Crystal structure of bulky-ligand-protected Au₂₄(S-C₄H₉)₁₆

Atomically precise thiol­ate-protected gold nanomolecules have attracted inter­est due to their distinct electronic and chemical properties. The structure of these nanomolecules is important for understanding their peculiar properties. Here, we report the X-ray crystal structure of a 24-atom gold nanomolecule protected by 16 tert-butylthiolate ligands. The com­position of Au₂₄(S-C₄H₉)₁₆ {poly[hexa­deca­kis­(μ-tert-butyl­thiol­ato)tetra­cosa­gold]} was confirmed by X-ray crystallography and electrospray ionization mass spectrometry (ESI–MS). The nanomolecule was synthesized in a one-phase synthesis and crystallized from a hexa­ne–ethanol layered solution. The X-ray structure confirms the 16-atom core protected by two monomeric and two trimeric staples with four bridging ligands. The Au₂₄(S-C₄H₉)₁₆ cluster follows the shell-closing magic number of 8.

Computing details

Data collection: APEX3 (Bruker, 2019); cell refinement: SAINT (Bruker, 2019); data reduction: SAINT (Bruker, 2019); program(s) used to solve structure: SHELXT2018 (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2018 (Sheldrick, 2015b); molecular graphics: OLEX2 (Dolomanov et al., 2009) and CrystalMaker (Palmer, 2014); software used to prepare material for publication: OLEX2 (Dolomanov et al., 2009).

Poly[hexadecakis(µ-tert-butylthiolato)tetracosagold]

Crystal data

[Au24(C4H9S)16]	F(000) = 10720
Mr = 6153.94	Dx = 3.457 Mg m^−3
Monoclinic, Cc	Cu Kα radiation, λ = 1.54178 Å
a = 15.5946 (6) Å	Cell parameters from 9932 reflections
b = 25.9193 (6) Å	θ = 3.0–70.3°
c = 29.7621 (8) Å	µ = 57.21 mm^−1
β = 100.655 (2)°	T = 120 K
V = 11822.5 (6) Å^3	Blade, metallic dark brown
Z = 4	0.08 × 0.04 × 0.02 mm

Data collection

Bruker PHOTON-II CMOS diffractometer	19685 reflections with I > 2σ(I)
Detector resolution: 7.41 pixels mm^-1	Rint = 0.074
φ and ω scans	θmax = 70.5°, θmin = 3.0°
Absorption correction: multi-scan (SADABS2014; Bruker, 2014)	h = −18→18
Tmin = 0.362, Tmax = 0.753	k = −31→31
57304 measured reflections	l = −35→36
21231 independent reflections

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.049	w = 1/[σ^2(Fo^2) + (0.069P)^2] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.121	(Δ/σ)max = 0.010
S = 1.00	Δρmax = 3.09 e Å^−3
21231 reflections	Δρmin = −2.63 e Å^−3
986 parameters	Absolute structure: Refined as an inversion twin.
26 restraints	Absolute structure parameter: 0.42 (2)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refined as a 2-component inversion twin.

Throughout the data collection, the crystal was kept below 120 K. The structure was modeled in OLEX2 (Dolomanov et al., 2009) and solved by SHELXT using Intrinsic Phasing methods (Sheldrick, 2015a) and refined by full-matrix least-squares analysis (Sheldrick, 2015b). All the non-H atoms were refined using anisotropic displacement parameters.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Au1	0.48656 (7)	0.39408 (4)	0.48381 (3)	0.0270 (2)
Au2	0.63701 (7)	0.35358 (4)	0.54737 (3)	0.0300 (2)
Au3	0.68088 (7)	0.44516 (4)	0.51519 (3)	0.0288 (2)
Au4	0.34676 (7)	0.44264 (4)	0.51240 (3)	0.0295 (2)
Au5	0.62699 (7)	0.35197 (4)	0.44863 (3)	0.0303 (2)
Au6	0.46906 (7)	0.38877 (4)	0.57375 (3)	0.0316 (2)
Au7	0.51448 (7)	0.47869 (4)	0.53718 (4)	0.0322 (2)
Au8	0.48267 (7)	0.39670 (4)	0.39177 (3)	0.0317 (2)
Au9	0.33519 (7)	0.44164 (4)	0.41360 (3)	0.0306 (2)
Au10	0.44719 (7)	0.28862 (4)	0.52848 (4)	0.0324 (2)
Au11	0.15871 (7)	0.43636 (4)	0.43341 (4)	0.0337 (2)
Au12	0.30058 (7)	0.34698 (4)	0.44428 (4)	0.0309 (2)
Au13	0.46782 (7)	0.30463 (4)	0.43278 (4)	0.0335 (2)
Au14	0.52263 (7)	0.50266 (4)	0.43415 (4)	0.0317 (2)
Au15	0.69043 (7)	0.43254 (4)	0.60389 (3)	0.0328 (2)
Au16	0.31547 (8)	0.35753 (4)	0.35777 (4)	0.0337 (2)
Au17	0.64687 (7)	0.42724 (4)	0.37638 (3)	0.0334 (2)
Au18	0.86223 (8)	0.45830 (5)	0.58461 (4)	0.0366 (2)
Au19	0.13455 (8)	0.33778 (4)	0.36547 (4)	0.0366 (2)
Au20	0.69865 (8)	0.54454 (4)	0.57753 (4)	0.0370 (2)
Au21	0.82084 (8)	0.35953 (4)	0.52016 (4)	0.0361 (2)
Au22	0.47777 (8)	0.36298 (5)	0.30111 (4)	0.0395 (3)
Au23	0.57686 (8)	0.40599 (5)	0.66969 (4)	0.0388 (3)
Au24	0.28957 (8)	0.24427 (5)	0.37934 (5)	0.0435 (3)
S1	0.3792 (5)	0.5288 (2)	0.4256 (2)	0.0342 (13)
S2	0.1957 (4)	0.4502 (3)	0.5108 (2)	0.0337 (13)
S3	0.3025 (4)	0.3149 (3)	0.5186 (2)	0.0332 (13)
S4	0.6675 (4)	0.4812 (2)	0.43970 (19)	0.0296 (12)
S5	0.5930 (5)	0.2664 (2)	0.5378 (2)	0.0353 (13)
S6	0.6244 (5)	0.3809 (3)	0.3095 (2)	0.0402 (15)
S7	0.1151 (5)	0.4257 (3)	0.3548 (2)	0.0362 (13)
S8	0.4457 (5)	0.3652 (3)	0.6473 (2)	0.0372 (14)
S9	0.1404 (5)	0.2500 (3)	0.3750 (3)	0.0412 (15)
S10	0.8450 (5)	0.5459 (3)	0.5722 (3)	0.0397 (14)
S11	0.5559 (5)	0.5487 (3)	0.5874 (2)	0.0376 (14)
S12	0.7770 (5)	0.3453 (3)	0.4425 (2)	0.0355 (13)
S13	0.3348 (5)	0.3370 (3)	0.2827 (2)	0.0421 (15)
S14	0.8808 (4)	0.3707 (3)	0.5965 (2)	0.0374 (14)
S15	0.4377 (5)	0.2355 (3)	0.3803 (3)	0.0443 (16)
S16	0.7079 (5)	0.4483 (3)	0.6838 (2)	0.0434 (16)
C1	0.714 (2)	0.5830 (11)	0.4569 (11)	0.043 (7)
H1A	0.652242	0.590500	0.446595	0.064*
H1B	0.749033	0.612851	0.450662	0.064*
H1C	0.725665	0.575910	0.489769	0.064*
C2	0.740 (2)	0.5351 (10)	0.4308 (9)	0.035 (6)
C3	0.380 (2)	0.4677 (15)	0.6534 (15)	0.063 (11)
H3A	0.329150	0.487604	0.657552	0.095*
H3B	0.389933	0.471823	0.621935	0.095*
H3C	0.431850	0.480110	0.674713	0.095*
C4	0.196 (2)	0.5293 (12)	0.5694 (9)	0.039 (6)
H4A	0.187557	0.565961	0.575526	0.059*
H4B	0.258010	0.520716	0.577603	0.059*
H4C	0.162853	0.508362	0.587737	0.059*
C5	0.534 (3)	0.6254 (15)	0.5204 (17)	0.073 (12)
H5A	0.597285	0.630157	0.524461	0.110*
H5B	0.504484	0.657485	0.509040	0.110*
H5C	0.515870	0.597609	0.498401	0.110*
C6	0.784 (2)	0.4059 (12)	0.7190 (9)	0.043 (7)
C7	0.8309 (19)	0.5198 (10)	0.4464 (10)	0.036 (6)
H7A	0.837394	0.504480	0.476945	0.054*
H7B	0.868696	0.550103	0.447530	0.054*
H7C	0.847415	0.494352	0.425125	0.054*
C8	0.7320 (19)	0.2423 (14)	0.6059 (12)	0.048 (8)
H8A	0.761273	0.214509	0.592254	0.072*
H8B	0.751724	0.242233	0.639122	0.072*
H8C	0.746257	0.275537	0.593402	0.072*
C9	0.630 (2)	0.2336 (11)	0.5944 (11)	0.043 (7)
C10	0.885 (3)	0.6359 (13)	0.6168 (13)	0.055 (9)
H10A	0.916744	0.648639	0.593640	0.083*
H10B	0.902982	0.655062	0.645314	0.083*
H10C	0.821940	0.640760	0.605925	0.083*
C11	0.511 (2)	0.6119 (14)	0.5644 (16)	0.057 (9)
C12	0.545 (3)	0.6507 (12)	0.5982 (13)	0.065 (11)
H12A	0.515308	0.647983	0.624378	0.097*
H12B	0.535219	0.685065	0.584554	0.097*
H12C	0.607721	0.645063	0.608425	0.097*
C13	0.196 (3)	0.5536 (12)	0.4877 (12)	0.052 (9)
H13A	0.176293	0.541931	0.456136	0.078*
H13B	0.260008	0.554160	0.494571	0.078*
H13C	0.173670	0.588400	0.491263	0.078*
C14	−0.005 (2)	0.4378 (13)	0.3394 (13)	0.051 (8)
C15	1.005 (2)	0.2978 (15)	0.5985 (17)	0.065 (11)
H15A	0.986871	0.281014	0.624790	0.098*
H15B	1.064308	0.286975	0.596595	0.098*
H15C	0.964963	0.287773	0.570424	0.098*
C16	1.0024 (18)	0.3563 (13)	0.6043 (10)	0.042 (7)
C17	0.311 (3)	0.384 (2)	0.1982 (12)	0.077 (14)
H17A	0.285440	0.412804	0.178961	0.115*
H17B	0.293684	0.351319	0.182224	0.115*
H17C	0.374271	0.386865	0.204555	0.115*
C18	0.239 (2)	0.2521 (10)	0.5739 (11)	0.041 (7)
H18A	0.200378	0.276606	0.585297	0.062*
H18B	0.299659	0.258941	0.588513	0.062*
H18C	0.223296	0.216829	0.581040	0.062*
C19	0.758 (3)	0.406 (2)	0.7669 (12)	0.073 (13)
H19A	0.785615	0.435855	0.784485	0.110*
H19B	0.778077	0.374278	0.783114	0.110*
H19C	0.694696	0.408960	0.763397	0.110*
C20	0.164 (2)	0.5183 (12)	0.5190 (11)	0.044 (7)
C21	0.381 (3)	0.6205 (15)	0.3829 (16)	0.067 (9)
H21A	0.379130	0.640433	0.354743	0.101*
H21B	0.440507	0.621763	0.401038	0.101*
H21C	0.340174	0.635108	0.400642	0.101*
C22	0.779 (2)	0.2413 (13)	0.4660 (10)	0.047 (8)
H22A	0.808647	0.251069	0.496710	0.071*
H22B	0.795829	0.206135	0.459186	0.071*
H22C	0.715582	0.242710	0.464419	0.071*
C23	0.368 (2)	0.4057 (19)	0.7162 (12)	0.065 (12)
H23A	0.338334	0.435791	0.726356	0.098*
H23B	0.428385	0.404684	0.732407	0.098*
H23C	0.337618	0.374168	0.722965	0.098*
C24	0.3654 (16)	0.4094 (13)	0.6629 (11)	0.041 (7)
C25	0.095 (3)	0.1610 (14)	0.323 (2)	0.080 (15)
H25A	0.050749	0.144011	0.300429	0.120*
H25B	0.088274	0.150219	0.353951	0.120*
H25C	0.153342	0.151176	0.318208	0.120*
C26	0.125 (3)	0.2370 (15)	0.2815 (14)	0.071 (12)
H26A	0.185094	0.223494	0.285331	0.107*
H26B	0.127176	0.274815	0.281761	0.107*
H26C	0.091672	0.225031	0.252296	0.107*
C27	0.879 (2)	0.4254 (18)	0.7218 (12)	0.060 (10)
H27A	0.896244	0.420735	0.692162	0.091*
H27B	0.917869	0.405874	0.745245	0.091*
H27C	0.881467	0.462128	0.729895	0.091*
C28	0.138 (2)	0.2740 (12)	0.5031 (13)	0.048 (8)
H28A	0.136421	0.283870	0.471090	0.072*
H28B	0.120872	0.303524	0.519925	0.072*
H28C	0.098206	0.245223	0.504418	0.072*
C29	0.278 (3)	0.3848 (17)	0.2415 (11)	0.061 (10)
C30	0.611 (2)	0.1772 (16)	0.5875 (15)	0.068 (12)
H30A	0.547450	0.171867	0.580201	0.102*
H30B	0.635080	0.158359	0.615462	0.102*
H30C	0.637199	0.164483	0.562173	0.102*
C31	0.603 (2)	0.3993 (19)	0.2164 (11)	0.063 (11)
H31A	0.643766	0.370466	0.215607	0.094*
H31B	0.605932	0.422637	0.190789	0.094*
H31C	0.543893	0.385964	0.213945	0.094*
C32	0.291 (3)	0.4407 (12)	0.2617 (14)	0.062 (10)
H32A	0.299081	0.464765	0.237456	0.093*
H32B	0.342291	0.441388	0.286158	0.093*
H32C	0.239171	0.450770	0.273972	0.093*
C34	0.578 (2)	0.4773 (15)	0.2654 (14)	0.058 (9)
H34A	0.516609	0.472013	0.250825	0.087*
H34B	0.602310	0.505769	0.250209	0.087*
H34C	0.580862	0.485624	0.297745	0.087*
C33	0.776 (2)	0.3492 (12)	0.7015 (13)	0.051 (8)
H33A	0.714499	0.339642	0.693765	0.076*
H33B	0.806222	0.326201	0.725529	0.076*
H33C	0.802976	0.346079	0.674334	0.076*
C35	0.588 (3)	0.2577 (19)	0.6311 (13)	0.073 (13)
H35A	0.591898	0.295363	0.629423	0.109*
H35B	0.617660	0.245855	0.661181	0.109*
H35C	0.526106	0.247581	0.626497	0.109*
C36	0.725 (2)	0.4417 (15)	0.2671 (12)	0.056 (10)
H36A	0.747539	0.451508	0.298940	0.084*
H36B	0.733295	0.470466	0.246915	0.084*
H36C	0.757787	0.411552	0.259280	0.084*
C37	0.085 (3)	0.2187 (14)	0.3189 (17)	0.066 (11)
C38	−0.015 (3)	0.4978 (14)	0.3480 (13)	0.060 (9)
H38A	0.020208	0.507277	0.377569	0.090*
H38B	−0.076736	0.505727	0.348241	0.090*
H38C	0.004146	0.517369	0.323614	0.090*
C39	0.475 (2)	0.1748 (15)	0.4064 (15)	0.059 (9)
C40	0.804 (2)	0.2775 (11)	0.4321 (10)	0.039 (6)
C41	0.276 (3)	0.3928 (17)	0.6382 (12)	0.062 (10)
H41A	0.266434	0.356543	0.645303	0.093*
H41B	0.272602	0.396638	0.605134	0.093*
H41C	0.231391	0.414269	0.648100	0.093*
C42	0.995 (3)	0.5676 (18)	0.6288 (17)	0.077 (14)
H42A	1.004088	0.530243	0.628248	0.115*
H42B	1.027415	0.581758	0.657605	0.115*
H42C	1.016420	0.583566	0.603091	0.115*
C43	0.577 (3)	0.1744 (17)	0.417 (2)	0.087 (15)
H43A	0.599467	0.160970	0.390961	0.130*
H43B	0.597446	0.152444	0.444011	0.130*
H43C	0.598773	0.209665	0.423952	0.130*
C44	0.759 (3)	0.2640 (14)	0.3864 (12)	0.056 (9)
H44A	0.799314	0.245118	0.370598	0.084*
H44B	0.739679	0.295527	0.369414	0.084*
H44C	0.708709	0.242258	0.388434	0.084*
C45	0.260 (3)	0.2103 (12)	0.5022 (14)	0.056 (9)
H45A	0.218567	0.182172	0.503381	0.084*
H45B	0.317901	0.200093	0.518600	0.084*
H45C	0.262986	0.217869	0.470245	0.084*
C46	0.066 (2)	0.5194 (13)	0.5101 (10)	0.045 (7)
H46A	0.043687	0.485495	0.517146	0.067*
H46B	0.044091	0.527666	0.477911	0.067*
H46C	0.045777	0.545624	0.529513	0.067*
C47	0.905 (3)	0.2756 (16)	0.4347 (16)	0.068 (11)
H47A	0.934541	0.280591	0.466479	0.102*
H47B	0.922511	0.302988	0.415590	0.102*
H47C	0.921475	0.241989	0.423791	0.102*
C48	0.444 (3)	0.1320 (11)	0.3708 (14)	0.057 (9)
H48A	0.398233	0.145426	0.346806	0.085*
H48B	0.421878	0.102610	0.385876	0.085*
H48C	0.493878	0.120685	0.357230	0.085*
C49	0.872 (3)	0.5599 (17)	0.6666 (10)	0.063 (11)
H49A	0.808662	0.555178	0.659234	0.094*
H49B	0.886456	0.585390	0.691149	0.094*
H49C	0.900068	0.526959	0.676569	0.094*
C50	1.041 (3)	0.3817 (14)	0.5685 (14)	0.058 (9)
H50A	1.020701	0.364517	0.539179	0.086*
H50B	1.104735	0.379547	0.576431	0.086*
H50C	1.023193	0.418025	0.566219	0.086*
C51	0.629 (2)	0.4284 (12)	0.2612 (10)	0.042 (7)
C52	−0.0273 (19)	0.4280 (16)	0.2880 (11)	0.053 (9)
H52A	−0.036491	0.461077	0.271850	0.080*
H52B	−0.080492	0.407209	0.280896	0.080*
H52C	0.021031	0.409557	0.278317	0.080*
C53	0.230 (2)	0.2578 (11)	0.5243 (10)	0.039 (7)
C54	1.040 (3)	0.3729 (19)	0.6536 (10)	0.070 (13)
H54A	1.005805	0.401969	0.662054	0.105*
H54B	1.100783	0.383476	0.655766	0.105*
H54C	1.036652	0.343965	0.674387	0.105*
C55	−0.006 (2)	0.232 (2)	0.3154 (18)	0.083 (15)
H55A	−0.038802	0.219054	0.286434	0.124*
H55B	−0.011478	0.269555	0.316631	0.124*
H55C	−0.028116	0.216340	0.340905	0.124*
C56	−0.055 (2)	0.4076 (17)	0.3673 (13)	0.061 (11)
H56A	−0.030950	0.372618	0.371494	0.091*
H56B	−0.116282	0.405736	0.351886	0.091*
H56C	−0.051580	0.424103	0.397210	0.091*
C57	0.904 (3)	0.5784 (16)	0.6252 (15)	0.061 (9)
C58	0.188 (3)	0.368 (2)	0.2337 (13)	0.080 (15)
H58A	0.176246	0.349845	0.260825	0.120*
H58B	0.177057	0.344609	0.207328	0.120*
H58C	0.149321	0.398003	0.227555	0.120*
C59	0.253 (2)	0.5625 (18)	0.3556 (15)	0.069 (10)
H59A	0.224689	0.584227	0.375668	0.104*
H59B	0.233935	0.526668	0.357700	0.104*
H59C	0.235942	0.574555	0.323968	0.104*
C60	0.437 (2)	0.1631 (14)	0.4508 (12)	0.053 (8)
H60A	0.470807	0.181888	0.476697	0.080*
H60B	0.440553	0.125971	0.457117	0.080*
H60C	0.375774	0.174110	0.446262	0.080*
C61	0.357 (2)	0.5661 (13)	0.3712 (12)	0.049 (5)
C62	0.404 (3)	0.6057 (19)	0.559 (2)	0.084 (15)
H62A	0.381628	0.584341	0.532422	0.127*
H62B	0.376642	0.639816	0.555405	0.127*
H62C	0.390539	0.589194	0.586693	0.127*
C63	0.395 (3)	0.5435 (19)	0.3357 (16)	0.075 (10)
H63A	0.404626	0.570212	0.313825	0.113*
H63B	0.356292	0.516918	0.319995	0.113*
H63C	0.451573	0.527803	0.349079	0.113*
C64	0.722 (2)	0.5497 (10)	0.3794 (8)	0.035 (6)
H64A	0.738792	0.521009	0.361478	0.052*
H64B	0.755350	0.580499	0.374680	0.052*
H64C	0.659314	0.556733	0.369539	0.052*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Au1	0.0311 (5)	0.0270 (4)	0.0217 (4)	0.0039 (4)	0.0015 (4)	−0.0005 (3)
Au2	0.0347 (5)	0.0296 (5)	0.0240 (5)	0.0029 (4)	0.0010 (4)	0.0029 (4)
Au3	0.0345 (5)	0.0285 (5)	0.0230 (5)	0.0024 (4)	0.0039 (4)	0.0018 (4)
Au4	0.0314 (5)	0.0309 (5)	0.0250 (5)	0.0050 (4)	0.0022 (4)	0.0015 (4)
Au5	0.0329 (5)	0.0321 (5)	0.0251 (5)	0.0045 (4)	0.0028 (4)	0.0018 (4)
Au6	0.0385 (6)	0.0322 (5)	0.0229 (5)	0.0043 (4)	0.0023 (4)	0.0017 (4)
Au7	0.0358 (6)	0.0300 (5)	0.0301 (5)	0.0004 (4)	0.0044 (4)	−0.0043 (4)
Au8	0.0348 (5)	0.0367 (5)	0.0219 (5)	0.0041 (4)	0.0007 (4)	0.0012 (4)
Au9	0.0341 (5)	0.0295 (5)	0.0268 (5)	0.0030 (4)	0.0023 (4)	0.0020 (4)
Au10	0.0368 (6)	0.0289 (5)	0.0305 (5)	0.0006 (4)	0.0033 (4)	0.0016 (4)
Au11	0.0341 (6)	0.0344 (5)	0.0308 (5)	0.0032 (5)	0.0012 (4)	−0.0016 (4)
Au12	0.0344 (5)	0.0295 (5)	0.0278 (5)	0.0033 (4)	0.0028 (4)	0.0020 (4)
Au13	0.0378 (6)	0.0284 (5)	0.0328 (5)	0.0015 (4)	0.0027 (4)	−0.0041 (4)
Au14	0.0353 (5)	0.0312 (5)	0.0277 (5)	0.0008 (4)	0.0033 (4)	0.0015 (4)
Au15	0.0385 (6)	0.0374 (5)	0.0220 (5)	0.0009 (5)	0.0045 (4)	−0.0008 (4)
Au16	0.0359 (6)	0.0381 (5)	0.0250 (5)	0.0010 (5)	−0.0001 (4)	−0.0027 (4)
Au17	0.0383 (6)	0.0384 (5)	0.0227 (5)	0.0014 (5)	0.0034 (4)	0.0014 (4)
Au18	0.0374 (6)	0.0379 (6)	0.0340 (5)	0.0032 (5)	0.0049 (4)	−0.0020 (4)
Au19	0.0367 (6)	0.0329 (5)	0.0383 (6)	0.0039 (5)	0.0024 (5)	−0.0030 (4)
Au20	0.0393 (6)	0.0333 (5)	0.0365 (6)	0.0024 (5)	0.0019 (5)	−0.0034 (4)
Au21	0.0357 (6)	0.0350 (5)	0.0368 (6)	0.0032 (5)	0.0044 (5)	−0.0006 (4)
Au22	0.0468 (7)	0.0455 (6)	0.0257 (5)	−0.0027 (5)	0.0053 (5)	−0.0039 (4)
Au23	0.0383 (6)	0.0512 (7)	0.0256 (5)	0.0034 (5)	0.0022 (4)	0.0005 (4)
Au24	0.0420 (7)	0.0353 (6)	0.0484 (7)	0.0069 (5)	−0.0044 (5)	−0.0066 (5)
S1	0.039 (3)	0.029 (3)	0.035 (3)	0.007 (3)	0.007 (3)	0.005 (2)
S2	0.032 (3)	0.037 (3)	0.032 (3)	0.003 (3)	0.004 (2)	−0.003 (2)
S3	0.035 (3)	0.035 (3)	0.029 (3)	−0.003 (3)	0.005 (2)	0.003 (2)
S4	0.035 (3)	0.030 (3)	0.023 (3)	0.000 (3)	0.003 (2)	0.003 (2)
S5	0.038 (3)	0.031 (3)	0.036 (3)	0.001 (3)	0.004 (3)	−0.002 (2)
S6	0.045 (4)	0.047 (4)	0.027 (3)	0.006 (3)	0.005 (3)	−0.001 (3)
S7	0.039 (3)	0.034 (3)	0.033 (3)	0.000 (3)	0.000 (3)	−0.001 (2)
S8	0.042 (4)	0.046 (4)	0.024 (3)	0.006 (3)	0.007 (3)	0.005 (2)
S9	0.040 (4)	0.036 (3)	0.046 (4)	0.000 (3)	0.005 (3)	−0.001 (3)
S10	0.038 (4)	0.038 (3)	0.041 (4)	0.003 (3)	0.001 (3)	−0.001 (3)
S11	0.045 (4)	0.032 (3)	0.036 (3)	0.000 (3)	0.007 (3)	−0.005 (2)
S12	0.036 (3)	0.034 (3)	0.036 (3)	0.005 (3)	0.006 (3)	−0.001 (2)
S13	0.052 (4)	0.051 (4)	0.023 (3)	−0.004 (3)	0.005 (3)	−0.007 (3)
S14	0.032 (3)	0.043 (3)	0.035 (3)	0.000 (3)	0.001 (3)	0.000 (3)
S15	0.047 (4)	0.043 (4)	0.040 (4)	0.002 (3)	−0.002 (3)	−0.009 (3)
S16	0.051 (4)	0.057 (4)	0.021 (3)	0.002 (3)	0.003 (3)	−0.005 (3)
C1	0.054 (18)	0.031 (13)	0.042 (15)	−0.002 (13)	0.003 (13)	−0.018 (11)
C2	0.044 (15)	0.028 (12)	0.033 (13)	−0.012 (12)	0.010 (11)	−0.008 (10)
C3	0.05 (2)	0.06 (2)	0.07 (3)	0.005 (17)	−0.006 (18)	−0.034 (19)
C4	0.050 (17)	0.043 (15)	0.025 (13)	−0.002 (13)	0.008 (12)	−0.013 (11)
C5	0.08 (3)	0.037 (17)	0.11 (4)	0.020 (19)	0.03 (3)	−0.002 (19)
C6	0.044 (16)	0.050 (17)	0.023 (13)	0.001 (13)	−0.022 (11)	0.001 (11)
C7	0.044 (15)	0.021 (11)	0.044 (14)	0.005 (11)	0.008 (12)	−0.006 (10)
C8	0.030 (15)	0.06 (2)	0.053 (18)	0.004 (14)	0.010 (13)	0.013 (15)
C9	0.047 (17)	0.028 (13)	0.048 (16)	0.018 (13)	−0.007 (13)	0.001 (11)
C10	0.06 (2)	0.041 (17)	0.05 (2)	−0.009 (16)	−0.015 (16)	−0.006 (14)
C11	0.029 (15)	0.047 (19)	0.09 (3)	0.022 (14)	0.009 (16)	0.012 (18)
C12	0.11 (3)	0.029 (15)	0.05 (2)	0.023 (19)	0.00 (2)	−0.014 (14)
C13	0.08 (2)	0.039 (16)	0.048 (18)	0.021 (16)	0.032 (17)	0.028 (14)
C14	0.051 (19)	0.046 (18)	0.052 (19)	0.012 (15)	0.000 (15)	−0.006 (14)
C15	0.041 (19)	0.05 (2)	0.10 (3)	0.015 (16)	−0.008 (19)	0.011 (19)
C16	0.027 (13)	0.06 (2)	0.031 (15)	0.009 (13)	−0.005 (11)	−0.008 (12)
C17	0.08 (3)	0.12 (4)	0.024 (16)	−0.04 (3)	0.005 (17)	−0.007 (18)
C18	0.056 (18)	0.021 (12)	0.050 (17)	−0.002 (12)	0.019 (14)	0.003 (11)
C19	0.05 (2)	0.14 (4)	0.032 (17)	0.00 (2)	0.002 (15)	−0.01 (2)
C20	0.047 (17)	0.041 (16)	0.041 (16)	0.022 (14)	0.000 (13)	−0.008 (12)
C21	0.07 (2)	0.048 (17)	0.08 (2)	0.004 (16)	0.012 (17)	0.026 (15)
C22	0.053 (18)	0.056 (19)	0.031 (14)	0.020 (16)	0.002 (13)	−0.012 (12)
C23	0.049 (19)	0.12 (3)	0.038 (17)	0.04 (2)	0.025 (15)	0.014 (18)
C24	0.011 (11)	0.062 (19)	0.050 (17)	0.011 (12)	0.008 (10)	−0.023 (14)
C25	0.10 (3)	0.033 (18)	0.12 (4)	−0.01 (2)	0.06 (3)	−0.02 (2)
C26	0.10 (3)	0.05 (2)	0.05 (2)	−0.02 (2)	−0.02 (2)	0.003 (16)
C27	0.048 (19)	0.10 (3)	0.039 (17)	−0.002 (19)	0.010 (14)	−0.011 (17)
C28	0.034 (15)	0.038 (15)	0.08 (2)	−0.001 (13)	0.028 (15)	0.013 (15)
C29	0.07 (2)	0.08 (3)	0.024 (15)	−0.01 (2)	−0.011 (15)	−0.002 (14)
C30	0.06 (2)	0.07 (2)	0.08 (3)	0.027 (19)	0.012 (19)	0.06 (2)
C31	0.049 (19)	0.11 (3)	0.024 (15)	0.00 (2)	−0.012 (13)	−0.001 (16)
C32	0.08 (3)	0.033 (16)	0.07 (2)	0.024 (17)	0.01 (2)	0.027 (15)
C34	0.048 (19)	0.06 (2)	0.06 (2)	−0.003 (17)	−0.007 (16)	0.003 (16)
C33	0.048 (18)	0.037 (16)	0.07 (2)	−0.006 (14)	0.010 (16)	−0.003 (14)
C35	0.07 (3)	0.11 (3)	0.05 (2)	0.02 (2)	0.05 (2)	0.04 (2)
C36	0.05 (2)	0.08 (2)	0.042 (17)	−0.009 (18)	0.018 (15)	0.039 (16)
C37	0.07 (2)	0.035 (17)	0.10 (3)	0.015 (17)	0.03 (2)	−0.022 (18)
C38	0.08 (3)	0.045 (19)	0.06 (2)	0.009 (18)	0.001 (18)	0.003 (15)
C39	0.039 (17)	0.06 (2)	0.08 (3)	0.014 (16)	−0.003 (17)	−0.009 (18)
C40	0.052 (17)	0.025 (12)	0.040 (15)	0.006 (13)	0.008 (13)	−0.013 (10)
C41	0.07 (2)	0.08 (3)	0.033 (17)	−0.01 (2)	0.008 (16)	0.010 (16)
C42	0.05 (2)	0.07 (3)	0.09 (3)	−0.014 (19)	−0.04 (2)	0.00 (2)
C43	0.09 (3)	0.05 (2)	0.11 (4)	0.03 (2)	0.00 (3)	0.01 (2)
C44	0.07 (2)	0.048 (18)	0.047 (18)	0.011 (18)	0.009 (17)	0.002 (14)
C45	0.06 (2)	0.029 (15)	0.07 (2)	0.001 (15)	0.009 (19)	−0.008 (15)
C46	0.042 (16)	0.054 (18)	0.036 (14)	0.029 (15)	0.003 (12)	−0.006 (12)
C47	0.06 (2)	0.06 (2)	0.09 (3)	0.04 (2)	0.02 (2)	0.02 (2)
C48	0.08 (3)	0.021 (13)	0.08 (2)	−0.014 (15)	0.03 (2)	−0.019 (14)
C49	0.07 (2)	0.09 (3)	0.018 (13)	−0.03 (2)	−0.007 (14)	0.007 (14)
C50	0.06 (2)	0.050 (19)	0.06 (2)	0.008 (18)	0.030 (19)	0.002 (16)
C51	0.049 (17)	0.041 (15)	0.038 (15)	0.002 (14)	0.013 (13)	−0.020 (12)
C52	0.023 (13)	0.09 (3)	0.047 (17)	0.032 (16)	0.000 (12)	−0.023 (16)
C53	0.050 (17)	0.041 (15)	0.034 (14)	−0.016 (13)	0.029 (13)	−0.023 (11)
C54	0.07 (2)	0.11 (3)	0.018 (14)	0.04 (2)	−0.010 (14)	−0.014 (16)
C55	0.037 (19)	0.11 (4)	0.09 (3)	−0.01 (2)	−0.01 (2)	−0.03 (3)
C56	0.031 (15)	0.09 (3)	0.06 (2)	0.030 (18)	0.025 (15)	0.03 (2)
C57	0.06 (2)	0.06 (2)	0.07 (2)	0.020 (18)	0.004 (18)	−0.003 (17)
C58	0.05 (2)	0.16 (5)	0.034 (18)	−0.02 (3)	−0.001 (15)	0.00 (2)
C59	0.050 (17)	0.08 (2)	0.066 (19)	0.005 (16)	−0.019 (15)	0.039 (16)
C60	0.06 (2)	0.048 (18)	0.044 (18)	0.011 (16)	−0.005 (15)	−0.009 (14)
C61	0.050 (10)	0.042 (10)	0.052 (10)	0.015 (9)	0.000 (9)	0.014 (9)
C62	0.09 (3)	0.07 (3)	0.10 (4)	0.02 (3)	0.04 (3)	0.01 (3)
C63	0.08 (2)	0.07 (2)	0.064 (19)	0.011 (19)	−0.002 (18)	0.013 (17)
C64	0.059 (18)	0.036 (13)	0.011 (10)	−0.002 (13)	0.012 (11)	0.008 (9)

Geometric parameters (Å, º)

Au1—Au2	2.9230 (15)	C13—H13A	0.9800
Au1—Au3	3.2804 (15)	C13—H13B	0.9800
Au1—Au4	2.7834 (15)	C13—H13C	0.9800
Au1—Au5	2.8164 (15)	C13—C20	1.46 (4)
Au1—Au6	2.7438 (14)	C14—C38	1.59 (5)
Au1—Au7	2.6957 (15)	C14—C52	1.53 (5)
Au1—Au8	2.7297 (14)	C14—C56	1.47 (5)
Au1—Au9	3.1040 (14)	C15—H15A	0.9800
Au1—Au10	3.1493 (15)	C15—H15B	0.9800
Au1—Au12	3.1661 (15)	C15—H15C	0.9800
Au1—Au13	2.7575 (15)	C15—C16	1.53 (5)
Au1—Au14	3.2756 (15)	C16—C50	1.47 (5)
Au2—Au3	2.6947 (15)	C16—C54	1.54 (4)
Au2—Au5	2.9143 (14)	C17—H17A	0.9800
Au2—Au6	3.0114 (16)	C17—H17B	0.9800
Au2—Au10	3.3614 (16)	C17—H17C	0.9800
Au2—Au15	2.6822 (15)	C17—C29	1.47 (5)
Au2—Au21	3.1235 (17)	C18—H18A	0.9800
Au2—S5	2.363 (7)	C18—H18B	0.9800
Au3—Au5	3.1383 (15)	C18—H18C	0.9800
Au3—Au7	2.9233 (15)	C18—C53	1.46 (4)
Au3—Au15	2.6370 (14)	C19—H19A	0.9800
Au3—Au18	3.1972 (16)	C19—H19B	0.9800
Au3—Au20	3.1567 (15)	C19—H19C	0.9800
Au3—Au21	3.0971 (15)	C20—C46	1.50 (4)
Au3—S4	2.406 (6)	C21—H21A	0.9800
Au4—Au6	2.7630 (15)	C21—H21B	0.9800
Au4—Au7	2.7468 (16)	C21—H21C	0.9800
Au4—Au9	2.9127 (14)	C21—C61	1.48 (5)
Au4—Au12	3.1995 (15)	C22—H22A	0.9800
Au4—S2	2.356 (7)	C22—H22B	0.9800
Au5—Au8	2.8044 (15)	C22—H22C	0.9800
Au5—Au13	2.7308 (16)	C22—C40	1.48 (5)
Au5—Au17	2.9618 (15)	C23—H23A	0.9800
Au5—Au21	3.3659 (16)	C23—H23B	0.9800
Au5—S12	2.386 (7)	C23—H23C	0.9800
Au6—Au7	2.7208 (15)	C23—C24	1.59 (4)
Au6—Au10	2.9155 (15)	C24—C41	1.51 (5)
Au6—Au23	3.0665 (15)	C25—H25A	0.9800
Au6—S8	2.364 (6)	C25—H25B	0.9800
Au7—Au14	3.1545 (15)	C25—H25C	0.9800
Au7—Au15	3.2995 (16)	C25—C37	1.51 (5)
Au7—Au20	3.3657 (16)	C26—H26A	0.9800
Au7—S11	2.364 (7)	C26—H26B	0.9800
Au8—Au9	2.7606 (16)	C26—H26C	0.9800
Au8—Au13	2.7098 (16)	C26—C37	1.46 (6)
Au8—Au14	3.0384 (15)	C27—H27A	0.9800
Au8—Au16	2.8068 (16)	C27—H27B	0.9800
Au8—Au17	2.7976 (16)	C27—H27C	0.9800
Au8—Au22	2.8238 (15)	C28—H28A	0.9800
Au9—Au11	2.9225 (16)	C28—H28B	0.9800
Au9—Au12	2.7068 (15)	C28—H28C	0.9800
Au9—Au14	3.2801 (16)	C28—C53	1.51 (5)
Au9—Au16	2.7238 (15)	C29—C32	1.57 (5)
Au9—S1	2.370 (7)	C29—C58	1.45 (5)
Au10—Au13	2.9542 (15)	C30—H30A	0.9800
Au10—S3	2.323 (7)	C30—H30B	0.9800
Au10—S5	2.313 (7)	C30—H30C	0.9800
Au11—Au12	3.1782 (15)	C31—H31A	0.9800
Au11—Au19	3.2369 (15)	C31—H31B	0.9800
Au11—S2	2.296 (7)	C31—H31C	0.9800
Au11—S7	2.329 (7)	C31—C51	1.52 (4)
Au12—Au13	2.9076 (16)	C32—H32A	0.9800
Au12—Au16	2.6419 (15)	C32—H32B	0.9800
Au12—Au19	3.1648 (15)	C32—H32C	0.9800
Au12—Au24	3.2757 (16)	C34—H34A	0.9800
Au12—S3	2.358 (6)	C34—H34B	0.9800
Au13—Au16	3.2476 (15)	C34—H34C	0.9800
Au13—Au24	3.3269 (17)	C34—C51	1.52 (5)
Au13—S15	2.367 (7)	C33—H33A	0.9800
Au14—S1	2.306 (7)	C33—H33B	0.9800
Au14—S4	2.304 (7)	C33—H33C	0.9800
Au15—Au18	2.9192 (17)	C35—H35A	0.9800
Au15—Au20	3.0159 (16)	C35—H35B	0.9800
Au15—Au23	2.9543 (16)	C35—H35C	0.9800
Au15—S16	2.378 (7)	C36—H36A	0.9800
Au16—Au19	2.9179 (17)	C36—H36B	0.9800
Au16—Au22	3.2936 (17)	C36—H36C	0.9800
Au16—Au24	3.0477 (17)	C36—C51	1.52 (5)
Au16—S13	2.370 (7)	C37—C55	1.43 (6)
Au17—S4	2.321 (6)	C38—H38A	0.9800
Au17—S6	2.296 (7)	C38—H38B	0.9800
Au18—Au20	3.3688 (16)	C38—H38C	0.9800
Au18—Au21	3.1926 (16)	C39—C43	1.57 (6)
Au18—S10	2.307 (7)	C39—C48	1.55 (5)
Au18—S14	2.307 (7)	C39—C60	1.57 (6)
Au19—S7	2.314 (7)	C40—C44	1.45 (5)
Au19—S9	2.294 (7)	C40—C47	1.57 (5)
Au20—S10	2.318 (8)	C41—H41A	0.9800
Au20—S11	2.301 (8)	C41—H41B	0.9800
Au21—S12	2.316 (7)	C41—H41C	0.9800
Au21—S14	2.309 (7)	C42—H42A	0.9800
Au22—S6	2.302 (8)	C42—H42B	0.9800
Au22—S13	2.297 (8)	C42—H42C	0.9800
Au23—S8	2.289 (8)	C42—C57	1.43 (6)
Au23—S16	2.289 (8)	C43—H43A	0.9800
Au24—S9	2.310 (8)	C43—H43B	0.9800
Au24—S15	2.317 (8)	C43—H43C	0.9800
S1—C61	1.86 (3)	C44—H44A	0.9800
S2—C20	1.86 (3)	C44—H44B	0.9800
S3—C53	1.89 (3)	C44—H44C	0.9800
S4—C2	1.85 (3)	C45—H45A	0.9800
S5—C9	1.88 (3)	C45—H45B	0.9800
S6—C51	1.91 (3)	C45—H45C	0.9800
S7—C14	1.87 (4)	C45—C53	1.51 (4)
S8—C24	1.82 (3)	C46—H46A	0.9800
S9—C37	1.91 (5)	C46—H46B	0.9800
S10—C57	1.87 (4)	C46—H46C	0.9800
S11—C11	1.86 (3)	C47—H47A	0.9800
S12—C40	1.85 (3)	C47—H47B	0.9800
S13—C29	1.85 (4)	C47—H47C	0.9800
S14—C16	1.90 (3)	C48—H48A	0.9800
S15—C39	1.80 (4)	C48—H48B	0.9800
S16—C6	1.81 (3)	C48—H48C	0.9800
C1—H1A	0.9800	C49—H49A	0.9800
C1—H1B	0.9800	C49—H49B	0.9800
C1—H1C	0.9800	C49—H49C	0.9800
C1—C2	1.56 (4)	C49—C57	1.49 (6)
C2—C7	1.46 (4)	C50—H50A	0.9800
C2—C64	1.55 (3)	C50—H50B	0.9800
C3—H3A	0.9800	C50—H50C	0.9800
C3—H3B	0.9800	C52—H52A	0.9800
C3—H3C	0.9800	C52—H52B	0.9800
C3—C24	1.56 (5)	C52—H52C	0.9800
C4—H4A	0.9800	C54—H54A	0.9800
C4—H4B	0.9800	C54—H54B	0.9800
C4—H4C	0.9800	C54—H54C	0.9800
C4—C20	1.52 (4)	C55—H55A	0.9800
C5—H5A	0.9800	C55—H55B	0.9800
C5—H5B	0.9800	C55—H55C	0.9800
C5—H5C	0.9800	C56—H56A	0.9800
C5—C11	1.46 (6)	C56—H56B	0.9800
C6—C19	1.55 (5)	C56—H56C	0.9800
C6—C27	1.54 (5)	C58—H58A	0.9800
C6—C33	1.55 (4)	C58—H58B	0.9800
C7—H7A	0.9800	C58—H58C	0.9800
C7—H7B	0.9800	C59—H59A	0.9800
C7—H7C	0.9800	C59—H59B	0.9800
C8—H8A	0.9800	C59—H59C	0.9800
C8—H8B	0.9800	C59—C61	1.61 (5)
C8—H8C	0.9800	C60—H60A	0.9800
C8—C9	1.58 (4)	C60—H60B	0.9800
C9—C30	1.50 (5)	C60—H60C	0.9800
C9—C35	1.51 (5)	C61—C63	1.43 (6)
C10—H10A	0.9800	C62—H62A	0.9800
C10—H10B	0.9800	C62—H62B	0.9800
C10—H10C	0.9800	C62—H62C	0.9800
C10—C57	1.53 (5)	C63—H63A	0.9800
C11—C12	1.45 (5)	C63—H63B	0.9800
C11—C62	1.65 (6)	C63—H63C	0.9800
C12—H12A	0.9800	C64—H64A	0.9800
C12—H12B	0.9800	C64—H64B	0.9800
C12—H12C	0.9800	C64—H64C	0.9800
Au2—Au1—Au3	51.10 (3)	S11—Au20—Au18	139.68 (18)
Au2—Au1—Au9	176.23 (5)	S11—Au20—S10	175.1 (3)
Au2—Au1—Au10	67.10 (4)	Au2—Au21—Au5	53.21 (3)
Au2—Au1—Au12	132.27 (5)	Au2—Au21—Au18	88.69 (4)
Au2—Au1—Au14	114.60 (4)	Au3—Au21—Au2	51.34 (3)
Au4—Au1—Au2	123.02 (4)	Au3—Au21—Au5	57.92 (3)
Au4—Au1—Au3	117.71 (4)	Au3—Au21—Au18	61.08 (4)
Au4—Au1—Au5	174.73 (5)	Au18—Au21—Au5	119.01 (4)
Au4—Au1—Au9	59.00 (3)	S12—Au21—Au2	97.77 (18)
Au4—Au1—Au10	92.22 (4)	S12—Au21—Au3	89.49 (17)
Au4—Au1—Au12	64.69 (4)	S12—Au21—Au5	45.12 (18)
Au4—Au1—Au14	87.65 (4)	S12—Au21—Au18	135.82 (18)
Au5—Au1—Au2	61.00 (4)	S14—Au21—Au2	88.59 (18)
Au5—Au1—Au3	61.40 (4)	S14—Au21—Au3	96.35 (18)
Au5—Au1—Au9	116.77 (4)	S14—Au21—Au5	141.49 (18)
Au5—Au1—Au10	92.65 (4)	S14—Au21—Au18	46.21 (18)
Au5—Au1—Au12	115.74 (4)	S14—Au21—S12	173.2 (3)
Au5—Au1—Au14	87.42 (4)	Au8—Au22—Au16	53.96 (4)
Au6—Au1—Au2	64.11 (4)	S6—Au22—Au8	89.02 (17)
Au6—Au1—Au3	89.76 (4)	S6—Au22—Au16	142.68 (17)
Au6—Au1—Au4	59.98 (4)	S13—Au22—Au8	99.93 (17)
Au6—Au1—Au5	124.59 (5)	S13—Au22—Au16	46.02 (16)
Au6—Au1—Au9	118.44 (5)	S13—Au22—S6	170.6 (2)
Au6—Au1—Au10	58.82 (4)	Au15—Au23—Au6	73.10 (4)
Au6—Au1—Au12	95.38 (4)	S8—Au23—Au6	49.83 (16)
Au6—Au1—Au13	118.40 (5)	S8—Au23—Au15	121.81 (16)
Au6—Au1—Au14	122.66 (4)	S16—Au23—Au6	123.87 (17)
Au7—Au1—Au2	83.56 (4)	S16—Au23—Au15	52.07 (17)
Au7—Au1—Au3	57.58 (4)	S16—Au23—S8	173.7 (2)
Au7—Au1—Au4	60.15 (4)	Au12—Au24—Au13	52.25 (3)
Au7—Au1—Au5	118.84 (5)	Au16—Au24—Au12	49.23 (3)
Au7—Au1—Au6	60.02 (4)	Au16—Au24—Au13	61.07 (4)
Au7—Au1—Au8	122.84 (5)	S9—Au24—Au12	85.63 (19)
Au7—Au1—Au9	95.37 (4)	S9—Au24—Au13	137.77 (19)
Au7—Au1—Au10	118.70 (4)	S9—Au24—Au16	95.62 (19)
Au7—Au1—Au12	124.73 (5)	S9—Au24—S15	176.8 (3)
Au7—Au1—Au13	176.15 (6)	S15—Au24—Au12	97.45 (18)
Au7—Au1—Au14	62.90 (4)	S15—Au24—Au13	45.36 (18)
Au8—Au1—Au2	121.64 (5)	S15—Au24—Au16	85.8 (2)
Au8—Au1—Au3	97.10 (4)	Au14—S1—Au9	89.1 (2)
Au8—Au1—Au4	114.97 (5)	C61—S1—Au9	111.2 (12)
Au8—Au1—Au5	60.73 (4)	C61—S1—Au14	105.5 (12)
Au8—Au1—Au6	172.99 (6)	Au11—S2—Au4	94.1 (2)
Au8—Au1—Au9	56.04 (4)	C20—S2—Au4	111.5 (11)
Au8—Au1—Au10	118.38 (5)	C20—S2—Au11	104.8 (10)
Au8—Au1—Au12	77.75 (4)	Au10—S3—Au12	93.8 (2)
Au8—Au1—Au13	59.18 (4)	C53—S3—Au10	110.0 (11)
Au8—Au1—Au14	59.97 (4)	C53—S3—Au12	117.1 (9)
Au9—Au1—Au3	125.37 (4)	Au14—S4—Au3	94.3 (2)
Au9—Au1—Au10	116.46 (4)	Au14—S4—Au17	95.8 (2)
Au9—Au1—Au12	51.14 (3)	Au17—S4—Au3	120.0 (3)
Au9—Au1—Au14	61.81 (3)	C2—S4—Au3	118.6 (9)
Au10—Au1—Au3	118.17 (4)	C2—S4—Au14	115.1 (10)
Au10—Au1—Au12	65.51 (3)	C2—S4—Au17	109.6 (9)
Au10—Au1—Au14	178.00 (5)	Au10—S5—Au2	91.9 (2)
Au12—Au1—Au3	174.81 (4)	C9—S5—Au2	107.0 (10)
Au12—Au1—Au14	112.68 (4)	C9—S5—Au10	110.5 (11)
Au13—Au1—Au2	92.59 (4)	Au17—S6—Au22	100.9 (3)
Au13—Au1—Au3	119.63 (5)	C51—S6—Au17	107.1 (9)
Au13—Au1—Au4	122.64 (5)	C51—S6—Au22	102.9 (11)
Au13—Au1—Au5	58.66 (4)	Au19—S7—Au11	88.4 (2)
Au13—Au1—Au9	88.46 (4)	C14—S7—Au11	108.6 (12)
Au13—Au1—Au10	59.58 (4)	C14—S7—Au19	107.3 (12)
Au13—Au1—Au12	58.31 (4)	Au23—S8—Au6	82.4 (2)
Au13—Au1—Au14	118.91 (4)	C24—S8—Au6	107.7 (12)
Au14—Au1—Au3	63.58 (3)	C24—S8—Au23	104.7 (10)
Au1—Au2—Au6	55.05 (3)	Au19—S9—Au24	95.0 (3)
Au1—Au2—Au10	59.66 (3)	C37—S9—Au19	108.1 (13)
Au1—Au2—Au21	118.68 (4)	C37—S9—Au24	108.3 (12)
Au3—Au2—Au1	71.33 (4)	Au18—S10—Au20	93.5 (3)
Au3—Au2—Au5	67.91 (4)	C57—S10—Au18	106.5 (13)
Au3—Au2—Au6	96.67 (4)	C57—S10—Au20	106.6 (13)
Au3—Au2—Au10	130.95 (5)	Au20—S11—Au7	92.3 (2)
Au3—Au2—Au21	63.82 (4)	C11—S11—Au7	113.7 (14)
Au5—Au2—Au1	57.70 (3)	C11—S11—Au20	107.7 (11)
Au5—Au2—Au6	112.35 (4)	Au21—S12—Au5	91.4 (2)
Au5—Au2—Au10	86.72 (4)	C40—S12—Au5	109.7 (11)
Au5—Au2—Au21	67.66 (4)	C40—S12—Au21	106.6 (10)
Au6—Au2—Au10	54.11 (3)	Au22—S13—Au16	89.8 (2)
Au6—Au2—Au21	159.52 (5)	C29—S13—Au16	110.2 (13)
Au15—Au2—Au1	104.53 (5)	C29—S13—Au22	106.7 (13)
Au15—Au2—Au3	58.74 (4)	Au18—S14—Au21	87.5 (2)
Au15—Au2—Au5	126.58 (5)	C16—S14—Au18	107.8 (11)
Au15—Au2—Au6	77.85 (4)	C16—S14—Au21	108.0 (9)
Au15—Au2—Au10	130.46 (5)	Au24—S15—Au13	90.5 (3)
Au15—Au2—Au21	86.07 (4)	C39—S15—Au13	111.5 (13)
Au21—Au2—Au10	143.46 (5)	C39—S15—Au24	109.2 (13)
S5—Au2—Au1	94.89 (17)	Au23—S16—Au15	78.5 (2)
S5—Au2—Au3	152.45 (17)	C6—S16—Au15	114.6 (11)
S5—Au2—Au5	84.54 (17)	C6—S16—Au23	106.6 (11)
S5—Au2—Au6	94.24 (18)	H1A—C1—H1B	109.5
S5—Au2—Au10	43.44 (17)	H1A—C1—H1C	109.5
S5—Au2—Au15	148.71 (17)	H1B—C1—H1C	109.5
S5—Au2—Au21	106.02 (18)	C2—C1—H1A	109.5
Au2—Au3—Au1	57.58 (4)	C2—C1—H1B	109.5
Au2—Au3—Au5	59.37 (3)	C2—C1—H1C	109.5
Au2—Au3—Au7	83.57 (4)	C1—C2—S4	108 (2)
Au2—Au3—Au18	96.69 (4)	C7—C2—S4	109 (2)
Au2—Au3—Au20	120.68 (5)	C7—C2—C1	113 (2)
Au2—Au3—Au21	64.84 (4)	C7—C2—C64	112 (2)
Au5—Au3—Au1	51.99 (3)	C64—C2—S4	108.6 (19)
Au5—Au3—Au18	126.27 (4)	C64—C2—C1	106 (2)
Au5—Au3—Au20	169.49 (5)	H3A—C3—H3B	109.5
Au7—Au3—Au1	51.11 (3)	H3A—C3—H3C	109.5
Au7—Au3—Au5	103.01 (4)	H3B—C3—H3C	109.5
Au7—Au3—Au18	122.64 (4)	C24—C3—H3A	109.5
Au7—Au3—Au20	67.10 (4)	C24—C3—H3B	109.5
Au7—Au3—Au21	148.13 (5)	C24—C3—H3C	109.5
Au15—Au3—Au1	96.50 (4)	H4A—C4—H4B	109.5
Au15—Au3—Au2	60.39 (4)	H4A—C4—H4C	109.5
Au15—Au3—Au5	119.70 (5)	H4B—C4—H4C	109.5
Au15—Au3—Au7	72.59 (4)	C20—C4—H4A	109.5
Au15—Au3—Au18	59.12 (4)	C20—C4—H4B	109.5
Au15—Au3—Au20	61.97 (4)	C20—C4—H4C	109.5
Au15—Au3—Au21	87.39 (4)	H5A—C5—H5B	109.5
Au18—Au3—Au1	152.52 (4)	H5A—C5—H5C	109.5
Au20—Au3—Au1	118.21 (4)	H5B—C5—H5C	109.5
Au20—Au3—Au18	64.03 (4)	C11—C5—H5A	109.5
Au21—Au3—Au1	109.28 (4)	C11—C5—H5B	109.5
Au21—Au3—Au5	65.34 (4)	C11—C5—H5C	109.5
Au21—Au3—Au18	60.93 (4)	C19—C6—S16	106 (3)
Au21—Au3—Au20	124.90 (5)	C27—C6—S16	111 (3)
S4—Au3—Au1	88.56 (16)	C27—C6—C19	111 (3)
S4—Au3—Au2	133.61 (15)	C27—C6—C33	110 (3)
S4—Au3—Au5	75.07 (15)	C33—C6—S16	112 (2)
S4—Au3—Au7	99.60 (16)	C33—C6—C19	107 (3)
S4—Au3—Au15	164.17 (15)	C2—C7—H7A	109.5
S4—Au3—Au18	118.39 (16)	C2—C7—H7B	109.5
S4—Au3—Au20	102.44 (15)	C2—C7—H7C	109.5
S4—Au3—Au21	105.13 (16)	H7A—C7—H7B	109.5
Au1—Au4—Au9	65.99 (4)	H7A—C7—H7C	109.5
Au1—Au4—Au12	63.46 (4)	H7B—C7—H7C	109.5
Au6—Au4—Au1	59.30 (4)	H8A—C8—H8B	109.5
Au6—Au4—Au9	124.68 (5)	H8A—C8—H8C	109.5
Au6—Au4—Au12	94.25 (4)	H8B—C8—H8C	109.5
Au7—Au4—Au1	58.34 (4)	C9—C8—H8A	109.5
Au7—Au4—Au6	59.18 (4)	C9—C8—H8B	109.5
Au7—Au4—Au9	98.76 (5)	C9—C8—H8C	109.5
Au7—Au4—Au12	121.69 (5)	C8—C9—S5	105 (2)
Au9—Au4—Au12	52.32 (3)	C30—C9—S5	107 (2)
S2—Au4—Au1	150.25 (17)	C30—C9—C8	110 (3)
S2—Au4—Au6	128.39 (17)	C30—C9—C35	114 (3)
S2—Au4—Au7	151.21 (17)	C35—C9—S5	111 (2)
S2—Au4—Au9	96.04 (16)	C35—C9—C8	110 (3)
S2—Au4—Au12	86.80 (16)	H10A—C10—H10B	109.5
Au1—Au5—Au2	61.31 (4)	H10A—C10—H10C	109.5
Au1—Au5—Au3	66.60 (4)	H10B—C10—H10C	109.5
Au1—Au5—Au17	101.98 (4)	C57—C10—H10A	109.5
Au1—Au5—Au21	114.29 (4)	C57—C10—H10B	109.5
Au2—Au5—Au3	52.72 (3)	C57—C10—H10C	109.5
Au2—Au5—Au17	136.83 (5)	C5—C11—S11	113 (3)
Au2—Au5—Au21	59.13 (3)	C5—C11—C62	111 (4)
Au3—Au5—Au21	56.74 (3)	C12—C11—S11	107 (3)
Au8—Au5—Au1	58.11 (4)	C12—C11—C5	109 (4)
Au8—Au5—Au2	119.34 (5)	C12—C11—C62	112 (4)
Au8—Au5—Au3	98.86 (4)	C62—C11—S11	105 (3)
Au8—Au5—Au17	57.97 (4)	C11—C12—H12A	109.5
Au8—Au5—Au21	152.16 (5)	C11—C12—H12B	109.5
Au13—Au5—Au1	59.59 (4)	C11—C12—H12C	109.5
Au13—Au5—Au2	93.33 (4)	H12A—C12—H12B	109.5
Au13—Au5—Au3	125.71 (5)	H12A—C12—H12C	109.5
Au13—Au5—Au8	58.61 (4)	H12B—C12—H12C	109.5
Au13—Au5—Au17	112.61 (5)	H13A—C13—H13B	109.5
Au13—Au5—Au21	144.77 (5)	H13A—C13—H13C	109.5
Au17—Au5—Au3	84.24 (4)	H13B—C13—H13C	109.5
Au17—Au5—Au21	102.62 (4)	C20—C13—H13A	109.5
S12—Au5—Au1	153.80 (17)	C20—C13—H13B	109.5
S12—Au5—Au2	101.99 (17)	C20—C13—H13C	109.5
S12—Au5—Au3	87.26 (17)	C38—C14—S7	104 (3)
S12—Au5—Au8	132.26 (17)	C52—C14—S7	104 (2)
S12—Au5—Au13	145.78 (17)	C52—C14—C38	108 (3)
S12—Au5—Au17	75.91 (17)	C56—C14—S7	113 (2)
S12—Au5—Au21	43.46 (17)	C56—C14—C38	111 (3)
Au1—Au6—Au2	60.83 (4)	C56—C14—C52	116 (3)
Au1—Au6—Au4	60.72 (4)	H15A—C15—H15B	109.5
Au1—Au6—Au10	67.55 (4)	H15A—C15—H15C	109.5
Au1—Au6—Au23	139.89 (5)	H15B—C15—H15C	109.5
Au2—Au6—Au23	86.18 (4)	C16—C15—H15A	109.5
Au4—Au6—Au2	120.54 (5)	C16—C15—H15B	109.5
Au4—Au6—Au10	97.88 (4)	C16—C15—H15C	109.5
Au4—Au6—Au23	137.26 (5)	C15—C16—S14	103 (2)
Au7—Au6—Au1	59.11 (4)	C15—C16—C54	112 (3)
Au7—Au6—Au2	81.48 (4)	C50—C16—S14	111 (2)
Au7—Au6—Au4	60.11 (4)	C50—C16—C15	110 (3)
Au7—Au6—Au10	126.49 (5)	C50—C16—C54	116 (3)
Au7—Au6—Au23	96.28 (5)	C54—C16—S14	105 (2)
Au10—Au6—Au2	69.08 (4)	H17A—C17—H17B	109.5
Au10—Au6—Au23	123.85 (5)	H17A—C17—H17C	109.5
S8—Au6—Au1	167.43 (19)	H17B—C17—H17C	109.5
S8—Au6—Au2	116.94 (18)	C29—C17—H17A	109.5
S8—Au6—Au4	122.47 (18)	C29—C17—H17B	109.5
S8—Au6—Au7	133.45 (18)	C29—C17—H17C	109.5
S8—Au6—Au10	99.94 (18)	H18A—C18—H18B	109.5
S8—Au6—Au23	47.74 (18)	H18A—C18—H18C	109.5
Au1—Au7—Au3	71.31 (4)	H18B—C18—H18C	109.5
Au1—Au7—Au4	61.51 (4)	C53—C18—H18A	109.5
Au1—Au7—Au6	60.87 (4)	C53—C18—H18B	109.5
Au1—Au7—Au14	67.58 (4)	C53—C18—H18C	109.5
Au1—Au7—Au15	94.90 (4)	C6—C19—H19A	109.5
Au1—Au7—Au20	131.07 (5)	C6—C19—H19B	109.5
Au3—Au7—Au14	69.14 (4)	C6—C19—H19C	109.5
Au3—Au7—Au15	49.69 (3)	H19A—C19—H19B	109.5
Au3—Au7—Au20	59.77 (4)	H19A—C19—H19C	109.5
Au4—Au7—Au3	132.79 (5)	H19B—C19—H19C	109.5
Au4—Au7—Au14	90.77 (4)	C4—C20—S2	105 (2)
Au4—Au7—Au15	133.07 (5)	C13—C20—S2	112 (2)
Au4—Au7—Au20	167.33 (5)	C13—C20—C4	115 (3)
Au6—Au7—Au3	98.19 (5)	C13—C20—C46	110 (3)
Au6—Au7—Au4	60.70 (4)	C46—C20—S2	106 (2)
Au6—Au7—Au14	128.16 (5)	C46—C20—C4	108 (3)
Au6—Au7—Au15	72.41 (4)	H21A—C21—H21B	109.5
Au6—Au7—Au20	124.04 (5)	H21A—C21—H21C	109.5
Au14—Au7—Au15	118.55 (4)	H21B—C21—H21C	109.5
Au14—Au7—Au20	93.55 (4)	C61—C21—H21A	109.5
Au15—Au7—Au20	53.80 (3)	C61—C21—H21B	109.5
S11—Au7—Au1	173.06 (19)	C61—C21—H21C	109.5
S11—Au7—Au3	102.70 (19)	H22A—C22—H22B	109.5
S11—Au7—Au4	124.48 (19)	H22A—C22—H22C	109.5
S11—Au7—Au6	117.75 (18)	H22B—C22—H22C	109.5
S11—Au7—Au14	114.09 (18)	C40—C22—H22A	109.5
S11—Au7—Au15	78.36 (18)	C40—C22—H22B	109.5
S11—Au7—Au20	43.10 (19)	C40—C22—H22C	109.5
Au1—Au8—Au5	61.17 (4)	H23A—C23—H23B	109.5
Au1—Au8—Au9	68.85 (4)	H23A—C23—H23C	109.5
Au1—Au8—Au14	68.97 (4)	H23B—C23—H23C	109.5
Au1—Au8—Au16	101.51 (5)	C24—C23—H23A	109.5
Au1—Au8—Au17	108.68 (5)	C24—C23—H23B	109.5
Au1—Au8—Au22	160.54 (6)	C24—C23—H23C	109.5
Au5—Au8—Au14	92.47 (4)	C3—C24—S8	115 (2)
Au5—Au8—Au16	131.03 (5)	C3—C24—C23	105 (3)
Au5—Au8—Au22	109.00 (5)	C23—C24—S8	109 (2)
Au9—Au8—Au5	130.02 (5)	C41—C24—S8	108 (2)
Au9—Au8—Au14	68.70 (4)	C41—C24—C3	110 (3)
Au9—Au8—Au16	58.58 (4)	C41—C24—C23	108 (3)
Au9—Au8—Au17	138.31 (5)	H25A—C25—H25B	109.5
Au9—Au8—Au22	118.61 (5)	H25A—C25—H25C	109.5
Au13—Au8—Au1	60.92 (4)	H25B—C25—H25C	109.5
Au13—Au8—Au5	59.34 (4)	C37—C25—H25A	109.5
Au13—Au8—Au9	96.96 (5)	C37—C25—H25B	109.5
Au13—Au8—Au14	129.58 (5)	C37—C25—H25C	109.5
Au13—Au8—Au16	72.11 (4)	H26A—C26—H26B	109.5
Au13—Au8—Au17	118.68 (5)	H26A—C26—H26C	109.5
Au13—Au8—Au22	99.69 (5)	H26B—C26—H26C	109.5
Au16—Au8—Au14	125.61 (5)	C37—C26—H26A	109.5
Au16—Au8—Au22	71.60 (4)	C37—C26—H26B	109.5
Au17—Au8—Au5	63.84 (4)	C37—C26—H26C	109.5
Au17—Au8—Au14	71.85 (4)	C6—C27—H27A	109.5
Au17—Au8—Au16	149.39 (5)	C6—C27—H27B	109.5
Au17—Au8—Au22	78.17 (4)	C6—C27—H27C	109.5
Au22—Au8—Au14	130.07 (5)	H27A—C27—H27B	109.5
Au1—Au9—Au14	61.67 (3)	H27A—C27—H27C	109.5
Au4—Au9—Au1	55.00 (3)	H27B—C27—H27C	109.5
Au4—Au9—Au11	71.43 (4)	H28A—C28—H28B	109.5
Au4—Au9—Au14	85.45 (4)	H28A—C28—H28C	109.5
Au8—Au9—Au1	55.10 (3)	H28B—C28—H28C	109.5
Au8—Au9—Au4	110.03 (5)	C53—C28—H28A	109.5
Au8—Au9—Au11	152.17 (5)	C53—C28—H28B	109.5
Au8—Au9—Au14	59.66 (4)	C53—C28—H28C	109.5
Au11—Au9—Au1	118.22 (4)	C17—C29—S13	112 (3)
Au11—Au9—Au14	145.58 (5)	C17—C29—C32	108 (4)
Au12—Au9—Au1	65.62 (4)	C32—C29—S13	111 (2)
Au12—Au9—Au4	69.30 (4)	C58—C29—S13	104 (3)
Au12—Au9—Au8	85.63 (4)	C58—C29—C17	110 (3)
Au12—Au9—Au11	68.62 (4)	C58—C29—C32	113 (4)
Au12—Au9—Au14	126.91 (5)	C9—C30—H30A	109.5
Au12—Au9—Au16	58.22 (4)	C9—C30—H30B	109.5
Au16—Au9—Au1	94.53 (4)	C9—C30—H30C	109.5
Au16—Au9—Au4	127.01 (5)	H30A—C30—H30B	109.5
Au16—Au9—Au8	61.56 (4)	H30A—C30—H30C	109.5
Au16—Au9—Au11	94.67 (5)	H30B—C30—H30C	109.5
Au16—Au9—Au14	119.73 (5)	H31A—C31—H31B	109.5
S1—Au9—Au1	96.57 (17)	H31A—C31—H31C	109.5
S1—Au9—Au4	82.96 (16)	H31B—C31—H31C	109.5
S1—Au9—Au8	101.94 (17)	C51—C31—H31A	109.5
S1—Au9—Au11	105.77 (17)	C51—C31—H31B	109.5
S1—Au9—Au12	152.13 (17)	C51—C31—H31C	109.5
S1—Au9—Au14	44.65 (17)	C29—C32—H32A	109.5
S1—Au9—Au16	148.43 (17)	C29—C32—H32B	109.5
Au1—Au10—Au2	53.23 (3)	C29—C32—H32C	109.5
Au6—Au10—Au1	53.63 (3)	H32A—C32—H32B	109.5
Au6—Au10—Au2	56.81 (3)	H32A—C32—H32C	109.5
Au6—Au10—Au13	107.23 (4)	H32B—C32—H32C	109.5
Au13—Au10—Au1	53.60 (3)	H34A—C34—H34B	109.5
Au13—Au10—Au2	80.87 (4)	H34A—C34—H34C	109.5
S3—Au10—Au1	87.28 (16)	H34B—C34—H34C	109.5
S3—Au10—Au2	132.76 (17)	C51—C34—H34A	109.5
S3—Au10—Au6	79.92 (17)	C51—C34—H34B	109.5
S3—Au10—Au13	96.51 (16)	C51—C34—H34C	109.5
S5—Au10—Au1	90.16 (17)	C6—C33—H33A	109.5
S5—Au10—Au2	44.64 (16)	C6—C33—H33B	109.5
S5—Au10—Au6	97.92 (17)	C6—C33—H33C	109.5
S5—Au10—Au13	82.58 (17)	H33A—C33—H33B	109.5
S5—Au10—S3	177.3 (2)	H33A—C33—H33C	109.5
Au9—Au11—Au12	52.47 (3)	H33B—C33—H33C	109.5
Au9—Au11—Au19	85.19 (4)	C9—C35—H35A	109.5
Au12—Au11—Au19	59.11 (3)	C9—C35—H35B	109.5
S2—Au11—Au9	97.12 (18)	C9—C35—H35C	109.5
S2—Au11—Au12	88.32 (17)	H35A—C35—H35B	109.5
S2—Au11—Au19	136.74 (17)	H35A—C35—H35C	109.5
S2—Au11—S7	176.8 (2)	H35B—C35—H35C	109.5
S7—Au11—Au9	85.05 (19)	H36A—C36—H36B	109.5
S7—Au11—Au12	94.85 (18)	H36A—C36—H36C	109.5
S7—Au11—Au19	45.62 (17)	H36B—C36—H36C	109.5
Au1—Au12—Au4	51.85 (3)	C51—C36—H36A	109.5
Au1—Au12—Au11	109.23 (4)	C51—C36—H36B	109.5
Au1—Au12—Au24	118.49 (4)	C51—C36—H36C	109.5
Au4—Au12—Au24	170.00 (5)	C25—C37—S9	109 (4)
Au9—Au12—Au1	63.24 (4)	C26—C37—S9	110 (3)
Au9—Au12—Au4	58.38 (3)	C26—C37—C25	109 (3)
Au9—Au12—Au11	58.90 (4)	C55—C37—S9	104 (3)
Au9—Au12—Au13	93.63 (5)	C55—C37—C25	110 (4)
Au9—Au12—Au19	90.29 (4)	C55—C37—C26	115 (5)
Au9—Au12—Au24	121.97 (5)	C14—C38—H38A	109.5
Au11—Au12—Au4	64.56 (3)	C14—C38—H38B	109.5
Au11—Au12—Au24	124.95 (4)	C14—C38—H38C	109.5
Au13—Au12—Au1	53.80 (3)	H38A—C38—H38B	109.5
Au13—Au12—Au4	105.40 (4)	H38A—C38—H38C	109.5
Au13—Au12—Au11	152.36 (5)	H38B—C38—H38C	109.5
Au13—Au12—Au19	120.86 (5)	C43—C39—S15	109 (3)
Au13—Au12—Au24	64.78 (4)	C48—C39—S15	107 (3)
Au16—Au12—Au1	94.75 (4)	C48—C39—C43	108 (3)
Au16—Au12—Au4	119.16 (5)	C48—C39—C60	109 (3)
Au16—Au12—Au9	61.21 (4)	C60—C39—S15	113 (2)
Au16—Au12—Au11	90.60 (4)	C60—C39—C43	110 (4)
Au16—Au12—Au13	71.45 (4)	C22—C40—S12	113 (2)
Au16—Au12—Au19	59.52 (4)	C22—C40—C47	110 (3)
Au16—Au12—Au24	60.89 (4)	C44—C40—S12	108 (2)
Au19—Au12—Au1	150.71 (5)	C44—C40—C22	110 (3)
Au19—Au12—Au4	125.83 (4)	C44—C40—C47	110 (3)
Au19—Au12—Au11	61.37 (3)	C47—C40—S12	106 (2)
Au19—Au12—Au24	63.58 (4)	C24—C41—H41A	109.5
S3—Au12—Au1	86.29 (17)	C24—C41—H41B	109.5
S3—Au12—Au4	73.52 (17)	C24—C41—H41C	109.5
S3—Au12—Au9	131.85 (17)	H41A—C41—H41B	109.5
S3—Au12—Au11	103.91 (17)	H41A—C41—H41C	109.5
S3—Au12—Au13	96.96 (17)	H41B—C41—H41C	109.5
S3—Au12—Au16	164.28 (17)	H42A—C42—H42B	109.5
S3—Au12—Au19	122.38 (17)	H42A—C42—H42C	109.5
S3—Au12—Au24	104.91 (17)	H42B—C42—H42C	109.5
Au1—Au13—Au10	66.82 (4)	C57—C42—H42A	109.5
Au1—Au13—Au12	67.90 (4)	C57—C42—H42B	109.5
Au1—Au13—Au16	90.76 (4)	C57—C42—H42C	109.5
Au1—Au13—Au24	130.75 (5)	C39—C43—H43A	109.5
Au5—Au13—Au1	61.75 (4)	C39—C43—H43B	109.5
Au5—Au13—Au10	98.87 (5)	C39—C43—H43C	109.5
Au5—Au13—Au12	128.06 (5)	H43A—C43—H43B	109.5
Au5—Au13—Au16	117.07 (5)	H43A—C43—H43C	109.5
Au5—Au13—Au24	161.14 (5)	H43B—C43—H43C	109.5
Au8—Au13—Au1	59.90 (4)	C40—C44—H44A	109.5
Au8—Au13—Au5	62.05 (4)	C40—C44—H44B	109.5
Au8—Au13—Au10	126.27 (5)	C40—C44—H44C	109.5
Au8—Au13—Au12	82.75 (4)	H44A—C44—H44B	109.5
Au8—Au13—Au16	55.33 (4)	H44A—C44—H44C	109.5
Au8—Au13—Au24	109.40 (5)	H44B—C44—H44C	109.5
Au10—Au13—Au16	121.73 (5)	H45A—C45—H45B	109.5
Au10—Au13—Au24	99.47 (5)	H45A—C45—H45C	109.5
Au12—Au13—Au10	71.31 (4)	H45B—C45—H45C	109.5
Au12—Au13—Au16	50.46 (3)	C53—C45—H45A	109.5
Au12—Au13—Au24	62.97 (4)	C53—C45—H45B	109.5
Au16—Au13—Au24	55.22 (3)	C53—C45—H45C	109.5
S15—Au13—Au1	171.2 (2)	C20—C46—H46A	109.5
S15—Au13—Au5	121.1 (2)	C20—C46—H46B	109.5
S15—Au13—Au8	113.1 (2)	C20—C46—H46C	109.5
S15—Au13—Au10	119.1 (2)	H46A—C46—H46B	109.5
S15—Au13—Au12	106.9 (2)	H46A—C46—H46C	109.5
S15—Au13—Au16	80.53 (19)	H46B—C46—H46C	109.5
S15—Au13—Au24	44.1 (2)	C40—C47—H47A	109.5
Au1—Au14—Au9	56.52 (3)	C40—C47—H47B	109.5
Au7—Au14—Au1	49.53 (3)	C40—C47—H47C	109.5
Au7—Au14—Au9	83.78 (4)	H47A—C47—H47B	109.5
Au8—Au14—Au1	51.06 (3)	H47A—C47—H47C	109.5
Au8—Au14—Au7	100.57 (4)	H47B—C47—H47C	109.5
Au8—Au14—Au9	51.64 (3)	C39—C48—H48A	109.5
S1—Au14—Au1	93.38 (16)	C39—C48—H48B	109.5
S1—Au14—Au7	87.30 (16)	C39—C48—H48C	109.5
S1—Au14—Au8	95.73 (17)	H48A—C48—H48B	109.5
S1—Au14—Au9	46.26 (17)	H48A—C48—H48C	109.5
S4—Au14—Au1	90.45 (15)	H48B—C48—H48C	109.5
S4—Au14—Au7	95.62 (14)	H49A—C49—H49B	109.5
S4—Au14—Au8	86.23 (16)	H49A—C49—H49C	109.5
S4—Au14—Au9	136.50 (16)	H49B—C49—H49C	109.5
S4—Au14—S1	176.1 (2)	C57—C49—H49A	109.5
Au2—Au15—Au7	76.82 (4)	C57—C49—H49B	109.5
Au2—Au15—Au18	103.95 (5)	C57—C49—H49C	109.5
Au2—Au15—Au20	126.48 (5)	C16—C50—H50A	109.5
Au2—Au15—Au23	94.78 (5)	C16—C50—H50B	109.5
Au3—Au15—Au2	60.87 (4)	C16—C50—H50C	109.5
Au3—Au15—Au7	57.72 (4)	H50A—C50—H50B	109.5
Au3—Au15—Au18	70.05 (4)	H50A—C50—H50C	109.5
Au3—Au15—Au20	67.51 (4)	H50B—C50—H50C	109.5
Au3—Au15—Au23	139.70 (5)	C31—C51—S6	107 (2)
Au18—Au15—Au7	119.35 (5)	C34—C51—S6	113 (2)
Au18—Au15—Au20	69.15 (4)	C34—C51—C31	115 (3)
Au18—Au15—Au23	150.24 (5)	C34—C51—C36	109 (3)
Au20—Au15—Au7	64.22 (4)	C36—C51—S6	104 (2)
Au23—Au15—Au7	87.11 (4)	C36—C51—C31	108 (3)
Au23—Au15—Au20	117.14 (5)	C14—C52—H52A	109.5
S16—Au15—Au2	136.3 (2)	C14—C52—H52B	109.5
S16—Au15—Au3	162.6 (2)	C14—C52—H52C	109.5
S16—Au15—Au7	117.9 (2)	H52A—C52—H52B	109.5
S16—Au15—Au18	102.6 (2)	H52A—C52—H52C	109.5
S16—Au15—Au20	95.3 (2)	H52B—C52—H52C	109.5
S16—Au15—Au23	49.4 (2)	C18—C53—S3	102.9 (19)
Au8—Au16—Au13	52.56 (4)	C18—C53—C28	111 (3)
Au8—Au16—Au19	151.94 (5)	C18—C53—C45	112 (3)
Au8—Au16—Au22	54.44 (4)	C28—C53—S3	106 (2)
Au8—Au16—Au24	115.02 (5)	C45—C53—S3	111 (2)
Au9—Au16—Au8	59.86 (4)	C45—C53—C28	113 (3)
Au9—Au16—Au13	86.15 (4)	C16—C54—H54A	109.5
Au9—Au16—Au19	95.41 (5)	C16—C54—H54B	109.5
Au9—Au16—Au22	105.50 (5)	C16—C54—H54C	109.5
Au9—Au16—Au24	130.30 (5)	H54A—C54—H54B	109.5
Au12—Au16—Au8	85.94 (4)	H54A—C54—H54C	109.5
Au12—Au16—Au9	60.57 (4)	H54B—C54—H54C	109.5
Au12—Au16—Au13	58.08 (4)	C37—C55—H55A	109.5
Au12—Au16—Au19	69.19 (4)	C37—C55—H55B	109.5
Au12—Au16—Au22	135.87 (5)	C37—C55—H55C	109.5
Au12—Au16—Au24	69.88 (4)	H55A—C55—H55B	109.5
Au13—Au16—Au22	80.58 (4)	H55A—C55—H55C	109.5
Au19—Au16—Au13	117.84 (5)	H55B—C55—H55C	109.5
Au19—Au16—Au22	153.32 (5)	C14—C56—H56A	109.5
Au19—Au16—Au24	69.32 (4)	C14—C56—H56B	109.5
Au24—Au16—Au13	63.71 (4)	C14—C56—H56C	109.5
Au24—Au16—Au22	107.07 (5)	H56A—C56—H56B	109.5
S13—Au16—Au8	98.6 (2)	H56A—C56—H56C	109.5
S13—Au16—Au9	137.3 (2)	H56B—C56—H56C	109.5
S13—Au16—Au12	160.9 (2)	C10—C57—S10	104 (3)
S13—Au16—Au13	110.4 (2)	C42—C57—S10	107 (3)
S13—Au16—Au19	109.1 (2)	C42—C57—C10	111 (4)
S13—Au16—Au22	44.2 (2)	C42—C57—C49	111 (4)
S13—Au16—Au24	91.5 (2)	C49—C57—S10	111 (3)
Au8—Au17—Au5	58.19 (4)	C49—C57—C10	111 (4)
S4—Au17—Au5	79.90 (15)	C29—C58—H58A	109.5
S4—Au17—Au8	91.80 (17)	C29—C58—H58B	109.5
S6—Au17—Au5	105.3 (2)	C29—C58—H58C	109.5
S6—Au17—Au8	89.8 (2)	H58A—C58—H58B	109.5
S6—Au17—S4	174.5 (2)	H58A—C58—H58C	109.5
Au3—Au18—Au20	57.40 (3)	H58B—C58—H58C	109.5
Au15—Au18—Au3	50.83 (3)	H59A—C59—H59B	109.5
Au15—Au18—Au20	56.78 (4)	H59A—C59—H59C	109.5
Au15—Au18—Au21	81.01 (4)	H59B—C59—H59C	109.5
Au21—Au18—Au3	57.98 (3)	C61—C59—H59A	109.5
Au21—Au18—Au20	115.33 (5)	C61—C59—H59B	109.5
S10—Au18—Au3	86.50 (18)	C61—C59—H59C	109.5
S10—Au18—Au15	99.9 (2)	C39—C60—H60A	109.5
S10—Au18—Au20	43.37 (19)	C39—C60—H60B	109.5
S10—Au18—Au21	133.51 (19)	C39—C60—H60C	109.5
S10—Au18—S14	179.3 (3)	H60A—C60—H60B	109.5
S14—Au18—Au3	93.73 (17)	H60A—C60—H60C	109.5
S14—Au18—Au15	80.72 (18)	H60B—C60—H60C	109.5
S14—Au18—Au20	137.27 (18)	C21—C61—S1	107 (3)
S14—Au18—Au21	46.27 (17)	C21—C61—C59	109 (3)
Au12—Au19—Au11	59.52 (3)	C59—C61—S1	103 (2)
Au16—Au19—Au11	84.72 (4)	C63—C61—S1	113 (3)
Au16—Au19—Au12	51.29 (3)	C63—C61—C21	116 (4)
S7—Au19—Au11	46.00 (17)	C63—C61—C59	108 (4)
S7—Au19—Au12	95.52 (17)	C11—C62—H62A	109.5
S7—Au19—Au16	85.44 (19)	C11—C62—H62B	109.5
S9—Au19—Au11	135.2 (2)	C11—C62—H62C	109.5
S9—Au19—Au12	88.57 (19)	H62A—C62—H62B	109.5
S9—Au19—Au16	99.6 (2)	H62A—C62—H62C	109.5
S9—Au19—S7	174.8 (3)	H62B—C62—H62C	109.5
Au3—Au20—Au7	53.14 (3)	C61—C63—H63A	109.5
Au3—Au20—Au18	58.57 (3)	C61—C63—H63B	109.5
Au7—Au20—Au18	105.80 (4)	C61—C63—H63C	109.5
Au15—Au20—Au3	50.52 (3)	H63A—C63—H63B	109.5
Au15—Au20—Au7	61.98 (4)	H63A—C63—H63C	109.5
Au15—Au20—Au18	54.07 (4)	H63B—C63—H63C	109.5
S10—Au20—Au3	87.29 (18)	C2—C64—H64A	109.5
S10—Au20—Au7	140.32 (18)	C2—C64—H64B	109.5
S10—Au20—Au15	96.99 (18)	C2—C64—H64C	109.5
S10—Au20—Au18	43.12 (18)	H64A—C64—H64B	109.5
S11—Au20—Au3	97.56 (17)	H64A—C64—H64C	109.5
S11—Au20—Au7	44.57 (17)	H64B—C64—H64C	109.5
S11—Au20—Au15	85.61 (17)
Au2—S5—C9—C8	−58 (2)	Au14—S1—C61—C63	41 (3)
Au2—S5—C9—C30	−174 (2)	Au14—S4—C2—C1	43 (2)
Au2—S5—C9—C35	61 (3)	Au14—S4—C2—C7	165.8 (16)
Au3—S4—C2—C1	−67 (2)	Au14—S4—C2—C64	−72 (2)
Au3—S4—C2—C7	55 (2)	Au15—S16—C6—C19	−157 (2)
Au3—S4—C2—C64	177.5 (16)	Au15—S16—C6—C27	83 (2)
Au4—S2—C20—C4	−74 (2)	Au15—S16—C6—C33	−40 (3)
Au4—S2—C20—C13	52 (3)	Au16—S13—C29—C17	161 (3)
Au4—S2—C20—C46	171.4 (17)	Au16—S13—C29—C32	41 (3)
Au5—S12—C40—C22	−53 (2)	Au16—S13—C29—C58	−81 (3)
Au5—S12—C40—C44	69 (3)	Au17—S4—C2—C1	149.5 (18)
Au5—S12—C40—C47	−173 (2)	Au17—S4—C2—C7	−87.7 (19)
Au6—S8—C24—C3	−46 (2)	Au17—S4—C2—C64	35 (2)
Au6—S8—C24—C23	−164 (2)	Au18—S10—C57—C10	−176 (2)
Au6—S8—C24—C41	78 (2)	Au18—S10—C57—C42	66 (3)
Au7—S11—C11—C5	−57 (3)	Au18—S10—C57—C49	−55 (3)
Au7—S11—C11—C12	−178 (3)	Au19—S7—C14—C38	163 (2)
Au7—S11—C11—C62	64 (3)	Au19—S7—C14—C52	−84 (3)
Au9—S1—C61—C21	176 (2)	Au19—S7—C14—C56	42 (3)
Au9—S1—C61—C59	62 (3)	Au20—S10—C57—C10	−77 (3)
Au9—S1—C61—C63	−55 (3)	Au20—S10—C57—C42	165 (3)
Au10—S3—C53—C18	81 (2)	Au20—S10—C57—C49	43 (3)
Au10—S3—C53—C28	−162.4 (18)	Au20—S11—C11—C5	44 (3)
Au10—S3—C53—C45	−39 (3)	Au20—S11—C11—C12	−77 (3)
Au10—S5—C9—C8	−156.3 (18)	Au20—S11—C11—C62	165 (3)
Au10—S5—C9—C30	87 (2)	Au21—S12—C40—C22	45 (2)
Au10—S5—C9—C35	−38 (3)	Au21—S12—C40—C44	167 (2)
Au11—S2—C20—C4	−174.7 (19)	Au21—S12—C40—C47	−75 (2)
Au11—S2—C20—C13	−49 (3)	Au22—S13—C29—C17	65 (3)
Au11—S2—C20—C46	71 (2)	Au22—S13—C29—C32	−55 (3)
Au11—S7—C14—C38	68 (3)	Au22—S13—C29—C58	−177 (3)
Au11—S7—C14—C52	−178 (2)	Au23—S8—C24—C3	41 (2)
Au11—S7—C14—C56	−52 (3)	Au23—S8—C24—C23	−77 (3)
Au12—S3—C53—C18	−173.6 (17)	Au23—S8—C24—C41	165 (2)
Au12—S3—C53—C28	−57 (2)	Au23—S16—C6—C19	−72 (3)
Au12—S3—C53—C45	66 (3)	Au23—S16—C6—C27	168 (2)
Au13—S15—C39—C43	−69 (3)	Au23—S16—C6—C33	44 (3)
Au13—S15—C39—C48	175 (2)	Au24—S15—C39—C43	−167 (3)
Au13—S15—C39—C60	55 (3)	Au24—S15—C39—C48	76 (3)
Au14—S1—C61—C21	−89 (3)	Au24—S15—C39—C60	−44 (3)
Au14—S1—C61—C59	157 (2)