organic compounds
The minor diastereomer ( adduct) of the tertiary homoallylic alcohols, formed in the Zn-mediated reaction between 2-methyl-1-phenyl-1-propanone (isobutyrophenone) and 3-chloro-1-phenylpropene (cinnamyl chloride) in tetrahydrofuran/NH4Cl(aq), was isolated and crystallized. The structure of the title compound,C19H22O, confirms that the major and minor diastereomers of the adduct formed in the reaction have syn and anti configurations, respectively.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 130781