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The structures of two methylated hexacyclic cage diketones, 1-methylhexacyclo[10.2.1.02,11.04,9.04,14.09,13]pentadeca-5,7-diene-3,10-dione, C16H14O2, and 13,14-dimethylhexacyclo[10.2.1.02,11.04,9.04,14.09,13]pentadeca-5,7-diene-3,10-dione, C17H16O2, have been determined. All bond lengths and angles are consistent with strained-cage geometry.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks text, ta1064a, ta1064b

CCDC references: 127143; 127144

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