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5,8,11,14-Tetraoxa-2,17-dithiabicyclo[16.4.1]tricosa-1(22),18,20-trien-23-one (C17H24O5S2) forms an endocyclic 1:1-complex with [HgCl2]. The mercury(II) ion is surrounded by four ethereal O atoms and one S atom. The mesomeric effect lowers the basicity of the sulfur atoms on the tropone ring making them less likely to act as ligand atoms.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks TA1067, 1

fcf

Structure factor file (CIF format)
Contains datablock TA1067

CCDC reference: 127003

-1
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