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In the title complex, {[Ni(C16H10O4)(C12H8N2)(H2O)]·H2O}n, the NiII ion is in a distorted octa­hedral geometry and coordinated by two N atoms of a 1,10-phenanthroline (phen) ligand, three carboxylate O atoms of two different bpea2− ligands and one water mol­ecule. The [Ni(phen)H2O] units are connected by two different 4,4′-(ethene-1,2-di­yl)dibenzoate (bpea2−) bridges, forming a one-dimensional zigzag chain structure. One bpea2− ligand coordinates to Ni in a bis-monodentate fashion, while the other acts as a bis-bidentate chelate.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806048707/sj2171sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806048707/sj2171Isup2.hkl
Contains datablock I

CCDC reference: 630483

Key indicators

  • Single-crystal X-ray study
  • T = 295 K
  • Mean [sigma](C-C) = 0.005 Å
  • R factor = 0.042
  • wR factor = 0.124
  • Data-to-parameter ratio = 15.6

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT420_ALERT_2_B D-H Without Acceptor O2W - H2W2 ... ?
Alert level C PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.92 Ratio PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 4
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 2 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: RAPID-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Poly[[[aqua(1,10-phenanthroline-κ2N,N')nickel(II)]-µ3– 4,4'-(ethene-1,2-diyl)dibenzoato-µ2-4,4'-(ethene-1,2-diyl)dibenzoato] monohydrate] top
Crystal data top
[Ni(C16H10O4)(C12H8N2)(H2O)]·H2OZ = 2
Mr = 541.19F(000) = 560
Triclinic, P1Dx = 1.511 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 10.055 (4) ÅCell parameters from 10323 reflections
b = 11.476 (5) Åθ = 3.1–27.5°
c = 11.793 (5) ŵ = 0.86 mm1
α = 104.101 (19)°T = 295 K
β = 103.065 (16)°Block, green
γ = 107.632 (16)°0.36 × 0.25 × 0.15 mm
V = 1189.8 (9) Å3
Data collection top
Rigaku R-AXIS RAPID
diffractometer
5413 independent reflections
Radiation source: fine-focus sealed tube4576 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.020
Detector resolution: 10 pixels mm-1θmax = 27.5°, θmin = 3.1°
ω scansh = 1213
Absorption correction: multi-scan
(ABSCOR; Higashi, 1995)
k = 1414
Tmin = 0.746, Tmax = 0.881l = 1515
11792 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.042Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.124H atoms treated by a mixture of independent and constrained refinement
S = 1.08 w = 1/[σ2(Fo2) + (0.078P)2 + 0.3494P]
where P = (Fo2 + 2Fc2)/3
5413 reflections(Δ/σ)max = 0.001
346 parametersΔρmax = 1.11 e Å3
6 restraintsΔρmin = 0.65 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ni10.69933 (3)0.65303 (3)0.68740 (3)0.02947 (11)
O10.47449 (17)0.57825 (16)0.67232 (15)0.0349 (3)
O20.64850 (17)0.63558 (16)0.84814 (15)0.0362 (4)
O30.74054 (19)0.48907 (16)0.63733 (18)0.0428 (4)
O40.5467 (2)0.31757 (19)0.6185 (2)0.0496 (5)
O1W0.68511 (18)0.65233 (17)0.51106 (16)0.0366 (4)
H1W10.621 (2)0.682 (2)0.483 (2)0.044*
H1W20.655 (3)0.5722 (11)0.472 (2)0.044*
O2W0.3649 (5)0.1809 (6)0.7382 (4)0.1503 (18)
H2W10.393 (7)0.221 (6)0.688 (5)0.180*
H2W20.278 (4)0.121 (5)0.696 (5)0.180*
N10.9232 (2)0.7644 (2)0.76179 (19)0.0384 (4)
N20.6955 (3)0.8399 (2)0.7375 (2)0.0407 (5)
C10.5140 (2)0.5939 (2)0.7870 (2)0.0307 (4)
C20.3997 (2)0.5677 (2)0.8493 (2)0.0328 (5)
C30.2518 (3)0.4983 (3)0.7791 (2)0.0454 (6)
H30.22450.46580.69340.054*
C40.1456 (3)0.4774 (3)0.8360 (2)0.0458 (6)
H40.04730.42910.78850.055*
C50.1836 (3)0.5278 (2)0.9636 (2)0.0346 (5)
C60.3315 (3)0.5928 (2)1.0339 (2)0.0365 (5)
H60.35900.62331.11970.044*
C70.4389 (2)0.6126 (2)0.9763 (2)0.0358 (5)
H70.53790.65651.02390.043*
C80.0714 (3)0.5141 (2)1.0267 (2)0.0376 (5)
H80.10300.52611.11070.045*
C90.6708 (2)0.3690 (2)0.6106 (2)0.0335 (5)
C100.7499 (3)0.2824 (2)0.5695 (2)0.0353 (5)
C110.8781 (3)0.3291 (3)0.5413 (2)0.0441 (6)
H110.91280.41440.54240.053*
C120.9553 (3)0.2516 (3)0.5118 (3)0.0519 (7)
H121.03950.28440.49100.062*
C130.9087 (3)0.1262 (3)0.5128 (3)0.0544 (7)
C140.7770 (4)0.0773 (3)0.5358 (3)0.0608 (8)
H140.74160.00840.53350.073*
C150.6971 (3)0.1541 (3)0.5622 (3)0.0501 (7)
H150.60770.11900.57500.060*
C161.0059 (4)0.0548 (3)0.4916 (3)0.0601 (8)
H161.08240.09190.46370.072*
C170.9540 (3)0.8927 (3)0.8062 (2)0.0447 (6)
C181.0342 (3)0.7238 (3)0.7724 (3)0.0535 (7)
H181.01300.63510.74260.064*
C191.1824 (3)0.8091 (4)0.8267 (4)0.0760 (11)
H191.25780.77760.83170.091*
C201.2139 (4)0.9389 (4)0.8720 (3)0.0793 (12)
H201.31160.99670.90860.095*
C211.0993 (4)0.9858 (3)0.8636 (3)0.0654 (10)
C221.1217 (5)1.1182 (4)0.9115 (4)0.0861 (14)
H221.21751.17970.94900.103*
C231.0104 (6)1.1566 (3)0.9044 (4)0.0898 (16)
H231.02991.24450.93840.108*
C240.8570 (5)1.0657 (3)0.8450 (3)0.0668 (10)
C250.7324 (6)1.0974 (3)0.8340 (4)0.0837 (14)
H250.74351.18350.86680.100*
C260.5935 (5)1.0028 (4)0.7751 (4)0.0754 (12)
H260.51041.02400.76750.091*
C270.5795 (4)0.8745 (3)0.7270 (3)0.0550 (7)
H270.48560.81060.68590.066*
C280.8320 (3)0.9330 (2)0.7954 (2)0.0457 (6)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ni10.02470 (16)0.02582 (16)0.03594 (17)0.00822 (11)0.01362 (11)0.00530 (11)
O10.0290 (7)0.0382 (8)0.0354 (8)0.0101 (6)0.0152 (7)0.0081 (7)
O20.0281 (7)0.0391 (9)0.0393 (9)0.0105 (7)0.0138 (7)0.0099 (7)
O30.0399 (9)0.0325 (9)0.0574 (11)0.0174 (7)0.0219 (8)0.0068 (8)
O40.0390 (9)0.0458 (10)0.0791 (14)0.0232 (8)0.0298 (10)0.0278 (10)
O1W0.0311 (8)0.0376 (9)0.0391 (9)0.0117 (7)0.0142 (7)0.0085 (7)
O2W0.118 (3)0.170 (5)0.113 (3)0.001 (3)0.020 (3)0.047 (3)
N10.0294 (9)0.0377 (10)0.0388 (11)0.0044 (8)0.0119 (8)0.0069 (9)
N20.0521 (12)0.0337 (10)0.0437 (11)0.0204 (9)0.0235 (10)0.0130 (9)
C10.0280 (10)0.0270 (10)0.0361 (11)0.0100 (8)0.0138 (9)0.0064 (9)
C20.0292 (10)0.0335 (11)0.0378 (11)0.0120 (9)0.0165 (9)0.0098 (9)
C30.0311 (11)0.0600 (16)0.0346 (12)0.0083 (11)0.0137 (10)0.0067 (11)
C40.0258 (11)0.0597 (16)0.0417 (13)0.0064 (11)0.0141 (10)0.0093 (12)
C50.0343 (11)0.0369 (12)0.0397 (12)0.0151 (9)0.0208 (10)0.0150 (10)
C60.0361 (11)0.0419 (12)0.0339 (11)0.0158 (10)0.0157 (10)0.0117 (10)
C70.0286 (10)0.0387 (12)0.0385 (12)0.0110 (9)0.0129 (9)0.0107 (10)
C80.0380 (12)0.0415 (12)0.0384 (12)0.0146 (10)0.0216 (10)0.0141 (10)
C90.0331 (11)0.0346 (11)0.0368 (11)0.0182 (9)0.0122 (9)0.0112 (9)
C100.0367 (11)0.0376 (12)0.0341 (11)0.0211 (10)0.0102 (9)0.0084 (9)
C110.0387 (13)0.0451 (14)0.0462 (14)0.0182 (11)0.0167 (11)0.0060 (11)
C120.0442 (14)0.0628 (18)0.0479 (15)0.0274 (13)0.0169 (12)0.0066 (13)
C130.0606 (17)0.075 (2)0.0417 (14)0.0481 (16)0.0177 (13)0.0136 (14)
C140.083 (2)0.0467 (16)0.076 (2)0.0412 (16)0.0354 (18)0.0290 (16)
C150.0584 (17)0.0422 (14)0.0683 (18)0.0293 (13)0.0332 (15)0.0256 (14)
C160.0639 (19)0.069 (2)0.0589 (18)0.0420 (17)0.0230 (16)0.0165 (16)
C170.0460 (14)0.0375 (13)0.0346 (12)0.0019 (11)0.0148 (11)0.0056 (10)
C180.0318 (12)0.0633 (18)0.0556 (16)0.0119 (12)0.0124 (12)0.0129 (14)
C190.0292 (14)0.107 (3)0.072 (2)0.0105 (17)0.0101 (14)0.022 (2)
C200.0361 (15)0.096 (3)0.062 (2)0.0162 (17)0.0054 (14)0.013 (2)
C210.0605 (19)0.0532 (17)0.0439 (15)0.0184 (15)0.0121 (14)0.0061 (13)
C220.091 (3)0.051 (2)0.065 (2)0.025 (2)0.021 (2)0.0005 (17)
C230.142 (4)0.0253 (14)0.067 (2)0.008 (2)0.042 (3)0.0003 (14)
C240.114 (3)0.0297 (13)0.0551 (18)0.0190 (16)0.0399 (19)0.0107 (13)
C250.158 (4)0.0422 (18)0.079 (3)0.054 (3)0.065 (3)0.0246 (18)
C260.122 (3)0.073 (2)0.084 (3)0.072 (3)0.064 (3)0.043 (2)
C270.075 (2)0.0532 (17)0.0619 (18)0.0408 (16)0.0373 (16)0.0264 (15)
C280.0692 (17)0.0265 (11)0.0365 (12)0.0092 (11)0.0236 (12)0.0078 (10)
Geometric parameters (Å, º) top
Ni1—O32.0254 (18)C10—C151.378 (4)
Ni1—O1W2.0499 (19)C10—C111.387 (3)
Ni1—N12.071 (2)C11—C121.379 (4)
Ni1—N22.096 (2)C11—H110.9300
Ni1—O12.1090 (18)C12—C131.376 (5)
Ni1—O22.1109 (18)C12—H120.9300
Ni1—C12.434 (2)C13—C141.389 (5)
O1—C11.271 (3)C13—C161.478 (4)
O2—C11.256 (3)C14—C151.388 (4)
O3—C91.262 (3)C14—H140.9300
O4—C91.244 (3)C15—H150.9300
O1W—H1W10.853 (10)C16—C16ii1.296 (7)
O1W—H1W20.844 (10)C16—H160.9300
O2W—H2W10.88 (7)C17—C211.410 (4)
O2W—H2W20.87 (5)C17—C281.427 (4)
N1—C181.326 (4)C18—C191.403 (4)
N1—C171.347 (3)C18—H180.9300
N2—C271.331 (4)C19—C201.361 (6)
N2—C281.351 (4)C19—H190.9300
C1—C21.494 (3)C20—C211.406 (6)
C2—C71.377 (3)C20—H200.9300
C2—C31.392 (3)C21—C221.413 (6)
C3—C41.377 (3)C22—C231.314 (7)
C3—H30.9300C22—H220.9300
C4—C51.388 (4)C23—C241.463 (6)
C4—H40.9300C23—H230.9300
C5—C61.387 (3)C24—C251.394 (6)
C5—C81.477 (3)C24—C281.412 (4)
C6—C71.392 (3)C25—C261.374 (6)
C6—H60.9300C25—H250.9300
C7—H70.9300C26—C271.394 (5)
C8—C8i1.331 (5)C26—H260.9300
C8—H80.9300C27—H270.9300
C9—C101.508 (3)
O3—Ni1—O1W85.52 (8)O4—C9—O3126.1 (2)
O3—Ni1—N190.86 (9)O4—C9—C10118.2 (2)
O1W—Ni1—N194.87 (8)O3—C9—C10115.7 (2)
O3—Ni1—N2169.40 (8)C15—C10—C11118.3 (2)
O1W—Ni1—N290.81 (8)C15—C10—C9120.0 (2)
N1—Ni1—N279.53 (9)C11—C10—C9121.6 (2)
O3—Ni1—O1102.00 (7)C12—C11—C10121.3 (3)
O1W—Ni1—O1101.29 (7)C12—C11—H11119.3
N1—Ni1—O1160.00 (8)C10—C11—H11119.3
N2—Ni1—O188.47 (8)C13—C12—C11120.6 (3)
O3—Ni1—O298.42 (7)C13—C12—H12119.7
O1W—Ni1—O2163.75 (7)C11—C12—H12119.7
N1—Ni1—O2100.81 (8)C12—C13—C14118.2 (3)
N2—Ni1—O287.86 (8)C12—C13—C16116.7 (3)
O1—Ni1—O262.49 (6)C14—C13—C16125.1 (3)
O3—Ni1—C1102.70 (7)C15—C14—C13121.2 (3)
O1W—Ni1—C1132.70 (7)C15—C14—H14119.4
N1—Ni1—C1130.84 (8)C13—C14—H14119.4
N2—Ni1—C187.10 (8)C10—C15—C14120.2 (3)
O1—Ni1—C131.45 (7)C10—C15—H15119.9
O2—Ni1—C131.05 (7)C14—C15—H15119.9
C1—O1—Ni188.54 (13)C16ii—C16—C13125.8 (4)
C1—O2—Ni188.84 (14)C16ii—C16—H16117.1
C9—O3—Ni1136.53 (15)C13—C16—H16117.1
Ni1—O1W—H1W1111.5 (19)N1—C17—C21122.8 (3)
Ni1—O1W—H1W2101.7 (19)N1—C17—C28117.2 (2)
H1W1—O1W—H1W2109.0 (15)C21—C17—C28120.0 (3)
H2W1—O2W—H2W2107 (6)N1—C18—C19122.7 (3)
C18—N1—C17118.6 (2)N1—C18—H18118.6
C18—N1—Ni1127.95 (19)C19—C18—H18118.6
C17—N1—Ni1113.45 (18)C20—C19—C18118.8 (4)
C27—N2—C28118.7 (3)C20—C19—H19120.6
C27—N2—Ni1128.8 (2)C18—C19—H19120.6
C28—N2—Ni1112.30 (18)C19—C20—C21120.2 (3)
O2—C1—O1120.07 (19)C19—C20—H20119.9
O2—C1—C2120.4 (2)C21—C20—H20119.9
O1—C1—C2119.5 (2)C20—C21—C17116.8 (3)
O2—C1—Ni160.11 (11)C20—C21—C22124.0 (3)
O1—C1—Ni160.01 (11)C17—C21—C22119.1 (4)
C2—C1—Ni1175.60 (16)C23—C22—C21121.6 (4)
C7—C2—C3119.3 (2)C23—C22—H22119.2
C7—C2—C1120.7 (2)C21—C22—H22119.2
C3—C2—C1120.1 (2)C22—C23—C24122.3 (3)
C4—C3—C2120.3 (2)C22—C23—H23118.9
C4—C3—H3119.9C24—C23—H23118.9
C2—C3—H3119.9C25—C24—C28116.7 (3)
C3—C4—C5120.7 (2)C25—C24—C23126.2 (3)
C3—C4—H4119.6C28—C24—C23117.1 (4)
C5—C4—H4119.6C26—C25—C24120.6 (3)
C6—C5—C4118.9 (2)C26—C25—H25119.7
C6—C5—C8119.1 (2)C24—C25—H25119.7
C4—C5—C8122.0 (2)C25—C26—C27118.7 (4)
C5—C6—C7120.2 (2)C25—C26—H26120.6
C5—C6—H6119.9C27—C26—H26120.6
C7—C6—H6119.9N2—C27—C26122.5 (4)
C2—C7—C6120.5 (2)N2—C27—H27118.7
C2—C7—H7119.8C26—C27—H27118.7
C6—C7—H7119.8N2—C28—C24122.7 (3)
C8i—C8—C5125.3 (3)N2—C28—C17117.4 (2)
C8i—C8—H8117.3C24—C28—C17119.9 (3)
C5—C8—H8117.3
O3—Ni1—O1—C194.78 (14)C4—C5—C6—C73.2 (4)
O1W—Ni1—O1—C1177.45 (13)C8—C5—C6—C7176.9 (2)
N1—Ni1—O1—C134.2 (3)C3—C2—C7—C62.2 (4)
N2—Ni1—O1—C186.94 (14)C1—C2—C7—C6177.2 (2)
O2—Ni1—O1—C11.45 (12)C5—C6—C7—C20.2 (4)
O3—Ni1—O2—C1100.66 (14)C6—C5—C8—C8i161.5 (3)
O1W—Ni1—O2—C12.4 (3)C4—C5—C8—C8i18.6 (5)
N1—Ni1—O2—C1166.83 (13)Ni1—O3—C9—O46.2 (4)
N2—Ni1—O2—C187.92 (14)Ni1—O3—C9—C10175.83 (16)
O1—Ni1—O2—C11.47 (12)O4—C9—C10—C1511.1 (4)
O1W—Ni1—O3—C9105.7 (2)O3—C9—C10—C15167.0 (2)
N1—Ni1—O3—C9159.5 (2)O4—C9—C10—C11170.6 (2)
N2—Ni1—O3—C9175.7 (4)O3—C9—C10—C1111.3 (3)
O1—Ni1—O3—C95.1 (3)C15—C10—C11—C122.8 (4)
O2—Ni1—O3—C958.4 (3)C9—C10—C11—C12175.6 (2)
C1—Ni1—O3—C927.1 (3)C10—C11—C12—C131.8 (4)
O3—Ni1—N1—C184.4 (2)C11—C12—C13—C144.5 (5)
O1W—Ni1—N1—C1890.0 (2)C11—C12—C13—C16174.4 (3)
N2—Ni1—N1—C18179.9 (2)C12—C13—C14—C152.7 (5)
O1—Ni1—N1—C18126.1 (3)C16—C13—C14—C15176.0 (3)
O2—Ni1—N1—C1894.4 (2)C11—C10—C15—C144.5 (4)
C1—Ni1—N1—C18103.3 (2)C9—C10—C15—C14173.9 (3)
O3—Ni1—N1—C17177.30 (18)C13—C14—C15—C101.9 (5)
O1W—Ni1—N1—C1791.73 (18)C12—C13—C16—C16ii168.3 (4)
N2—Ni1—N1—C171.81 (17)C14—C13—C16—C16ii10.4 (7)
O1—Ni1—N1—C1752.2 (3)C18—N1—C17—C210.1 (4)
O2—Ni1—N1—C1783.95 (18)Ni1—N1—C17—C21178.4 (2)
C1—Ni1—N1—C1775.0 (2)C18—N1—C17—C28178.8 (2)
O3—Ni1—N2—C27156.6 (4)Ni1—N1—C17—C280.3 (3)
O1W—Ni1—N2—C2787.0 (2)C17—N1—C18—C190.7 (4)
N1—Ni1—N2—C27178.2 (2)Ni1—N1—C18—C19178.9 (2)
O1—Ni1—N2—C2714.2 (2)N1—C18—C19—C200.9 (5)
O2—Ni1—N2—C2776.8 (2)C18—C19—C20—C210.3 (6)
C1—Ni1—N2—C2745.7 (2)C19—C20—C21—C170.4 (5)
O3—Ni1—N2—C2828.3 (5)C19—C20—C21—C22177.9 (4)
O1W—Ni1—N2—C2897.86 (17)N1—C17—C21—C200.7 (4)
N1—Ni1—N2—C283.06 (16)C28—C17—C21—C20179.3 (3)
O1—Ni1—N2—C28160.87 (17)N1—C17—C21—C22177.7 (3)
O2—Ni1—N2—C2898.35 (17)C28—C17—C21—C220.9 (4)
C1—Ni1—N2—C28129.42 (18)C20—C21—C22—C23178.0 (4)
Ni1—O2—C1—O12.5 (2)C17—C21—C22—C230.4 (6)
Ni1—O2—C1—C2174.94 (18)C21—C22—C23—C241.1 (6)
Ni1—O1—C1—O22.5 (2)C22—C23—C24—C25179.5 (4)
Ni1—O1—C1—C2174.96 (18)C22—C23—C24—C280.5 (5)
O3—Ni1—C1—O285.22 (14)C28—C24—C25—C261.4 (5)
O1W—Ni1—C1—O2179.10 (12)C23—C24—C25—C26179.6 (3)
N1—Ni1—C1—O217.20 (17)C24—C25—C26—C270.2 (5)
N2—Ni1—C1—O290.68 (14)C28—N2—C27—C261.0 (4)
O1—Ni1—C1—O2177.5 (2)Ni1—N2—C27—C26173.8 (2)
O3—Ni1—C1—O192.29 (14)C25—C26—C27—N21.0 (5)
O1W—Ni1—C1—O13.40 (17)C27—N2—C28—C240.2 (4)
N1—Ni1—C1—O1165.29 (13)Ni1—N2—C28—C24175.8 (2)
N2—Ni1—C1—O191.81 (14)C27—N2—C28—C17179.5 (2)
O2—Ni1—C1—O1177.5 (2)Ni1—N2—C28—C173.9 (3)
O2—C1—C2—C713.2 (3)C25—C24—C28—N21.4 (4)
O1—C1—C2—C7164.2 (2)C23—C24—C28—N2179.5 (3)
O2—C1—C2—C3167.4 (2)C25—C24—C28—C17178.3 (3)
O1—C1—C2—C315.2 (3)C23—C24—C28—C170.8 (4)
C7—C2—C3—C41.5 (4)N1—C17—C28—N22.5 (3)
C1—C2—C3—C4177.9 (2)C21—C17—C28—N2178.8 (2)
C2—C3—C4—C51.6 (4)N1—C17—C28—C24177.3 (2)
C3—C4—C5—C64.0 (4)C21—C17—C28—C241.5 (4)
C3—C4—C5—C8176.1 (3)
Symmetry codes: (i) x, y+1, z+2; (ii) x+2, y, z+1.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H1W1···O4iii0.85 (1)1.84 (1)2.650 (3)158 (2)
O1W—H1W2···O1iii0.84 (1)1.94 (2)2.706 (3)150 (2)
O2W—H2W1···O40.88 (7)2.07 (7)2.882 (5)154 (6)
Symmetry code: (iii) x+1, y+1, z+1.
 

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