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The crystal structure of the title compound, {bis­[2-(2-oxido-2-naphthyl­idene­amino)­phenyl] di­sulfide-[kappa]5O,N,S,N',O'}chloroiron(III), [FeCl(C34H22N2O2S2)], has been determined. The structure consists of monomeric iron(III) complexes with distorted octahedral coordination. The di­sulfide functions as a pentadentate ligand and the FeIII atom is coordinated through two N, two O and one S atom, and one chloride ion. The distance between the second S atom and the FeIII atom is a non-bonding 3.8473 (14) Å.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270101000038/sk1428sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270101000038/sk1428Isup2.hkl
Contains datablock I

CCDC reference: 163888

Computing details top

Data collection: Nonius Diffractometer Control Software (Nonius, 1993); cell refinement: Nonius Diffractometer Control Software; data reduction: X-RED (Stoe & Cie, 1991); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

(I) top
Crystal data top
[FeCl(C34H22N2O2S2)]Dx = 1.544 Mg m3
Mr = 645.96Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, P212121Cell parameters from 25 reflections
a = 8.558 (3) Åθ = 3.0–13.9°
b = 12.989 (3) ŵ = 0.83 mm1
c = 24.991 (5) ÅT = 293 K
V = 2778.0 (13) Å3Plate, dark red
Z = 40.55 × 0.40 × 0.08 mm
F(000) = 1324
Data collection top
Nonius CAD-4
diffractometer
4728 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.018
Graphite monochromatorθmax = 26.0°, θmin = 1.6°
ω/2θ scansh = 107
Absorption correction: empirical (using intensity measurements) via ψ scans (north et al., 1968)k = 161
Tmin = 0.593, Tmax = 0.774l = 301
5939 measured reflections3 standard reflections every 120 min
5069 independent reflections intensity decay: 0.02%
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.024H-atom parameters constrained
wR(F2) = 0.067Calculated w = 1/[σ2(Fo2) + (0.0392P)2 + 0.4861P]
where P = (Fo2 + 2Fc2)/3
S = 1.08(Δ/σ)max = 0.001
5069 reflectionsΔρmax = 0.27 e Å3
379 parametersΔρmin = 0.24 e Å3
0 restraintsAbsolute structure: Flack (1983)
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.012 (11)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. The structure was solved by direct-phase determination. The parameters of the complete structure have been refined by full-matrix least-squares methods including anisotropic displacement parameters for non-H atoms.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
C10.6630 (2)0.73301 (14)0.31384 (7)0.0324 (4)
C20.6148 (3)0.69691 (17)0.36385 (8)0.0392 (5)
H20.55250.73790.38570.047*
C30.6599 (3)0.60074 (17)0.38066 (8)0.0428 (5)
H30.62810.57660.41400.051*
C40.7522 (3)0.53981 (16)0.34829 (9)0.0423 (5)
H40.78490.47570.36050.051*
C50.7965 (3)0.57268 (15)0.29822 (8)0.0364 (4)
H50.85740.53050.27660.044*
C60.7498 (2)0.66971 (14)0.27996 (8)0.0307 (4)
C70.8002 (2)0.64240 (15)0.18932 (7)0.0341 (4)
H70.78180.57350.19730.041*
C80.8363 (3)0.66746 (15)0.13501 (8)0.0358 (4)
C90.7880 (3)0.59794 (16)0.09261 (8)0.0398 (5)
C100.7155 (3)0.50200 (19)0.10189 (9)0.0537 (6)
H100.70680.47770.13680.064*
C110.6578 (4)0.4439 (2)0.06069 (11)0.0647 (8)
H110.61130.38070.06800.078*
C120.6680 (4)0.4781 (2)0.00775 (11)0.0627 (7)
H120.62500.43940.01990.075*
C130.7411 (3)0.5680 (2)0.00263 (10)0.0552 (7)
H130.75100.58980.03790.066*
C140.8028 (3)0.62985 (18)0.03884 (8)0.0454 (5)
C150.8752 (4)0.7256 (2)0.02764 (9)0.0589 (7)
H150.88700.74600.00780.071*
C160.9277 (3)0.78813 (19)0.06710 (10)0.0541 (7)
H160.97960.84870.05830.065*
C170.9047 (3)0.76260 (16)0.12177 (9)0.0389 (5)
C180.3952 (2)0.77534 (15)0.21298 (8)0.0378 (4)
C190.2837 (3)0.69704 (18)0.21318 (11)0.0506 (6)
H190.22120.68760.24320.061*
C200.2649 (3)0.6338 (2)0.16980 (12)0.0590 (7)
H200.19000.58200.17050.071*
C210.3568 (3)0.64697 (18)0.12537 (11)0.0531 (6)
H210.34370.60410.09590.064*
C220.4688 (3)0.72385 (17)0.12419 (9)0.0407 (5)
H220.53130.73170.09400.049*
C230.4891 (2)0.78954 (15)0.16774 (8)0.0337 (4)
C240.6118 (2)0.92253 (14)0.12338 (8)0.0333 (4)
H240.53800.90650.09740.040*
C250.7144 (2)1.00621 (14)0.11135 (8)0.0346 (4)
C260.7104 (3)1.05080 (16)0.05849 (8)0.0381 (5)
C270.6413 (3)1.00198 (19)0.01401 (9)0.0472 (5)
H270.59840.93670.01810.057*
C280.6360 (3)1.0485 (2)0.03515 (10)0.0562 (7)
H280.58701.01540.06350.067*
C290.7029 (3)1.1445 (2)0.04302 (10)0.0616 (7)
H290.69851.17570.07650.074*
C300.7750 (4)1.1929 (2)0.00148 (11)0.0579 (7)
H300.82131.25680.00710.070*
C310.7808 (3)1.14813 (17)0.04984 (9)0.0434 (5)
C320.8559 (3)1.19764 (17)0.09423 (10)0.0493 (6)
H320.89911.26270.08940.059*
C330.8659 (3)1.15326 (15)0.14241 (9)0.0421 (5)
H330.91751.18760.16990.051*
C340.7992 (3)1.05444 (14)0.15279 (8)0.0353 (4)
N10.60919 (19)0.86619 (12)0.16632 (6)0.0320 (3)
N20.79098 (19)0.70777 (11)0.22836 (6)0.0309 (3)
O10.81454 (19)1.01521 (10)0.20029 (6)0.0390 (3)
O20.94517 (18)0.83141 (11)0.15752 (6)0.0412 (3)
S10.62204 (6)0.86184 (4)0.294950 (19)0.03709 (12)
S20.39412 (7)0.85892 (5)0.26873 (2)0.04634 (14)
Cl10.98794 (6)0.88678 (4)0.28787 (2)0.04487 (13)
Fe10.81711 (3)0.870103 (19)0.216916 (11)0.03199 (8)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.0348 (10)0.0295 (9)0.0331 (9)0.0004 (8)0.0030 (8)0.0003 (7)
C20.0399 (12)0.0448 (12)0.0329 (10)0.0029 (10)0.0006 (9)0.0025 (8)
C30.0516 (14)0.0447 (11)0.0321 (9)0.0118 (10)0.0004 (9)0.0074 (8)
C40.0515 (13)0.0325 (10)0.0428 (11)0.0041 (9)0.0077 (10)0.0087 (9)
C50.0418 (12)0.0293 (9)0.0380 (10)0.0007 (9)0.0012 (9)0.0007 (8)
C60.0321 (10)0.0282 (8)0.0318 (9)0.0041 (7)0.0012 (8)0.0018 (7)
C70.0401 (11)0.0256 (8)0.0366 (9)0.0009 (8)0.0019 (9)0.0020 (7)
C80.0401 (12)0.0308 (9)0.0364 (10)0.0052 (9)0.0059 (9)0.0024 (7)
C90.0431 (13)0.0361 (10)0.0401 (10)0.0079 (9)0.0089 (9)0.0010 (8)
C100.0762 (19)0.0429 (12)0.0420 (11)0.0085 (13)0.0079 (12)0.0046 (10)
C110.081 (2)0.0533 (15)0.0594 (15)0.0139 (14)0.0091 (14)0.0147 (12)
C120.0697 (19)0.0690 (18)0.0496 (13)0.0069 (16)0.0048 (13)0.0205 (12)
C130.0620 (17)0.0678 (17)0.0360 (11)0.0157 (14)0.0043 (11)0.0052 (11)
C140.0525 (14)0.0450 (11)0.0386 (10)0.0136 (12)0.0100 (10)0.0014 (9)
C150.082 (2)0.0556 (14)0.0391 (12)0.0107 (14)0.0217 (12)0.0082 (11)
C160.0676 (18)0.0423 (12)0.0523 (13)0.0013 (12)0.0263 (12)0.0089 (11)
C170.0369 (12)0.0344 (10)0.0453 (11)0.0037 (9)0.0105 (9)0.0024 (9)
C180.0341 (10)0.0365 (10)0.0429 (10)0.0025 (8)0.0001 (9)0.0086 (9)
C190.0400 (12)0.0501 (12)0.0619 (13)0.0074 (10)0.0046 (11)0.0169 (11)
C200.0470 (14)0.0431 (12)0.0869 (18)0.0164 (12)0.0040 (13)0.0145 (14)
C210.0538 (15)0.0389 (12)0.0666 (15)0.0104 (11)0.0118 (12)0.0030 (11)
C220.0422 (12)0.0356 (10)0.0444 (11)0.0018 (10)0.0034 (10)0.0017 (9)
C230.0325 (11)0.0291 (9)0.0395 (10)0.0002 (8)0.0020 (8)0.0060 (8)
C240.0346 (11)0.0283 (9)0.0370 (9)0.0001 (8)0.0000 (8)0.0008 (8)
C250.0365 (12)0.0258 (9)0.0413 (10)0.0004 (8)0.0004 (9)0.0033 (8)
C260.0349 (12)0.0354 (10)0.0440 (11)0.0030 (9)0.0036 (9)0.0076 (8)
C270.0492 (15)0.0501 (13)0.0424 (11)0.0088 (11)0.0016 (10)0.0067 (10)
C280.0515 (16)0.0743 (17)0.0426 (12)0.0073 (14)0.0004 (11)0.0079 (12)
C290.0613 (17)0.0754 (18)0.0482 (12)0.0017 (15)0.0037 (12)0.0269 (13)
C300.0583 (17)0.0525 (14)0.0631 (15)0.0043 (13)0.0094 (13)0.0234 (12)
C310.0405 (12)0.0367 (11)0.0530 (12)0.0001 (10)0.0061 (10)0.0103 (9)
C320.0509 (15)0.0299 (10)0.0670 (14)0.0047 (10)0.0058 (12)0.0117 (10)
C330.0445 (12)0.0259 (9)0.0560 (12)0.0041 (9)0.0037 (10)0.0014 (9)
C340.0366 (11)0.0256 (9)0.0437 (10)0.0027 (8)0.0011 (9)0.0023 (8)
N10.0315 (8)0.0262 (7)0.0382 (8)0.0021 (7)0.0007 (7)0.0027 (7)
N20.0322 (9)0.0269 (7)0.0335 (7)0.0004 (6)0.0015 (7)0.0026 (6)
O10.0504 (9)0.0244 (6)0.0423 (7)0.0017 (6)0.0049 (7)0.0010 (5)
O20.0399 (8)0.0332 (7)0.0504 (8)0.0030 (6)0.0099 (7)0.0010 (6)
S10.0435 (3)0.0296 (2)0.0382 (2)0.0062 (2)0.0011 (2)0.0015 (2)
S20.0385 (3)0.0548 (3)0.0457 (3)0.0139 (3)0.0044 (2)0.0011 (3)
Cl10.0434 (3)0.0380 (3)0.0532 (3)0.0043 (2)0.0130 (2)0.0061 (2)
Fe10.03431 (15)0.02348 (12)0.03819 (14)0.00129 (11)0.00098 (12)0.00242 (11)
Geometric parameters (Å, º) top
C1—C61.394 (3)C19—H190.9300
C1—C21.397 (3)C20—C211.371 (4)
C1—S11.7738 (19)C20—H200.9300
C2—C31.373 (3)C21—C221.385 (3)
C2—H20.9300C21—H210.9300
C3—C41.380 (3)C22—C231.394 (3)
C3—H30.9300C22—H220.9300
C4—C51.376 (3)C23—N11.431 (2)
C4—H40.9300C24—N11.299 (2)
C5—C61.399 (3)C24—C251.430 (3)
C5—H50.9300C24—H240.9300
C6—N21.425 (2)C25—C341.411 (3)
C7—N21.296 (2)C25—C261.443 (3)
C7—C81.430 (3)C26—C271.410 (3)
C7—H70.9300C26—C311.417 (3)
C8—C171.407 (3)C27—C281.370 (3)
C8—C91.452 (3)C27—H270.9300
C9—C101.411 (3)C28—C291.386 (4)
C9—C141.412 (3)C28—H280.9300
C10—C111.369 (4)C29—C301.361 (4)
C10—H100.9300C29—H290.9300
C11—C121.398 (4)C30—C311.410 (3)
C11—H110.9300C30—H300.9300
C12—C131.350 (4)C31—C321.434 (3)
C12—H120.9300C32—C331.338 (3)
C13—C141.414 (3)C32—H320.9300
C13—H130.9300C33—C341.428 (3)
C14—C151.417 (4)C33—H330.9300
C15—C161.354 (4)C34—O11.298 (2)
C15—H150.9300N1—Fe12.1834 (17)
C16—C171.420 (3)N2—Fe12.1396 (16)
C16—H160.9300O1—Fe11.9302 (14)
C17—O21.310 (3)O2—Fe11.9122 (15)
C18—C191.395 (3)S1—S22.0580 (10)
C18—C231.399 (3)S1—Fe12.5694 (7)
C18—S21.766 (2)Cl1—Fe12.3084 (7)
C19—C201.370 (4)
C6—C1—C2120.16 (18)C23—C22—H22119.6
C6—C1—S1120.00 (14)C22—C23—C18118.61 (19)
C2—C1—S1119.76 (16)C22—C23—N1119.73 (19)
C3—C2—C1119.7 (2)C18—C23—N1121.59 (18)
C3—C2—H2120.1N1—C24—C25127.77 (19)
C1—C2—H2120.1N1—C24—H24116.1
C2—C3—C4120.20 (19)C25—C24—H24116.1
C2—C3—H3119.9C34—C25—C24119.95 (18)
C4—C3—H3119.9C34—C25—C26120.40 (18)
C5—C4—C3120.87 (19)C24—C25—C26118.87 (18)
C5—C4—H4119.6C27—C26—C31117.35 (19)
C3—C4—H4119.6C27—C26—C25123.47 (19)
C4—C5—C6119.8 (2)C31—C26—C25119.2 (2)
C4—C5—H5120.1C28—C27—C26121.5 (2)
C6—C5—H5120.1C28—C27—H27119.2
C1—C6—C5119.05 (18)C26—C27—H27119.2
C1—C6—N2118.46 (16)C27—C28—C29120.7 (2)
C5—C6—N2122.47 (18)C27—C28—H28119.7
N2—C7—C8125.37 (18)C29—C28—H28119.7
N2—C7—H7117.3C30—C29—C28119.6 (2)
C8—C7—H7117.3C30—C29—H29120.2
C17—C8—C7120.87 (18)C28—C29—H29120.2
C17—C8—C9119.54 (18)C29—C30—C31121.3 (2)
C7—C8—C9119.33 (18)C29—C30—H30119.4
C10—C9—C14117.1 (2)C31—C30—H30119.4
C10—C9—C8123.7 (2)C30—C31—C26119.5 (2)
C14—C9—C8119.1 (2)C30—C31—C32122.3 (2)
C11—C10—C9121.5 (2)C26—C31—C32118.22 (19)
C11—C10—H10119.3C33—C32—C31122.1 (2)
C9—C10—H10119.3C33—C32—H32118.9
C10—C11—C12120.9 (3)C31—C32—H32118.9
C10—C11—H11119.5C32—C33—C34121.7 (2)
C12—C11—H11119.5C32—C33—H33119.2
C13—C12—C11119.0 (2)C34—C33—H33119.2
C13—C12—H12120.5O1—C34—C25123.27 (18)
C11—C12—H12120.5O1—C34—C33118.58 (19)
C12—C13—C14121.6 (2)C25—C34—C33118.10 (18)
C12—C13—H13119.2C24—N1—C23115.11 (17)
C14—C13—H13119.2C24—N1—Fe1116.83 (14)
C13—C14—C9119.8 (2)C23—N1—Fe1125.95 (12)
C13—C14—C15121.2 (2)C7—N2—C6117.97 (16)
C9—C14—C15119.0 (2)C7—N2—Fe1122.60 (13)
C16—C15—C14121.8 (2)C6—N2—Fe1119.25 (12)
C16—C15—H15119.1C34—O1—Fe1125.53 (12)
C14—C15—H15119.1C17—O2—Fe1123.85 (14)
C15—C16—C17121.0 (2)C1—S1—S2104.76 (7)
C15—C16—H16119.5C1—S1—Fe196.48 (7)
C17—C16—H16119.5S2—S1—Fe1112.02 (3)
O2—C17—C8123.29 (19)C18—S2—S1104.91 (7)
O2—C17—C16117.4 (2)O2—Fe1—O195.51 (6)
C8—C17—C16119.3 (2)O2—Fe1—N284.53 (6)
C19—C18—C23119.5 (2)O1—Fe1—N2171.85 (6)
C19—C18—S2116.20 (17)O2—Fe1—N190.66 (7)
C23—C18—S2124.02 (16)O1—Fe1—N183.61 (6)
C20—C19—C18121.0 (2)N2—Fe1—N188.24 (6)
C20—C19—H19119.5O2—Fe1—Cl1104.95 (6)
C18—C19—H19119.5O1—Fe1—Cl194.65 (5)
C19—C20—C21119.9 (2)N2—Fe1—Cl193.21 (5)
C19—C20—H20120.0N1—Fe1—Cl1164.39 (5)
C21—C20—H20120.0O2—Fe1—S1161.90 (5)
C20—C21—C22120.3 (2)O1—Fe1—S1101.35 (5)
C20—C21—H21119.9N2—Fe1—S177.84 (4)
C22—C21—H21119.9N1—Fe1—S184.78 (5)
C21—C22—C23120.7 (2)Cl1—Fe1—S180.35 (3)
C21—C22—H22119.6
C6—C1—C2—C33.3 (3)C26—C25—C34—O1176.0 (2)
S1—C1—C2—C3173.53 (17)C24—C25—C34—C33163.20 (19)
C1—C2—C3—C40.1 (3)C26—C25—C34—C336.6 (3)
C2—C3—C4—C52.1 (3)C32—C33—C34—O1179.3 (2)
C3—C4—C5—C61.0 (3)C32—C33—C34—C253.3 (3)
C2—C1—C6—C54.3 (3)C25—C24—N1—C23178.12 (19)
S1—C1—C6—C5172.52 (15)C25—C24—N1—Fe117.4 (3)
C2—C1—C6—N2177.34 (18)C22—C23—N1—C2449.7 (3)
S1—C1—C6—N25.9 (3)C18—C23—N1—C24133.3 (2)
C4—C5—C6—C12.2 (3)C22—C23—N1—Fe1113.18 (19)
C4—C5—C6—N2179.52 (18)C18—C23—N1—Fe163.8 (2)
N2—C7—C8—C1716.7 (3)C8—C7—N2—C6178.5 (2)
N2—C7—C8—C9157.4 (2)C8—C7—N2—Fe13.5 (3)
C17—C8—C9—C10178.6 (2)C1—C6—N2—C7147.16 (19)
C7—C8—C9—C104.4 (3)C5—C6—N2—C734.5 (3)
C17—C8—C9—C143.6 (3)C1—C6—N2—Fe128.0 (2)
C7—C8—C9—C14170.6 (2)C5—C6—N2—Fe1150.29 (15)
C14—C9—C10—C111.9 (4)C25—C34—O1—Fe130.1 (3)
C8—C9—C10—C11173.3 (3)C33—C34—O1—Fe1152.52 (16)
C9—C10—C11—C120.4 (5)C8—C17—O2—Fe144.4 (3)
C10—C11—C12—C132.5 (5)C16—C17—O2—Fe1133.64 (19)
C11—C12—C13—C142.1 (4)C6—C1—S1—S2101.93 (16)
C12—C13—C14—C90.2 (4)C2—C1—S1—S281.26 (17)
C12—C13—C14—C15178.1 (3)C6—C1—S1—Fe112.91 (17)
C10—C9—C14—C132.2 (3)C2—C1—S1—Fe1163.90 (16)
C8—C9—C14—C13173.2 (2)C19—C18—S2—S1129.12 (16)
C10—C9—C14—C15179.8 (2)C23—C18—S2—S157.25 (18)
C8—C9—C14—C154.8 (3)C1—S1—S2—C1862.15 (10)
C13—C14—C15—C16176.6 (3)Fe1—S1—S2—C1841.30 (8)
C9—C14—C15—C161.4 (4)C17—O2—Fe1—O1124.03 (17)
C14—C15—C16—C173.4 (4)C17—O2—Fe1—N247.79 (17)
C7—C8—C17—O22.9 (3)C17—O2—Fe1—N140.38 (17)
C9—C8—C17—O2176.98 (19)C17—O2—Fe1—Cl1139.65 (16)
C7—C8—C17—C16175.1 (2)C17—O2—Fe1—S134.7 (3)
C9—C8—C17—C161.1 (3)C34—O1—Fe1—O241.73 (19)
C15—C16—C17—O2173.6 (2)C34—O1—Fe1—N248.2 (5)
C15—C16—C17—C84.6 (4)C34—O1—Fe1—N148.31 (18)
C23—C18—C19—C200.1 (3)C34—O1—Fe1—Cl1147.27 (17)
S2—C18—C19—C20174.02 (19)C34—O1—Fe1—S1131.66 (17)
C18—C19—C20—C210.1 (4)C7—N2—Fe1—O228.06 (16)
C19—C20—C21—C220.2 (4)C6—N2—Fe1—O2156.98 (15)
C20—C21—C22—C230.6 (4)C7—N2—Fe1—O162.6 (5)
C21—C22—C23—C180.8 (3)C6—N2—Fe1—O1112.3 (4)
C21—C22—C23—N1177.9 (2)C7—N2—Fe1—N162.77 (16)
C19—C18—C23—C220.6 (3)C6—N2—Fe1—N1112.19 (14)
S2—C18—C23—C22173.98 (16)C7—N2—Fe1—Cl1132.78 (16)
C19—C18—C23—N1177.56 (19)C6—N2—Fe1—Cl152.26 (14)
S2—C18—C23—N19.0 (3)C7—N2—Fe1—S1147.81 (16)
N1—C24—C25—C3417.5 (3)C6—N2—Fe1—S127.15 (13)
N1—C24—C25—C26172.5 (2)C24—N1—Fe1—O255.30 (15)
C34—C25—C26—C27173.5 (2)C23—N1—Fe1—O2107.33 (16)
C24—C25—C26—C2716.6 (3)C24—N1—Fe1—O140.18 (14)
C34—C25—C26—C315.5 (3)C23—N1—Fe1—O1157.20 (16)
C24—C25—C26—C31164.40 (19)C24—N1—Fe1—N2139.80 (15)
C31—C26—C27—C282.9 (4)C23—N1—Fe1—N222.82 (16)
C25—C26—C27—C28178.0 (2)C24—N1—Fe1—Cl1124.57 (17)
C26—C27—C28—C291.9 (4)C23—N1—Fe1—Cl172.8 (2)
C27—C28—C29—C300.2 (4)C24—N1—Fe1—S1142.25 (14)
C28—C29—C30—C311.1 (4)C23—N1—Fe1—S155.13 (15)
C29—C30—C31—C260.0 (4)C1—S1—Fe1—O231.90 (18)
C29—C30—C31—C32179.9 (3)S2—S1—Fe1—O276.92 (17)
C27—C26—C31—C302.0 (3)C1—S1—Fe1—O1169.73 (8)
C25—C26—C31—C30178.9 (2)S2—S1—Fe1—O181.45 (5)
C27—C26—C31—C32178.1 (2)C1—S1—Fe1—N218.55 (8)
C25—C26—C31—C321.0 (3)S2—S1—Fe1—N290.27 (5)
C30—C31—C32—C33177.7 (3)C1—S1—Fe1—N1107.87 (8)
C26—C31—C32—C332.4 (4)S2—S1—Fe1—N10.95 (5)
C31—C32—C33—C341.3 (4)C1—S1—Fe1—Cl176.89 (7)
C24—C25—C34—O114.2 (3)S2—S1—Fe1—Cl1174.29 (3)
 

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