In the title compound, [CuCl(C12H8N2)2]Cl·CH3OH·4.5H2O, the coordination geometry around the Cu atom is that of a trigonal bipyramid, with the central Cu atom bound to one Cl atom and four N atoms of the two phenanthroline ligands. The dihedral angle between the two phenanthroline planes is 49.6 (1)°; the dihedral angles between these planes and the equatorial plane of the trigonal bipyramid are 79.2 (1) and 88.4 (1)°.
Supporting information
CCDC reference: 239055
Key indicators
- Single-crystal X-ray study
- T = 173 K
- Mean (C-C) = 0.011 Å
- R factor = 0.097
- wR factor = 0.279
- Data-to-parameter ratio = 13.2
checkCIF/PLATON results
No syntax errors found
Alert level A
PLAT413_ALERT_2_A Short Inter XH3 .. XHn H20 .. H25B .. 1.65 Ang.
PLAT432_ALERT_2_A Short Inter X...Y Contact O3W .. C25 .. 2.44 Ang.
Alert level B
PLAT214_ALERT_2_B Atom O2W (Anion/Solvent) ADP max/min Ratio 5.60 prolat
PLAT413_ALERT_2_B Short Inter XH3 .. XHn H11 .. H25A .. 2.05 Ang.
PLAT413_ALERT_2_B Short Inter XH3 .. XHn H12 .. H25B .. 2.09 Ang.
PLAT415_ALERT_2_B Short Inter D-H..H-X H3WB .. H25C .. 2.07 Ang.
PLAT417_ALERT_2_B Short Inter D-H..H-D H1A .. H1A .. 1.30 Ang.
PLAT417_ALERT_2_B Short Inter D-H..H-D H2WB .. H2WB .. 1.33 Ang.
PLAT417_ALERT_2_B Short Inter D-H..H-D H4WA .. H5WA .. 1.98 Ang.
PLAT417_ALERT_2_B Short Inter D-H..H-D H4WA .. H5WB .. 1.68 Ang.
PLAT417_ALERT_2_B Short Inter D-H..H-D H5WA .. H6WA .. 2.00 Ang.
PLAT420_ALERT_2_B D-H Without Acceptor O5W - H5WA ... ?
PLAT431_ALERT_2_B Short Inter HL..A Contact Cl1 .. Cl2 .. 3.16 Ang.
PLAT432_ALERT_2_B Short Inter X...Y Contact O4W .. C25 .. 2.75 Ang.
PLAT432_ALERT_2_B Short Inter X...Y Contact O4W .. C25 .. 2.75 Ang.
Alert level C
RFACR01_ALERT_3_C The value of the weighted R factor is > 0.25
Weighted R factor given 0.279
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 0.50 Ratio
PLAT084_ALERT_2_C High R2 Value .................................. 0.28
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Cu1 - N2 .. 5.69 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Cu1 - N4 .. 5.25 su
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 11
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 9
N4 -CU1 -N2 -C6 99.00 4.00 1.555 1.555 1.555 1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 13
N4 -CU1 -N2 -C12 -82.00 4.00 1.555 1.555 1.555 1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 25
N2 -CU1 -N4 -C24 -156.00 3.00 1.555 1.555 1.555 1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 29
N2 -CU1 -N4 -C18 35.00 4.00 1.555 1.555 1.555 1.555
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 9
2 ALERT level A = In general: serious problem
13 ALERT level B = Potentially serious problem
13 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
18 ALERT type 2 Indicator that the structure model may be wrong or deficient
2 ALERT type 3 Indicator that the structure quality may be low
5 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL/PC (Sheldrick, 1999); software used to prepare material for publication: SHELXTL/PC.
Chlorobis(1,10-phenanthroline)copper(II) chloride methanol 4.5-hydrate
top
Crystal data top
[CuCl(C12H8N2)2]Cl·CH4O·4.5H2O | F(000) = 2512 |
Mr = 607.96 | Dx = 1.552 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 4822 reflections |
a = 23.387 (5) Å | θ = 2.2–25.2° |
b = 30.418 (7) Å | µ = 1.09 mm−1 |
c = 7.3816 (16) Å | T = 173 K |
β = 97.714 (3)° | Block, green |
V = 5204 (2) Å3 | 0.38 × 0.30 × 0.20 mm |
Z = 8 | |
Data collection top
Bruker SMART 1K CCD area-detector diffractometer | 4524 independent reflections |
Radiation source: fine-focus sealed tube | 3292 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.075 |
φ and ω scans | θmax = 25.0°, θmin = 1.3° |
Absorption correction: multi-scan (SADABS; Sheldrick, 2000) | h = −24→27 |
Tmin = 0.682, Tmax = 0.811 | k = −36→36 |
12342 measured reflections | l = −8→5 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.097 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.279 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.06 | w = 1/[σ2(Fo2) + (0.1394P)2 + 34.1552P] where P = (Fo2 + 2Fc2)/3 |
4524 reflections | (Δ/σ)max = 0.001 |
343 parameters | Δρmax = 1.04 e Å−3 |
0 restraints | Δρmin = −0.80 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Cu1 | 0.77549 (4) | 0.88115 (3) | 0.34383 (12) | 0.0464 (3) | |
N1 | 0.8107 (2) | 0.9440 (2) | 0.4049 (7) | 0.0446 (13) | |
N2 | 0.7099 (3) | 0.9169 (2) | 0.2277 (8) | 0.0487 (14) | |
N3 | 0.7271 (2) | 0.84575 (19) | 0.5120 (7) | 0.0436 (12) | |
N4 | 0.8384 (3) | 0.8448 (2) | 0.4747 (8) | 0.0516 (14) | |
Cl1 | 0.79099 (8) | 0.85266 (6) | 0.0583 (2) | 0.0538 (5) | |
C1 | 0.8602 (3) | 0.9574 (3) | 0.4932 (10) | 0.0536 (17) | |
H1 | 0.8871 | 0.9360 | 0.5456 | 0.064* | |
C2 | 0.8752 (3) | 1.0024 (3) | 0.5135 (11) | 0.059 (2) | |
H2 | 0.9124 | 1.0105 | 0.5719 | 0.071* | |
C3 | 0.8371 (4) | 1.0338 (3) | 0.4505 (10) | 0.0564 (19) | |
H3 | 0.8466 | 1.0640 | 0.4686 | 0.068* | |
C4 | 0.7825 (3) | 1.0213 (2) | 0.3567 (9) | 0.0464 (16) | |
C5 | 0.7717 (3) | 0.9757 (2) | 0.3382 (8) | 0.0414 (14) | |
C6 | 0.7179 (3) | 0.9605 (2) | 0.2432 (8) | 0.0422 (14) | |
C7 | 0.7385 (4) | 1.0514 (3) | 0.2815 (11) | 0.059 (2) | |
H7 | 0.7452 | 1.0821 | 0.2962 | 0.071* | |
C8 | 0.6876 (4) | 1.0374 (3) | 0.1900 (11) | 0.063 (2) | |
H8 | 0.6598 | 1.0584 | 0.1401 | 0.075* | |
C9 | 0.6753 (3) | 0.9917 (2) | 0.1674 (10) | 0.0488 (16) | |
C10 | 0.6235 (3) | 0.9741 (3) | 0.0731 (10) | 0.060 (2) | |
H10 | 0.5937 | 0.9933 | 0.0204 | 0.072* | |
C11 | 0.6166 (3) | 0.9292 (3) | 0.0579 (12) | 0.061 (2) | |
H11 | 0.5820 | 0.9173 | −0.0054 | 0.073* | |
C12 | 0.6599 (3) | 0.9018 (3) | 0.1348 (11) | 0.0564 (18) | |
H12 | 0.6545 | 0.8709 | 0.1223 | 0.068* | |
C13 | 0.6712 (3) | 0.8469 (2) | 0.5308 (10) | 0.0514 (17) | |
H13 | 0.6478 | 0.8695 | 0.4710 | 0.062* | |
C14 | 0.6455 (3) | 0.8156 (3) | 0.6372 (10) | 0.0564 (19) | |
H14 | 0.6056 | 0.8173 | 0.6493 | 0.068* | |
C15 | 0.6794 (3) | 0.7827 (3) | 0.7223 (10) | 0.0565 (19) | |
H15 | 0.6630 | 0.7617 | 0.7951 | 0.068* | |
C16 | 0.7375 (3) | 0.7801 (2) | 0.7025 (9) | 0.0492 (16) | |
C17 | 0.7604 (3) | 0.8127 (2) | 0.5978 (8) | 0.0410 (14) | |
C18 | 0.8200 (3) | 0.8120 (2) | 0.5771 (9) | 0.0448 (15) | |
C19 | 0.7757 (4) | 0.7464 (2) | 0.7852 (9) | 0.0544 (18) | |
H19 | 0.7610 | 0.7239 | 0.8555 | 0.065* | |
C20 | 0.8327 (4) | 0.7463 (2) | 0.7637 (10) | 0.0553 (18) | |
H20 | 0.8571 | 0.7237 | 0.8187 | 0.066* | |
C21 | 0.8562 (3) | 0.7793 (2) | 0.6612 (9) | 0.0508 (16) | |
C22 | 0.9153 (3) | 0.7809 (3) | 0.6330 (11) | 0.0589 (19) | |
H22 | 0.9419 | 0.7594 | 0.6865 | 0.071* | |
C23 | 0.9329 (3) | 0.8134 (3) | 0.5289 (11) | 0.063 (2) | |
H23 | 0.9722 | 0.8145 | 0.5093 | 0.076* | |
C24 | 0.8948 (3) | 0.8455 (3) | 0.4490 (11) | 0.0573 (18) | |
H24 | 0.9084 | 0.8679 | 0.3763 | 0.069* | |
C25 | 0.4385 (6) | 0.1759 (5) | 0.968 (2) | 0.116 (4) | |
H25A | 0.4375 | 0.1483 | 1.0354 | 0.174* | |
H25B | 0.3992 | 0.1843 | 0.9168 | 0.174* | |
H25C | 0.4555 | 0.1990 | 1.0503 | 0.174* | |
O1 | 0.4703 (4) | 0.1706 (3) | 0.8321 (13) | 0.106 (3) | |
H1A | 0.4762 | 0.1952 | 0.7862 | 0.159* | |
Cl2 | 0.0774 (3) | 0.8361 (3) | 0.4757 (10) | 0.235 (3) | |
O1W | 0.0000 | 0.0774 (5) | 0.7500 | 0.117 (4) | |
H1WA | 0.0098 | 0.0601 | 0.6691 | 0.048* | |
O2W | 0.9883 (13) | 0.0716 (16) | 0.394 (8) | 0.87 (7) | |
H2WA | 0.9603 | 0.0894 | 0.3658 | 0.048* | |
H2WB | 0.9866 | 0.0524 | 0.3238 | 0.048* | |
O3W | 0.4512 (4) | 0.2473 (5) | 0.1189 (14) | 0.170 (6) | |
H3WB | 0.4514 | 0.2517 | 0.2265 | 0.048* | |
H3WA | 0.4521 | 0.2702 | 0.0627 | 0.048* | |
O4W | 0.5000 | 0.1300 (5) | 0.2500 | 0.120 (4) | |
H4WA | 0.4785 | 0.1145 | 0.3012 | 0.048* | |
O5W | 0.0546 (4) | 0.5847 (4) | −0.0333 (15) | 0.133 (4) | |
H5WA | 0.0459 | 0.5669 | 0.0425 | 0.048* | |
H5WB | 0.0461 | 0.6094 | −0.0033 | 0.048* | |
O6W | 1.0000 | 0.5129 (9) | 0.7500 | 0.200 (10) | |
H6WA | 0.9808 | 0.5294 | 0.6742 | 0.048* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Cu1 | 0.0447 (5) | 0.0478 (6) | 0.0478 (5) | −0.0010 (3) | 0.0101 (4) | 0.0028 (3) |
N1 | 0.036 (3) | 0.056 (3) | 0.043 (3) | −0.002 (2) | 0.010 (2) | 0.002 (2) |
N2 | 0.054 (3) | 0.052 (3) | 0.041 (3) | −0.014 (3) | 0.010 (3) | −0.001 (2) |
N3 | 0.040 (3) | 0.052 (3) | 0.040 (3) | −0.003 (2) | 0.008 (2) | −0.005 (2) |
N4 | 0.056 (4) | 0.057 (4) | 0.044 (3) | −0.010 (3) | 0.014 (3) | −0.004 (3) |
Cl1 | 0.0660 (11) | 0.0501 (10) | 0.0474 (9) | −0.0001 (8) | 0.0152 (8) | −0.0026 (7) |
C1 | 0.047 (4) | 0.062 (5) | 0.055 (4) | −0.009 (3) | 0.020 (3) | 0.001 (3) |
C2 | 0.051 (4) | 0.069 (5) | 0.061 (4) | −0.023 (4) | 0.023 (4) | −0.014 (4) |
C3 | 0.070 (5) | 0.052 (4) | 0.051 (4) | −0.008 (4) | 0.024 (4) | −0.007 (3) |
C4 | 0.055 (4) | 0.046 (4) | 0.043 (3) | −0.004 (3) | 0.025 (3) | 0.002 (3) |
C5 | 0.044 (3) | 0.049 (4) | 0.034 (3) | −0.003 (3) | 0.013 (3) | −0.005 (3) |
C6 | 0.031 (3) | 0.062 (4) | 0.036 (3) | 0.000 (3) | 0.013 (2) | 0.004 (3) |
C7 | 0.085 (6) | 0.044 (4) | 0.055 (4) | 0.007 (4) | 0.029 (4) | 0.000 (3) |
C8 | 0.071 (5) | 0.071 (5) | 0.050 (4) | 0.008 (4) | 0.020 (4) | 0.008 (4) |
C9 | 0.051 (4) | 0.053 (4) | 0.046 (4) | 0.010 (3) | 0.023 (3) | 0.008 (3) |
C10 | 0.046 (4) | 0.088 (6) | 0.049 (4) | 0.004 (4) | 0.015 (3) | 0.010 (4) |
C11 | 0.042 (4) | 0.076 (6) | 0.064 (5) | −0.002 (4) | 0.002 (3) | 0.009 (4) |
C12 | 0.044 (4) | 0.072 (5) | 0.056 (4) | −0.005 (4) | 0.014 (3) | 0.010 (4) |
C13 | 0.045 (4) | 0.055 (4) | 0.055 (4) | −0.005 (3) | 0.013 (3) | −0.005 (3) |
C14 | 0.052 (4) | 0.068 (5) | 0.053 (4) | −0.011 (4) | 0.022 (3) | −0.008 (4) |
C15 | 0.060 (5) | 0.068 (5) | 0.042 (4) | −0.019 (4) | 0.008 (3) | 0.004 (3) |
C16 | 0.060 (4) | 0.048 (4) | 0.040 (3) | −0.010 (3) | 0.009 (3) | −0.004 (3) |
C17 | 0.049 (4) | 0.039 (3) | 0.037 (3) | −0.004 (3) | 0.012 (3) | −0.007 (3) |
C18 | 0.047 (4) | 0.047 (4) | 0.041 (3) | 0.000 (3) | 0.007 (3) | −0.004 (3) |
C19 | 0.071 (5) | 0.054 (4) | 0.035 (3) | −0.013 (4) | −0.004 (3) | 0.000 (3) |
C20 | 0.067 (5) | 0.047 (4) | 0.050 (4) | −0.001 (3) | −0.002 (3) | 0.001 (3) |
C21 | 0.058 (4) | 0.051 (4) | 0.042 (4) | 0.008 (3) | 0.003 (3) | −0.002 (3) |
C22 | 0.051 (4) | 0.061 (5) | 0.062 (4) | 0.009 (4) | −0.004 (4) | −0.002 (4) |
C23 | 0.041 (4) | 0.087 (6) | 0.062 (5) | 0.010 (4) | 0.012 (3) | −0.007 (4) |
C24 | 0.047 (4) | 0.062 (5) | 0.066 (5) | 0.003 (3) | 0.018 (3) | 0.003 (4) |
C25 | 0.081 (8) | 0.127 (11) | 0.137 (12) | 0.008 (8) | 0.005 (8) | 0.007 (9) |
O1 | 0.107 (6) | 0.090 (5) | 0.113 (6) | −0.012 (5) | −0.016 (5) | 0.037 (5) |
Cl2 | 0.182 (6) | 0.328 (10) | 0.198 (6) | −0.017 (6) | 0.034 (5) | 0.060 (6) |
O1W | 0.053 (6) | 0.194 (13) | 0.108 (9) | 0.000 | 0.020 (6) | 0.000 |
O2W | 0.22 (3) | 0.99 (9) | 1.32 (17) | −0.34 (5) | −0.19 (5) | 0.84 (11) |
O3W | 0.078 (6) | 0.303 (15) | 0.118 (7) | −0.067 (7) | −0.023 (5) | 0.112 (8) |
O4W | 0.086 (8) | 0.138 (11) | 0.141 (12) | 0.000 | 0.027 (8) | 0.000 |
O5W | 0.089 (6) | 0.152 (8) | 0.154 (9) | 0.047 (6) | 0.001 (6) | −0.037 (7) |
O6W | 0.031 (5) | 0.42 (3) | 0.143 (13) | 0.000 | −0.001 (6) | 0.000 |
Geometric parameters (Å, º) top
Cu1—N2 | 1.979 (6) | C13—H13 | 0.9500 |
Cu1—N4 | 1.986 (7) | C14—C15 | 1.374 (12) |
Cu1—N3 | 2.087 (5) | C14—H14 | 0.9500 |
Cu1—N1 | 2.105 (6) | C15—C16 | 1.388 (11) |
Cu1—Cl1 | 2.351 (2) | C15—H15 | 0.9500 |
N1—C1 | 1.316 (9) | C16—C17 | 1.408 (9) |
N1—C5 | 1.374 (9) | C16—C19 | 1.442 (11) |
N2—C6 | 1.344 (9) | C17—C18 | 1.423 (9) |
N2—C12 | 1.355 (9) | C18—C21 | 1.396 (10) |
N3—C13 | 1.334 (9) | C19—C20 | 1.364 (11) |
N3—C17 | 1.372 (9) | C19—H19 | 0.9500 |
N4—C24 | 1.357 (9) | C20—C21 | 1.411 (11) |
N4—C18 | 1.355 (9) | C20—H20 | 0.9500 |
C1—C2 | 1.418 (11) | C21—C22 | 1.427 (11) |
C1—H1 | 0.9500 | C22—C23 | 1.350 (12) |
C2—C3 | 1.345 (12) | C22—H22 | 0.9500 |
C2—H2 | 0.9500 | C23—C24 | 1.398 (11) |
C3—C4 | 1.421 (11) | C23—H23 | 0.9500 |
C3—H3 | 0.9500 | C24—H24 | 0.9500 |
C4—C5 | 1.412 (9) | C25—O1 | 1.334 (15) |
C4—C7 | 1.431 (11) | C25—H25A | 0.9800 |
C5—C6 | 1.431 (9) | C25—H25B | 0.9800 |
C6—C9 | 1.434 (9) | C25—H25C | 0.9800 |
C7—C8 | 1.355 (12) | O1—H1A | 0.8400 |
C7—H7 | 0.9500 | O1W—H1WA | 0.8497 |
C8—C9 | 1.423 (11) | O2W—H2WA | 0.8535 |
C8—H8 | 0.9500 | O2W—H2WB | 0.7761 |
C9—C10 | 1.418 (11) | O3W—H3WB | 0.8048 |
C10—C11 | 1.379 (12) | O3W—H3WA | 0.8110 |
C10—H10 | 0.9500 | O4W—H4WA | 0.8188 |
C11—C12 | 1.375 (11) | O5W—H5WA | 0.8226 |
C11—H11 | 0.9500 | O5W—H5WB | 0.8159 |
C12—H12 | 0.9500 | O6W—H6WA | 0.8356 |
C13—C14 | 1.419 (10) | | |
| | | |
N2—Cu1—N4 | 176.1 (2) | C10—C11—C12 | 119.7 (8) |
N2—Cu1—N3 | 95.2 (2) | C10—C11—H11 | 120.2 |
N4—Cu1—N3 | 81.3 (2) | C12—C11—H11 | 120.2 |
N2—Cu1—N1 | 81.5 (2) | N2—C12—C11 | 122.8 (8) |
N4—Cu1—N1 | 99.2 (2) | N2—C12—H12 | 118.6 |
N3—Cu1—N1 | 124.6 (2) | C11—C12—H12 | 118.6 |
N2—Cu1—Cl1 | 91.03 (17) | N3—C13—C14 | 122.3 (7) |
N4—Cu1—Cl1 | 92.15 (18) | N3—C13—H13 | 118.9 |
N3—Cu1—Cl1 | 120.27 (16) | C14—C13—H13 | 118.9 |
N1—Cu1—Cl1 | 115.06 (16) | C15—C14—C13 | 118.7 (7) |
C1—N1—C5 | 117.3 (6) | C15—C14—H14 | 120.7 |
C1—N1—Cu1 | 132.8 (5) | C13—C14—H14 | 120.7 |
C5—N1—Cu1 | 109.9 (4) | C14—C15—C16 | 120.4 (7) |
C6—N2—C12 | 118.6 (7) | C14—C15—H15 | 119.8 |
C6—N2—Cu1 | 114.5 (4) | C16—C15—H15 | 119.8 |
C12—N2—Cu1 | 126.8 (5) | C15—C16—C17 | 117.9 (7) |
C13—N3—C17 | 118.3 (6) | C15—C16—C19 | 123.8 (7) |
C13—N3—Cu1 | 131.7 (5) | C17—C16—C19 | 118.3 (7) |
C17—N3—Cu1 | 109.4 (4) | N3—C17—C16 | 122.3 (6) |
C24—N4—C18 | 118.5 (7) | N3—C17—C18 | 117.7 (6) |
C24—N4—Cu1 | 126.4 (5) | C16—C17—C18 | 119.9 (6) |
C18—N4—Cu1 | 114.3 (5) | N4—C18—C21 | 123.6 (7) |
N1—C1—C2 | 122.7 (8) | N4—C18—C17 | 115.9 (6) |
N1—C1—H1 | 118.7 | C21—C18—C17 | 120.5 (7) |
C2—C1—H1 | 118.7 | C20—C19—C16 | 120.8 (7) |
C3—C2—C1 | 120.4 (8) | C20—C19—H19 | 119.6 |
C3—C2—H2 | 119.8 | C16—C19—H19 | 119.6 |
C1—C2—H2 | 119.8 | C19—C20—C21 | 121.2 (7) |
C2—C3—C4 | 119.3 (7) | C19—C20—H20 | 119.4 |
C2—C3—H3 | 120.3 | C21—C20—H20 | 119.4 |
C4—C3—H3 | 120.3 | C18—C21—C20 | 119.3 (7) |
C5—C4—C3 | 116.5 (7) | C18—C21—C22 | 116.9 (7) |
C5—C4—C7 | 118.7 (7) | C20—C21—C22 | 123.7 (7) |
C3—C4—C7 | 124.8 (7) | C23—C22—C21 | 118.8 (7) |
N1—C5—C4 | 123.7 (6) | C23—C22—H22 | 120.6 |
N1—C5—C6 | 116.4 (6) | C21—C22—H22 | 120.6 |
C4—C5—C6 | 119.9 (6) | C22—C23—C24 | 121.8 (7) |
N2—C6—C5 | 117.6 (6) | C22—C23—H23 | 119.1 |
N2—C6—C9 | 122.6 (6) | C24—C23—H23 | 119.1 |
C5—C6—C9 | 119.7 (7) | N4—C24—C23 | 120.4 (7) |
C8—C7—C4 | 121.9 (8) | N4—C24—H24 | 119.8 |
C8—C7—H7 | 119.0 | C23—C24—H24 | 119.8 |
C4—C7—H7 | 119.0 | O1—C25—H25A | 109.5 |
C7—C8—C9 | 121.1 (8) | O1—C25—H25B | 109.5 |
C7—C8—H8 | 119.5 | H25A—C25—H25B | 109.5 |
C9—C8—H8 | 119.5 | O1—C25—H25C | 109.5 |
C8—C9—C10 | 124.9 (7) | H25A—C25—H25C | 109.5 |
C8—C9—C6 | 118.7 (7) | H25B—C25—H25C | 109.5 |
C10—C9—C6 | 116.4 (7) | C25—O1—H1A | 109.5 |
C11—C10—C9 | 119.9 (7) | H2WA—O2W—H2WB | 110.3 |
C11—C10—H10 | 120.1 | H3WB—O3W—H3WA | 111.5 |
C9—C10—H10 | 120.1 | H5WA—O5W—H5WB | 109.3 |
| | | |
N2—Cu1—N1—C1 | 179.5 (6) | C4—C5—C6—C9 | 0.0 (8) |
N4—Cu1—N1—C1 | 3.4 (6) | C5—C4—C7—C8 | −1.5 (10) |
N3—Cu1—N1—C1 | 89.1 (6) | C3—C4—C7—C8 | 178.6 (7) |
Cl1—Cu1—N1—C1 | −93.3 (6) | C4—C7—C8—C9 | 1.2 (11) |
N2—Cu1—N1—C5 | 0.8 (4) | C7—C8—C9—C10 | −179.6 (7) |
N4—Cu1—N1—C5 | −175.4 (4) | C7—C8—C9—C6 | −0.2 (10) |
N3—Cu1—N1—C5 | −89.7 (4) | N2—C6—C9—C8 | −179.7 (6) |
Cl1—Cu1—N1—C5 | 87.9 (4) | C5—C6—C9—C8 | −0.4 (9) |
N4—Cu1—N2—C6 | 99 (4) | N2—C6—C9—C10 | −0.2 (9) |
N3—Cu1—N2—C6 | 123.6 (5) | C5—C6—C9—C10 | 179.1 (6) |
N1—Cu1—N2—C6 | −0.7 (4) | C8—C9—C10—C11 | 179.2 (7) |
Cl1—Cu1—N2—C6 | −115.9 (4) | C6—C9—C10—C11 | −0.2 (10) |
N4—Cu1—N2—C12 | −82 (4) | C9—C10—C11—C12 | 0.1 (12) |
N3—Cu1—N2—C12 | −57.5 (6) | C6—N2—C12—C11 | −0.9 (10) |
N1—Cu1—N2—C12 | 178.3 (6) | Cu1—N2—C12—C11 | −179.8 (6) |
Cl1—Cu1—N2—C12 | 63.1 (6) | C10—C11—C12—N2 | 0.4 (12) |
N2—Cu1—N3—C13 | 0.8 (6) | C17—N3—C13—C14 | 0.5 (10) |
N4—Cu1—N3—C13 | 179.1 (7) | Cu1—N3—C13—C14 | 171.4 (5) |
N1—Cu1—N3—C13 | 84.0 (7) | N3—C13—C14—C15 | −0.5 (11) |
Cl1—Cu1—N3—C13 | −93.5 (6) | C13—C14—C15—C16 | −0.7 (11) |
N2—Cu1—N3—C17 | 172.2 (4) | C14—C15—C16—C17 | 1.8 (11) |
N4—Cu1—N3—C17 | −9.4 (4) | C14—C15—C16—C19 | −179.1 (7) |
N1—Cu1—N3—C17 | −104.6 (4) | C13—N3—C17—C16 | 0.7 (9) |
Cl1—Cu1—N3—C17 | 78.0 (4) | Cu1—N3—C17—C16 | −172.1 (5) |
N2—Cu1—N4—C24 | −156 (3) | C13—N3—C17—C18 | −179.8 (6) |
N3—Cu1—N4—C24 | 179.6 (7) | Cu1—N3—C17—C18 | 7.5 (7) |
N1—Cu1—N4—C24 | −56.6 (6) | C15—C16—C17—N3 | −1.8 (10) |
Cl1—Cu1—N4—C24 | 59.3 (6) | C19—C16—C17—N3 | 179.1 (6) |
N2—Cu1—N4—C18 | 35 (4) | C15—C16—C17—C18 | 178.6 (6) |
N3—Cu1—N4—C18 | 10.3 (5) | C19—C16—C17—C18 | −0.5 (9) |
N1—Cu1—N4—C18 | 134.2 (5) | C24—N4—C18—C21 | 1.4 (10) |
Cl1—Cu1—N4—C18 | −110.0 (5) | Cu1—N4—C18—C21 | 171.6 (5) |
C5—N1—C1—C2 | −3.0 (9) | C24—N4—C18—C17 | −179.4 (6) |
Cu1—N1—C1—C2 | 178.3 (5) | Cu1—N4—C18—C17 | −9.2 (7) |
N1—C1—C2—C3 | 3.8 (11) | N3—C17—C18—N4 | 0.7 (9) |
C1—C2—C3—C4 | −2.6 (11) | C16—C17—C18—N4 | −179.7 (6) |
C2—C3—C4—C5 | 0.9 (9) | N3—C17—C18—C21 | 179.9 (6) |
C2—C3—C4—C7 | −179.3 (7) | C16—C17—C18—C21 | −0.5 (10) |
C1—N1—C5—C4 | 1.2 (9) | C15—C16—C19—C20 | −178.5 (7) |
Cu1—N1—C5—C4 | −179.8 (5) | C17—C16—C19—C20 | 0.6 (10) |
C1—N1—C5—C6 | −179.7 (5) | C16—C19—C20—C21 | 0.4 (11) |
Cu1—N1—C5—C6 | −0.7 (6) | N4—C18—C21—C20 | −179.4 (6) |
C3—C4—C5—N1 | −0.1 (9) | C17—C18—C21—C20 | 1.5 (10) |
C7—C4—C5—N1 | −180.0 (6) | N4—C18—C21—C22 | −1.1 (10) |
C3—C4—C5—C6 | −179.2 (6) | C17—C18—C21—C22 | 179.8 (6) |
C7—C4—C5—C6 | 0.9 (8) | C19—C20—C21—C18 | −1.4 (11) |
C12—N2—C6—C5 | −178.5 (6) | C19—C20—C21—C22 | −179.6 (7) |
Cu1—N2—C6—C5 | 0.5 (7) | C18—C21—C22—C23 | 0.3 (11) |
C12—N2—C6—C9 | 0.8 (9) | C20—C21—C22—C23 | 178.5 (7) |
Cu1—N2—C6—C9 | 179.8 (5) | C21—C22—C23—C24 | 0.2 (12) |
N1—C5—C6—N2 | 0.2 (8) | C18—N4—C24—C23 | −0.9 (11) |
C4—C5—C6—N2 | 179.3 (5) | Cu1—N4—C24—C23 | −169.7 (6) |
N1—C5—C6—C9 | −179.1 (5) | C22—C23—C24—N4 | 0.1 (13) |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O6W—H6WA···O5Wi | 0.84 | 2.09 | 2.90 (2) | 163 |
O5W—H5WB···O4Wii | 0.82 | 2.36 | 2.936 (12) | 128 |
O4W—H4WA···O5Wiii | 0.82 | 2.17 | 2.936 (12) | 156 |
O3W—H3WA···Cl2iii | 0.81 | 2.13 | 2.847 (17) | 148 |
O3W—H3WB···O3Wi | 0.80 | 2.41 | 2.786 (17) | 110 |
O2W—H2WA···Cl2iv | 0.85 | 2.75 | 3.40 (6) | 134 |
O1W—H1WA···O2Wv | 0.85 | 2.06 | 2.61 (6) | 122 |
Symmetry codes: (i) −x+1, y, −z+1/2; (ii) x−1/2, y+1/2, z; (iii) −x+1/2, y−1/2, −z+1/2; (iv) −x+1, −y+1, −z+1; (v) x−1, y, z. |