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The inter­metallic title compound, penta­cerium diplatinum tetra­indide, crystallizes in space group Pbam and adopts the Lu5Ni2In4 structure type. One Ce atom exhibits site symmetry 2/m and all other atoms (two Ce, one Pt and two In) are located on mirror planes.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806007264/wm2005sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806007264/wm2005Isup2.hkl
Contains datablock I

Key indicators

  • Single-crystal X-ray study
  • T = 291 K
  • Mean [sigma](e-Ce)= 0.001 Å
  • R factor = 0.036
  • wR factor = 0.115
  • Data-to-parameter ratio = 39.7

checkCIF/PLATON results

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No errors found in this datablock

Computing details top

Data collection: CAD-4 EXPRESS (Enraf–Nonius, 1994); cell refinement: CAD-4 EXPRESS; data reduction: XCAD4 (Harms & Wocadlo, 1995); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg, 1998) and ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

pentacerium diplatinum tetraindide top
Crystal data top
Ce5Pt2In4F(000) = 1284
Mr = 1550.06Dx = 8.839 Mg m3
Orthorhombic, PbamMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2 2abCell parameters from 25 reflections
a = 8.2088 (14) Åθ = 18.2–23.1°
b = 18.579 (4) ŵ = 50.69 mm1
c = 3.8188 (8) ÅT = 291 K
V = 582.4 (2) Å3Lath, metallic light-grey
Z = 20.07 × 0.04 × 0.01 mm
Data collection top
Enraf–Nonius CAD-4
diffractometer
1149 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.000
Graphite monochromatorθmax = 35.0°, θmin = 2.2°
ω scansh = 130
Absorption correction: ψ scan
(North et al., 1968)
k = 029
Tmin = 0.090, Tmax = 0.602l = 06
1430 measured reflections1 standard reflections every 120 min
1430 independent reflections intensity decay: none
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.037 w = 1/[σ2(Fo2) + (0.1P)2]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.115(Δ/σ)max < 0.001
S = 0.82Δρmax = 2.46 e Å3
1430 reflectionsΔρmin = 4.63 e Å3
36 parametersExtinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
0 restraintsExtinction coefficient: 0.0017 (3)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ce10.12160 (8)0.41785 (4)0.00000.01245 (16)
Ce20.24262 (8)0.22254 (4)0.00000.01195 (16)
Ce30.00000.00000.00000.0134 (2)
Pt0.01979 (6)0.30468 (2)0.50000.01234 (14)
In10.29027 (10)0.07173 (5)0.50000.01462 (19)
In20.43306 (11)0.34996 (5)0.50000.01504 (19)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ce10.0110 (3)0.0103 (3)0.0160 (3)0.0003 (2)0.0000.000
Ce20.0113 (3)0.0113 (3)0.0133 (3)0.00148 (19)0.0000.000
Ce30.0122 (4)0.0116 (4)0.0163 (4)0.0001 (3)0.0000.000
Pt0.0122 (2)0.0094 (2)0.0154 (2)0.00008 (13)0.0000.000
In10.0102 (3)0.0096 (3)0.0241 (5)0.0013 (3)0.0000.000
In20.0123 (4)0.0093 (3)0.0234 (5)0.0008 (3)0.0000.000
Geometric parameters (Å, º) top
Ce1—Pti2.9606 (7)Ce3—In2xii3.4233 (9)
Ce1—Pt2.9606 (7)Ce3—In2ii3.4233 (9)
Ce1—In1ii3.3288 (10)Ce3—In2xiii3.4233 (9)
Ce1—In1iii3.3288 (10)Ce3—Ce1xiii3.4609 (8)
Ce1—In23.4313 (10)Ce3—Ce1ii3.4609 (8)
Ce1—In2i3.4313 (10)Ce3—Ce3viii3.8188 (8)
Ce1—Ce3iv3.4609 (8)Ce3—Ce3i3.8188 (8)
Ce1—In1v3.5131 (10)Pt—In2iii2.9599 (11)
Ce1—In1vi3.5131 (10)Pt—Ce1viii2.9606 (7)
Ce1—Ce1vii3.6474 (14)Pt—In1iii2.9703 (10)
Ce1—Ce23.7623 (12)Pt—Ce2ii3.0130 (8)
Ce1—Ce1viii3.8188 (8)Pt—Ce2iii3.0130 (8)
Ce1—Ce1i3.8188 (8)Pt—Ce2viii3.0530 (7)
Ce1—Ce2ii4.0597 (11)Pt—In23.4952 (12)
Ce2—Ptix3.0130 (8)Pt—Ptviii3.8188 (8)
Ce2—Ptiv3.0130 (8)Pt—Pti3.8188 (8)
Ce2—Pti3.0530 (7)In1—Ptix2.9703 (10)
Ce2—Pt3.0530 (7)In1—In2iii3.2734 (13)
Ce2—In1i3.4132 (11)In1—Ce1ix3.3288 (10)
Ce2—In13.4132 (11)In1—Ce1iv3.3288 (10)
Ce2—In23.4196 (10)In1—Ce3viii3.3315 (8)
Ce2—In2i3.4196 (10)In1—Ce2viii3.4132 (11)
Ce2—In2ii3.4521 (10)In1—Ce1xiii3.5131 (10)
Ce2—In2iii3.4521 (10)In1—Ce1xiv3.5131 (10)
Ce2—Ce2viii3.8188 (8)In2—Ptix2.9599 (11)
Ce2—Ce2i3.8188 (8)In2—In1ix3.2734 (13)
Ce2—Ce1iv4.0597 (11)In2—Ce2viii3.4196 (10)
Ce3—In1x3.3315 (8)In2—Ce3ix3.4233 (9)
Ce3—In13.3315 (8)In2—Ce3iv3.4233 (9)
Ce3—In1xi3.3315 (8)In2—Ce1viii3.4313 (10)
Ce3—In1i3.3315 (8)In2—Ce2ix3.4521 (10)
Ce3—In2iii3.4233 (9)In2—Ce2iv3.4521 (10)
Pti—Ce1—Pt80.32 (3)In2xii—Ce3—In2ii112.20 (2)
Pti—Ce1—In1ii55.995 (19)In1x—Ce3—In2xiii96.24 (2)
Pt—Ce1—In1ii100.40 (3)In1—Ce3—In2xiii83.76 (2)
Pti—Ce1—In1iii100.40 (3)In1xi—Ce3—In2xiii57.95 (2)
Pt—Ce1—In1iii55.995 (19)In1i—Ce3—In2xiii122.05 (2)
In1ii—Ce1—In1iii70.00 (3)In2iii—Ce3—In2xiii112.20 (2)
Pti—Ce1—In2107.95 (3)In2xii—Ce3—In2xiii67.80 (2)
Pt—Ce1—In265.82 (2)In2ii—Ce3—In2xiii180.000 (16)
In1ii—Ce1—In2161.69 (3)In1x—Ce3—Ce1xiii117.743 (19)
In1iii—Ce1—In2108.12 (2)In1—Ce3—Ce1xiii62.257 (19)
Pti—Ce1—In2i65.82 (2)In1xi—Ce3—Ce1xiii117.743 (19)
Pt—Ce1—In2i107.95 (3)In1i—Ce3—Ce1xiii62.257 (19)
In1ii—Ce1—In2i108.12 (2)In2iii—Ce3—Ce1xiii120.210 (17)
In1iii—Ce1—In2i161.69 (3)In2xii—Ce3—Ce1xiii59.790 (17)
In2—Ce1—In2i67.62 (2)In2ii—Ce3—Ce1xiii120.210 (17)
Pti—Ce1—Ce3iv124.510 (18)In2xiii—Ce3—Ce1xiii59.790 (17)
Pt—Ce1—Ce3iv124.510 (18)In1x—Ce3—Ce1ii62.257 (19)
In1ii—Ce1—Ce3iv135.05 (2)In1—Ce3—Ce1ii117.743 (19)
In1iii—Ce1—Ce3iv135.05 (2)In1xi—Ce3—Ce1ii62.257 (19)
In2—Ce1—Ce3iv59.56 (2)In1i—Ce3—Ce1ii117.743 (19)
In2i—Ce1—Ce3iv59.56 (2)In2iii—Ce3—Ce1ii59.790 (17)
Pti—Ce1—In1v170.60 (2)In2xii—Ce3—Ce1ii120.210 (17)
Pt—Ce1—In1v106.591 (19)In2ii—Ce3—Ce1ii59.790 (17)
In1ii—Ce1—In1v115.64 (2)In2xiii—Ce3—Ce1ii120.210 (17)
In1iii—Ce1—In1v79.00 (3)Ce1xiii—Ce3—Ce1ii180.00 (2)
In2—Ce1—In1v80.98 (2)In1x—Ce3—Ce3viii124.969 (11)
In2i—Ce1—In1v116.63 (3)In1—Ce3—Ce3viii55.031 (11)
Ce3iv—Ce1—In1v57.065 (17)In1xi—Ce3—Ce3viii55.031 (11)
Pti—Ce1—In1vi106.591 (18)In1i—Ce3—Ce3viii124.969 (11)
Pt—Ce1—In1vi170.60 (2)In2iii—Ce3—Ce3viii56.098 (11)
In1ii—Ce1—In1vi79.00 (3)In2xii—Ce3—Ce3viii123.902 (11)
In1iii—Ce1—In1vi115.64 (2)In2ii—Ce3—Ce3viii123.902 (11)
In2—Ce1—In1vi116.63 (3)In2xiii—Ce3—Ce3viii56.098 (11)
In2i—Ce1—In1vi80.98 (2)Ce1xiii—Ce3—Ce3viii90.0
Ce3iv—Ce1—In1vi57.065 (17)Ce1ii—Ce3—Ce3viii90.0
In1v—Ce1—In1vi65.85 (2)In1x—Ce3—Ce3i55.031 (11)
Pti—Ce1—Ce1vii116.09 (3)In1—Ce3—Ce3i124.969 (11)
Pt—Ce1—Ce1vii116.09 (3)In1xi—Ce3—Ce3i124.969 (11)
In1ii—Ce1—Ce1vii60.27 (2)In1i—Ce3—Ce3i55.031 (11)
In1iii—Ce1—Ce1vii60.27 (2)In2iii—Ce3—Ce3i123.902 (11)
In2—Ce1—Ce1vii135.68 (2)In2xii—Ce3—Ce3i56.098 (11)
In2i—Ce1—Ce1vii135.68 (2)In2ii—Ce3—Ce3i56.098 (11)
Ce3iv—Ce1—Ce1vii97.02 (3)In2xiii—Ce3—Ce3i123.902 (11)
In1v—Ce1—Ce1vii55.37 (2)Ce1xiii—Ce3—Ce3i90.0
In1vi—Ce1—Ce1vii55.37 (2)Ce1ii—Ce3—Ce3i90.0
Pti—Ce1—Ce252.378 (17)Ce3viii—Ce3—Ce3i180.0
Pt—Ce1—Ce252.378 (17)In2iii—Pt—Ce1viii139.222 (13)
In1ii—Ce1—Ce2105.77 (2)In2iii—Pt—Ce1139.222 (13)
In1iii—Ce1—Ce2105.77 (2)Ce1viii—Pt—Ce180.32 (3)
In2—Ce1—Ce256.542 (18)In2iii—Pt—In1iii126.71 (3)
In2i—Ce1—Ce256.542 (18)Ce1viii—Pt—In1iii68.29 (2)
Ce3iv—Ce1—Ce2100.86 (2)Ce1—Pt—In1iii68.29 (2)
In1v—Ce1—Ce2136.93 (2)In2iii—Pt—Ce2ii69.85 (2)
In1vi—Ce1—Ce2136.93 (2)Ce1viii—Pt—Ce2ii137.82 (3)
Ce1vii—Ce1—Ce2162.12 (3)Ce1—Pt—Ce2ii85.622 (19)
Pti—Ce1—Ce1viii130.161 (13)In1iii—Pt—Ce2ii69.56 (2)
Pt—Ce1—Ce1viii49.839 (13)In2iii—Pt—Ce2iii69.85 (2)
In1ii—Ce1—Ce1viii125.001 (13)Ce1viii—Pt—Ce2iii85.622 (19)
In1iii—Ce1—Ce1viii54.999 (13)Ce1—Pt—Ce2iii137.82 (3)
In2—Ce1—Ce1viii56.188 (12)In1iii—Pt—Ce2iii69.56 (2)
In2i—Ce1—Ce1viii123.812 (12)Ce2ii—Pt—Ce2iii78.65 (3)
Ce3iv—Ce1—Ce1viii90.0In2iii—Pt—Ce2viii70.06 (2)
In1v—Ce1—Ce1viii57.077 (12)Ce1viii—Pt—Ce2viii77.44 (2)
In1vi—Ce1—Ce1viii122.923 (12)Ce1—Pt—Ce2viii126.10 (3)
Ce1vii—Ce1—Ce1viii90.0In1iii—Pt—Ce2viii140.040 (13)
Ce2—Ce1—Ce1viii90.0Ce2ii—Pt—Ce2viii139.896 (19)
Pti—Ce1—Ce1i49.839 (13)Ce2iii—Pt—Ce2viii88.407 (15)
Pt—Ce1—Ce1i130.161 (13)In2iii—Pt—Ce270.06 (2)
In1ii—Ce1—Ce1i54.999 (13)Ce1viii—Pt—Ce2126.10 (3)
In1iii—Ce1—Ce1i125.001 (13)Ce1—Pt—Ce277.44 (2)
In2—Ce1—Ce1i123.812 (12)In1iii—Pt—Ce2140.040 (13)
In2i—Ce1—Ce1i56.188 (12)Ce2ii—Pt—Ce288.407 (15)
Ce3iv—Ce1—Ce1i90.0Ce2iii—Pt—Ce2139.896 (19)
In1v—Ce1—Ce1i122.923 (12)Ce2viii—Pt—Ce277.43 (2)
In1vi—Ce1—Ce1i57.078 (12)In2iii—Pt—In2117.84 (3)
Ce1vii—Ce1—Ce1i90.0Ce1viii—Pt—In263.582 (18)
Ce2—Ce1—Ce1i90.0Ce1—Pt—In263.582 (18)
Ce1viii—Ce1—Ce1i180.00 (4)In1iii—Pt—In2115.44 (3)
Pti—Ce1—Ce2ii47.732 (14)Ce2ii—Pt—In2140.654 (13)
Pt—Ce1—Ce2ii47.732 (14)Ce2iii—Pt—In2140.654 (13)
In1ii—Ce1—Ce2ii53.93 (2)Ce2viii—Pt—In262.53 (2)
In1iii—Ce1—Ce2ii53.93 (2)Ce2—Pt—In262.53 (2)
In2—Ce1—Ce2ii109.56 (2)In2iii—Pt—Ptviii90.0
In2i—Ce1—Ce2ii109.56 (2)Ce1viii—Pt—Ptviii49.839 (13)
Ce3iv—Ce1—Ce2ii166.19 (2)Ce1—Pt—Ptviii130.161 (13)
In1v—Ce1—Ce2ii132.89 (2)In1iii—Pt—Ptviii90.0
In1vi—Ce1—Ce2ii132.89 (2)Ce2ii—Pt—Ptviii129.325 (12)
Ce1vii—Ce1—Ce2ii96.79 (3)Ce2iii—Pt—Ptviii50.675 (13)
Ce2—Ce1—Ce2ii65.333 (17)Ce2viii—Pt—Ptviii51.287 (12)
Ce1viii—Ce1—Ce2ii90.0Ce2—Pt—Ptviii128.713 (12)
Ce1i—Ce1—Ce2ii90.0In2—Pt—Ptviii90.0
Ptix—Ce2—Ptiv78.65 (3)In2iii—Pt—Pti90.0
Ptix—Ce2—Pti158.86 (3)Ce1viii—Pt—Pti130.161 (13)
Ptiv—Ce2—Pti98.047 (16)Ce1—Pt—Pti49.839 (13)
Ptix—Ce2—Pt98.047 (16)In1iii—Pt—Pti90.0
Ptiv—Ce2—Pt158.86 (3)Ce2ii—Pt—Pti50.675 (12)
Pti—Ce2—Pt77.43 (2)Ce2iii—Pt—Pti129.325 (13)
Ptix—Ce2—In1i97.48 (2)Ce2viii—Pt—Pti128.713 (12)
Ptiv—Ce2—In1i54.632 (18)Ce2—Pt—Pti51.287 (12)
Pti—Ce2—In1i97.42 (2)In2—Pt—Pti90.0
Pt—Ce2—In1i145.99 (3)Ptviii—Pt—Pti180.00 (4)
Ptix—Ce2—In154.632 (18)Ptix—In1—In2iii102.98 (3)
Ptiv—Ce2—In197.48 (2)Ptix—In1—Ce1ix55.719 (19)
Pti—Ce2—In1145.99 (3)In2iii—In1—Ce1ix134.91 (2)
Pt—Ce2—In197.42 (2)Ptix—In1—Ce1iv55.719 (19)
In1i—Ce2—In168.03 (3)In2iii—In1—Ce1iv134.91 (2)
Ptix—Ce2—In254.35 (2)Ce1ix—In1—Ce1iv70.00 (3)
Ptiv—Ce2—In297.17 (3)Ptix—In1—Ce3139.720 (18)
Pti—Ce2—In2106.08 (3)In2iii—In1—Ce362.43 (2)
Pt—Ce2—In265.08 (2)Ce1ix—In1—Ce3159.45 (3)
In1i—Ce2—In2145.92 (3)Ce1iv—In1—Ce3106.194 (17)
In1—Ce2—In2101.74 (2)Ptix—In1—Ce3viii139.720 (18)
Ptix—Ce2—In2i97.17 (3)In2iii—In1—Ce3viii62.43 (2)
Ptiv—Ce2—In2i54.35 (2)Ce1ix—In1—Ce3viii106.194 (17)
Pti—Ce2—In2i65.08 (2)Ce1iv—In1—Ce3viii159.45 (3)
Pt—Ce2—In2i106.08 (3)Ce3—In1—Ce3viii69.94 (2)
In1i—Ce2—In2i101.74 (2)Ptix—In1—Ce2viii55.81 (2)
In1—Ce2—In2i145.92 (3)In2iii—In1—Ce2viii62.12 (2)
In2—Ce2—In2i67.89 (3)Ce1ix—In1—Ce2viii74.04 (2)
Ptix—Ce2—In2ii147.23 (3)Ce1iv—In1—Ce2viii111.52 (3)
Ptiv—Ce2—In2ii98.04 (2)Ce3—In1—Ce2viii124.54 (3)
Pti—Ce2—In2ii53.71 (2)Ce3viii—In1—Ce2viii85.74 (2)
Pt—Ce2—In2ii95.74 (3)Ptix—In1—Ce255.81 (2)
In1i—Ce2—In2ii56.95 (2)In2iii—In1—Ce262.12 (2)
In1—Ce2—In2ii94.21 (3)Ce1ix—In1—Ce2111.52 (3)
In2—Ce2—In2ii156.27 (3)Ce1iv—In1—Ce274.04 (2)
In2i—Ce2—In2ii107.324 (18)Ce3—In1—Ce285.74 (2)
Ptix—Ce2—In2iii98.04 (2)Ce3viii—In1—Ce2124.54 (3)
Ptiv—Ce2—In2iii147.23 (3)Ce2viii—In1—Ce268.03 (3)
Pti—Ce2—In2iii95.74 (3)Ptix—In1—Ce1xiii119.90 (3)
Pt—Ce2—In2iii53.71 (2)In2iii—In1—Ce1xiii123.11 (3)
In1i—Ce2—In2iii94.21 (3)Ce1ix—In1—Ce1xiii101.00 (3)
In1—Ce2—In2iii56.95 (2)Ce1iv—In1—Ce1xiii64.36 (2)
In2—Ce2—In2iii107.324 (18)Ce3—In1—Ce1xiii60.678 (17)
In2i—Ce2—In2iii156.27 (3)Ce3viii—In1—Ce1xiii97.66 (3)
In2ii—Ce2—In2iii67.16 (2)Ce2viii—In1—Ce1xiii174.67 (3)
Ptix—Ce2—Ce1111.18 (2)Ce2—In1—Ce1xiii112.804 (18)
Ptiv—Ce2—Ce1111.18 (2)Ptix—In1—Ce1xiv119.90 (3)
Pti—Ce2—Ce150.183 (14)In2iii—In1—Ce1xiv123.11 (3)
Pt—Ce2—Ce150.183 (14)Ce1ix—In1—Ce1xiv64.36 (2)
In1i—Ce2—Ce1145.290 (14)Ce1iv—In1—Ce1xiv101.00 (3)
In1—Ce2—Ce1145.290 (14)Ce3—In1—Ce1xiv97.66 (3)
In2—Ce2—Ce156.84 (2)Ce3viii—In1—Ce1xiv60.678 (17)
In2i—Ce2—Ce156.84 (2)Ce2viii—In1—Ce1xiv112.804 (18)
In2ii—Ce2—Ce1100.48 (2)Ce2—In1—Ce1xiv174.67 (3)
In2iii—Ce2—Ce1100.48 (2)Ce1xiii—In1—Ce1xiv65.85 (2)
Ptix—Ce2—Ce2viii50.675 (13)Ptix—In2—In1ix102.47 (3)
Ptiv—Ce2—Ce2viii129.325 (12)Ptix—In2—Ce255.81 (2)
Pti—Ce2—Ce2viii128.713 (12)In1ix—In2—Ce2135.83 (2)
Pt—Ce2—Ce2viii51.287 (12)Ptix—In2—Ce2viii55.81 (2)
In1i—Ce2—Ce2viii124.016 (13)In1ix—In2—Ce2viii135.83 (2)
In1—Ce2—Ce2viii55.984 (13)Ce2—In2—Ce2viii67.89 (3)
In2—Ce2—Ce2viii56.057 (13)Ptix—In2—Ce3ix138.75 (2)
In2i—Ce2—Ce2viii123.943 (13)In1ix—In2—Ce3ix59.618 (19)
In2ii—Ce2—Ce2viii123.581 (12)Ce2—In2—Ce3ix161.54 (3)
In2iii—Ce2—Ce2viii56.419 (12)Ce2viii—In2—Ce3ix109.006 (18)
Ce1—Ce2—Ce2viii90.0Ptix—In2—Ce3iv138.75 (2)
Ptix—Ce2—Ce2i129.325 (13)In1ix—In2—Ce3iv59.618 (19)
Ptiv—Ce2—Ce2i50.675 (13)Ce2—In2—Ce3iv109.006 (18)
Pti—Ce2—Ce2i51.287 (12)Ce2viii—In2—Ce3iv161.54 (3)
Pt—Ce2—Ce2i128.713 (12)Ce3ix—In2—Ce3iv67.80 (2)
In1i—Ce2—Ce2i55.984 (13)Ptix—In2—Ce1122.41 (3)
In1—Ce2—Ce2i124.016 (13)In1ix—In2—Ce1120.27 (3)
In2—Ce2—Ce2i123.943 (13)Ce2—In2—Ce166.62 (2)
In2i—Ce2—Ce2i56.057 (13)Ce2viii—In2—Ce1102.98 (3)
In2ii—Ce2—Ce2i56.419 (12)Ce3ix—In2—Ce197.51 (3)
In2iii—Ce2—Ce2i123.581 (12)Ce3iv—In2—Ce160.650 (17)
Ce1—Ce2—Ce2i90.0Ptix—In2—Ce1viii122.41 (3)
Ce2viii—Ce2—Ce2i180.00 (5)In1ix—In2—Ce1viii120.27 (3)
Ptix—Ce2—Ce1iv46.647 (15)Ce2—In2—Ce1viii102.98 (3)
Ptiv—Ce2—Ce1iv46.647 (15)Ce2viii—In2—Ce1viii66.62 (2)
Pti—Ce2—Ce1iv141.287 (12)Ce3ix—In2—Ce1viii60.650 (17)
Pt—Ce2—Ce1iv141.287 (12)Ce3iv—In2—Ce1viii97.51 (3)
In1i—Ce2—Ce1iv52.031 (18)Ce1—In2—Ce1viii67.62 (2)
In1—Ce2—Ce1iv52.031 (18)Ptix—In2—Ce2ix56.237 (19)
In2—Ce2—Ce1iv95.42 (3)In1ix—In2—Ce2ix60.93 (2)
In2i—Ce2—Ce1iv95.42 (3)Ce2—In2—Ce2ix112.04 (3)
In2ii—Ce2—Ce1iv108.26 (2)Ce2viii—In2—Ce2ix75.970 (17)
In2iii—Ce2—Ce1iv108.26 (2)Ce3ix—In2—Ce2ix83.75 (2)
Ce1—Ce2—Ce1iv145.29 (3)Ce3iv—In2—Ce2ix120.54 (3)
Ce2viii—Ce2—Ce1iv90.0Ce1—In2—Ce2ix178.60 (3)
Ce2i—Ce2—Ce1iv90.0Ce1viii—In2—Ce2ix112.589 (16)
In1x—Ce3—In1180.00 (3)Ptix—In2—Ce2iv56.237 (19)
In1x—Ce3—In1xi69.94 (2)In1ix—In2—Ce2iv60.93 (2)
In1—Ce3—In1xi110.06 (2)Ce2—In2—Ce2iv75.970 (17)
In1x—Ce3—In1i110.06 (2)Ce2viii—In2—Ce2iv112.04 (3)
In1—Ce3—In1i69.94 (2)Ce3ix—In2—Ce2iv120.54 (3)
In1xi—Ce3—In1i180.00 (3)Ce3iv—In2—Ce2iv83.75 (2)
In1x—Ce3—In2iii122.05 (2)Ce1—In2—Ce2iv112.589 (16)
In1—Ce3—In2iii57.95 (2)Ce1viii—In2—Ce2iv178.60 (3)
In1xi—Ce3—In2iii83.76 (2)Ce2ix—In2—Ce2iv67.16 (2)
In1i—Ce3—In2iii96.24 (2)Ptix—In2—Pt89.99 (3)
In1x—Ce3—In2xii57.95 (2)In1ix—In2—Pt167.53 (3)
In1—Ce3—In2xii122.05 (2)Ce2—In2—Pt52.387 (17)
In1xi—Ce3—In2xii96.24 (2)Ce2viii—In2—Pt52.387 (17)
In1i—Ce3—In2xii83.76 (2)Ce3ix—In2—Pt110.60 (2)
In2iii—Ce3—In2xii180.00 (4)Ce3iv—In2—Pt110.60 (2)
In1x—Ce3—In2ii83.76 (2)Ce1—In2—Pt50.599 (18)
In1—Ce3—In2ii96.24 (2)Ce1viii—In2—Pt50.599 (18)
In1xi—Ce3—In2ii122.05 (2)Ce2ix—In2—Pt128.36 (2)
In1i—Ce3—In2ii57.95 (2)Ce2iv—In2—Pt128.36 (2)
In2iii—Ce3—In2ii67.80 (2)
Symmetry codes: (i) x, y, z1; (ii) x1/2, y+1/2, z; (iii) x1/2, y+1/2, z+1; (iv) x+1/2, y+1/2, z; (v) x+1/2, y+1/2, z; (vi) x+1/2, y+1/2, z1; (vii) x, y+1, z; (viii) x, y, z+1; (ix) x+1/2, y+1/2, z+1; (x) x, y, z; (xi) x, y, z+1; (xii) x+1/2, y1/2, z1; (xiii) x+1/2, y1/2, z; (xiv) x+1/2, y1/2, z+1.
 

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