Bis(N,N-cyclo-heptamethylenedithiocarbamato-S,S')platinum(II), a Platinum Dithiocarbamate Containing a Large Carbocyclic Ring

The title compound, [Pt(C₈H₁₄NS₂)₂], contains the largest carbocyclic dithiocarbamate ligand yet characterized. Typical Pt-S distances and S-Pt-S angles are observed, but there is a pronounced twist between the planes defined by Pt, S(1), S(2), C(1) and N(1), C(2), C(8) relative to open-chain analogues.

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