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In the title compound, [Cd(C24H27N7)](ClO4)2, the Cd2+ ion is coordinated by six N atoms from the tripodal organic ligand in the form of a trigonal anti­prism.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806056261/sa2029sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806056261/sa2029Isup2.hkl
Contains datablock I

CCDC reference: 636791

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.036
  • wR factor = 0.113
  • Data-to-parameter ratio = 15.3

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 2.23 PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT142_ALERT_4_C su on b - Axis Small or Missing (x 100000) ..... 10 Ang.
Alert level G PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature . 293 K
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 2 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT-Plus (Bruker, 1998); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

{Tris[2-(2-pyridylmethyleneamino-κ2N,N')ethyl]amine}cadmium(II) bis(perchlorate) top
Crystal data top
[Cd(C24H27N7)](ClO4)2F(000) = 2928
Mr = 724.83Dx = 1.614 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
a = 28.4372 (3) ÅCell parameters from 44848 reflections
b = 10.8977 (1) Åθ = 1.5–28.4°
c = 19.6203 (2) ŵ = 0.97 mm1
β = 101.140 (1)°T = 293 K
V = 5965.77 (10) Å3Prism, yellow
Z = 80.30 × 0.20 × 0.20 mm
Data collection top
Bruker SMART 1K CCD
diffractometer
5866 independent reflections
Radiation source: fine-focus sealed tube4911 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.028
φ and ω scansθmax = 26.0°, θmin = 1.5°
Absorption correction: multi-scan
(SADABS; Sheldrick, 2002)
h = 3434
Tmin = 0.760, Tmax = 0.830k = 1313
66248 measured reflectionsl = 2424
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.036H-atom parameters constrained
wR(F2) = 0.113 w = 1/[σ2(Fo2) + (0.0656P)2 + 9.6103P]
where P = (Fo2 + 2Fc2)/3
S = 1.02(Δ/σ)max = 0.001
5866 reflectionsΔρmax = 1.05 e Å3
384 parametersΔρmin = 0.47 e Å3
0 restraintsExtinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methodsExtinction coefficient: 0.00032 (7)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Cd10.135523 (8)0.17651 (2)0.231879 (12)0.05316 (12)
N10.08713 (12)0.2007 (3)0.09207 (16)0.0682 (8)
N20.10936 (12)0.3723 (3)0.20165 (17)0.0666 (8)
N30.10991 (11)0.2765 (3)0.32978 (17)0.0674 (8)
N40.17905 (12)0.1054 (3)0.15214 (16)0.0684 (8)
N50.21878 (11)0.2077 (3)0.27679 (18)0.0663 (8)
N60.06456 (10)0.0673 (3)0.20539 (14)0.0574 (7)
N70.14175 (10)0.0127 (3)0.30027 (14)0.0557 (6)
C10.07342 (19)0.3314 (4)0.0827 (3)0.0849 (13)
H1A0.04140.34230.09200.102*
H1B0.07280.35490.03490.102*
C20.10748 (18)0.4130 (4)0.1299 (2)0.0844 (12)
H2A0.13910.40820.11850.101*
H2B0.09670.49750.12460.101*
C30.08982 (15)0.4322 (4)0.2431 (2)0.0763 (11)
H30.07620.50810.22950.092*
C40.08788 (14)0.3855 (4)0.3125 (2)0.0703 (10)
C50.06428 (16)0.4473 (5)0.3569 (3)0.0885 (14)
H50.04910.52150.34350.106*
C60.06322 (19)0.3987 (6)0.4213 (3)0.0990 (17)
H60.04710.43920.45160.119*
C70.08577 (18)0.2919 (6)0.4397 (2)0.0913 (15)
H70.08610.25830.48340.110*
C80.10862 (16)0.2320 (5)0.3922 (2)0.0816 (12)
H80.12360.15740.40500.098*
C90.12135 (19)0.1646 (4)0.0494 (2)0.0835 (13)
H9A0.14040.23520.04170.100*
H9B0.10420.13650.00460.100*
C100.15447 (17)0.0624 (5)0.0840 (2)0.0838 (12)
H10A0.13590.01050.08910.101*
H10B0.17770.04190.05560.101*
C110.22319 (16)0.1103 (4)0.1683 (2)0.0812 (12)
H110.24160.08190.13730.097*
C120.24722 (15)0.1604 (4)0.2362 (3)0.0746 (11)
C130.29665 (18)0.1597 (6)0.2572 (4)0.1070 (19)
H130.31600.12600.22890.128*
C140.3164 (2)0.2090 (6)0.3201 (4)0.122 (2)
H140.34950.21020.33470.147*
C150.2871 (2)0.2574 (5)0.3623 (3)0.1097 (19)
H150.30010.29070.40550.132*
C160.23849 (16)0.2547 (4)0.3384 (2)0.0813 (12)
H160.21850.28690.36630.098*
C170.04555 (15)0.1195 (4)0.0834 (2)0.0753 (11)
H17A0.05460.03870.06980.090*
H17B0.02080.15080.04650.090*
C180.02572 (14)0.1089 (4)0.1494 (2)0.0733 (10)
H18A0.01370.18790.16120.088*
H18B0.00050.05060.14290.088*
C190.06223 (12)0.0354 (3)0.23402 (16)0.0563 (8)
H190.03480.08300.22140.068*
C200.10201 (12)0.0813 (3)0.28701 (15)0.0521 (7)
C210.09784 (15)0.1907 (3)0.32072 (19)0.0656 (9)
H210.07000.23740.30970.079*
C220.13565 (16)0.2295 (4)0.37114 (19)0.0755 (11)
H220.13350.30230.39510.091*
C230.17613 (17)0.1601 (4)0.3854 (2)0.0740 (11)
H230.20200.18440.41930.089*
C240.17823 (14)0.0533 (4)0.34878 (19)0.0672 (9)
H240.20620.00710.35810.081*
Cl10.02407 (3)0.72427 (9)0.10928 (4)0.0645 (2)
O10.01584 (14)0.6230 (3)0.06281 (18)0.1061 (11)
O20.01174 (14)0.8141 (4)0.0905 (2)0.1129 (13)
O30.06875 (12)0.7784 (4)0.1072 (2)0.1192 (13)
O40.02221 (18)0.6850 (3)0.17787 (17)0.1150 (14)
Cl20.20737 (4)0.50163 (11)0.48813 (6)0.0853 (3)
O50.18870 (17)0.4950 (5)0.4147 (2)0.1374 (15)
O60.2513 (2)0.4376 (6)0.5043 (3)0.175 (2)
O70.2207 (3)0.6205 (6)0.4989 (5)0.253 (5)
O80.1750 (3)0.4689 (11)0.5213 (4)0.283 (5)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cd10.05070 (17)0.05560 (17)0.05454 (17)0.00379 (10)0.01355 (11)0.00087 (10)
N10.074 (2)0.072 (2)0.0556 (16)0.0085 (16)0.0067 (15)0.0132 (14)
N20.0678 (19)0.0576 (17)0.075 (2)0.0033 (15)0.0150 (16)0.0065 (16)
N30.0658 (18)0.0721 (19)0.0672 (19)0.0003 (16)0.0198 (15)0.0134 (16)
N40.068 (2)0.077 (2)0.0642 (18)0.0140 (16)0.0228 (15)0.0037 (15)
N50.0540 (17)0.0682 (18)0.076 (2)0.0056 (14)0.0116 (15)0.0058 (16)
N60.0482 (14)0.0705 (18)0.0515 (14)0.0038 (13)0.0049 (11)0.0049 (14)
N70.0565 (15)0.0574 (16)0.0514 (14)0.0022 (13)0.0058 (12)0.0033 (12)
C10.093 (3)0.078 (3)0.079 (3)0.013 (2)0.003 (2)0.026 (2)
C20.094 (3)0.068 (2)0.091 (3)0.009 (2)0.019 (2)0.024 (2)
C30.070 (2)0.056 (2)0.104 (3)0.0054 (18)0.019 (2)0.002 (2)
C40.060 (2)0.064 (2)0.088 (3)0.0067 (18)0.0189 (19)0.023 (2)
C50.072 (3)0.081 (3)0.118 (4)0.006 (2)0.035 (3)0.040 (3)
C60.086 (3)0.115 (4)0.106 (4)0.025 (3)0.042 (3)0.054 (3)
C70.092 (3)0.118 (4)0.071 (3)0.024 (3)0.032 (2)0.030 (3)
C80.085 (3)0.099 (3)0.064 (2)0.009 (2)0.022 (2)0.017 (2)
C90.103 (3)0.098 (3)0.051 (2)0.005 (2)0.017 (2)0.006 (2)
C100.089 (3)0.105 (3)0.061 (2)0.013 (3)0.024 (2)0.012 (2)
C110.071 (3)0.097 (3)0.082 (3)0.018 (2)0.032 (2)0.007 (2)
C120.053 (2)0.078 (3)0.094 (3)0.0036 (18)0.019 (2)0.022 (2)
C130.055 (3)0.123 (4)0.144 (5)0.009 (3)0.023 (3)0.034 (4)
C140.059 (3)0.125 (5)0.167 (7)0.015 (3)0.017 (4)0.045 (5)
C150.094 (4)0.091 (4)0.126 (5)0.030 (3)0.024 (3)0.025 (3)
C160.076 (3)0.073 (3)0.089 (3)0.016 (2)0.002 (2)0.001 (2)
C170.074 (2)0.085 (3)0.058 (2)0.003 (2)0.0084 (18)0.010 (2)
C180.057 (2)0.084 (3)0.072 (2)0.0043 (19)0.0050 (17)0.012 (2)
C190.0506 (17)0.070 (2)0.0500 (17)0.0032 (15)0.0136 (14)0.0008 (16)
C200.0568 (18)0.0597 (19)0.0414 (15)0.0011 (15)0.0132 (13)0.0013 (14)
C210.076 (2)0.069 (2)0.0530 (19)0.0139 (18)0.0152 (17)0.0054 (16)
C220.100 (3)0.069 (2)0.055 (2)0.001 (2)0.011 (2)0.0165 (18)
C230.088 (3)0.073 (2)0.054 (2)0.007 (2)0.0033 (19)0.0073 (17)
C240.067 (2)0.068 (2)0.060 (2)0.0027 (18)0.0025 (17)0.0050 (17)
Cl10.0633 (5)0.0739 (5)0.0529 (4)0.0041 (4)0.0026 (4)0.0025 (4)
O10.128 (3)0.102 (2)0.083 (2)0.018 (2)0.008 (2)0.0288 (19)
O20.091 (2)0.142 (3)0.102 (3)0.039 (2)0.009 (2)0.018 (2)
O30.072 (2)0.153 (3)0.137 (3)0.022 (2)0.031 (2)0.041 (3)
O40.185 (4)0.093 (2)0.0591 (18)0.002 (2)0.003 (2)0.0148 (15)
Cl20.0879 (7)0.0834 (7)0.0866 (7)0.0051 (6)0.0221 (6)0.0142 (6)
O50.132 (3)0.176 (4)0.102 (3)0.002 (3)0.017 (2)0.005 (3)
O60.162 (5)0.201 (6)0.152 (4)0.064 (5)0.010 (3)0.010 (4)
O70.261 (8)0.121 (4)0.305 (9)0.035 (5)0.128 (7)0.010 (5)
O80.221 (8)0.472 (15)0.189 (6)0.073 (9)0.124 (6)0.013 (8)
Geometric parameters (Å, º) top
Cd1—N22.300 (3)C9—C101.530 (6)
Cd1—N42.308 (3)C9—H9A0.9700
Cd1—N62.314 (3)C9—H9B0.9700
Cd1—N52.386 (3)C10—H10A0.9700
Cd1—N32.439 (3)C10—H10B0.9700
Cd1—N72.448 (3)C11—C121.479 (7)
N1—C91.455 (6)C11—H110.9300
N1—C171.460 (5)C12—C131.386 (7)
N1—C11.479 (5)C13—C141.363 (10)
N2—C31.253 (5)C13—H130.9300
N2—C21.466 (5)C14—C151.387 (10)
N2—N32.719 (5)C14—H140.9300
N3—C81.324 (5)C15—C161.372 (7)
N3—C41.355 (5)C15—H150.9300
N4—C111.235 (5)C16—H160.9300
N4—C101.461 (5)C17—C181.512 (6)
N4—N52.726 (5)C17—H17A0.9700
N5—C161.333 (5)C17—H17B0.9700
N5—C121.342 (6)C18—H18A0.9700
N6—C191.259 (4)C18—H18B0.9700
N6—C181.472 (4)C19—C201.469 (5)
N6—N72.732 (4)C19—H190.9300
N7—C201.338 (4)C20—C211.379 (5)
N7—C241.340 (4)C21—C221.379 (6)
C1—C21.497 (7)C21—H210.9300
C1—H1A0.9700C22—C231.361 (6)
C1—H1B0.9700C22—H220.9300
C2—H2A0.9700C23—C241.374 (5)
C2—H2B0.9700C23—H230.9300
C3—C41.465 (6)C24—H240.9300
C3—H30.9300Cl1—O31.409 (4)
C4—C51.374 (6)Cl1—O21.410 (3)
C5—C61.375 (8)Cl1—O11.422 (3)
C5—H50.9300Cl1—O41.423 (3)
C6—C71.345 (8)Cl2—O81.277 (6)
C6—H60.9300Cl2—O71.355 (6)
C7—C81.397 (6)Cl2—O61.413 (5)
C7—H70.9300Cl2—O51.438 (4)
C8—H80.9300
N2—Cd1—N4109.00 (12)C6—C7—C8118.9 (5)
N2—Cd1—N6101.24 (11)C6—C7—H7120.5
N4—Cd1—N6103.52 (11)C8—C7—H7120.5
N2—Cd1—N5102.21 (11)N3—C8—C7123.1 (5)
N4—Cd1—N570.99 (12)N3—C8—H8118.5
N6—Cd1—N5156.41 (11)C7—C8—H8118.5
N2—Cd1—N369.97 (12)N1—C9—C10111.3 (3)
N4—Cd1—N3164.70 (12)N1—C9—H9A109.4
N6—Cd1—N391.53 (10)C10—C9—H9A109.4
N5—Cd1—N394.10 (11)N1—C9—H9B109.4
N2—Cd1—N7155.31 (11)C10—C9—H9B109.4
N4—Cd1—N795.59 (11)H9A—C9—H9B108.0
N6—Cd1—N769.95 (9)N4—C10—C9108.5 (4)
N5—Cd1—N787.48 (10)N4—C10—H10A110.0
N3—Cd1—N786.90 (11)C9—C10—H10A110.0
C9—N1—C17112.7 (4)N4—C10—H10B110.0
C9—N1—C1112.2 (4)C9—C10—H10B110.0
C17—N1—C1112.4 (4)H10A—C10—H10B108.4
C3—N2—C2121.8 (4)N4—C11—C12121.2 (4)
C3—N2—Cd1118.5 (3)N4—C11—H11119.4
C2—N2—Cd1118.5 (3)C12—C11—H11119.4
C3—N2—N361.6 (3)N5—C12—C13121.2 (5)
C2—N2—N3174.7 (3)N5—C12—C11116.7 (4)
Cd1—N2—N357.42 (10)C13—C12—C11122.1 (5)
C8—N3—C4117.3 (4)C14—C13—C12119.0 (6)
C8—N3—Cd1129.1 (3)C14—C13—H13120.5
C4—N3—Cd1112.9 (3)C12—C13—H13120.5
C8—N3—N2177.8 (3)C13—C14—C15120.0 (5)
C4—N3—N260.8 (2)C13—C14—H14120.0
Cd1—N3—N252.61 (9)C15—C14—H14120.0
C11—N4—C10122.1 (4)C16—C15—C14118.0 (6)
C11—N4—Cd1117.6 (3)C16—C15—H15121.0
C10—N4—Cd1120.2 (3)C14—C15—H15121.0
C11—N4—N561.8 (3)N5—C16—C15122.5 (5)
C10—N4—N5173.8 (3)N5—C16—H16118.7
Cd1—N4—N555.83 (10)C15—C16—H16118.7
C16—N5—C12119.3 (4)N1—C17—C18112.0 (3)
C16—N5—Cd1127.1 (3)N1—C17—H17A109.2
C12—N5—Cd1113.3 (3)C18—C17—H17A109.2
C16—N5—N4178.5 (3)N1—C17—H17B109.2
C12—N5—N460.3 (2)C18—C17—H17B109.2
Cd1—N5—N453.17 (9)H17A—C17—H17B107.9
C19—N6—C18120.7 (3)N6—C18—C17108.2 (3)
C19—N6—Cd1118.4 (2)N6—C18—H18A110.1
C18—N6—Cd1120.3 (2)C17—C18—H18A110.1
C19—N6—N761.1 (2)N6—C18—H18B110.1
C18—N6—N7174.7 (2)C17—C18—H18B110.1
Cd1—N6—N757.33 (8)H18A—C18—H18B108.4
C20—N7—C24117.6 (3)N6—C19—C20121.2 (3)
C20—N7—Cd1113.3 (2)N6—C19—H19119.4
C24—N7—Cd1129.1 (2)C20—C19—H19119.4
C20—N7—N660.56 (18)N7—C20—C21122.5 (3)
C24—N7—N6177.3 (3)N7—C20—C19117.0 (3)
Cd1—N7—N652.72 (8)C21—C20—C19120.5 (3)
N1—C1—C2111.8 (4)C20—C21—C22118.8 (4)
N1—C1—H1A109.2C20—C21—H21120.6
C2—C1—H1A109.2C22—C21—H21120.6
N1—C1—H1B109.2C23—C22—C21119.2 (4)
C2—C1—H1B109.2C23—C22—H22120.4
H1A—C1—H1B107.9C21—C22—H22120.4
N2—C2—C1108.3 (4)C22—C23—C24119.0 (4)
N2—C2—H2A110.0C22—C23—H23120.5
C1—C2—H2A110.0C24—C23—H23120.5
N2—C2—H2B110.0N7—C24—C23123.0 (4)
C1—C2—H2B110.0N7—C24—H24118.5
H2A—C2—H2B108.4C23—C24—H24118.5
N2—C3—C4121.6 (4)O3—Cl1—O2108.2 (3)
N2—C3—H3119.2O3—Cl1—O1110.1 (2)
C4—C3—H3119.2O2—Cl1—O1110.5 (2)
N3—C4—C5122.0 (4)O3—Cl1—O4110.6 (3)
N3—C4—C3116.0 (3)O2—Cl1—O4107.4 (3)
C5—C4—C3122.0 (4)O1—Cl1—O4110.0 (2)
C4—C5—C6119.6 (5)O8—Cl2—O7113.2 (7)
C4—C5—H5120.2O8—Cl2—O6116.2 (6)
C6—C5—H5120.2O7—Cl2—O6103.2 (5)
C7—C6—C5119.1 (4)O8—Cl2—O5109.5 (4)
C7—C6—H6120.4O7—Cl2—O5104.0 (4)
C5—C6—H6120.4O6—Cl2—O5109.8 (3)
N4—Cd1—N2—C3171.8 (3)N2—Cd1—N7—C24104.9 (4)
N6—Cd1—N2—C379.5 (3)N4—Cd1—N7—C2480.0 (3)
N5—Cd1—N2—C397.9 (3)N6—Cd1—N7—C24177.6 (3)
N3—Cd1—N2—C38.0 (3)N5—Cd1—N7—C249.4 (3)
N7—Cd1—N2—C313.4 (5)N3—Cd1—N7—C2484.8 (3)
N4—Cd1—N2—C220.1 (3)N2—Cd1—N7—N672.7 (3)
N6—Cd1—N2—C288.6 (3)N4—Cd1—N7—N6102.37 (12)
N5—Cd1—N2—C294.0 (3)N5—Cd1—N7—N6172.99 (12)
N3—Cd1—N2—C2176.1 (3)N3—Cd1—N7—N692.76 (11)
N7—Cd1—N2—C2154.7 (3)C19—N6—N7—C202.1 (3)
N4—Cd1—N2—N3163.80 (12)Cd1—N6—N7—C20179.3 (2)
N6—Cd1—N2—N387.51 (11)C19—N6—N7—Cd1177.2 (2)
N5—Cd1—N2—N389.94 (12)C9—N1—C1—C286.7 (5)
N7—Cd1—N2—N321.4 (3)C17—N1—C1—C2145.0 (4)
N2—Cd1—N3—C8178.2 (4)C3—N2—C2—C1106.6 (5)
N4—Cd1—N3—C892.9 (6)Cd1—N2—C2—C161.1 (4)
N6—Cd1—N3—C876.8 (4)N1—C1—C2—N256.5 (5)
N5—Cd1—N3—C880.2 (4)C2—N2—C3—C4174.1 (4)
N7—Cd1—N3—C87.0 (4)Cd1—N2—C3—C46.5 (5)
N2—Cd1—N3—C48.7 (2)N3—N2—C3—C41.2 (3)
N4—Cd1—N3—C497.6 (5)C8—N3—C4—C51.2 (6)
N6—Cd1—N3—C492.7 (3)Cd1—N3—C4—C5169.7 (3)
N5—Cd1—N3—C4110.2 (3)N2—N3—C4—C5177.6 (4)
N7—Cd1—N3—C4162.5 (3)C8—N3—C4—C3179.8 (4)
N4—Cd1—N3—N288.9 (4)Cd1—N3—C4—C38.9 (4)
N6—Cd1—N3—N2101.41 (11)N2—N3—C4—C31.0 (3)
N5—Cd1—N3—N2101.51 (12)N2—C3—C4—N32.3 (6)
N7—Cd1—N3—N2171.24 (11)N2—C3—C4—C5176.4 (4)
C3—N2—N3—C41.2 (3)N3—C4—C5—C60.8 (6)
Cd1—N2—N3—C4170.8 (3)C3—C4—C5—C6179.4 (4)
C3—N2—N3—Cd1172.0 (3)C4—C5—C6—C70.6 (7)
N2—Cd1—N4—C1199.5 (3)C5—C6—C7—C81.5 (7)
N6—Cd1—N4—C11153.4 (3)C4—N3—C8—C70.1 (6)
N5—Cd1—N4—C112.7 (3)Cd1—N3—C8—C7169.0 (3)
N3—Cd1—N4—C1116.0 (7)C6—C7—C8—N31.2 (7)
N7—Cd1—N4—C1182.7 (3)C17—N1—C9—C1082.3 (4)
N2—Cd1—N4—C1077.6 (3)C1—N1—C9—C10149.6 (4)
N6—Cd1—N4—C1029.6 (3)C11—N4—C10—C9121.7 (5)
N5—Cd1—N4—C10174.3 (3)Cd1—N4—C10—C955.2 (5)
N3—Cd1—N4—C10161.0 (4)N1—C9—C10—N457.6 (5)
N7—Cd1—N4—C10100.3 (3)C10—N4—C11—C12176.7 (4)
N2—Cd1—N4—N596.78 (12)Cd1—N4—C11—C120.3 (6)
N6—Cd1—N4—N5156.08 (11)N5—N4—C11—C122.2 (3)
N3—Cd1—N4—N513.3 (5)C16—N5—C12—C130.0 (6)
N7—Cd1—N4—N585.39 (11)Cd1—N5—C12—C13173.8 (4)
N2—Cd1—N5—C1675.8 (3)N4—N5—C12—C13178.3 (5)
N4—Cd1—N5—C16178.1 (4)C16—N5—C12—C11179.7 (4)
N6—Cd1—N5—C1698.0 (4)Cd1—N5—C12—C116.4 (4)
N3—Cd1—N5—C165.4 (3)N4—N5—C12—C112.0 (3)
N7—Cd1—N5—C1681.3 (3)N4—C11—C12—N54.4 (6)
N2—Cd1—N5—C12111.0 (3)N4—C11—C12—C13175.9 (5)
N4—Cd1—N5—C124.8 (3)N5—C12—C13—C140.6 (8)
N6—Cd1—N5—C1275.3 (4)C11—C12—C13—C14179.1 (5)
N3—Cd1—N5—C12178.7 (3)C12—C13—C14—C150.9 (9)
N7—Cd1—N5—C1292.0 (3)C13—C14—C15—C160.6 (9)
N2—Cd1—N5—N4106.13 (13)C12—N5—C16—C150.3 (6)
N6—Cd1—N5—N480.1 (3)Cd1—N5—C16—C15173.2 (3)
N3—Cd1—N5—N4176.50 (12)C14—C15—C16—N50.0 (8)
N7—Cd1—N5—N496.79 (11)C9—N1—C17—C18148.4 (3)
C11—N4—N5—C122.4 (3)C1—N1—C17—C1883.6 (4)
Cd1—N4—N5—C12174.9 (3)C19—N6—C18—C17115.4 (4)
C11—N4—N5—Cd1177.3 (3)Cd1—N6—C18—C1756.0 (4)
N2—Cd1—N6—C19158.8 (3)N1—C17—C18—N656.1 (5)
N4—Cd1—N6—C1988.3 (3)C18—N6—C19—C20176.2 (3)
N5—Cd1—N6—C1914.9 (4)Cd1—N6—C19—C204.7 (4)
N3—Cd1—N6—C1988.9 (3)N7—N6—C19—C202.0 (2)
N7—Cd1—N6—C192.8 (2)C24—N7—C20—C210.6 (5)
N2—Cd1—N6—C1829.6 (3)Cd1—N7—C20—C21179.0 (3)
N4—Cd1—N6—C1883.3 (3)N6—N7—C20—C21178.5 (4)
N5—Cd1—N6—C18156.7 (3)C24—N7—C20—C19179.7 (3)
N3—Cd1—N6—C1899.5 (3)Cd1—N7—C20—C191.2 (4)
N7—Cd1—N6—C18174.4 (3)N6—N7—C20—C191.8 (2)
N2—Cd1—N6—N7156.01 (11)N6—C19—C20—N74.0 (5)
N4—Cd1—N6—N791.08 (11)N6—C19—C20—C21176.3 (3)
N5—Cd1—N6—N717.7 (3)N7—C20—C21—C221.5 (6)
N3—Cd1—N6—N786.14 (11)C19—C20—C21—C22178.7 (3)
N2—Cd1—N7—C2073.4 (3)C20—C21—C22—C231.0 (6)
N4—Cd1—N7—C20101.7 (2)C21—C22—C23—C240.3 (7)
N6—Cd1—N7—C200.6 (2)C20—N7—C24—C230.8 (6)
N5—Cd1—N7—C20172.3 (2)Cd1—N7—C24—C23177.4 (3)
N3—Cd1—N7—C2093.4 (2)C22—C23—C24—N71.3 (7)
 

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