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The characteristics of a new ferroelectric measurement system at the European Synchrotron Radiation Facility are presented. The electric-field-induced phase transitions of Pb(Mg1/3Nb2/3)O3-xPbTiO3 are determined via in situ measurements of electric polarization within the synchrotron diffraction beamline. Real-time data collection methods on single-crystal samples are employed as a function of frequency to determine the microstructural origin of piezoelectric effects within these materials, probing the dynamic ferroelectric response.

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