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The title compound, [Mn2O2(C10H8N2)4](ClO4)3.2C6H5NO2.0.5H2O, retains a half water molecule and incorporates two nitrobenzene molecules in the structure when recrystallized from a mixture of nitrobenzene and nitromethane. The two manganese sites have differing geometries suggestive of oxidation states MnIII and MnIV. The supposed d4 configuration of MnIII implies a Jahn-Teller distortion, which is observed.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, os1015

hkl

Structure factor file (CIF format)
Contains datablock 1

CCDC reference: 130778

-1
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