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In the binuclear title molecule, [Zn2(C9H7NO4)Cl2(C12H8N2)2], the two metal centres are bridged by a 2,6-dimethyl­pyridine-3,5-dicarboxyl­ate ligand. The binuclear unit is extended to form a two-dimensional supra­molecular motif via [pi]-[pi] stacking inter­actions between neighbouring phenanthroline rings.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270107009663/sf3026sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270107009663/sf3026Isup2.hkl
Contains datablock I

CCDC reference: 626295

Computing details top

Data collection: SMART (Siemens, 1996); cell refinement: SMART; data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.

µ-2,6-dimethylpyridine-3,5-dicarboxylato-κ4O3,O3':O5,O5'– bis[chloro(1,10-phenanthroline-κ2N,N')zinc(II)] top
Crystal data top
[Zn2(C9H7NO4)Cl2(C12H8N2)2]Dx = 1.653 Mg m3
Mr = 755.20Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Pna21Cell parameters from 2873 reflections
a = 31.578 (14) Åθ = 2.6–23.2°
b = 8.006 (4) ŵ = 1.81 mm1
c = 12.006 (6) ÅT = 298 K
V = 3035 (2) Å3Block, colourless
Z = 40.26 × 0.15 × 0.08 mm
F(000) = 1528
Data collection top
Bruker SMART CCD area-detector
diffractometer
5169 independent reflections
Radiation source: fine-focus sealed tube3397 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.061
φ and ω scansθmax = 25.0°, θmin = 1.3°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 3537
Tmin = 0.651, Tmax = 0.869k = 99
15087 measured reflectionsl = 1413
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.047H-atom parameters constrained
wR(F2) = 0.089 w = 1/[σ2(Fo2) + (0.0208P)2 + 2.4767P]
where P = (Fo2 + 2Fc2)/3
S = 1.03(Δ/σ)max = 0.001
5169 reflectionsΔρmax = 0.40 e Å3
415 parametersΔρmin = 0.39 e Å3
1 restraintAbsolute structure: Flack (1983), with how many Friedel pairs?
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.24 (2)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Zn10.47867 (2)0.46526 (9)0.31994 (8)0.0410 (2)
Zn20.76990 (2)0.44179 (10)0.57552 (8)0.0444 (2)
Cl10.48476 (8)0.2632 (3)0.1945 (2)0.0612 (8)
Cl20.76579 (7)0.2298 (2)0.6924 (2)0.0557 (7)
N10.6259 (2)0.9287 (6)0.4534 (8)0.0389 (13)
N20.42480 (16)0.5913 (7)0.2646 (5)0.0332 (14)
N30.43876 (16)0.4226 (7)0.4527 (5)0.0374 (15)
N40.82374 (18)0.5735 (7)0.6289 (5)0.0403 (16)
N50.80858 (17)0.4042 (7)0.4389 (5)0.0382 (15)
O10.51835 (15)0.6550 (6)0.3405 (4)0.0511 (13)
O20.54272 (15)0.4342 (7)0.4277 (5)0.0561 (15)
O30.72638 (15)0.6124 (6)0.5627 (5)0.0580 (14)
O40.70198 (15)0.4167 (7)0.4502 (5)0.0595 (16)
C10.5887 (2)0.8522 (9)0.4337 (8)0.038 (2)
C20.5857 (2)0.6782 (10)0.4282 (7)0.0334 (19)
C30.6224 (3)0.5877 (7)0.4475 (9)0.0329 (15)
H30.62120.47170.44560.039*
C40.6608 (2)0.6652 (9)0.4697 (7)0.0302 (19)
C50.6611 (2)0.8381 (9)0.4681 (7)0.034 (2)
C60.5521 (2)0.9669 (10)0.4251 (9)0.055 (3)
H6A0.56171.08020.43170.083*
H6B0.53230.94300.48370.083*
H6C0.53850.95180.35430.083*
C70.5465 (2)0.5827 (10)0.3991 (7)0.036 (2)
C80.6993 (3)0.5543 (11)0.4939 (9)0.046 (2)
C90.7012 (2)0.9427 (10)0.4857 (8)0.050 (2)
H9A0.69431.05920.48060.075*
H9B0.72170.91500.42950.075*
H9C0.71280.91940.55800.075*
C100.4183 (2)0.6741 (9)0.1711 (7)0.0440 (19)
H100.44060.68350.12070.053*
C110.3795 (3)0.7487 (9)0.1440 (10)0.049 (3)
H110.37640.80810.07790.059*
C120.3465 (2)0.7329 (9)0.2155 (9)0.042 (2)
H120.32040.77970.19780.051*
C130.35161 (18)0.6471 (8)0.3148 (7)0.0364 (16)
C140.39145 (19)0.5775 (8)0.3364 (6)0.0335 (17)
C150.3997 (2)0.4863 (8)0.4361 (6)0.0281 (16)
C160.3665 (2)0.4671 (9)0.5133 (6)0.0359 (18)
C170.3755 (2)0.3770 (9)0.6116 (6)0.044 (2)
H170.35460.36010.66510.052*
C180.4156 (3)0.3146 (11)0.6267 (7)0.051 (2)
H180.42220.25550.69110.061*
C190.4464 (2)0.3403 (9)0.5452 (6)0.045 (2)
H190.47340.29730.55670.054*
C200.3189 (2)0.6229 (9)0.3958 (7)0.049 (2)
H200.29220.66790.38230.058*
C210.3254 (2)0.5382 (10)0.4897 (7)0.047 (2)
H210.30330.52460.54030.056*
C220.8303 (3)0.6572 (10)0.7210 (7)0.051 (2)
H220.80760.67420.76900.061*
C230.8696 (3)0.7218 (11)0.7506 (10)0.056 (3)
H230.87340.77420.81900.067*
C240.9020 (3)0.7070 (10)0.6779 (10)0.058 (3)
H240.92820.75330.69520.070*
C250.8965 (2)0.6218 (8)0.5757 (8)0.0412 (17)
C260.85598 (19)0.5546 (8)0.5548 (6)0.0317 (16)
C270.8484 (2)0.4632 (8)0.4549 (6)0.0347 (18)
C280.8813 (2)0.4409 (9)0.3776 (6)0.0384 (19)
C290.8715 (3)0.3493 (9)0.2826 (6)0.050 (2)
H290.89260.32770.23040.060*
C300.8314 (3)0.2902 (10)0.2648 (8)0.054 (2)
H300.82460.23210.20010.064*
C310.8008 (2)0.3206 (9)0.3476 (7)0.048 (2)
H310.77360.27910.33680.058*
C320.9289 (2)0.5989 (10)0.4958 (7)0.051 (2)
H320.95550.64530.50830.062*
C330.9220 (3)0.5119 (11)0.4027 (8)0.056 (2)
H330.94420.49680.35270.067*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Zn10.0268 (4)0.0492 (5)0.0469 (5)0.0039 (4)0.0005 (4)0.0023 (6)
Zn20.0283 (4)0.0521 (5)0.0527 (5)0.0054 (4)0.0006 (4)0.0055 (5)
Cl10.0461 (15)0.0781 (16)0.0594 (19)0.0048 (10)0.0054 (16)0.0256 (12)
Cl20.0370 (14)0.0630 (14)0.067 (2)0.0034 (9)0.0103 (15)0.0011 (11)
N10.033 (3)0.038 (3)0.045 (4)0.001 (4)0.000 (3)0.006 (4)
N20.033 (3)0.039 (4)0.028 (3)0.004 (3)0.005 (3)0.002 (3)
N30.029 (3)0.047 (4)0.037 (4)0.002 (3)0.006 (3)0.001 (3)
N40.034 (3)0.048 (4)0.040 (4)0.003 (3)0.003 (3)0.003 (3)
N50.035 (3)0.040 (4)0.040 (4)0.002 (3)0.006 (3)0.003 (3)
O10.029 (2)0.067 (3)0.057 (4)0.008 (3)0.017 (3)0.010 (3)
O20.049 (3)0.048 (4)0.071 (4)0.012 (3)0.008 (3)0.005 (3)
O30.038 (3)0.072 (4)0.064 (4)0.014 (3)0.017 (3)0.018 (3)
O40.050 (3)0.052 (4)0.077 (4)0.016 (3)0.002 (3)0.014 (3)
C10.023 (4)0.035 (4)0.056 (6)0.005 (3)0.002 (4)0.003 (4)
C20.020 (4)0.046 (5)0.034 (5)0.001 (4)0.000 (4)0.008 (4)
C30.033 (3)0.028 (4)0.037 (4)0.003 (4)0.001 (3)0.002 (5)
C40.026 (4)0.042 (5)0.023 (4)0.004 (4)0.003 (4)0.002 (4)
C50.028 (4)0.041 (5)0.034 (5)0.002 (4)0.002 (4)0.011 (4)
C60.033 (5)0.048 (5)0.085 (8)0.001 (4)0.001 (5)0.015 (5)
C70.038 (5)0.041 (5)0.029 (5)0.011 (4)0.004 (4)0.004 (4)
C80.038 (5)0.048 (5)0.052 (6)0.007 (4)0.006 (4)0.009 (4)
C90.027 (4)0.066 (6)0.057 (6)0.002 (4)0.005 (4)0.007 (5)
C100.039 (5)0.054 (5)0.040 (5)0.002 (4)0.003 (4)0.004 (5)
C110.046 (6)0.048 (6)0.054 (8)0.001 (4)0.012 (6)0.005 (4)
C120.023 (4)0.044 (5)0.061 (7)0.003 (3)0.004 (5)0.001 (4)
C130.022 (3)0.031 (4)0.056 (5)0.008 (3)0.001 (4)0.000 (5)
C140.034 (4)0.030 (4)0.036 (4)0.004 (3)0.002 (4)0.002 (4)
C150.025 (4)0.026 (4)0.033 (4)0.006 (3)0.003 (3)0.006 (3)
C160.035 (4)0.030 (4)0.042 (5)0.017 (4)0.002 (4)0.005 (4)
C170.057 (5)0.041 (5)0.033 (5)0.020 (4)0.009 (4)0.006 (3)
C180.061 (6)0.059 (5)0.032 (5)0.010 (5)0.014 (5)0.005 (4)
C190.036 (4)0.051 (5)0.047 (6)0.011 (4)0.011 (4)0.001 (4)
C200.028 (4)0.038 (5)0.080 (7)0.001 (4)0.006 (4)0.003 (5)
C210.027 (4)0.052 (5)0.061 (6)0.007 (4)0.012 (4)0.003 (5)
C220.056 (5)0.055 (6)0.042 (5)0.007 (5)0.004 (4)0.013 (5)
C230.074 (8)0.057 (6)0.037 (7)0.008 (5)0.016 (7)0.011 (4)
C240.060 (7)0.042 (5)0.071 (8)0.010 (5)0.016 (6)0.003 (5)
C250.038 (4)0.026 (4)0.060 (5)0.005 (3)0.003 (5)0.002 (4)
C260.031 (4)0.029 (4)0.035 (5)0.003 (3)0.002 (3)0.004 (4)
C270.037 (4)0.025 (4)0.042 (5)0.004 (3)0.011 (4)0.003 (4)
C280.039 (4)0.037 (5)0.039 (5)0.010 (4)0.006 (4)0.002 (4)
C290.053 (5)0.050 (5)0.048 (6)0.009 (4)0.014 (4)0.005 (4)
C300.078 (7)0.050 (5)0.034 (5)0.013 (5)0.003 (5)0.001 (4)
C310.057 (5)0.041 (5)0.047 (6)0.003 (4)0.013 (4)0.005 (4)
C320.034 (4)0.052 (6)0.069 (6)0.002 (4)0.002 (4)0.003 (5)
C330.045 (5)0.055 (6)0.068 (7)0.006 (4)0.020 (5)0.014 (5)
Geometric parameters (Å, º) top
Zn1—O11.985 (5)C10—H100.9300
Zn1—N32.061 (6)C11—C121.355 (13)
Zn1—N22.087 (6)C11—H110.9300
Zn1—Cl12.218 (3)C12—C131.386 (13)
Zn1—O22.414 (5)C12—H120.9300
Zn2—O31.944 (5)C13—C141.400 (8)
Zn2—N52.067 (6)C13—C201.432 (10)
Zn2—N42.101 (6)C14—C151.426 (10)
Zn2—Cl22.206 (3)C15—C161.407 (9)
Zn2—O42.627 (5)C16—C171.412 (9)
N1—C51.340 (10)C16—C211.447 (10)
N1—C11.346 (10)C17—C181.374 (10)
N2—C101.320 (9)C17—H170.9300
N2—C141.365 (8)C18—C191.395 (10)
N3—C191.313 (9)C18—H180.9300
N3—C151.350 (8)C19—H190.9300
N4—C221.310 (9)C20—C211.331 (11)
N4—C261.360 (8)C20—H200.9300
N5—C311.308 (9)C21—H210.9300
N5—C271.356 (8)C22—C231.390 (11)
O1—C71.274 (9)C22—H220.9300
O2—C71.243 (8)C23—C241.351 (13)
O3—C81.275 (10)C23—H230.9300
O4—C81.223 (9)C24—C251.414 (13)
C1—C21.398 (11)C24—H240.9300
C1—C61.479 (10)C25—C261.411 (8)
C2—C31.384 (10)C25—C321.415 (10)
C2—C71.496 (10)C26—C271.425 (10)
C3—C41.388 (10)C27—C281.406 (9)
C3—H30.9300C28—C291.390 (10)
C4—C51.385 (10)C28—C331.437 (11)
C4—C81.535 (11)C29—C301.371 (11)
C5—C91.533 (10)C29—H290.9300
C6—H6A0.9600C30—C311.408 (11)
C6—H6B0.9600C30—H300.9300
C6—H6C0.9600C31—H310.9300
C9—H9A0.9600C32—C331.335 (11)
C9—H9B0.9600C32—H320.9300
C9—H9C0.9600C33—H330.9300
C10—C111.403 (10)
O1—Zn1—N3114.6 (2)N2—C10—H10118.5
O1—Zn1—N2100.6 (2)C11—C10—H10118.5
N3—Zn1—N280.1 (2)C12—C11—C10119.1 (10)
O1—Zn1—Cl1126.00 (17)C12—C11—H11120.5
N3—Zn1—Cl1117.22 (18)C10—C11—H11120.5
N2—Zn1—Cl1101.96 (17)C11—C12—C13120.1 (8)
O1—Zn1—O258.87 (19)C11—C12—H12119.9
N3—Zn1—O294.6 (2)C13—C12—H12119.9
N2—Zn1—O2154.6 (2)C12—C13—C14117.4 (7)
Cl1—Zn1—O2102.47 (15)C12—C13—C20124.5 (7)
O3—Zn2—N5117.2 (2)C14—C13—C20118.0 (7)
O3—Zn2—N4104.1 (2)N2—C14—C13123.0 (7)
N5—Zn2—N480.6 (2)N2—C14—C15115.5 (6)
O3—Zn2—Cl2123.35 (19)C13—C14—C15121.5 (7)
N5—Zn2—Cl2115.29 (17)N3—C15—C16122.8 (7)
N4—Zn2—Cl2103.88 (18)N3—C15—C14119.0 (6)
O3—Zn2—O455.32 (19)C16—C15—C14118.2 (6)
N5—Zn2—O491.0 (2)C15—C16—C17117.2 (7)
N4—Zn2—O4150.9 (2)C15—C16—C21119.8 (7)
Cl2—Zn2—O4104.91 (15)C17—C16—C21123.1 (7)
C5—N1—C1120.2 (5)C18—C17—C16118.8 (7)
C10—N2—C14117.3 (6)C18—C17—H17120.6
C10—N2—Zn1129.8 (5)C16—C17—H17120.6
C14—N2—Zn1112.8 (4)C17—C18—C19119.7 (8)
C19—N3—C15118.9 (6)C17—C18—H18120.1
C19—N3—Zn1128.7 (5)C19—C18—H18120.1
C15—N3—Zn1112.4 (5)N3—C19—C18122.7 (7)
C22—N4—C26119.4 (6)N3—C19—H19118.7
C22—N4—Zn2130.0 (5)C18—C19—H19118.7
C26—N4—Zn2110.5 (5)C21—C20—C13122.1 (7)
C31—N5—C27118.1 (7)C21—C20—H20118.9
C31—N5—Zn2128.9 (5)C13—C20—H20118.9
C27—N5—Zn2112.6 (5)C20—C21—C16120.3 (7)
C7—O1—Zn199.3 (4)C20—C21—H21119.8
C7—O2—Zn180.5 (5)C16—C21—H21119.8
C8—O3—Zn2105.6 (5)N4—C22—C23123.2 (8)
C8—O4—Zn275.0 (5)N4—C22—H22118.4
N1—C1—C2121.3 (6)C23—C22—H22118.4
N1—C1—C6114.3 (7)C24—C23—C22118.6 (10)
C2—C1—C6124.3 (6)C24—C23—H23120.7
C3—C2—C1117.3 (6)C22—C23—H23120.7
C3—C2—C7117.6 (7)C23—C24—C25120.7 (9)
C1—C2—C7125.1 (6)C23—C24—H24119.7
C2—C3—C4121.9 (6)C25—C24—H24119.7
C2—C3—H3119.1C26—C25—C24116.7 (8)
C4—C3—H3119.1C26—C25—C32119.1 (8)
C5—C4—C3116.8 (6)C24—C25—C32124.2 (7)
C5—C4—C8125.1 (6)N4—C26—C25121.3 (7)
C3—C4—C8118.1 (7)N4—C26—C27118.8 (6)
N1—C5—C4122.4 (6)C25—C26—C27119.9 (7)
N1—C5—C9114.1 (7)N5—C27—C28123.2 (7)
C4—C5—C9123.4 (6)N5—C27—C26117.0 (7)
C1—C6—H6A109.5C28—C27—C26119.8 (7)
C1—C6—H6B109.5C29—C28—C27116.4 (7)
H6A—C6—H6B109.5C29—C28—C33125.4 (8)
C1—C6—H6C109.5C27—C28—C33118.2 (8)
H6A—C6—H6C109.5C30—C29—C28121.1 (8)
H6B—C6—H6C109.5C30—C29—H29119.5
O2—C7—O1121.3 (7)C28—C29—H29119.5
O2—C7—C2120.3 (7)C29—C30—C31117.7 (8)
O1—C7—C2118.3 (7)C29—C30—H30121.2
O4—C8—O3124.1 (8)C31—C30—H30121.2
O4—C8—C4119.6 (8)N5—C31—C30123.5 (7)
O3—C8—C4116.3 (7)N5—C31—H31118.3
C5—C9—H9A109.5C30—C31—H31118.3
C5—C9—H9B109.5C33—C32—C25121.2 (7)
H9A—C9—H9B109.5C33—C32—H32119.4
C5—C9—H9C109.5C25—C32—H32119.4
H9A—C9—H9C109.5C32—C33—C28121.9 (8)
H9B—C9—H9C109.5C32—C33—H33119.1
N2—C10—C11123.1 (8)C28—C33—H33119.1
O1—Zn1—N2—C1066.7 (6)C3—C4—C8—O430.8 (13)
N3—Zn1—N2—C10179.9 (7)C5—C4—C8—O333.1 (12)
Cl1—Zn1—N2—C1063.9 (6)C3—C4—C8—O3147.0 (8)
O2—Zn1—N2—C10100.3 (7)C14—N2—C10—C110.9 (11)
O1—Zn1—N2—C14116.2 (4)Zn1—N2—C10—C11177.9 (6)
N3—Zn1—N2—C142.7 (4)N2—C10—C11—C121.4 (12)
Cl1—Zn1—N2—C14113.2 (4)C10—C11—C12—C131.3 (12)
O2—Zn1—N2—C1482.6 (6)C11—C12—C13—C140.8 (11)
O1—Zn1—N3—C1982.2 (6)C11—C12—C13—C20179.8 (7)
N2—Zn1—N3—C19179.4 (6)C10—N2—C14—C130.3 (10)
Cl1—Zn1—N3—C1982.2 (6)Zn1—N2—C14—C13177.8 (5)
O2—Zn1—N3—C1924.4 (6)C10—N2—C14—C15179.7 (6)
O1—Zn1—N3—C15100.1 (5)Zn1—N2—C14—C152.1 (7)
N2—Zn1—N3—C152.9 (4)C12—C13—C14—N20.2 (10)
Cl1—Zn1—N3—C1595.5 (5)C20—C13—C14—N2179.4 (6)
O2—Zn1—N3—C15157.9 (4)C12—C13—C14—C15179.7 (6)
O3—Zn2—N4—C2263.0 (7)C20—C13—C14—C150.6 (10)
N5—Zn2—N4—C22178.9 (7)C19—N3—C15—C160.5 (10)
Cl2—Zn2—N4—C2267.2 (7)Zn1—N3—C15—C16177.5 (5)
O4—Zn2—N4—C22104.0 (7)C19—N3—C15—C14179.3 (6)
O3—Zn2—N4—C26121.2 (5)Zn1—N3—C15—C142.7 (8)
N5—Zn2—N4—C265.3 (5)N2—C14—C15—N30.4 (9)
Cl2—Zn2—N4—C26108.6 (4)C13—C14—C15—N3179.7 (6)
O4—Zn2—N4—C2680.1 (6)N2—C14—C15—C16179.8 (6)
O3—Zn2—N5—C3179.4 (7)C13—C14—C15—C160.1 (10)
N4—Zn2—N5—C31179.5 (7)N3—C15—C16—C170.0 (10)
Cl2—Zn2—N5—C3178.5 (6)C14—C15—C16—C17179.7 (6)
O4—Zn2—N5—C3128.5 (6)N3—C15—C16—C21179.7 (6)
O3—Zn2—N5—C27107.4 (5)C14—C15—C16—C210.5 (10)
N4—Zn2—N5—C276.3 (4)C15—C16—C17—C180.4 (10)
Cl2—Zn2—N5—C2794.7 (5)C21—C16—C17—C18179.8 (7)
O4—Zn2—N5—C27158.3 (5)C16—C17—C18—C190.4 (12)
N3—Zn1—O1—C780.8 (5)C15—N3—C19—C180.5 (11)
N2—Zn1—O1—C7164.7 (5)Zn1—N3—C19—C18177.1 (6)
Cl1—Zn1—O1—C781.9 (5)C17—C18—C19—N30.1 (12)
O2—Zn1—O1—C70.8 (4)C12—C13—C20—C21179.4 (8)
O1—Zn1—O2—C70.8 (5)C14—C13—C20—C210.4 (11)
N3—Zn1—O2—C7116.9 (5)C13—C20—C21—C160.2 (12)
N2—Zn1—O2—C740.3 (7)C15—C16—C21—C200.7 (11)
Cl1—Zn1—O2—C7123.9 (5)C17—C16—C21—C20179.6 (7)
N5—Zn2—O3—C869.9 (6)C26—N4—C22—C233.4 (12)
N4—Zn2—O3—C8156.5 (6)Zn2—N4—C22—C23172.1 (6)
Cl2—Zn2—O3—C886.0 (6)N4—C22—C23—C244.3 (14)
O4—Zn2—O3—C80.7 (5)C22—C23—C24—C252.4 (13)
O3—Zn2—O4—C80.7 (6)C23—C24—C25—C260.0 (12)
N5—Zn2—O4—C8122.3 (6)C23—C24—C25—C32179.1 (8)
N4—Zn2—O4—C850.0 (7)C22—N4—C26—C250.7 (10)
Cl2—Zn2—O4—C8121.2 (6)Zn2—N4—C26—C25175.6 (5)
C5—N1—C1—C20.0 (14)C22—N4—C26—C27180.0 (7)
C5—N1—C1—C6176.9 (8)Zn2—N4—C26—C273.7 (8)
N1—C1—C2—C32.2 (10)C24—C25—C26—N41.0 (10)
C6—C1—C2—C3174.4 (10)C32—C25—C26—N4179.9 (7)
N1—C1—C2—C7175.6 (10)C24—C25—C26—C27178.3 (7)
C6—C1—C2—C77.8 (11)C32—C25—C26—C270.8 (10)
C1—C2—C3—C41.1 (14)C31—N5—C27—C280.9 (10)
C7—C2—C3—C4176.9 (7)Zn2—N5—C27—C28174.9 (6)
C2—C3—C4—C52.0 (14)C31—N5—C27—C26179.7 (7)
C2—C3—C4—C8178.0 (8)Zn2—N5—C27—C266.3 (8)
C1—N1—C5—C43.5 (14)N4—C26—C27—N51.7 (10)
C1—N1—C5—C9178.0 (7)C25—C26—C27—N5179.0 (6)
C3—C4—C5—N14.4 (9)N4—C26—C27—C28179.5 (6)
C8—C4—C5—N1175.7 (10)C25—C26—C27—C280.1 (10)
C3—C4—C5—C9177.2 (9)N5—C27—C28—C291.7 (11)
C8—C4—C5—C92.7 (10)C26—C27—C28—C29179.5 (6)
Zn1—O2—C7—O11.3 (7)N5—C27—C28—C33178.8 (6)
Zn1—O2—C7—C2175.5 (8)C26—C27—C28—C330.1 (11)
Zn1—O1—C7—O21.6 (9)C27—C28—C29—C302.4 (11)
Zn1—O1—C7—C2175.3 (6)C33—C28—C29—C30178.3 (8)
C3—C2—C7—O224.0 (12)C28—C29—C30—C312.1 (11)
C1—C2—C7—O2158.3 (7)C27—N5—C31—C300.6 (11)
C3—C2—C7—O1152.9 (8)Zn2—N5—C31—C30173.5 (5)
C1—C2—C7—O124.9 (12)C29—C30—C31—N51.3 (12)
Zn2—O4—C8—O31.1 (8)C26—C25—C32—C331.6 (12)
Zn2—O4—C8—C4178.7 (9)C24—C25—C32—C33177.5 (8)
Zn2—O3—C8—O41.4 (11)C25—C32—C33—C281.6 (13)
Zn2—O3—C8—C4179.2 (6)C29—C28—C33—C32179.8 (8)
C5—C4—C8—O4149.1 (8)C27—C28—C33—C320.8 (12)
 

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