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The title compound, [HB(pz)3]VCl2(thf) or [VCl2(C9H10BN6)(C4H8O)] (pz = pyrazolyl, thf = tetrahydrofuran), is an analogue of the unknown [eta]5-CpVCl2 (Cp = unsubstituted cyclopentadienyl). The pyrazolyl complex was prepared from VCl3(thf)3 and K[HB(pz)3]. The molecule adopts a structure comparable to the piano-stool arrangement of a half-sandwich complex.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks mat1, global

fcf

Structure factor file (CIF format)
Contains datablock mat1

CCDC reference: 130606

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