	2.19	2.990 (6)	148
N8—H8C···N12ⁱⁱⁱ	0.90	2.15	3.040 (6)	172
N11—H11B···O6^iv	0.90	2.18	3.002 (6)	151
N11—H11C···N9ⁱ	0.90	2.10	3.003 (6)	178
O1W—H1WA···O4^v	0.71 (9)	2.17 (9)	2.817 (7)	151 (9)
O1W—H1WB···O1	0.88 (10)	1.96 (11)	2.839 (8)	173 (1)

Symmetry codes: (i) x+1, y, z; (ii) −x+1, −y+1, −z+1; (iii) x−1, y, z; (iv) −x+3, −y+2, −z+2; (v) −x+3, −y+1, −z+2.

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Bis(2-amino­pyrimidine)silver(I) tri­fluoro­methane­sulfonate hemihydrate

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Bis(2-aminopyrimidine)silver(I) trifluoromethanesulfonate hemihydrate