The title complex, [Ni(C2H8N2)3](C10H6O6S2)·H2O or [Ni(en)3](2,6-nds)·H2O (en = ethylenediamine and nds = naphthalene-2,6-disulfonate), contains one [Ni(en)3]2+ cation, one water molecule, and two separate halves of centrosymmetric 2,6-nds2− dianions in the asymmetric unit. The anions lie on inversion centres. A three-dimensional open framework is assembled by means of hydrogen-bonding interactions between the anions and the cations, in which there is a channel parallel to the c axis, with one of the 2,6-nds dianions occupying the channel.
Supporting information
CCDC reference: 251574
Key indicators
- Single-crystal X-ray study
- T = 293 K
- R factor = 0.056
- wR factor = 0.159
- Data-to-parameter ratio = 16.1
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Ni1 - N1 .. 5.55 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Ni1 - N6 .. 5.72 su
PLAT420_ALERT_2_C D-H Without Acceptor N2 - H2N2 ... ?
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 14
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
4 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
3 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
1 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.
Bis[tris(ethylenediamine-
κ2N,
N')nickel(II)
bis{naphthalene-2,6-disulfonate) dihydrate
top
Crystal data top
[Ni(C2H8N2)3](C10H6O6S2)·H2O | F(000) = 1144 |
Mr = 543.30 | Dx = 1.541 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 18755 reflections |
a = 7.5989 (17) Å | θ = 3.0–27.4° |
b = 13.185 (4) Å | µ = 1.06 mm−1 |
c = 23.380 (5) Å | T = 293 K |
β = 91.527 (12)° | Prism, red |
V = 2341.7 (10) Å3 | 0.37 × 0.26 × 0.22 mm |
Z = 4 | |
Data collection top
Rigaku R-AXIS RAPID diffractometer | 5320 independent reflections |
Radiation source: fine-focus sealed tube | 4195 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.066 |
Detector resolution: 10 pixels mm-1 | θmax = 27.5°, θmin = 3.0° |
ω scans | h = −9→8 |
Absorption correction: multi-scan (ABSCOR; Higashi, 1995) | k = −17→17 |
Tmin = 0.696, Tmax = 0.801 | l = −30→30 |
19154 measured reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.056 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.159 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.06 | w = 1/[σ2(Fo2) + (0.0908P)2 + 1.0885P] where P = (Fo2 + 2Fc2)/3 |
5320 reflections | (Δ/σ)max = 0.001 |
331 parameters | Δρmax = 0.83 e Å−3 |
21 restraints | Δρmin = −0.54 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Ni1 | 0.05065 (5) | 0.49184 (3) | 0.68413 (2) | 0.0323 (1) | |
S1 | 0.4931 (1) | 0.29867 (6) | 0.56738 (3) | 0.0391 (2) | |
S2 | 0.0004 (1) | 0.09959 (6) | 0.32728 (3) | 0.0413 (2) | |
O1W | 0.2640 (4) | 0.4358 (2) | 0.4426 (1) | 0.0594 (7) | |
O1 | 0.6417 (4) | 0.3599 (2) | 0.5507 (1) | 0.0602 (7) | |
O2 | 0.3249 (4) | 0.3400 (2) | 0.5472 (1) | 0.0562 (7) | |
O3 | 0.4943 (3) | 0.2774 (2) | 0.62768 (9) | 0.0474 (6) | |
O4 | 0.1774 (4) | 0.1219 (2) | 0.3091 (1) | 0.0610 (7) | |
O5 | −0.0744 (4) | 0.0102 (2) | 0.3005 (1) | 0.0582 (8) | |
O6 | −0.1148 (4) | 0.1877 (2) | 0.3213 (1) | 0.0596 (7) | |
N1 | 0.2089 (4) | 0.3616 (2) | 0.6984 (1) | 0.0431 (6) | |
N2 | −0.1455 (4) | 0.3802 (2) | 0.6689 (1) | 0.0477 (7) | |
N3 | −0.0067 (4) | 0.5036 (2) | 0.7722 (1) | 0.0461 (7) | |
N4 | −0.1301 (4) | 0.6131 (2) | 0.6783 (1) | 0.0415 (6) | |
N5 | 0.1105 (4) | 0.5051 (2) | 0.5973 (1) | 0.0403 (6) | |
N6 | 0.2694 (4) | 0.5907 (2) | 0.6932 (1) | 0.0406 (6) | |
C1 | 0.0956 (6) | 0.2711 (3) | 0.6991 (2) | 0.0550 (9) | |
C2 | −0.0514 (6) | 0.2850 (3) | 0.6557 (2) | 0.0550 (9) | |
C3 | −0.1019 (5) | 0.5989 (3) | 0.7802 (2) | 0.0541 (9) | |
C4 | −0.2289 (5) | 0.6153 (3) | 0.7310 (2) | 0.0537 (9) | |
C5 | 0.3689 (5) | 0.5864 (3) | 0.6400 (2) | 0.0483 (8) | |
C6 | 0.2365 (5) | 0.5884 (3) | 0.5907 (1) | 0.0470 (8) | |
C7 | 0.4846 (4) | 0.0927 (2) | 0.5593 (1) | 0.0391 (7) | |
C8 | 0.5133 (4) | 0.1815 (2) | 0.5316 (1) | 0.0366 (7) | |
C9 | 0.5452 (5) | 0.1828 (3) | 0.4728 (1) | 0.0462 (8) | |
C10 | 0.5455 (5) | 0.0941 (3) | 0.4434 (1) | 0.0468 (8) | |
C11 | 0.5147 (5) | 0.0004 (2) | 0.4705 (1) | 0.0370 (7) | |
C12 | −0.0263 (5) | −0.0206 (3) | 0.4217 (2) | 0.0397 (7) | |
C13 | 0.0142 (4) | 0.0741 (2) | 0.4015 (1) | 0.0362 (6) | |
C14 | 0.0616 (5) | 0.1527 (3) | 0.4392 (1) | 0.0428 (7) | |
C15 | 0.0649 (5) | 0.1361 (3) | 0.4964 (1) | 0.0437 (7) | |
C16 | 0.0223 (4) | 0.0403 (2) | 0.5191 (1) | 0.0371 (7) | |
H1W1 | 0.297 (7) | 0.496 (2) | 0.450 (2) | 0.089* | |
H1W2 | 0.279 (7) | 0.399 (3) | 0.472 (1) | 0.089* | |
H1N1 | 0.269 (4) | 0.370 (3) | 0.7314 (8) | 0.065* | |
H1N2 | 0.296 (3) | 0.351 (3) | 0.674 (1) | 0.065* | |
H2N1 | −0.218 (4) | 0.398 (3) | 0.640 (1) | 0.072* | |
H2N2 | −0.220 (4) | 0.366 (4) | 0.697 (1) | 0.072* | |
H3N1 | 0.097 (3) | 0.498 (3) | 0.791 (2) | 0.069* | |
H3N2 | −0.068 (4) | 0.452 (2) | 0.787 (2) | 0.069* | |
H4N1 | −0.205 (4) | 0.609 (3) | 0.648 (1) | 0.062* | |
H4N2 | −0.079 (5) | 0.674 (2) | 0.672 (2) | 0.062* | |
H5N1 | 0.011 (3) | 0.512 (3) | 0.576 (2) | 0.061* | |
H5N2 | 0.157 (4) | 0.449 (2) | 0.582 (2) | 0.061* | |
H6N1 | 0.342 (4) | 0.576 (3) | 0.722 (1) | 0.061* | |
H6N2 | 0.245 (5) | 0.656 (1) | 0.699 (2) | 0.061* | |
H1B | 0.0481 | 0.2621 | 0.7368 | 0.066* | |
H1A | 0.1636 | 0.2113 | 0.6899 | 0.066* | |
H2B | −0.0045 | 0.2886 | 0.6176 | 0.066* | |
H2A | −0.1319 | 0.2280 | 0.6571 | 0.066* | |
H3B | −0.0191 | 0.6549 | 0.7825 | 0.065* | |
H3A | −0.1651 | 0.5965 | 0.8157 | 0.065* | |
H4B | −0.3176 | 0.5623 | 0.7303 | 0.064* | |
H4A | −0.2875 | 0.6802 | 0.7349 | 0.064* | |
H5B | 0.4384 | 0.5248 | 0.6389 | 0.058* | |
H5A | 0.4478 | 0.6441 | 0.6378 | 0.058* | |
H6B | 0.1747 | 0.6528 | 0.5901 | 0.056* | |
H6A | 0.2966 | 0.5811 | 0.5549 | 0.056* | |
H7 | 0.4642 | 0.0933 | 0.5983 | 0.047* | |
H9 | 0.5660 | 0.2437 | 0.4542 | 0.055* | |
H10 | 0.5665 | 0.0951 | 0.4044 | 0.056* | |
H12 | −0.0565 | −0.0721 | 0.3961 | 0.048* | |
H14 | 0.0907 | 0.2162 | 0.4250 | 0.051* | |
H15 | 0.0958 | 0.1888 | 0.5211 | 0.052* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Ni1 | 0.0351 (2) | 0.0291 (2) | 0.0328 (2) | −0.00049 (15) | 0.00123 (16) | −0.00110 (14) |
S1 | 0.0527 (5) | 0.0264 (4) | 0.0382 (4) | 0.0008 (3) | 0.0010 (3) | −0.0035 (3) |
S2 | 0.0517 (5) | 0.0369 (4) | 0.0352 (4) | 0.0032 (4) | −0.0015 (3) | −0.0005 (3) |
O1 | 0.079 (2) | 0.0413 (14) | 0.0607 (16) | −0.0216 (14) | 0.0149 (14) | −0.0091 (12) |
O2 | 0.0696 (18) | 0.0417 (14) | 0.0567 (15) | 0.0188 (13) | −0.0098 (12) | −0.0099 (11) |
O3 | 0.0662 (16) | 0.0382 (12) | 0.0377 (12) | 0.0041 (12) | 0.0021 (11) | −0.0034 (10) |
O4 | 0.0572 (16) | 0.072 (2) | 0.0542 (15) | −0.0029 (15) | 0.0137 (12) | 0.0047 (14) |
O5 | 0.085 (2) | 0.0488 (16) | 0.0405 (13) | −0.0074 (13) | −0.0104 (13) | −0.0067 (10) |
O6 | 0.0794 (19) | 0.0496 (16) | 0.0494 (14) | 0.0204 (14) | −0.0044 (13) | 0.0044 (11) |
O1W | 0.078 (2) | 0.0478 (16) | 0.0514 (15) | −0.0044 (15) | −0.0139 (13) | 0.0031 (12) |
N1 | 0.0468 (16) | 0.0409 (15) | 0.0415 (14) | 0.0023 (13) | −0.0016 (12) | 0.0003 (12) |
N2 | 0.0421 (16) | 0.0409 (16) | 0.0598 (18) | −0.0044 (13) | −0.0029 (13) | 0.0013 (14) |
N3 | 0.0511 (18) | 0.0527 (19) | 0.0345 (15) | 0.0024 (14) | 0.0007 (13) | 0.0033 (12) |
N4 | 0.0409 (15) | 0.0383 (15) | 0.0451 (15) | 0.0027 (12) | −0.0010 (12) | −0.0019 (12) |
N5 | 0.0475 (17) | 0.0396 (15) | 0.0340 (14) | 0.0008 (12) | 0.0025 (12) | −0.0044 (11) |
N6 | 0.0426 (15) | 0.0373 (15) | 0.0417 (14) | 0.0007 (12) | −0.0016 (11) | −0.0008 (11) |
C1 | 0.067 (3) | 0.0351 (18) | 0.063 (2) | −0.0017 (17) | 0.0013 (19) | 0.0106 (16) |
C2 | 0.061 (2) | 0.0377 (18) | 0.066 (2) | −0.0137 (17) | −0.0005 (18) | −0.0003 (17) |
C3 | 0.062 (2) | 0.057 (2) | 0.0432 (18) | 0.0096 (19) | 0.0053 (16) | −0.0135 (16) |
C4 | 0.050 (2) | 0.055 (2) | 0.056 (2) | 0.0176 (18) | 0.0111 (16) | −0.0043 (17) |
C5 | 0.0421 (18) | 0.049 (2) | 0.055 (2) | −0.0076 (16) | 0.0098 (15) | 0.0051 (16) |
C6 | 0.059 (2) | 0.0416 (19) | 0.0410 (17) | −0.0030 (16) | 0.0094 (15) | 0.0049 (14) |
C7 | 0.0513 (19) | 0.0304 (15) | 0.0356 (15) | −0.0002 (13) | 0.0028 (13) | −0.0011 (12) |
C8 | 0.0431 (17) | 0.0281 (14) | 0.0385 (15) | 0.0010 (13) | 0.0022 (13) | −0.0021 (12) |
C9 | 0.068 (2) | 0.0277 (15) | 0.0429 (17) | −0.0044 (15) | 0.0071 (16) | 0.0028 (13) |
C10 | 0.074 (2) | 0.0320 (16) | 0.0350 (15) | −0.0006 (16) | 0.0125 (15) | −0.0001 (13) |
C11 | 0.0446 (18) | 0.0308 (16) | 0.0359 (16) | 0.0021 (13) | 0.0047 (13) | −0.0013 (11) |
C12 | 0.0473 (19) | 0.0356 (16) | 0.0359 (15) | 0.0001 (14) | −0.0030 (13) | −0.0067 (12) |
C13 | 0.0398 (16) | 0.0341 (15) | 0.0343 (14) | 0.0023 (13) | −0.0039 (12) | −0.0027 (12) |
C14 | 0.054 (2) | 0.0319 (16) | 0.0422 (16) | −0.0018 (14) | 0.0004 (14) | 0.0028 (13) |
C15 | 0.057 (2) | 0.0334 (16) | 0.0405 (16) | −0.0066 (15) | −0.0033 (14) | −0.0055 (13) |
C16 | 0.0434 (17) | 0.0311 (15) | 0.0366 (15) | 0.0008 (13) | −0.0033 (12) | −0.0032 (13) |
Geometric parameters (Å, º) top
Ni1—N5 | 2.101 (3) | C1—H1B | 0.9700 |
Ni1—N4 | 2.109 (3) | C1—H1A | 0.9700 |
Ni1—N1 | 2.117 (3) | C2—H2B | 0.9700 |
Ni1—N6 | 2.119 (3) | C2—H2A | 0.9700 |
Ni1—N2 | 2.118 (3) | C3—C4 | 1.496 (5) |
Ni1—N3 | 2.122 (3) | C3—H3B | 0.9700 |
S1—O3 | 1.437 (2) | C3—H3A | 0.9700 |
S1—O1 | 1.450 (3) | C4—H4B | 0.9700 |
S1—O2 | 1.457 (3) | C4—H4A | 0.9700 |
S1—C8 | 1.766 (3) | C5—C6 | 1.509 (5) |
S2—O5 | 1.444 (3) | C5—H5B | 0.9700 |
S2—O4 | 1.452 (3) | C5—H5A | 0.9700 |
S2—O6 | 1.459 (3) | C6—H6B | 0.9700 |
S2—C13 | 1.768 (3) | C6—H6A | 0.9700 |
O1W—H1W1 | 0.85 (3) | C7—C8 | 1.358 (4) |
O1W—H1W2 | 0.85 (3) | C7—C11i | 1.411 (4) |
N1—C1 | 1.472 (5) | C7—H7 | 0.9300 |
N1—H1N1 | 0.89 (3) | C8—C9 | 1.401 (5) |
N1—H1N2 | 0.89 (3) | C9—C10 | 1.357 (5) |
N2—C2 | 1.481 (5) | C9—H9 | 0.9300 |
N2—H2N1 | 0.89 (3) | C10—C11 | 1.410 (4) |
N2—H2N2 | 0.89 (3) | C10—H10 | 0.9300 |
N3—C3 | 1.465 (5) | C11—C11i | 1.405 (6) |
N3—H3N1 | 0.90 (3) | C11—C7i | 1.411 (4) |
N3—H3N2 | 0.90 (3) | C12—C13 | 1.372 (4) |
N4—C4 | 1.460 (4) | C12—C16ii | 1.407 (4) |
N4—H4N1 | 0.90 (3) | C12—H12 | 0.9300 |
N4—H4N2 | 0.90 (3) | C13—C14 | 1.401 (4) |
N5—C6 | 1.468 (5) | C14—C15 | 1.353 (4) |
N5—H5N1 | 0.90 (3) | C14—H14 | 0.9300 |
N5—H5N2 | 0.90 (3) | C15—C16 | 1.412 (5) |
N6—C5 | 1.473 (4) | C15—H15 | 0.9300 |
N6—H6N1 | 0.89 (3) | C16—C12ii | 1.407 (4) |
N6—H6N2 | 0.89 (3) | C16—C16ii | 1.424 (6) |
C1—C2 | 1.500 (6) | | |
| | | |
N1—Ni1—N6 | 92.44 (11) | C2—N2—H2N2 | 107 (3) |
N1—Ni1—N2 | 81.80 (12) | C2—C1—H1B | 110.0 |
N1—Ni1—N3 | 92.13 (12) | C3—N3—Ni1 | 107.5 (2) |
N2—Ni1—N3 | 93.01 (13) | C3—N3—H3N1 | 116 (3) |
N4—Ni1—N1 | 172.15 (11) | C3—N3—H3N2 | 110 (3) |
N4—Ni1—N6 | 92.74 (12) | C3—C4—H4B | 110.1 |
N4—Ni1—N2 | 93.53 (13) | C3—C4—H4A | 110.1 |
N4—Ni1—N3 | 81.77 (11) | C4—C3—H3B | 109.7 |
N5—Ni1—N2 | 93.71 (12) | C4—C3—H3A | 109.7 |
N5—Ni1—N6 | 81.68 (11) | C4—N4—Ni1 | 108.0 (2) |
N5—Ni1—N4 | 91.83 (11) | C4—N4—H4N1 | 110 (3) |
N5—Ni1—N1 | 94.76 (11) | C4—N4—H4N2 | 111 (3) |
N5—Ni1—N3 | 170.99 (12) | C5—N6—Ni1 | 108.2 (2) |
N6—Ni1—N2 | 172.33 (12) | C5—N6—H6N1 | 109 (3) |
N6—Ni1—N3 | 92.26 (12) | C5—N6—H6N2 | 107 (3) |
Ni1—N1—H1N1 | 108 (3) | C5—C6—H6B | 109.8 |
Ni1—N1—H1N2 | 117 (3) | C5—C6—H6A | 109.8 |
Ni1—N2—H2N1 | 111 (3) | C6—N5—Ni1 | 108.8 (2) |
Ni1—N2—H2N2 | 119 (3) | C6—N5—H5N1 | 114 (3) |
Ni1—N3—H3N1 | 106 (3) | C6—N5—H5N2 | 108 (3) |
Ni1—N3—H3N2 | 116 (3) | C6—C5—H5B | 110.3 |
Ni1—N4—H4N1 | 114 (3) | C6—C5—H5A | 110.3 |
Ni1—N4—H4N2 | 114 (3) | C7—C8—C9 | 120.8 (3) |
Ni1—N5—H5N1 | 110 (3) | C7—C8—S1 | 120.7 (2) |
Ni1—N5—H5N2 | 114 (3) | C8—C7—C11i | 120.8 (3) |
Ni1—N6—H6N1 | 114 (3) | C8—C7—H7 | 119.6 |
Ni1—N6—H6N2 | 116 (3) | C8—C9—H9 | 120.3 |
N1—C1—C2 | 108.6 (3) | C9—C10—C11 | 121.6 (3) |
N1—C1—H1B | 110.0 | C9—C10—H10 | 119.2 |
N1—C1—H1A | 110.0 | C9—C8—S1 | 118.3 (2) |
N2—C2—C1 | 108.5 (3) | C10—C9—C8 | 119.3 (3) |
N2—C2—H2B | 110.0 | C10—C9—H9 | 120.3 |
N2—C2—H2A | 110.0 | C10—C11—C7i | 122.5 (3) |
N3—C3—H3B | 109.7 | C11—C10—H10 | 119.2 |
N3—C3—H3A | 109.7 | C11i—C11—C10 | 118.7 (3) |
N3—C3—C4 | 109.6 (3) | C11i—C11—C7i | 118.7 (3) |
N4—C4—C3 | 108.0 (3) | C11i—C7—H7 | 119.6 |
N4—C4—H4B | 110.1 | C12ii—C16—C15 | 122.5 (3) |
N4—C4—H4A | 110.1 | C12ii—C16—C16ii | 118.6 (4) |
N5—C6—C5 | 109.3 (3) | C12—C13—C14 | 120.8 (3) |
N5—C6—H6B | 109.8 | C12—C13—S2 | 120.2 (2) |
N5—C6—H6A | 109.8 | C13—C12—C16ii | 120.4 (3) |
N6—C5—C6 | 107.3 (3) | C13—C12—H12 | 119.8 |
N6—C5—H5B | 110.3 | C13—C14—H14 | 120.0 |
N6—C5—H5A | 110.3 | C14—C15—C16 | 121.2 (3) |
O3—S1—O1 | 112.82 (17) | C14—C15—H15 | 119.4 |
O3—S1—O2 | 111.89 (16) | C14—C13—S2 | 119.0 (2) |
O1—S1—O2 | 112.79 (18) | C15—C14—C13 | 120.0 (3) |
O3—S1—C8 | 107.22 (15) | C15—C14—H14 | 120.0 |
O1—S1—C8 | 106.38 (15) | C15—C16—C16ii | 118.9 (4) |
O2—S1—C8 | 105.11 (15) | C16—C15—H15 | 119.4 |
O5—S2—O4 | 113.30 (19) | C16ii—C12—H12 | 119.8 |
O5—S2—O6 | 112.36 (18) | H1N1—N1—H1N2 | 101.8 (15) |
O4—S2—O6 | 111.67 (18) | H1W1—O1W—H1W2 | 110 (4) |
O5—S2—C13 | 106.39 (16) | H2N1—N2—H2N2 | 102.6 (15) |
O4—S2—C13 | 107.13 (16) | H3N1—N3—H3N2 | 102.3 (15) |
O6—S2—C13 | 105.37 (15) | H4N1—N4—H4N2 | 101 (3) |
C1—N1—Ni1 | 109.2 (2) | H5N1—N5—H5N2 | 102 (3) |
C1—N1—H1N1 | 112 (3) | H6N1—N6—H6N2 | 102 (3) |
C1—N1—H1N2 | 108 (3) | H1B—C1—H1A | 108.4 |
C1—C2—H2B | 110.0 | H2B—C2—H2A | 108.4 |
C1—C2—H2A | 110.0 | H3B—C3—H3A | 108.2 |
C2—C1—H1A | 110.0 | H4B—C4—H4A | 108.4 |
C2—N2—Ni1 | 106.4 (2) | H5B—C5—H5A | 108.5 |
C2—N2—H2N1 | 111 (3) | H6B—C6—H6A | 108.3 |
| | | |
Ni1—N1—C1—C2 | 36.4 (4) | N3—Ni1—N1—C1 | 84.0 (2) |
Ni1—N2—C2—C1 | 46.4 (3) | N3—Ni1—N6—C5 | 169.2 (2) |
Ni1—N3—C3—C4 | 39.7 (4) | N3—Ni1—N2—C2 | −112.2 (2) |
Ni1—N4—C4—C3 | 43.2 (4) | N3—C3—C4—N4 | −56.4 (4) |
Ni1—N6—C5—C6 | 43.1 (3) | N4—Ni1—N2—C2 | 165.9 (2) |
Ni1—N5—C6—C5 | 39.5 (3) | N4—Ni1—N3—C3 | −12.3 (3) |
S1—C8—C9—C10 | −174.1 (3) | N4—Ni1—N5—C6 | 80.4 (2) |
S2—C13—C14—C15 | 176.9 (3) | N4—Ni1—N6—C5 | −108.9 (2) |
O1—S1—C8—C7 | 136.7 (3) | N5—Ni1—N2—C2 | 73.8 (2) |
O1—S1—C8—C7 | 136.7 (3) | N5—Ni1—N1—C1 | −101.8 (2) |
O1—S1—C8—C7 | 136.7 (3) | N5—N1—N4—C4 | 170.9 (2) |
O1—S1—C8—C9 | −48.5 (3) | N5—Ni1—N6—C5 | −17.5 (2) |
O2—S1—C8—C9 | 71.4 (3) | N6—Ni1—N4—C4 | −109.0 (2) |
O3—S1—C8—C7 | 15.7 (3) | N6—Ni1—N1—C1 | 176.3 (2) |
O4—S2—C13—C12 | −115.4 (3) | N6—Ni1—N3—C3 | 80.1 (3) |
O4—S2—C13—C14 | 66.5 (3) | N6—Ni1—N5—C6 | −12.1 (2) |
O5—S2—C13—C12 | 6.1 (3) | N6—C5—C6—N5 | −55.6 (4) |
O5—S2—C13—C14 | −172.0 (3) | C7—C8—C9—C10 | 0.7 (6) |
O6—S2—C13—C14 | −52.5 (3) | C8—C9—C10—C11 | −0.1 (6) |
O6—S2—C13—C12 | 125.5 (3) | C9—C10—C11—C11i | −0.8 (7) |
N1—Ni1—N2—C2 | −20.5 (2) | C9—C10—C11—C7i | −179.6 (4) |
N1—Ni1—N3—C3 | 172.6 (3) | C11i—C7—C8—C9 | −0.3 (5) |
N1—Ni1—N5—C6 | −103.9 (2) | C11i—C7—C8—S1 | 174.4 (3) |
N1—Ni1—N6—C5 | 77.0 (2) | C12—C13—C14—C15 | −1.1 (5) |
N1—C1—C2—N2 | −56.2 (4) | C13—C14—C15—C16 | 0.4 (6) |
N2—Ni1—N1—C1 | −8.8 (2) | C14—C15—C16—C12ii | 179.4 (3) |
N2—Ni1—N3—C3 | −105.5 (3) | C14—C15—C16—C16ii | 0.9 (6) |
N2—Ni1—N4—C4 | 75.4 (3) | C16ii—C12—C13—C14 | 0.5 (5) |
N2—Ni1—N5—C6 | 174.0 (2) | C16ii—C12—C13—S2 | −177.5 (3) |
N3—Ni1—N4—C4 | −17.1 (2) | | |
Symmetry codes: (i) −x+1, −y, −z+1; (ii) −x, −y, −z+1. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O1W—H1W1···O1iii | 0.85 (3) | 1.95 (3) | 2.790 (4) | 168 (4) |
O1W—H1W2···O2 | 0.85 (3) | 1.94 (3) | 2.781 (4) | 169 (4) |
N1—H1N1···O6iv | 0.89 (3) | 2.38 (2) | 3.206 (4) | 153 (4) |
N1—H1N1···O5iv | 0.89 (3) | 2.53 (3) | 3.326 (4) | 148 (4) |
N1—H1N2···O3 | 0.89 (3) | 2.11 (3) | 2.977 (4) | 161 (4) |
N2—H2N1···O1v | 0.89 (3) | 2.37 (3) | 3.175 (4) | 150 (4) |
N3—H3N1···O5iv | 0.90 (3) | 2.50 (2) | 3.339 (5) | 155 (4) |
N3—H3N2···O4vi | 0.90 (3) | 2.24 (3) | 3.058 (4) | 151 (3) |
N4—H4N1···O1Wvii | 0.90 (3) | 2.23 (2) | 3.049 (4) | 151 (4) |
N4—H4N2···O6vii | 0.90 (3) | 2.35 (3) | 3.219 (4) | 161 (3) |
N5—H5N1···O1Wvii | 0.90 (3) | 2.23 (3) | 3.071 (5) | 156 (3) |
N5—H5N2···O2 | 0.90 (3) | 2.10 (3) | 2.977 (4) | 165 (3) |
N6—H6N1···O5iv | 0.89 (3) | 2.22 (3) | 3.054 (4) | 155 (4) |
N6—H6N2···O6vii | 0.89 (3) | 2.33 (3) | 3.163 (4) | 155 (3) |
Symmetry codes: (iii) −x+1, −y+1, −z+1; (iv) x+1/2, −y+1/2, z+1/2; (v) x−1, y, z; (vi) x−1/2, −y+1/2, z+1/2; (vii) −x, −y+1, −z+1. |