Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806000523/wk6072sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806000523/wk6072Isup2.hkl |
CCDC reference: 298562
Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.
[Rh2(C5H4N)2(C8H12)2] | F(000) = 1232 |
Mr = 610.36 | Dx = 1.747 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
a = 13.9304 (7) Å | Cell parameters from 6511 reflections |
b = 12.0102 (6) Å | θ = 2.2–24.7° |
c = 14.1320 (7) Å | µ = 1.45 mm−1 |
β = 101.015 (1)° | T = 146 K |
V = 2320.8 (2) Å3 | Block, orange-red |
Z = 4 | 0.33 × 0.19 × 0.16 mm |
Bruker SMART 1K CCD diffractometer | 3802 independent reflections |
Radiation source: fine-focus sealed tube | 3334 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.068 |
ω scans | θmax = 24.7°, θmin = 2.2° |
Absorption correction: multi-scan (Blessing, 1995) | h = −16→13 |
Tmin = 0.647, Tmax = 0.801 | k = −13→13 |
10107 measured reflections | l = −15→16 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.032 | Hydrogen site location: geom and difmap |
wR(F2) = 0.082 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.00 | w = 1/[σ2(Fo2) + (0.056P)2] where P = (Fo2 + 2Fc2)/3 |
3802 reflections | (Δ/σ)max = 0.001 |
321 parameters | Δρmax = 0.53 e Å−3 |
0 restraints | Δρmin = −1.29 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Rh1 | 0.641066 (19) | 0.22054 (2) | 0.927451 (17) | 0.01570 (11) | |
Rh2 | 0.806775 (19) | 0.38377 (2) | 0.834246 (18) | 0.01645 (11) | |
O1 | 0.76655 (18) | 0.2799 (2) | 1.01752 (16) | 0.0210 (6) | |
O2 | 0.73320 (18) | 0.26027 (18) | 0.74591 (15) | 0.0184 (5) | |
N1 | 0.8551 (2) | 0.2423 (2) | 1.0054 (2) | 0.0182 (6) | |
N2 | 0.7456 (2) | 0.1522 (2) | 0.77256 (19) | 0.0154 (6) | |
C1 | 0.5647 (3) | 0.2702 (3) | 1.0428 (3) | 0.0222 (8) | |
H1 | 0.616 (3) | 0.272 (3) | 1.096 (3) | 0.019 (10)* | |
C2 | 0.5552 (3) | 0.3567 (3) | 0.9758 (2) | 0.0217 (8) | |
H2 | 0.608 (3) | 0.409 (3) | 0.990 (3) | 0.023 (10)* | |
C3 | 0.4624 (3) | 0.3799 (3) | 0.9025 (3) | 0.0267 (9) | |
H3A | 0.4559 | 0.4612 | 0.8915 | 0.032* | |
H3B | 0.4052 | 0.3545 | 0.9289 | 0.032* | |
C4 | 0.4621 (3) | 0.3210 (3) | 0.8054 (2) | 0.0248 (8) | |
H4A | 0.3936 | 0.3048 | 0.7744 | 0.030* | |
H4B | 0.4895 | 0.3723 | 0.7626 | 0.030* | |
C5 | 0.5197 (3) | 0.2138 (3) | 0.8146 (2) | 0.0206 (8) | |
H5 | 0.543 (3) | 0.191 (3) | 0.756 (3) | 0.022 (10)* | |
C6 | 0.5117 (3) | 0.1291 (3) | 0.8815 (2) | 0.0197 (8) | |
H6 | 0.533 (3) | 0.056 (4) | 0.870 (3) | 0.041 (12)* | |
C7 | 0.4411 (3) | 0.1335 (3) | 0.9509 (3) | 0.0242 (8) | |
H7A | 0.4185 | 0.0571 | 0.9612 | 0.029* | |
H7B | 0.3832 | 0.1781 | 0.9218 | 0.029* | |
C8 | 0.4877 (3) | 0.1847 (3) | 1.0491 (2) | 0.0260 (8) | |
H8A | 0.4356 | 0.2197 | 1.0778 | 0.031* | |
H8B | 0.5171 | 0.1243 | 1.0929 | 0.031* | |
C9 | 0.7135 (3) | 0.1158 (3) | 0.8533 (2) | 0.0166 (7) | |
C10 | 0.7295 (3) | 0.0022 (3) | 0.8730 (2) | 0.0205 (8) | |
H10 | 0.7099 | −0.0282 | 0.9284 | 0.025* | |
C11 | 0.7725 (3) | −0.0675 (3) | 0.8152 (3) | 0.0228 (8) | |
H11 | 0.7837 | −0.1437 | 0.8317 | 0.027* | |
C12 | 0.7992 (3) | −0.0247 (3) | 0.7328 (3) | 0.0249 (8) | |
H12 | 0.8271 | −0.0717 | 0.6912 | 0.030* | |
C13 | 0.7848 (3) | 0.0857 (3) | 0.7123 (2) | 0.0204 (8) | |
H13 | 0.8022 | 0.1160 | 0.6558 | 0.024* | |
C14 | 0.9029 (3) | 0.1763 (3) | 1.0759 (2) | 0.0225 (8) | |
H14 | 0.8742 | 0.1590 | 1.1299 | 0.027* | |
C15 | 0.9923 (3) | 0.1341 (3) | 1.0701 (3) | 0.0260 (9) | |
H15 | 1.0258 | 0.0861 | 1.1189 | 0.031* | |
C16 | 1.0337 (3) | 0.1626 (3) | 0.9913 (3) | 0.0251 (8) | |
H16 | 1.0961 | 0.1345 | 0.9855 | 0.030* | |
C17 | 0.9831 (3) | 0.2319 (3) | 0.9217 (2) | 0.0212 (8) | |
H17 | 1.0120 | 0.2509 | 0.8682 | 0.025* | |
C18 | 0.8902 (3) | 0.2764 (3) | 0.9263 (2) | 0.0178 (8) | |
C19 | 0.8464 (3) | 0.5092 (3) | 0.9363 (3) | 0.0262 (8) | |
H19 | 0.871 (3) | 0.478 (3) | 1.000 (3) | 0.015 (9)* | |
C20 | 0.9099 (3) | 0.5111 (3) | 0.8701 (3) | 0.0283 (9) | |
H20 | 0.969 (3) | 0.480 (3) | 0.887 (3) | 0.019 (9)* | |
C21 | 0.9060 (4) | 0.5978 (4) | 0.7926 (3) | 0.0534 (14) | |
H21A | 0.8959 | 0.6714 | 0.8207 | 0.064* | |
H21B | 0.9703 | 0.5996 | 0.7726 | 0.064* | |
C22 | 0.8298 (4) | 0.5816 (4) | 0.7063 (3) | 0.0467 (12) | |
H22A | 0.8620 | 0.5603 | 0.6523 | 0.056* | |
H22B | 0.7969 | 0.6539 | 0.6894 | 0.056* | |
C23 | 0.7526 (3) | 0.4959 (3) | 0.7138 (3) | 0.0255 (8) | |
H23 | 0.737 (3) | 0.451 (3) | 0.664 (3) | 0.028 (11)* | |
C24 | 0.6908 (3) | 0.5014 (3) | 0.7777 (3) | 0.0246 (8) | |
H24 | 0.633 (3) | 0.454 (3) | 0.772 (2) | 0.014 (9)* | |
C25 | 0.6883 (4) | 0.5949 (4) | 0.8484 (3) | 0.0437 (12) | |
H25A | 0.6947 | 0.6663 | 0.8153 | 0.052* | |
H25B | 0.6235 | 0.5947 | 0.8674 | 0.052* | |
C26 | 0.7645 (3) | 0.5907 (4) | 0.9370 (4) | 0.0478 (13) | |
H26A | 0.7326 | 0.5722 | 0.9919 | 0.057* | |
H26B | 0.7932 | 0.6660 | 0.9489 | 0.057* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Rh1 | 0.01333 (17) | 0.02128 (18) | 0.01199 (16) | 0.00158 (10) | 0.00117 (11) | −0.00191 (10) |
Rh2 | 0.01531 (17) | 0.01777 (18) | 0.01507 (17) | 0.00113 (10) | −0.00015 (12) | −0.00025 (10) |
O1 | 0.0141 (13) | 0.0321 (15) | 0.0163 (12) | 0.0023 (10) | 0.0016 (10) | −0.0030 (10) |
O2 | 0.0229 (14) | 0.0164 (12) | 0.0145 (12) | 0.0024 (10) | 0.0000 (10) | 0.0011 (10) |
N1 | 0.0113 (15) | 0.0219 (15) | 0.0206 (15) | 0.0012 (12) | 0.0009 (12) | −0.0029 (12) |
N2 | 0.0160 (15) | 0.0164 (15) | 0.0126 (14) | −0.0009 (12) | −0.0005 (11) | −0.0010 (11) |
C1 | 0.020 (2) | 0.030 (2) | 0.0165 (18) | 0.0025 (16) | 0.0045 (16) | −0.0093 (15) |
C2 | 0.022 (2) | 0.024 (2) | 0.0188 (19) | 0.0007 (16) | 0.0034 (15) | −0.0063 (15) |
C3 | 0.026 (2) | 0.025 (2) | 0.030 (2) | 0.0066 (16) | 0.0073 (17) | −0.0051 (16) |
C4 | 0.022 (2) | 0.030 (2) | 0.0203 (18) | 0.0040 (16) | −0.0017 (15) | 0.0008 (16) |
C5 | 0.0152 (19) | 0.029 (2) | 0.0158 (18) | 0.0028 (15) | −0.0008 (15) | −0.0066 (15) |
C6 | 0.0165 (19) | 0.024 (2) | 0.0186 (18) | −0.0033 (15) | 0.0025 (15) | −0.0057 (15) |
C7 | 0.019 (2) | 0.032 (2) | 0.0220 (19) | −0.0002 (16) | 0.0042 (15) | −0.0014 (15) |
C8 | 0.026 (2) | 0.034 (2) | 0.0198 (19) | 0.0002 (17) | 0.0063 (16) | −0.0034 (16) |
C9 | 0.0129 (18) | 0.0209 (19) | 0.0146 (17) | −0.0027 (14) | −0.0005 (14) | 0.0000 (13) |
C10 | 0.0166 (18) | 0.0254 (19) | 0.0186 (17) | 0.0019 (15) | 0.0007 (14) | 0.0046 (15) |
C11 | 0.0183 (19) | 0.0187 (19) | 0.029 (2) | −0.0002 (15) | −0.0017 (15) | −0.0009 (15) |
C12 | 0.022 (2) | 0.028 (2) | 0.0241 (19) | 0.0056 (16) | 0.0037 (15) | −0.0070 (16) |
C13 | 0.0207 (19) | 0.027 (2) | 0.0138 (17) | 0.0017 (15) | 0.0042 (14) | −0.0030 (15) |
C14 | 0.021 (2) | 0.028 (2) | 0.0168 (17) | −0.0035 (16) | −0.0021 (14) | 0.0015 (15) |
C15 | 0.025 (2) | 0.0242 (19) | 0.026 (2) | 0.0033 (16) | −0.0024 (16) | 0.0077 (16) |
C16 | 0.0152 (19) | 0.030 (2) | 0.029 (2) | 0.0085 (16) | 0.0003 (15) | −0.0012 (16) |
C17 | 0.0181 (19) | 0.028 (2) | 0.0175 (18) | 0.0015 (15) | 0.0036 (15) | −0.0018 (15) |
C18 | 0.0197 (19) | 0.0169 (18) | 0.0161 (17) | −0.0035 (14) | 0.0016 (15) | −0.0029 (13) |
C19 | 0.028 (2) | 0.025 (2) | 0.0229 (19) | −0.0015 (17) | −0.0024 (16) | −0.0076 (16) |
C20 | 0.017 (2) | 0.031 (2) | 0.034 (2) | −0.0010 (17) | −0.0016 (17) | −0.0020 (17) |
C21 | 0.049 (3) | 0.056 (3) | 0.050 (3) | −0.031 (3) | −0.003 (2) | 0.012 (2) |
C22 | 0.043 (3) | 0.047 (3) | 0.049 (3) | −0.011 (2) | 0.005 (2) | 0.023 (2) |
C23 | 0.030 (2) | 0.023 (2) | 0.023 (2) | 0.0009 (17) | 0.0020 (17) | 0.0053 (17) |
C24 | 0.021 (2) | 0.026 (2) | 0.025 (2) | 0.0069 (17) | 0.0017 (16) | 0.0055 (16) |
C25 | 0.045 (3) | 0.046 (3) | 0.037 (2) | 0.025 (2) | 0.000 (2) | −0.007 (2) |
C26 | 0.033 (3) | 0.049 (3) | 0.057 (3) | 0.006 (2) | −0.003 (2) | −0.030 (2) |
Rh1—Rh2 | 3.4740 (4) | C8—H8B | 0.9900 |
Rh1—C9 | 2.026 (3) | C9—C10 | 1.401 (5) |
Rh1—O1 | 2.082 (2) | C10—C11 | 1.384 (5) |
Rh1—C5 | 2.093 (3) | C10—H10 | 0.9500 |
Rh1—C6 | 2.104 (4) | C11—C12 | 1.387 (5) |
Rh1—C1 | 2.192 (3) | C11—H11 | 0.9500 |
Rh1—C2 | 2.210 (4) | C12—C13 | 1.364 (5) |
Rh2—C18 | 2.032 (3) | C12—H12 | 0.9500 |
Rh2—O2 | 2.078 (2) | C13—H13 | 0.9500 |
Rh2—C19 | 2.086 (4) | C14—C15 | 1.362 (5) |
Rh2—C20 | 2.093 (4) | C14—H14 | 0.9500 |
Rh2—C24 | 2.180 (4) | C15—C16 | 1.391 (5) |
Rh2—C23 | 2.188 (4) | C15—H15 | 0.9500 |
O1—N1 | 1.354 (4) | C16—C17 | 1.375 (5) |
O2—N2 | 1.353 (3) | C16—H16 | 0.9500 |
N1—C14 | 1.345 (5) | C17—C18 | 1.413 (5) |
N1—C18 | 1.366 (5) | C17—H17 | 0.9500 |
N2—C13 | 1.356 (4) | C19—C20 | 1.406 (6) |
N2—C9 | 1.374 (4) | C19—C26 | 1.503 (6) |
C1—C2 | 1.395 (5) | C19—H19 | 0.98 (3) |
C1—C8 | 1.501 (5) | C20—C21 | 1.504 (6) |
C1—H1 | 0.93 (4) | C20—H20 | 0.90 (4) |
C2—C3 | 1.520 (5) | C21—C22 | 1.469 (6) |
C2—H2 | 0.96 (4) | C21—H21A | 0.9900 |
C3—C4 | 1.543 (5) | C21—H21B | 0.9900 |
C3—H3A | 0.9900 | C22—C23 | 1.507 (6) |
C3—H3B | 0.9900 | C22—H22A | 0.9900 |
C4—C5 | 1.510 (5) | C22—H22B | 0.9900 |
C4—H4A | 0.9900 | C23—C24 | 1.363 (5) |
C4—H4B | 0.9900 | C23—H23 | 0.89 (4) |
C5—C6 | 1.408 (5) | C24—C25 | 1.509 (6) |
C5—H5 | 0.98 (4) | C24—H24 | 0.98 (4) |
C6—C7 | 1.516 (5) | C25—C26 | 1.479 (6) |
C6—H6 | 0.95 (5) | C25—H25A | 0.9900 |
C7—C8 | 1.544 (5) | C25—H25B | 0.9900 |
C7—H7A | 0.9900 | C26—H26A | 0.9900 |
C7—H7B | 0.9900 | C26—H26B | 0.9900 |
C8—H8A | 0.9900 | ||
C9—Rh1—O1 | 94.94 (12) | C7—C8—H8A | 108.8 |
C9—Rh1—C5 | 89.50 (14) | C1—C8—H8B | 108.8 |
O1—Rh1—C5 | 160.22 (12) | C7—C8—H8B | 108.8 |
C9—Rh1—C6 | 89.89 (14) | H8A—C8—H8B | 107.7 |
O1—Rh1—C6 | 159.56 (12) | N2—C9—C10 | 114.3 (3) |
C5—Rh1—C6 | 39.19 (14) | N2—C9—Rh1 | 120.3 (2) |
C9—Rh1—C1 | 156.07 (14) | C10—C9—Rh1 | 125.3 (3) |
O1—Rh1—C1 | 85.53 (12) | C11—C10—C9 | 122.8 (3) |
C5—Rh1—C1 | 98.12 (14) | C11—C10—H10 | 118.6 |
C6—Rh1—C1 | 82.12 (14) | C9—C10—H10 | 118.6 |
C9—Rh1—C2 | 166.41 (13) | C10—C11—C12 | 119.2 (3) |
O1—Rh1—C2 | 89.91 (12) | C10—C11—H11 | 120.4 |
C5—Rh1—C2 | 81.83 (14) | C12—C11—H11 | 120.4 |
C6—Rh1—C2 | 89.95 (15) | C13—C12—C11 | 119.1 (3) |
C1—Rh1—C2 | 36.94 (14) | C13—C12—H12 | 120.5 |
C18—Rh2—O2 | 95.01 (11) | C11—C12—H12 | 120.5 |
C18—Rh2—C19 | 88.45 (14) | N2—C13—C12 | 120.0 (3) |
O2—Rh2—C19 | 164.95 (13) | N2—C13—H13 | 120.0 |
C18—Rh2—C20 | 91.54 (15) | C12—C13—H13 | 120.0 |
O2—Rh2—C20 | 154.63 (13) | N1—C14—C15 | 120.3 (3) |
C19—Rh2—C20 | 39.32 (16) | N1—C14—H14 | 119.9 |
C18—Rh2—C24 | 159.93 (14) | C15—C14—H14 | 119.9 |
O2—Rh2—C24 | 89.79 (12) | C14—C15—C16 | 118.7 (3) |
C19—Rh2—C24 | 82.23 (15) | C14—C15—H15 | 120.6 |
C20—Rh2—C24 | 92.40 (16) | C16—C15—H15 | 120.6 |
C18—Rh2—C23 | 163.48 (15) | C17—C16—C15 | 119.2 (3) |
O2—Rh2—C23 | 85.11 (12) | C17—C16—H16 | 120.4 |
C19—Rh2—C23 | 95.71 (15) | C15—C16—H16 | 120.4 |
C20—Rh2—C23 | 81.81 (15) | C16—C17—C18 | 123.0 (3) |
C24—Rh2—C23 | 36.35 (14) | C16—C17—H17 | 118.5 |
N1—O1—Rh1 | 119.14 (19) | C18—C17—H17 | 118.5 |
N2—O2—Rh2 | 119.68 (18) | N1—C18—C17 | 113.5 (3) |
C14—N1—O1 | 115.9 (3) | N1—C18—Rh2 | 117.7 (2) |
C14—N1—C18 | 125.3 (3) | C17—C18—Rh2 | 128.9 (3) |
O1—N1—C18 | 118.7 (3) | C20—C19—C26 | 124.7 (4) |
O2—N2—C13 | 115.8 (3) | C20—C19—Rh2 | 70.6 (2) |
O2—N2—C9 | 119.5 (3) | C26—C19—Rh2 | 111.9 (3) |
C13—N2—C9 | 124.6 (3) | C20—C19—H19 | 118 (2) |
C2—C1—C8 | 125.0 (3) | C26—C19—H19 | 112 (2) |
C2—C1—Rh1 | 72.2 (2) | Rh2—C19—H19 | 111 (2) |
C8—C1—Rh1 | 108.2 (2) | C19—C20—C21 | 123.7 (4) |
C2—C1—H1 | 119 (2) | C19—C20—Rh2 | 70.1 (2) |
C8—C1—H1 | 115 (2) | C21—C20—Rh2 | 113.7 (3) |
Rh1—C1—H1 | 101 (2) | C19—C20—H20 | 119 (2) |
C1—C2—C3 | 123.9 (4) | C21—C20—H20 | 113 (2) |
C1—C2—Rh1 | 70.8 (2) | Rh2—C20—H20 | 108 (2) |
C3—C2—Rh1 | 111.4 (2) | C22—C21—C20 | 115.6 (4) |
C1—C2—H2 | 112 (2) | C22—C21—H21A | 108.4 |
C3—C2—H2 | 123 (2) | C20—C21—H21A | 108.4 |
Rh1—C2—H2 | 96 (2) | C22—C21—H21B | 108.4 |
C2—C3—C4 | 112.3 (3) | C20—C21—H21B | 108.4 |
C2—C3—H3A | 109.1 | H21A—C21—H21B | 107.4 |
C4—C3—H3A | 109.1 | C21—C22—C23 | 116.3 (4) |
C2—C3—H3B | 109.1 | C21—C22—H22A | 108.2 |
C4—C3—H3B | 109.1 | C23—C22—H22A | 108.2 |
H3A—C3—H3B | 107.9 | C21—C22—H22B | 108.2 |
C5—C4—C3 | 113.8 (3) | C23—C22—H22B | 108.2 |
C5—C4—H4A | 108.8 | H22A—C22—H22B | 107.4 |
C3—C4—H4A | 108.8 | C24—C23—C22 | 124.3 (4) |
C5—C4—H4B | 108.8 | C24—C23—Rh2 | 71.5 (2) |
C3—C4—H4B | 108.8 | C22—C23—Rh2 | 109.3 (3) |
H4A—C4—H4B | 107.7 | C24—C23—H23 | 118 (3) |
C6—C5—C4 | 124.4 (3) | C22—C23—H23 | 115 (3) |
C6—C5—Rh1 | 70.9 (2) | Rh2—C23—H23 | 104 (3) |
C4—C5—Rh1 | 111.8 (2) | C23—C24—C25 | 124.9 (4) |
C6—C5—H5 | 117 (2) | C23—C24—Rh2 | 72.1 (2) |
C4—C5—H5 | 115 (2) | C25—C24—Rh2 | 110.4 (3) |
Rh1—C5—H5 | 107 (2) | C23—C24—H24 | 122 (2) |
C5—C6—C7 | 123.7 (3) | C25—C24—H24 | 112 (2) |
C5—C6—Rh1 | 70.0 (2) | Rh2—C24—H24 | 101 (2) |
C7—C6—Rh1 | 113.9 (2) | C26—C25—C24 | 115.6 (4) |
C5—C6—H6 | 119 (3) | C26—C25—H25A | 108.4 |
C7—C6—H6 | 114 (3) | C24—C25—H25A | 108.4 |
Rh1—C6—H6 | 105 (3) | C26—C25—H25B | 108.4 |
C6—C7—C8 | 112.5 (3) | C24—C25—H25B | 108.4 |
C6—C7—H7A | 109.1 | H25A—C25—H25B | 107.5 |
C8—C7—H7A | 109.1 | C25—C26—C19 | 116.1 (4) |
C6—C7—H7B | 109.1 | C25—C26—H26A | 108.3 |
C8—C7—H7B | 109.1 | C19—C26—H26A | 108.3 |
H7A—C7—H7B | 107.8 | C25—C26—H26B | 108.3 |
C1—C8—C7 | 113.6 (3) | C19—C26—H26B | 108.3 |
C1—C8—H8A | 108.8 | H26A—C26—H26B | 107.4 |
C9—Rh1—O1—N1 | 1.6 (2) | N2—C9—C10—C11 | −1.0 (5) |
C5—Rh1—O1—N1 | −100.8 (4) | Rh1—C9—C10—C11 | 174.6 (3) |
C6—Rh1—O1—N1 | 104.7 (4) | C9—C10—C11—C12 | −1.6 (5) |
C1—Rh1—O1—N1 | 157.6 (2) | C10—C11—C12—C13 | 1.8 (5) |
C2—Rh1—O1—N1 | −165.7 (2) | O2—N2—C13—C12 | −179.4 (3) |
C18—Rh2—O2—N2 | 7.8 (2) | C9—N2—C13—C12 | −3.4 (5) |
C19—Rh2—O2—N2 | −94.9 (5) | C11—C12—C13—N2 | 0.5 (5) |
C20—Rh2—O2—N2 | 112.2 (3) | O1—N1—C14—C15 | 179.8 (3) |
C24—Rh2—O2—N2 | −152.6 (2) | C18—N1—C14—C15 | −2.6 (5) |
C23—Rh2—O2—N2 | 171.3 (2) | N1—C14—C15—C16 | 1.4 (6) |
Rh1—O1—N1—C14 | −110.7 (3) | C14—C15—C16—C17 | −0.2 (6) |
Rh1—O1—N1—C18 | 71.6 (3) | C15—C16—C17—C18 | 0.0 (6) |
Rh2—O2—N2—C13 | −118.3 (3) | C14—N1—C18—C17 | 2.3 (5) |
Rh2—O2—N2—C9 | 65.5 (3) | O1—N1—C18—C17 | 179.8 (3) |
C9—Rh1—C1—C2 | −172.1 (3) | C14—N1—C18—Rh2 | −176.4 (3) |
O1—Rh1—C1—C2 | 95.8 (2) | O1—N1—C18—Rh2 | 1.1 (4) |
C5—Rh1—C1—C2 | −64.6 (2) | C16—C17—C18—N1 | −1.0 (5) |
C6—Rh1—C1—C2 | −100.5 (2) | C16—C17—C18—Rh2 | 177.5 (3) |
C9—Rh1—C1—C8 | −50.1 (5) | O2—Rh2—C18—N1 | −91.6 (3) |
O1—Rh1—C1—C8 | −142.3 (3) | C19—Rh2—C18—N1 | 73.7 (3) |
C5—Rh1—C1—C8 | 57.3 (3) | C20—Rh2—C18—N1 | 112.9 (3) |
C6—Rh1—C1—C8 | 21.4 (3) | C24—Rh2—C18—N1 | 11.6 (6) |
C2—Rh1—C1—C8 | 121.9 (4) | C23—Rh2—C18—N1 | 178.7 (4) |
C8—C1—C2—C3 | 3.2 (6) | O2—Rh2—C18—C17 | 90.0 (3) |
Rh1—C1—C2—C3 | 103.4 (3) | C19—Rh2—C18—C17 | −104.7 (3) |
C8—C1—C2—Rh1 | −100.2 (3) | C20—Rh2—C18—C17 | −65.5 (3) |
C9—Rh1—C2—C1 | 166.2 (5) | C24—Rh2—C18—C17 | −166.8 (4) |
O1—Rh1—C2—C1 | −82.7 (2) | C23—Rh2—C18—C17 | 0.3 (7) |
C5—Rh1—C2—C1 | 115.4 (2) | C18—Rh2—C19—C20 | 94.3 (2) |
C6—Rh1—C2—C1 | 76.9 (2) | O2—Rh2—C19—C20 | −162.0 (4) |
C9—Rh1—C2—C3 | 46.4 (7) | C24—Rh2—C19—C20 | −103.5 (3) |
O1—Rh1—C2—C3 | 157.5 (3) | C23—Rh2—C19—C20 | −69.6 (3) |
C5—Rh1—C2—C3 | −4.5 (3) | C18—Rh2—C19—C26 | −145.1 (3) |
C6—Rh1—C2—C3 | −42.9 (3) | O2—Rh2—C19—C26 | −41.5 (7) |
C1—Rh1—C2—C3 | −119.8 (4) | C20—Rh2—C19—C26 | 120.6 (4) |
C1—C2—C3—C4 | −92.6 (4) | C24—Rh2—C19—C26 | 17.1 (3) |
Rh1—C2—C3—C4 | −11.9 (4) | C23—Rh2—C19—C26 | 50.9 (3) |
C2—C3—C4—C5 | 29.5 (5) | C26—C19—C20—C21 | 2.0 (6) |
C3—C4—C5—C6 | 47.8 (5) | Rh2—C19—C20—C21 | 105.8 (4) |
C3—C4—C5—Rh1 | −33.3 (4) | C26—C19—C20—Rh2 | −103.8 (4) |
C9—Rh1—C5—C6 | 90.4 (2) | C18—Rh2—C20—C19 | −85.7 (2) |
O1—Rh1—C5—C6 | −166.2 (3) | O2—Rh2—C20—C19 | 169.2 (2) |
C1—Rh1—C5—C6 | −66.8 (2) | C24—Rh2—C20—C19 | 74.7 (2) |
C2—Rh1—C5—C6 | −100.0 (2) | C23—Rh2—C20—C19 | 109.5 (3) |
C9—Rh1—C5—C4 | −149.2 (3) | C18—Rh2—C20—C21 | 155.3 (4) |
O1—Rh1—C5—C4 | −45.9 (5) | O2—Rh2—C20—C21 | 50.2 (5) |
C6—Rh1—C5—C4 | 120.3 (4) | C19—Rh2—C20—C21 | −119.1 (5) |
C1—Rh1—C5—C4 | 53.5 (3) | C24—Rh2—C20—C21 | −44.4 (4) |
C2—Rh1—C5—C4 | 20.3 (3) | C23—Rh2—C20—C21 | −9.5 (4) |
C4—C5—C6—C7 | 2.1 (6) | C19—C20—C21—C22 | −79.5 (6) |
Rh1—C5—C6—C7 | 106.0 (3) | Rh2—C20—C21—C22 | 1.6 (6) |
C4—C5—C6—Rh1 | −103.8 (3) | C20—C21—C22—C23 | 12.3 (7) |
C9—Rh1—C6—C5 | −89.3 (2) | C21—C22—C23—C24 | 61.0 (7) |
O1—Rh1—C6—C5 | 166.7 (3) | C21—C22—C23—Rh2 | −19.3 (6) |
C1—Rh1—C6—C5 | 113.3 (2) | C18—Rh2—C23—C24 | −172.6 (4) |
C2—Rh1—C6—C5 | 77.1 (2) | O2—Rh2—C23—C24 | 96.3 (2) |
C9—Rh1—C6—C7 | 151.8 (3) | C19—Rh2—C23—C24 | −68.6 (3) |
O1—Rh1—C6—C7 | 47.8 (5) | C20—Rh2—C23—C24 | −105.5 (3) |
C5—Rh1—C6—C7 | −118.9 (4) | C18—Rh2—C23—C22 | −51.7 (6) |
C1—Rh1—C6—C7 | −5.6 (3) | O2—Rh2—C23—C22 | −142.9 (3) |
C2—Rh1—C6—C7 | −41.8 (3) | C19—Rh2—C23—C22 | 52.2 (3) |
C5—C6—C7—C8 | −92.3 (4) | C20—Rh2—C23—C22 | 15.3 (3) |
Rh1—C6—C7—C8 | −11.2 (4) | C24—Rh2—C23—C22 | 120.8 (4) |
C2—C1—C8—C7 | 46.9 (5) | C22—C23—C24—C25 | 1.7 (6) |
Rh1—C1—C8—C7 | −33.9 (4) | Rh2—C23—C24—C25 | 102.8 (4) |
C6—C7—C8—C1 | 30.6 (5) | C22—C23—C24—Rh2 | −101.2 (4) |
O2—N2—C9—C10 | 179.4 (3) | C18—Rh2—C24—C23 | 173.8 (3) |
C13—N2—C9—C10 | 3.5 (5) | O2—Rh2—C24—C23 | −82.0 (2) |
O2—N2—C9—Rh1 | 3.6 (4) | C19—Rh2—C24—C23 | 110.8 (3) |
C13—N2—C9—Rh1 | −172.3 (3) | C20—Rh2—C24—C23 | 72.7 (3) |
O1—Rh1—C9—N2 | −89.1 (3) | C18—Rh2—C24—C25 | 52.4 (6) |
C5—Rh1—C9—N2 | 71.6 (3) | O2—Rh2—C24—C25 | 156.5 (3) |
C6—Rh1—C9—N2 | 110.8 (3) | C19—Rh2—C24—C25 | −10.7 (3) |
C1—Rh1—C9—N2 | −179.2 (3) | C20—Rh2—C24—C25 | −48.8 (3) |
C2—Rh1—C9—N2 | 21.5 (7) | C23—Rh2—C24—C25 | −121.5 (4) |
O1—Rh1—C9—C10 | 95.6 (3) | C23—C24—C25—C26 | −79.8 (6) |
C5—Rh1—C9—C10 | −103.7 (3) | Rh2—C24—C25—C26 | 2.2 (6) |
C6—Rh1—C9—C10 | −64.5 (3) | C24—C25—C26—C19 | 12.3 (7) |
C1—Rh1—C9—C10 | 5.4 (5) | C20—C19—C26—C25 | 59.7 (6) |
C2—Rh1—C9—C10 | −153.9 (5) | Rh2—C19—C26—C25 | −21.2 (6) |