Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806010415/sj2016sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806010415/sj2016Isup2.hkl |
CCDC reference: 605184
Data collection: APEX II V 1.0-22 (Bruker 2003); cell refinement: SAINT V7.12 (Bruker 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 2003); software used to prepare material for publication: SHELXTL.
C22H18N4NiO6 | F(000) = 2032 |
Mr = 493.11 | Dx = 1.607 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 2483 reflections |
a = 25.944 (9) Å | θ = 2.2–25.6° |
b = 8.450 (3) Å | µ = 1.00 mm−1 |
c = 22.105 (12) Å | T = 273 K |
β = 122.747 (3)° | Block, red |
V = 4076 (3) Å3 | 0.20 × 0.12 × 0.10 mm |
Z = 8 |
Bruker APEX II CCD area detector diffractometer | 3602 independent reflections |
Radiation source: fine-focus sealed tube | 2870 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.027 |
φ and ω scans | θmax = 25.0°, θmin = 1.9° |
Absorption correction: multi-scan SADABS (Sheldrick, 1996) | h = −30→24 |
Tmin = 0.737, Tmax = 0.905 | k = −9→10 |
10646 measured reflections | l = −25→26 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.030 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.080 | H-atom parameters constrained |
S = 1.07 | w = 1/[σ2(Fo2) + (0.0456P)2] where P = (Fo2 + 2Fc2)/3 |
3602 reflections | (Δ/σ)max < 0.001 |
300 parameters | Δρmax = 0.24 e Å−3 |
0 restraints | Δρmin = −0.25 e Å−3 |
Experimental. Spectroscopic analysis: IR (KBr, ν cm-1): 1725, 1671, 1653, 1616, 1592, 1441, 1347, 1210. (IR spectra were recorded on a BIO-RAD FTS 3000 infrared spectrophotometer). Analysis, required for NiC22H18N4O6: C 53.59, H 3.68, N 11.36%; found: C 53.39, H 3.72, N 11.51%. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Ni1 | 0.082205 (11) | 0.72661 (3) | 0.998512 (14) | 0.02824 (11) | |
O1 | 0.17371 (7) | 0.6609 (3) | 1.20184 (8) | 0.0586 (5) | |
O2 | 0.24595 (7) | 0.5924 (2) | 1.14929 (8) | 0.0511 (5) | |
O3 | 0.12962 (8) | 1.0364 (2) | 0.85400 (8) | 0.0480 (5) | |
O4 | 0.07721 (9) | 0.8438 (3) | 0.77439 (9) | 0.0637 (6) | |
O5 | −0.13223 (7) | 0.7146 (2) | 0.87449 (8) | 0.0439 (4) | |
O6 | −0.12191 (8) | 0.9249 (2) | 0.94179 (10) | 0.0582 (5) | |
N1 | 0.09042 (8) | 0.6589 (2) | 1.08311 (9) | 0.0310 (4) | |
N2 | 0.16055 (7) | 0.6480 (2) | 1.03562 (9) | 0.0310 (4) | |
N3 | 0.07901 (8) | 0.8198 (2) | 0.92026 (9) | 0.0299 (4) | |
N4 | 0.00122 (8) | 0.7907 (2) | 0.95679 (9) | 0.0314 (4) | |
C1 | 0.15112 (10) | 0.6527 (3) | 1.13755 (12) | 0.0374 (6) | |
C2 | 0.19230 (10) | 0.6276 (3) | 1.10799 (12) | 0.0359 (6) | |
C3 | 0.18582 (10) | 0.6094 (3) | 0.99530 (12) | 0.0325 (5) | |
C4 | 0.23100 (10) | 0.4931 (3) | 1.01787 (13) | 0.0413 (6) | |
H4 | 0.2450 | 0.4404 | 1.0610 | 0.050* | |
C5 | 0.25508 (12) | 0.4554 (3) | 0.97758 (15) | 0.0506 (7) | |
H5 | 0.2849 | 0.3770 | 0.9937 | 0.061* | |
C6 | 0.23575 (12) | 0.5318 (3) | 0.91358 (15) | 0.0519 (7) | |
H6 | 0.2530 | 0.5074 | 0.8872 | 0.062* | |
C7 | 0.19110 (11) | 0.6435 (3) | 0.88963 (13) | 0.0428 (6) | |
H7 | 0.1777 | 0.6945 | 0.8463 | 0.051* | |
C8 | 0.16463 (10) | 0.6837 (3) | 0.92862 (12) | 0.0320 (5) | |
C9 | 0.11574 (10) | 0.7996 (3) | 0.89838 (11) | 0.0313 (5) | |
C10 | 0.10501 (11) | 0.8947 (3) | 0.83467 (13) | 0.0409 (6) | |
C11 | 0.12694 (15) | 1.1353 (4) | 0.79849 (16) | 0.0749 (10) | |
H11A | 0.1485 | 1.0844 | 0.7797 | 0.112* | |
H11B | 0.1456 | 1.2358 | 0.8187 | 0.112* | |
H11C | 0.0849 | 1.1511 | 0.7604 | 0.112* | |
C12 | 0.03025 (10) | 0.9395 (3) | 0.88709 (12) | 0.0360 (6) | |
H12A | 0.0187 | 0.9609 | 0.8382 | 0.043* | |
H12B | 0.0441 | 1.0374 | 0.9142 | 0.043* | |
C13 | −0.02358 (10) | 0.8734 (3) | 0.88745 (12) | 0.0390 (6) | |
H13A | −0.0508 | 0.9582 | 0.8826 | 0.047* | |
H13B | −0.0465 | 0.8002 | 0.8478 | 0.047* | |
C14 | −0.03523 (10) | 0.7577 (3) | 0.97815 (12) | 0.0313 (5) | |
C15 | −0.10164 (10) | 0.8103 (3) | 0.93009 (12) | 0.0372 (6) | |
C16 | −0.19546 (11) | 0.7589 (4) | 0.81912 (14) | 0.0594 (8) | |
H16A | −0.2198 | 0.7608 | 0.8398 | 0.089* | |
H16B | −0.2122 | 0.6830 | 0.7807 | 0.089* | |
H16C | −0.1957 | 0.8619 | 0.8006 | 0.089* | |
C17 | −0.01689 (10) | 0.6803 (3) | 1.04514 (11) | 0.0308 (5) | |
C18 | −0.06217 (11) | 0.6509 (3) | 1.06063 (13) | 0.0392 (6) | |
H18 | −0.1025 | 0.6792 | 1.0268 | 0.047* | |
C19 | −0.04887 (12) | 0.5824 (3) | 1.12344 (13) | 0.0452 (6) | |
H19 | −0.0794 | 0.5670 | 1.1329 | 0.054* | |
C20 | 0.01115 (12) | 0.5363 (3) | 1.17303 (13) | 0.0458 (6) | |
H20 | 0.0206 | 0.4870 | 1.2155 | 0.055* | |
C21 | 0.05670 (11) | 0.5624 (3) | 1.16020 (12) | 0.0413 (6) | |
H21 | 0.0965 | 0.5298 | 1.1940 | 0.050* | |
C22 | 0.04439 (10) | 0.6378 (3) | 1.09684 (11) | 0.0307 (5) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Ni1 | 0.02410 (16) | 0.03571 (19) | 0.02549 (16) | 0.00069 (12) | 0.01380 (13) | 0.00005 (12) |
O1 | 0.0364 (10) | 0.1034 (16) | 0.0270 (9) | −0.0081 (10) | 0.0113 (8) | −0.0069 (10) |
O2 | 0.0254 (9) | 0.0813 (14) | 0.0382 (9) | 0.0051 (9) | 0.0117 (7) | 0.0115 (9) |
O3 | 0.0484 (10) | 0.0496 (12) | 0.0427 (10) | −0.0035 (9) | 0.0224 (8) | 0.0126 (9) |
O4 | 0.0713 (14) | 0.0844 (15) | 0.0304 (10) | −0.0074 (11) | 0.0242 (9) | −0.0029 (10) |
O5 | 0.0277 (9) | 0.0527 (11) | 0.0368 (9) | 0.0042 (8) | 0.0080 (7) | −0.0059 (8) |
O6 | 0.0401 (10) | 0.0629 (13) | 0.0637 (12) | 0.0122 (9) | 0.0230 (9) | −0.0142 (10) |
N1 | 0.0281 (10) | 0.0393 (11) | 0.0269 (9) | −0.0006 (8) | 0.0158 (8) | −0.0001 (8) |
N2 | 0.0234 (9) | 0.0400 (12) | 0.0293 (10) | 0.0021 (8) | 0.0141 (8) | 0.0028 (8) |
N3 | 0.0280 (10) | 0.0322 (11) | 0.0268 (9) | −0.0009 (8) | 0.0132 (8) | −0.0013 (8) |
N4 | 0.0295 (10) | 0.0386 (11) | 0.0250 (9) | 0.0015 (8) | 0.0140 (8) | −0.0018 (8) |
C1 | 0.0304 (13) | 0.0487 (16) | 0.0290 (13) | −0.0020 (11) | 0.0134 (11) | 0.0005 (11) |
C2 | 0.0277 (12) | 0.0433 (15) | 0.0320 (13) | −0.0033 (10) | 0.0132 (10) | 0.0022 (11) |
C3 | 0.0263 (11) | 0.0342 (13) | 0.0378 (13) | −0.0036 (10) | 0.0178 (10) | −0.0022 (10) |
C4 | 0.0358 (13) | 0.0428 (15) | 0.0468 (14) | 0.0035 (11) | 0.0233 (12) | 0.0023 (12) |
C5 | 0.0446 (15) | 0.0444 (16) | 0.0695 (19) | 0.0063 (12) | 0.0353 (14) | −0.0038 (14) |
C6 | 0.0503 (16) | 0.0561 (18) | 0.0684 (19) | −0.0009 (14) | 0.0445 (15) | −0.0103 (15) |
C7 | 0.0444 (15) | 0.0480 (16) | 0.0469 (15) | −0.0043 (12) | 0.0318 (12) | −0.0045 (12) |
C8 | 0.0294 (12) | 0.0339 (13) | 0.0363 (12) | −0.0053 (10) | 0.0200 (10) | −0.0041 (10) |
C9 | 0.0312 (12) | 0.0363 (14) | 0.0292 (11) | −0.0078 (10) | 0.0183 (10) | −0.0062 (10) |
C10 | 0.0336 (13) | 0.0566 (18) | 0.0354 (14) | 0.0045 (12) | 0.0204 (11) | 0.0048 (12) |
C11 | 0.080 (2) | 0.075 (2) | 0.074 (2) | 0.0031 (18) | 0.0447 (18) | 0.0373 (18) |
C12 | 0.0388 (13) | 0.0362 (14) | 0.0334 (12) | 0.0056 (10) | 0.0198 (11) | 0.0037 (10) |
C13 | 0.0327 (13) | 0.0521 (16) | 0.0323 (12) | 0.0090 (11) | 0.0176 (10) | 0.0063 (11) |
C14 | 0.0283 (12) | 0.0325 (13) | 0.0328 (12) | −0.0037 (9) | 0.0163 (10) | −0.0099 (10) |
C15 | 0.0310 (13) | 0.0466 (16) | 0.0373 (13) | 0.0007 (11) | 0.0206 (11) | −0.0020 (12) |
C16 | 0.0316 (14) | 0.078 (2) | 0.0463 (16) | 0.0073 (13) | 0.0067 (12) | 0.0020 (14) |
C17 | 0.0303 (12) | 0.0333 (13) | 0.0325 (12) | −0.0062 (10) | 0.0195 (10) | −0.0096 (10) |
C18 | 0.0322 (13) | 0.0421 (15) | 0.0469 (14) | −0.0072 (11) | 0.0238 (11) | −0.0100 (12) |
C19 | 0.0501 (16) | 0.0524 (17) | 0.0513 (16) | −0.0142 (13) | 0.0393 (14) | −0.0111 (13) |
C20 | 0.0539 (17) | 0.0563 (17) | 0.0375 (14) | −0.0092 (13) | 0.0316 (13) | −0.0035 (12) |
C21 | 0.0419 (14) | 0.0517 (16) | 0.0325 (13) | −0.0020 (12) | 0.0216 (11) | 0.0000 (11) |
C22 | 0.0317 (12) | 0.0345 (14) | 0.0296 (12) | −0.0067 (10) | 0.0189 (10) | −0.0095 (10) |
Ni1—N1 | 1.8544 (19) | C6—H6 | 0.9300 |
Ni1—N2 | 1.8553 (18) | C7—C8 | 1.404 (3) |
Ni1—N4 | 1.8605 (19) | C7—H7 | 0.9300 |
Ni1—N3 | 1.861 (2) | C8—C9 | 1.448 (3) |
O1—C1 | 1.211 (3) | C9—C10 | 1.511 (3) |
O2—C2 | 1.218 (3) | C11—H11A | 0.9600 |
O3—C10 | 1.315 (3) | C11—H11B | 0.9600 |
O3—C11 | 1.455 (3) | C11—H11C | 0.9600 |
O4—C10 | 1.200 (3) | C12—C13 | 1.508 (3) |
O5—C15 | 1.319 (3) | C12—H12A | 0.9700 |
O5—C16 | 1.469 (3) | C12—H12B | 0.9700 |
O6—C15 | 1.195 (3) | C13—H13A | 0.9700 |
N1—C1 | 1.371 (3) | C13—H13B | 0.9700 |
N1—C22 | 1.394 (3) | C14—C17 | 1.444 (3) |
N2—C2 | 1.357 (3) | C14—C15 | 1.521 (3) |
N2—C3 | 1.401 (3) | C16—H16A | 0.9600 |
N3—C9 | 1.292 (3) | C16—H16B | 0.9600 |
N3—C12 | 1.469 (3) | C16—H16C | 0.9600 |
N4—C14 | 1.295 (3) | C17—C18 | 1.412 (3) |
N4—C13 | 1.478 (3) | C17—C22 | 1.413 (3) |
C1—C2 | 1.539 (3) | C18—C19 | 1.365 (3) |
C3—C4 | 1.398 (3) | C18—H18 | 0.9300 |
C3—C8 | 1.412 (3) | C19—C20 | 1.390 (3) |
C4—C5 | 1.374 (3) | C19—H19 | 0.9300 |
C4—H4 | 0.9300 | C20—C21 | 1.374 (3) |
C5—C6 | 1.379 (4) | C20—H20 | 0.9300 |
C5—H5 | 0.9300 | C21—C22 | 1.409 (3) |
C6—C7 | 1.360 (4) | C21—H21 | 0.9300 |
N1—Ni1—N2 | 86.72 (8) | O3—C10—C9 | 111.7 (2) |
N1—Ni1—N4 | 94.17 (8) | O3—C11—H11A | 109.5 |
N2—Ni1—N4 | 175.35 (8) | O3—C11—H11B | 109.5 |
N1—Ni1—N3 | 172.24 (8) | H11A—C11—H11B | 109.5 |
N2—Ni1—N3 | 92.86 (8) | O3—C11—H11C | 109.5 |
N4—Ni1—N3 | 86.88 (8) | H11A—C11—H11C | 109.5 |
C10—O3—C11 | 117.1 (2) | H11B—C11—H11C | 109.5 |
C15—O5—C16 | 117.25 (19) | N3—C12—C13 | 107.01 (19) |
C1—N1—C22 | 121.10 (18) | N3—C12—H12A | 110.3 |
C1—N1—Ni1 | 110.35 (15) | C13—C12—H12A | 110.3 |
C22—N1—Ni1 | 127.92 (14) | N3—C12—H12B | 110.3 |
C2—N2—C3 | 121.74 (18) | C13—C12—H12B | 110.3 |
C2—N2—Ni1 | 112.81 (14) | H12A—C12—H12B | 108.6 |
C3—N2—Ni1 | 125.44 (14) | N4—C13—C12 | 107.21 (17) |
C9—N3—C12 | 121.00 (19) | N4—C13—H13A | 110.3 |
C9—N3—Ni1 | 128.35 (16) | C12—C13—H13A | 110.3 |
C12—N3—Ni1 | 110.40 (14) | N4—C13—H13B | 110.3 |
C14—N4—C13 | 119.04 (19) | C12—C13—H13B | 110.3 |
C14—N4—Ni1 | 127.46 (16) | H13A—C13—H13B | 108.5 |
C13—N4—Ni1 | 113.14 (14) | N4—C14—C17 | 124.8 (2) |
O1—C1—N1 | 128.7 (2) | N4—C14—C15 | 117.2 (2) |
O1—C1—C2 | 120.0 (2) | C17—C14—C15 | 117.96 (19) |
N1—C1—C2 | 111.35 (19) | O6—C15—O5 | 125.8 (2) |
O2—C2—N2 | 129.3 (2) | O6—C15—C14 | 123.4 (2) |
O2—C2—C1 | 119.3 (2) | O5—C15—C14 | 110.78 (19) |
N2—C2—C1 | 111.41 (18) | O5—C16—H16A | 109.5 |
C4—C3—N2 | 121.8 (2) | O5—C16—H16B | 109.5 |
C4—C3—C8 | 117.6 (2) | H16A—C16—H16B | 109.5 |
N2—C3—C8 | 120.6 (2) | O5—C16—H16C | 109.5 |
C5—C4—C3 | 121.3 (2) | H16A—C16—H16C | 109.5 |
C5—C4—H4 | 119.4 | H16B—C16—H16C | 109.5 |
C3—C4—H4 | 119.4 | C18—C17—C22 | 118.6 (2) |
C4—C5—C6 | 121.0 (2) | C18—C17—C14 | 118.2 (2) |
C4—C5—H5 | 119.5 | C22—C17—C14 | 123.2 (2) |
C6—C5—H5 | 119.5 | C19—C18—C17 | 122.4 (2) |
C7—C6—C5 | 119.0 (2) | C19—C18—H18 | 118.8 |
C7—C6—H6 | 120.5 | C17—C18—H18 | 118.8 |
C5—C6—H6 | 120.5 | C18—C19—C20 | 118.7 (2) |
C6—C7—C8 | 121.7 (2) | C18—C19—H19 | 120.7 |
C6—C7—H7 | 119.1 | C20—C19—H19 | 120.7 |
C8—C7—H7 | 119.1 | C21—C20—C19 | 120.9 (2) |
C7—C8—C3 | 119.3 (2) | C21—C20—H20 | 119.5 |
C7—C8—C9 | 118.5 (2) | C19—C20—H20 | 119.5 |
C3—C8—C9 | 122.12 (19) | C20—C21—C22 | 121.3 (2) |
N3—C9—C8 | 123.8 (2) | C20—C21—H21 | 119.3 |
N3—C9—C10 | 118.5 (2) | C22—C21—H21 | 119.3 |
C8—C9—C10 | 117.61 (19) | N1—C22—C21 | 120.9 (2) |
O4—C10—O3 | 125.5 (2) | N1—C22—C17 | 120.9 (2) |
O4—C10—C9 | 122.8 (3) | C21—C22—C17 | 118.0 (2) |
N2—Ni1—N1—C1 | 25.48 (17) | N2—C3—C8—C9 | −1.2 (3) |
N4—Ni1—N1—C1 | −159.10 (16) | C12—N3—C9—C8 | −179.9 (2) |
N3—Ni1—N1—C1 | −61.6 (6) | Ni1—N3—C9—C8 | 6.4 (3) |
N2—Ni1—N1—C22 | −163.7 (2) | C12—N3—C9—C10 | −3.8 (3) |
N4—Ni1—N1—C22 | 11.7 (2) | Ni1—N3—C9—C10 | −177.48 (16) |
N3—Ni1—N1—C22 | 109.2 (5) | C7—C8—C9—N3 | 163.7 (2) |
N1—Ni1—N2—C2 | −18.82 (17) | C3—C8—C9—N3 | −15.5 (3) |
N4—Ni1—N2—C2 | −119.9 (9) | C7—C8—C9—C10 | −12.4 (3) |
N3—Ni1—N2—C2 | 153.43 (16) | C3—C8—C9—C10 | 168.3 (2) |
N1—Ni1—N2—C3 | 160.10 (19) | C11—O3—C10—O4 | −5.0 (4) |
N4—Ni1—N2—C3 | 59.0 (10) | C11—O3—C10—C9 | 175.1 (2) |
N3—Ni1—N2—C3 | −27.65 (19) | N3—C9—C10—O4 | −96.4 (3) |
N1—Ni1—N3—C9 | 98.6 (6) | C8—C9—C10—O4 | 79.9 (3) |
N2—Ni1—N3—C9 | 11.9 (2) | N3—C9—C10—O3 | 83.5 (3) |
N4—Ni1—N3—C9 | −163.4 (2) | C8—C9—C10—O3 | −100.1 (2) |
N1—Ni1—N3—C12 | −75.7 (6) | C9—N3—C12—C13 | 145.4 (2) |
N2—Ni1—N3—C12 | −162.31 (15) | Ni1—N3—C12—C13 | −39.9 (2) |
N4—Ni1—N3—C12 | 22.34 (15) | C14—N4—C13—C12 | 163.0 (2) |
N1—Ni1—N4—C14 | −13.5 (2) | Ni1—N4—C13—C12 | −23.3 (2) |
N2—Ni1—N4—C14 | 87.3 (10) | N3—C12—C13—N4 | 39.6 (2) |
N3—Ni1—N4—C14 | 174.20 (19) | C13—N4—C14—C17 | −178.8 (2) |
N1—Ni1—N4—C13 | 173.48 (16) | Ni1—N4—C14—C17 | 8.6 (3) |
N2—Ni1—N4—C13 | −85.7 (10) | C13—N4—C14—C15 | −1.1 (3) |
N3—Ni1—N4—C13 | 1.18 (16) | Ni1—N4—C14—C15 | −173.76 (15) |
C22—N1—C1—O1 | −15.9 (4) | C16—O5—C15—O6 | 4.9 (4) |
Ni1—N1—C1—O1 | 155.7 (2) | C16—O5—C15—C14 | −173.9 (2) |
C22—N1—C1—C2 | 162.4 (2) | N4—C14—C15—O6 | −101.4 (3) |
Ni1—N1—C1—C2 | −26.0 (2) | C17—C14—C15—O6 | 76.4 (3) |
C3—N2—C2—O2 | 8.5 (4) | N4—C14—C15—O5 | 77.5 (3) |
Ni1—N2—C2—O2 | −172.6 (2) | C17—C14—C15—O5 | −104.7 (2) |
C3—N2—C2—C1 | −170.7 (2) | N4—C14—C17—C18 | −179.4 (2) |
Ni1—N2—C2—C1 | 8.3 (2) | C15—C14—C17—C18 | 3.0 (3) |
O1—C1—C2—O2 | 11.0 (4) | N4—C14—C17—C22 | 2.9 (3) |
N1—C1—C2—O2 | −167.4 (2) | C15—C14—C17—C22 | −174.7 (2) |
O1—C1—C2—N2 | −169.7 (2) | C22—C17—C18—C19 | −0.3 (4) |
N1—C1—C2—N2 | 11.8 (3) | C14—C17—C18—C19 | −178.1 (2) |
C2—N2—C3—C4 | 27.0 (3) | C17—C18—C19—C20 | −1.8 (4) |
Ni1—N2—C3—C4 | −151.82 (18) | C18—C19—C20—C21 | 1.7 (4) |
C2—N2—C3—C8 | −155.2 (2) | C19—C20—C21—C22 | 0.5 (4) |
Ni1—N2—C3—C8 | 25.9 (3) | C1—N1—C22—C21 | −20.0 (3) |
N2—C3—C4—C5 | 179.4 (2) | Ni1—N1—C22—C21 | 170.11 (17) |
C8—C3—C4—C5 | 1.6 (3) | C1—N1—C22—C17 | 165.0 (2) |
C3—C4—C5—C6 | 0.5 (4) | Ni1—N1—C22—C17 | −5.0 (3) |
C4—C5—C6—C7 | −1.6 (4) | C20—C21—C22—N1 | −177.7 (2) |
C5—C6—C7—C8 | 0.6 (4) | C20—C21—C22—C17 | −2.5 (3) |
C6—C7—C8—C3 | 1.5 (4) | C18—C17—C22—N1 | 177.6 (2) |
C6—C7—C8—C9 | −177.8 (2) | C14—C17—C22—N1 | −4.7 (3) |
C4—C3—C8—C7 | −2.6 (3) | C18—C17—C22—C21 | 2.4 (3) |
N2—C3—C8—C7 | 179.6 (2) | C14—C17—C22—C21 | −179.9 (2) |
C4—C3—C8—C9 | 176.7 (2) |
D—H···A | D—H | H···A | D···A | D—H···A |
C12—H12B···O6i | 0.97 | 2.71 | 3.398 (9) | 128 |
C12—H12A···O4ii | 0.97 | 2.58 | 3.225 (9) | 124 |
C13—H13B···O4ii | 0.97 | 2.39 | 3.068 (9) | 126 |
C11—H11A···O2iii | 0.96 | 2.75 | 3.434 (9) | 129 |
C7—H7···O2iii | 0.93 | 2.64 | 3.148 (4) | 115 |
Symmetry codes: (i) −x, −y+2, −z+2; (ii) −x, y, −z+3/2; (iii) −x+1/2, −y+3/2, −z+2. |