metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
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ISSN: 2056-9890
Volume 70| Part 8| August 2014| Pages m293-m294

(Benzyl­di­phenyl­phosphane-1κP)[μ-bis­(di­phenylphosphan­yl)methane-2:3κ2P:P′]nona­carbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0)

aChemical Sciences Programme, School of Distance Education, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia, bDepartment of Chemistry, Gokhale Centenary College, Ankola 581 314, NK, Karnataka, India, and cX-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
*Correspondence e-mail: omarsa@usm.my

Edited by J. Simpson, University of Otago, New Zealand (Received 24 June 2014; accepted 2 July 2014; online 11 July 2014)

The asymmetric unit of the title compound, [Ru3(C19H17P)(C25H22P2)(CO)9], consists of two independent mol­ecules. The bis­(di­phenyl­phosphan­yl)methane ligand bridges an Ru—Ru bond and the benzyl­diphenyl­phosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyl­diphenyl­phosphane ligand is the longest of the three Ru—Ru bonds in both mol­ecules. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming layers parallel to the ac plane. C—H⋯π contacts further stabilize the crystal packing.

Keywords: crystal structure.

Related literature

For general background to triruthenium complexes of the structural type [Ru3(CO)9(LL)(L)] (where LL is a bidentate ligand and L a monodentate ligand), see: Koutsantonis et al. (2002[Koutsantonis, G. A., Torabi, A. A., Humphreys, A. S., Skelton, B. W. & White, A. H. (2002). J. Organomet. Chem. 655, 227-232.]); Shawkataly et al. (1998[bin Shawkataly, O., Ramalingam, K., Ashari, D. M., Fun, H.-K. & Razak, I. A. (1998). Acta Cryst. C54, 329-331.], 2009[Shawkataly, O. bin, Khan, I. A., Yeap, C. S. & Fun, H.-K. (2009). Acta Cryst. E65, m1626-m1627.], 2010[Shawkataly, O. bin, Khan, I. A., Yeap, C. S. & Fun, H.-K. (2010). Acta Cryst. E66, m30-m31.], 2011[Shawkataly, O. bin, Khan, I. A., Sirat, S. S., Yeap, C. S. & Fun, H.-K. (2011). Acta Cryst. E67, m175-m176.], 2012[Shawkataly, O. bin, Khan, I. A., Sirat, S. S., Quah, C. K. & Fun, H.-K. (2012). Acta Cryst. E68, m812-m813.]). For the use of Group 15 ligands in stabilizing metal clusters, see: Bruce et al. (1988a[Bruce, M. I., Liddel, M. J., Hughes, C. A., Patrick, J. M., Skelton, B. W. & White, A. H. (1988a). J. Organomet. Chem. 347, 181-205.],b[Bruce, M. I., Liddel, M. J., Shawkataly, O. B., Hughes, C. A., Skelton, B. W. & White, A. H. (1988b). J. Organomet. Chem. 347, 207-235.]). For a general method of preparation of ruthenium cluster phosphane derivatives, see: Bruce et al. (1983[Bruce, M. I., Matisons, J. G. & Nicholson, B. K. (1983). J. Organomet. Chem. 247, 321-343.]). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986[Cosier, J. & Glazer, A. M. (1986). J. Appl. Cryst. 19, 105-107.]).

[Scheme 1]

Experimental

Crystal data
  • [Ru3(C19H17P)(C25H22P2)(CO)9]

  • Mr = 1215.96

  • Monoclinic, P 21 /n

  • a = 13.4308 (2) Å

  • b = 35.3969 (6) Å

  • c = 20.6967 (3) Å

  • β = 97.620 (1)°

  • V = 9752.5 (3) Å3

  • Z = 8

  • Mo Kα radiation

  • μ = 1.07 mm−1

  • T = 100 K

  • 0.51 × 0.14 × 0.05 mm

Data collection
  • Bruker SMART APEXII CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.612, Tmax = 0.950

  • 96674 measured reflections

  • 22388 independent reflections

  • 17595 reflections with I > 2σ(I)

  • Rint = 0.058

Refinement
  • R[F2 > 2σ(F2)] = 0.043

  • wR(F2) = 0.089

  • S = 1.06

  • 22388 reflections

  • 1225 parameters

  • H-atom parameters constrained

  • Δρmax = 1.96 e Å−3

  • Δρmin = −0.61 e Å−3

Table 1
Selected bond lengths (Å)

Ru1A—P1A 2.3353 (10)
Ru1A—Ru3A 2.8454 (4)
Ru1A—Ru2A 2.9054 (4)
Ru2A—P2A 2.3232 (10)
Ru2A—Ru3A 2.8353 (4)
Ru3A—P3A 2.3196 (10)
Ru1B—P1B 2.3406 (10)
Ru1B—Ru2B 2.8504 (4)
Ru1B—Ru3B 2.8992 (4)
Ru2B—P2B 2.3195 (10)
Ru2B—Ru3B 2.8451 (4)
Ru3B—P3B 2.3191 (10)

Table 2
Hydrogen-bond geometry (Å, °)

Cg1 and Cg2 are the centroids of the C8B–C13B and C29A–C34A rings, respectively.

D—H⋯A D—H H⋯A DA D—H⋯A
C5A—H5AA⋯O1Ai 0.95 2.55 3.221 (5) 127
C10B—H10B⋯O1Bii 0.95 2.58 3.250 (5) 128
C3B—H3BACg1 0.95 2.78 3.485 (4) 131
C12B—H12BCg2iii 0.95 2.67 3.539 (4) 153
Symmetry codes: (i) -x+1, -y, -z+1; (ii) -x+2, -y, -z; (iii) x, y, z-1.

Data collection: APEX2 (Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]).

Supporting information


Comment top

The synthesis and structural reports on substituted triruthenium clusters towards group 15 ligands are of interest as these ligands can often be used to stabilize metal clusters (Bruce et al., 1988a,b). In the title compound, each Ru atom carries one equatorial and two axial terminal carbonyl ligands (Figures 1 & 2, Table 1). The bond lengths and angles are normal and correspond to those observed in related structures Koutsantonis et al. (2002), Shawkataly et al. (1998, 2009, 2010, 2011, 2012). The Ru–Ru bond cis to the P(C19H17) ligand is the longest Ru—Ru distance [Ru1A—Ru2A = 2.9054 (4) Å, Ru1B—Ru3B = 2.8992 (4) Å] in both molecules when compared to the other Ru—Ru distances [Ru1A—Ru3A = 2.8454 (4) Å and Ru2A—Ru3A = 2.8353 (4) Å]; [Ru1B—Ru2B = 2.8504 (4) and Ru2B—Ru3B = 2.8451 (4) Å]. The two phenyl rings (C8—C13 and C14—C19) of the benzyldiphenylphosphane ligand bound to the P1 atom make dihedral angles of 64.7 (2) and 68.6 (2)° with one another in the two molecules. They also subtend dihedral angles of 47.2 (2) & 59.8 (2) or 40.0 (2) & 46.3 (2)° respectively for molecules A and B with the (C2—C7) benzene rings of the benzyl groups. In the dppm ligand, the two benzene rings attached to each P2 (C29—C34 and C35—C40) and P3 (C42—C47 and C48—C53) phosphorus atoms make dihedral angles of 72.1 (2) and 80.2 (2)° with one another for molecule A and 86.9 (2) and 75.7 (2)° for molecule B.

In the crystal structure, molecules are linked by C5A—H5A···O1A and C10B—H10B···O1B hydrogen bonds, Fig.2, to form two dimensional layers parallel to the ac plane. C—H···π contacts, Table 2, further stabilise the crystal packing.

Related literature top

For general background to triruthenium complexes of the structural type [Ru3(CO)9(LL)(L)] (where LL is a bidentate ligand and L a monodentate ligand), see: Koutsantonis et al. (2002), Shawkataly et al. (1998, 2009, 2010, 2011, 2012). For the use of Group 15 ligands in stabilizing metal clusters, see: Bruce et al. (1988a,b). For a general method of preparation of ruthenium cluster phosphane derivatives, see Bruce et al. (1983). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986).

Experimental top

All manipulations were performed under a dry oxygen-free nitrogen atmosphere using standard Schlenk technique. The Ru3(CO)12 (Aldrich), P(C19H17) (Strem Chemicals) and bis(diphenylphosphanyl)methane (Aldrich) were used as received. Ru3(Ph2PCH2PPh2)(CO)10 was prepared from Ru3(CO)12 and Ph2PCH2PPh2 using the benzophenone ketyl radical under mild conditions (Bruce et al. 1983). The title compound was then obtained by refluxing equimolar quantities of Ru3(Ph2PCH2PPh2)(CO)10 with P(C19H17) in n-hexane under a nitrogen atmosphere. Crystal suitable for X-ray diffraction were grown by solvent/solvent diffusion of CH3OH into CH2Cl2.

Refinement top

All H atoms were positioned geometrically and refined using a riding model with with C–H = 0.95–0.99 Å and Uiso(H) = 1.2Ueq(C).

Computing details top

Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009).

Figures top
[Figure 1] Fig. 1. Molecule A the title compound, showing 50% probability displacement ellipsoids.
[Figure 2] Fig. 2. Molecule B the title compound, showing 50% probability displacement ellipsoids.
[Figure 3] Fig. 3. The crystal packing of (I). Dashed lines indicate hydrogen bonds. H atoms not involved in the hydrogen bond interactions have been omitted for clarity.
(Benzyldiphenylphosphane-1κP)[µ-bis(diphenylphosphanyl)methane-2:3κ2P:P']nonacarbonyl-1κ3C,2κ3C,3κ3C-triangulo-triruthenium(0) top
Crystal data top
[Ru3(C19H17P)(C25H22P2)(CO)9]F(000) = 4848
Mr = 1215.96Dx = 1.656 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 9920 reflections
a = 13.4308 (2) Åθ = 2.3–30.2°
b = 35.3969 (6) ŵ = 1.07 mm1
c = 20.6967 (3) ÅT = 100 K
β = 97.620 (1)°Plate, red
V = 9752.5 (3) Å30.51 × 0.14 × 0.05 mm
Z = 8
Data collection top
Bruker SMART APEXII CCD area-detector
diffractometer
22388 independent reflections
Radiation source: fine-focus sealed tube17595 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.058
ϕ and ω scansθmax = 27.5°, θmin = 1.2°
Absorption correction: multi-scan
(SADABS; Bruker, 2009)
h = 1717
Tmin = 0.612, Tmax = 0.950k = 4545
96674 measured reflectionsl = 2626
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.043Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.089H-atom parameters constrained
S = 1.06 w = 1/[σ2(Fo2) + (0.0272P)2 + 21.4411P]
where P = (Fo2 + 2Fc2)/3
22388 reflections(Δ/σ)max = 0.002
1225 parametersΔρmax = 1.96 e Å3
0 restraintsΔρmin = 0.61 e Å3
Crystal data top
[Ru3(C19H17P)(C25H22P2)(CO)9]V = 9752.5 (3) Å3
Mr = 1215.96Z = 8
Monoclinic, P21/nMo Kα radiation
a = 13.4308 (2) ŵ = 1.07 mm1
b = 35.3969 (6) ÅT = 100 K
c = 20.6967 (3) Å0.51 × 0.14 × 0.05 mm
β = 97.620 (1)°
Data collection top
Bruker SMART APEXII CCD area-detector
diffractometer
22388 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2009)
17595 reflections with I > 2σ(I)
Tmin = 0.612, Tmax = 0.950Rint = 0.058
96674 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0430 restraints
wR(F2) = 0.089H-atom parameters constrained
S = 1.06 w = 1/[σ2(Fo2) + (0.0272P)2 + 21.4411P]
where P = (Fo2 + 2Fc2)/3
22388 reflectionsΔρmax = 1.96 e Å3
1225 parametersΔρmin = 0.61 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ru1A0.72460 (2)0.138334 (8)0.539334 (13)0.01007 (6)
Ru2A0.90993 (2)0.106019 (9)0.604698 (13)0.01080 (7)
Ru3A0.90419 (2)0.140114 (9)0.480298 (13)0.01118 (7)
P1A0.60626 (7)0.13535 (3)0.61229 (4)0.01132 (19)
P2A1.08419 (7)0.10615 (3)0.61365 (4)0.01167 (19)
P3A1.06732 (7)0.12496 (3)0.46467 (4)0.01180 (19)
O1A0.6812 (2)0.05736 (8)0.49014 (13)0.0190 (6)
O2A0.5845 (2)0.16919 (8)0.42524 (13)0.0232 (7)
O3A0.7657 (2)0.22181 (8)0.57580 (14)0.0213 (6)
O4A0.8945 (2)0.03101 (8)0.52916 (14)0.0283 (7)
O5A0.8844 (2)0.06222 (9)0.72792 (14)0.0279 (7)
O6A0.9021 (2)0.17726 (8)0.68794 (13)0.0188 (6)
O7A0.8433 (2)0.06813 (8)0.40158 (14)0.0249 (7)
O8A0.8176 (2)0.19088 (9)0.36830 (14)0.0294 (7)
O9A0.9857 (2)0.20861 (8)0.56152 (13)0.0198 (6)
C1A0.4736 (3)0.13267 (11)0.57326 (19)0.0165 (8)
H1AA0.42920.13720.60710.020*
H1AB0.46160.15330.54090.020*
C2A0.4433 (3)0.09552 (11)0.53939 (18)0.0154 (8)
C3A0.4421 (3)0.09125 (11)0.47277 (19)0.0167 (8)
H3AA0.46500.11130.44800.020*
C4A0.4077 (3)0.05795 (12)0.4416 (2)0.0233 (9)
H4AA0.40530.05560.39570.028*
C5A0.3770 (4)0.02826 (13)0.4777 (2)0.0284 (10)
H5AA0.35400.00550.45660.034*
C6A0.3798 (3)0.03178 (12)0.5446 (2)0.0267 (10)
H6AA0.35890.01140.56940.032*
C7A0.4132 (3)0.06505 (12)0.5750 (2)0.0206 (9)
H7AA0.41570.06720.62100.025*
C8A0.6067 (3)0.09785 (11)0.67336 (17)0.0135 (8)
C9A0.6511 (3)0.06318 (11)0.66451 (19)0.0168 (8)
H9AA0.68620.05940.62810.020*
C10A0.6446 (3)0.03396 (12)0.7085 (2)0.0204 (9)
H10A0.67470.01020.70190.025*
C11A0.5948 (3)0.03925 (12)0.76183 (19)0.0207 (9)
H11A0.59170.01940.79230.025*
C12A0.5492 (3)0.07369 (12)0.77108 (18)0.0203 (9)
H12A0.51440.07730.80770.024*
C13A0.5543 (3)0.10282 (12)0.72690 (18)0.0175 (8)
H13A0.52220.12620.73300.021*
C14A0.6054 (3)0.17780 (11)0.66222 (18)0.0148 (8)
C15A0.5429 (3)0.20827 (11)0.64259 (19)0.0185 (8)
H15A0.49710.20650.60360.022*
C16A0.5467 (3)0.24122 (12)0.6795 (2)0.0226 (9)
H16A0.50300.26160.66600.027*
C17A0.6145 (3)0.24419 (12)0.7359 (2)0.0232 (9)
H17A0.61740.26670.76100.028*
C18A0.6780 (3)0.21432 (12)0.75574 (19)0.0201 (9)
H18A0.72470.21640.79430.024*
C19A0.6731 (3)0.18144 (12)0.71899 (18)0.0172 (8)
H19A0.71670.16100.73280.021*
C20A0.7031 (3)0.08688 (11)0.51039 (17)0.0140 (8)
C21A0.6377 (3)0.15730 (11)0.46847 (18)0.0143 (8)
C22A0.7568 (3)0.19032 (11)0.56464 (18)0.0155 (8)
C23A0.8975 (3)0.06004 (12)0.55399 (19)0.0186 (9)
C24A0.8915 (3)0.07910 (11)0.68156 (19)0.0169 (8)
C25A0.9020 (3)0.15224 (11)0.65249 (18)0.0153 (8)
C26A0.8625 (3)0.09425 (12)0.43299 (18)0.0167 (8)
C27A0.8528 (3)0.17142 (12)0.40919 (18)0.0185 (9)
C28A0.9525 (3)0.18268 (11)0.53423 (17)0.0154 (8)
C29A1.1497 (3)0.06687 (11)0.65981 (17)0.0131 (8)
C30A1.2479 (3)0.07002 (12)0.69070 (18)0.0163 (8)
H30A1.28270.09330.68920.020*
C31A1.2954 (3)0.03952 (12)0.72368 (19)0.0200 (9)
H31A1.36210.04220.74510.024*
C32A1.2467 (3)0.00529 (12)0.72574 (19)0.0204 (9)
H32A1.27980.01560.74800.024*
C33A1.1490 (3)0.00165 (11)0.69510 (18)0.0180 (8)
H33A1.11490.02180.69640.022*
C34A1.1006 (3)0.03221 (11)0.66248 (18)0.0173 (8)
H34A1.03350.02950.64180.021*
C35A1.1490 (3)0.14688 (11)0.65245 (18)0.0136 (8)
C36A1.2073 (3)0.17161 (12)0.62093 (19)0.0187 (9)
H36A1.21400.16770.57630.022*
C37A1.2559 (3)0.20199 (12)0.6542 (2)0.0240 (9)
H37A1.29440.21890.63190.029*
C38A1.2487 (3)0.20764 (12)0.7193 (2)0.0241 (10)
H38A1.28270.22820.74190.029*
C39A1.1913 (3)0.18314 (12)0.75164 (19)0.0205 (9)
H39A1.18690.18670.79670.025*
C40A1.1408 (3)0.15377 (11)0.71835 (18)0.0174 (8)
H40A1.09960.13780.74040.021*
C41A1.1356 (3)0.09986 (11)0.53572 (16)0.0139 (8)
H41A1.13600.07250.52560.017*
H41B1.20630.10860.54170.017*
C42A1.1501 (3)0.16317 (11)0.44539 (17)0.0147 (8)
C43A1.1139 (3)0.19955 (11)0.43306 (18)0.0168 (8)
H43A1.04570.20510.43680.020*
C44A1.1767 (3)0.22808 (12)0.41526 (19)0.0192 (9)
H44A1.15110.25290.40670.023*
C45A1.2761 (3)0.22019 (12)0.41019 (19)0.0210 (9)
H45A1.31940.23970.39920.025*
C46A1.3126 (3)0.18380 (13)0.4211 (2)0.0252 (10)
H46A1.38060.17830.41680.030*
C47A1.2500 (3)0.15534 (12)0.43837 (19)0.0204 (9)
H47A1.27530.13040.44540.024*
C48A1.0805 (3)0.09275 (11)0.39672 (18)0.0150 (8)
C49A1.0541 (3)0.10695 (13)0.33411 (19)0.0235 (9)
H49A1.03230.13240.32860.028*
C50A1.0591 (4)0.08461 (14)0.2798 (2)0.0287 (11)
H50A1.04120.09480.23740.034*
C51A1.0902 (3)0.04710 (14)0.2872 (2)0.0276 (10)
H51A1.09220.03150.25010.033*
C52A1.1182 (4)0.03287 (13)0.3491 (2)0.0266 (10)
H52A1.14130.00760.35440.032*
C53A1.1128 (3)0.05540 (12)0.4039 (2)0.0218 (9)
H53A1.13120.04520.44630.026*
Ru1B0.95027 (2)0.141361 (8)0.065726 (13)0.00935 (6)
Ru2B0.77097 (2)0.149707 (9)0.124216 (13)0.01061 (7)
Ru3B0.75930 (2)0.114774 (8)0.000365 (13)0.01013 (6)
P1B1.06230 (7)0.13458 (3)0.01102 (4)0.01099 (19)
P2B0.60760 (7)0.13624 (3)0.14157 (4)0.01093 (19)
P3B0.58565 (7)0.11496 (3)0.00632 (4)0.01164 (19)
O1B0.9909 (2)0.06047 (8)0.11646 (13)0.0166 (6)
O2B1.0914 (2)0.16740 (8)0.18338 (13)0.0228 (6)
O3B0.9172 (2)0.22463 (8)0.02485 (13)0.0197 (6)
O4B0.8322 (2)0.07807 (9)0.20321 (14)0.0254 (7)
O5B0.8601 (2)0.20092 (9)0.23486 (14)0.0299 (8)
O6B0.6945 (2)0.21945 (8)0.04407 (13)0.0218 (6)
O7N0.7780 (2)0.03940 (8)0.07390 (14)0.0248 (7)
O8B0.7763 (2)0.07413 (9)0.12786 (14)0.0269 (7)
O9B0.7655 (2)0.18688 (8)0.08184 (13)0.0187 (6)
C1B1.1966 (3)0.12882 (11)0.02456 (18)0.0165 (8)
H1BA1.23880.12870.01120.020*
H1BB1.21700.15080.05280.020*
C2B1.2164 (3)0.09327 (11)0.06379 (18)0.0153 (8)
C3B1.2189 (3)0.05801 (12)0.0341 (2)0.0197 (9)
H3BA1.21440.05640.01200.024*
C4B1.2277 (3)0.02531 (12)0.0709 (2)0.0251 (10)
H4BA1.22540.00150.04970.030*
C5B1.2400 (3)0.02696 (13)0.1386 (2)0.0249 (10)
H5BA1.24560.00440.16370.030*
C6B1.2438 (3)0.06168 (13)0.1687 (2)0.0239 (10)
H6BA1.25560.06320.21490.029*
C7B1.2304 (3)0.09446 (12)0.13185 (19)0.0182 (8)
H7BA1.23090.11820.15330.022*
C8B1.0501 (3)0.09557 (11)0.06920 (18)0.0133 (8)
C9B1.0016 (3)0.06219 (11)0.05504 (18)0.0147 (8)
H9BA0.96630.06130.01820.018*
C10B1.0042 (3)0.03033 (12)0.09388 (19)0.0183 (8)
H10B0.97240.00770.08300.022*
C11B1.0535 (3)0.03176 (12)0.14880 (19)0.0204 (9)
H11B1.05540.01000.17550.024*
C12B1.1000 (3)0.06507 (12)0.16466 (18)0.0188 (9)
H12B1.13200.06630.20290.023*
C13B1.0996 (3)0.09638 (12)0.12477 (17)0.0160 (8)
H13B1.13330.11870.13510.019*
C14B1.0666 (3)0.17601 (11)0.06273 (18)0.0144 (8)
C15B0.9946 (3)0.18015 (11)0.11765 (18)0.0161 (8)
H15B0.94860.16020.12980.019*
C16B0.9894 (3)0.21294 (12)0.15472 (19)0.0199 (9)
H16B0.94000.21530.19190.024*
C17B1.0561 (3)0.24223 (12)0.1375 (2)0.0229 (9)
H17B1.05230.26480.16260.028*
C18B1.1283 (3)0.23856 (12)0.0836 (2)0.0240 (9)
H18B1.17460.25850.07200.029*
C19B1.1334 (3)0.20558 (12)0.0461 (2)0.0210 (9)
H19B1.18280.20330.00900.025*
C20B0.9702 (3)0.08984 (11)0.09573 (17)0.0121 (8)
C21B1.0387 (3)0.15807 (10)0.13762 (18)0.0139 (8)
C22B0.9234 (3)0.19355 (11)0.03834 (18)0.0147 (8)
C23B0.8131 (3)0.10392 (12)0.17163 (19)0.0189 (9)
C24B0.8253 (3)0.18124 (12)0.19488 (18)0.0173 (8)
C25B0.7259 (3)0.19271 (12)0.07068 (18)0.0157 (8)
C26B0.7733 (3)0.06860 (12)0.04949 (18)0.0173 (8)
C27B0.7730 (3)0.08942 (11)0.07923 (19)0.0167 (8)
C28B0.7662 (3)0.16171 (11)0.04736 (17)0.0145 (8)
C29B0.5948 (3)0.10651 (11)0.21202 (17)0.0134 (8)
C30B0.5342 (3)0.07484 (12)0.21128 (19)0.0217 (9)
H30B0.49640.06690.17150.026*
C31B0.5280 (4)0.05449 (13)0.2683 (2)0.0283 (10)
H31B0.48750.03240.26700.034*
C32B0.5804 (3)0.06624 (13)0.3264 (2)0.0259 (10)
H32B0.57660.05210.36510.031*
C33B0.6382 (3)0.09836 (13)0.32857 (19)0.0233 (9)
H33B0.67300.10670.36900.028*
C34B0.6458 (3)0.11862 (12)0.27211 (17)0.0183 (8)
H34B0.68580.14080.27410.022*
C35B0.5234 (3)0.17437 (11)0.15831 (17)0.0124 (7)
C36B0.4232 (3)0.16650 (12)0.1637 (2)0.0189 (8)
H36B0.39840.14150.15630.023*
C37B0.3592 (3)0.19484 (12)0.17970 (19)0.0207 (9)
H37B0.29090.18920.18290.025*
C38B0.3950 (3)0.23121 (12)0.19101 (18)0.0175 (8)
H38B0.35100.25070.20140.021*
C39B0.4948 (3)0.23925 (11)0.18723 (18)0.0170 (8)
H39B0.51970.26410.19600.020*
C40B0.5586 (3)0.21108 (11)0.17060 (17)0.0150 (8)
H40B0.62690.21690.16760.018*
C41B0.5392 (3)0.10925 (11)0.07339 (17)0.0121 (7)
H41C0.46770.11690.06840.015*
H41D0.54230.08210.08510.015*
C42B0.5198 (3)0.15548 (11)0.04562 (18)0.0145 (8)
C43B0.4648 (3)0.18089 (12)0.01374 (19)0.0192 (9)
H43B0.45980.17740.03120.023*
C44B0.4166 (3)0.21164 (12)0.0470 (2)0.0251 (10)
H44B0.38010.22910.02450.030*
C45B0.4223 (3)0.21653 (12)0.1132 (2)0.0240 (9)
H45B0.38870.23710.13620.029*
C46B0.4773 (3)0.19118 (12)0.1454 (2)0.0228 (9)
H46B0.48120.19440.19050.027*
C47B0.5265 (3)0.16125 (12)0.11224 (18)0.0181 (8)
H47B0.56510.14440.13460.022*
C48B0.5174 (3)0.07522 (11)0.04912 (17)0.0135 (8)
C49B0.4157 (3)0.07783 (12)0.07362 (19)0.0198 (9)
H49B0.38090.10100.07020.024*
C50B0.3648 (3)0.04685 (13)0.1030 (2)0.0240 (10)
H50B0.29580.04900.12000.029*
C51B0.4146 (3)0.01286 (12)0.10756 (18)0.0217 (9)
H51B0.37970.00830.12780.026*
C52B0.5151 (3)0.00967 (12)0.08257 (19)0.0198 (9)
H52B0.54930.01360.08530.024*
C53B0.5654 (3)0.04081 (11)0.05346 (18)0.0164 (8)
H53B0.63430.03850.03610.020*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ru1A0.00897 (15)0.01017 (14)0.01122 (13)0.00034 (12)0.00190 (11)0.00117 (11)
Ru2A0.00956 (15)0.01208 (15)0.01064 (13)0.00028 (12)0.00093 (11)0.00143 (11)
Ru3A0.00985 (15)0.01421 (15)0.00964 (13)0.00038 (12)0.00186 (11)0.00057 (11)
P1A0.0110 (5)0.0106 (5)0.0127 (4)0.0003 (4)0.0029 (4)0.0005 (4)
P2A0.0109 (5)0.0128 (5)0.0112 (4)0.0015 (4)0.0011 (4)0.0002 (4)
P3A0.0104 (5)0.0156 (5)0.0096 (4)0.0007 (4)0.0022 (4)0.0001 (4)
O1A0.0198 (16)0.0153 (15)0.0220 (14)0.0020 (12)0.0030 (12)0.0018 (12)
O2A0.0228 (16)0.0214 (16)0.0227 (15)0.0000 (13)0.0069 (13)0.0055 (12)
O3A0.0196 (16)0.0150 (16)0.0291 (16)0.0028 (12)0.0020 (12)0.0020 (12)
O4A0.038 (2)0.0155 (16)0.0276 (16)0.0026 (14)0.0094 (14)0.0023 (13)
O5A0.0244 (17)0.0380 (19)0.0213 (15)0.0017 (15)0.0032 (13)0.0149 (14)
O6A0.0179 (15)0.0184 (15)0.0199 (14)0.0009 (12)0.0020 (11)0.0039 (12)
O7A0.0243 (17)0.0259 (17)0.0249 (15)0.0053 (14)0.0051 (13)0.0101 (13)
O8A0.0332 (19)0.0349 (19)0.0187 (15)0.0028 (15)0.0019 (13)0.0114 (13)
O9A0.0217 (16)0.0200 (15)0.0182 (14)0.0043 (13)0.0051 (12)0.0042 (12)
C1A0.014 (2)0.016 (2)0.0205 (19)0.0014 (16)0.0052 (15)0.0004 (15)
C2A0.0095 (19)0.015 (2)0.0205 (19)0.0022 (16)0.0017 (15)0.0025 (15)
C3A0.013 (2)0.016 (2)0.0214 (19)0.0024 (16)0.0018 (15)0.0036 (16)
C4A0.024 (2)0.027 (2)0.019 (2)0.0002 (19)0.0020 (17)0.0041 (17)
C5A0.030 (3)0.018 (2)0.035 (2)0.008 (2)0.002 (2)0.0049 (19)
C6A0.028 (3)0.020 (2)0.031 (2)0.006 (2)0.0000 (19)0.0075 (18)
C7A0.018 (2)0.022 (2)0.021 (2)0.0025 (18)0.0010 (16)0.0032 (17)
C8A0.0101 (19)0.016 (2)0.0148 (17)0.0020 (15)0.0023 (14)0.0031 (15)
C9A0.013 (2)0.020 (2)0.0181 (19)0.0003 (16)0.0014 (15)0.0014 (16)
C10A0.017 (2)0.016 (2)0.028 (2)0.0006 (17)0.0022 (17)0.0075 (17)
C11A0.019 (2)0.024 (2)0.0180 (19)0.0058 (18)0.0014 (16)0.0110 (17)
C12A0.019 (2)0.029 (2)0.0134 (18)0.0091 (18)0.0045 (16)0.0018 (16)
C13A0.016 (2)0.017 (2)0.0198 (19)0.0015 (17)0.0025 (16)0.0007 (16)
C14A0.014 (2)0.017 (2)0.0146 (18)0.0007 (16)0.0071 (15)0.0016 (15)
C15A0.016 (2)0.019 (2)0.0190 (19)0.0011 (17)0.0011 (16)0.0022 (16)
C16A0.026 (2)0.015 (2)0.027 (2)0.0027 (18)0.0039 (18)0.0008 (17)
C17A0.031 (3)0.018 (2)0.022 (2)0.0072 (19)0.0099 (18)0.0029 (17)
C18A0.023 (2)0.022 (2)0.0161 (19)0.0070 (18)0.0033 (16)0.0006 (16)
C19A0.015 (2)0.019 (2)0.0177 (18)0.0018 (17)0.0042 (16)0.0008 (16)
C20A0.0106 (19)0.018 (2)0.0134 (17)0.0028 (16)0.0025 (14)0.0055 (15)
C21A0.014 (2)0.0130 (19)0.0168 (18)0.0048 (16)0.0033 (15)0.0021 (15)
C22A0.0089 (19)0.020 (2)0.0185 (19)0.0004 (16)0.0030 (15)0.0009 (16)
C23A0.016 (2)0.019 (2)0.0192 (19)0.0020 (17)0.0052 (16)0.0045 (16)
C24A0.0097 (19)0.017 (2)0.023 (2)0.0013 (16)0.0003 (15)0.0001 (16)
C25A0.0106 (19)0.019 (2)0.0165 (18)0.0004 (16)0.0037 (15)0.0039 (16)
C26A0.012 (2)0.021 (2)0.0161 (18)0.0015 (17)0.0002 (15)0.0035 (16)
C27A0.015 (2)0.024 (2)0.0165 (19)0.0024 (17)0.0014 (16)0.0023 (16)
C28A0.014 (2)0.020 (2)0.0128 (17)0.0027 (17)0.0052 (15)0.0014 (15)
C29A0.0124 (19)0.018 (2)0.0094 (16)0.0042 (16)0.0029 (14)0.0008 (14)
C30A0.011 (2)0.023 (2)0.0147 (18)0.0014 (17)0.0003 (15)0.0046 (16)
C31A0.011 (2)0.028 (2)0.0195 (19)0.0039 (17)0.0011 (16)0.0028 (17)
C32A0.020 (2)0.023 (2)0.0173 (19)0.0104 (18)0.0020 (16)0.0024 (16)
C33A0.024 (2)0.012 (2)0.0179 (18)0.0007 (17)0.0040 (17)0.0003 (15)
C34A0.017 (2)0.020 (2)0.0145 (18)0.0029 (17)0.0021 (15)0.0000 (15)
C35A0.0078 (18)0.014 (2)0.0176 (18)0.0028 (15)0.0023 (14)0.0010 (15)
C36A0.018 (2)0.022 (2)0.0154 (18)0.0035 (17)0.0001 (16)0.0003 (16)
C37A0.021 (2)0.022 (2)0.028 (2)0.0048 (19)0.0021 (18)0.0035 (18)
C38A0.021 (2)0.018 (2)0.030 (2)0.0005 (18)0.0088 (18)0.0076 (18)
C39A0.020 (2)0.022 (2)0.0180 (19)0.0032 (18)0.0036 (16)0.0034 (16)
C40A0.014 (2)0.020 (2)0.0184 (19)0.0012 (17)0.0014 (15)0.0003 (16)
C41A0.0129 (19)0.017 (2)0.0110 (17)0.0055 (16)0.0018 (14)0.0007 (14)
C42A0.014 (2)0.018 (2)0.0115 (17)0.0034 (16)0.0016 (14)0.0012 (15)
C43A0.018 (2)0.019 (2)0.0146 (18)0.0014 (17)0.0055 (15)0.0015 (15)
C44A0.021 (2)0.017 (2)0.0195 (19)0.0007 (17)0.0017 (16)0.0013 (16)
C45A0.019 (2)0.023 (2)0.021 (2)0.0054 (18)0.0031 (17)0.0042 (17)
C46A0.013 (2)0.032 (3)0.032 (2)0.0008 (19)0.0058 (18)0.0072 (19)
C47A0.013 (2)0.023 (2)0.025 (2)0.0018 (17)0.0042 (16)0.0086 (17)
C48A0.0092 (19)0.021 (2)0.0152 (18)0.0027 (16)0.0044 (14)0.0032 (15)
C49A0.027 (2)0.024 (2)0.0185 (19)0.0018 (19)0.0008 (17)0.0018 (17)
C50A0.034 (3)0.040 (3)0.0118 (19)0.006 (2)0.0017 (18)0.0033 (18)
C51A0.025 (2)0.037 (3)0.023 (2)0.014 (2)0.0118 (18)0.0149 (19)
C52A0.032 (3)0.021 (2)0.029 (2)0.002 (2)0.010 (2)0.0087 (18)
C53A0.026 (2)0.020 (2)0.019 (2)0.0025 (18)0.0031 (17)0.0038 (16)
Ru1B0.00733 (14)0.00995 (14)0.01097 (13)0.00050 (12)0.00192 (11)0.00086 (11)
Ru2B0.00823 (15)0.01379 (15)0.01019 (13)0.00051 (12)0.00259 (11)0.00082 (11)
Ru3B0.00708 (14)0.01262 (15)0.01073 (13)0.00025 (12)0.00130 (11)0.00110 (11)
P1B0.0095 (5)0.0114 (5)0.0126 (4)0.0003 (4)0.0033 (4)0.0003 (4)
P2B0.0091 (5)0.0128 (5)0.0111 (4)0.0002 (4)0.0023 (3)0.0013 (4)
P3B0.0083 (5)0.0148 (5)0.0120 (4)0.0001 (4)0.0019 (4)0.0011 (4)
O1B0.0151 (15)0.0147 (15)0.0200 (13)0.0003 (12)0.0019 (11)0.0014 (11)
O2B0.0235 (17)0.0186 (15)0.0239 (15)0.0002 (13)0.0057 (13)0.0056 (12)
O3B0.0211 (16)0.0133 (15)0.0245 (15)0.0024 (12)0.0022 (12)0.0033 (11)
O4B0.0240 (17)0.0272 (17)0.0271 (16)0.0105 (14)0.0111 (13)0.0122 (13)
O5B0.0311 (19)0.0370 (19)0.0211 (15)0.0134 (15)0.0013 (14)0.0114 (14)
O6B0.0259 (17)0.0207 (16)0.0203 (14)0.0053 (13)0.0083 (12)0.0021 (12)
O7N0.0214 (17)0.0198 (16)0.0310 (16)0.0047 (13)0.0042 (13)0.0085 (13)
O8B0.0246 (17)0.0347 (18)0.0207 (15)0.0043 (14)0.0003 (13)0.0118 (13)
O9B0.0195 (16)0.0186 (15)0.0186 (14)0.0002 (12)0.0051 (12)0.0037 (12)
C1B0.0097 (19)0.022 (2)0.0188 (19)0.0005 (16)0.0058 (15)0.0009 (16)
C2B0.0046 (18)0.021 (2)0.0197 (19)0.0015 (16)0.0004 (14)0.0037 (16)
C3B0.013 (2)0.024 (2)0.021 (2)0.0057 (17)0.0009 (16)0.0009 (17)
C4B0.022 (2)0.017 (2)0.035 (2)0.0064 (18)0.0004 (19)0.0015 (18)
C5B0.016 (2)0.024 (2)0.033 (2)0.0043 (19)0.0023 (18)0.0127 (19)
C6B0.013 (2)0.034 (3)0.023 (2)0.0000 (19)0.0009 (17)0.0076 (18)
C7B0.011 (2)0.020 (2)0.024 (2)0.0015 (16)0.0017 (16)0.0014 (16)
C8B0.0090 (18)0.0139 (19)0.0168 (18)0.0026 (15)0.0008 (14)0.0032 (15)
C9B0.013 (2)0.016 (2)0.0156 (18)0.0018 (16)0.0027 (15)0.0030 (15)
C10B0.016 (2)0.017 (2)0.0214 (19)0.0011 (17)0.0030 (16)0.0024 (16)
C11B0.023 (2)0.019 (2)0.0188 (19)0.0035 (18)0.0017 (17)0.0085 (16)
C12B0.020 (2)0.021 (2)0.0158 (18)0.0078 (18)0.0043 (16)0.0002 (16)
C13B0.014 (2)0.021 (2)0.0136 (17)0.0027 (16)0.0025 (15)0.0014 (15)
C14B0.015 (2)0.0133 (19)0.0171 (18)0.0009 (16)0.0095 (15)0.0014 (15)
C15B0.015 (2)0.017 (2)0.0178 (18)0.0011 (16)0.0057 (15)0.0012 (15)
C16B0.025 (2)0.019 (2)0.0161 (19)0.0040 (18)0.0054 (17)0.0016 (16)
C17B0.033 (3)0.014 (2)0.023 (2)0.0043 (19)0.0083 (18)0.0064 (16)
C18B0.031 (3)0.012 (2)0.031 (2)0.0040 (18)0.0067 (19)0.0003 (17)
C19B0.022 (2)0.019 (2)0.022 (2)0.0002 (18)0.0037 (17)0.0029 (16)
C20B0.0060 (18)0.018 (2)0.0129 (17)0.0021 (15)0.0031 (14)0.0045 (15)
C21B0.0114 (19)0.0097 (19)0.0207 (19)0.0018 (15)0.0024 (15)0.0018 (15)
C22B0.0109 (19)0.019 (2)0.0144 (17)0.0001 (16)0.0020 (14)0.0029 (15)
C23B0.014 (2)0.026 (2)0.0183 (19)0.0020 (18)0.0072 (16)0.0007 (17)
C24B0.015 (2)0.023 (2)0.0152 (18)0.0013 (17)0.0059 (15)0.0025 (16)
C25B0.014 (2)0.020 (2)0.0133 (17)0.0025 (17)0.0058 (15)0.0050 (16)
C26B0.0081 (19)0.025 (2)0.0166 (18)0.0008 (17)0.0045 (15)0.0023 (16)
C27B0.012 (2)0.018 (2)0.0202 (19)0.0009 (16)0.0006 (15)0.0009 (16)
C28B0.0090 (19)0.021 (2)0.0136 (17)0.0016 (16)0.0030 (14)0.0054 (16)
C29B0.0126 (19)0.018 (2)0.0098 (16)0.0030 (16)0.0028 (14)0.0000 (14)
C30B0.025 (2)0.023 (2)0.0183 (19)0.0064 (19)0.0064 (17)0.0014 (17)
C31B0.037 (3)0.022 (2)0.029 (2)0.008 (2)0.012 (2)0.0029 (18)
C32B0.027 (3)0.033 (3)0.020 (2)0.007 (2)0.0095 (18)0.0100 (18)
C33B0.023 (2)0.034 (3)0.0148 (19)0.007 (2)0.0065 (17)0.0001 (17)
C34B0.019 (2)0.024 (2)0.0122 (17)0.0008 (18)0.0021 (15)0.0021 (16)
C35B0.0109 (19)0.0154 (19)0.0110 (16)0.0016 (15)0.0015 (14)0.0013 (14)
C36B0.010 (2)0.017 (2)0.030 (2)0.0030 (16)0.0041 (16)0.0029 (17)
C37B0.014 (2)0.025 (2)0.023 (2)0.0010 (18)0.0033 (16)0.0052 (17)
C38B0.017 (2)0.022 (2)0.0148 (18)0.0059 (17)0.0040 (15)0.0011 (15)
C39B0.021 (2)0.016 (2)0.0142 (18)0.0003 (17)0.0033 (16)0.0002 (15)
C40B0.014 (2)0.019 (2)0.0126 (17)0.0008 (16)0.0035 (15)0.0007 (15)
C41B0.0099 (18)0.0121 (19)0.0144 (17)0.0014 (15)0.0019 (14)0.0029 (14)
C42B0.0064 (18)0.016 (2)0.0203 (19)0.0024 (15)0.0000 (15)0.0012 (15)
C43B0.017 (2)0.022 (2)0.0179 (19)0.0037 (17)0.0015 (16)0.0005 (16)
C44B0.024 (2)0.020 (2)0.030 (2)0.0069 (19)0.0017 (19)0.0061 (18)
C45B0.019 (2)0.022 (2)0.028 (2)0.0027 (18)0.0069 (18)0.0061 (18)
C46B0.015 (2)0.030 (2)0.022 (2)0.0023 (18)0.0009 (17)0.0073 (18)
C47B0.016 (2)0.022 (2)0.0158 (18)0.0009 (17)0.0030 (15)0.0023 (16)
C48B0.0107 (19)0.019 (2)0.0112 (17)0.0039 (16)0.0023 (14)0.0002 (14)
C49B0.012 (2)0.028 (2)0.0201 (19)0.0000 (17)0.0018 (16)0.0043 (17)
C50B0.011 (2)0.038 (3)0.023 (2)0.0025 (19)0.0021 (17)0.0066 (19)
C51B0.024 (2)0.026 (2)0.0152 (19)0.0090 (19)0.0030 (17)0.0040 (16)
C52B0.021 (2)0.020 (2)0.0184 (19)0.0043 (18)0.0017 (16)0.0007 (16)
C53B0.012 (2)0.019 (2)0.0169 (18)0.0037 (16)0.0018 (15)0.0010 (15)
Geometric parameters (Å, º) top
Ru1A—C21A1.873 (4)Ru1B—C21B1.873 (4)
Ru1A—C20A1.927 (4)Ru1B—C20B1.934 (4)
Ru1A—C22A1.946 (4)Ru1B—C22B1.952 (4)
Ru1A—P1A2.3353 (10)Ru1B—P1B2.3406 (10)
Ru1A—Ru3A2.8454 (4)Ru1B—Ru2B2.8504 (4)
Ru1A—Ru2A2.9054 (4)Ru1B—Ru3B2.8992 (4)
Ru2A—C24A1.898 (4)Ru2B—C24B1.906 (4)
Ru2A—C25A1.922 (4)Ru2B—C25B1.932 (4)
Ru2A—C23A1.932 (4)Ru2B—C23B1.940 (4)
Ru2A—P2A2.3232 (10)Ru2B—P2B2.3195 (10)
Ru2A—Ru3A2.8353 (4)Ru2B—Ru3B2.8451 (4)
Ru3A—C27A1.898 (4)Ru3B—C27B1.893 (4)
Ru3A—C28A1.935 (4)Ru3B—C26B1.929 (4)
Ru3A—C26A1.940 (4)Ru3B—C28B1.933 (4)
Ru3A—P3A2.3196 (10)Ru3B—P3B2.3191 (10)
P1A—C14A1.825 (4)P1B—C14B1.821 (4)
P1A—C8A1.832 (4)P1B—C8B1.825 (4)
P1A—C1A1.859 (4)P1B—C1B1.867 (4)
P2A—C35A1.815 (4)P2B—C35B1.823 (4)
P2A—C29A1.843 (4)P2B—C29B1.825 (4)
P2A—C41A1.850 (4)P2B—C41B1.845 (4)
P3A—C42A1.828 (4)P3B—C42B1.820 (4)
P3A—C48A1.837 (4)P3B—C48B1.841 (4)
P3A—C41A1.854 (4)P3B—C41B1.850 (4)
O1A—C20A1.150 (5)O1B—C20B1.145 (4)
O2A—C21A1.149 (4)O2B—C21B1.153 (5)
O3A—C22A1.141 (5)O3B—C22B1.136 (5)
O4A—C23A1.147 (5)O4B—C23B1.134 (5)
O5A—C24A1.145 (5)O5B—C24B1.134 (5)
O6A—C25A1.150 (5)O6B—C25B1.147 (5)
O7A—C26A1.140 (5)O7N—C26B1.148 (5)
O8A—C27A1.144 (5)O8B—C27B1.149 (5)
O9A—C28A1.138 (5)O9B—C28B1.141 (5)
C1A—C2A1.520 (5)C1B—C2B1.502 (5)
C1A—H1AA0.9900C1B—H1BA0.9900
C1A—H1AB0.9900C1B—H1BB0.9900
C2A—C3A1.385 (5)C2B—C3B1.393 (6)
C2A—C7A1.397 (5)C2B—C7B1.397 (5)
C3A—C4A1.392 (6)C3B—C4B1.382 (6)
C3A—H3AA0.9500C3B—H3BA0.9500
C4A—C5A1.383 (6)C4B—C5B1.389 (6)
C4A—H4AA0.9500C4B—H4BA0.9500
C5A—C6A1.385 (6)C5B—C6B1.376 (6)
C5A—H5AA0.9500C5B—H5BA0.9500
C6A—C7A1.382 (6)C6B—C7B1.387 (6)
C6A—H6AA0.9500C6B—H6BA0.9500
C7A—H7AA0.9500C7B—H7BA0.9500
C8A—C9A1.388 (5)C8B—C9B1.399 (5)
C8A—C13A1.400 (5)C8B—C13B1.403 (5)
C9A—C10A1.389 (5)C9B—C10B1.388 (5)
C9A—H9AA0.9500C9B—H9BA0.9500
C10A—C11A1.376 (6)C10B—C11B1.390 (5)
C10A—H10A0.9500C10B—H10B0.9500
C11A—C12A1.389 (6)C11B—C12B1.394 (6)
C11A—H11A0.9500C11B—H11B0.9500
C12A—C13A1.386 (5)C12B—C13B1.382 (5)
C12A—H12A0.9500C12B—H12B0.9500
C13A—H13A0.9500C13B—H13B0.9500
C14A—C19A1.393 (5)C14B—C19B1.391 (6)
C14A—C15A1.394 (6)C14B—C15B1.399 (5)
C15A—C16A1.391 (5)C15B—C16B1.388 (5)
C15A—H15A0.9500C15B—H15B0.9500
C16A—C17A1.386 (6)C16B—C17B1.386 (6)
C16A—H16A0.9500C16B—H16B0.9500
C17A—C18A1.386 (6)C17B—C18B1.383 (6)
C17A—H17A0.9500C17B—H17B0.9500
C18A—C19A1.387 (5)C18B—C19B1.399 (6)
C18A—H18A0.9500C18B—H18B0.9500
C19A—H19A0.9500C19B—H19B0.9500
C29A—C30A1.391 (5)C29B—C30B1.385 (6)
C29A—C34A1.397 (6)C29B—C34B1.405 (5)
C30A—C31A1.386 (5)C30B—C31B1.395 (6)
C30A—H30A0.9500C30B—H30B0.9500
C31A—C32A1.380 (6)C31B—C32B1.374 (6)
C31A—H31A0.9500C31B—H31B0.9500
C32A—C33A1.386 (6)C32B—C33B1.374 (6)
C32A—H32A0.9500C32B—H32B0.9500
C33A—C34A1.390 (5)C33B—C34B1.386 (5)
C33A—H33A0.9500C33B—H33B0.9500
C34A—H34A0.9500C34B—H34B0.9500
C35A—C36A1.393 (5)C35B—C36B1.393 (5)
C35A—C40A1.404 (5)C35B—C40B1.395 (5)
C36A—C37A1.392 (6)C36B—C37B1.389 (6)
C36A—H36A0.9500C36B—H36B0.9500
C37A—C38A1.378 (6)C37B—C38B1.383 (6)
C37A—H37A0.9500C37B—H37B0.9500
C38A—C39A1.390 (6)C38B—C39B1.382 (6)
C38A—H38A0.9500C38B—H38B0.9500
C39A—C40A1.375 (6)C39B—C40B1.388 (5)
C39A—H39A0.9500C39B—H39B0.9500
C40A—H40A0.9500C40B—H40B0.9500
C41A—H41A0.9900C41B—H41C0.9900
C41A—H41B0.9900C41B—H41D0.9900
C42A—C43A1.388 (6)C42B—C43B1.385 (5)
C42A—C47A1.397 (5)C42B—C47B1.409 (5)
C43A—C44A1.396 (5)C43B—C44B1.400 (6)
C43A—H43A0.9500C43B—H43B0.9500
C44A—C45A1.381 (6)C44B—C45B1.392 (6)
C44A—H44A0.9500C44B—H44B0.9500
C45A—C46A1.386 (6)C45B—C46B1.388 (6)
C45A—H45A0.9500C45B—H45B0.9500
C46A—C47A1.389 (6)C46B—C47B1.382 (6)
C46A—H46A0.9500C46B—H46B0.9500
C47A—H47A0.9500C47B—H47B0.9500
C48A—C49A1.391 (5)C48B—C53B1.387 (5)
C48A—C53A1.393 (6)C48B—C49B1.396 (5)
C49A—C50A1.383 (6)C49B—C50B1.389 (6)
C49A—H49A0.9500C49B—H49B0.9500
C50A—C51A1.394 (7)C50B—C51B1.385 (6)
C50A—H50A0.9500C50B—H50B0.9500
C51A—C52A1.380 (6)C51B—C52B1.385 (6)
C51A—H51A0.9500C51B—H51B0.9500
C52A—C53A1.397 (5)C52B—C53B1.388 (5)
C52A—H52A0.9500C52B—H52B0.9500
C53A—H53A0.9500C53B—H53B0.9500
C21A—Ru1A—C20A92.48 (16)C21B—Ru1B—C20B89.79 (15)
C21A—Ru1A—C22A88.00 (16)C21B—Ru1B—C22B90.29 (16)
C20A—Ru1A—C22A174.93 (16)C20B—Ru1B—C22B176.63 (15)
C21A—Ru1A—P1A96.65 (12)C21B—Ru1B—P1B100.04 (12)
C20A—Ru1A—P1A94.10 (11)C20B—Ru1B—P1B92.70 (11)
C22A—Ru1A—P1A90.85 (11)C22B—Ru1B—P1B90.60 (11)
C21A—Ru1A—Ru3A97.54 (11)C21B—Ru1B—Ru2B96.46 (12)
C20A—Ru1A—Ru3A89.31 (11)C20B—Ru1B—Ru2B92.88 (10)
C22A—Ru1A—Ru3A85.63 (11)C22B—Ru1B—Ru2B83.77 (11)
P1A—Ru1A—Ru3A165.24 (3)P1B—Ru1B—Ru2B162.58 (3)
C21A—Ru1A—Ru2A155.76 (12)C21B—Ru1B—Ru3B154.94 (12)
C20A—Ru1A—Ru2A81.74 (11)C20B—Ru1B—Ru3B85.51 (11)
C22A—Ru1A—Ru2A95.78 (11)C22B—Ru1B—Ru3B93.01 (11)
P1A—Ru1A—Ru2A107.20 (3)P1B—Ru1B—Ru3B104.75 (3)
Ru3A—Ru1A—Ru2A59.067 (10)Ru2B—Ru1B—Ru3B59.310 (10)
C24A—Ru2A—C25A88.49 (16)C24B—Ru2B—C25B92.16 (16)
C24A—Ru2A—C23A91.20 (17)C24B—Ru2B—C23B92.57 (17)
C25A—Ru2A—C23A171.90 (17)C25B—Ru2B—C23B175.23 (16)
C24A—Ru2A—P2A100.14 (12)C24B—Ru2B—P2B105.96 (12)
C25A—Ru2A—P2A94.67 (12)C25B—Ru2B—P2B91.13 (12)
C23A—Ru2A—P2A93.35 (13)C23B—Ru2B—P2B88.18 (12)
C24A—Ru2A—Ru3A169.64 (12)C24B—Ru2B—Ru3B156.83 (11)
C25A—Ru2A—Ru3A96.22 (11)C25B—Ru2B—Ru3B81.21 (11)
C23A—Ru2A—Ru3A82.83 (11)C23B—Ru2B—Ru3B94.17 (12)
P2A—Ru2A—Ru3A88.70 (3)P2B—Ru2B—Ru3B96.40 (3)
C24A—Ru2A—Ru1A112.89 (12)C24B—Ru2B—Ru1B97.34 (12)
C25A—Ru2A—Ru1A78.57 (11)C25B—Ru2B—Ru1B93.23 (11)
C23A—Ru2A—Ru1A94.12 (12)C23B—Ru2B—Ru1B85.54 (11)
P2A—Ru2A—Ru1A145.91 (3)P2B—Ru2B—Ru1B156.11 (3)
Ru3A—Ru2A—Ru1A59.411 (10)Ru3B—Ru2B—Ru1B61.198 (10)
C27A—Ru3A—C28A93.00 (17)C27B—Ru3B—C26B92.62 (17)
C27A—Ru3A—C26A92.66 (17)C27B—Ru3B—C28B87.53 (16)
C28A—Ru3A—C26A174.30 (16)C26B—Ru3B—C28B171.69 (16)
C27A—Ru3A—P3A106.25 (12)C27B—Ru3B—P3B99.65 (12)
C28A—Ru3A—P3A90.55 (12)C26B—Ru3B—P3B93.26 (12)
C26A—Ru3A—P3A87.18 (12)C28B—Ru3B—P3B94.90 (11)
C27A—Ru3A—Ru2A156.38 (12)C27B—Ru3B—Ru2B170.95 (12)
C28A—Ru3A—Ru2A80.85 (11)C26B—Ru3B—Ru2B83.90 (12)
C26A—Ru3A—Ru2A94.21 (11)C28B—Ru3B—Ru2B94.70 (11)
P3A—Ru3A—Ru2A96.65 (3)P3B—Ru3B—Ru2B88.92 (3)
C27A—Ru3A—Ru1A95.98 (12)C27B—Ru3B—Ru1B112.31 (12)
C28A—Ru3A—Ru1A90.47 (11)C26B—Ru3B—Ru1B90.30 (11)
C26A—Ru3A—Ru1A89.65 (12)C28B—Ru3B—Ru1B81.97 (11)
P3A—Ru3A—Ru1A157.65 (3)P3B—Ru3B—Ru1B147.64 (3)
Ru2A—Ru3A—Ru1A61.522 (10)Ru2B—Ru3B—Ru1B59.492 (10)
C14A—P1A—C8A101.86 (17)C14B—P1B—C8B103.22 (17)
C14A—P1A—C1A102.16 (18)C14B—P1B—C1B102.44 (18)
C8A—P1A—C1A100.24 (17)C8B—P1B—C1B100.09 (18)
C14A—P1A—Ru1A112.63 (12)C14B—P1B—Ru1B112.94 (12)
C8A—P1A—Ru1A122.60 (13)C8B—P1B—Ru1B121.04 (13)
C1A—P1A—Ru1A114.63 (12)C1B—P1B—Ru1B114.71 (12)
C35A—P2A—C29A101.65 (17)C35B—P2B—C29B98.54 (17)
C35A—P2A—C41A105.59 (18)C35B—P2B—C41B105.67 (17)
C29A—P2A—C41A98.81 (16)C29B—P2B—C41B102.85 (17)
C35A—P2A—Ru2A117.11 (13)C35B—P2B—Ru2B120.05 (13)
C29A—P2A—Ru2A116.51 (13)C29B—P2B—Ru2B115.70 (13)
C41A—P2A—Ru2A114.77 (12)C41B—P2B—Ru2B111.91 (12)
C42A—P3A—C48A99.72 (17)C42B—P3B—C48B101.87 (17)
C42A—P3A—C41A106.04 (18)C42B—P3B—C41B106.45 (17)
C48A—P3A—C41A102.82 (17)C48B—P3B—C41B98.07 (16)
C42A—P3A—Ru3A118.19 (13)C42B—P3B—Ru3B116.88 (13)
C48A—P3A—Ru3A116.05 (13)C48B—P3B—Ru3B117.15 (13)
C41A—P3A—Ru3A112.18 (12)C41B—P3B—Ru3B114.07 (12)
C2A—C1A—P1A115.3 (3)C2B—C1B—P1B113.4 (3)
C2A—C1A—H1AA108.5C2B—C1B—H1BA108.9
P1A—C1A—H1AA108.5P1B—C1B—H1BA108.9
C2A—C1A—H1AB108.5C2B—C1B—H1BB108.9
P1A—C1A—H1AB108.5P1B—C1B—H1BB108.9
H1AA—C1A—H1AB107.5H1BA—C1B—H1BB107.7
C3A—C2A—C7A118.4 (4)C3B—C2B—C7B117.6 (4)
C3A—C2A—C1A121.4 (4)C3B—C2B—C1B121.7 (3)
C7A—C2A—C1A120.2 (3)C7B—C2B—C1B120.7 (4)
C2A—C3A—C4A120.8 (4)C4B—C3B—C2B120.9 (4)
C2A—C3A—H3AA119.6C4B—C3B—H3BA119.6
C4A—C3A—H3AA119.6C2B—C3B—H3BA119.6
C5A—C4A—C3A119.8 (4)C3B—C4B—C5B120.7 (4)
C5A—C4A—H4AA120.1C3B—C4B—H4BA119.7
C3A—C4A—H4AA120.1C5B—C4B—H4BA119.7
C4A—C5A—C6A120.0 (4)C6B—C5B—C4B119.1 (4)
C4A—C5A—H5AA120.0C6B—C5B—H5BA120.4
C6A—C5A—H5AA120.0C4B—C5B—H5BA120.4
C7A—C6A—C5A119.8 (4)C5B—C6B—C7B120.3 (4)
C7A—C6A—H6AA120.1C5B—C6B—H6BA119.9
C5A—C6A—H6AA120.1C7B—C6B—H6BA119.9
C6A—C7A—C2A121.1 (4)C6B—C7B—C2B121.3 (4)
C6A—C7A—H7AA119.5C6B—C7B—H7BA119.4
C2A—C7A—H7AA119.5C2B—C7B—H7BA119.4
C9A—C8A—C13A119.1 (4)C9B—C8B—C13B118.3 (3)
C9A—C8A—P1A120.8 (3)C9B—C8B—P1B120.3 (3)
C13A—C8A—P1A119.9 (3)C13B—C8B—P1B121.0 (3)
C8A—C9A—C10A120.4 (4)C10B—C9B—C8B121.1 (4)
C8A—C9A—H9AA119.8C10B—C9B—H9BA119.4
C10A—C9A—H9AA119.8C8B—C9B—H9BA119.4
C11A—C10A—C9A120.2 (4)C9B—C10B—C11B119.7 (4)
C11A—C10A—H10A119.9C9B—C10B—H10B120.2
C9A—C10A—H10A119.9C11B—C10B—H10B120.2
C10A—C11A—C12A120.0 (4)C10B—C11B—C12B120.0 (4)
C10A—C11A—H11A120.0C10B—C11B—H11B120.0
C12A—C11A—H11A120.0C12B—C11B—H11B120.0
C13A—C12A—C11A120.0 (4)C13B—C12B—C11B120.0 (4)
C13A—C12A—H12A120.0C13B—C12B—H12B120.0
C11A—C12A—H12A120.0C11B—C12B—H12B120.0
C12A—C13A—C8A120.2 (4)C12B—C13B—C8B120.9 (4)
C12A—C13A—H13A119.9C12B—C13B—H13B119.6
C8A—C13A—H13A119.9C8B—C13B—H13B119.6
C19A—C14A—C15A118.4 (4)C19B—C14B—C15B118.4 (4)
C19A—C14A—P1A120.1 (3)C19B—C14B—P1B122.0 (3)
C15A—C14A—P1A121.4 (3)C15B—C14B—P1B119.3 (3)
C16A—C15A—C14A120.8 (4)C16B—C15B—C14B121.1 (4)
C16A—C15A—H15A119.6C16B—C15B—H15B119.5
C14A—C15A—H15A119.6C14B—C15B—H15B119.5
C17A—C16A—C15A119.9 (4)C17B—C16B—C15B119.9 (4)
C17A—C16A—H16A120.0C17B—C16B—H16B120.0
C15A—C16A—H16A120.0C15B—C16B—H16B120.0
C16A—C17A—C18A120.1 (4)C18B—C17B—C16B119.8 (4)
C16A—C17A—H17A120.0C18B—C17B—H17B120.1
C18A—C17A—H17A120.0C16B—C17B—H17B120.1
C17A—C18A—C19A119.7 (4)C17B—C18B—C19B120.2 (4)
C17A—C18A—H18A120.2C17B—C18B—H18B119.9
C19A—C18A—H18A120.2C19B—C18B—H18B119.9
C18A—C19A—C14A121.2 (4)C14B—C19B—C18B120.5 (4)
C18A—C19A—H19A119.4C14B—C19B—H19B119.7
C14A—C19A—H19A119.4C18B—C19B—H19B119.7
O1A—C20A—Ru1A173.2 (3)O1B—C20B—Ru1B173.4 (3)
O2A—C21A—Ru1A179.5 (4)O2B—C21B—Ru1B177.3 (4)
O3A—C22A—Ru1A172.5 (3)O3B—C22B—Ru1B173.3 (3)
O4A—C23A—Ru2A173.4 (3)O4B—C23B—Ru2B173.9 (3)
O5A—C24A—Ru2A177.1 (4)O5B—C24B—Ru2B176.6 (3)
O6A—C25A—Ru2A171.3 (3)O6B—C25B—Ru2B173.1 (3)
O7A—C26A—Ru3A174.3 (3)O7N—C26B—Ru3B173.6 (3)
O8A—C27A—Ru3A176.1 (4)O8B—C27B—Ru3B176.6 (4)
O9A—C28A—Ru3A173.8 (3)O9B—C28B—Ru3B171.4 (3)
C30A—C29A—C34A118.4 (4)C30B—C29B—C34B118.3 (3)
C30A—C29A—P2A122.4 (3)C30B—C29B—P2B125.2 (3)
C34A—C29A—P2A119.2 (3)C34B—C29B—P2B116.4 (3)
C31A—C30A—C29A120.7 (4)C29B—C30B—C31B120.6 (4)
C31A—C30A—H30A119.7C29B—C30B—H30B119.7
C29A—C30A—H30A119.7C31B—C30B—H30B119.7
C32A—C31A—C30A120.7 (4)C32B—C31B—C30B120.2 (4)
C32A—C31A—H31A119.7C32B—C31B—H31B119.9
C30A—C31A—H31A119.7C30B—C31B—H31B119.9
C31A—C32A—C33A119.4 (4)C33B—C32B—C31B120.1 (4)
C31A—C32A—H32A120.3C33B—C32B—H32B120.0
C33A—C32A—H32A120.3C31B—C32B—H32B120.0
C32A—C33A—C34A120.2 (4)C32B—C33B—C34B120.3 (4)
C32A—C33A—H33A119.9C32B—C33B—H33B119.8
C34A—C33A—H33A119.9C34B—C33B—H33B119.8
C33A—C34A—C29A120.7 (4)C33B—C34B—C29B120.4 (4)
C33A—C34A—H34A119.7C33B—C34B—H34B119.8
C29A—C34A—H34A119.7C29B—C34B—H34B119.8
C36A—C35A—C40A117.8 (4)C36B—C35B—C40B118.7 (4)
C36A—C35A—P2A123.9 (3)C36B—C35B—P2B119.8 (3)
C40A—C35A—P2A118.2 (3)C40B—C35B—P2B121.4 (3)
C37A—C36A—C35A120.6 (4)C37B—C36B—C35B120.6 (4)
C37A—C36A—H36A119.7C37B—C36B—H36B119.7
C35A—C36A—H36A119.7C35B—C36B—H36B119.7
C38A—C37A—C36A120.4 (4)C38B—C37B—C36B120.0 (4)
C38A—C37A—H37A119.8C38B—C37B—H37B120.0
C36A—C37A—H37A119.8C36B—C37B—H37B120.0
C37A—C38A—C39A119.7 (4)C39B—C38B—C37B120.0 (4)
C37A—C38A—H38A120.1C39B—C38B—H38B120.0
C39A—C38A—H38A120.1C37B—C38B—H38B120.0
C40A—C39A—C38A119.9 (4)C38B—C39B—C40B120.1 (4)
C40A—C39A—H39A120.1C38B—C39B—H39B119.9
C38A—C39A—H39A120.1C40B—C39B—H39B119.9
C39A—C40A—C35A121.4 (4)C39B—C40B—C35B120.6 (4)
C39A—C40A—H40A119.3C39B—C40B—H40B119.7
C35A—C40A—H40A119.3C35B—C40B—H40B119.7
P2A—C41A—P3A115.5 (2)P2B—C41B—P3B115.6 (2)
P2A—C41A—H41A108.4P2B—C41B—H41C108.4
P3A—C41A—H41A108.4P3B—C41B—H41C108.4
P2A—C41A—H41B108.4P2B—C41B—H41D108.4
P3A—C41A—H41B108.4P3B—C41B—H41D108.4
H41A—C41A—H41B107.5H41C—C41B—H41D107.4
C43A—C42A—C47A118.9 (4)C43B—C42B—C47B118.7 (4)
C43A—C42A—P3A121.2 (3)C43B—C42B—P3B123.9 (3)
C47A—C42A—P3A119.8 (3)C47B—C42B—P3B117.5 (3)
C42A—C43A—C44A120.7 (4)C42B—C43B—C44B120.7 (4)
C42A—C43A—H43A119.6C42B—C43B—H43B119.6
C44A—C43A—H43A119.6C44B—C43B—H43B119.6
C45A—C44A—C43A119.8 (4)C45B—C44B—C43B119.9 (4)
C45A—C44A—H44A120.1C45B—C44B—H44B120.0
C43A—C44A—H44A120.1C43B—C44B—H44B120.0
C44A—C45A—C46A120.0 (4)C46B—C45B—C44B119.6 (4)
C44A—C45A—H45A120.0C46B—C45B—H45B120.2
C46A—C45A—H45A120.0C44B—C45B—H45B120.2
C45A—C46A—C47A120.2 (4)C47B—C46B—C45B120.5 (4)
C45A—C46A—H46A119.9C47B—C46B—H46B119.8
C47A—C46A—H46A119.9C45B—C46B—H46B119.8
C46A—C47A—C42A120.3 (4)C46B—C47B—C42B120.6 (4)
C46A—C47A—H47A119.8C46B—C47B—H47B119.7
C42A—C47A—H47A119.8C42B—C47B—H47B119.7
C49A—C48A—C53A118.7 (4)C53B—C48B—C49B118.4 (4)
C49A—C48A—P3A116.8 (3)C53B—C48B—P3B119.8 (3)
C53A—C48A—P3A124.5 (3)C49B—C48B—P3B121.7 (3)
C50A—C49A—C48A121.1 (4)C50B—C49B—C48B120.5 (4)
C50A—C49A—H49A119.4C50B—C49B—H49B119.8
C48A—C49A—H49A119.4C48B—C49B—H49B119.8
C49A—C50A—C51A120.0 (4)C51B—C50B—C49B120.2 (4)
C49A—C50A—H50A120.0C51B—C50B—H50B119.9
C51A—C50A—H50A120.0C49B—C50B—H50B119.9
C52A—C51A—C50A119.4 (4)C52B—C51B—C50B120.0 (4)
C52A—C51A—H51A120.3C52B—C51B—H51B120.0
C50A—C51A—H51A120.3C50B—C51B—H51B120.0
C51A—C52A—C53A120.5 (4)C51B—C52B—C53B119.5 (4)
C51A—C52A—H52A119.7C51B—C52B—H52B120.3
C53A—C52A—H52A119.7C53B—C52B—H52B120.3
C48A—C53A—C52A120.2 (4)C48B—C53B—C52B121.4 (4)
C48A—C53A—H53A119.9C48B—C53B—H53B119.3
C52A—C53A—H53A119.9C52B—C53B—H53B119.3
C21A—Ru1A—Ru2A—C24A155.6 (3)C50A—C51A—C52A—C53A1.8 (7)
C20A—Ru1A—Ru2A—C24A78.05 (17)C49A—C48A—C53A—C52A0.0 (6)
C22A—Ru1A—Ru2A—C24A106.41 (17)P3A—C48A—C53A—C52A178.6 (3)
P1A—Ru1A—Ru2A—C24A13.71 (13)C51A—C52A—C53A—C48A1.0 (7)
Ru3A—Ru1A—Ru2A—C24A172.22 (13)C21B—Ru1B—Ru2B—C24B16.11 (17)
C21A—Ru1A—Ru2A—C25A121.0 (3)C20B—Ru1B—Ru2B—C24B106.22 (16)
C20A—Ru1A—Ru2A—C25A161.48 (15)C22B—Ru1B—Ru2B—C24B73.48 (16)
C22A—Ru1A—Ru2A—C25A22.98 (16)P1B—Ru1B—Ru2B—C24B145.24 (15)
P1A—Ru1A—Ru2A—C25A69.71 (12)Ru3B—Ru1B—Ru2B—C24B170.73 (12)
Ru3A—Ru1A—Ru2A—C25A104.35 (11)C21B—Ru1B—Ru2B—C25B108.70 (16)
C21A—Ru1A—Ru2A—C23A62.5 (3)C20B—Ru1B—Ru2B—C25B161.18 (15)
C20A—Ru1A—Ru2A—C23A15.00 (16)C22B—Ru1B—Ru2B—C25B19.12 (16)
C22A—Ru1A—Ru2A—C23A160.55 (16)P1B—Ru1B—Ru2B—C25B52.64 (15)
P1A—Ru1A—Ru2A—C23A106.76 (12)Ru3B—Ru1B—Ru2B—C25B78.13 (11)
Ru3A—Ru1A—Ru2A—C23A79.17 (12)C21B—Ru1B—Ru2B—C23B75.91 (17)
C21A—Ru1A—Ru2A—P2A39.7 (3)C20B—Ru1B—Ru2B—C23B14.20 (16)
C20A—Ru1A—Ru2A—P2A117.18 (12)C22B—Ru1B—Ru2B—C23B165.50 (16)
C22A—Ru1A—Ru2A—P2A58.36 (12)P1B—Ru1B—Ru2B—C23B122.74 (15)
P1A—Ru1A—Ru2A—P2A151.05 (5)Ru3B—Ru1B—Ru2B—C23B97.25 (12)
Ru3A—Ru1A—Ru2A—P2A23.01 (5)C21B—Ru1B—Ru2B—P2B151.15 (13)
C21A—Ru1A—Ru2A—Ru3A16.6 (3)C20B—Ru1B—Ru2B—P2B61.04 (12)
C20A—Ru1A—Ru2A—Ru3A94.17 (11)C22B—Ru1B—Ru2B—P2B119.26 (13)
C22A—Ru1A—Ru2A—Ru3A81.37 (11)P1B—Ru1B—Ru2B—P2B47.50 (12)
P1A—Ru1A—Ru2A—Ru3A174.06 (3)Ru3B—Ru1B—Ru2B—P2B22.01 (7)
C24A—Ru2A—Ru3A—C27A63.1 (7)C21B—Ru1B—Ru2B—Ru3B173.16 (11)
C25A—Ru2A—Ru3A—C27A53.6 (3)C20B—Ru1B—Ru2B—Ru3B83.04 (10)
C23A—Ru2A—Ru3A—C27A118.3 (3)C22B—Ru1B—Ru2B—Ru3B97.25 (11)
P2A—Ru2A—Ru3A—C27A148.1 (3)P1B—Ru1B—Ru2B—Ru3B25.50 (9)
Ru1A—Ru2A—Ru3A—C27A19.2 (3)C24B—Ru2B—Ru3B—C26B117.9 (3)
C24A—Ru2A—Ru3A—C28A139.4 (7)C25B—Ru2B—Ru3B—C26B167.41 (16)
C25A—Ru2A—Ru3A—C28A22.77 (16)C23B—Ru2B—Ru3B—C26B11.38 (17)
C23A—Ru2A—Ru3A—C28A165.33 (17)P2B—Ru2B—Ru3B—C26B77.26 (12)
P2A—Ru2A—Ru3A—C28A71.78 (12)Ru1B—Ru2B—Ru3B—C26B93.96 (12)
Ru1A—Ru2A—Ru3A—C28A95.56 (12)C24B—Ru2B—Ru3B—C28B53.9 (3)
C24A—Ru2A—Ru3A—C26A43.4 (7)C25B—Ru2B—Ru3B—C28B20.82 (16)
C25A—Ru2A—Ru3A—C26A160.09 (17)C23B—Ru2B—Ru3B—C28B160.39 (16)
C23A—Ru2A—Ru3A—C26A11.80 (17)P2B—Ru2B—Ru3B—C28B110.97 (11)
P2A—Ru2A—Ru3A—C26A105.35 (12)Ru1B—Ru2B—Ru3B—C28B77.81 (11)
Ru1A—Ru2A—Ru3A—C26A87.31 (12)C24B—Ru2B—Ru3B—P3B148.7 (3)
C24A—Ru2A—Ru3A—P3A131.1 (7)C25B—Ru2B—Ru3B—P3B74.01 (12)
C25A—Ru2A—Ru3A—P3A112.26 (12)C23B—Ru2B—Ru3B—P3B104.78 (12)
C23A—Ru2A—Ru3A—P3A75.84 (13)P2B—Ru2B—Ru3B—P3B16.14 (4)
P2A—Ru2A—Ru3A—P3A17.70 (4)Ru1B—Ru2B—Ru3B—P3B172.64 (3)
Ru1A—Ru2A—Ru3A—P3A174.96 (3)C24B—Ru2B—Ru3B—Ru1B24.0 (3)
C24A—Ru2A—Ru3A—Ru1A43.9 (7)C25B—Ru2B—Ru3B—Ru1B98.63 (12)
C25A—Ru2A—Ru3A—Ru1A72.78 (12)C23B—Ru2B—Ru3B—Ru1B82.58 (12)
C23A—Ru2A—Ru3A—Ru1A99.11 (12)P2B—Ru2B—Ru3B—Ru1B171.22 (3)
P2A—Ru2A—Ru3A—Ru1A167.34 (3)C21B—Ru1B—Ru3B—C27B159.5 (3)
C21A—Ru1A—Ru3A—C27A14.43 (17)C20B—Ru1B—Ru3B—C27B79.65 (17)
C20A—Ru1A—Ru3A—C27A106.84 (16)C22B—Ru1B—Ru3B—C27B103.37 (17)
C22A—Ru1A—Ru3A—C27A72.97 (17)P1B—Ru1B—Ru3B—C27B11.96 (13)
P1A—Ru1A—Ru3A—C27A149.57 (16)Ru2B—Ru1B—Ru3B—C27B175.70 (13)
Ru2A—Ru1A—Ru3A—C27A172.38 (12)C21B—Ru1B—Ru3B—C26B66.5 (3)
C21A—Ru1A—Ru3A—C28A107.50 (16)C20B—Ru1B—Ru3B—C26B13.31 (15)
C20A—Ru1A—Ru3A—C28A160.09 (15)C22B—Ru1B—Ru3B—C26B163.67 (16)
C22A—Ru1A—Ru3A—C28A20.10 (16)P1B—Ru1B—Ru3B—C26B104.92 (12)
P1A—Ru1A—Ru3A—C28A56.50 (16)Ru2B—Ru1B—Ru3B—C26B82.74 (12)
Ru2A—Ru1A—Ru3A—C28A79.32 (11)C21B—Ru1B—Ru3B—C28B116.5 (3)
C21A—Ru1A—Ru3A—C26A78.21 (16)C20B—Ru1B—Ru3B—C28B163.63 (15)
C20A—Ru1A—Ru3A—C26A14.20 (15)C22B—Ru1B—Ru3B—C28B19.39 (15)
C22A—Ru1A—Ru3A—C26A165.60 (16)P1B—Ru1B—Ru3B—C28B72.02 (11)
P1A—Ru1A—Ru3A—C26A117.80 (16)Ru2B—Ru1B—Ru3B—C28B100.32 (11)
Ru2A—Ru1A—Ru3A—C26A94.98 (11)C21B—Ru1B—Ru3B—P3B30.1 (3)
C21A—Ru1A—Ru3A—P3A159.91 (14)C20B—Ru1B—Ru3B—P3B109.89 (11)
C20A—Ru1A—Ru3A—P3A67.50 (13)C22B—Ru1B—Ru3B—P3B67.09 (12)
C22A—Ru1A—Ru3A—P3A112.70 (13)P1B—Ru1B—Ru3B—P3B158.50 (6)
P1A—Ru1A—Ru3A—P3A36.10 (14)Ru2B—Ru1B—Ru3B—P3B13.84 (5)
Ru2A—Ru1A—Ru3A—P3A13.28 (7)C21B—Ru1B—Ru3B—Ru2B16.2 (3)
C21A—Ru1A—Ru3A—Ru2A173.19 (12)C20B—Ru1B—Ru3B—Ru2B96.04 (10)
C20A—Ru1A—Ru3A—Ru2A80.78 (11)C22B—Ru1B—Ru3B—Ru2B80.93 (11)
C22A—Ru1A—Ru3A—Ru2A99.42 (11)P1B—Ru1B—Ru3B—Ru2B172.34 (3)
P1A—Ru1A—Ru3A—Ru2A22.82 (11)C21B—Ru1B—P1B—C14B94.96 (18)
C21A—Ru1A—P1A—C14A93.36 (18)C20B—Ru1B—P1B—C14B174.77 (18)
C20A—Ru1A—P1A—C14A173.65 (18)C22B—Ru1B—P1B—C14B4.56 (18)
C22A—Ru1A—P1A—C14A5.28 (18)Ru2B—Ru1B—P1B—C14B66.21 (17)
Ru3A—Ru1A—P1A—C14A70.66 (18)Ru3B—Ru1B—P1B—C14B88.71 (14)
Ru2A—Ru1A—P1A—C14A91.04 (14)C21B—Ru1B—P1B—C8B142.05 (18)
C21A—Ru1A—P1A—C8A144.57 (19)C20B—Ru1B—P1B—C8B51.78 (18)
C20A—Ru1A—P1A—C8A51.58 (18)C22B—Ru1B—P1B—C8B127.55 (18)
C22A—Ru1A—P1A—C8A127.35 (19)Ru2B—Ru1B—P1B—C8B56.79 (18)
Ru3A—Ru1A—P1A—C8A51.4 (2)Ru3B—Ru1B—P1B—C8B34.28 (15)
Ru2A—Ru1A—P1A—C8A31.03 (15)C21B—Ru1B—P1B—C1B21.92 (18)
C21A—Ru1A—P1A—C1A22.88 (18)C20B—Ru1B—P1B—C1B68.35 (18)
C20A—Ru1A—P1A—C1A70.10 (18)C22B—Ru1B—P1B—C1B112.32 (18)
C22A—Ru1A—P1A—C1A110.96 (18)Ru2B—Ru1B—P1B—C1B176.92 (15)
Ru3A—Ru1A—P1A—C1A173.10 (15)Ru3B—Ru1B—P1B—C1B154.41 (14)
Ru2A—Ru1A—P1A—C1A152.72 (14)C24B—Ru2B—P2B—C35B50.18 (18)
C24A—Ru2A—P2A—C35A93.65 (18)C25B—Ru2B—P2B—C35B42.39 (17)
C25A—Ru2A—P2A—C35A4.34 (18)C23B—Ru2B—P2B—C35B142.33 (18)
C23A—Ru2A—P2A—C35A174.53 (18)Ru3B—Ru2B—P2B—C35B123.68 (13)
Ru3A—Ru2A—P2A—C35A91.79 (14)Ru1B—Ru2B—P2B—C35B142.97 (13)
Ru1A—Ru2A—P2A—C35A72.12 (15)C24B—Ru2B—P2B—C29B67.78 (19)
C24A—Ru2A—P2A—C29A26.94 (18)C25B—Ru2B—P2B—C29B160.35 (18)
C25A—Ru2A—P2A—C29A116.24 (17)C23B—Ru2B—P2B—C29B24.37 (18)
C23A—Ru2A—P2A—C29A64.88 (17)Ru3B—Ru2B—P2B—C29B118.37 (14)
Ru3A—Ru2A—P2A—C29A147.63 (13)Ru1B—Ru2B—P2B—C29B99.07 (15)
Ru1A—Ru2A—P2A—C29A167.30 (12)C24B—Ru2B—P2B—C41B174.86 (18)
C24A—Ru2A—P2A—C41A141.69 (18)C25B—Ru2B—P2B—C41B82.29 (17)
C25A—Ru2A—P2A—C41A129.01 (18)C23B—Ru2B—P2B—C41B92.99 (18)
C23A—Ru2A—P2A—C41A49.87 (18)Ru3B—Ru2B—P2B—C41B1.00 (14)
Ru3A—Ru2A—P2A—C41A32.88 (14)Ru1B—Ru2B—P2B—C41B18.29 (16)
Ru1A—Ru2A—P2A—C41A52.55 (15)C27B—Ru3B—P3B—C42B90.63 (19)
C27A—Ru3A—P3A—C42A48.17 (19)C26B—Ru3B—P3B—C42B176.15 (18)
C28A—Ru3A—P3A—C42A45.12 (17)C28B—Ru3B—P3B—C42B2.30 (18)
C26A—Ru3A—P3A—C42A140.12 (17)Ru2B—Ru3B—P3B—C42B92.32 (14)
Ru2A—Ru3A—P3A—C42A125.97 (13)Ru1B—Ru3B—P3B—C42B80.42 (15)
Ru1A—Ru3A—P3A—C42A137.70 (14)C27B—Ru3B—P3B—C48B30.65 (18)
C27A—Ru3A—P3A—C48A70.20 (19)C26B—Ru3B—P3B—C48B62.58 (18)
C28A—Ru3A—P3A—C48A163.49 (18)C28B—Ru3B—P3B—C48B118.97 (17)
C26A—Ru3A—P3A—C48A21.74 (18)Ru2B—Ru3B—P3B—C48B146.40 (13)
Ru2A—Ru3A—P3A—C48A115.66 (14)Ru1B—Ru3B—P3B—C48B158.30 (13)
Ru1A—Ru3A—P3A—C48A103.93 (15)C27B—Ru3B—P3B—C41B144.34 (18)
C27A—Ru3A—P3A—C41A172.02 (18)C26B—Ru3B—P3B—C41B51.12 (18)
C28A—Ru3A—P3A—C41A78.74 (18)C28B—Ru3B—P3B—C41B127.33 (17)
C26A—Ru3A—P3A—C41A96.03 (18)Ru2B—Ru3B—P3B—C41B32.71 (13)
Ru2A—Ru3A—P3A—C41A2.12 (14)Ru1B—Ru3B—P3B—C41B44.61 (15)
Ru1A—Ru3A—P3A—C41A13.84 (17)C14B—P1B—C1B—C2B173.1 (3)
C14A—P1A—C1A—C2A167.3 (3)C8B—P1B—C1B—C2B67.0 (3)
C8A—P1A—C1A—C2A62.7 (3)Ru1B—P1B—C1B—C2B64.2 (3)
Ru1A—P1A—C1A—C2A70.6 (3)P1B—C1B—C2B—C3B74.7 (4)
P1A—C1A—C2A—C3A97.4 (4)P1B—C1B—C2B—C7B103.7 (4)
P1A—C1A—C2A—C7A84.3 (4)C7B—C2B—C3B—C4B4.5 (6)
C7A—C2A—C3A—C4A2.7 (6)C1B—C2B—C3B—C4B173.9 (4)
C1A—C2A—C3A—C4A175.6 (4)C2B—C3B—C4B—C5B3.6 (6)
C2A—C3A—C4A—C5A1.9 (6)C3B—C4B—C5B—C6B0.4 (7)
C3A—C4A—C5A—C6A0.5 (7)C4B—C5B—C6B—C7B3.2 (6)
C4A—C5A—C6A—C7A0.1 (7)C5B—C6B—C7B—C2B2.2 (6)
C5A—C6A—C7A—C2A0.7 (7)C3B—C2B—C7B—C6B1.7 (6)
C3A—C2A—C7A—C6A2.1 (6)C1B—C2B—C7B—C6B176.8 (4)
C1A—C2A—C7A—C6A176.2 (4)C14B—P1B—C8B—C9B151.7 (3)
C14A—P1A—C8A—C9A150.7 (3)C1B—P1B—C8B—C9B102.9 (3)
C1A—P1A—C8A—C9A104.4 (3)Ru1B—P1B—C8B—C9B24.2 (4)
Ru1A—P1A—C8A—C9A23.7 (4)C14B—P1B—C8B—C13B36.5 (4)
C14A—P1A—C8A—C13A34.9 (4)C1B—P1B—C8B—C13B69.0 (3)
C1A—P1A—C8A—C13A70.0 (3)Ru1B—P1B—C8B—C13B164.0 (3)
Ru1A—P1A—C8A—C13A161.8 (3)C13B—C8B—C9B—C10B1.5 (6)
C13A—C8A—C9A—C10A0.7 (6)P1B—C8B—C9B—C10B170.5 (3)
P1A—C8A—C9A—C10A175.2 (3)C8B—C9B—C10B—C11B1.7 (6)
C8A—C9A—C10A—C11A0.6 (6)C9B—C10B—C11B—C12B0.0 (6)
C9A—C10A—C11A—C12A1.2 (6)C10B—C11B—C12B—C13B1.8 (6)
C10A—C11A—C12A—C13A0.4 (6)C11B—C12B—C13B—C8B2.0 (6)
C11A—C12A—C13A—C8A0.9 (6)C9B—C8B—C13B—C12B0.4 (6)
C9A—C8A—C13A—C12A1.5 (6)P1B—C8B—C13B—C12B172.3 (3)
P1A—C8A—C13A—C12A176.0 (3)C8B—P1B—C14B—C19B137.6 (3)
C8A—P1A—C14A—C19A48.6 (3)C1B—P1B—C14B—C19B34.0 (4)
C1A—P1A—C14A—C19A151.9 (3)Ru1B—P1B—C14B—C19B90.0 (3)
Ru1A—P1A—C14A—C19A84.6 (3)C8B—P1B—C14B—C15B48.7 (3)
C8A—P1A—C14A—C15A136.0 (3)C1B—P1B—C14B—C15B152.3 (3)
C1A—P1A—C14A—C15A32.6 (4)Ru1B—P1B—C14B—C15B83.8 (3)
Ru1A—P1A—C14A—C15A90.9 (3)C19B—C14B—C15B—C16B0.2 (6)
C19A—C14A—C15A—C16A1.2 (6)P1B—C14B—C15B—C16B173.7 (3)
P1A—C14A—C15A—C16A176.7 (3)C14B—C15B—C16B—C17B0.0 (6)
C14A—C15A—C16A—C17A1.0 (6)C15B—C16B—C17B—C18B0.5 (6)
C15A—C16A—C17A—C18A0.3 (6)C16B—C17B—C18B—C19B0.7 (6)
C16A—C17A—C18A—C19A0.2 (6)C15B—C14B—C19B—C18B0.0 (6)
C17A—C18A—C19A—C14A0.1 (6)P1B—C14B—C19B—C18B173.8 (3)
C15A—C14A—C19A—C18A0.6 (6)C17B—C18B—C19B—C14B0.5 (6)
P1A—C14A—C19A—C18A176.2 (3)Ru3B—Ru1B—C20B—O1B179 (100)
C20A—Ru1A—C21A—O2A169 (100)C35B—P2B—C29B—C30B99.8 (4)
Ru3A—Ru1A—C21A—O2A102 (100)C41B—P2B—C29B—C30B8.6 (4)
Ru2A—Ru1A—C21A—O2A116 (100)Ru2B—P2B—C29B—C30B130.9 (3)
Ru2A—Ru1A—C22A—O3A180 (100)C35B—P2B—C29B—C34B75.8 (3)
C35A—P2A—C29A—C30A25.8 (3)C41B—P2B—C29B—C34B175.9 (3)
C41A—P2A—C29A—C30A82.2 (3)Ru2B—P2B—C29B—C34B53.6 (3)
Ru2A—P2A—C29A—C30A154.3 (3)C34B—C29B—C30B—C31B3.1 (6)
C35A—P2A—C29A—C34A156.2 (3)P2B—C29B—C30B—C31B178.5 (3)
C41A—P2A—C29A—C34A95.8 (3)C29B—C30B—C31B—C32B1.6 (7)
Ru2A—P2A—C29A—C34A27.7 (3)C30B—C31B—C32B—C33B0.7 (7)
C34A—C29A—C30A—C31A0.5 (5)C31B—C32B—C33B—C34B1.4 (7)
P2A—C29A—C30A—C31A178.5 (3)C32B—C33B—C34B—C29B0.1 (6)
C29A—C30A—C31A—C32A0.9 (6)C30B—C29B—C34B—C33B2.4 (6)
C30A—C31A—C32A—C33A0.8 (6)P2B—C29B—C34B—C33B178.2 (3)
C31A—C32A—C33A—C34A0.1 (6)C29B—P2B—C35B—C36B58.6 (3)
C32A—C33A—C34A—C29A0.3 (6)C41B—P2B—C35B—C36B47.4 (3)
C30A—C29A—C34A—C33A0.2 (5)Ru2B—P2B—C35B—C36B175.0 (3)
P2A—C29A—C34A—C33A177.9 (3)C29B—P2B—C35B—C40B116.7 (3)
C29A—P2A—C35A—C36A115.1 (3)C41B—P2B—C35B—C40B137.3 (3)
C41A—P2A—C35A—C36A12.4 (4)Ru2B—P2B—C35B—C40B9.7 (3)
Ru2A—P2A—C35A—C36A116.8 (3)C40B—C35B—C36B—C37B1.3 (6)
C29A—P2A—C35A—C40A64.3 (3)P2B—C35B—C36B—C37B176.7 (3)
C41A—P2A—C35A—C40A167.0 (3)C35B—C36B—C37B—C38B0.6 (6)
Ru2A—P2A—C35A—C40A63.9 (3)C36B—C37B—C38B—C39B0.9 (6)
C40A—C35A—C36A—C37A0.2 (6)C37B—C38B—C39B—C40B1.5 (6)
P2A—C35A—C36A—C37A179.1 (3)C38B—C39B—C40B—C35B0.8 (6)
C35A—C36A—C37A—C38A1.3 (6)C36B—C35B—C40B—C39B0.6 (5)
C36A—C37A—C38A—C39A0.9 (7)P2B—C35B—C40B—C39B176.0 (3)
C37A—C38A—C39A—C40A1.0 (6)C35B—P2B—C41B—P3B107.6 (2)
C38A—C39A—C40A—C35A2.6 (6)C29B—P2B—C41B—P3B149.6 (2)
C36A—C35A—C40A—C39A2.2 (6)Ru2B—P2B—C41B—P3B24.7 (2)
P2A—C35A—C40A—C39A177.2 (3)C42B—P3B—C41B—P2B88.3 (2)
C35A—P2A—C41A—P3A90.8 (2)C48B—P3B—C41B—P2B166.7 (2)
C29A—P2A—C41A—P3A164.4 (2)Ru3B—P3B—C41B—P2B42.1 (2)
Ru2A—P2A—C41A—P3A39.7 (3)C48B—P3B—C42B—C43B115.4 (4)
C42A—P3A—C41A—P2A109.5 (2)C41B—P3B—C42B—C43B13.2 (4)
C48A—P3A—C41A—P2A146.2 (2)Ru3B—P3B—C42B—C43B115.6 (3)
Ru3A—P3A—C41A—P2A20.9 (3)C48B—P3B—C42B—C47B65.3 (3)
C48A—P3A—C42A—C43A119.5 (3)C41B—P3B—C42B—C47B167.5 (3)
C41A—P3A—C42A—C43A134.1 (3)Ru3B—P3B—C42B—C47B63.7 (3)
Ru3A—P3A—C42A—C43A7.2 (4)C47B—C42B—C43B—C44B0.2 (6)
C48A—P3A—C42A—C47A56.0 (3)P3B—C42B—C43B—C44B179.5 (3)
C41A—P3A—C42A—C47A50.5 (3)C42B—C43B—C44B—C45B1.1 (7)
Ru3A—P3A—C42A—C47A177.3 (3)C43B—C44B—C45B—C46B1.1 (7)
C47A—C42A—C43A—C44A1.3 (6)C44B—C45B—C46B—C47B0.1 (7)
P3A—C42A—C43A—C44A176.8 (3)C45B—C46B—C47B—C42B1.4 (6)
C42A—C43A—C44A—C45A0.4 (6)C43B—C42B—C47B—C46B1.4 (6)
C43A—C44A—C45A—C46A1.7 (6)P3B—C42B—C47B—C46B179.2 (3)
C44A—C45A—C46A—C47A1.2 (6)C42B—P3B—C48B—C53B154.1 (3)
C45A—C46A—C47A—C42A0.5 (6)C41B—P3B—C48B—C53B97.1 (3)
C43A—C42A—C47A—C46A1.8 (6)Ru3B—P3B—C48B—C53B25.3 (3)
P3A—C42A—C47A—C46A177.4 (3)C42B—P3B—C48B—C49B30.6 (3)
C42A—P3A—C48A—C49A58.6 (3)C41B—P3B—C48B—C49B78.2 (3)
C41A—P3A—C48A—C49A167.6 (3)Ru3B—P3B—C48B—C49B159.4 (3)
Ru3A—P3A—C48A—C49A69.6 (3)C53B—C48B—C49B—C50B1.5 (6)
C42A—P3A—C48A—C53A122.8 (4)P3B—C48B—C49B—C50B177.0 (3)
C41A—P3A—C48A—C53A13.8 (4)C48B—C49B—C50B—C51B0.8 (6)
Ru3A—P3A—C48A—C53A109.0 (3)C49B—C50B—C51B—C52B0.2 (6)
C53A—C48A—C49A—C50A0.3 (6)C50B—C51B—C52B—C53B0.4 (6)
P3A—C48A—C49A—C50A178.4 (3)C49B—C48B—C53B—C52B1.4 (6)
C48A—C49A—C50A—C51A0.5 (7)P3B—C48B—C53B—C52B176.8 (3)
C49A—C50A—C51A—C52A1.5 (7)C51B—C52B—C53B—C48B0.4 (6)
Hydrogen-bond geometry (Å, º) top
Cg1 and Cg2 are the centroids of the C8B–C13B and C29A–C34A rings, respectively.
D—H···AD—HH···AD···AD—H···A
C5A—H5AA···O1Ai0.952.553.221 (5)127
C10B—H10B···O1Bii0.952.583.250 (5)128
C3B—H3BA···Cg10.952.783.485 (4)131
C12B—H12B···Cg2iii0.952.673.539 (4)153
Symmetry codes: (i) x+1, y, z+1; (ii) x+2, y, z; (iii) x, y, z1.
Selected bond lengths (Å) top
Ru1A—P1A2.3353 (10)Ru1B—P1B2.3406 (10)
Ru1A—Ru3A2.8454 (4)Ru1B—Ru2B2.8504 (4)
Ru1A—Ru2A2.9054 (4)Ru1B—Ru3B2.8992 (4)
Ru2A—P2A2.3232 (10)Ru2B—P2B2.3195 (10)
Ru2A—Ru3A2.8353 (4)Ru2B—Ru3B2.8451 (4)
Ru3A—P3A2.3196 (10)Ru3B—P3B2.3191 (10)
Hydrogen-bond geometry (Å, º) top
Cg1 and Cg2 are the centroids of the C8B–C13B and C29A–C34A rings, respectively.
D—H···AD—HH···AD···AD—H···A
C5A—H5AA···O1Ai0.95002.55003.221 (5)127.00
C10B—H10B···O1Bii0.95002.58003.250 (5)128.00
C3B—H3BA···Cg10.95002.78003.485 (4)131.00
C12B—H12B···Cg2iii0.95002.67003.539 (4)153.00
Symmetry codes: (i) x+1, y, z+1; (ii) x+2, y, z; (iii) x, y, z1.
 

Footnotes

Thomson Reuters ResearcherID: B-6034-2009.

§Thomson Reuters ResearcherID: E-2833-2010.

Thomson Reuters Researcher ID: E-6050-2011.

Acknowledgements

The authors would like to thank the Malaysian Government and Universiti Sains Malaysia (USM) for the Research Grant 1001/PJJAUH/811188. IAK is grateful to USM for a Visiting Researcher position.

References

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Volume 70| Part 8| August 2014| Pages m293-m294
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