A dinuclear phosphite rhodium(I) complex obtained by syngas treatment of a Rh/hy­droxy phospho­nite olefin hydro­formyl­ation precatalyst

A hy­droxy phospho­nite was found to be unstable during the catalyst pre­formation routine applied towards a rhodium olefin hydro­formyl­ation catalyst. C—P bond cleavage occurred when the phospho­nite was reacted with [(acac)Rh(1,5-COD)] (acac is acetyl acetate and 1,5-COD is cyclo­octa-1,5-diene) at 80 °C and 20 bar of CO/H₂. As a result, a nearly planar six-membered ring structure consisting of two rhodium(I) cations and two bridging phospho­rous acid diester anions was formed, namely bis­[μ-(4,8-di-tert-butyl-2,10-di­meth­oxy­dibenzo[d,f][1,3,2]di­oxa­phosphepin-6-yl)­oxy]-1:2κ²P:O;1:2κ²O:P-bis­{[6-([1,1′-bi­phen­yl]-2-yl­oxy)-4,8-di-tert-butyl-2,10-di­meth­oxy­dibenzo[d,f][1,3,2]di­oxa­phos­phepine-κP]carbonyl­rho­dium(I)} toluene tetrasolvate, [Rh₂(C₂₂H₂₈O₅P)₂(C₃₄H₃₇O₅P)₂(CO)₂]·4C₇H₈. Further coordination of phosphite and of carbonyl groups resulted in 16-electron rhodium centres.

Computing details

Data collection: APEX2 (Bruker, 2014); cell refinement: SAINT (Bruker, 2013); data reduction: SAINT (Bruker, 2013); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: XP in SHELXTL (Sheldrick, 2008).

Bis[µ-(4,8-di-tert-butyl-2,10-dimethoxydibenzo[d,f]\ [1,3,2]dioxaphosphepin-6-yl)oxy]-1:2κ²P:\ O;\ 1:2κ²O:P-bis{[6-([1,1'-biphenyl]-2-yloxy)-4,8-di-tert-\ butyl-2,10-dimethoxydibenzo[d,f][1,3,2]dioxaphosphepine-\ κP]carbonylrhodium} toluene tatrasolvate

Crystal data

[Rh2(C22H28O5P)2(C34H37O5P)2(CO)2]·4C7H8	F(000) = 2680
Mr = 2550.41	Dx = 1.319 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 13.4100 (5) Å	Cell parameters from 9938 reflections
b = 15.5455 (5) Å	θ = 2.3–30.3°
c = 31.1570 (11) Å	µ = 0.38 mm^−1
β = 98.7430 (14)°	T = 150 K
V = 6419.7 (4) Å^3	Prism, yellow
Z = 2	0.41 × 0.34 × 0.32 mm

Data collection

Bruker APEXII CCD diffractometer	15481 independent reflections
Radiation source: fine-focus sealed tube	13358 reflections with I > 2σ(I)
Detector resolution: 8.3333 pixels mm^-1	Rint = 0.040
φ and ω scans	θmax = 28.0°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Bruker, 2014)	h = −17→17
Tmin = 0.86, Tmax = 0.89	k = −20→20
140325 measured reflections	l = −41→41

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.035	H-atom parameters constrained
wR(F^2) = 0.093	w = 1/[σ^2(Fo^2) + (0.0453P)^2 + 5.3591P] where P = (Fo^2 + 2Fc^2)/3
S = 1.03	(Δ/σ)max = 0.001
15481 reflections	Δρmax = 0.81 e Å^−3
760 parameters	Δρmin = −0.39 e Å^−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	−0.05877 (14)	1.10380 (12)	0.15205 (6)	0.0222 (3)
C2	0.00322 (15)	1.14899 (13)	0.12855 (6)	0.0274 (4)
H2	0.0414	1.1195	0.1098	0.033*
C3	0.00930 (18)	1.23754 (14)	0.13250 (7)	0.0342 (5)
H3	0.0526	1.2690	0.1167	0.041*
C4	−0.04732 (19)	1.28050 (14)	0.15927 (7)	0.0387 (5)
H4	−0.0437	1.3414	0.1618	0.046*
C5	−0.10935 (17)	1.23413 (13)	0.18239 (7)	0.0343 (5)
H5	−0.1486	1.2640	0.2005	0.041*
C6	−0.11587 (14)	1.14461 (12)	0.17978 (6)	0.0255 (4)
C7	−0.17942 (15)	1.09749 (13)	0.20697 (6)	0.0273 (4)
C8	−0.28188 (16)	1.11705 (15)	0.20360 (7)	0.0346 (5)
H8	−0.3115	1.1573	0.1825	0.042*
C9	−0.34058 (17)	1.07785 (17)	0.23096 (8)	0.0427 (6)
H9	−0.4104	1.0913	0.2284	0.051*
C10	−0.29892 (18)	1.01997 (17)	0.26169 (8)	0.0435 (6)
H10	−0.3397	0.9937	0.2804	0.052*
C11	−0.19711 (18)	0.99962 (15)	0.26553 (8)	0.0390 (5)
H11	−0.1681	0.9597	0.2869	0.047*
C12	−0.13792 (16)	1.03784 (14)	0.23793 (7)	0.0307 (4)
H12	−0.0686	1.0231	0.2402	0.037*
C13	−0.03331 (13)	0.84098 (11)	0.19468 (5)	0.0199 (3)
C14	−0.12566 (14)	0.81619 (12)	0.20717 (6)	0.0227 (4)
C15	−0.12299 (14)	0.79805 (13)	0.25087 (6)	0.0263 (4)
H15	−0.1840	0.7824	0.2609	0.032*
C16	−0.03476 (15)	0.80181 (13)	0.28062 (6)	0.0258 (4)
C17	0.05601 (14)	0.81946 (12)	0.26674 (6)	0.0240 (4)
H17	0.1171	0.8184	0.2867	0.029*
C18	0.05714 (13)	0.83903 (11)	0.22290 (6)	0.0208 (3)
C19	0.15755 (13)	0.84937 (12)	0.20853 (5)	0.0212 (3)
C20	0.23197 (14)	0.78886 (13)	0.22332 (6)	0.0252 (4)
H20	0.2171	0.7417	0.2407	0.030*
C21	0.32743 (15)	0.79833 (14)	0.21237 (6)	0.0288 (4)
C22	0.35060 (14)	0.87008 (14)	0.18910 (6)	0.0285 (4)
H22	0.4176	0.8766	0.1832	0.034*
C23	0.28013 (14)	0.93226 (12)	0.17423 (6)	0.0242 (4)
C24	0.18141 (13)	0.91769 (12)	0.18293 (6)	0.0208 (3)
C25	−0.22374 (14)	0.80187 (13)	0.17502 (6)	0.0259 (4)
C26	−0.20636 (17)	0.72748 (15)	0.14487 (8)	0.0385 (5)
H26A	−0.2689	0.7156	0.1251	0.058*
H26B	−0.1860	0.6761	0.1622	0.058*
H26C	−0.1530	0.7431	0.1280	0.058*
C27	−0.25697 (16)	0.88192 (14)	0.14816 (7)	0.0340 (5)
H27A	−0.2625	0.9306	0.1676	0.051*
H27B	−0.3226	0.8712	0.1304	0.051*
H27C	−0.2071	0.8952	0.1292	0.051*
C28	−0.31157 (16)	0.77680 (18)	0.19899 (7)	0.0414 (6)
H28A	−0.3218	0.8221	0.2198	0.062*
H28B	−0.2957	0.7225	0.2145	0.062*
H28C	−0.3732	0.7698	0.1779	0.062*
C29	0.03783 (16)	0.79999 (15)	0.35515 (6)	0.0334 (5)
H29A	0.0934	0.7618	0.3506	0.050*
H29B	0.0190	0.7890	0.3838	0.050*
H29C	0.0593	0.8600	0.3534	0.050*
C30	0.38639 (18)	0.67199 (17)	0.25083 (9)	0.0474 (6)
H30A	0.3739	0.6951	0.2788	0.071*
H30B	0.4455	0.6341	0.2555	0.071*
H30C	0.3273	0.6393	0.2374	0.071*
C31	0.31189 (15)	1.01366 (14)	0.15168 (7)	0.0305 (4)
C32	0.26525 (17)	1.01554 (16)	0.10375 (7)	0.0386 (5)
H32A	0.1917	1.0199	0.1013	0.058*
H32B	0.2829	0.9626	0.0896	0.058*
H32C	0.2913	1.0653	0.0896	0.058*
C33	0.28132 (19)	1.09348 (15)	0.17499 (8)	0.0433 (6)
H33A	0.3148	1.0929	0.2052	0.065*
H33B	0.2080	1.0937	0.1743	0.065*
H33C	0.3016	1.1451	0.1605	0.065*
C34	0.42695 (17)	1.01700 (18)	0.15328 (9)	0.0468 (6)
H34A	0.4459	1.0720	0.1414	0.070*
H34B	0.4484	0.9697	0.1360	0.070*
H34C	0.4600	1.0114	0.1834	0.070*
C35	−0.01994 (13)	0.74019 (11)	−0.00710 (5)	0.0190 (3)
C36	−0.10642 (13)	0.71434 (11)	0.01005 (6)	0.0211 (3)
C37	−0.09665 (14)	0.64049 (12)	0.03547 (6)	0.0242 (4)
H37	−0.1521	0.6226	0.0490	0.029*
C38	−0.00846 (15)	0.59184 (12)	0.04181 (6)	0.0234 (4)
C39	0.07087 (14)	0.61313 (11)	0.02026 (6)	0.0216 (3)
H39	0.1287	0.5772	0.0224	0.026*
C40	0.06490 (13)	0.68827 (11)	−0.00473 (6)	0.0191 (3)
C41	0.14602 (13)	0.70671 (11)	−0.03120 (6)	0.0195 (3)
C42	0.17301 (14)	0.64030 (11)	−0.05760 (6)	0.0222 (3)
H42	0.1406	0.5859	−0.0581	0.027*
C43	0.24729 (14)	0.65520 (12)	−0.08274 (6)	0.0243 (4)
C44	0.29977 (14)	0.73246 (12)	−0.07929 (6)	0.0243 (4)
H44	0.3529	0.7402	−0.0959	0.029*
C45	0.27748 (13)	0.79902 (11)	−0.05244 (6)	0.0202 (3)
C46	0.19454 (13)	0.78558 (11)	−0.03043 (5)	0.0186 (3)
C47	−0.20971 (14)	0.75849 (13)	−0.00268 (6)	0.0255 (4)
C48	−0.23840 (16)	0.75233 (15)	−0.05224 (7)	0.0329 (4)
H48A	−0.3043	0.7795	−0.0611	0.049*
H48B	−0.2418	0.6917	−0.0610	0.049*
H48C	−0.1874	0.7819	−0.0663	0.049*
C49	−0.20901 (16)	0.85279 (14)	0.01137 (8)	0.0351 (5)
H49A	−0.1854	0.8568	0.0426	0.053*
H49B	−0.2774	0.8763	0.0048	0.053*
H49C	−0.1638	0.8856	−0.0044	0.053*
C50	−0.29270 (16)	0.71236 (17)	0.01750 (8)	0.0392 (5)
H50A	−0.2764	0.7144	0.0492	0.059*
H50B	−0.2971	0.6523	0.0079	0.059*
H50C	−0.3575	0.7410	0.0083	0.059*
C51	0.07793 (17)	0.46875 (13)	0.07478 (7)	0.0328 (4)
H51A	0.0858	0.4419	0.0470	0.049*
H51B	0.0699	0.4239	0.0961	0.049*
H51C	0.1379	0.5033	0.0852	0.049*
C52	0.22870 (18)	0.51538 (14)	−0.11391 (8)	0.0390 (5)
H52A	0.2455	0.4870	−0.0857	0.059*
H52B	0.2532	0.4804	−0.1363	0.059*
H52C	0.1553	0.5219	−0.1209	0.059*
C53	0.34312 (14)	0.88047 (12)	−0.04674 (6)	0.0244 (4)
C54	0.43790 (16)	0.87090 (14)	−0.06847 (8)	0.0349 (5)
H54A	0.4765	0.8206	−0.0565	0.052*
H54B	0.4797	0.9226	−0.0630	0.052*
H54C	0.4180	0.8634	−0.0998	0.052*
C55	0.28377 (16)	0.95709 (13)	−0.06802 (8)	0.0367 (5)
H55A	0.2640	0.9457	−0.0991	0.055*
H55B	0.3260	1.0088	−0.0642	0.055*
H55C	0.2232	0.9659	−0.0545	0.055*
C56	0.37997 (18)	0.89737 (17)	0.00145 (7)	0.0413 (5)
H56A	0.3218	0.9059	0.0166	0.062*
H56B	0.4223	0.9490	0.0046	0.062*
H56C	0.4194	0.8480	0.0141	0.062*
C57	0.10115 (15)	0.83262 (12)	0.08053 (6)	0.0259 (4)
C58	0.43179 (16)	0.65168 (12)	0.08541 (7)	0.0611 (8)
C59	0.50365 (15)	0.59332 (16)	0.10454 (7)	0.0776 (11)
H59	0.5499	0.6096	0.1294	0.093*
C60	0.50780 (16)	0.51116 (14)	0.08730 (9)	0.0863 (12)
H60	0.5569	0.4713	0.1004	0.104*
C61	0.4401 (2)	0.48734 (13)	0.05094 (10)	0.0995 (14)
H61	0.4429	0.4312	0.0392	0.119*
C62	0.3682 (2)	0.54570 (17)	0.03182 (8)	0.1091 (16)
H62	0.3219	0.5294	0.0070	0.131*
C63	0.36407 (16)	0.62787 (15)	0.04905 (7)	0.0756 (10)
H63	0.3150	0.6678	0.0360	0.091*
C64	0.4267 (3)	0.7386 (3)	0.10370 (13)	0.0878 (11)
H64A	0.4834	0.7730	0.0968	0.132*
H64B	0.4302	0.7346	0.1353	0.132*
H64C	0.3630	0.7659	0.0912	0.132*
C65	0.21479 (11)	0.53242 (11)	0.17671 (5)	0.0518 (7)
C66	0.17226 (11)	0.60699 (10)	0.15723 (5)	0.0410 (5)
H66	0.2077	0.6395	0.1386	0.049*
C67	0.07787 (11)	0.63405 (9)	0.16505 (5)	0.0401 (5)
H67	0.0488	0.6850	0.1517	0.048*
C68	0.02601 (10)	0.58654 (12)	0.19234 (6)	0.0534 (7)
H68	−0.0385	0.6050	0.1977	0.064*
C69	0.06854 (13)	0.51197 (11)	0.21182 (6)	0.0584 (7)
H69	0.0331	0.4795	0.2305	0.070*
C70	0.16293 (14)	0.48491 (9)	0.20400 (5)	0.0539 (7)
H70	0.1920	0.4339	0.2173	0.065*
C71	0.3155 (3)	0.5033 (3)	0.16757 (13)	0.1101 (18)
H71A	0.3065	0.4573	0.1458	0.165*
H71B	0.3554	0.4818	0.1944	0.165*
H71C	0.3507	0.5518	0.1565	0.165*
O1	−0.07102 (9)	1.01463 (8)	0.14786 (4)	0.0223 (3)
O2	−0.02939 (9)	0.85920 (8)	0.15060 (4)	0.0199 (2)
O3	0.10367 (9)	0.97617 (8)	0.16894 (4)	0.0214 (3)
O4	−0.04594 (11)	0.78438 (11)	0.32282 (4)	0.0363 (4)
O5	0.40458 (11)	0.74111 (11)	0.22297 (5)	0.0396 (4)
O6	−0.01933 (9)	0.81766 (7)	−0.02991 (4)	0.0185 (2)
O7	0.16567 (9)	0.84936 (8)	−0.00312 (4)	0.0191 (2)
O8	0.04755 (9)	0.96021 (8)	−0.04265 (4)	0.0205 (2)
O9	−0.00905 (11)	0.52279 (9)	0.06893 (4)	0.0284 (3)
O10	0.27510 (11)	0.59780 (9)	−0.11224 (5)	0.0327 (3)
O11	0.14861 (13)	0.77373 (10)	0.09226 (5)	0.0397 (4)
P1	0.00872 (3)	0.94829 (3)	0.13333 (2)	0.01749 (9)
P2	0.05519 (3)	0.89371 (3)	−0.00705 (2)	0.01635 (9)
Rh1	0.03018 (2)	0.92806 (2)	0.06248 (2)	0.01662 (4)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.0273 (9)	0.0181 (8)	0.0207 (8)	0.0008 (7)	0.0012 (7)	−0.0029 (7)
C2	0.0380 (10)	0.0240 (9)	0.0208 (9)	0.0007 (8)	0.0062 (8)	−0.0004 (7)
C3	0.0498 (13)	0.0260 (10)	0.0276 (10)	−0.0036 (9)	0.0083 (9)	0.0021 (8)
C4	0.0599 (14)	0.0191 (10)	0.0373 (12)	0.0044 (9)	0.0083 (10)	−0.0023 (8)
C5	0.0452 (12)	0.0241 (10)	0.0346 (11)	0.0081 (9)	0.0091 (9)	−0.0073 (8)
C6	0.0290 (9)	0.0238 (9)	0.0234 (9)	0.0042 (7)	0.0026 (7)	−0.0028 (7)
C7	0.0282 (9)	0.0276 (10)	0.0268 (9)	0.0005 (8)	0.0066 (7)	−0.0116 (8)
C8	0.0303 (10)	0.0392 (12)	0.0338 (11)	0.0049 (9)	0.0029 (8)	−0.0140 (9)
C9	0.0275 (10)	0.0544 (15)	0.0485 (14)	−0.0058 (10)	0.0129 (10)	−0.0218 (12)
C10	0.0444 (13)	0.0458 (14)	0.0459 (13)	−0.0115 (11)	0.0255 (11)	−0.0144 (11)
C11	0.0495 (13)	0.0340 (12)	0.0373 (12)	−0.0015 (10)	0.0187 (10)	−0.0034 (9)
C12	0.0311 (10)	0.0297 (10)	0.0330 (10)	0.0026 (8)	0.0105 (8)	−0.0034 (8)
C13	0.0281 (9)	0.0167 (8)	0.0160 (8)	−0.0020 (7)	0.0071 (6)	0.0013 (6)
C14	0.0258 (9)	0.0206 (9)	0.0222 (9)	−0.0035 (7)	0.0053 (7)	0.0025 (7)
C15	0.0264 (9)	0.0292 (10)	0.0248 (9)	−0.0061 (8)	0.0092 (7)	0.0034 (8)
C16	0.0320 (10)	0.0284 (10)	0.0180 (8)	−0.0057 (8)	0.0070 (7)	0.0036 (7)
C17	0.0257 (9)	0.0264 (9)	0.0195 (8)	−0.0039 (7)	0.0025 (7)	0.0033 (7)
C18	0.0252 (8)	0.0187 (8)	0.0195 (8)	−0.0033 (7)	0.0066 (7)	0.0012 (7)
C19	0.0232 (8)	0.0244 (9)	0.0163 (8)	−0.0026 (7)	0.0036 (6)	−0.0014 (7)
C20	0.0276 (9)	0.0273 (9)	0.0206 (8)	0.0003 (7)	0.0033 (7)	0.0025 (7)
C21	0.0272 (9)	0.0338 (11)	0.0251 (9)	0.0054 (8)	0.0025 (7)	0.0011 (8)
C22	0.0213 (9)	0.0395 (11)	0.0257 (9)	−0.0033 (8)	0.0069 (7)	−0.0007 (8)
C23	0.0258 (9)	0.0291 (10)	0.0187 (8)	−0.0063 (7)	0.0062 (7)	−0.0009 (7)
C24	0.0227 (8)	0.0220 (9)	0.0175 (8)	−0.0011 (7)	0.0028 (6)	−0.0011 (7)
C25	0.0254 (9)	0.0280 (10)	0.0238 (9)	−0.0067 (7)	0.0018 (7)	0.0053 (7)
C26	0.0386 (12)	0.0345 (12)	0.0396 (12)	−0.0088 (9)	−0.0032 (9)	−0.0058 (9)
C27	0.0287 (10)	0.0338 (11)	0.0369 (11)	−0.0045 (8)	−0.0032 (8)	0.0086 (9)
C28	0.0277 (10)	0.0620 (16)	0.0335 (11)	−0.0138 (10)	0.0012 (9)	0.0134 (11)
C29	0.0370 (11)	0.0451 (13)	0.0188 (9)	−0.0089 (9)	0.0061 (8)	0.0027 (8)
C30	0.0368 (12)	0.0439 (14)	0.0575 (16)	0.0082 (10)	−0.0053 (11)	0.0154 (12)
C31	0.0298 (10)	0.0332 (11)	0.0300 (10)	−0.0110 (8)	0.0091 (8)	0.0032 (8)
C32	0.0410 (12)	0.0448 (13)	0.0311 (11)	−0.0114 (10)	0.0087 (9)	0.0110 (10)
C33	0.0486 (14)	0.0325 (12)	0.0502 (14)	−0.0162 (10)	0.0124 (11)	−0.0044 (10)
C34	0.0347 (12)	0.0576 (16)	0.0491 (14)	−0.0167 (11)	0.0098 (10)	0.0127 (12)
C35	0.0253 (8)	0.0135 (8)	0.0185 (8)	−0.0005 (6)	0.0042 (6)	0.0002 (6)
C36	0.0237 (8)	0.0192 (8)	0.0214 (8)	−0.0022 (7)	0.0070 (7)	−0.0036 (7)
C37	0.0278 (9)	0.0226 (9)	0.0240 (9)	−0.0052 (7)	0.0097 (7)	−0.0008 (7)
C38	0.0336 (10)	0.0170 (8)	0.0202 (8)	−0.0058 (7)	0.0065 (7)	0.0000 (7)
C39	0.0267 (9)	0.0167 (8)	0.0224 (8)	0.0005 (7)	0.0069 (7)	−0.0009 (7)
C40	0.0229 (8)	0.0155 (8)	0.0199 (8)	−0.0021 (6)	0.0069 (6)	−0.0013 (6)
C41	0.0224 (8)	0.0172 (8)	0.0202 (8)	0.0032 (6)	0.0076 (6)	0.0020 (6)
C42	0.0253 (9)	0.0159 (8)	0.0264 (9)	0.0021 (7)	0.0074 (7)	−0.0008 (7)
C43	0.0262 (9)	0.0213 (9)	0.0273 (9)	0.0046 (7)	0.0099 (7)	−0.0037 (7)
C44	0.0245 (9)	0.0229 (9)	0.0281 (9)	0.0018 (7)	0.0120 (7)	−0.0004 (7)
C45	0.0212 (8)	0.0178 (8)	0.0224 (8)	0.0016 (6)	0.0059 (7)	0.0023 (7)
C46	0.0216 (8)	0.0156 (8)	0.0193 (8)	0.0047 (6)	0.0054 (6)	0.0002 (6)
C47	0.0204 (8)	0.0285 (10)	0.0284 (9)	−0.0004 (7)	0.0065 (7)	−0.0022 (8)
C48	0.0305 (10)	0.0367 (11)	0.0304 (10)	0.0013 (9)	0.0012 (8)	−0.0026 (9)
C49	0.0263 (10)	0.0329 (11)	0.0461 (12)	0.0057 (8)	0.0054 (9)	−0.0110 (9)
C50	0.0246 (10)	0.0507 (14)	0.0440 (13)	−0.0022 (9)	0.0106 (9)	0.0073 (11)
C51	0.0443 (12)	0.0215 (9)	0.0314 (10)	−0.0001 (8)	0.0025 (9)	0.0083 (8)
C52	0.0471 (13)	0.0257 (10)	0.0499 (13)	−0.0056 (9)	0.0254 (11)	−0.0156 (10)
C53	0.0239 (9)	0.0216 (9)	0.0298 (9)	−0.0032 (7)	0.0109 (7)	−0.0015 (7)
C54	0.0293 (10)	0.0316 (11)	0.0478 (13)	−0.0071 (8)	0.0192 (9)	−0.0056 (9)
C55	0.0340 (11)	0.0213 (10)	0.0574 (14)	−0.0013 (8)	0.0148 (10)	0.0071 (9)
C56	0.0382 (12)	0.0527 (14)	0.0340 (11)	−0.0191 (11)	0.0092 (9)	−0.0092 (10)
C57	0.0363 (10)	0.0252 (9)	0.0173 (8)	0.0042 (8)	0.0074 (7)	0.0004 (7)
C58	0.0578 (17)	0.0594 (18)	0.0649 (19)	−0.0025 (14)	0.0058 (14)	0.0092 (15)
C59	0.0421 (16)	0.085 (3)	0.098 (3)	−0.0023 (16)	−0.0126 (16)	0.024 (2)
C60	0.0446 (17)	0.073 (2)	0.139 (4)	0.0028 (16)	0.007 (2)	0.028 (2)
C61	0.076 (3)	0.097 (3)	0.121 (4)	0.009 (2)	0.001 (2)	−0.003 (3)
C62	0.105 (3)	0.100 (3)	0.109 (4)	0.020 (3)	−0.028 (3)	−0.014 (3)
C63	0.065 (2)	0.081 (2)	0.072 (2)	0.0034 (18)	−0.0186 (17)	0.0108 (19)
C64	0.093 (3)	0.085 (3)	0.082 (3)	0.014 (2)	0.001 (2)	−0.009 (2)
C65	0.0674 (17)	0.0544 (16)	0.0352 (12)	0.0279 (14)	0.0124 (12)	0.0054 (11)
C66	0.0507 (14)	0.0354 (12)	0.0384 (12)	0.0080 (10)	0.0117 (10)	0.0022 (10)
C67	0.0465 (13)	0.0317 (11)	0.0418 (12)	0.0024 (10)	0.0055 (10)	−0.0007 (10)
C68	0.0394 (13)	0.0693 (19)	0.0519 (15)	0.0016 (13)	0.0081 (11)	0.0142 (14)
C69	0.0558 (16)	0.070 (2)	0.0484 (15)	−0.0059 (14)	0.0047 (13)	0.0232 (14)
C70	0.0779 (19)	0.0463 (15)	0.0354 (13)	0.0129 (14)	0.0017 (12)	0.0101 (11)
C71	0.117 (3)	0.141 (4)	0.084 (3)	0.095 (3)	0.052 (2)	0.049 (3)
O1	0.0262 (6)	0.0181 (6)	0.0242 (6)	−0.0010 (5)	0.0086 (5)	−0.0030 (5)
O2	0.0268 (6)	0.0177 (6)	0.0159 (6)	−0.0029 (5)	0.0057 (5)	0.0026 (5)
O3	0.0238 (6)	0.0196 (6)	0.0207 (6)	−0.0029 (5)	0.0033 (5)	0.0006 (5)
O4	0.0340 (8)	0.0580 (10)	0.0177 (6)	−0.0144 (7)	0.0062 (6)	0.0076 (6)
O5	0.0284 (7)	0.0465 (9)	0.0439 (9)	0.0115 (7)	0.0051 (6)	0.0116 (7)
O6	0.0224 (6)	0.0143 (6)	0.0193 (6)	0.0003 (5)	0.0048 (5)	0.0004 (5)
O7	0.0209 (6)	0.0155 (6)	0.0219 (6)	0.0024 (5)	0.0063 (5)	−0.0014 (5)
O8	0.0286 (6)	0.0151 (6)	0.0194 (6)	0.0034 (5)	0.0088 (5)	0.0023 (5)
O9	0.0383 (7)	0.0200 (6)	0.0281 (7)	−0.0032 (6)	0.0090 (6)	0.0074 (5)
O10	0.0401 (8)	0.0234 (7)	0.0397 (8)	−0.0024 (6)	0.0229 (7)	−0.0100 (6)
O11	0.0582 (10)	0.0314 (8)	0.0284 (7)	0.0217 (7)	0.0035 (7)	0.0045 (6)
P1	0.0217 (2)	0.0164 (2)	0.0153 (2)	−0.00067 (16)	0.00582 (16)	0.00060 (16)
P2	0.0205 (2)	0.0132 (2)	0.01642 (19)	0.00155 (15)	0.00628 (15)	0.00047 (15)
Rh1	0.02171 (7)	0.01364 (7)	0.01554 (7)	0.00143 (5)	0.00610 (5)	0.00137 (5)

Geometric parameters (Å, º)

C1—C2	1.381 (3)	C39—H39	0.9500
C1—C6	1.392 (3)	C40—C41	1.489 (2)
C1—O1	1.400 (2)	C41—C46	1.387 (2)
C2—C3	1.383 (3)	C41—C42	1.401 (2)
C2—H2	0.9500	C42—C43	1.377 (2)
C3—C4	1.382 (3)	C42—H42	0.9500
C3—H3	0.9500	C43—O10	1.373 (2)
C4—C5	1.383 (3)	C43—C44	1.388 (3)
C4—H4	0.9500	C44—C45	1.391 (2)
C5—C6	1.396 (3)	C44—H44	0.9500
C5—H5	0.9500	C45—C46	1.408 (2)
C6—C7	1.483 (3)	C45—C53	1.537 (2)
C7—C12	1.392 (3)	C46—O7	1.399 (2)
C7—C8	1.395 (3)	C47—C49	1.529 (3)
C8—C9	1.386 (3)	C47—C48	1.536 (3)
C8—H8	0.9500	C47—C50	1.537 (3)
C9—C10	1.370 (4)	C48—H48A	0.9800
C9—H9	0.9500	C48—H48B	0.9800
C10—C11	1.389 (3)	C48—H48C	0.9800
C10—H10	0.9500	C49—H49A	0.9800
C11—C12	1.389 (3)	C49—H49B	0.9800
C11—H11	0.9500	C49—H49C	0.9800
C12—H12	0.9500	C50—H50A	0.9800
C13—C18	1.386 (3)	C50—H50B	0.9800
C13—C14	1.407 (2)	C50—H50C	0.9800
C13—O2	1.411 (2)	C51—O9	1.427 (3)
C14—C15	1.386 (3)	C51—H51A	0.9800
C14—C25	1.543 (3)	C51—H51B	0.9800
C15—C16	1.389 (3)	C51—H51C	0.9800
C15—H15	0.9500	C52—O10	1.422 (2)
C16—O4	1.373 (2)	C52—H52A	0.9800
C16—C17	1.380 (3)	C52—H52B	0.9800
C17—C18	1.402 (2)	C52—H52C	0.9800
C17—H17	0.9500	C53—C55	1.527 (3)
C18—C19	1.491 (2)	C53—C56	1.531 (3)
C19—C24	1.395 (2)	C53—C54	1.535 (3)
C19—C20	1.398 (3)	C54—H54A	0.9800
C20—C21	1.382 (3)	C54—H54B	0.9800
C20—H20	0.9500	C54—H54C	0.9800
C21—O5	1.366 (2)	C55—H55A	0.9800
C21—C22	1.391 (3)	C55—H55B	0.9800
C22—C23	1.382 (3)	C55—H55C	0.9800
C22—H22	0.9500	C56—H56A	0.9800
C23—C24	1.409 (2)	C56—H56B	0.9800
C23—C31	1.539 (3)	C56—H56C	0.9800
C24—O3	1.402 (2)	C57—O11	1.143 (2)
C25—C27	1.528 (3)	C57—Rh1	1.8057 (19)
C25—C26	1.530 (3)	C58—C59	1.3900
C25—C28	1.538 (3)	C58—C63	1.3900
C26—H26A	0.9800	C58—C64	1.472 (4)
C26—H26B	0.9800	C59—C60	1.3900
C26—H26C	0.9800	C59—H59	0.9500
C27—H27A	0.9800	C60—C61	1.3900
C27—H27B	0.9800	C60—H60	0.9500
C27—H27C	0.9800	C61—C62	1.3900
C28—H28A	0.9800	C61—H61	0.9500
C28—H28B	0.9800	C62—C63	1.3900
C28—H28C	0.9800	C62—H62	0.9500
C29—O4	1.411 (2)	C63—H63	0.9500
C29—H29A	0.9800	C64—H64A	0.9800
C29—H29B	0.9800	C64—H64B	0.9800
C29—H29C	0.9800	C64—H64C	0.9800
C30—O5	1.425 (3)	C65—C66	1.3900
C30—H30A	0.9800	C65—C70	1.3900
C30—H30B	0.9800	C65—C71	1.492 (3)
C30—H30C	0.9800	C66—C67	1.3900
C31—C33	1.525 (3)	C66—H66	0.9500
C31—C32	1.529 (3)	C67—C68	1.3900
C31—C34	1.537 (3)	C67—H67	0.9500
C32—H32A	0.9800	C68—C69	1.3900
C32—H32B	0.9800	C68—H68	0.9500
C32—H32C	0.9800	C69—C70	1.3900
C33—H33A	0.9800	C69—H69	0.9500
C33—H33B	0.9800	C70—H70	0.9500
C33—H33C	0.9800	C71—H71A	0.9800
C34—H34A	0.9800	C71—H71B	0.9800
C34—H34B	0.9800	C71—H71C	0.9800
C34—H34C	0.9800	O1—P1	1.5999 (13)
C35—C40	1.388 (2)	O2—P1	1.5976 (12)
C35—O6	1.399 (2)	O3—P1	1.6157 (13)
C35—C36	1.407 (2)	O6—P2	1.6393 (13)
C36—C37	1.390 (3)	O7—P2	1.6217 (12)
C36—C47	1.543 (3)	O8—P2	1.5081 (12)
C37—C38	1.392 (3)	O8—Rh1^i	2.0710 (12)
C37—H37	0.9500	P1—Rh1	2.2906 (4)
C38—O9	1.367 (2)	P2—Rh1	2.3049 (4)
C38—C39	1.382 (2)	Rh1—O8^i	2.0711 (12)
C39—C40	1.399 (2)
C2—C1—C6	122.00 (17)	C43—C42—C41	118.93 (17)
C2—C1—O1	121.74 (16)	C43—C42—H42	120.5
C6—C1—O1	116.20 (16)	C41—C42—H42	120.5
C1—C2—C3	119.42 (18)	O10—C43—C42	124.42 (17)
C1—C2—H2	120.3	O10—C43—C44	115.35 (16)
C3—C2—H2	120.3	C42—C43—C44	120.23 (17)
C4—C3—C2	120.3 (2)	C43—C44—C45	122.50 (16)
C4—C3—H3	119.9	C43—C44—H44	118.7
C2—C3—H3	119.9	C45—C44—H44	118.7
C3—C4—C5	119.4 (2)	C44—C45—C46	116.12 (16)
C3—C4—H4	120.3	C44—C45—C53	120.70 (15)
C5—C4—H4	120.3	C46—C45—C53	123.15 (15)
C4—C5—C6	121.78 (19)	C41—C46—O7	117.70 (14)
C4—C5—H5	119.1	C41—C46—C45	121.73 (15)
C6—C5—H5	119.1	O7—C46—C45	120.21 (15)
C1—C6—C5	117.08 (18)	C49—C47—C48	109.71 (17)
C1—C6—C7	123.20 (17)	C49—C47—C50	107.67 (17)
C5—C6—C7	119.70 (17)	C48—C47—C50	107.21 (17)
C12—C7—C8	118.9 (2)	C49—C47—C36	112.74 (16)
C12—C7—C6	121.40 (17)	C48—C47—C36	107.97 (15)
C8—C7—C6	119.61 (19)	C50—C47—C36	111.41 (16)
C9—C8—C7	120.2 (2)	C47—C48—H48A	109.5
C9—C8—H8	119.9	C47—C48—H48B	109.5
C7—C8—H8	119.9	H48A—C48—H48B	109.5
C10—C9—C8	120.6 (2)	C47—C48—H48C	109.5
C10—C9—H9	119.7	H48A—C48—H48C	109.5
C8—C9—H9	119.7	H48B—C48—H48C	109.5
C9—C10—C11	120.1 (2)	C47—C49—H49A	109.5
C9—C10—H10	120.0	C47—C49—H49B	109.5
C11—C10—H10	120.0	H49A—C49—H49B	109.5
C10—C11—C12	119.7 (2)	C47—C49—H49C	109.5
C10—C11—H11	120.1	H49A—C49—H49C	109.5
C12—C11—H11	120.1	H49B—C49—H49C	109.5
C11—C12—C7	120.5 (2)	C47—C50—H50A	109.5
C11—C12—H12	119.7	C47—C50—H50B	109.5
C7—C12—H12	119.7	H50A—C50—H50B	109.5
C18—C13—C14	122.73 (16)	C47—C50—H50C	109.5
C18—C13—O2	117.61 (15)	H50A—C50—H50C	109.5
C14—C13—O2	119.25 (15)	H50B—C50—H50C	109.5
C15—C14—C13	115.79 (17)	O9—C51—H51A	109.5
C15—C14—C25	120.03 (16)	O9—C51—H51B	109.5
C13—C14—C25	123.99 (16)	H51A—C51—H51B	109.5
C14—C15—C16	122.64 (17)	O9—C51—H51C	109.5
C14—C15—H15	118.7	H51A—C51—H51C	109.5
C16—C15—H15	118.7	H51B—C51—H51C	109.5
O4—C16—C17	124.70 (17)	O10—C52—H52A	109.5
O4—C16—C15	115.14 (16)	O10—C52—H52B	109.5
C17—C16—C15	120.13 (17)	H52A—C52—H52B	109.5
C16—C17—C18	119.28 (17)	O10—C52—H52C	109.5
C16—C17—H17	120.4	H52A—C52—H52C	109.5
C18—C17—H17	120.4	H52B—C52—H52C	109.5
C13—C18—C17	119.01 (16)	C55—C53—C56	111.18 (18)
C13—C18—C19	123.40 (15)	C55—C53—C54	107.22 (16)
C17—C18—C19	117.38 (16)	C56—C53—C54	106.48 (17)
C24—C19—C20	119.12 (16)	C55—C53—C45	109.93 (16)
C24—C19—C18	123.38 (16)	C56—C53—C45	110.40 (16)
C20—C19—C18	117.44 (16)	C54—C53—C45	111.55 (15)
C21—C20—C19	119.26 (18)	C53—C54—H54A	109.5
C21—C20—H20	120.4	C53—C54—H54B	109.5
C19—C20—H20	120.4	H54A—C54—H54B	109.5
O5—C21—C20	124.53 (19)	C53—C54—H54C	109.5
O5—C21—C22	115.29 (18)	H54A—C54—H54C	109.5
C20—C21—C22	120.19 (18)	H54B—C54—H54C	109.5
C23—C22—C21	122.70 (17)	C53—C55—H55A	109.5
C23—C22—H22	118.7	C53—C55—H55B	109.5
C21—C22—H22	118.7	H55A—C55—H55B	109.5
C22—C23—C24	115.96 (17)	C53—C55—H55C	109.5
C22—C23—C31	120.39 (17)	H55A—C55—H55C	109.5
C24—C23—C31	123.59 (17)	H55B—C55—H55C	109.5
C19—C24—O3	116.57 (15)	C53—C56—H56A	109.5
C19—C24—C23	122.43 (17)	C53—C56—H56B	109.5
O3—C24—C23	120.80 (16)	H56A—C56—H56B	109.5
C27—C25—C26	109.77 (17)	C53—C56—H56C	109.5
C27—C25—C28	106.94 (17)	H56A—C56—H56C	109.5
C26—C25—C28	107.82 (18)	H56B—C56—H56C	109.5
C27—C25—C14	112.75 (16)	O11—C57—Rh1	177.9 (2)
C26—C25—C14	108.25 (16)	C59—C58—C63	120.0
C28—C25—C14	111.19 (16)	C59—C58—C64	120.2 (2)
C25—C26—H26A	109.5	C63—C58—C64	119.8 (2)
C25—C26—H26B	109.5	C60—C59—C58	120.0
H26A—C26—H26B	109.5	C60—C59—H59	120.0
C25—C26—H26C	109.5	C58—C59—H59	120.0
H26A—C26—H26C	109.5	C59—C60—C61	120.0
H26B—C26—H26C	109.5	C59—C60—H60	120.0
C25—C27—H27A	109.5	C61—C60—H60	120.0
C25—C27—H27B	109.5	C62—C61—C60	120.0
H27A—C27—H27B	109.5	C62—C61—H61	120.0
C25—C27—H27C	109.5	C60—C61—H61	120.0
H27A—C27—H27C	109.5	C61—C62—C63	120.0
H27B—C27—H27C	109.5	C61—C62—H62	120.0
C25—C28—H28A	109.5	C63—C62—H62	120.0
C25—C28—H28B	109.5	C62—C63—C58	120.0
H28A—C28—H28B	109.5	C62—C63—H63	120.0
C25—C28—H28C	109.5	C58—C63—H63	120.0
H28A—C28—H28C	109.5	C58—C64—H64A	109.5
H28B—C28—H28C	109.5	C58—C64—H64B	109.5
O4—C29—H29A	109.5	H64A—C64—H64B	109.5
O4—C29—H29B	109.5	C58—C64—H64C	109.5
H29A—C29—H29B	109.5	H64A—C64—H64C	109.5
O4—C29—H29C	109.5	H64B—C64—H64C	109.5
H29A—C29—H29C	109.5	C66—C65—C70	120.0
H29B—C29—H29C	109.5	C66—C65—C71	119.52 (19)
O5—C30—H30A	109.5	C70—C65—C71	120.47 (19)
O5—C30—H30B	109.5	C65—C66—C67	120.0
H30A—C30—H30B	109.5	C65—C66—H66	120.0
O5—C30—H30C	109.5	C67—C66—H66	120.0
H30A—C30—H30C	109.5	C68—C67—C66	120.0
H30B—C30—H30C	109.5	C68—C67—H67	120.0
C33—C31—C32	110.5 (2)	C66—C67—H67	120.0
C33—C31—C34	107.35 (19)	C69—C68—C67	120.0
C32—C31—C34	106.89 (17)	C69—C68—H68	120.0
C33—C31—C23	109.79 (17)	C67—C68—H68	120.0
C32—C31—C23	111.18 (17)	C68—C69—C70	120.0
C34—C31—C23	111.05 (18)	C68—C69—H69	120.0
C31—C32—H32A	109.5	C70—C69—H69	120.0
C31—C32—H32B	109.5	C69—C70—C65	120.0
H32A—C32—H32B	109.5	C69—C70—H70	120.0
C31—C32—H32C	109.5	C65—C70—H70	120.0
H32A—C32—H32C	109.5	C65—C71—H71A	109.5
H32B—C32—H32C	109.5	C65—C71—H71B	109.5
C31—C33—H33A	109.5	H71A—C71—H71B	109.5
C31—C33—H33B	109.5	C65—C71—H71C	109.5
H33A—C33—H33B	109.5	H71A—C71—H71C	109.5
C31—C33—H33C	109.5	H71B—C71—H71C	109.5
H33A—C33—H33C	109.5	C1—O1—P1	126.22 (11)
H33B—C33—H33C	109.5	C13—O2—P1	124.26 (11)
C31—C34—H34A	109.5	C24—O3—P1	120.71 (11)
C31—C34—H34B	109.5	C16—O4—C29	117.31 (15)
H34A—C34—H34B	109.5	C21—O5—C30	116.40 (17)
C31—C34—H34C	109.5	C35—O6—P2	116.77 (10)
H34A—C34—H34C	109.5	C46—O7—P2	126.12 (11)
H34B—C34—H34C	109.5	P2—O8—Rh1^i	140.28 (7)
C40—C35—O6	117.37 (15)	C38—O9—C51	117.38 (15)
C40—C35—C36	122.00 (16)	C43—O10—C52	116.63 (15)
O6—C35—C36	120.50 (15)	O2—P1—O1	101.63 (7)
C37—C36—C35	116.15 (16)	O2—P1—O3	105.08 (7)
C37—C36—C47	121.14 (16)	O1—P1—O3	97.10 (7)
C35—C36—C47	122.34 (16)	O2—P1—Rh1	107.40 (5)
C36—C37—C38	122.28 (17)	O1—P1—Rh1	123.27 (5)
C36—C37—H37	118.9	O3—P1—Rh1	119.82 (5)
C38—C37—H37	118.9	O8—P2—O7	107.83 (7)
O9—C38—C39	124.45 (17)	O8—P2—O6	101.89 (7)
O9—C38—C37	115.45 (16)	O7—P2—O6	102.46 (6)
C39—C38—C37	120.06 (17)	O8—P2—Rh1	121.95 (5)
C38—C39—C40	119.16 (17)	O7—P2—Rh1	106.81 (5)
C38—C39—H39	120.4	O6—P2—Rh1	114.16 (5)
C40—C39—H39	120.4	C57—Rh1—O8^i	178.25 (7)
C35—C40—C39	119.49 (16)	C57—Rh1—P1	87.14 (6)
C35—C40—C41	121.36 (15)	O8^i—Rh1—P1	92.36 (3)
C39—C40—C41	118.95 (15)	C57—Rh1—P2	87.55 (6)
C46—C41—C42	119.95 (15)	O8^i—Rh1—P2	93.00 (3)
C46—C41—C40	122.74 (15)	P1—Rh1—P2	174.350 (16)
C42—C41—C40	117.31 (16)
C6—C1—C2—C3	0.0 (3)	C38—C39—C40—C41	−174.31 (16)
O1—C1—C2—C3	177.22 (18)	C35—C40—C41—C46	54.6 (2)
C1—C2—C3—C4	−0.9 (3)	C39—C40—C41—C46	−130.68 (18)
C2—C3—C4—C5	0.6 (3)	C35—C40—C41—C42	−125.56 (18)
C3—C4—C5—C6	0.6 (4)	C39—C40—C41—C42	49.2 (2)
C2—C1—C6—C5	1.1 (3)	C46—C41—C42—C43	−0.6 (3)
O1—C1—C6—C5	−176.24 (17)	C40—C41—C42—C43	179.59 (17)
C2—C1—C6—C7	−177.06 (18)	C41—C42—C43—O10	−174.92 (18)
O1—C1—C6—C7	5.6 (3)	C41—C42—C43—C44	5.0 (3)
C4—C5—C6—C1	−1.4 (3)	O10—C43—C44—C45	176.86 (17)
C4—C5—C6—C7	176.8 (2)	C42—C43—C44—C45	−3.1 (3)
C1—C6—C7—C12	59.9 (3)	C43—C44—C45—C46	−3.3 (3)
C5—C6—C7—C12	−118.2 (2)	C43—C44—C45—C53	174.90 (18)
C1—C6—C7—C8	−124.3 (2)	C42—C41—C46—O7	−179.21 (15)
C5—C6—C7—C8	57.5 (3)	C40—C41—C46—O7	0.6 (2)
C12—C7—C8—C9	0.4 (3)	C42—C41—C46—C45	−6.1 (3)
C6—C7—C8—C9	−175.45 (19)	C40—C41—C46—C45	173.78 (16)
C7—C8—C9—C10	0.3 (3)	C44—C45—C46—C41	7.8 (3)
C8—C9—C10—C11	−0.4 (4)	C53—C45—C46—C41	−170.31 (17)
C9—C10—C11—C12	−0.4 (3)	C44—C45—C46—O7	−179.22 (15)
C10—C11—C12—C7	1.1 (3)	C53—C45—C46—O7	2.7 (3)
C8—C7—C12—C11	−1.2 (3)	C37—C36—C47—C49	123.2 (2)
C6—C7—C12—C11	174.64 (19)	C35—C36—C47—C49	−64.0 (2)
C18—C13—C14—C15	6.5 (3)	C37—C36—C47—C48	−115.40 (19)
O2—C13—C14—C15	178.99 (16)	C35—C36—C47—C48	57.3 (2)
C18—C13—C14—C25	−168.51 (17)	C37—C36—C47—C50	2.1 (2)
O2—C13—C14—C25	3.9 (3)	C35—C36—C47—C50	174.80 (18)
C13—C14—C15—C16	−1.5 (3)	C44—C45—C53—C55	111.1 (2)
C25—C14—C15—C16	173.73 (18)	C46—C45—C53—C55	−70.9 (2)
C14—C15—C16—O4	178.17 (18)	C44—C45—C53—C56	−125.9 (2)
C14—C15—C16—C17	−3.7 (3)	C46—C45—C53—C56	52.1 (2)
O4—C16—C17—C18	−177.94 (18)	C44—C45—C53—C54	−7.7 (3)
C15—C16—C17—C18	4.1 (3)	C46—C45—C53—C54	170.29 (18)
C14—C13—C18—C17	−6.2 (3)	C63—C58—C59—C60	0.0
O2—C13—C18—C17	−178.77 (16)	C64—C58—C59—C60	179.6 (3)
C14—C13—C18—C19	168.40 (17)	C58—C59—C60—C61	0.0
O2—C13—C18—C19	−4.2 (3)	C59—C60—C61—C62	0.0
C16—C17—C18—C13	0.6 (3)	C60—C61—C62—C63	0.0
C16—C17—C18—C19	−174.28 (17)	C61—C62—C63—C58	0.0
C13—C18—C19—C24	52.2 (3)	C59—C58—C63—C62	0.0
C17—C18—C19—C24	−133.16 (19)	C64—C58—C63—C62	−179.6 (3)
C13—C18—C19—C20	−130.61 (19)	C70—C65—C66—C67	0.0
C17—C18—C19—C20	44.1 (2)	C71—C65—C66—C67	179.1 (3)
C24—C19—C20—C21	0.3 (3)	C65—C66—C67—C68	0.0
C18—C19—C20—C21	−177.09 (17)	C66—C67—C68—C69	0.0
C19—C20—C21—O5	−176.43 (18)	C67—C68—C69—C70	0.0
C19—C20—C21—C22	3.8 (3)	C68—C69—C70—C65	0.0
O5—C21—C22—C23	177.17 (18)	C66—C65—C70—C69	0.0
C20—C21—C22—C23	−3.0 (3)	C71—C65—C70—C69	−179.1 (3)
C21—C22—C23—C24	−1.8 (3)	C2—C1—O1—P1	26.3 (2)
C21—C22—C23—C31	175.35 (18)	C6—C1—O1—P1	−156.39 (14)
C20—C19—C24—O3	179.79 (15)	C18—C13—O2—P1	−63.9 (2)
C18—C19—C24—O3	−3.0 (2)	C14—C13—O2—P1	123.26 (15)
C20—C19—C24—C23	−5.4 (3)	C19—C24—O3—P1	−69.83 (18)
C18—C19—C24—C23	171.83 (17)	C23—C24—O3—P1	115.23 (16)
C22—C23—C24—C19	6.0 (3)	C17—C16—O4—C29	11.4 (3)
C31—C23—C24—C19	−171.03 (17)	C15—C16—O4—C29	−170.62 (19)
C22—C23—C24—O3	−179.34 (16)	C20—C21—O5—C30	−6.4 (3)
C31—C23—C24—O3	3.6 (3)	C22—C21—O5—C30	173.3 (2)
C15—C14—C25—C27	126.3 (2)	C40—C35—O6—P2	−71.52 (17)
C13—C14—C25—C27	−58.9 (2)	C36—C35—O6—P2	112.59 (15)
C15—C14—C25—C26	−112.1 (2)	C41—C46—O7—P2	−63.4 (2)
C13—C14—C25—C26	62.7 (2)	C45—C46—O7—P2	123.33 (15)
C15—C14—C25—C28	6.2 (3)	C39—C38—O9—C51	−0.8 (3)
C13—C14—C25—C28	−178.99 (19)	C37—C38—O9—C51	177.12 (17)
C22—C23—C31—C33	−124.4 (2)	C42—C43—O10—C52	−5.2 (3)
C24—C23—C31—C33	52.6 (3)	C44—C43—O10—C52	174.89 (19)
C22—C23—C31—C32	113.1 (2)	C13—O2—P1—O1	−61.60 (14)
C24—C23—C31—C32	−70.0 (2)	C13—O2—P1—O3	39.12 (14)
C22—C23—C31—C34	−5.8 (3)	C13—O2—P1—Rh1	167.75 (12)
C24—C23—C31—C34	171.14 (19)	C1—O1—P1—O2	160.96 (13)
C40—C35—C36—C37	9.9 (3)	C1—O1—P1—O3	53.90 (14)
O6—C35—C36—C37	−174.39 (15)	C1—O1—P1—Rh1	−79.02 (14)
C40—C35—C36—C47	−163.16 (17)	C24—O3—P1—O2	49.52 (13)
O6—C35—C36—C47	12.5 (3)	C24—O3—P1—O1	153.65 (12)
C35—C36—C37—C38	−3.4 (3)	C24—O3—P1—Rh1	−71.24 (13)
C47—C36—C37—C38	169.73 (17)	Rh1^i—O8—P2—O7	−156.08 (11)
C36—C37—C38—O9	177.68 (16)	Rh1^i—O8—P2—O6	96.51 (12)
C36—C37—C38—C39	−4.3 (3)	Rh1^i—O8—P2—Rh1	−32.11 (15)
O9—C38—C39—C40	−176.40 (16)	C46—O7—P2—O8	−78.92 (14)
C37—C38—C39—C40	5.8 (3)	C46—O7—P2—O6	28.10 (14)
O6—C35—C40—C39	175.53 (15)	C46—O7—P2—Rh1	148.40 (12)
C36—C35—C40—C39	−8.6 (3)	C35—O6—P2—O8	172.30 (11)
O6—C35—C40—C41	−9.8 (2)	C35—O6—P2—O7	60.77 (12)
C36—C35—C40—C41	166.06 (16)	C35—O6—P2—Rh1	−54.30 (12)
C38—C39—C40—C35	0.5 (3)

Symmetry code: (i) −x, −y+2, −z.