Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804025735/su6145sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804025735/su6145Isup2.hkl |
CCDC reference: 255434
Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.
[PdCl2(C11H24S2)] | F(000) = 1616 |
Mr = 397.76 | Dx = 1.558 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 991 reflections |
a = 23.142 (12) Å | θ = 2.4–26.2° |
b = 12.221 (6) Å | µ = 1.63 mm−1 |
c = 12.031 (6) Å | T = 293 K |
β = 94.484 (9)° | Block, yellow |
V = 3392 (3) Å3 | 0.20 × 0.18 × 0.14 mm |
Z = 8 |
Bruker SMART CCD area-detector diffractometer | 6923 independent reflections |
Radiation source: fine-focus sealed tube | 3957 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.047 |
φ and ω scans | θmax = 26.4°, θmin = 0.9° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −28→28 |
Tmin = 0.668, Tmax = 0.795 | k = −15→12 |
19045 measured reflections | l = −15→12 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.046 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.132 | H-atom parameters constrained |
S = 1.08 | w = 1/[σ2(Fo2) + (0.053P)2 + 0.6086P] where P = (Fo2 + 2Fc2)/3 |
6923 reflections | (Δ/σ)max = 0.001 |
293 parameters | Δρmax = 0.72 e Å−3 |
26 restraints | Δρmin = −0.79 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Pd1 | 0.01529 (2) | 0.12382 (3) | 0.08447 (4) | 0.04512 (16) | |
Pd2 | 0.48662 (2) | 0.63844 (3) | 0.41746 (4) | 0.04191 (16) | |
Cl1 | −0.07641 (8) | 0.18564 (14) | 0.02342 (15) | 0.0707 (5) | |
Cl2 | 0.05874 (9) | 0.25946 (14) | −0.01526 (14) | 0.0687 (5) | |
Cl3 | 0.44585 (8) | 0.77367 (12) | 0.52220 (14) | 0.0614 (5) | |
Cl4 | 0.57864 (7) | 0.68847 (13) | 0.49218 (13) | 0.0571 (4) | |
S1 | −0.03511 (8) | 0.00488 (12) | 0.18532 (13) | 0.0552 (5) | |
S2 | 0.10842 (8) | 0.07373 (13) | 0.13781 (13) | 0.0556 (5) | |
S3 | 0.39597 (8) | 0.61305 (13) | 0.33227 (14) | 0.0551 (4) | |
S4 | 0.53599 (7) | 0.51148 (11) | 0.32367 (12) | 0.0483 (4) | |
C1 | −0.1976 (5) | −0.0068 (9) | 0.4060 (9) | 0.151 (4) | |
H1A | −0.1820 | −0.0724 | 0.4406 | 0.227* | |
H1B | −0.2348 | −0.0223 | 0.3684 | 0.227* | |
H1C | −0.2017 | 0.0481 | 0.4619 | 0.227* | |
C2 | −0.1569 (4) | 0.0344 (9) | 0.3223 (8) | 0.126 (4) | |
H2A | −0.1569 | −0.0166 | 0.2605 | 0.152* | |
H2B | −0.1705 | 0.1045 | 0.2931 | 0.152* | |
C3 | −0.0967 (4) | 0.0466 (7) | 0.3749 (6) | 0.099 (3) | |
H3A | −0.0824 | −0.0248 | 0.3993 | 0.119* | |
H3B | −0.0976 | 0.0926 | 0.4404 | 0.119* | |
C4 | −0.0552 (3) | 0.0955 (5) | 0.2980 (6) | 0.074 (2) | |
H4A | −0.0201 | 0.1169 | 0.3421 | 0.088* | |
H4B | −0.0724 | 0.1613 | 0.2650 | 0.088* | |
C5 | 0.0101 (4) | −0.0930 (5) | 0.2610 (6) | 0.073 (2) | |
H5A | −0.0112 | −0.1215 | 0.3210 | 0.088* | |
H5B | 0.0165 | −0.1535 | 0.2113 | 0.088* | |
C6 | 0.0695 (4) | −0.0542 (6) | 0.3118 (6) | 0.077 (2) | |
H6A | 0.0647 | 0.0162 | 0.3473 | 0.093* | |
H6B | 0.0834 | −0.1055 | 0.3693 | 0.093* | |
C7 | 0.1149 (3) | −0.0432 (5) | 0.2285 (6) | 0.069 (2) | |
H7A | 0.1138 | −0.1086 | 0.1827 | 0.082* | |
H7B | 0.1527 | −0.0407 | 0.2695 | 0.082* | |
C8 | 0.1332 (3) | 0.1813 (5) | 0.2340 (5) | 0.0634 (19) | |
H8A | 0.1246 | 0.2517 | 0.1991 | 0.076* | |
H8B | 0.1116 | 0.1768 | 0.2998 | 0.076* | |
C9 | 0.1970 (4) | 0.1759 (7) | 0.2693 (9) | 0.119 (4) | |
H9A | 0.2058 | 0.1060 | 0.3050 | 0.143* | |
H9B | 0.2189 | 0.1807 | 0.2039 | 0.143* | |
C10 | 0.2149 (4) | 0.2654 (8) | 0.3473 (11) | 0.166 (6) | |
H10A | 0.1869 | 0.2697 | 0.4030 | 0.199* | |
H10B | 0.2127 | 0.3336 | 0.3059 | 0.199* | |
C11 | 0.2735 (5) | 0.2580 (10) | 0.4062 (11) | 0.188 (6) | |
H11A | 0.2756 | 0.1946 | 0.4535 | 0.283* | |
H11B | 0.2809 | 0.3224 | 0.4508 | 0.283* | |
H11C | 0.3020 | 0.2522 | 0.3526 | 0.283* | |
C12 | 0.2423 (5) | 0.6824 (10) | 0.5580 (9) | 0.145 (4) | |
H12A | 0.2798 | 0.6963 | 0.5949 | 0.218* | |
H12B | 0.2142 | 0.6766 | 0.6124 | 0.218* | |
H12C | 0.2318 | 0.7414 | 0.5077 | 0.218* | |
C13 | 0.2438 (4) | 0.5789 (8) | 0.4947 (9) | 0.113 (3) | |
H13A | 0.2049 | 0.5614 | 0.4639 | 0.136* | |
H13B | 0.2566 | 0.5204 | 0.5452 | 0.136* | |
C14 | 0.2843 (3) | 0.5845 (7) | 0.3992 (7) | 0.090 (3) | |
H14A | 0.2770 | 0.5219 | 0.3506 | 0.108* | |
H14B | 0.2757 | 0.6501 | 0.3557 | 0.108* | |
C15 | 0.3484 (3) | 0.5855 (6) | 0.4423 (6) | 0.0642 (19) | |
H15A | 0.3585 | 0.5151 | 0.4758 | 0.077* | |
H15B | 0.3545 | 0.6409 | 0.4998 | 0.077* | |
C16 | 0.3878 (3) | 0.4849 (5) | 0.2539 (6) | 0.073 (2) | |
H16A | 0.3847 | 0.4252 | 0.3062 | 0.087* | |
H16B | 0.3518 | 0.4877 | 0.2068 | 0.087* | |
C17 | 0.4360 (4) | 0.4606 (5) | 0.1830 (5) | 0.069 (2) | |
H17A | 0.4456 | 0.5273 | 0.1448 | 0.083* | |
H17B | 0.4223 | 0.4079 | 0.1266 | 0.083* | |
C18 | 0.4905 (3) | 0.4163 (5) | 0.2440 (5) | 0.0635 (19) | |
H18A | 0.5136 | 0.3823 | 0.1896 | 0.076* | |
H18B | 0.4794 | 0.3591 | 0.2940 | 0.076* | |
C19 | 0.5652 (3) | 0.5942 (5) | 0.2150 (5) | 0.0544 (17) | |
H19A | 0.5333 | 0.6260 | 0.1688 | 0.065* | |
H19B | 0.5877 | 0.6538 | 0.2497 | 0.065* | |
C20 | 0.6033 (3) | 0.5299 (6) | 0.1414 (5) | 0.065 (2) | |
H20A | 0.6179 | 0.5792 | 0.0870 | 0.078* | |
H20B | 0.5797 | 0.4751 | 0.1010 | 0.078* | |
C21 | 0.6547 (3) | 0.4730 (7) | 0.2052 (7) | 0.085 (2) | |
H21A | 0.6761 | 0.5263 | 0.2518 | 0.102* | |
H21B | 0.6403 | 0.4175 | 0.2535 | 0.102* | |
C22 | 0.6950 (4) | 0.4204 (8) | 0.1287 (8) | 0.119 (3) | |
H22A | 0.6738 | 0.3691 | 0.0809 | 0.179* | |
H22B | 0.7254 | 0.3829 | 0.1723 | 0.179* | |
H22C | 0.7116 | 0.4757 | 0.0843 | 0.179* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Pd1 | 0.0631 (4) | 0.0369 (3) | 0.0346 (3) | 0.0032 (2) | −0.0010 (2) | 0.0001 (2) |
Pd2 | 0.0498 (3) | 0.0339 (2) | 0.0414 (3) | −0.0004 (2) | −0.0003 (2) | −0.00213 (19) |
Cl1 | 0.0735 (14) | 0.0602 (11) | 0.0744 (12) | 0.0111 (9) | −0.0197 (10) | −0.0058 (9) |
Cl2 | 0.0938 (15) | 0.0616 (10) | 0.0509 (10) | −0.0074 (10) | 0.0060 (10) | 0.0150 (8) |
Cl3 | 0.0664 (12) | 0.0469 (9) | 0.0701 (11) | 0.0071 (8) | −0.0001 (9) | −0.0177 (8) |
Cl4 | 0.0535 (11) | 0.0551 (10) | 0.0610 (10) | −0.0045 (8) | −0.0063 (8) | −0.0060 (8) |
S1 | 0.0771 (14) | 0.0422 (9) | 0.0463 (10) | −0.0090 (8) | 0.0051 (9) | −0.0067 (7) |
S2 | 0.0660 (12) | 0.0524 (9) | 0.0482 (9) | 0.0100 (9) | 0.0023 (8) | −0.0059 (8) |
S3 | 0.0567 (12) | 0.0499 (9) | 0.0565 (10) | 0.0000 (8) | −0.0095 (8) | −0.0037 (8) |
S4 | 0.0622 (12) | 0.0374 (8) | 0.0459 (9) | 0.0041 (7) | 0.0077 (8) | 0.0010 (7) |
C1 | 0.136 (8) | 0.176 (8) | 0.147 (8) | −0.024 (6) | 0.048 (7) | 0.007 (7) |
C2 | 0.104 (9) | 0.172 (11) | 0.102 (8) | −0.044 (8) | −0.001 (7) | 0.014 (7) |
C3 | 0.147 (10) | 0.087 (6) | 0.066 (5) | −0.010 (6) | 0.031 (6) | −0.004 (5) |
C4 | 0.100 (7) | 0.063 (4) | 0.060 (4) | −0.014 (4) | 0.023 (4) | −0.017 (4) |
C5 | 0.118 (7) | 0.039 (4) | 0.062 (4) | −0.003 (4) | 0.006 (5) | 0.012 (3) |
C6 | 0.119 (7) | 0.050 (4) | 0.058 (5) | 0.007 (4) | −0.017 (5) | 0.018 (4) |
C7 | 0.078 (6) | 0.051 (4) | 0.074 (5) | 0.014 (4) | −0.015 (4) | 0.001 (4) |
C8 | 0.072 (5) | 0.061 (4) | 0.055 (4) | −0.001 (4) | −0.005 (4) | −0.006 (3) |
C9 | 0.094 (8) | 0.075 (6) | 0.177 (10) | 0.002 (5) | −0.052 (7) | −0.002 (6) |
C10 | 0.108 (9) | 0.079 (7) | 0.291 (16) | −0.014 (6) | −0.105 (10) | 0.007 (8) |
C11 | 0.177 (9) | 0.150 (8) | 0.230 (9) | 0.002 (7) | −0.045 (8) | −0.019 (7) |
C12 | 0.131 (7) | 0.153 (8) | 0.157 (8) | −0.005 (7) | 0.050 (6) | −0.002 (7) |
C13 | 0.059 (6) | 0.123 (8) | 0.160 (10) | −0.012 (6) | 0.027 (6) | 0.009 (7) |
C14 | 0.056 (5) | 0.092 (6) | 0.118 (7) | −0.001 (5) | −0.008 (5) | −0.008 (5) |
C15 | 0.050 (5) | 0.064 (4) | 0.078 (5) | −0.002 (4) | 0.003 (4) | 0.001 (4) |
C16 | 0.074 (6) | 0.066 (5) | 0.075 (5) | −0.009 (4) | −0.015 (4) | −0.019 (4) |
C17 | 0.110 (7) | 0.046 (4) | 0.049 (4) | −0.016 (4) | −0.011 (4) | −0.001 (3) |
C18 | 0.085 (6) | 0.045 (4) | 0.062 (4) | −0.010 (4) | 0.023 (4) | −0.008 (3) |
C19 | 0.064 (5) | 0.045 (3) | 0.054 (4) | −0.004 (3) | 0.004 (3) | 0.011 (3) |
C20 | 0.074 (6) | 0.065 (4) | 0.060 (4) | −0.020 (4) | 0.023 (4) | −0.008 (4) |
C21 | 0.074 (6) | 0.094 (6) | 0.090 (6) | 0.022 (5) | 0.025 (5) | 0.004 (5) |
C22 | 0.101 (6) | 0.113 (6) | 0.149 (7) | 0.002 (5) | 0.045 (6) | −0.028 (6) |
Pd1—S1 | 2.2731 (18) | C9—H9A | 0.9700 |
Pd1—S2 | 2.284 (2) | C9—H9B | 0.9700 |
Pd1—Cl1 | 2.317 (2) | C10—C11 | 1.482 (8) |
Pd1—Cl2 | 2.3211 (18) | C10—H10A | 0.9700 |
Pd2—S4 | 2.2776 (17) | C10—H10B | 0.9700 |
Pd2—S3 | 2.283 (2) | C11—H11A | 0.9600 |
Pd2—Cl3 | 2.3229 (17) | C11—H11B | 0.9600 |
Pd2—Cl4 | 2.3276 (19) | C11—H11C | 0.9600 |
S1—C5 | 1.791 (7) | C12—C13 | 1.478 (13) |
S1—C4 | 1.838 (6) | C12—H12A | 0.9600 |
S2—C7 | 1.797 (7) | C12—H12B | 0.9600 |
S2—C8 | 1.815 (6) | C12—H12C | 0.9600 |
S3—C15 | 1.818 (7) | C13—C14 | 1.539 (11) |
S3—C16 | 1.830 (6) | C13—H13A | 0.9700 |
S4—C18 | 1.795 (7) | C13—H13B | 0.9700 |
S4—C19 | 1.825 (6) | C14—C15 | 1.534 (9) |
C1—C2 | 1.517 (12) | C14—H14A | 0.9700 |
C1—H1A | 0.9600 | C14—H14B | 0.9700 |
C1—H1B | 0.9600 | C15—H15A | 0.9700 |
C1—H1C | 0.9600 | C15—H15B | 0.9700 |
C2—C3 | 1.492 (8) | C16—C17 | 1.486 (9) |
C2—H2A | 0.9700 | C16—H16A | 0.9700 |
C2—H2B | 0.9700 | C16—H16B | 0.9700 |
C3—C4 | 1.508 (9) | C17—C18 | 1.510 (10) |
C3—H3A | 0.9700 | C17—H17A | 0.9700 |
C3—H3B | 0.9700 | C17—H17B | 0.9700 |
C4—H4A | 0.9700 | C18—H18A | 0.9700 |
C4—H4B | 0.9700 | C18—H18B | 0.9700 |
C5—C6 | 1.534 (10) | C19—C20 | 1.516 (8) |
C5—H5A | 0.9700 | C19—H19A | 0.9700 |
C5—H5B | 0.9700 | C19—H19B | 0.9700 |
C6—C7 | 1.514 (9) | C20—C21 | 1.532 (10) |
C6—H6A | 0.9700 | C20—H20A | 0.9700 |
C6—H6B | 0.9700 | C20—H20B | 0.9700 |
C7—H7A | 0.9700 | C21—C22 | 1.505 (10) |
C7—H7B | 0.9700 | C21—H21A | 0.9700 |
C8—C9 | 1.506 (10) | C21—H21B | 0.9700 |
C8—H8A | 0.9700 | C22—H22A | 0.9600 |
C8—H8B | 0.9700 | C22—H22B | 0.9600 |
C9—C10 | 1.480 (12) | C22—H22C | 0.9600 |
S1—Pd1—S2 | 101.01 (7) | C9—C10—C11 | 117.3 (9) |
S1—Pd1—Cl1 | 83.24 (8) | C9—C10—H10A | 108.0 |
S2—Pd1—Cl1 | 175.71 (7) | C11—C10—H10A | 108.0 |
S1—Pd1—Cl2 | 173.61 (7) | C9—C10—H10B | 108.0 |
S2—Pd1—Cl2 | 84.21 (7) | C11—C10—H10B | 108.0 |
Cl1—Pd1—Cl2 | 91.51 (7) | H10A—C10—H10B | 107.2 |
S4—Pd2—S3 | 99.44 (7) | C10—C11—H11A | 109.5 |
S4—Pd2—Cl3 | 173.84 (6) | C10—C11—H11B | 109.5 |
S3—Pd2—Cl3 | 86.69 (7) | H11A—C11—H11B | 109.5 |
S4—Pd2—Cl4 | 83.75 (7) | C10—C11—H11C | 109.5 |
S3—Pd2—Cl4 | 171.90 (6) | H11A—C11—H11C | 109.5 |
Cl3—Pd2—Cl4 | 90.10 (7) | H11B—C11—H11C | 109.5 |
C5—S1—C4 | 101.4 (3) | C13—C12—H12A | 109.5 |
C5—S1—Pd1 | 113.3 (3) | C13—C12—H12B | 109.5 |
C4—S1—Pd1 | 100.3 (2) | H12A—C12—H12B | 109.5 |
C7—S2—C8 | 100.4 (3) | C13—C12—H12C | 109.5 |
C7—S2—Pd1 | 114.6 (3) | H12A—C12—H12C | 109.5 |
C8—S2—Pd1 | 103.2 (2) | H12B—C12—H12C | 109.5 |
C15—S3—C16 | 99.9 (3) | C12—C13—C14 | 112.8 (8) |
C15—S3—Pd2 | 106.6 (2) | C12—C13—H13A | 109.0 |
C16—S3—Pd2 | 113.7 (2) | C14—C13—H13A | 109.0 |
C18—S4—C19 | 102.2 (3) | C12—C13—H13B | 109.0 |
C18—S4—Pd2 | 114.2 (2) | C14—C13—H13B | 109.0 |
C19—S4—Pd2 | 101.9 (2) | H13A—C13—H13B | 107.8 |
C2—C1—H1A | 109.5 | C15—C14—C13 | 112.2 (7) |
C2—C1—H1B | 109.5 | C15—C14—H14A | 109.2 |
H1A—C1—H1B | 109.5 | C13—C14—H14A | 109.2 |
C2—C1—H1C | 109.5 | C15—C14—H14B | 109.2 |
H1A—C1—H1C | 109.5 | C13—C14—H14B | 109.2 |
H1B—C1—H1C | 109.5 | H14A—C14—H14B | 107.9 |
C3—C2—C1 | 111.1 (8) | C14—C15—S3 | 112.3 (5) |
C3—C2—H2A | 109.4 | C14—C15—H15A | 109.1 |
C1—C2—H2A | 109.4 | S3—C15—H15A | 109.1 |
C3—C2—H2B | 109.4 | C14—C15—H15B | 109.1 |
C1—C2—H2B | 109.4 | S3—C15—H15B | 109.1 |
H2A—C2—H2B | 108.0 | H15A—C15—H15B | 107.9 |
C2—C3—C4 | 113.5 (7) | C17—C16—S3 | 114.5 (5) |
C2—C3—H3A | 108.9 | C17—C16—H16A | 108.6 |
C4—C3—H3A | 108.9 | S3—C16—H16A | 108.6 |
C2—C3—H3B | 108.9 | C17—C16—H16B | 108.6 |
C4—C3—H3B | 108.9 | S3—C16—H16B | 108.6 |
H3A—C3—H3B | 107.7 | H16A—C16—H16B | 107.6 |
C3—C4—S1 | 115.0 (5) | C16—C17—C18 | 115.4 (6) |
C3—C4—H4A | 108.5 | C16—C17—H17A | 108.4 |
S1—C4—H4A | 108.5 | C18—C17—H17A | 108.4 |
C3—C4—H4B | 108.5 | C16—C17—H17B | 108.4 |
S1—C4—H4B | 108.5 | C18—C17—H17B | 108.4 |
H4A—C4—H4B | 107.5 | H17A—C17—H17B | 107.5 |
C6—C5—S1 | 117.7 (5) | C17—C18—S4 | 117.4 (5) |
C6—C5—H5A | 107.9 | C17—C18—H18A | 108.0 |
S1—C5—H5A | 107.9 | S4—C18—H18A | 108.0 |
C6—C5—H5B | 107.9 | C17—C18—H18B | 108.0 |
S1—C5—H5B | 107.9 | S4—C18—H18B | 108.0 |
H5A—C5—H5B | 107.2 | H18A—C18—H18B | 107.2 |
C7—C6—C5 | 114.3 (6) | C20—C19—S4 | 113.3 (4) |
C7—C6—H6A | 108.7 | C20—C19—H19A | 108.9 |
C5—C6—H6A | 108.7 | S4—C19—H19A | 108.9 |
C7—C6—H6B | 108.7 | C20—C19—H19B | 108.9 |
C5—C6—H6B | 108.7 | S4—C19—H19B | 108.9 |
H6A—C6—H6B | 107.6 | H19A—C19—H19B | 107.7 |
C6—C7—S2 | 116.3 (5) | C19—C20—C21 | 114.0 (6) |
C6—C7—H7A | 108.2 | C19—C20—H20A | 108.7 |
S2—C7—H7A | 108.2 | C21—C20—H20A | 108.7 |
C6—C7—H7B | 108.2 | C19—C20—H20B | 108.7 |
S2—C7—H7B | 108.2 | C21—C20—H20B | 108.7 |
H7A—C7—H7B | 107.4 | H20A—C20—H20B | 107.6 |
C9—C8—S2 | 113.7 (5) | C22—C21—C20 | 112.5 (7) |
C9—C8—H8A | 108.8 | C22—C21—H21A | 109.1 |
S2—C8—H8A | 108.8 | C20—C21—H21A | 109.1 |
C9—C8—H8B | 108.8 | C22—C21—H21B | 109.1 |
S2—C8—H8B | 108.8 | C20—C21—H21B | 109.1 |
H8A—C8—H8B | 107.7 | H21A—C21—H21B | 107.8 |
C10—C9—C8 | 111.5 (8) | C21—C22—H22A | 109.5 |
C10—C9—H9A | 109.3 | C21—C22—H22B | 109.5 |
C8—C9—H9A | 109.3 | H22A—C22—H22B | 109.5 |
C10—C9—H9B | 109.3 | C21—C22—H22C | 109.5 |
C8—C9—H9B | 109.3 | H22A—C22—H22C | 109.5 |
H9A—C9—H9B | 108.0 | H22B—C22—H22C | 109.5 |
S2—Pd1—S1—C5 | −4.9 (3) | S1—C5—C6—C7 | −77.2 (7) |
Cl1—Pd1—S1—C5 | 175.7 (3) | C5—C6—C7—S2 | 75.3 (7) |
S2—Pd1—S1—C4 | 102.4 (3) | C8—S2—C7—C6 | 74.4 (6) |
Cl1—Pd1—S1—C4 | −77.0 (3) | Pd1—S2—C7—C6 | −35.5 (6) |
S1—Pd1—S2—C7 | 4.4 (3) | C7—S2—C8—C9 | 69.7 (7) |
Cl2—Pd1—S2—C7 | −179.4 (3) | Pd1—S2—C8—C9 | −171.8 (6) |
S1—Pd1—S2—C8 | −103.8 (2) | S2—C8—C9—C10 | 179.8 (7) |
S1—Pd1—S2—C8 | −103.8 (2) | C8—C9—C10—C11 | 168.2 (10) |
Cl2—Pd1—S2—C8 | 72.4 (2) | C12—C13—C14—C15 | 71.9 (11) |
S4—Pd2—S3—C15 | 125.1 (2) | C13—C14—C15—S3 | −171.2 (6) |
Cl3—Pd2—S3—C15 | −55.5 (2) | C16—S3—C15—C14 | −70.4 (6) |
S4—Pd2—S3—C16 | 16.0 (3) | Pd2—S3—C15—C14 | 171.0 (5) |
Cl3—Pd2—S3—C16 | −164.6 (3) | C15—S3—C16—C17 | −158.5 (5) |
S3—Pd2—S4—C18 | −13.5 (2) | Pd2—S3—C16—C17 | −45.3 (6) |
Cl4—Pd2—S4—C18 | 174.1 (2) | S3—C16—C17—C18 | 78.1 (7) |
S3—Pd2—S4—C19 | 95.9 (2) | C16—C17—C18—S4 | −75.7 (7) |
Cl4—Pd2—S4—C19 | −76.6 (2) | C19—S4—C18—C17 | −69.7 (6) |
C1—C2—C3—C4 | −175.6 (8) | Pd2—S4—C18—C17 | 39.5 (6) |
C2—C3—C4—S1 | −71.7 (9) | C18—S4—C19—C20 | −64.4 (5) |
C5—S1—C4—C3 | −71.3 (7) | Pd2—S4—C19—C20 | 177.3 (4) |
Pd1—S1—C4—C3 | 172.2 (6) | S4—C19—C20—C21 | −57.2 (7) |
C4—S1—C5—C6 | −69.6 (6) | C19—C20—C21—C22 | −173.8 (6) |
Pd1—S1—C5—C6 | 37.0 (6) |