Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S160053680603947X/sg2068sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S160053680603947X/sg2068Isup2.hkl |
CCDC reference: 628390
Data collection: SMART (Bruker, 1997); cell refinement: SMART; data reduction: SAINT (Bruker, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.
[Mn2(C7H5O2)4(C5H5N)4] | F(000) = 940 |
Mr = 910.72 | Dx = 1.385 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
a = 12.7476 (8) Å | θ = 1.6–25.1° |
b = 8.4582 (5) Å | µ = 0.64 mm−1 |
c = 20.5745 (13) Å | T = 296 K |
β = 100.185 (1)° | Cubic, brown |
V = 2183.4 (2) Å3 | 0.36 × 0.28 × 0.19 mm |
Z = 2 |
Bruker SMART CCD area-detector diffractometer | 3874 independent reflections |
Radiation source: fine-focus sealed tube | 3137 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.020 |
φ and ω scans | θmax = 25.1°, θmin = 1.6° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −14→15 |
Tmin = 0.802, Tmax = 0.886 | k = −10→9 |
10609 measured reflections | l = −23→24 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.031 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.087 | H-atom parameters constrained |
S = 1.21 | w = 1/[σ2(Fo2) + (0.0406P)2] where P = (Fo2 + 2Fc2)/3 |
3874 reflections | (Δ/σ)max < 0.001 |
280 parameters | Δρmax = 0.18 e Å−3 |
0 restraints | Δρmin = −0.21 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Mn1 | 0.12067 (2) | 1.02280 (3) | 0.094604 (13) | 0.04750 (12) | |
N1 | 0.17963 (12) | 1.23206 (19) | 0.03985 (7) | 0.0545 (4) | |
N2 | 0.08805 (12) | 0.78523 (18) | 0.14006 (7) | 0.0535 (4) | |
O1 | 0.11903 (11) | 0.89294 (17) | 0.00695 (6) | 0.0628 (4) | |
O2 | 0.03473 (10) | 0.89972 (17) | −0.09672 (7) | 0.0644 (4) | |
O3 | 0.29414 (11) | 0.98457 (15) | 0.14702 (7) | 0.0589 (4) | |
O4 | 0.18380 (10) | 1.12919 (16) | 0.19301 (6) | 0.0603 (4) | |
C1 | 0.11800 (14) | 0.8911 (2) | −0.05371 (9) | 0.0472 (4) | |
C2 | 0.22147 (14) | 0.8710 (2) | −0.07784 (9) | 0.0458 (4) | |
C3 | 0.31724 (15) | 0.8773 (2) | −0.03417 (10) | 0.0595 (5) | |
H3 | 0.3175 | 0.8969 | 0.0103 | 0.071* | |
C4 | 0.41207 (17) | 0.8548 (3) | −0.05587 (13) | 0.0806 (7) | |
H4 | 0.4761 | 0.8601 | −0.0262 | 0.097* | |
C5 | 0.41211 (19) | 0.8245 (3) | −0.12141 (15) | 0.0937 (8) | |
H5 | 0.4763 | 0.8084 | −0.1360 | 0.112* | |
C6 | 0.3182 (2) | 0.8179 (3) | −0.16537 (12) | 0.0892 (8) | |
H6 | 0.3184 | 0.7968 | −0.2097 | 0.107* | |
C7 | 0.22248 (16) | 0.8429 (3) | −0.14351 (10) | 0.0653 (6) | |
H7 | 0.1587 | 0.8407 | −0.1735 | 0.078* | |
C8 | 0.27439 (15) | 1.0671 (2) | 0.19455 (9) | 0.0500 (4) | |
C9 | 0.35986 (15) | 1.0951 (2) | 0.25298 (9) | 0.0513 (5) | |
C10 | 0.34451 (18) | 1.2006 (3) | 0.30164 (10) | 0.0714 (6) | |
H10 | 0.2801 | 1.2544 | 0.2981 | 0.086* | |
C11 | 0.4240 (2) | 1.2270 (3) | 0.35548 (12) | 0.0914 (8) | |
H11 | 0.4131 | 1.2985 | 0.3880 | 0.110* | |
C12 | 0.5189 (2) | 1.1481 (4) | 0.36104 (13) | 0.1004 (9) | |
H12 | 0.5723 | 1.1661 | 0.3973 | 0.121* | |
C13 | 0.5352 (2) | 1.0432 (4) | 0.31361 (14) | 0.0949 (9) | |
H13 | 0.5998 | 0.9897 | 0.3178 | 0.114* | |
C14 | 0.45608 (17) | 1.0154 (3) | 0.25903 (11) | 0.0697 (6) | |
H14 | 0.4677 | 0.9437 | 0.2268 | 0.084* | |
C15 | 0.11335 (17) | 1.3257 (3) | 0.00015 (10) | 0.0699 (6) | |
H15 | 0.0405 | 1.3089 | −0.0031 | 0.084* | |
C16 | 0.1464 (2) | 1.4463 (3) | −0.03652 (12) | 0.0794 (7) | |
H16 | 0.0970 | 1.5103 | −0.0630 | 0.095* | |
C17 | 0.2532 (2) | 1.4698 (3) | −0.03310 (13) | 0.0814 (7) | |
H17 | 0.2780 | 1.5476 | −0.0585 | 0.098* | |
C18 | 0.3231 (2) | 1.3763 (3) | 0.00847 (13) | 0.0829 (7) | |
H18 | 0.3963 | 1.3914 | 0.0127 | 0.099* | |
C19 | 0.28281 (16) | 1.2597 (3) | 0.04379 (10) | 0.0673 (6) | |
H19 | 0.3307 | 1.1969 | 0.0719 | 0.081* | |
C20 | 0.00719 (17) | 0.7578 (3) | 0.17137 (9) | 0.0629 (5) | |
H20 | −0.0396 | 0.8401 | 0.1755 | 0.075* | |
C21 | −0.0105 (2) | 0.6117 (3) | 0.19816 (11) | 0.0795 (7) | |
H21 | −0.0673 | 0.5966 | 0.2203 | 0.095* | |
C22 | 0.0582 (2) | 0.4894 (3) | 0.19115 (11) | 0.0773 (7) | |
H22 | 0.0479 | 0.3895 | 0.2079 | 0.093* | |
C23 | 0.1409 (2) | 0.5172 (3) | 0.15952 (11) | 0.0710 (6) | |
H23 | 0.1883 | 0.4366 | 0.1544 | 0.085* | |
C24 | 0.15392 (17) | 0.6644 (2) | 0.13520 (10) | 0.0642 (5) | |
H24 | 0.2117 | 0.6818 | 0.1141 | 0.077* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Mn1 | 0.04106 (18) | 0.0540 (2) | 0.04667 (19) | 0.00364 (13) | 0.00575 (12) | 0.00017 (12) |
N1 | 0.0531 (10) | 0.0546 (10) | 0.0546 (10) | −0.0003 (8) | 0.0065 (7) | −0.0004 (8) |
N2 | 0.0567 (10) | 0.0533 (10) | 0.0514 (9) | 0.0034 (8) | 0.0118 (7) | −0.0016 (7) |
O1 | 0.0714 (9) | 0.0686 (10) | 0.0514 (8) | 0.0012 (7) | 0.0191 (7) | −0.0048 (7) |
O2 | 0.0442 (8) | 0.0847 (10) | 0.0636 (9) | 0.0156 (7) | 0.0074 (7) | −0.0014 (7) |
O3 | 0.0527 (8) | 0.0694 (9) | 0.0520 (8) | 0.0056 (6) | 0.0026 (6) | −0.0063 (7) |
O4 | 0.0518 (8) | 0.0644 (9) | 0.0620 (8) | 0.0094 (7) | 0.0029 (6) | −0.0037 (7) |
C1 | 0.0498 (11) | 0.0392 (10) | 0.0530 (12) | 0.0040 (8) | 0.0107 (9) | −0.0002 (8) |
C2 | 0.0445 (10) | 0.0425 (10) | 0.0505 (11) | 0.0057 (8) | 0.0085 (8) | 0.0045 (8) |
C3 | 0.0519 (12) | 0.0569 (13) | 0.0676 (13) | 0.0026 (9) | 0.0049 (10) | −0.0013 (10) |
C4 | 0.0432 (12) | 0.0855 (17) | 0.110 (2) | 0.0053 (11) | 0.0045 (12) | 0.0010 (15) |
C5 | 0.0561 (15) | 0.115 (2) | 0.118 (2) | 0.0164 (14) | 0.0370 (16) | 0.0132 (18) |
C6 | 0.0788 (17) | 0.125 (2) | 0.0722 (16) | 0.0243 (16) | 0.0356 (14) | 0.0101 (15) |
C7 | 0.0573 (12) | 0.0824 (16) | 0.0569 (13) | 0.0158 (11) | 0.0122 (10) | 0.0058 (11) |
C8 | 0.0509 (12) | 0.0486 (11) | 0.0491 (11) | −0.0034 (9) | 0.0053 (9) | 0.0077 (9) |
C9 | 0.0517 (12) | 0.0543 (12) | 0.0463 (11) | −0.0102 (9) | 0.0046 (8) | 0.0066 (9) |
C10 | 0.0772 (15) | 0.0725 (15) | 0.0620 (13) | −0.0094 (12) | 0.0059 (11) | −0.0039 (11) |
C11 | 0.109 (2) | 0.098 (2) | 0.0619 (15) | −0.0301 (18) | 0.0014 (14) | −0.0142 (14) |
C12 | 0.092 (2) | 0.126 (3) | 0.0705 (17) | −0.0361 (19) | −0.0211 (15) | 0.0036 (17) |
C13 | 0.0566 (15) | 0.128 (2) | 0.091 (2) | −0.0069 (15) | −0.0138 (14) | 0.0078 (18) |
C14 | 0.0572 (14) | 0.0856 (17) | 0.0632 (14) | −0.0027 (12) | 0.0024 (11) | 0.0035 (11) |
C15 | 0.0646 (14) | 0.0710 (15) | 0.0682 (14) | −0.0055 (11) | −0.0039 (11) | 0.0070 (12) |
C16 | 0.0881 (19) | 0.0663 (16) | 0.0765 (16) | 0.0001 (13) | −0.0054 (13) | 0.0147 (12) |
C17 | 0.103 (2) | 0.0526 (14) | 0.0918 (19) | −0.0037 (14) | 0.0272 (16) | 0.0107 (12) |
C18 | 0.0689 (15) | 0.0663 (16) | 0.119 (2) | −0.0014 (12) | 0.0315 (14) | 0.0156 (15) |
C19 | 0.0555 (13) | 0.0631 (14) | 0.0839 (15) | 0.0069 (11) | 0.0137 (11) | 0.0124 (11) |
C20 | 0.0694 (14) | 0.0666 (14) | 0.0559 (12) | 0.0066 (11) | 0.0198 (10) | −0.0012 (10) |
C21 | 0.0971 (19) | 0.0824 (18) | 0.0663 (14) | −0.0119 (14) | 0.0340 (13) | 0.0082 (12) |
C22 | 0.111 (2) | 0.0574 (15) | 0.0631 (15) | −0.0038 (13) | 0.0143 (14) | 0.0083 (11) |
C23 | 0.0899 (17) | 0.0554 (14) | 0.0675 (15) | 0.0117 (12) | 0.0135 (13) | 0.0010 (11) |
C24 | 0.0671 (13) | 0.0594 (14) | 0.0692 (14) | 0.0098 (11) | 0.0205 (11) | 0.0031 (11) |
Mn1—O2i | 2.0943 (12) | C9—C10 | 1.381 (3) |
Mn1—O1 | 2.1086 (13) | C9—C14 | 1.386 (3) |
Mn1—O4 | 2.2316 (13) | C10—C11 | 1.381 (3) |
Mn1—N2 | 2.2854 (16) | C10—H10 | 0.9300 |
Mn1—N1 | 2.2948 (16) | C11—C12 | 1.368 (4) |
Mn1—O3 | 2.3052 (13) | C11—H11 | 0.9300 |
Mn1—C8 | 2.6044 (19) | C12—C13 | 1.362 (4) |
N1—C19 | 1.324 (2) | C12—H12 | 0.9300 |
N1—C15 | 1.328 (2) | C13—C14 | 1.391 (3) |
N2—C20 | 1.329 (2) | C13—H13 | 0.9300 |
N2—C24 | 1.337 (2) | C14—H14 | 0.9300 |
O1—C1 | 1.246 (2) | C15—C16 | 1.378 (3) |
O2—C1 | 1.258 (2) | C15—H15 | 0.9300 |
O2—Mn1i | 2.0943 (12) | C16—C17 | 1.365 (3) |
O3—C8 | 1.262 (2) | C16—H16 | 0.9300 |
O4—C8 | 1.264 (2) | C17—C18 | 1.372 (3) |
C1—C2 | 1.499 (2) | C17—H17 | 0.9300 |
C2—C7 | 1.374 (3) | C18—C19 | 1.377 (3) |
C2—C3 | 1.383 (3) | C18—H18 | 0.9300 |
C3—C4 | 1.374 (3) | C19—H19 | 0.9300 |
C3—H3 | 0.9300 | C20—C21 | 1.387 (3) |
C4—C5 | 1.373 (3) | C20—H20 | 0.9300 |
C4—H4 | 0.9300 | C21—C22 | 1.379 (3) |
C5—C6 | 1.368 (3) | C21—H21 | 0.9300 |
C5—H5 | 0.9300 | C22—C23 | 1.354 (3) |
C6—C7 | 1.389 (3) | C22—H22 | 0.9300 |
C6—H6 | 0.9300 | C23—C24 | 1.363 (3) |
C7—H7 | 0.9300 | C23—H23 | 0.9300 |
C8—C9 | 1.492 (3) | C24—H24 | 0.9300 |
O2i—Mn1—O1 | 108.33 (5) | O3—C8—C9 | 119.66 (18) |
O2i—Mn1—O4 | 92.61 (5) | O4—C8—C9 | 119.20 (18) |
O1—Mn1—O4 | 158.98 (5) | O3—C8—Mn1 | 62.24 (10) |
O2i—Mn1—N2 | 91.45 (6) | O4—C8—Mn1 | 58.90 (9) |
O1—Mn1—N2 | 85.24 (5) | C9—C8—Mn1 | 178.09 (15) |
O4—Mn1—N2 | 92.62 (5) | C10—C9—C14 | 119.07 (19) |
O2i—Mn1—N1 | 99.32 (6) | C10—C9—C8 | 120.68 (19) |
O1—Mn1—N1 | 86.36 (5) | C14—C9—C8 | 120.25 (19) |
O4—Mn1—N1 | 92.15 (5) | C9—C10—C11 | 120.5 (2) |
N2—Mn1—N1 | 168.00 (5) | C9—C10—H10 | 119.7 |
O2i—Mn1—O3 | 150.09 (5) | C11—C10—H10 | 119.7 |
O1—Mn1—O3 | 100.99 (5) | C12—C11—C10 | 120.1 (3) |
O4—Mn1—O3 | 57.99 (5) | C12—C11—H11 | 120.0 |
N2—Mn1—O3 | 85.07 (5) | C10—C11—H11 | 120.0 |
N1—Mn1—O3 | 88.14 (5) | C13—C12—C11 | 120.2 (2) |
O2i—Mn1—C8 | 121.40 (6) | C13—C12—H12 | 119.9 |
O1—Mn1—C8 | 129.98 (6) | C11—C12—H12 | 119.9 |
O4—Mn1—C8 | 29.01 (5) | C12—C13—C14 | 120.5 (3) |
N2—Mn1—C8 | 88.24 (5) | C12—C13—H13 | 119.7 |
N1—Mn1—C8 | 90.61 (6) | C14—C13—H13 | 119.7 |
O3—Mn1—C8 | 28.98 (5) | C9—C14—C13 | 119.6 (2) |
C19—N1—C15 | 116.70 (18) | C9—C14—H14 | 120.2 |
C19—N1—Mn1 | 120.94 (13) | C13—C14—H14 | 120.2 |
C15—N1—Mn1 | 122.27 (14) | N1—C15—C16 | 123.7 (2) |
C20—N2—C24 | 116.98 (18) | N1—C15—H15 | 118.1 |
C20—N2—Mn1 | 124.39 (14) | C16—C15—H15 | 118.1 |
C24—N2—Mn1 | 118.62 (13) | C17—C16—C15 | 118.6 (2) |
C1—O1—Mn1 | 149.33 (13) | C17—C16—H16 | 120.7 |
C1—O2—Mn1i | 133.40 (12) | C15—C16—H16 | 120.7 |
C8—O3—Mn1 | 88.78 (11) | C16—C17—C18 | 118.7 (2) |
C8—O4—Mn1 | 92.08 (11) | C16—C17—H17 | 120.6 |
O1—C1—O2 | 124.19 (17) | C18—C17—H17 | 120.6 |
O1—C1—C2 | 118.63 (16) | C17—C18—C19 | 118.7 (2) |
O2—C1—C2 | 117.13 (16) | C17—C18—H18 | 120.7 |
C7—C2—C3 | 118.99 (17) | C19—C18—H18 | 120.7 |
C7—C2—C1 | 120.47 (17) | N1—C19—C18 | 123.6 (2) |
C3—C2—C1 | 120.53 (17) | N1—C19—H19 | 118.2 |
C4—C3—C2 | 120.7 (2) | C18—C19—H19 | 118.2 |
C4—C3—H3 | 119.7 | N2—C20—C21 | 122.9 (2) |
C2—C3—H3 | 119.7 | N2—C20—H20 | 118.6 |
C5—C4—C3 | 119.9 (2) | C21—C20—H20 | 118.6 |
C5—C4—H4 | 120.1 | C22—C21—C20 | 118.4 (2) |
C3—C4—H4 | 120.1 | C22—C21—H21 | 120.8 |
C6—C5—C4 | 120.3 (2) | C20—C21—H21 | 120.8 |
C6—C5—H5 | 119.9 | C23—C22—C21 | 118.8 (2) |
C4—C5—H5 | 119.9 | C23—C22—H22 | 120.6 |
C5—C6—C7 | 119.7 (2) | C21—C22—H22 | 120.6 |
C5—C6—H6 | 120.1 | C22—C23—C24 | 119.4 (2) |
C7—C6—H6 | 120.1 | C22—C23—H23 | 120.3 |
C2—C7—C6 | 120.4 (2) | C24—C23—H23 | 120.3 |
C2—C7—H7 | 119.8 | N2—C24—C23 | 123.5 (2) |
C6—C7—H7 | 119.8 | N2—C24—H24 | 118.3 |
O3—C8—O4 | 121.12 (17) | C23—C24—H24 | 118.3 |
O2i—Mn1—N1—C19 | 159.57 (15) | C3—C2—C7—C6 | 1.4 (3) |
O1—Mn1—N1—C19 | −92.44 (15) | C1—C2—C7—C6 | −177.3 (2) |
O4—Mn1—N1—C19 | 66.57 (15) | C5—C6—C7—C2 | −1.4 (4) |
N2—Mn1—N1—C19 | −46.8 (3) | Mn1—O3—C8—O4 | −1.63 (18) |
O3—Mn1—N1—C19 | 8.70 (15) | Mn1—O3—C8—C9 | 179.78 (15) |
C8—Mn1—N1—C19 | 37.58 (15) | Mn1—O4—C8—O3 | 1.68 (18) |
O2i—Mn1—N1—C15 | −24.15 (17) | Mn1—O4—C8—C9 | −179.72 (15) |
O1—Mn1—N1—C15 | 83.84 (16) | O2i—Mn1—C8—O3 | 173.63 (10) |
O4—Mn1—N1—C15 | −117.16 (16) | O1—Mn1—C8—O3 | 0.72 (14) |
N2—Mn1—N1—C15 | 129.5 (3) | O4—Mn1—C8—O3 | −178.37 (18) |
O3—Mn1—N1—C15 | −175.02 (16) | N2—Mn1—C8—O3 | 83.01 (11) |
C8—Mn1—N1—C15 | −146.14 (16) | N1—Mn1—C8—O3 | −85.05 (11) |
O2i—Mn1—N2—C20 | −17.37 (16) | O2i—Mn1—C8—O4 | −8.00 (13) |
O1—Mn1—N2—C20 | −125.65 (15) | O1—Mn1—C8—O4 | 179.09 (10) |
O4—Mn1—N2—C20 | 75.31 (15) | N2—Mn1—C8—O4 | −98.62 (11) |
N1—Mn1—N2—C20 | −171.3 (2) | N1—Mn1—C8—O4 | 93.32 (11) |
O3—Mn1—N2—C20 | 132.86 (16) | O3—Mn1—C8—O4 | 178.37 (18) |
C8—Mn1—N2—C20 | 104.00 (16) | O2i—Mn1—C8—C9 | −1 (4) |
O2i—Mn1—N2—C24 | 162.55 (14) | O1—Mn1—C8—C9 | −173 (4) |
O1—Mn1—N2—C24 | 54.28 (15) | O4—Mn1—C8—C9 | 7 (4) |
O4—Mn1—N2—C24 | −104.76 (14) | N2—Mn1—C8—C9 | −91 (4) |
N1—Mn1—N2—C24 | 8.6 (3) | N1—Mn1—C8—C9 | 101 (4) |
O3—Mn1—N2—C24 | −47.21 (14) | O3—Mn1—C8—C9 | −174 (4) |
C8—Mn1—N2—C24 | −76.08 (15) | O3—C8—C9—C10 | 171.81 (18) |
O2i—Mn1—O1—C1 | 79.5 (2) | O4—C8—C9—C10 | −6.8 (3) |
O4—Mn1—O1—C1 | −105.6 (3) | Mn1—C8—C9—C10 | −14 (4) |
N2—Mn1—O1—C1 | 169.5 (2) | O3—C8—C9—C14 | −8.1 (3) |
N1—Mn1—O1—C1 | −19.1 (2) | O4—C8—C9—C14 | 173.28 (18) |
O3—Mn1—O1—C1 | −106.5 (2) | Mn1—C8—C9—C14 | 166 (4) |
C8—Mn1—O1—C1 | −106.9 (2) | C14—C9—C10—C11 | 0.3 (3) |
O2i—Mn1—O3—C8 | −10.94 (17) | C8—C9—C10—C11 | −179.62 (19) |
O1—Mn1—O3—C8 | −179.44 (11) | C9—C10—C11—C12 | −0.2 (4) |
O4—Mn1—O3—C8 | 0.93 (10) | C10—C11—C12—C13 | −0.1 (4) |
N2—Mn1—O3—C8 | −95.27 (11) | C11—C12—C13—C14 | 0.2 (4) |
N1—Mn1—O3—C8 | 94.63 (11) | C10—C9—C14—C13 | −0.2 (3) |
O2i—Mn1—O4—C8 | 173.17 (11) | C8—C9—C14—C13 | 179.7 (2) |
O1—Mn1—O4—C8 | −1.9 (2) | C12—C13—C14—C9 | 0.0 (4) |
N2—Mn1—O4—C8 | 81.60 (11) | C19—N1—C15—C16 | 0.5 (3) |
N1—Mn1—O4—C8 | −87.39 (11) | Mn1—N1—C15—C16 | −175.92 (17) |
O3—Mn1—O4—C8 | −0.93 (10) | N1—C15—C16—C17 | 1.3 (4) |
Mn1—O1—C1—O2 | −85.6 (3) | C15—C16—C17—C18 | −2.4 (4) |
Mn1—O1—C1—C2 | 96.9 (3) | C16—C17—C18—C19 | 1.7 (4) |
Mn1i—O2—C1—O1 | 19.0 (3) | C15—N1—C19—C18 | −1.2 (3) |
Mn1i—O2—C1—C2 | −163.49 (12) | Mn1—N1—C19—C18 | 175.25 (18) |
O1—C1—C2—C7 | 169.52 (18) | C17—C18—C19—N1 | 0.1 (4) |
O2—C1—C2—C7 | −8.2 (3) | C24—N2—C20—C21 | −0.2 (3) |
O1—C1—C2—C3 | −9.2 (3) | Mn1—N2—C20—C21 | 179.72 (16) |
O2—C1—C2—C3 | 173.16 (17) | N2—C20—C21—C22 | −0.9 (4) |
C7—C2—C3—C4 | −0.4 (3) | C20—C21—C22—C23 | 1.1 (4) |
C1—C2—C3—C4 | 178.29 (18) | C21—C22—C23—C24 | −0.3 (4) |
C2—C3—C4—C5 | −0.6 (4) | C20—N2—C24—C23 | 1.1 (3) |
C3—C4—C5—C6 | 0.6 (4) | Mn1—N2—C24—C23 | −178.86 (17) |
C4—C5—C6—C7 | 0.4 (4) | C22—C23—C24—N2 | −0.8 (4) |
Symmetry code: (i) −x, −y+2, −z. |