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The cation of the title compound, [Au4(PPh2CH2PPhCH2PPh2)2Cl2][Au(C6F5)3Cl]2 or [Au4Cl2(C32H29P3)2][AuCl(C6F5)3]2, displays a rhomboidal geometry for the Au atoms, with short Au...Au distances of 3.104 (2) and 3.185 (1) Å; the linear coordination at the AuI atoms is distorted: P-Au-P 164.7 (2)° and P-Au-Cl 170.67 (11)°. The anion shows the expected square-planar geometry at AuIII, with the Au atom 0.022 (5) Å out of the plane of the four donor atoms.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270100012518/qa0390sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270100012518/qa0390Isup2.hkl
Contains datablock I

CCDC reference: 153926

Computing details top

Data collection: DIF4 (Stoe & Cie, 1988); cell refinement: DIF4; data reduction: REDU4 (Stoe & Cie, 1988); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); software used to prepare material for publication: SHELXL97.

(I) top
Crystal data top
[Au4(C32H29P3)2Cl2][AuCl(C6F5)3]2Z = 1
Mr = 3338.88F(000) = 1560
Triclinic, P1Dx = 2.207 Mg m3
a = 12.193 (6) ÅMo Kα radiation, λ = 0.71073 Å
b = 14.439 (8) ÅCell parameters from 52 reflections
c = 16.531 (9) Åθ = 9–11.5°
α = 65.93 (2)°µ = 9.03 mm1
β = 86.36 (3)°T = 173 K
γ = 71.46 (3)°Prism, colourless
V = 2512 (2) Å30.34 × 0.30 × 0.23 mm
Data collection top
Siemens–Stoe AED-2
diffractometer
6194 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.060
Graphite monochromatorθmax = 25.0°, θmin = 3.1°
ω/θ scansh = 144
Absorption correction: ψ scan
(XEMP; Siemens, 1990)
k = 1717
Tmin = 0.039, Tmax = 0.125l = 1919
12573 measured reflections3 standard reflections every 60 min
8863 independent reflections intensity decay: 4.5%
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.049Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.104H-atom parameters constrained
S = 0.98 w = 1/[σ2(Fo2) + (0.0493P)2]
where P = (Fo2 + 2Fc2)/3
8863 reflections(Δ/σ)max = 0.001
658 parametersΔρmax = 2.44 e Å3
40 restraintsΔρmin = 1.92 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Au10.01597 (4)0.53497 (4)0.13997 (2)0.02311 (12)
Au20.15015 (4)0.51505 (4)0.01107 (3)0.02507 (12)
Au30.25340 (4)0.86948 (4)0.39366 (3)0.02417 (12)
P10.1287 (2)0.6986 (2)0.09338 (16)0.0206 (6)
P20.2138 (2)0.6919 (3)0.07028 (17)0.0234 (7)
P30.1508 (3)0.3723 (2)0.22389 (17)0.0246 (7)
Cl10.0671 (2)0.9926 (3)0.35046 (19)0.0356 (7)
Cl20.1161 (3)0.3360 (3)0.09273 (19)0.0395 (8)
F10.1882 (7)0.8070 (7)0.5991 (4)0.055 (2)
F20.2133 (7)0.8831 (8)0.7164 (4)0.069 (3)
F30.3106 (7)1.0410 (8)0.6708 (5)0.073 (3)
F40.3902 (8)1.1159 (7)0.5074 (5)0.065 (3)
F50.3665 (7)1.0388 (6)0.3888 (4)0.047 (2)
F60.3599 (6)0.6419 (7)0.5545 (4)0.060 (2)
F70.5756 (6)0.5058 (7)0.5979 (5)0.061 (2)
F80.7497 (6)0.5548 (7)0.4952 (5)0.067 (3)
F90.7041 (6)0.7395 (8)0.3494 (5)0.064 (2)
F100.4867 (6)0.8785 (6)0.3044 (4)0.0449 (19)
F110.2678 (6)0.9713 (6)0.1821 (4)0.0451 (19)
F120.2481 (7)0.9038 (7)0.0575 (4)0.056 (2)
F130.1957 (7)0.7217 (7)0.0997 (5)0.060 (2)
F140.1714 (7)0.6010 (7)0.2725 (6)0.059 (2)
F150.2001 (6)0.6635 (6)0.3997 (4)0.0450 (19)
C10.1589 (10)0.7694 (9)0.0269 (6)0.025 (3)
H1A0.08720.77990.05510.030*
H1B0.21740.84080.04170.030*
C20.1677 (9)0.7309 (9)0.1835 (6)0.022 (2)
H2A0.22580.79810.22340.026*
H2B0.09290.74460.18470.026*
C110.2638 (9)0.6876 (8)0.1409 (6)0.021 (2)
C120.3612 (9)0.7786 (10)0.1180 (7)0.034 (3)
H120.35800.84560.07500.041*
C130.4637 (10)0.7705 (13)0.1588 (8)0.050 (4)
H130.53060.83220.14310.060*
C140.4682 (11)0.6735 (10)0.2216 (7)0.046 (4)
H140.53800.66890.24960.055*
C150.3719 (11)0.5829 (11)0.2441 (7)0.041 (3)
H150.37570.51620.28750.049*
C160.2689 (10)0.5891 (11)0.2032 (7)0.040 (3)
H160.20310.52660.21760.048*
C210.1004 (8)0.7912 (9)0.1302 (6)0.027 (3)
C220.0871 (9)0.8858 (10)0.0724 (7)0.036 (3)
H220.08800.90330.01040.043*
C230.0721 (10)0.9573 (11)0.1053 (9)0.047 (4)
H230.06361.02360.06530.056*
C240.0696 (10)0.9314 (12)0.1948 (8)0.052 (4)
H240.05780.97910.21690.063*
C250.0840 (13)0.8377 (14)0.2518 (9)0.066 (5)
H250.08450.82110.31370.080*
C260.0979 (10)0.7655 (12)0.2204 (7)0.043 (4)
H260.10570.69910.26090.052*
C310.3705 (10)0.7486 (8)0.0815 (6)0.026 (3)
C320.4241 (10)0.8563 (10)0.1314 (6)0.036 (3)
H320.37850.90150.16000.043*
C330.5441 (10)0.8991 (11)0.1400 (7)0.046 (4)
H330.58090.97350.17390.055*
C340.6087 (11)0.8336 (10)0.0995 (8)0.051 (4)
H340.69090.86290.10610.061*
C350.5575 (11)0.7257 (12)0.0492 (8)0.048 (4)
H350.60400.68120.02170.057*
C360.4365 (10)0.6823 (11)0.0390 (8)0.041 (3)
H360.40000.60840.00340.049*
C510.1060 (10)0.3188 (8)0.3349 (6)0.029 (3)
C520.0826 (14)0.3824 (12)0.3817 (8)0.091 (7)
H520.09490.45000.35760.110*
C530.0407 (17)0.3451 (15)0.4650 (9)0.113 (9)
H530.02560.38750.49840.136*
C540.0209 (15)0.2505 (11)0.4994 (8)0.066 (5)
H540.01050.22830.55560.079*
C550.0451 (10)0.1859 (11)0.4549 (7)0.040 (3)
H550.03450.11760.48060.048*
C560.0853 (9)0.2218 (9)0.3720 (6)0.027 (3)
H560.09930.17870.33930.032*
C610.2948 (9)0.3764 (8)0.2336 (7)0.030 (3)
C620.3756 (10)0.2916 (10)0.2976 (9)0.057 (4)
H620.35400.23320.33950.068*
C630.4873 (13)0.2922 (14)0.3004 (12)0.089 (7)
H630.54210.23370.34510.107*
C640.5225 (14)0.3734 (13)0.2416 (11)0.085 (7)
H640.60100.37120.24350.102*
C650.4420 (12)0.4579 (13)0.1797 (10)0.057 (4)
H650.46430.51670.13920.069*
C660.3286 (10)0.4605 (11)0.1745 (7)0.042 (4)
H660.27390.52000.13020.050*
C710.2737 (9)0.9219 (11)0.4894 (7)0.032 (3)
C720.2375 (11)0.8837 (11)0.5743 (7)0.038 (3)
C730.2475 (10)0.9231 (12)0.6356 (7)0.044 (4)
C740.3006 (11)0.9998 (13)0.6116 (9)0.049 (4)
C750.3394 (11)1.0391 (13)0.5306 (9)0.050 (4)
C760.3276 (11)0.9982 (10)0.4704 (7)0.033 (3)
C810.4158 (9)0.7653 (9)0.4284 (7)0.024 (3)
C820.4456 (10)0.6677 (11)0.5010 (7)0.035 (3)
C830.5545 (11)0.5988 (11)0.5267 (8)0.042 (3)
C840.6413 (11)0.6226 (12)0.4737 (9)0.045 (4)
C850.6165 (11)0.7156 (12)0.4003 (8)0.042 (3)
C860.5059 (11)0.7872 (10)0.3789 (7)0.030 (3)
C910.2382 (9)0.8167 (10)0.2974 (7)0.028 (3)
C920.2448 (9)0.8774 (10)0.2082 (7)0.027 (3)
C930.2347 (10)0.8433 (11)0.1422 (7)0.034 (3)
C940.2117 (10)0.7511 (11)0.1650 (8)0.036 (3)
C950.1985 (10)0.6904 (11)0.2509 (9)0.038 (3)
C960.2139 (10)0.7255 (10)0.3149 (8)0.030 (3)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Au10.0228 (2)0.0221 (3)0.0202 (2)0.0030 (2)0.00062 (17)0.00736 (19)
Au20.0297 (3)0.0230 (3)0.0211 (2)0.0098 (2)0.00228 (18)0.00672 (19)
Au30.0255 (2)0.0218 (3)0.0251 (2)0.0055 (2)0.00009 (18)0.0109 (2)
P10.0208 (15)0.0228 (18)0.0178 (12)0.0065 (13)0.0032 (11)0.0085 (12)
P20.0246 (15)0.0256 (19)0.0205 (13)0.0084 (14)0.0023 (12)0.0097 (13)
P30.0303 (17)0.0194 (18)0.0212 (13)0.0035 (14)0.0044 (12)0.0080 (13)
Cl10.0286 (16)0.035 (2)0.0449 (16)0.0017 (14)0.0045 (13)0.0255 (15)
Cl20.0371 (17)0.0253 (19)0.0451 (16)0.0115 (15)0.0031 (14)0.0028 (14)
F10.054 (5)0.071 (7)0.041 (4)0.028 (5)0.007 (4)0.019 (4)
F20.059 (5)0.110 (9)0.034 (4)0.012 (5)0.007 (4)0.037 (5)
F30.076 (6)0.085 (7)0.068 (5)0.010 (5)0.022 (5)0.065 (5)
F40.079 (6)0.060 (7)0.077 (5)0.026 (5)0.013 (5)0.042 (5)
F50.066 (5)0.041 (5)0.042 (4)0.023 (4)0.007 (4)0.021 (4)
F60.041 (5)0.059 (6)0.043 (4)0.012 (4)0.012 (4)0.009 (4)
F70.049 (5)0.041 (6)0.052 (4)0.000 (4)0.001 (4)0.010 (4)
F80.026 (4)0.051 (6)0.090 (6)0.013 (4)0.002 (4)0.014 (5)
F90.034 (4)0.072 (7)0.075 (5)0.016 (5)0.017 (4)0.023 (5)
F100.043 (4)0.041 (5)0.045 (4)0.014 (4)0.012 (3)0.013 (4)
F110.064 (5)0.030 (5)0.035 (4)0.023 (4)0.005 (3)0.001 (3)
F120.066 (5)0.055 (6)0.028 (3)0.001 (5)0.004 (4)0.013 (4)
F130.051 (5)0.079 (7)0.068 (5)0.003 (5)0.009 (4)0.061 (5)
F140.069 (6)0.034 (5)0.103 (6)0.026 (5)0.022 (5)0.051 (5)
F150.059 (5)0.032 (5)0.045 (4)0.021 (4)0.029 (4)0.016 (4)
C10.033 (6)0.027 (7)0.012 (5)0.009 (6)0.002 (4)0.006 (5)
C20.028 (6)0.025 (7)0.015 (5)0.012 (5)0.006 (4)0.009 (5)
C110.024 (6)0.021 (7)0.020 (5)0.010 (5)0.006 (4)0.009 (5)
C120.025 (6)0.038 (9)0.032 (6)0.005 (6)0.000 (5)0.011 (6)
C130.031 (8)0.075 (13)0.055 (8)0.011 (8)0.011 (6)0.043 (9)
C140.034 (8)0.072 (12)0.046 (7)0.024 (8)0.023 (6)0.036 (8)
C150.048 (8)0.041 (9)0.040 (7)0.028 (8)0.017 (6)0.014 (7)
C160.045 (8)0.038 (9)0.039 (7)0.019 (7)0.014 (6)0.014 (6)
C210.016 (6)0.037 (8)0.034 (6)0.013 (6)0.002 (5)0.019 (6)
C220.047 (8)0.036 (9)0.037 (6)0.017 (7)0.002 (6)0.022 (6)
C230.039 (8)0.033 (9)0.070 (9)0.006 (7)0.012 (7)0.025 (8)
C240.026 (7)0.077 (13)0.077 (10)0.003 (8)0.005 (7)0.064 (10)
C250.065 (11)0.109 (17)0.049 (8)0.026 (11)0.001 (8)0.055 (11)
C260.034 (7)0.075 (12)0.030 (6)0.025 (8)0.012 (5)0.025 (7)
C310.028 (6)0.024 (7)0.028 (5)0.009 (6)0.006 (5)0.013 (5)
C320.038 (7)0.031 (8)0.029 (6)0.009 (6)0.009 (5)0.004 (6)
C330.029 (7)0.039 (10)0.044 (7)0.012 (7)0.011 (6)0.008 (7)
C340.024 (7)0.071 (13)0.049 (8)0.006 (8)0.005 (6)0.031 (8)
C350.043 (8)0.053 (11)0.047 (7)0.021 (8)0.008 (7)0.017 (8)
C360.037 (8)0.038 (9)0.043 (7)0.013 (7)0.008 (6)0.013 (6)
C510.039 (7)0.029 (8)0.017 (5)0.010 (6)0.004 (5)0.009 (5)
C520.21 (2)0.055 (12)0.033 (7)0.066 (14)0.046 (10)0.029 (8)
C530.23 (3)0.088 (18)0.054 (10)0.069 (18)0.050 (13)0.054 (11)
C540.110 (14)0.041 (11)0.030 (7)0.019 (10)0.024 (8)0.007 (7)
C550.035 (7)0.034 (9)0.035 (6)0.004 (7)0.004 (6)0.006 (6)
C560.031 (6)0.016 (7)0.032 (6)0.009 (6)0.008 (5)0.008 (5)
C610.025 (6)0.030 (8)0.045 (7)0.016 (6)0.001 (5)0.021 (6)
C620.045 (9)0.020 (8)0.091 (10)0.002 (7)0.044 (8)0.008 (8)
C630.063 (12)0.041 (12)0.147 (18)0.020 (10)0.068 (12)0.040 (13)
C640.030 (9)0.086 (17)0.159 (19)0.008 (10)0.019 (11)0.084 (16)
C650.055 (10)0.067 (13)0.088 (11)0.043 (10)0.025 (9)0.053 (10)
C660.043 (8)0.052 (10)0.037 (7)0.016 (7)0.008 (6)0.023 (7)
C710.020 (6)0.042 (9)0.032 (6)0.004 (6)0.010 (5)0.022 (6)
C720.037 (8)0.035 (9)0.031 (6)0.003 (7)0.007 (6)0.014 (6)
C730.022 (7)0.062 (11)0.030 (6)0.009 (7)0.008 (5)0.018 (7)
C740.036 (8)0.078 (12)0.048 (8)0.006 (8)0.008 (6)0.049 (9)
C750.036 (8)0.057 (11)0.058 (9)0.004 (8)0.010 (7)0.032 (8)
C760.041 (7)0.021 (7)0.037 (6)0.003 (6)0.005 (6)0.016 (6)
C810.025 (6)0.014 (7)0.034 (6)0.006 (5)0.003 (5)0.011 (5)
C820.033 (7)0.038 (9)0.034 (6)0.022 (7)0.002 (6)0.008 (6)
C830.043 (8)0.023 (8)0.039 (7)0.004 (7)0.007 (6)0.003 (6)
C840.031 (8)0.050 (10)0.051 (8)0.006 (7)0.004 (6)0.022 (8)
C850.035 (8)0.051 (10)0.047 (7)0.017 (7)0.017 (6)0.024 (7)
C860.042 (8)0.019 (7)0.029 (6)0.011 (6)0.002 (5)0.008 (5)
C910.023 (6)0.028 (8)0.028 (6)0.007 (6)0.000 (5)0.009 (5)
C920.018 (6)0.022 (7)0.037 (6)0.004 (5)0.005 (5)0.010 (6)
C930.034 (7)0.033 (8)0.034 (6)0.000 (6)0.002 (5)0.020 (6)
C940.033 (7)0.042 (9)0.046 (7)0.007 (7)0.003 (6)0.035 (7)
C950.019 (6)0.040 (9)0.067 (8)0.009 (6)0.011 (6)0.036 (8)
C960.026 (7)0.018 (7)0.048 (7)0.009 (6)0.012 (5)0.018 (6)
Geometric parameters (Å, º) top
Au1—P32.307 (3)C24—C251.356 (15)
Au1—P12.307 (3)C24—H240.9500
Au1—Au2i3.1037 (15)C25—C261.397 (15)
Au1—Au23.1850 (14)C25—H250.9500
Au2—P22.237 (3)C26—H260.9500
Au2—Cl22.285 (3)C31—C321.379 (13)
Au2—Au1i3.1037 (15)C31—C361.389 (13)
Au3—C812.014 (11)C32—C331.387 (14)
Au3—C912.065 (10)C32—H320.9500
Au3—C712.071 (10)C33—C341.362 (14)
Au3—Cl12.330 (3)C33—H330.9500
P1—C111.805 (10)C34—C351.378 (14)
P1—C211.806 (11)C34—H340.9500
P1—C11.825 (9)C35—C361.398 (14)
P2—C311.812 (11)C35—H350.9500
P2—C21.828 (9)C36—H360.9500
P2—C11.845 (10)C51—C521.381 (13)
P3—C611.795 (11)C51—C561.381 (12)
P3—C511.803 (10)C52—C531.387 (15)
P3—C2i1.818 (10)C52—H520.9500
F1—C721.334 (15)C53—C541.345 (16)
F2—C731.321 (14)C53—H530.9500
F3—C741.365 (13)C54—C551.362 (14)
F4—C751.349 (16)C54—H540.9500
F5—C761.356 (13)C55—C561.372 (13)
F6—C821.369 (13)C55—H550.9500
F7—C831.337 (14)C56—H560.9500
F8—C841.336 (15)C61—C661.378 (13)
F9—C851.360 (14)C61—C621.378 (13)
F10—C861.350 (13)C62—C631.368 (16)
F11—C921.360 (13)C62—H620.9500
F12—C931.346 (13)C63—C641.357 (17)
F13—C941.355 (12)C63—H630.9500
F14—C951.336 (14)C64—C651.359 (16)
F15—C961.355 (13)C64—H640.9500
C1—H1A0.9900C65—C661.379 (15)
C1—H1B0.9900C65—H650.9500
C2—P3i1.818 (10)C66—H660.9500
C2—H2A0.9900C71—C761.376 (17)
C2—H2B0.9900C71—C721.382 (16)
C11—C161.393 (13)C72—C731.376 (17)
C11—C121.393 (12)C73—C741.37 (2)
C12—C131.397 (13)C74—C751.345 (19)
C12—H120.9500C75—C761.382 (16)
C13—C141.378 (14)C81—C861.368 (15)
C13—H130.9500C81—C821.382 (16)
C14—C151.383 (14)C82—C831.349 (17)
C14—H140.9500C83—C841.369 (18)
C15—C161.400 (13)C84—C851.351 (19)
C15—H150.9500C85—C861.374 (17)
C16—H160.9500C91—C961.354 (16)
C21—C221.364 (13)C91—C921.388 (14)
C21—C261.382 (11)C92—C931.393 (15)
C22—C231.409 (14)C93—C941.345 (17)
C22—H220.9500C94—C951.362 (17)
C23—C241.370 (14)C95—F141.336 (14)
C23—H230.9500C95—C961.392 (15)
P3—Au1—P1164.40 (9)C34—C35—H35120.3
P3—Au1—Au2i80.43 (8)C36—C35—H35120.3
P1—Au1—Au2i114.89 (7)C31—C36—C35119.1 (12)
P3—Au1—Au2112.15 (8)C31—C36—H36120.4
P1—Au1—Au277.84 (8)C35—C36—H36120.4
Au2i—Au1—Au268.96 (4)C52—C51—C56118.9 (11)
P2—Au2—Cl2170.67 (11)C52—C51—P3117.8 (8)
P2—Au2—Au1i93.89 (8)C56—C51—P3123.0 (7)
Cl2—Au2—Au1i89.63 (9)C51—C52—C53118.4 (13)
P2—Au2—Au192.77 (8)C51—C52—H52120.8
Cl2—Au2—Au194.03 (9)C53—C52—H52120.8
Au1i—Au2—Au1111.04 (4)C54—C53—C52121.4 (13)
C81—Au3—C9189.1 (4)C54—C53—H53119.3
C81—Au3—C7189.6 (4)C52—C53—H53119.3
C91—Au3—C71178.3 (4)C53—C54—C55121.0 (13)
C81—Au3—Cl1178.6 (3)C53—C54—H54119.5
C91—Au3—Cl190.6 (3)C55—C54—H54119.5
C71—Au3—Cl190.8 (3)C54—C55—C56118.4 (12)
C11—P1—C21102.0 (4)C54—C55—H55120.8
C11—P1—C1107.5 (5)C56—C55—H55120.8
C21—P1—C1105.9 (5)C55—C56—C51121.7 (10)
C11—P1—Au1112.2 (3)C55—C56—H56119.1
C21—P1—Au1113.7 (3)C51—C56—H56119.1
C1—P1—Au1114.6 (4)C66—C61—C62118.8 (11)
C31—P2—C2106.0 (5)C66—C61—P3121.0 (8)
C31—P2—C1106.3 (5)C62—C61—P3120.0 (9)
C2—P2—C1103.0 (5)C63—C62—C61119.5 (13)
C31—P2—Au2113.2 (3)C63—C62—H62120.3
C2—P2—Au2113.3 (4)C61—C62—H62120.3
C1—P2—Au2114.1 (3)C64—C63—C62122.4 (14)
C61—P3—C51107.3 (5)C64—C63—H63118.8
C61—P3—C2i105.1 (5)C62—C63—H63118.8
C51—P3—C2i104.8 (5)C63—C64—C65117.9 (15)
C61—P3—Au1114.9 (4)C63—C64—H64121.0
C51—P3—Au1109.9 (4)C65—C64—H64121.0
C2i—P3—Au1114.2 (3)C64—C65—C66121.5 (14)
F14—F14—C950 (10)C64—C65—H65119.2
P1—C1—P2110.0 (6)C66—C65—H65119.2
P1—C1—H1A109.7C65—C66—C61119.8 (12)
P2—C1—H1A109.7C65—C66—H66120.1
P1—C1—H1B109.7C61—C66—H66120.1
P2—C1—H1B109.7C76—C71—C72116.2 (10)
H1A—C1—H1B108.2C76—C71—Au3119.9 (8)
P3i—C2—P2111.8 (6)C72—C71—Au3123.9 (10)
P3i—C2—H2A109.3F1—C72—C73117.1 (11)
P2—C2—H2A109.3F1—C72—C71120.0 (11)
P3i—C2—H2B109.3C73—C72—C71122.9 (13)
P2—C2—H2B109.3F2—C73—C74121.5 (12)
H2A—C2—H2B107.9F2—C73—C72120.8 (14)
C16—C11—C12120.3 (11)C74—C73—C72117.5 (12)
C16—C11—P1119.9 (8)C75—C74—F3118.7 (14)
C12—C11—P1119.8 (8)C75—C74—C73122.5 (12)
C11—C12—C13119.4 (11)F3—C74—C73118.8 (12)
C11—C12—H12120.3C74—C75—F4121.8 (12)
C13—C12—H12120.3C74—C75—C76118.5 (14)
C14—C13—C12120.4 (12)F4—C75—C76119.7 (13)
C14—C13—H13119.8F5—C76—C71119.6 (9)
C12—C13—H13119.8F5—C76—C75118.0 (12)
C13—C14—C15120.4 (12)C71—C76—C75122.3 (12)
C13—C14—H14119.8C86—C81—C82114.8 (11)
C15—C14—H14119.8C86—C81—Au3121.0 (9)
C14—C15—C16120.1 (12)C82—C81—Au3124.2 (8)
C14—C15—H15120.0C83—C82—F6117.2 (11)
C16—C15—H15120.0C83—C82—C81124.8 (11)
C11—C16—C15119.4 (12)F6—C82—C81117.8 (11)
C11—C16—H16120.3F7—C83—C82120.9 (12)
C15—C16—H16120.3F7—C83—C84120.7 (12)
C22—C21—C26120.0 (11)C82—C83—C84118.2 (12)
C22—C21—P1122.4 (7)F8—C84—C85120.6 (12)
C26—C21—P1117.4 (9)F8—C84—C83120.0 (13)
C21—C22—C23119.5 (10)C85—C84—C83119.4 (13)
C21—C22—H22120.2C84—C85—F9118.8 (12)
C23—C22—H22120.2C84—C85—C86121.0 (12)
C24—C23—C22120.2 (12)F9—C85—C86120.2 (12)
C24—C23—H23119.9F10—C86—C81120.2 (11)
C22—C23—H23119.9F10—C86—C85118.1 (11)
C25—C24—C23120.0 (13)C81—C86—C85121.6 (11)
C25—C24—H24120.0C96—C91—C92115.1 (10)
C23—C24—H24120.0C96—C91—Au3123.4 (8)
C24—C25—C26120.5 (12)C92—C91—Au3121.4 (9)
C24—C25—H25119.7F11—C92—C91120.6 (10)
C26—C25—H25119.7F11—C92—C93117.0 (10)
C21—C26—C25119.7 (12)C91—C92—C93122.3 (12)
C21—C26—H26120.2C94—C93—F12122.0 (10)
C25—C26—H26120.2C94—C93—C92119.0 (11)
C32—C31—C36120.2 (12)F12—C93—C92119.0 (12)
C32—C31—P2120.6 (8)C93—C94—F13118.5 (11)
C36—C31—P2119.2 (8)C93—C94—C95121.5 (11)
C31—C32—C33120.4 (11)F13—C94—C95119.9 (12)
C31—C32—H32119.8F14—C95—F140.0 (11)
C33—C32—H32119.8F14—C95—C94121.1 (11)
C34—C33—C32119.4 (12)F14—C95—C94121.1 (11)
C34—C33—H33120.3F14—C95—C96121.5 (12)
C32—C33—H33120.3F14—C95—C96121.5 (12)
C33—C34—C35121.5 (13)C94—C95—C96117.4 (12)
C33—C34—H34119.2C91—C96—F15119.5 (10)
C35—C34—H34119.2C91—C96—C95124.5 (11)
C34—C35—C36119.5 (12)F15—C96—C95116.0 (11)
Symmetry code: (i) x, y+1, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C32—H32···F11ii0.952.513.412 (14)159
C52—H52···F140.952.503.417 (17)163
Symmetry code: (ii) x, y+2, z.
 

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