Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806042310/sg2072sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806042310/sg2072Isup2.hkl |
CCDC reference: 628392
Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: DIRDIF96 (Beurskens et al., 1996); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997) and POV-RAY for Windows (The POV-RAY Team, 2002); software used to prepare material for publication: SHELXTL (Bruker, 2003).
[Cu(C26H24N6)2](PF6)2 | F(000) = 2560 |
Mr = 1258.04 | Dx = 1.565 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 7632 reflections |
a = 13.6235 (7) Å | θ = 3.0–26.4° |
b = 16.6329 (9) Å | µ = 0.95 mm−1 |
c = 23.8071 (12) Å | T = 193 K |
β = 98.3298 (10)° | Prism, dark green |
V = 5337.7 (5) Å3 | 0.48 × 0.29 × 0.15 mm |
Z = 4 |
Bruker SMART 1000 CCD area-detector/PLATFORM diffractometer | 5470 independent reflections |
Radiation source: fine-focus sealed tube | 4525 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.032 |
Detector resolution: 8.192 pixels mm-1 | θmax = 26.4°, θmin = 3.0° |
ω scans | h = −17→17 |
Absorption correction: multi-scan (SADABS; Bruker, 2003) | k = −20→19 |
Tmin = 0.659, Tmax = 0.871 | l = −29→29 |
16047 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.045 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.130 | H-atom parameters constrained |
S = 1.03 | w = 1/[σ2(Fo2) + (0.0733P)2 + 9.7413P] where P = (Fo2 + 2Fc2)/3 |
5470 reflections | (Δ/σ)max = 0.001 |
362 parameters | Δρmax = 1.13 e Å−3 |
0 restraints | Δρmin = −0.47 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Cu1 | 0.0000 | 0.74609 (3) | 0.2500 | 0.02701 (14) | |
Cu2 | 0.0000 | 0.52185 (3) | 0.2500 | 0.02982 (14) | |
N1 | 0.02959 (16) | 0.68855 (13) | 0.17702 (9) | 0.0254 (4) | |
N2 | 0.13590 (16) | 0.57968 (13) | 0.25802 (9) | 0.0268 (5) | |
N11 | −0.11800 (17) | 0.78589 (14) | 0.19463 (10) | 0.0306 (5) | |
N12 | −0.2251 (2) | 0.83997 (18) | 0.32364 (13) | 0.0476 (7) | |
N21 | 0.05936 (19) | 0.47870 (14) | 0.32624 (10) | 0.0335 (5) | |
N22 | 0.05996 (19) | 0.20530 (16) | 0.36129 (12) | 0.0421 (6) | |
C1 | −0.0388 (2) | 0.70632 (16) | 0.13211 (11) | 0.0302 (6) | |
C2 | −0.0326 (3) | 0.67862 (19) | 0.07759 (12) | 0.0409 (7) | |
H2 | −0.0836 | 0.6900 | 0.0470 | 0.049* | |
C3 | 0.0495 (3) | 0.6342 (2) | 0.06904 (14) | 0.0482 (8) | |
H3 | 0.0563 | 0.6152 | 0.0322 | 0.058* | |
C4 | 0.1217 (3) | 0.61768 (19) | 0.11426 (13) | 0.0413 (7) | |
H4 | 0.1795 | 0.5884 | 0.1089 | 0.050* | |
C5 | 0.1081 (2) | 0.64470 (15) | 0.16802 (12) | 0.0291 (6) | |
C6 | 0.1770 (2) | 0.62250 (15) | 0.21993 (12) | 0.0291 (6) | |
C7 | 0.2763 (2) | 0.64592 (17) | 0.22913 (15) | 0.0386 (7) | |
H7 | 0.3049 | 0.6738 | 0.2006 | 0.046* | |
C8 | 0.3323 (2) | 0.62758 (18) | 0.28087 (17) | 0.0458 (8) | |
H8 | 0.3998 | 0.6439 | 0.2886 | 0.055* | |
C9 | 0.2903 (2) | 0.58598 (18) | 0.32087 (15) | 0.0418 (7) | |
H9 | 0.3272 | 0.5745 | 0.3570 | 0.050* | |
C10 | 0.1922 (2) | 0.56077 (16) | 0.30759 (12) | 0.0324 (6) | |
C11 | −0.1199 (2) | 0.75750 (17) | 0.14488 (12) | 0.0335 (6) | |
H11 | −0.1739 | 0.7695 | 0.1161 | 0.040* | |
C12 | −0.2034 (2) | 0.8359 (2) | 0.20389 (14) | 0.0426 (7) | |
H12A | −0.2519 | 0.8023 | 0.2205 | 0.051* | |
H12B | −0.2364 | 0.8564 | 0.1669 | 0.051* | |
C13 | −0.1738 (3) | 0.9060 (2) | 0.24273 (16) | 0.0512 (9) | |
H13A | −0.2267 | 0.9472 | 0.2367 | 0.061* | |
H13B | −0.1126 | 0.9302 | 0.2322 | 0.061* | |
C14 | −0.1556 (2) | 0.88405 (19) | 0.30508 (15) | 0.0429 (7) | |
C15 | −0.0744 (3) | 0.9121 (2) | 0.3414 (2) | 0.0612 (11) | |
H15 | −0.0247 | 0.9432 | 0.3274 | 0.073* | |
C16 | −0.0669 (3) | 0.8937 (3) | 0.3998 (2) | 0.0692 (12) | |
H16 | −0.0125 | 0.9127 | 0.4259 | 0.083* | |
C17 | −0.1395 (3) | 0.8479 (3) | 0.41781 (19) | 0.0638 (11) | |
H17 | −0.1369 | 0.8344 | 0.4568 | 0.077* | |
C18 | −0.2155 (3) | 0.8221 (2) | 0.37858 (16) | 0.0565 (9) | |
H18 | −0.2650 | 0.7892 | 0.3912 | 0.068* | |
C21 | 0.1453 (2) | 0.50682 (17) | 0.34426 (12) | 0.0361 (6) | |
H21 | 0.1782 | 0.4929 | 0.3809 | 0.043* | |
C22 | 0.0194 (3) | 0.41871 (18) | 0.36212 (13) | 0.0423 (7) | |
H22A | −0.0462 | 0.4363 | 0.3707 | 0.051* | |
H22B | 0.0645 | 0.4126 | 0.3984 | 0.051* | |
C23 | 0.0095 (2) | 0.33919 (18) | 0.33066 (12) | 0.0349 (6) | |
H23A | −0.0498 | 0.3414 | 0.3013 | 0.042* | |
H23B | 0.0682 | 0.3318 | 0.3111 | 0.042* | |
C24 | 0.0005 (2) | 0.26718 (17) | 0.36830 (12) | 0.0315 (6) | |
C25 | −0.0646 (2) | 0.26591 (19) | 0.40762 (13) | 0.0401 (7) | |
H25 | −0.1055 | 0.3111 | 0.4120 | 0.048* | |
C26 | −0.0696 (3) | 0.1975 (2) | 0.44071 (14) | 0.0490 (8) | |
H26 | −0.1146 | 0.1948 | 0.4676 | 0.059* | |
C27 | −0.0082 (3) | 0.1340 (2) | 0.43374 (15) | 0.0504 (9) | |
H27 | −0.0092 | 0.0867 | 0.4560 | 0.060* | |
C28 | 0.0547 (3) | 0.1405 (2) | 0.39381 (16) | 0.0486 (8) | |
H28 | 0.0969 | 0.0964 | 0.3891 | 0.058* | |
P | 0.25333 (6) | 0.54905 (5) | 0.52515 (3) | 0.03605 (19) | |
F1 | 0.2754 (3) | 0.52976 (18) | 0.59089 (11) | 0.1014 (11) | |
F2 | 0.2349 (2) | 0.57017 (18) | 0.46013 (9) | 0.0839 (8) | |
F3 | 0.2346 (2) | 0.45664 (14) | 0.51445 (12) | 0.0791 (8) | |
F4 | 0.2715 (3) | 0.64234 (14) | 0.53689 (11) | 0.0917 (10) | |
F5 | 0.36595 (19) | 0.5362 (2) | 0.51895 (16) | 0.1044 (11) | |
F6 | 0.1414 (2) | 0.5619 (2) | 0.53143 (16) | 0.1025 (11) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Cu1 | 0.0281 (2) | 0.0275 (2) | 0.0252 (2) | 0.000 | 0.00288 (17) | 0.000 |
Cu2 | 0.0287 (3) | 0.0289 (3) | 0.0322 (3) | 0.000 | 0.00544 (18) | 0.000 |
N1 | 0.0294 (11) | 0.0206 (10) | 0.0270 (10) | −0.0039 (9) | 0.0068 (8) | −0.0001 (8) |
N2 | 0.0279 (11) | 0.0211 (10) | 0.0318 (11) | 0.0029 (9) | 0.0056 (9) | −0.0042 (9) |
N11 | 0.0295 (12) | 0.0260 (12) | 0.0361 (12) | 0.0023 (9) | 0.0040 (9) | 0.0045 (9) |
N12 | 0.0427 (15) | 0.0464 (16) | 0.0539 (17) | 0.0052 (13) | 0.0077 (12) | −0.0044 (13) |
N21 | 0.0469 (14) | 0.0250 (12) | 0.0302 (12) | 0.0064 (10) | 0.0109 (10) | 0.0019 (9) |
N22 | 0.0352 (13) | 0.0393 (14) | 0.0528 (16) | 0.0037 (11) | 0.0102 (11) | 0.0057 (12) |
C1 | 0.0361 (14) | 0.0257 (13) | 0.0286 (13) | −0.0055 (11) | 0.0041 (11) | 0.0028 (10) |
C2 | 0.0541 (19) | 0.0387 (17) | 0.0290 (14) | −0.0061 (14) | 0.0029 (13) | −0.0017 (12) |
C3 | 0.068 (2) | 0.0463 (19) | 0.0325 (16) | −0.0012 (17) | 0.0136 (15) | −0.0087 (14) |
C4 | 0.0505 (18) | 0.0366 (16) | 0.0404 (16) | 0.0007 (14) | 0.0185 (14) | −0.0075 (13) |
C5 | 0.0326 (14) | 0.0217 (12) | 0.0348 (14) | −0.0046 (10) | 0.0110 (11) | −0.0017 (10) |
C6 | 0.0300 (13) | 0.0201 (12) | 0.0383 (14) | 0.0020 (10) | 0.0089 (11) | −0.0063 (10) |
C7 | 0.0300 (15) | 0.0283 (15) | 0.0590 (19) | −0.0018 (11) | 0.0119 (13) | −0.0026 (13) |
C8 | 0.0285 (15) | 0.0321 (16) | 0.073 (2) | −0.0003 (12) | −0.0035 (15) | −0.0102 (15) |
C9 | 0.0384 (16) | 0.0287 (15) | 0.0537 (18) | 0.0055 (12) | −0.0091 (14) | −0.0090 (13) |
C10 | 0.0344 (14) | 0.0236 (13) | 0.0375 (14) | 0.0070 (11) | −0.0006 (11) | −0.0079 (11) |
C11 | 0.0329 (15) | 0.0325 (15) | 0.0331 (14) | −0.0014 (12) | −0.0018 (11) | 0.0059 (11) |
C12 | 0.0371 (16) | 0.0440 (18) | 0.0463 (17) | 0.0139 (14) | 0.0047 (13) | 0.0036 (14) |
C13 | 0.058 (2) | 0.0289 (16) | 0.071 (2) | 0.0110 (15) | 0.0222 (18) | 0.0031 (15) |
C14 | 0.0399 (17) | 0.0306 (15) | 0.0581 (19) | 0.0127 (13) | 0.0069 (14) | −0.0107 (14) |
C15 | 0.0395 (19) | 0.0388 (19) | 0.106 (3) | 0.0055 (15) | 0.013 (2) | −0.011 (2) |
C16 | 0.057 (2) | 0.067 (3) | 0.075 (3) | 0.015 (2) | −0.020 (2) | −0.025 (2) |
C17 | 0.065 (3) | 0.066 (3) | 0.058 (2) | 0.015 (2) | 0.0003 (19) | −0.0081 (19) |
C18 | 0.055 (2) | 0.058 (2) | 0.057 (2) | 0.0108 (18) | 0.0088 (17) | −0.0038 (18) |
C21 | 0.0500 (18) | 0.0270 (14) | 0.0297 (14) | 0.0098 (13) | 0.0006 (12) | −0.0025 (11) |
C22 | 0.063 (2) | 0.0307 (15) | 0.0363 (15) | 0.0049 (14) | 0.0182 (14) | 0.0059 (12) |
C23 | 0.0424 (16) | 0.0329 (15) | 0.0303 (14) | 0.0001 (13) | 0.0082 (12) | 0.0049 (12) |
C24 | 0.0319 (14) | 0.0310 (14) | 0.0314 (13) | −0.0036 (11) | 0.0041 (11) | 0.0014 (11) |
C25 | 0.0465 (18) | 0.0369 (16) | 0.0393 (16) | −0.0045 (14) | 0.0143 (13) | −0.0030 (13) |
C26 | 0.066 (2) | 0.0461 (19) | 0.0386 (16) | −0.0167 (17) | 0.0187 (15) | −0.0025 (14) |
C27 | 0.065 (2) | 0.0400 (18) | 0.0435 (18) | −0.0132 (16) | −0.0002 (16) | 0.0118 (14) |
C28 | 0.0447 (18) | 0.0375 (17) | 0.062 (2) | 0.0050 (14) | 0.0019 (16) | 0.0107 (15) |
P | 0.0420 (4) | 0.0345 (4) | 0.0326 (4) | −0.0043 (3) | 0.0084 (3) | −0.0022 (3) |
F1 | 0.170 (3) | 0.087 (2) | 0.0441 (13) | −0.031 (2) | 0.0057 (16) | 0.0151 (13) |
F2 | 0.123 (2) | 0.0898 (19) | 0.0369 (11) | −0.0166 (17) | 0.0057 (13) | −0.0044 (12) |
F3 | 0.105 (2) | 0.0421 (12) | 0.102 (2) | −0.0194 (13) | 0.0576 (16) | −0.0194 (12) |
F4 | 0.171 (3) | 0.0449 (13) | 0.0694 (16) | −0.0367 (16) | 0.0536 (18) | −0.0140 (11) |
F5 | 0.0464 (14) | 0.116 (3) | 0.151 (3) | −0.0049 (15) | 0.0180 (16) | 0.034 (2) |
F6 | 0.0686 (17) | 0.092 (2) | 0.158 (3) | 0.0184 (15) | 0.0559 (19) | 0.016 (2) |
Cu1—N1 | 2.074 (2) | C11—H11 | 0.9500 |
Cu1—N1i | 2.074 (2) | C12—C13 | 1.505 (5) |
Cu1—N11 | 2.036 (2) | C12—H12A | 0.9900 |
Cu1—N11i | 2.036 (2) | C12—H12B | 0.9900 |
Cu2—N2 | 2.070 (2) | C13—C14 | 1.514 (5) |
Cu2—N2i | 2.071 (2) | C13—H13A | 0.9900 |
Cu2—N21 | 2.010 (2) | C13—H13B | 0.9900 |
Cu2—N21i | 2.010 (2) | C14—C15 | 1.383 (5) |
N1—C1 | 1.345 (3) | C15—C16 | 1.412 (6) |
N1—C5 | 1.337 (3) | C15—H15 | 0.9500 |
N2—C6 | 1.338 (4) | C16—C17 | 1.366 (7) |
N2—C10 | 1.349 (4) | C16—H16 | 0.9500 |
N11—C11 | 1.272 (4) | C17—C18 | 1.360 (6) |
N11—C12 | 1.473 (4) | C17—H17 | 0.9500 |
N12—C14 | 1.323 (5) | C18—H18 | 0.9500 |
N12—C18 | 1.329 (5) | C21—H21 | 0.9500 |
N21—C21 | 1.276 (4) | C22—C23 | 1.516 (4) |
N21—C22 | 1.468 (4) | C22—H22A | 0.9900 |
N22—C24 | 1.335 (4) | C22—H22B | 0.9900 |
N22—C28 | 1.335 (4) | C23—C24 | 1.511 (4) |
C1—C2 | 1.391 (4) | C23—H23A | 0.9900 |
C1—C11 | 1.462 (4) | C23—H23B | 0.9900 |
C2—C3 | 1.380 (5) | C24—C25 | 1.380 (4) |
C2—H2 | 0.9500 | C25—C26 | 1.391 (5) |
C3—C4 | 1.376 (5) | C25—H25 | 0.9500 |
C3—H3 | 0.9500 | C26—C27 | 1.372 (5) |
C4—C5 | 1.394 (4) | C26—H26 | 0.9500 |
C4—H4 | 0.9500 | C27—C28 | 1.373 (5) |
C5—C6 | 1.486 (4) | C27—H27 | 0.9500 |
C6—C7 | 1.394 (4) | C28—H28 | 0.9500 |
C7—C8 | 1.386 (5) | P—F1 | 1.583 (3) |
C7—H7 | 0.9500 | P—F2 | 1.572 (2) |
C8—C9 | 1.368 (5) | P—F3 | 1.573 (2) |
C8—H8 | 0.9500 | P—F4 | 1.590 (2) |
C9—C10 | 1.392 (4) | P—F5 | 1.577 (3) |
C9—H9 | 0.9500 | P—F6 | 1.569 (3) |
C10—C21 | 1.462 (4) | ||
N1—Cu1—N1i | 125.03 (12) | C12—C13—H13A | 108.7 |
N11—Cu1—N1 | 80.72 (9) | C12—C13—H13B | 108.7 |
N1—Cu1—N11i | 117.48 (9) | C14—C13—H13A | 108.7 |
N1i—Cu1—N11 | 117.48 (9) | C14—C13—H13B | 108.7 |
N1i—Cu1—N11i | 80.72 (9) | H13A—C13—H13B | 107.6 |
N11—Cu1—N11i | 142.05 (13) | N12—C14—C13 | 116.0 (3) |
N2—Cu2—N2i | 124.63 (12) | N12—C14—C15 | 121.6 (4) |
N2—Cu2—N21 | 81.09 (10) | C13—C14—C15 | 122.3 (4) |
N2—Cu2—N21i | 119.12 (9) | C14—C15—C16 | 118.7 (4) |
N2i—Cu2—N21 | 119.12 (9) | C14—C15—H15 | 120.7 |
N2i—Cu2—N21i | 81.09 (10) | C16—C15—H15 | 120.7 |
N21i—Cu2—N21 | 138.15 (14) | C15—C16—C17 | 118.5 (4) |
Cu1—N1—C1 | 111.60 (18) | C15—C16—H16 | 120.7 |
Cu1—N1—C5 | 130.02 (18) | C17—C16—H16 | 120.7 |
C1—N1—C5 | 118.1 (2) | C16—C17—C18 | 118.3 (4) |
Cu2—N2—C6 | 129.91 (19) | C16—C17—H17 | 120.8 |
Cu2—N2—C10 | 111.12 (18) | C18—C17—H17 | 120.8 |
C6—N2—C10 | 118.4 (2) | N12—C18—C17 | 124.2 (4) |
Cu1—N11—C11 | 112.96 (19) | N12—C18—H18 | 117.9 |
Cu1—N11—C12 | 130.81 (19) | C17—C18—H18 | 117.9 |
C11—N11—C12 | 116.0 (2) | N21—C21—C10 | 118.9 (3) |
C14—N12—C18 | 118.7 (3) | N21—C21—H21 | 120.5 |
Cu2—N21—C21 | 113.72 (19) | C10—C21—H21 | 120.5 |
Cu2—N21—C22 | 129.3 (2) | N21—C22—C23 | 108.6 (2) |
C21—N21—C22 | 116.9 (3) | N21—C22—H22A | 110.0 |
C24—N22—C28 | 117.7 (3) | N21—C22—H22B | 110.0 |
N1—C1—C2 | 122.7 (3) | C23—C22—H22A | 110.0 |
N1—C1—C11 | 114.8 (2) | C23—C22—H22B | 110.0 |
C2—C1—C11 | 122.5 (3) | H22A—C22—H22B | 108.3 |
C1—C2—C3 | 118.4 (3) | C22—C23—C24 | 114.1 (2) |
C1—C2—H2 | 120.8 | C22—C23—H23A | 108.7 |
C3—C2—H2 | 120.8 | C22—C23—H23B | 108.7 |
C2—C3—C4 | 119.6 (3) | C24—C23—H23A | 108.7 |
C2—C3—H3 | 120.2 | C24—C23—H23B | 108.7 |
C4—C3—H3 | 120.2 | H23A—C23—H23B | 107.6 |
C3—C4—C5 | 118.6 (3) | N22—C24—C23 | 115.7 (3) |
C3—C4—H4 | 120.7 | N22—C24—C25 | 122.3 (3) |
C5—C4—H4 | 120.7 | C23—C24—C25 | 122.0 (3) |
N1—C5—C4 | 122.6 (3) | C24—C25—C26 | 119.0 (3) |
N1—C5—C6 | 115.2 (2) | C24—C25—H25 | 120.5 |
C4—C5—C6 | 122.1 (3) | C26—C25—H25 | 120.5 |
N2—C6—C5 | 114.8 (2) | C25—C26—C27 | 118.8 (3) |
N2—C6—C7 | 122.3 (3) | C25—C26—H26 | 120.6 |
C5—C6—C7 | 122.9 (3) | C27—C26—H26 | 120.6 |
C6—C7—C8 | 118.4 (3) | C26—C27—C28 | 118.3 (3) |
C6—C7—H7 | 120.8 | C26—C27—H27 | 120.8 |
C8—C7—H7 | 120.8 | C28—C27—H27 | 120.8 |
C7—C8—C9 | 119.9 (3) | N22—C28—C27 | 123.9 (3) |
C7—C8—H8 | 120.1 | N22—C28—H28 | 118.1 |
C9—C8—H8 | 120.1 | C27—C28—H28 | 118.1 |
C8—C9—C10 | 118.6 (3) | F1—P—F2 | 177.88 (18) |
C8—C9—H9 | 120.7 | F1—P—F3 | 88.01 (16) |
C10—C9—H9 | 120.7 | F1—P—F4 | 91.24 (16) |
N2—C10—C9 | 122.3 (3) | F1—P—F5 | 91.0 (2) |
N2—C10—C21 | 115.0 (2) | F1—P—F6 | 89.0 (2) |
C9—C10—C21 | 122.5 (3) | F2—P—F3 | 93.43 (16) |
N11—C11—C1 | 119.7 (2) | F2—P—F4 | 87.33 (15) |
N11—C11—H11 | 120.1 | F2—P—F5 | 87.51 (18) |
C1—C11—H11 | 120.1 | F2—P—F6 | 92.57 (18) |
N11—C12—C13 | 112.4 (3) | F3—P—F4 | 179.07 (15) |
N11—C12—H12A | 109.1 | F3—P—F5 | 89.41 (17) |
N11—C12—H12B | 109.1 | F3—P—F6 | 90.67 (16) |
C13—C12—H12A | 109.1 | F4—P—F5 | 91.16 (19) |
C13—C12—H12B | 109.1 | F4—P—F6 | 88.77 (19) |
H12A—C12—H12B | 107.9 | F5—P—F6 | 179.9 (3) |
C12—C13—C14 | 114.0 (3) | ||
N1i—Cu1—N1—C1 | 118.19 (18) | C18—N12—C14—C15 | −0.5 (5) |
N1i—Cu1—N1—C5 | −68.5 (2) | C14—N12—C18—C17 | 1.7 (5) |
N11—Cu1—N1—C1 | 1.03 (17) | Cu2—N21—C21—C10 | −3.9 (3) |
N11—Cu1—N1—C5 | 174.3 (2) | C22—N21—C21—C10 | 174.2 (2) |
N11i—Cu1—N1—C1 | −143.62 (17) | Cu2—N21—C22—C23 | 63.1 (3) |
N11i—Cu1—N1—C5 | 29.7 (3) | C21—N21—C22—C23 | −114.7 (3) |
N1—Cu1—N11—C11 | 1.5 (2) | C28—N22—C24—C23 | 179.8 (3) |
N1—Cu1—N11—C12 | 176.1 (3) | C28—N22—C24—C25 | 0.2 (5) |
N1i—Cu1—N11—C11 | −123.3 (2) | C24—N22—C28—C27 | 0.1 (5) |
N1i—Cu1—N11—C12 | 51.3 (3) | N1—C1—C2—C3 | −3.1 (4) |
N11i—Cu1—N11—C11 | 124.9 (2) | C11—C1—C2—C3 | 176.5 (3) |
N11i—Cu1—N11—C12 | −60.5 (2) | N1—C1—C11—N11 | 4.8 (4) |
N2i—Cu2—N2—C6 | −69.8 (2) | C2—C1—C11—N11 | −174.8 (3) |
N2i—Cu2—N2—C10 | 119.01 (18) | C1—C2—C3—C4 | 1.0 (5) |
N21—Cu2—N2—C6 | 170.8 (2) | C2—C3—C4—C5 | 1.7 (5) |
N21—Cu2—N2—C10 | −0.35 (17) | C3—C4—C5—N1 | −2.5 (5) |
N21i—Cu2—N2—C6 | 29.9 (3) | C3—C4—C5—C6 | 173.7 (3) |
N21i—Cu2—N2—C10 | −141.23 (17) | N1—C5—C6—N2 | 59.2 (3) |
N2—Cu2—N21—C21 | 2.4 (2) | N1—C5—C6—C7 | −119.3 (3) |
N2—Cu2—N21—C22 | −175.4 (2) | C4—C5—C6—N2 | −117.2 (3) |
N2i—Cu2—N21—C21 | −122.5 (2) | C4—C5—C6—C7 | 64.2 (4) |
N2i—Cu2—N21—C22 | 59.7 (3) | N2—C6—C7—C8 | −3.5 (4) |
N21i—Cu2—N21—C21 | 126.6 (2) | C5—C6—C7—C8 | 174.9 (3) |
N21i—Cu2—N21—C22 | −51.2 (2) | C6—C7—C8—C9 | 1.4 (4) |
Cu1—N1—C1—C2 | 176.5 (2) | C7—C8—C9—C10 | 2.0 (5) |
Cu1—N1—C1—C11 | −3.1 (3) | C8—C9—C10—N2 | −3.7 (4) |
C5—N1—C1—C2 | 2.3 (4) | C8—C9—C10—C21 | 171.4 (3) |
C5—N1—C1—C11 | −177.3 (2) | N11—C12—C13—C14 | −78.7 (4) |
Cu1—N1—C5—C4 | −172.4 (2) | C12—C13—C14—N12 | −48.6 (4) |
Cu1—N1—C5—C6 | 11.2 (3) | C12—C13—C14—C15 | 135.1 (3) |
C1—N1—C5—C4 | 0.5 (4) | N12—C14—C15—C16 | −0.7 (5) |
C1—N1—C5—C6 | −175.9 (2) | C13—C14—C15—C16 | 175.4 (3) |
Cu2—N2—C6—C5 | 12.8 (3) | C14—C15—C16—C17 | 0.9 (6) |
Cu2—N2—C6—C7 | −168.7 (2) | C15—C16—C17—C18 | 0.1 (6) |
C10—N2—C6—C5 | −176.6 (2) | C16—C17—C18—N12 | −1.5 (6) |
C10—N2—C6—C7 | 1.9 (4) | N2—C10—C21—N21 | 3.7 (4) |
Cu2—N2—C10—C9 | 174.0 (2) | C9—C10—C21—N21 | −171.7 (3) |
Cu2—N2—C10—C21 | −1.5 (3) | N21—C22—C23—C24 | 161.8 (3) |
C6—N2—C10—C9 | 1.7 (4) | C22—C23—C24—N22 | −131.5 (3) |
C6—N2—C10—C21 | −173.7 (2) | C22—C23—C24—C25 | 48.1 (4) |
Cu1—N11—C11—C1 | −3.8 (3) | N22—C24—C25—C26 | −0.8 (5) |
C12—N11—C11—C1 | −179.2 (3) | C23—C24—C25—C26 | 179.7 (3) |
Cu1—N11—C12—C13 | 43.0 (4) | C24—C25—C26—C27 | 1.1 (5) |
C11—N11—C12—C13 | −142.5 (3) | C25—C26—C27—C28 | −0.8 (5) |
C18—N12—C14—C13 | −176.8 (3) | C26—C27—C28—N22 | 0.2 (6) |
Symmetry code: (i) −x, y, −z+1/2. |