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The title compound belongs to a family of dimeric clusters formed through bonding of electron-rich iron carbonyls to electron-deficient thallium atoms previously reported. Pressurization under CO of the thallium-iron carbonyl [Et4N]2[Tl2Fe4(CO)16] yielded crystals of [Et4N]2[Tl2Fe6(CO)24], which crystallizes in the orthorhombic, centrosymmetric space group Cmca.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, I

fcf

Structure factor file (CIF format)
Contains datablock global

CCDC reference: 130516

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