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The dimeric palladium(I) saccharinate complex [Pd2(sac)2(dppm)2], has been characterized as its di­chloro­methane solvate, i.e. [Pd2(C7H4NO3S)2(C25H22P2)2]·CH2Cl2. The complex features a Pd—Pd bond bridged by two dppm ligands, with the saccharinate ligands N-bonded trans to the Pd—Pd bond.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802012515/tk6069sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536802012515/tk6069Isup2.hkl
Contains datablock I

CCDC reference: 193713

Key indicators

  • Single-crystal X-ray study
  • T = 168 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.025
  • wR factor = 0.068
  • Data-to-parameter ratio = 16.2

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry








Computing details top

Data collection: SMART (Siemens, 1994); cell refinement: SAINT (Siemens, 1994); data reduction: SADABS (Sheldrick, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX(Farrugia, 1999).

Bis[µ-bis(diphenylphosphino)methane-κ2P:P']bis[(saccharinato- κN)palladium(I)] dichloromethane solvate top
Crystal data top
[Pd2(C7H4NO3S)2(C25H22P2)2]·CH2Cl2Dx = 1.590 Mg m3
Mr = 1430.80Melting point: >230 degrees celcius K
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
a = 13.819 (4) ÅCell parameters from 5200 reflections
b = 22.550 (7) Åθ = 2–26°
c = 20.230 (6) ŵ = 0.92 mm1
β = 108.53 (1)°T = 168 K
V = 5977 (3) Å3Block, orange
Z = 40.55 × 0.50 × 0.44 mm
F(000) = 2896
Data collection top
Siemens CCD
diffractometer
12130 independent reflections
Radiation source: fine-focus sealed tube10579 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.026
multi–scanθmax = 26.4°, θmin = 2.1°
Absorption correction: empirical (using intensity measurements)
(Blessing, 1995)
h = 1717
Tmin = 0.611, Tmax = 0.667k = 2827
74438 measured reflectionsl = 2125
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.025Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.068H-atom parameters constrained
S = 1.02 w = 1/[σ2(Fo2) + (0.0324P)2 + 6.6496P]
where P = (Fo2 + 2Fc2)/3
12130 reflections(Δ/σ)max = 0.002
748 parametersΔρmax = 0.56 e Å3
0 restraintsΔρmin = 0.66 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Pd10.904498 (12)0.153705 (7)0.682640 (8)0.01628 (5)
Pd20.785921 (12)0.149524 (7)0.759601 (8)0.01743 (5)
P10.89314 (4)0.25522 (2)0.69516 (3)0.01959 (11)
P20.90447 (4)0.21183 (3)0.83390 (3)0.02144 (12)
P30.90952 (4)0.05107 (2)0.68962 (3)0.01781 (11)
P40.69760 (4)0.08185 (2)0.67697 (3)0.01759 (11)
S11.14259 (4)0.16363 (3)0.68182 (3)0.02406 (12)
S20.71083 (5)0.07953 (3)0.88248 (3)0.02765 (12)
Cl11.28094 (7)0.37360 (4)0.82435 (5)0.0619 (2)
Cl21.43217 (7)0.28487 (5)0.81931 (5)0.0675 (3)
O111.15783 (13)0.19783 (8)0.74483 (8)0.0324 (4)
O121.18394 (13)0.10442 (8)0.69243 (10)0.0347 (4)
O130.92511 (13)0.18971 (8)0.52265 (8)0.0307 (4)
O210.75004 (14)0.02814 (8)0.85667 (10)0.0363 (4)
O220.76924 (14)0.09833 (9)0.95178 (9)0.0400 (4)
O230.55558 (14)0.19108 (8)0.76124 (10)0.0361 (4)
N11.02239 (14)0.16309 (8)0.63323 (10)0.0216 (4)
N20.69060 (14)0.13500 (8)0.82725 (9)0.0217 (4)
C10.96669 (17)0.26282 (10)0.78756 (11)0.0237 (5)
H1A0.96450.30340.80300.028*
H1B1.03730.25160.79580.028*
C20.78783 (16)0.01974 (9)0.69522 (11)0.0202 (4)
H2A0.76330.01160.66120.024*
H2B0.79720.00380.74140.024*
C111.00804 (17)0.18738 (10)0.56907 (11)0.0233 (5)
C121.10629 (18)0.21187 (10)0.56233 (12)0.0255 (5)
C131.1195 (2)0.24336 (11)0.50679 (13)0.0325 (5)
H131.06540.24920.46600.039*
C141.2167 (2)0.26612 (12)0.51412 (14)0.0393 (6)
H141.22710.28790.47790.047*
C151.2978 (2)0.25654 (13)0.57477 (15)0.0415 (7)
H151.36150.27220.57840.050*
C161.2859 (2)0.22428 (12)0.62995 (14)0.0361 (6)
H161.34040.21720.67020.043*
C171.18833 (18)0.20292 (10)0.62220 (12)0.0261 (5)
C210.58975 (18)0.15173 (10)0.80397 (12)0.0274 (5)
C220.52499 (18)0.11447 (11)0.83552 (12)0.0273 (5)
C230.4201 (2)0.11846 (12)0.82307 (13)0.0339 (6)
H230.38190.14840.79510.041*
C240.3743 (2)0.07651 (13)0.85358 (14)0.0381 (6)
H240.30410.07770.84510.046*
C250.4323 (2)0.03272 (12)0.89673 (14)0.0375 (6)
H250.40000.00560.91730.045*
C260.5366 (2)0.02833 (12)0.91003 (13)0.0364 (6)
H260.57500.00110.93870.044*
C270.58105 (18)0.07032 (11)0.87824 (12)0.0289 (5)
C1110.77480 (17)0.29633 (10)0.68557 (11)0.0227 (4)
C1120.7775 (2)0.35849 (10)0.68863 (13)0.0294 (5)
H1120.83760.37850.69160.035*
C1130.6907 (2)0.39020 (11)0.68723 (14)0.0343 (6)
H1130.69270.43140.68830.041*
C1140.6009 (2)0.36107 (12)0.68428 (14)0.0353 (6)
H1140.54400.38260.68520.042*
C1150.59661 (19)0.30008 (11)0.67997 (13)0.0329 (6)
H1150.53640.28040.67730.039*
C1160.68278 (17)0.26785 (10)0.67964 (12)0.0265 (5)
H1160.67880.22680.67540.032*
C1210.95779 (18)0.30281 (9)0.64882 (12)0.0245 (5)
C1221.0577 (2)0.32248 (11)0.67916 (14)0.0323 (5)
H1221.09250.31350.72550.039*
C1231.1058 (2)0.35565 (12)0.64021 (16)0.0410 (7)
H1231.17250.36860.66080.049*
C1241.0555 (2)0.36907 (12)0.57208 (16)0.0426 (7)
H1241.08810.39080.54630.051*
C1250.9561 (2)0.35024 (12)0.54158 (15)0.0423 (7)
H1250.92170.35990.49540.051*
C1260.9067 (2)0.31685 (11)0.57937 (13)0.0333 (5)
H1260.84000.30400.55830.040*
C2110.85627 (18)0.26575 (10)0.88301 (12)0.0267 (5)
C2120.75493 (19)0.28397 (11)0.85776 (13)0.0306 (5)
H2120.70860.26340.82140.037*
C2130.7232 (2)0.33340 (12)0.88737 (15)0.0395 (6)
H2130.65550.34560.87060.047*
C2140.7916 (2)0.36408 (13)0.94124 (16)0.0436 (7)
H2140.77050.39750.95980.052*
C2150.8915 (2)0.34504 (13)0.96754 (16)0.0442 (7)
H2150.93710.36531.00450.053*
C2160.9247 (2)0.29581 (12)0.93922 (14)0.0365 (6)
H2160.99190.28290.95750.044*
C2211.00788 (17)0.17356 (11)0.89847 (12)0.0260 (5)
C2221.1025 (2)0.16205 (13)0.89010 (14)0.0358 (6)
H2221.11640.17570.85070.043*
C2231.1761 (2)0.13014 (15)0.94076 (16)0.0479 (7)
H2231.23920.12290.93510.057*
C2241.1566 (2)0.10935 (14)0.99892 (15)0.0482 (7)
H2241.20660.08861.03280.058*
C2251.0625 (2)0.11928 (14)1.00696 (14)0.0466 (7)
H2251.04880.10451.04600.056*
C2260.9884 (2)0.15109 (13)0.95753 (13)0.0373 (6)
H2260.92530.15760.96350.045*
C3110.91858 (16)0.01309 (9)0.61214 (11)0.0210 (4)
C3120.88046 (17)0.04258 (10)0.54841 (12)0.0248 (5)
H3120.86420.08270.54730.030*
C3130.86679 (18)0.01167 (11)0.48634 (12)0.0295 (5)
H3130.83910.03090.44380.035*
C3140.89419 (19)0.04755 (11)0.48762 (13)0.0318 (5)
H3140.88460.06790.44610.038*
C3150.93580 (19)0.07642 (11)0.55070 (13)0.0313 (5)
H3150.95660.11570.55140.038*
C3160.94664 (18)0.04700 (10)0.61295 (12)0.0262 (5)
H3160.97240.06700.65510.031*
C3211.00566 (17)0.01922 (9)0.76507 (11)0.0220 (4)
C3221.09865 (17)0.00241 (11)0.76079 (13)0.0293 (5)
H3221.11280.00000.71890.035*
C3231.1697 (2)0.02743 (12)0.81896 (16)0.0424 (7)
H3231.23070.04230.81550.051*
C3241.1505 (2)0.03051 (13)0.88186 (15)0.0456 (7)
H3241.19760.04820.92030.055*
C3251.0603 (2)0.00694 (12)0.88724 (13)0.0417 (7)
H3251.04810.00790.92990.050*
C3260.98840 (19)0.01795 (11)0.82984 (12)0.0302 (5)
H3260.92860.03390.83420.036*
C4110.57747 (16)0.05206 (10)0.68280 (11)0.0205 (4)
C4120.57005 (18)0.00150 (11)0.71539 (12)0.0278 (5)
H4120.62780.02490.73360.033*
C4130.4762 (2)0.02021 (12)0.72090 (13)0.0338 (6)
H4130.47220.05580.74310.041*
C4140.38993 (19)0.01377 (13)0.69357 (14)0.0366 (6)
H4140.32800.00130.69780.044*
C4150.39528 (19)0.06666 (12)0.65960 (14)0.0349 (6)
H4150.33660.08900.63990.042*
C4160.48846 (18)0.08604 (11)0.65507 (12)0.0280 (5)
H4160.49200.12200.63340.034*
C4210.66644 (16)0.09332 (10)0.58308 (11)0.0203 (4)
C4220.69065 (17)0.14578 (10)0.55556 (12)0.0244 (5)
H4220.71920.17720.58510.029*
C4230.67233 (18)0.15137 (11)0.48428 (12)0.0293 (5)
H4230.68970.18620.46630.035*
C4240.62819 (19)0.10506 (12)0.44000 (12)0.0331 (6)
H4240.61550.10900.39220.040*
C4250.60276 (19)0.05267 (12)0.46695 (13)0.0325 (5)
H4250.57300.02160.43720.039*
C4260.62180 (17)0.04680 (11)0.53808 (12)0.0260 (5)
H4260.60480.01180.55600.031*
C911.3320 (2)0.30195 (16)0.85192 (17)0.0528 (8)
H91A1.35690.30060.90250.063*
H91B1.27850.27250.83580.063*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pd10.01605 (8)0.01613 (8)0.01796 (8)0.00035 (6)0.00726 (6)0.00084 (6)
Pd20.01643 (8)0.01926 (8)0.01796 (8)0.00166 (6)0.00738 (6)0.00286 (6)
P10.0206 (3)0.0173 (3)0.0217 (3)0.0016 (2)0.0078 (2)0.0021 (2)
P20.0203 (3)0.0252 (3)0.0200 (3)0.0042 (2)0.0080 (2)0.0052 (2)
P30.0167 (3)0.0168 (2)0.0205 (3)0.0006 (2)0.0068 (2)0.0001 (2)
P40.0163 (3)0.0184 (3)0.0184 (3)0.0008 (2)0.0060 (2)0.0013 (2)
S10.0202 (3)0.0293 (3)0.0250 (3)0.0012 (2)0.0106 (2)0.0009 (2)
S20.0281 (3)0.0305 (3)0.0262 (3)0.0014 (2)0.0114 (2)0.0009 (2)
Cl10.0568 (5)0.0653 (5)0.0604 (5)0.0081 (4)0.0140 (4)0.0113 (4)
Cl20.0534 (5)0.0873 (7)0.0588 (5)0.0130 (5)0.0138 (4)0.0219 (5)
O110.0296 (9)0.0453 (10)0.0238 (8)0.0050 (8)0.0105 (7)0.0041 (7)
O120.0289 (9)0.0353 (10)0.0428 (10)0.0063 (7)0.0154 (8)0.0074 (8)
O130.0285 (9)0.0352 (9)0.0262 (9)0.0029 (7)0.0058 (7)0.0014 (7)
O210.0389 (10)0.0329 (9)0.0405 (10)0.0048 (8)0.0174 (8)0.0003 (8)
O220.0387 (10)0.0515 (12)0.0280 (9)0.0061 (9)0.0081 (8)0.0025 (8)
O230.0349 (10)0.0323 (9)0.0439 (11)0.0033 (8)0.0165 (8)0.0065 (8)
N10.0165 (9)0.0228 (9)0.0270 (10)0.0020 (7)0.0091 (7)0.0013 (7)
N20.0207 (9)0.0263 (9)0.0216 (9)0.0062 (7)0.0118 (8)0.0001 (7)
C10.0233 (11)0.0247 (11)0.0244 (11)0.0066 (9)0.0094 (9)0.0047 (9)
C20.0185 (10)0.0191 (10)0.0238 (11)0.0003 (8)0.0080 (9)0.0003 (8)
C110.0280 (12)0.0203 (11)0.0242 (11)0.0012 (9)0.0118 (10)0.0033 (9)
C120.0311 (12)0.0220 (11)0.0270 (12)0.0035 (9)0.0144 (10)0.0045 (9)
C130.0410 (14)0.0335 (13)0.0272 (12)0.0068 (11)0.0168 (11)0.0024 (10)
C140.0485 (16)0.0406 (15)0.0390 (15)0.0120 (13)0.0282 (13)0.0001 (12)
C150.0374 (15)0.0503 (17)0.0446 (16)0.0183 (13)0.0242 (13)0.0075 (13)
C160.0306 (13)0.0461 (15)0.0358 (14)0.0098 (12)0.0167 (11)0.0035 (12)
C170.0279 (12)0.0283 (12)0.0263 (12)0.0044 (9)0.0149 (10)0.0034 (9)
C210.0293 (13)0.0292 (12)0.0263 (12)0.0021 (10)0.0125 (10)0.0042 (10)
C220.0289 (12)0.0290 (12)0.0271 (12)0.0027 (10)0.0135 (10)0.0070 (10)
C230.0320 (13)0.0374 (14)0.0338 (13)0.0015 (11)0.0125 (11)0.0049 (11)
C240.0304 (13)0.0515 (17)0.0386 (14)0.0107 (12)0.0195 (12)0.0118 (12)
C250.0444 (15)0.0425 (15)0.0339 (14)0.0168 (12)0.0241 (12)0.0034 (11)
C260.0447 (15)0.0369 (14)0.0298 (13)0.0054 (12)0.0149 (12)0.0017 (11)
C270.0293 (12)0.0324 (13)0.0277 (12)0.0044 (10)0.0131 (10)0.0056 (10)
C1110.0240 (11)0.0228 (11)0.0221 (11)0.0030 (9)0.0085 (9)0.0014 (9)
C1120.0326 (13)0.0227 (11)0.0341 (13)0.0030 (10)0.0123 (11)0.0053 (10)
C1130.0418 (15)0.0219 (12)0.0390 (14)0.0058 (10)0.0123 (12)0.0050 (10)
C1140.0340 (14)0.0346 (13)0.0387 (14)0.0120 (11)0.0138 (11)0.0039 (11)
C1150.0232 (12)0.0356 (14)0.0390 (14)0.0039 (10)0.0086 (10)0.0088 (11)
C1160.0258 (12)0.0224 (11)0.0286 (12)0.0010 (9)0.0050 (9)0.0038 (9)
C1210.0314 (12)0.0160 (10)0.0299 (12)0.0017 (9)0.0153 (10)0.0011 (9)
C1220.0358 (14)0.0269 (12)0.0352 (13)0.0076 (10)0.0128 (11)0.0014 (10)
C1230.0436 (16)0.0321 (14)0.0533 (18)0.0139 (12)0.0241 (14)0.0026 (12)
C1240.0590 (19)0.0278 (13)0.0526 (18)0.0043 (13)0.0340 (15)0.0075 (12)
C1250.0553 (18)0.0397 (15)0.0373 (15)0.0061 (13)0.0222 (14)0.0116 (12)
C1260.0353 (14)0.0315 (13)0.0356 (14)0.0021 (11)0.0147 (11)0.0038 (11)
C2110.0289 (12)0.0287 (12)0.0265 (12)0.0073 (10)0.0143 (10)0.0086 (9)
C2120.0311 (13)0.0329 (13)0.0304 (13)0.0042 (10)0.0131 (10)0.0085 (10)
C2130.0393 (15)0.0376 (14)0.0456 (16)0.0023 (12)0.0191 (13)0.0093 (12)
C2140.0517 (18)0.0362 (15)0.0514 (17)0.0050 (13)0.0286 (14)0.0187 (13)
C2150.0430 (16)0.0491 (17)0.0451 (16)0.0181 (13)0.0203 (13)0.0271 (13)
C2160.0297 (13)0.0439 (15)0.0380 (14)0.0094 (11)0.0135 (11)0.0173 (12)
C2210.0239 (11)0.0317 (12)0.0202 (11)0.0055 (9)0.0037 (9)0.0052 (9)
C2220.0303 (13)0.0491 (16)0.0286 (13)0.0028 (12)0.0101 (11)0.0026 (11)
C2230.0309 (15)0.063 (2)0.0456 (17)0.0086 (14)0.0068 (13)0.0012 (15)
C2240.0450 (17)0.0554 (18)0.0321 (15)0.0042 (14)0.0048 (13)0.0052 (13)
C2250.0498 (18)0.0578 (19)0.0273 (14)0.0073 (15)0.0054 (12)0.0069 (13)
C2260.0329 (14)0.0502 (16)0.0281 (13)0.0061 (12)0.0090 (11)0.0015 (11)
C3110.0191 (10)0.0211 (10)0.0246 (11)0.0016 (8)0.0094 (9)0.0030 (8)
C3120.0211 (11)0.0266 (11)0.0282 (12)0.0027 (9)0.0098 (9)0.0004 (9)
C3130.0258 (12)0.0404 (14)0.0237 (12)0.0001 (10)0.0100 (10)0.0007 (10)
C3140.0305 (13)0.0381 (14)0.0307 (13)0.0081 (11)0.0149 (10)0.0130 (11)
C3150.0370 (14)0.0227 (12)0.0392 (14)0.0032 (10)0.0191 (11)0.0073 (10)
C3160.0300 (12)0.0214 (11)0.0298 (12)0.0011 (9)0.0132 (10)0.0003 (9)
C3210.0211 (11)0.0176 (10)0.0249 (11)0.0011 (8)0.0039 (9)0.0006 (8)
C3220.0220 (12)0.0279 (12)0.0349 (13)0.0004 (9)0.0046 (10)0.0012 (10)
C3230.0263 (13)0.0342 (14)0.0557 (18)0.0060 (11)0.0027 (12)0.0015 (13)
C3240.0438 (17)0.0366 (15)0.0383 (16)0.0021 (12)0.0126 (13)0.0095 (12)
C3250.0536 (18)0.0403 (15)0.0233 (13)0.0153 (13)0.0012 (12)0.0033 (11)
C3260.0309 (13)0.0307 (13)0.0273 (12)0.0056 (10)0.0068 (10)0.0020 (10)
C4110.0181 (10)0.0244 (11)0.0201 (10)0.0043 (8)0.0076 (8)0.0055 (8)
C4120.0269 (12)0.0308 (12)0.0253 (12)0.0055 (10)0.0079 (10)0.0000 (9)
C4130.0361 (14)0.0378 (14)0.0296 (13)0.0145 (11)0.0136 (11)0.0034 (11)
C4140.0268 (13)0.0514 (16)0.0378 (14)0.0145 (12)0.0188 (11)0.0152 (12)
C4150.0207 (12)0.0451 (15)0.0402 (14)0.0022 (11)0.0114 (11)0.0098 (12)
C4160.0236 (12)0.0323 (12)0.0288 (12)0.0017 (10)0.0094 (10)0.0040 (10)
C4210.0155 (10)0.0257 (11)0.0197 (10)0.0022 (8)0.0058 (8)0.0005 (8)
C4220.0188 (11)0.0274 (12)0.0251 (11)0.0002 (9)0.0044 (9)0.0007 (9)
C4230.0260 (12)0.0350 (13)0.0263 (12)0.0012 (10)0.0073 (10)0.0086 (10)
C4240.0299 (13)0.0506 (16)0.0187 (11)0.0016 (11)0.0076 (10)0.0012 (10)
C4250.0306 (13)0.0402 (14)0.0255 (12)0.0031 (11)0.0071 (10)0.0104 (11)
C4260.0233 (11)0.0290 (12)0.0263 (12)0.0034 (9)0.0090 (9)0.0033 (9)
C910.0451 (18)0.066 (2)0.0464 (18)0.0046 (15)0.0130 (14)0.0058 (15)
Geometric parameters (Å, º) top
Pd1—N12.1757 (18)C123—H1230.9300
Pd1—P12.3139 (9)C124—C1251.382 (4)
Pd1—P32.3184 (9)C124—H1240.9300
Pd1—Pd22.5962 (6)C125—C1261.396 (4)
Pd2—N22.2049 (18)C125—H1250.9300
Pd2—P42.3056 (7)C126—H1260.9300
Pd2—P22.3133 (7)C211—C2121.391 (3)
P1—C11.830 (2)C211—C2161.401 (3)
P1—C1211.833 (2)C212—C2131.400 (4)
P1—C1111.836 (2)C212—H2120.9300
P2—C2211.818 (2)C213—C2141.380 (4)
P2—C2111.825 (2)C213—H2130.9300
P2—C11.858 (2)C214—C2151.381 (4)
P3—C3211.822 (2)C214—H2140.9300
P3—C3111.825 (2)C215—C2161.392 (4)
P3—C21.860 (2)C215—H2150.9300
P4—C4211.828 (2)C216—H2160.9300
P4—C4111.829 (2)C221—C2221.395 (3)
P4—C21.833 (2)C221—C2261.400 (3)
S1—O121.4413 (18)C222—C2231.393 (4)
S1—O111.4469 (18)C222—H2220.9300
S1—N11.6393 (19)C223—C2241.371 (4)
S1—C171.767 (2)C223—H2230.9300
S2—O221.4413 (19)C224—C2251.379 (4)
S2—O211.4455 (18)C224—H2240.9300
S2—N21.6409 (19)C225—C2261.382 (4)
S2—C271.780 (3)C225—H2250.9300
Cl1—C911.780 (4)C226—H2260.9300
Cl2—C911.755 (3)C311—C3121.396 (3)
O13—C111.230 (3)C311—C3161.408 (3)
O23—C211.224 (3)C312—C3131.395 (3)
N1—C111.364 (3)C312—H3120.9300
N2—C211.374 (3)C313—C3141.386 (4)
C1—H1A0.9700C313—H3130.9300
C1—H1B0.9700C314—C3151.384 (4)
C2—H2A0.9700C314—H3140.9300
C2—H2B0.9700C315—C3161.389 (3)
C11—C121.512 (3)C315—H3150.9300
C12—C171.386 (3)C316—H3160.9300
C12—C131.389 (3)C321—C3221.403 (3)
C13—C141.401 (4)C321—C3261.405 (3)
C13—H130.9300C322—C3231.390 (4)
C14—C151.390 (4)C322—H3220.9300
C14—H140.9300C323—C3241.381 (4)
C15—C161.385 (4)C323—H3230.9300
C15—H150.9300C324—C3251.392 (4)
C16—C171.393 (3)C324—H3240.9300
C16—H160.9300C325—C3261.385 (4)
C21—C221.509 (3)C325—H3250.9300
C22—C271.383 (3)C326—H3260.9300
C22—C231.392 (3)C411—C4121.395 (3)
C23—C241.387 (4)C411—C4161.406 (3)
C23—H230.9300C412—C4131.401 (3)
C24—C251.391 (4)C412—H4120.9300
C24—H240.9300C413—C4141.377 (4)
C25—C261.383 (4)C413—H4130.9300
C25—H250.9300C414—C4151.390 (4)
C26—C271.392 (3)C414—H4140.9300
C26—H260.9300C415—C4161.390 (3)
C111—C1161.395 (3)C415—H4150.9300
C111—C1121.403 (3)C416—H4160.9300
C112—C1131.389 (3)C421—C4221.393 (3)
C112—H1120.9300C421—C4261.397 (3)
C113—C1141.388 (4)C422—C4231.388 (3)
C113—H1130.9300C422—H4220.9300
C114—C1151.378 (4)C423—C4241.385 (4)
C114—H1140.9300C423—H4230.9300
C115—C1161.397 (3)C424—C4251.392 (4)
C115—H1150.9300C424—H4240.9300
C116—H1160.9300C425—C4261.384 (3)
C121—C1221.393 (3)C425—H4250.9300
C121—C1261.394 (3)C426—H4260.9300
C122—C1231.399 (4)C91—H91A0.9700
C122—H1220.9300C91—H91B0.9700
C123—C1241.366 (4)
N1—Pd1—P192.34 (5)C121—C122—C123120.3 (2)
N1—Pd1—P396.48 (5)C121—C122—H122119.9
P1—Pd1—P3169.32 (2)C123—C122—H122119.9
N1—Pd1—Pd2170.62 (5)C124—C123—C122120.4 (3)
P1—Pd1—Pd283.833 (15)C124—C123—H123119.8
P3—Pd1—Pd286.536 (14)C122—C123—H123119.8
N2—Pd2—P493.94 (5)C123—C124—C125119.8 (2)
N2—Pd2—P297.26 (5)C123—C124—H124120.1
P4—Pd2—P2167.26 (2)C125—C124—H124120.1
N2—Pd2—Pd1173.28 (5)C124—C125—C126120.7 (3)
P4—Pd2—Pd183.04 (2)C124—C125—H125119.6
P2—Pd2—Pd185.18 (2)C126—C125—H125119.6
C1—P1—C121105.36 (11)C121—C126—C125119.7 (3)
C1—P1—C111104.33 (10)C121—C126—H126120.2
C121—P1—C111102.29 (11)C125—C126—H126120.2
C1—P1—Pd199.76 (8)C212—C211—C216119.7 (2)
C121—P1—Pd1117.52 (7)C212—C211—P2119.73 (18)
C111—P1—Pd1125.25 (8)C216—C211—P2119.71 (19)
C221—P2—C211105.34 (11)C211—C212—C213119.6 (2)
C221—P2—C1105.79 (11)C211—C212—H212120.2
C211—P2—C199.78 (11)C213—C212—H212120.2
C221—P2—Pd2114.27 (8)C214—C213—C212120.5 (3)
C211—P2—Pd2116.92 (8)C214—C213—H213119.8
C1—P2—Pd2113.18 (7)C212—C213—H213119.8
C321—P3—C311107.67 (10)C213—C214—C215119.9 (3)
C321—P3—C2103.40 (10)C213—C214—H214120.0
C311—P3—C2100.62 (10)C215—C214—H214120.0
C321—P3—Pd1116.37 (7)C214—C215—C216120.6 (3)
C311—P3—Pd1115.15 (7)C214—C215—H215119.7
C2—P3—Pd1111.88 (7)C216—C215—H215119.7
C421—P4—C411101.55 (10)C215—C216—C211119.7 (3)
C421—P4—C2103.76 (10)C215—C216—H216120.2
C411—P4—C2106.24 (10)C211—C216—H216120.2
C421—P4—Pd2123.73 (8)C222—C221—C226118.5 (2)
C411—P4—Pd2118.58 (7)C222—C221—P2123.63 (19)
C2—P4—Pd2100.97 (7)C226—C221—P2117.68 (19)
O12—S1—O11115.01 (11)C223—C222—C221120.0 (3)
O12—S1—N1111.13 (10)C223—C222—H222120.0
O11—S1—N1111.61 (10)C221—C222—H222120.0
O12—S1—C17110.80 (11)C224—C223—C222120.7 (3)
O11—S1—C17110.53 (11)C224—C223—H223119.6
N1—S1—C1796.23 (11)C222—C223—H223119.6
O22—S2—O21115.39 (12)C223—C224—C225119.7 (3)
O22—S2—N2111.08 (11)C223—C224—H224120.1
O21—S2—N2111.56 (10)C225—C224—H224120.1
O22—S2—C27108.99 (11)C224—C225—C226120.5 (3)
O21—S2—C27112.13 (11)C224—C225—H225119.7
N2—S2—C2796.04 (11)C226—C225—H225119.7
C11—N1—S1112.38 (15)C225—C226—C221120.4 (3)
C11—N1—Pd1124.93 (15)C225—C226—H226119.8
S1—N1—Pd1119.29 (10)C221—C226—H226119.8
C21—N2—S2112.16 (15)C312—C311—C316119.4 (2)
C21—N2—Pd2119.17 (15)C312—C311—P3117.44 (16)
S2—N2—Pd2121.99 (10)C316—C311—P3122.38 (17)
P1—C1—P2105.17 (11)C313—C312—C311119.8 (2)
P1—C1—H1A110.7C313—C312—H312120.1
P2—C1—H1A110.7C311—C312—H312120.1
P1—C1—H1B110.7C314—C313—C312120.4 (2)
P2—C1—H1B110.7C314—C313—H313119.8
H1A—C1—H1B108.8C312—C313—H313119.8
P4—C2—P3105.53 (11)C315—C314—C313120.1 (2)
P4—C2—H2A110.6C315—C314—H314120.0
P3—C2—H2A110.6C313—C314—H314120.0
P4—C2—H2B110.6C314—C315—C316120.3 (2)
P3—C2—H2B110.6C314—C315—H315119.8
H2A—C2—H2B108.8C316—C315—H315119.8
O13—C11—N1124.2 (2)C315—C316—C311120.0 (2)
O13—C11—C12124.1 (2)C315—C316—H316120.0
N1—C11—C12111.69 (19)C311—C316—H316120.0
C17—C12—C13120.0 (2)C322—C321—C326118.8 (2)
C17—C12—C11112.1 (2)C322—C321—P3121.57 (18)
C13—C12—C11127.8 (2)C326—C321—P3119.63 (18)
C12—C13—C14118.0 (2)C323—C322—C321120.2 (2)
C12—C13—H13121.0C323—C322—H322119.9
C14—C13—H13121.0C321—C322—H322119.9
C15—C14—C13120.9 (2)C324—C323—C322120.7 (3)
C15—C14—H14119.6C324—C323—H323119.7
C13—C14—H14119.6C322—C323—H323119.7
C16—C15—C14121.6 (2)C323—C324—C325119.5 (2)
C16—C15—H15119.2C323—C324—H324120.3
C14—C15—H15119.2C325—C324—H324120.3
C15—C16—C17116.7 (3)C326—C325—C324120.7 (3)
C15—C16—H16121.7C326—C325—H325119.6
C17—C16—H16121.7C324—C325—H325119.6
C12—C17—C16122.8 (2)C325—C326—C321120.1 (2)
C12—C17—S1107.38 (17)C325—C326—H326120.0
C16—C17—S1129.8 (2)C321—C326—H326120.0
O23—C21—N2124.2 (2)C412—C411—C416118.3 (2)
O23—C21—C22123.7 (2)C412—C411—P4123.57 (17)
N2—C21—C22112.0 (2)C416—C411—P4118.10 (17)
C27—C22—C23120.2 (2)C411—C412—C413120.5 (2)
C27—C22—C21112.0 (2)C411—C412—H412119.8
C23—C22—C21127.6 (2)C413—C412—H412119.8
C24—C23—C22118.1 (3)C414—C413—C412120.4 (2)
C24—C23—H23120.9C414—C413—H413119.8
C22—C23—H23120.9C412—C413—H413119.8
C23—C24—C25120.6 (2)C413—C414—C415120.0 (2)
C23—C24—H24119.7C413—C414—H414120.0
C25—C24—H24119.7C415—C414—H414120.0
C26—C25—C24122.0 (2)C414—C415—C416119.9 (2)
C26—C25—H25119.0C414—C415—H415120.1
C24—C25—H25119.0C416—C415—H415120.1
C25—C26—C27116.6 (3)C415—C416—C411120.9 (2)
C25—C26—H26121.7C415—C416—H416119.5
C27—C26—H26121.7C411—C416—H416119.5
C22—C27—C26122.4 (2)C422—C421—C426119.3 (2)
C22—C27—S2107.56 (18)C422—C421—P4121.91 (17)
C26—C27—S2130.0 (2)C426—C421—P4118.69 (17)
C116—C111—C112118.3 (2)C423—C422—C421120.3 (2)
C116—C111—P1122.25 (17)C423—C422—H422119.8
C112—C111—P1119.30 (18)C421—C422—H422119.8
C113—C112—C111120.2 (2)C424—C423—C422120.1 (2)
C113—C112—H112119.9C424—C423—H423120.0
C111—C112—H112119.9C422—C423—H423120.0
C114—C113—C112120.8 (2)C423—C424—C425120.0 (2)
C114—C113—H113119.6C423—C424—H424120.0
C112—C113—H113119.6C425—C424—H424120.0
C115—C114—C113119.7 (2)C426—C425—C424120.0 (2)
C115—C114—H114120.2C426—C425—H425120.0
C113—C114—H114120.2C424—C425—H425120.0
C114—C115—C116120.0 (2)C425—C426—C421120.3 (2)
C114—C115—H115120.0C425—C426—H426119.9
C116—C115—H115120.0C421—C426—H426119.9
C111—C116—C115121.0 (2)Cl2—C91—Cl1111.29 (19)
C111—C116—H116119.5Cl2—C91—H91A109.4
C115—C116—H116119.5Cl1—C91—H91A109.4
C122—C121—C126119.0 (2)Cl2—C91—H91B109.4
C122—C121—P1122.46 (18)Cl1—C91—H91B109.4
C126—C121—P1118.38 (18)H91A—C91—H91B108.0
 

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