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metal-organic compounds
The title compound, tetra-n-butylammonium ![[mu]](/logos/entities/mu_rmgif.gif)
-bromo-bis(-p-chlorobenzenethiolato)bis(tricarbonylmolybdenum)(Mo-Mo), (C16H36N)[Mo2Br(C6H4ClS)2(CO)6], contains a Bu4N+ cation and a [Mo2(CO)6(p-Cl-C6H4S)2Br]- anion. The structure of the anion can be viewed as a cofacial bioctahedral dimer, in which two fac-Mo(CO)3 fragments are bridged by two p-Cl-C6H4S- groups and one Br- ligand. The mean Mo-Br distance is 2.765 (2) Å and the Mo-Br-Mo angle is 62.68 (4)°.
-bromo-bis(-p-chlorobenzenethiolato)bis(tricarbonylmolybdenum)(Mo-Mo), (C16H36N)[Mo2Br(C6H4ClS)2(CO)6], contains a Bu4N+ cation and a [Mo2(CO)6(p-Cl-C6H4S)2Br]- anion. The structure of the anion can be viewed as a cofacial bioctahedral dimer, in which two fac-Mo(CO)3 fragments are bridged by two p-Cl-C6H4S- groups and one Br- ligand. The mean Mo-Br distance is 2.765 (2) Å and the Mo-Br-Mo angle is 62.68 (4)°.Supporting information
 | Crystallographic Information File (CIF) |
 | Structure factor file (CIF format) |
CCDC reference: 130805
