2,5-Bis­[(cyclo­pentyl­di­phenyl­stannyl)­sulfanyl]-1,3,4-thia­diazo­le

The two Sn atoms in the title compound, [Sn₂(C₅H₉)₂(C₆H₅)₄(C₂N₂S₃)], exist in tetrahedral geometries.

Key indicators

• Single-crystal X-ray study
• T = 298 K
• Mean [sigma](N-C) = 0.011 Å
• R factor = 0.031
• wR factor = 0.071
• Data-to-parameter ratio = 8.8

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT034_ALERT_1_C No Flack Parameter Given. Z .GT. Si, NonCentro .          ?
PLAT165_ALERT_3_C Nr. of Status R Flagged Non-Hydrogen Atoms .....         24
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....         S1
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C15
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....       C15'
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C24
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C34
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....       C34'
PLAT301_ALERT_3_C Main Residue  Disorder .........................      19.00 Perc.
PLAT322_ALERT_2_C Check Hybridisation of  S2     in Main Residue .          ?

Alert level G
REFLT03_ALERT_4_G  WARNING: Large fraction of Friedel related reflns may
                     be needed to determine absolute structure
           From the CIF: _diffrn_reflns_theta_max           25.00
           From the CIF: _reflns_number_total               3207
           Count of symmetry unique reflns         3218
           Completeness (_total/calc)             99.66%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured         0
           Fraction of Friedel pairs measured     0.000
           Are heavy atom types Z>Si present          yes

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  10 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   7 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: CAD-4-PC (Kretschmar, 1994); cell refinement: CAD-4 VAX/PC Fortran System (Enraf-Nonius, 1988); data reduction: XCAD4 (Harms, 1997) in WinGX (Farrugia, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

2,5-Bis[(cyclopentyldiphenylstannyl)sulfanyl]-1,3,4-thiadiazole

Crystal data

[Sn2(C5H9)2(C6H5)4(C2N2S3)]	F(000) = 832
Mr = 832.24	Dx = 1.561 Mg m^−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2yb	Cell parameters from 25 reflections
a = 9.968 (1) Å	θ = 12.0–14.0°
b = 18.381 (2) Å	µ = 1.61 mm^−1
c = 10.215 (1) Å	T = 298 K
β = 108.883 (6)°	Block, colorless
V = 1771.0 (3) Å^3	0.3 × 0.3 × 0.2 mm
Z = 2

Data collection

Enraf-Nonius CAD-4 diffractometer	2788 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.016
Graphite monochromator	θmax = 25.0°, θmin = 2.1°
ω–2θ scans	h = −11→0
Absorption correction: empirical (using intensity measurements) via ψ scan (North et al., 1968)	k = −21→0
Tmin = 0.648, Tmax = 0.724	l = −11→12
3400 measured reflections	3 standard reflections every 60 min
3207 independent reflections	intensity decay: 2%

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.031	H-atom parameters constrained
wR(F^2) = 0.071	w = 1/[σ^2(Fo^2) + (0.0413P)^2] where P = (Fo^2 + 2Fc^2)/3
S = 0.97	(Δ/σ)max = 0.001
3207 reflections	Δρmax = 0.30 e Å^−3
365 parameters	Δρmin = −0.26 e Å^−3
47 restraints	Absolute structure: Flack (1983), no Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.00 (7)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Sn1	0.92198 (5)	0.50030 (3)	0.75752 (5)	0.05125 (15)
Sn2	0.75379 (5)	0.12829 (3)	0.57793 (5)	0.05372 (16)
S1	0.7576 (3)	0.46278 (15)	0.8828 (3)	0.0734 (7)
S2	0.6557 (3)	0.30648 (14)	0.8866 (2)	0.0683 (6)
S3	0.6518 (2)	0.15560 (14)	0.7633 (3)	0.0673 (6)
N1	0.8011 (7)	0.3488 (4)	0.7383 (7)	0.0622 (18)
N2	0.7736 (7)	0.2763 (4)	0.7079 (7)	0.0600 (17)
C1	1.1264 (4)	0.4568 (3)	0.8673 (5)	0.055 (2)
C2	1.1551 (5)	0.3827 (3)	0.8748 (5)	0.065 (2)
H2	1.0829	0.3496	0.8343	0.078*
C3	1.2916 (6)	0.3579 (3)	0.9430 (6)	0.082 (3)
H3	1.3108	0.3083	0.9480	0.098*
C4	1.3995 (4)	0.4072 (4)	1.0036 (5)	0.085 (3)
H4	1.4908	0.3907	1.0492	0.103*
C5	1.3708 (5)	0.4814 (3)	0.9961 (5)	0.077 (3)
H5	1.4429	0.5144	1.0367	0.092*
C6	1.2342 (5)	0.5062 (3)	0.9280 (5)	0.066 (2)
H6	1.2150	0.5558	0.9229	0.080*
C7	0.9336 (5)	0.6141 (2)	0.8048 (5)	0.054 (2)
C8	0.9607 (6)	0.6372 (3)	0.9404 (5)	0.069 (2)
H8	0.9714	0.6032	1.0106	0.083*
C9	0.9719 (7)	0.7111 (4)	0.9713 (5)	0.086 (3)
H9	0.9901	0.7265	1.0621	0.103*
C10	0.9559 (6)	0.7618 (3)	0.8665 (7)	0.080 (3)
H10	0.9634	0.8112	0.8871	0.096*
C11	0.9288 (6)	0.7387 (3)	0.7308 (6)	0.075 (3)
H11	0.9181	0.7727	0.6607	0.090*
C12	0.9176 (6)	0.6649 (3)	0.6999 (4)	0.067 (2)
H12	0.8994	0.6494	0.6091	0.080*
C13	0.8470 (6)	0.4835 (4)	0.5386 (6)	0.055 (2)	0.50
H13	0.8540	0.5306	0.4962	0.065*	0.50
C14	0.924 (3)	0.4285 (12)	0.477 (3)	0.063 (5)	0.50
H14A	1.0003	0.4518	0.4530	0.076*	0.50
H14B	0.9634	0.3896	0.5420	0.076*	0.50
C15	0.812 (5)	0.399 (2)	0.348 (4)	0.104 (4)	0.50
H15A	0.8128	0.4264	0.2667	0.124*	0.50
H15B	0.8304	0.3483	0.3337	0.124*	0.50
C16	0.671 (4)	0.408 (2)	0.373 (3)	0.102 (11)	0.50
H16A	0.5995	0.4244	0.2891	0.122*	0.50
H16B	0.6409	0.3612	0.3990	0.122*	0.50
C17	0.6915 (11)	0.4625 (16)	0.488 (3)	0.064 (6)	0.50
H17A	0.6645	0.4414	0.5625	0.076*	0.50
H17B	0.6331	0.5050	0.4535	0.076*	0.50
C13'	0.8470 (6)	0.4835 (4)	0.5386 (6)	0.055 (2)	0.50
H13B	0.8848	0.5239	0.4984	0.065*	0.50
C14'	0.909 (3)	0.4139 (10)	0.498 (3)	0.063 (5)	0.50
H14C	1.0048	0.4221	0.4981	0.076*	0.50
H14D	0.9096	0.3748	0.5624	0.076*	0.50
C15'	0.811 (5)	0.395 (2)	0.354 (3)	0.104 (4)	0.50
H15C	0.8504	0.4137	0.2846	0.124*	0.50
H15D	0.8006	0.3429	0.3427	0.124*	0.50
C16'	0.670 (4)	0.431 (2)	0.337 (3)	0.102 (11)	0.50
H16C	0.5996	0.3937	0.3345	0.122*	0.50
H16D	0.6384	0.4581	0.2518	0.122*	0.50
C17'	0.6889 (11)	0.4806 (16)	0.460 (3)	0.064 (6)	0.50
H17C	0.6376	0.4619	0.5188	0.076*	0.50
H17D	0.6532	0.5288	0.4285	0.076*	0.50
C18	0.7455 (8)	0.3725 (5)	0.8276 (8)	0.0548 (19)
C19	0.7011 (8)	0.2467 (5)	0.7787 (8)	0.0538 (19)
C20	0.9765 (4)	0.1451 (3)	0.6541 (5)	0.058 (2)
C21	1.0339 (7)	0.2099 (3)	0.6265 (6)	0.078 (3)
H21	0.9748	0.2460	0.5745	0.094*
C22	1.1796 (8)	0.2210 (4)	0.6765 (7)	0.106 (4)
H22	1.2180	0.2643	0.6579	0.127*
C23	1.2680 (5)	0.1671 (5)	0.7541 (7)	0.112 (5)
H23	1.3655	0.1745	0.7876	0.135*
C24	1.2106 (6)	0.1023 (5)	0.7818 (6)	0.114 (5)
H24	1.2697	0.0663	0.8338	0.137*
C25	1.0649 (6)	0.0913 (3)	0.7318 (6)	0.075 (3)
H25	1.0265	0.0479	0.7503	0.090*
C26	0.7115 (6)	0.0139 (2)	0.5572 (5)	0.052 (2)
C27	0.7218 (6)	−0.0293 (3)	0.6716 (4)	0.075 (3)
H27	0.7479	−0.0087	0.7595	0.090*
C28	0.6930 (7)	−0.1034 (3)	0.6549 (7)	0.088 (3)
H28	0.6999	−0.1323	0.7314	0.105*
C29	0.6540 (8)	−0.1342 (3)	0.5236 (8)	0.090 (3)
H29	0.6347	−0.1837	0.5124	0.108*
C30	0.6437 (7)	−0.0910 (3)	0.4091 (6)	0.086 (3)
H30	0.6176	−0.1116	0.3213	0.103*
C31	0.6724 (6)	−0.0169 (3)	0.4259 (5)	0.065 (2)
H31	0.6655	0.0120	0.3493	0.078*
C32	0.6357 (7)	0.1858 (5)	0.3977 (6)	0.067 (2)	0.50
H32	0.6534	0.2378	0.4167	0.080*	0.50
C33	0.6747 (15)	0.1678 (15)	0.2680 (14)	0.067 (5)	0.50
H33A	0.7522	0.1984	0.2629	0.080*	0.50
H33B	0.7030	0.1173	0.2690	0.080*	0.50
C34	0.543 (2)	0.182 (2)	0.1466 (9)	0.105 (7)	0.50
H34A	0.5558	0.2253	0.0970	0.126*	0.50
H34B	0.5231	0.1414	0.0834	0.126*	0.50
C35	0.4210 (16)	0.1938 (18)	0.2017 (16)	0.094 (6)	0.50
H35A	0.3415	0.1630	0.1528	0.113*	0.50
H35B	0.3901	0.2441	0.1900	0.113*	0.50
C36	0.4752 (11)	0.174 (2)	0.3543 (17)	0.090 (9)	0.50
H36A	0.4534	0.1237	0.3681	0.108*	0.50
H36B	0.4330	0.2051	0.4071	0.108*	0.50
C32'	0.6357 (7)	0.1858 (5)	0.3977 (6)	0.067 (2)	0.50
H32B	0.6292	0.2362	0.4264	0.080*	0.50
C33'	0.7016 (15)	0.1887 (16)	0.2825 (14)	0.067 (5)	0.50
H33C	0.7657	0.2298	0.2953	0.080*	0.50
H33D	0.7539	0.1444	0.2807	0.080*	0.50
C34'	0.577 (3)	0.197 (2)	0.1497 (10)	0.105 (7)	0.50
H34C	0.5576	0.2480	0.1274	0.126*	0.50
H34D	0.5980	0.1735	0.0733	0.126*	0.50
C35'	0.4526 (14)	0.1607 (17)	0.1767 (14)	0.094 (6)	0.50
H35C	0.3663	0.1879	0.1326	0.113*	0.50
H35D	0.4404	0.1116	0.1399	0.113*	0.50
C36'	0.4839 (16)	0.159 (2)	0.3316 (16)	0.094 (6)	0.50
H36C	0.4738	0.1103	0.3622	0.113*	0.50
H36D	0.4186	0.1908	0.3575	0.113*	0.50

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Sn1	0.0508 (3)	0.0541 (3)	0.0468 (3)	0.0008 (3)	0.0130 (2)	0.0044 (3)
Sn2	0.0461 (3)	0.0582 (3)	0.0543 (3)	−0.0010 (3)	0.0129 (2)	−0.0021 (3)
S1	0.0893 (17)	0.0573 (13)	0.0905 (16)	−0.0066 (12)	0.0526 (14)	−0.0080 (12)
S2	0.0821 (16)	0.0577 (13)	0.0861 (15)	0.0018 (12)	0.0564 (13)	0.0021 (12)
S3	0.0692 (14)	0.0569 (13)	0.0893 (16)	−0.0039 (11)	0.0444 (12)	−0.0024 (11)
N1	0.062 (4)	0.059 (5)	0.076 (5)	0.004 (4)	0.036 (4)	0.005 (4)
N2	0.061 (4)	0.062 (5)	0.067 (4)	0.006 (4)	0.035 (4)	0.000 (4)
C1	0.060 (5)	0.065 (5)	0.037 (4)	0.005 (4)	0.012 (4)	0.004 (4)
C2	0.068 (6)	0.060 (6)	0.063 (5)	0.008 (5)	0.015 (4)	0.008 (4)
C3	0.086 (7)	0.080 (7)	0.070 (6)	0.024 (6)	0.012 (5)	−0.005 (5)
C4	0.080 (7)	0.115 (9)	0.053 (5)	0.031 (7)	0.010 (5)	−0.017 (5)
C5	0.060 (5)	0.088 (8)	0.073 (6)	0.008 (5)	0.010 (4)	−0.011 (5)
C6	0.059 (5)	0.069 (6)	0.066 (5)	0.007 (5)	0.013 (4)	−0.004 (5)
C7	0.041 (4)	0.058 (6)	0.060 (5)	0.002 (4)	0.011 (3)	0.018 (4)
C8	0.080 (6)	0.063 (6)	0.057 (5)	0.004 (5)	0.010 (4)	0.005 (5)
C9	0.084 (7)	0.078 (7)	0.085 (7)	−0.006 (6)	0.011 (5)	−0.029 (6)
C10	0.074 (6)	0.051 (5)	0.114 (8)	−0.006 (5)	0.029 (6)	−0.007 (6)
C11	0.082 (7)	0.066 (6)	0.084 (7)	0.008 (5)	0.037 (5)	0.024 (5)
C12	0.069 (6)	0.060 (6)	0.075 (6)	0.002 (5)	0.030 (5)	0.004 (5)
C13	0.056 (4)	0.063 (6)	0.044 (4)	−0.001 (4)	0.015 (3)	0.002 (4)
C14	0.068 (7)	0.077 (8)	0.053 (7)	−0.004 (6)	0.031 (5)	0.013 (7)
C15	0.145 (11)	0.087 (8)	0.079 (7)	−0.007 (8)	0.036 (8)	−0.023 (7)
C16	0.081 (9)	0.11 (2)	0.098 (17)	−0.019 (13)	0.002 (11)	−0.008 (17)
C17	0.062 (5)	0.075 (15)	0.041 (11)	0.013 (6)	−0.002 (5)	0.024 (10)
C13'	0.056 (4)	0.063 (6)	0.044 (4)	−0.001 (4)	0.015 (3)	0.002 (4)
C14'	0.068 (7)	0.077 (8)	0.053 (7)	−0.004 (6)	0.031 (5)	0.013 (7)
C15'	0.145 (11)	0.087 (8)	0.079 (7)	−0.007 (8)	0.036 (8)	−0.023 (7)
C16'	0.081 (9)	0.11 (2)	0.098 (17)	−0.019 (13)	0.002 (11)	−0.008 (17)
C17'	0.062 (5)	0.075 (15)	0.041 (11)	0.013 (6)	−0.002 (5)	0.024 (10)
C18	0.053 (4)	0.058 (5)	0.060 (5)	0.003 (4)	0.027 (4)	0.005 (4)
C19	0.047 (4)	0.061 (5)	0.060 (5)	0.007 (4)	0.026 (4)	0.006 (4)
C20	0.046 (4)	0.081 (7)	0.048 (4)	0.000 (4)	0.014 (4)	−0.020 (4)
C21	0.063 (6)	0.107 (8)	0.073 (6)	−0.024 (6)	0.033 (5)	−0.022 (6)
C22	0.084 (8)	0.140 (11)	0.111 (9)	−0.050 (8)	0.056 (7)	−0.066 (8)
C23	0.052 (6)	0.174 (15)	0.112 (9)	−0.021 (8)	0.030 (6)	−0.069 (10)
C24	0.055 (6)	0.168 (14)	0.100 (8)	0.031 (7)	−0.004 (6)	−0.053 (8)
C25	0.051 (5)	0.100 (8)	0.069 (6)	0.007 (5)	0.012 (4)	−0.028 (5)
C26	0.039 (4)	0.055 (5)	0.061 (5)	0.004 (4)	0.015 (3)	0.003 (4)
C27	0.084 (7)	0.073 (7)	0.079 (6)	0.008 (5)	0.041 (5)	0.008 (5)
C28	0.112 (9)	0.061 (6)	0.102 (8)	0.009 (6)	0.052 (7)	0.021 (6)
C29	0.097 (8)	0.066 (7)	0.114 (9)	0.005 (6)	0.043 (7)	−0.004 (7)
C30	0.087 (7)	0.064 (6)	0.100 (8)	0.005 (5)	0.022 (6)	−0.030 (6)
C31	0.073 (6)	0.065 (6)	0.057 (5)	0.001 (5)	0.020 (4)	−0.001 (4)
C32	0.066 (6)	0.065 (6)	0.062 (5)	0.007 (5)	0.012 (4)	0.008 (4)
C33	0.043 (7)	0.065 (16)	0.086 (7)	−0.033 (8)	0.012 (6)	0.008 (7)
C34	0.055 (13)	0.18 (2)	0.066 (6)	−0.035 (14)	0.002 (6)	0.030 (8)
C35	0.054 (8)	0.16 (2)	0.073 (7)	0.024 (9)	0.021 (6)	0.013 (9)
C36	0.062 (13)	0.11 (2)	0.104 (17)	0.034 (13)	0.037 (12)	0.026 (16)
C32'	0.066 (6)	0.065 (6)	0.062 (5)	0.007 (5)	0.012 (4)	0.008 (4)
C33'	0.043 (7)	0.065 (16)	0.086 (7)	−0.033 (8)	0.012 (6)	0.008 (7)
C34'	0.055 (13)	0.18 (2)	0.066 (6)	−0.035 (14)	0.002 (6)	0.030 (8)
C35'	0.054 (8)	0.16 (2)	0.073 (7)	0.024 (9)	0.021 (6)	0.013 (9)
C36'	0.054 (8)	0.16 (2)	0.073 (7)	0.024 (9)	0.021 (6)	0.013 (9)

Geometric parameters (Å, º)

Sn1—C1	2.137 (4)	C15'—H15C	0.9700
Sn1—C7	2.142 (5)	C15'—H15D	0.9700
Sn1—C13	2.138 (6)	C16'—C17'	1.515 (9)
Sn1—S1	2.481 (2)	C16'—H16C	0.9700
Sn2—C20	2.124 (4)	C16'—H16D	0.9700
Sn2—C26	2.141 (5)	C17'—H17C	0.9700
Sn2—C32	2.119 (7)	C17'—H17D	0.9700
Sn2—S3	2.473 (2)	C20—C21	1.3900
S1—C18	1.744 (9)	C20—C25	1.3900
S2—C19	1.718 (8)	C21—C22	1.3900
S2—C18	1.727 (8)	C21—H21	0.9300
S3—C19	1.738 (9)	C22—C23	1.3900
N1—C18	1.288 (9)	C22—H22	0.9300
N1—N2	1.374 (9)	C23—C24	1.3900
N2—C19	1.296 (10)	C23—H23	0.9300
C1—C2	1.3900	C24—C25	1.3900
C1—C6	1.3900	C24—H24	0.9300
C2—C3	1.3900	C25—H25	0.9300
C2—H2	0.9300	C26—C27	1.3900
C3—C4	1.3900	C26—C31	1.3900
C3—H3	0.9300	C27—C28	1.3900
C4—C5	1.3900	C27—H27	0.9300
C4—H4	0.9300	C28—C29	1.3900
C5—C6	1.3900	C28—H28	0.9300
C5—H5	0.9300	C29—C30	1.3900
C6—H6	0.9300	C29—H29	0.9300
C7—C8	1.3900	C30—C31	1.3900
C7—C12	1.3900	C30—H30	0.9300
C8—C9	1.3900	C31—H31	0.9300
C8—H8	0.9300	C32—C36	1.531 (9)
C9—C10	1.3900	C32—C33	1.532 (9)
C9—H9	0.9300	C32—H32	0.9800
C10—C11	1.3900	C33—C34	1.511 (9)
C10—H10	0.9300	C33—H33A	0.9700
C11—C12	1.3900	C33—H33B	0.9700
C11—H11	0.9300	C34—C35	1.508 (9)
C12—H12	0.9300	C34—H34A	0.9700
C13—C17	1.517 (9)	C34—H34B	0.9700
C13—C14	1.524 (9)	C35—C36	1.519 (9)
C13—H13	0.9800	C35—H35A	0.9700
C14—C15	1.523 (9)	C35—H35B	0.9700
C14—H14A	0.9700	C36—H36A	0.9700
C14—H14B	0.9700	C36—H36B	0.9700
C15—C16	1.516 (10)	C33'—C34'	1.519 (9)
C15—H15A	0.9700	C33'—H33C	0.9700
C15—H15B	0.9700	C33'—H33D	0.9700
C16—C17	1.512 (9)	C34'—C35'	1.514 (10)
C16—H16A	0.9700	C34'—H34C	0.9700
C16—H16B	0.9700	C34'—H34D	0.9700
C17—H17A	0.9700	C35'—C36'	1.511 (9)
C17—H17B	0.9700	C35'—H35C	0.9700
C14'—C15'	1.521 (10)	C35'—H35D	0.9700
C14'—H14C	0.9700	C36'—H36C	0.9700
C14'—H14D	0.9700	C36'—H36D	0.9700
C15'—C16'	1.511 (9)
C1—Sn1—C7	105.9 (2)	C17'—C16'—H16D	110.1
C1—Sn1—C13	116.5 (2)	H16C—C16'—H16D	108.4
C1—Sn1—S1	107.6 (2)	C16'—C17'—H17C	110.4
C7—Sn1—C13	110.6 (2)	C16'—C17'—H17D	110.4
C7—Sn1—S1	98.7 (2)	H17C—C17'—H17D	108.6
C13—Sn1—S1	115.7 (2)	N1—C18—S2	113.6 (6)
C20—Sn2—C26	109.2 (2)	N1—C18—S1	123.4 (6)
C20—Sn2—C32	117.8 (3)	S2—C18—S1	123.0 (5)
C20—Sn2—S3	109.3 (2)	N2—C19—S2	113.6 (6)
C26—Sn2—C32	111.5 (3)	N2—C19—S3	123.1 (6)
C26—Sn2—S3	99.1 (2)	S2—C19—S3	123.3 (5)
C32—Sn2—S3	108.3 (2)	C21—C20—C25	120.0
C18—S1—Sn1	94.9 (3)	C21—C20—Sn2	120.0 (3)
C19—S2—C18	87.2 (4)	C25—C20—Sn2	120.0 (3)
C19—S3—Sn2	95.2 (3)	C20—C21—C22	120.0
C18—N1—N2	112.8 (7)	C20—C21—H21	120.0
C19—N2—N1	112.8 (7)	C22—C21—H21	120.0
C2—C1—C6	120.0	C23—C22—C21	120.0
C2—C1—Sn1	122.7 (3)	C23—C22—H22	120.0
C6—C1—Sn1	117.3 (3)	C21—C22—H22	120.0
C3—C2—C1	120.0	C22—C23—C24	120.0
C3—C2—H2	120.0	C22—C23—H23	120.0
C1—C2—H2	120.0	C24—C23—H23	120.0
C2—C3—C4	120.0	C23—C24—C25	120.0
C2—C3—H3	120.0	C23—C24—H24	120.0
C4—C3—H3	120.0	C25—C24—H24	120.0
C3—C4—C5	120.0	C24—C25—C20	120.0
C3—C4—H4	120.0	C24—C25—H25	120.0
C5—C4—H4	120.0	C20—C25—H25	120.0
C6—C5—C4	120.0	C27—C26—C31	120.0
C6—C5—H5	120.0	C27—C26—Sn2	121.3 (3)
C4—C5—H5	120.0	C31—C26—Sn2	118.7 (3)
C5—C6—C1	120.0	C28—C27—C26	120.0
C5—C6—H6	120.0	C28—C27—H27	120.0
C1—C6—H6	120.0	C26—C27—H27	120.0
C8—C7—C12	120.0	C27—C28—C29	120.0
C8—C7—Sn1	120.1 (3)	C27—C28—H28	120.0
C12—C7—Sn1	119.9 (3)	C29—C28—H28	120.0
C9—C8—C7	120.0	C30—C29—C28	120.0
C9—C8—H8	120.0	C30—C29—H29	120.0
C7—C8—H8	120.0	C28—C29—H29	120.0
C8—C9—C10	120.0	C29—C30—C31	120.0
C8—C9—H9	120.0	C29—C30—H30	120.0
C10—C9—H9	120.0	C31—C30—H30	120.0
C9—C10—C11	120.0	C30—C31—C26	120.0
C9—C10—H10	120.0	C30—C31—H31	120.0
C11—C10—H10	120.0	C26—C31—H31	120.0
C12—C11—C10	120.0	C36—C32—C33	104.6 (7)
C12—C11—H11	120.0	C36—C32—Sn2	114.6 (11)
C10—C11—H11	120.0	C33—C32—Sn2	114.8 (9)
C11—C12—C7	120.0	C36—C32—H32	107.5
C11—C12—H12	120.0	C33—C32—H32	107.5
C7—C12—H12	120.0	Sn2—C32—H32	107.5
C17—C13—C14	106.5 (6)	C34—C33—C32	105.9 (7)
C17—C13—Sn1	111.6 (12)	C34—C33—H33A	110.6
C14—C13—Sn1	118.5 (12)	C32—C33—H33A	110.6
C17—C13—H13	106.5	C34—C33—H33B	110.6
C14—C13—H13	106.5	C32—C33—H33B	110.6
Sn1—C13—H13	106.5	H33A—C33—H33B	108.7
C15—C14—C13	105.6 (7)	C35—C34—C33	108.1 (5)
C15—C14—H14A	110.6	C35—C34—H34A	110.1
C13—C14—H14A	110.6	C33—C34—H34A	110.1
C15—C14—H14B	110.6	C35—C34—H34B	110.1
C13—C14—H14B	110.6	C33—C34—H34B	110.1
H14A—C14—H14B	108.7	H34A—C34—H34B	108.4
C16—C15—C14	106.0 (8)	C34—C35—C36	106.7 (7)
C16—C15—H15A	110.5	C34—C35—H35A	110.4
C14—C15—H15A	110.5	C36—C35—H35A	110.4
C16—C15—H15B	110.5	C34—C35—H35B	110.4
C14—C15—H15B	110.5	C36—C35—H35B	110.4
H15A—C15—H15B	108.7	H35A—C35—H35B	108.6
C17—C16—C15	107.5 (6)	C35—C36—C32	104.7 (7)
C17—C16—H16A	110.2	C35—C36—H36A	110.8
C15—C16—H16A	110.2	C32—C36—H36A	110.8
C17—C16—H16B	110.2	C35—C36—H36B	110.8
C15—C16—H16B	110.2	C32—C36—H36B	110.8
H16A—C16—H16B	108.5	H36A—C36—H36B	108.9
C16—C17—C13	107.6 (5)	C34'—C33'—H33C	110.7
C16—C17—H17A	110.2	C34'—C33'—H33D	110.7
C13—C17—H17A	110.2	H33C—C33'—H33D	108.8
C16—C17—H17B	110.2	C35'—C34'—C33'	105.9 (8)
C13—C17—H17B	110.2	C35'—C34'—H34C	110.6
H17A—C17—H17B	108.5	C33'—C34'—H34C	110.6
C15'—C14'—H14C	110.7	C35'—C34'—H34D	110.6
C15'—C14'—H14D	110.7	C33'—C34'—H34D	110.6
H14C—C14'—H14D	108.8	H34C—C34'—H34D	108.7
C16'—C15'—C14'	106.8 (7)	C36'—C35'—C34'	107.2 (7)
C16'—C15'—H15C	110.4	C36'—C35'—H35C	110.3
C14'—C15'—H15C	110.4	C34'—C35'—H35C	110.3
C16'—C15'—H15D	110.4	C36'—C35'—H35D	110.3
C14'—C15'—H15D	110.4	C34'—C35'—H35D	110.3
H15C—C15'—H15D	108.6	H35C—C35'—H35D	108.5
C15'—C16'—C17'	107.9 (5)	C35'—C36'—H36C	110.2
C15'—C16'—H16C	110.1	C35'—C36'—H36D	110.2
C17'—C16'—H16C	110.1	H36C—C36'—H36D	108.5
C15'—C16'—H16D	110.1
C1—Sn1—S1—C18	−74.3 (3)	C19—S2—C18—N1	−0.3 (7)
C13—Sn1—S1—C18	57.9 (4)	C19—S2—C18—S1	179.0 (5)
C7—Sn1—S1—C18	175.9 (3)	Sn1—S1—C18—N1	−6.3 (7)
C32—Sn2—S3—C19	−67.0 (4)	Sn1—S1—C18—S2	174.4 (5)
C20—Sn2—S3—C19	62.5 (3)	N1—N2—C19—S2	1.7 (9)
C26—Sn2—S3—C19	176.6 (3)	N1—N2—C19—S3	−179.5 (6)
C18—N1—N2—C19	−2.0 (10)	C18—S2—C19—N2	−0.8 (6)
C13—Sn1—C1—C2	−64.2 (4)	C18—S2—C19—S3	−179.6 (5)
C7—Sn1—C1—C2	172.4 (3)	Sn2—S3—C19—N2	−2.7 (7)
S1—Sn1—C1—C2	67.6 (3)	Sn2—S3—C19—S2	176.0 (5)
C13—Sn1—C1—C6	113.2 (3)	C32—Sn2—C20—C21	26.0 (4)
C7—Sn1—C1—C6	−10.2 (3)	C26—Sn2—C20—C21	154.5 (3)
S1—Sn1—C1—C6	−115.0 (3)	S3—Sn2—C20—C21	−98.1 (3)
Sn1—C1—C2—C3	177.3 (4)	C32—Sn2—C20—C25	−154.1 (3)
Sn1—C1—C6—C5	−177.5 (3)	C26—Sn2—C20—C25	−25.5 (3)
C1—Sn1—C7—C8	−61.9 (3)	S3—Sn2—C20—C25	81.9 (3)
C13—Sn1—C7—C8	171.0 (3)	Sn2—C20—C21—C22	179.9 (4)
S1—Sn1—C7—C8	49.3 (3)	Sn2—C20—C25—C24	−179.9 (4)
C1—Sn1—C7—C12	116.4 (3)	C32—Sn2—C26—C27	−150.9 (3)
C13—Sn1—C7—C12	−10.6 (4)	C20—Sn2—C26—C27	77.2 (3)
S1—Sn1—C7—C12	−132.4 (3)	S3—Sn2—C26—C27	−37.0 (3)
Sn1—C7—C8—C9	178.3 (4)	C32—Sn2—C26—C31	28.8 (4)
C8—C7—C12—C11	0.0	C20—Sn2—C26—C31	−103.1 (3)
Sn1—C7—C12—C11	−178.3 (4)	S3—Sn2—C26—C31	142.7 (3)
C1—Sn1—C13—C17	137.7 (13)	Sn2—C26—C27—C28	179.7 (4)
C7—Sn1—C13—C17	−101.4 (13)	Sn2—C26—C31—C30	−179.7 (4)
S1—Sn1—C13—C17	9.8 (13)	C20—Sn2—C32—C36	−176.7 (13)
C1—Sn1—C13—C14	13.5 (13)	C26—Sn2—C32—C36	55.9 (13)
C7—Sn1—C13—C14	134.4 (13)	S3—Sn2—C32—C36	−52.2 (13)
S1—Sn1—C13—C14	−114.4 (13)	C20—Sn2—C32—C33	62.2 (11)
C17—C13—C14—C15	24 (2)	C26—Sn2—C32—C33	−65.2 (11)
Sn1—C13—C14—C15	151 (2)	S3—Sn2—C32—C33	−173.3 (10)
C13—C14—C15—C16	−26 (3)	C36—C32—C33—C34	27 (2)
C14—C15—C16—C17	18 (3)	Sn2—C32—C33—C34	152.9 (18)
C15—C16—C17—C13	−4 (3)	C32—C33—C34—C35	−11 (3)
C14—C13—C17—C16	−13 (3)	C33—C34—C35—C36	−9 (3)
Sn1—C13—C17—C16	−143 (2)	C34—C35—C36—C32	25 (3)
C14'—C15'—C16'—C17'	10 (4)	C33—C32—C36—C35	−32 (2)
N2—N1—C18—S2	1.3 (9)	Sn2—C32—C36—C35	−158.5 (14)
N2—N1—C18—S1	−178.0 (6)	C33'—C34'—C35'—C36'	22 (3)