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The title compound, [Fe(C5H5)(C8H9P)(C20H20P2)]PF6, was obtained by spontaneous resolution of the racemate from acetone/diethyl ether solution. The cationic piano-stool iron(II) complex exhibits pseudooctahedral coordination geometry, with Fe-P distances of 2.189 (3) and 2.178 (4) Å for the bidentate ligand, and 2.170 (3) Å for the phosphirane ligand. The bond parameters for the phosphirane ligand are in good agreement with those found for related complexes.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, mxp6

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 126479

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