metal-organic compounds
The Sn atom in the title compound, [(C6H11)2NH2]2[Sn(C2O4)2(CH3)2(H2O)].C2H6O, is chelated by two isobidentate oxalato groups and it exists in a trans-C2SnO5 pentagonal-bipyramidal environment [C-Sn-C 173.5 (2)°] . The coordinated water molecule is hydrogen bonded to a carbonyl O atom of an adjacent stannate [OO = 2.796 (3) Å] to form a centrosymmetric dinuclear tetraanion. These are linked into sheets through the two ammonium cations [NO 2.783 (3), 2.790 (3), 2.793 (3), 2.848 (3) Å]. The ethanol solvate molecule is hydrogen bonded to another doubly bonded carbonyl O atom [OO = 2.819 (9) Å].
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 128337