Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803025558/om6189sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536803025558/om6189Isup2.hkl |
CCDC reference: 227753
Data collection: XSCANS (Fait, 1991); cell refinement: XSCANS; data reduction: XSCANS; program(s) used to solve structure: SHELXTL-Plus (Sheldrick, 1998); program(s) used to refine structure: SHELXTL-Plus; molecular graphics: SHELXTL-Plus; software used to prepare material for publication: SHELXTL-Plus.
[Pd2(C6F5S)4(C18H10F5P)2] | F(000) = 3344 |
Mr = 1713.74 | Dx = 1.804 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 36 reflections |
a = 26.807 (3) Å | θ = 2.8–12.0° |
b = 14.3442 (18) Å | µ = 0.88 mm−1 |
c = 20.3758 (15) Å | T = 296 K |
β = 126.362 (6)° | Prism, red |
V = 6309.4 (13) Å3 | 0.3 × 0.3 × 0.2 mm |
Z = 4 |
Bruker P4 diffractometer | 3530 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube, FN4 | Rint = 0.037 |
Graphite monochromator | θmax = 25.0°, θmin = 1.8° |
2θ/ω scans | h = −1→31 |
Absorption correction: ψ scan (Fait, 1991) | k = −1→17 |
Tmin = 0.761, Tmax = 0.841 | l = −24→19 |
6476 measured reflections | 3 standard reflections every 97 reflections |
5561 independent reflections | intensity decay: 4.1% |
Refinement on F2 | Primary atom site location: heavy-atom method |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.047 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.111 | H-atom parameters constrained |
S = 1.00 | w = 1/[σ2(Fo2) + (0.0437P)2] where P = (Fo2 + 2Fc2)/3 |
5561 reflections | (Δ/σ)max = 0.001 |
442 parameters | Δρmax = 0.44 e Å−3 |
36 restraints | Δρmin = −0.31 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Pd1 | 0.304691 (17) | 0.73813 (3) | 0.10772 (2) | 0.04837 (14) | |
P1 | 0.32023 (7) | 0.63043 (12) | 0.20065 (9) | 0.0653 (4) | |
S1 | 0.21640 (6) | 0.66039 (9) | −0.00180 (7) | 0.0497 (3) | |
S2 | 0.38948 (7) | 0.82052 (12) | 0.21230 (8) | 0.0697 (5) | |
C1 | 0.2414 (2) | 0.5562 (4) | −0.0199 (3) | 0.0542 (14) | |
C2 | 0.2160 (3) | 0.4724 (4) | −0.0204 (4) | 0.0673 (16) | |
C3 | 0.2287 (4) | 0.3897 (5) | −0.0418 (5) | 0.097 (2) | |
C4 | 0.2695 (5) | 0.3898 (6) | −0.0606 (5) | 0.107 (3) | |
C5 | 0.3003 (4) | 0.4693 (6) | −0.0548 (4) | 0.093 (2) | |
C6 | 0.2839 (3) | 0.5522 (5) | −0.0377 (4) | 0.0702 (16) | |
C7 | 0.4184 (2) | 0.8848 (4) | 0.1676 (3) | 0.0553 (14) | |
C8 | 0.4405 (2) | 0.8438 (5) | 0.1280 (3) | 0.0641 (15) | |
C9 | 0.4655 (3) | 0.8951 (6) | 0.0965 (4) | 0.0707 (17) | |
C10 | 0.4695 (3) | 0.9886 (6) | 0.1045 (4) | 0.0775 (19) | |
C11 | 0.4495 (3) | 1.0319 (5) | 0.1436 (4) | 0.0710 (17) | |
C12 | 0.4240 (2) | 0.9807 (4) | 0.1742 (3) | 0.0601 (15) | |
C13 | 0.3749 (3) | 0.6613 (5) | 0.3095 (3) | 0.0701 (17) | |
C14 | 0.4296 (4) | 0.6188 (6) | 0.3666 (4) | 0.093 (2) | |
C15 | 0.4663 (4) | 0.6464 (7) | 0.4483 (4) | 0.106 (3) | |
C16 | 0.4483 (5) | 0.7164 (8) | 0.4728 (5) | 0.114 (3) | |
C17 | 0.3947 (4) | 0.7598 (7) | 0.4192 (5) | 0.102 (3) | |
C18 | 0.3591 (3) | 0.7328 (6) | 0.3382 (4) | 0.084 (2) | |
C19 | 0.2503 (4) | 0.6024 (6) | 0.1933 (4) | 0.101 (3) | |
C20 | 0.2526 (5) | 0.5293 (8) | 0.2410 (5) | 0.159 (4) | |
H20A | 0.2886 | 0.4945 | 0.2749 | 0.190* | |
C21 | 0.1994 (7) | 0.5105 (11) | 0.2359 (7) | 0.211 (7) | |
H21A | 0.1986 | 0.4624 | 0.2659 | 0.253* | |
C22 | 0.1486 (6) | 0.5644 (14) | 0.1858 (7) | 0.241 (8) | |
H22A | 0.1130 | 0.5504 | 0.1816 | 0.289* | |
C23 | 0.1460 (4) | 0.6372 (13) | 0.1413 (5) | 0.221 (6) | |
H23A | 0.1106 | 0.6737 | 0.1095 | 0.265* | |
C24 | 0.1990 (4) | 0.6545 (9) | 0.1455 (5) | 0.152 (4) | |
H24A | 0.1989 | 0.7028 | 0.1150 | 0.182* | |
C25 | 0.3505 (4) | 0.5268 (5) | 0.1851 (4) | 0.083 (2) | |
C26 | 0.3322 (4) | 0.4365 (7) | 0.1827 (5) | 0.129 (3) | |
H26A | 0.3002 | 0.4254 | 0.1874 | 0.155* | |
C27 | 0.3603 (8) | 0.3616 (11) | 0.1735 (10) | 0.192 (8) | |
H27A | 0.3495 | 0.3010 | 0.1765 | 0.230* | |
C28 | 0.4031 (8) | 0.3767 (12) | 0.1602 (9) | 0.187 (8) | |
H28A | 0.4203 | 0.3262 | 0.1517 | 0.224* | |
C29 | 0.4213 (5) | 0.4630 (9) | 0.1588 (5) | 0.144 (4) | |
H29A | 0.4508 | 0.4726 | 0.1493 | 0.173* | |
C30 | 0.3950 (4) | 0.5394 (6) | 0.1722 (4) | 0.105 (3) | |
H30A | 0.4080 | 0.5995 | 0.1723 | 0.125* | |
F2 | 0.17796 (16) | 0.4696 (2) | 0.0018 (2) | 0.0857 (11) | |
F3 | 0.1990 (2) | 0.3119 (3) | −0.0469 (3) | 0.147 (2) | |
F4 | 0.2832 (3) | 0.3103 (3) | −0.0816 (3) | 0.164 (2) | |
F5 | 0.3435 (2) | 0.4686 (4) | −0.0678 (3) | 0.1306 (17) | |
F6 | 0.31273 (17) | 0.6297 (3) | −0.0347 (2) | 0.0952 (12) | |
F8 | 0.43742 (18) | 0.7498 (3) | 0.1188 (3) | 0.0973 (12) | |
F9 | 0.48525 (18) | 0.8511 (4) | 0.0581 (3) | 0.1153 (15) | |
F10 | 0.49372 (18) | 1.0374 (3) | 0.0735 (3) | 0.1165 (15) | |
F11 | 0.4531 (2) | 1.1250 (3) | 0.1521 (2) | 0.1141 (14) | |
F12 | 0.40311 (16) | 1.0270 (3) | 0.2105 (2) | 0.0834 (10) | |
F14 | 0.4507 (2) | 0.5472 (4) | 0.3478 (2) | 0.1429 (19) | |
F15 | 0.5207 (3) | 0.6010 (4) | 0.5007 (3) | 0.173 (3) | |
F16 | 0.4839 (3) | 0.7408 (4) | 0.5515 (3) | 0.164 (2) | |
F17 | 0.3766 (3) | 0.8311 (4) | 0.4423 (3) | 0.158 (2) | |
F18 | 0.3063 (2) | 0.7793 (3) | 0.2865 (3) | 0.1163 (15) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Pd1 | 0.0437 (2) | 0.0583 (3) | 0.0460 (2) | −0.0089 (2) | 0.02812 (17) | −0.0056 (2) |
P1 | 0.0654 (10) | 0.0771 (11) | 0.0495 (8) | −0.0236 (9) | 0.0319 (8) | −0.0043 (8) |
S1 | 0.0470 (7) | 0.0552 (8) | 0.0505 (7) | −0.0098 (6) | 0.0309 (6) | −0.0061 (6) |
S2 | 0.0602 (9) | 0.0939 (12) | 0.0503 (8) | −0.0305 (9) | 0.0302 (7) | −0.0105 (8) |
C1 | 0.051 (3) | 0.061 (4) | 0.042 (3) | −0.004 (3) | 0.022 (3) | −0.007 (2) |
C2 | 0.056 (4) | 0.058 (4) | 0.064 (4) | −0.002 (3) | 0.023 (3) | −0.001 (3) |
C3 | 0.098 (6) | 0.063 (5) | 0.086 (5) | −0.003 (5) | 0.032 (4) | −0.006 (4) |
C4 | 0.136 (8) | 0.077 (6) | 0.090 (5) | 0.022 (6) | 0.058 (6) | −0.009 (5) |
C5 | 0.087 (5) | 0.110 (7) | 0.076 (5) | 0.036 (5) | 0.046 (4) | −0.002 (4) |
C6 | 0.074 (4) | 0.071 (4) | 0.068 (4) | 0.003 (4) | 0.044 (4) | −0.005 (3) |
C7 | 0.039 (3) | 0.073 (4) | 0.049 (3) | −0.008 (3) | 0.024 (2) | −0.008 (3) |
C8 | 0.050 (3) | 0.067 (4) | 0.066 (4) | −0.004 (3) | 0.030 (3) | −0.009 (3) |
C9 | 0.048 (3) | 0.102 (6) | 0.072 (4) | 0.003 (4) | 0.042 (3) | −0.002 (4) |
C10 | 0.045 (4) | 0.110 (6) | 0.073 (4) | −0.003 (4) | 0.033 (3) | 0.012 (4) |
C11 | 0.054 (4) | 0.072 (5) | 0.070 (4) | −0.004 (3) | 0.027 (3) | 0.010 (3) |
C12 | 0.044 (3) | 0.071 (4) | 0.057 (3) | 0.000 (3) | 0.025 (3) | −0.003 (3) |
C13 | 0.077 (4) | 0.079 (5) | 0.057 (4) | −0.028 (4) | 0.042 (4) | −0.001 (3) |
C14 | 0.105 (6) | 0.082 (5) | 0.071 (5) | −0.019 (5) | 0.040 (5) | −0.009 (4) |
C15 | 0.106 (7) | 0.112 (7) | 0.053 (4) | −0.033 (6) | 0.021 (5) | 0.004 (5) |
C16 | 0.136 (8) | 0.137 (9) | 0.061 (5) | −0.072 (7) | 0.054 (6) | −0.030 (6) |
C17 | 0.122 (7) | 0.125 (7) | 0.080 (5) | −0.056 (6) | 0.071 (5) | −0.043 (5) |
C18 | 0.083 (5) | 0.104 (6) | 0.078 (5) | −0.034 (5) | 0.055 (4) | −0.020 (4) |
C19 | 0.091 (5) | 0.169 (8) | 0.054 (4) | −0.069 (5) | 0.049 (4) | −0.027 (5) |
C20 | 0.171 (9) | 0.228 (11) | 0.089 (6) | −0.121 (8) | 0.084 (6) | −0.027 (6) |
C21 | 0.201 (12) | 0.342 (17) | 0.100 (8) | −0.169 (13) | 0.095 (8) | −0.029 (9) |
C22 | 0.138 (9) | 0.50 (2) | 0.104 (9) | −0.162 (13) | 0.084 (8) | −0.061 (12) |
C23 | 0.093 (6) | 0.51 (2) | 0.082 (6) | −0.047 (10) | 0.063 (5) | 0.002 (9) |
C24 | 0.084 (6) | 0.312 (13) | 0.080 (5) | −0.040 (8) | 0.060 (5) | −0.019 (7) |
C25 | 0.090 (5) | 0.068 (5) | 0.053 (4) | −0.007 (4) | 0.021 (4) | −0.001 (3) |
C26 | 0.135 (8) | 0.079 (6) | 0.106 (6) | −0.020 (6) | 0.036 (6) | 0.000 (5) |
C27 | 0.23 (2) | 0.074 (8) | 0.152 (11) | −0.007 (12) | 0.050 (12) | −0.015 (7) |
C28 | 0.206 (18) | 0.117 (13) | 0.118 (9) | 0.049 (13) | 0.030 (11) | −0.016 (9) |
C29 | 0.142 (9) | 0.151 (10) | 0.093 (6) | 0.057 (9) | 0.045 (6) | −0.004 (7) |
C30 | 0.121 (7) | 0.082 (6) | 0.087 (5) | 0.029 (5) | 0.049 (5) | 0.004 (4) |
F2 | 0.068 (2) | 0.071 (2) | 0.097 (3) | −0.0094 (19) | 0.037 (2) | 0.013 (2) |
F3 | 0.146 (4) | 0.055 (3) | 0.185 (5) | −0.015 (3) | 0.068 (4) | −0.013 (3) |
F4 | 0.200 (6) | 0.098 (4) | 0.169 (5) | 0.044 (4) | 0.096 (4) | −0.032 (3) |
F5 | 0.138 (4) | 0.154 (5) | 0.132 (4) | 0.051 (3) | 0.098 (3) | 0.000 (3) |
F6 | 0.094 (3) | 0.105 (3) | 0.125 (3) | 0.004 (2) | 0.086 (3) | −0.002 (3) |
F8 | 0.102 (3) | 0.081 (3) | 0.123 (3) | −0.001 (2) | 0.074 (3) | −0.017 (2) |
F9 | 0.101 (3) | 0.164 (4) | 0.122 (3) | 0.017 (3) | 0.088 (3) | −0.005 (3) |
F10 | 0.096 (3) | 0.152 (4) | 0.125 (3) | −0.017 (3) | 0.079 (3) | 0.033 (3) |
F11 | 0.134 (4) | 0.074 (3) | 0.126 (3) | −0.014 (3) | 0.072 (3) | 0.009 (2) |
F12 | 0.084 (2) | 0.086 (3) | 0.087 (2) | 0.001 (2) | 0.054 (2) | −0.017 (2) |
F14 | 0.136 (4) | 0.140 (4) | 0.072 (3) | 0.021 (4) | 0.018 (3) | −0.009 (3) |
F15 | 0.151 (5) | 0.168 (5) | 0.075 (3) | −0.009 (4) | −0.002 (3) | −0.002 (3) |
F16 | 0.198 (5) | 0.190 (5) | 0.068 (3) | −0.081 (4) | 0.060 (3) | −0.049 (3) |
F17 | 0.174 (5) | 0.185 (6) | 0.142 (4) | −0.051 (4) | 0.109 (4) | −0.078 (4) |
F18 | 0.108 (3) | 0.141 (4) | 0.114 (3) | −0.012 (3) | 0.073 (3) | −0.031 (3) |
Pd1—P1 | 2.2826 (16) | C13—C18 | 1.366 (9) |
Pd1—S2 | 2.3153 (14) | C14—F14 | 1.333 (8) |
Pd1—S1 | 2.3586 (13) | C14—C15 | 1.397 (9) |
Pd1—S1i | 2.3768 (14) | C15—C16 | 1.334 (12) |
P1—C25 | 1.810 (8) | C15—F15 | 1.358 (10) |
P1—C19 | 1.834 (7) | C16—C17 | 1.335 (12) |
P1—C13 | 1.846 (6) | C16—F16 | 1.338 (8) |
S1—C1 | 1.765 (6) | C17—F17 | 1.331 (9) |
S1—Pd1i | 2.3768 (14) | C17—C18 | 1.385 (10) |
S2—C7 | 1.765 (5) | C18—F18 | 1.338 (8) |
C1—C2 | 1.380 (8) | C19—C24 | 1.346 (12) |
C1—C6 | 1.386 (7) | C19—C20 | 1.406 (11) |
C2—F2 | 1.338 (7) | C20—C21 | 1.394 (13) |
C2—C3 | 1.376 (10) | C20—H20A | 0.9300 |
C3—F3 | 1.338 (8) | C21—C22 | 1.36 (2) |
C3—C4 | 1.355 (11) | C21—H21A | 0.9300 |
C4—F4 | 1.344 (8) | C22—C23 | 1.36 (2) |
C4—C5 | 1.372 (11) | C22—H22A | 0.9300 |
C5—F5 | 1.330 (8) | C23—C24 | 1.392 (11) |
C5—C6 | 1.382 (9) | C23—H23A | 0.9300 |
C6—F6 | 1.334 (7) | C24—H24A | 0.9300 |
C7—C12 | 1.381 (8) | C25—C30 | 1.375 (10) |
C7—C8 | 1.385 (7) | C25—C26 | 1.377 (10) |
C8—F8 | 1.357 (7) | C26—C27 | 1.387 (17) |
C8—C9 | 1.385 (8) | C26—H26A | 0.9300 |
C9—F9 | 1.334 (7) | C27—C28 | 1.34 (2) |
C9—C10 | 1.347 (9) | C27—H27A | 0.9300 |
C10—F10 | 1.341 (7) | C28—C29 | 1.337 (17) |
C10—C11 | 1.348 (9) | C28—H28A | 0.9300 |
C11—F11 | 1.342 (7) | C29—C30 | 1.414 (11) |
C11—C12 | 1.379 (8) | C29—H29A | 0.9300 |
C12—F12 | 1.338 (6) | C30—H30A | 0.9300 |
C13—C14 | 1.362 (9) | ||
P1—Pd1—S2 | 89.15 (5) | C14—C13—P1 | 127.2 (6) |
P1—Pd1—S1 | 92.99 (5) | C18—C13—P1 | 117.9 (6) |
S2—Pd1—S1 | 177.51 (6) | F14—C14—C13 | 121.7 (7) |
P1—Pd1—S1i | 174.80 (5) | F14—C14—C15 | 116.2 (8) |
S2—Pd1—S1i | 95.64 (5) | C13—C14—C15 | 122.1 (8) |
S1—Pd1—S1i | 82.26 (5) | C16—C15—F15 | 121.6 (8) |
C25—P1—C19 | 110.4 (4) | C16—C15—C14 | 120.3 (9) |
C25—P1—C13 | 106.8 (3) | F15—C15—C14 | 118.0 (9) |
C19—P1—C13 | 101.3 (3) | C17—C16—C15 | 119.8 (8) |
C25—P1—Pd1 | 106.9 (2) | C17—C16—F16 | 121.0 (10) |
C19—P1—Pd1 | 113.9 (3) | C15—C16—F16 | 119.2 (11) |
C13—P1—Pd1 | 117.3 (2) | F17—C17—C16 | 120.7 (8) |
C1—S1—Pd1 | 107.78 (17) | F17—C17—C18 | 119.8 (10) |
C1—S1—Pd1i | 104.12 (18) | C16—C17—C18 | 119.5 (9) |
Pd1—S1—Pd1i | 97.74 (5) | F18—C18—C13 | 119.3 (6) |
C7—S2—Pd1 | 106.48 (17) | F18—C18—C17 | 117.3 (8) |
C2—C1—C6 | 116.2 (6) | C13—C18—C17 | 123.4 (8) |
C2—C1—S1 | 119.4 (5) | C24—C19—C20 | 121.4 (8) |
C6—C1—S1 | 124.3 (5) | C24—C19—P1 | 119.6 (7) |
F2—C2—C3 | 117.6 (7) | C20—C19—P1 | 118.9 (8) |
F2—C2—C1 | 119.8 (6) | C21—C20—C19 | 118.0 (11) |
C3—C2—C1 | 122.6 (7) | C21—C20—H20A | 121.0 |
F3—C3—C4 | 121.4 (9) | C19—C20—H20A | 121.0 |
F3—C3—C2 | 119.7 (9) | C22—C21—C20 | 118.1 (12) |
C4—C3—C2 | 118.8 (8) | C22—C21—H21A | 121.0 |
F4—C4—C3 | 120.6 (10) | C20—C21—H21A | 121.0 |
F4—C4—C5 | 117.9 (10) | C23—C22—C21 | 124.9 (12) |
C3—C4—C5 | 121.5 (8) | C23—C22—H22A | 117.6 |
F5—C5—C4 | 121.8 (8) | C21—C22—H22A | 117.6 |
F5—C5—C6 | 120.0 (9) | C22—C23—C24 | 116.7 (13) |
C4—C5—C6 | 118.1 (7) | C22—C23—H23A | 121.7 |
F6—C6—C5 | 117.8 (6) | C24—C23—H23A | 121.7 |
F6—C6—C1 | 119.7 (6) | C19—C24—C23 | 120.9 (11) |
C5—C6—C1 | 122.4 (7) | C19—C24—H24A | 119.6 |
C12—C7—C8 | 114.9 (5) | C23—C24—H24A | 119.6 |
C12—C7—S2 | 121.7 (5) | C30—C25—C26 | 116.7 (9) |
C8—C7—S2 | 123.3 (5) | C30—C25—P1 | 117.1 (6) |
F8—C8—C7 | 119.4 (6) | C26—C25—P1 | 126.2 (8) |
F8—C8—C9 | 118.1 (6) | C25—C26—C27 | 121.5 (12) |
C7—C8—C9 | 122.5 (6) | C25—C26—H26A | 119.3 |
F9—C9—C10 | 120.8 (7) | C27—C26—H26A | 119.3 |
F9—C9—C8 | 119.4 (7) | C28—C27—C26 | 120.0 (18) |
C10—C9—C8 | 119.8 (6) | C28—C27—H27A | 120.0 |
F10—C10—C9 | 119.2 (7) | C26—C27—H27A | 120.0 |
F10—C10—C11 | 120.8 (7) | C29—C28—C27 | 121 (2) |
C9—C10—C11 | 120.1 (6) | C29—C28—H28A | 119.3 |
F11—C11—C10 | 120.8 (7) | C27—C28—H28A | 119.3 |
F11—C11—C12 | 119.2 (7) | C28—C29—C30 | 118.9 (14) |
C10—C11—C12 | 120.0 (6) | C28—C29—H29A | 120.6 |
F12—C12—C11 | 117.9 (6) | C30—C29—H29A | 120.6 |
F12—C12—C7 | 119.4 (5) | C25—C30—C29 | 121.5 (10) |
C11—C12—C7 | 122.7 (6) | C25—C30—H30A | 119.2 |
C14—C13—C18 | 114.9 (7) | C29—C30—H30A | 119.2 |
S2—Pd1—P1—C25 | −107.5 (3) | C8—C7—C12—F12 | 179.1 (4) |
S1—Pd1—P1—C25 | 73.8 (3) | S2—C7—C12—F12 | −4.6 (7) |
S2—Pd1—P1—C19 | 130.3 (3) | C8—C7—C12—C11 | 0.2 (8) |
S1—Pd1—P1—C19 | −48.4 (3) | S2—C7—C12—C11 | 176.4 (4) |
S2—Pd1—P1—C13 | 12.3 (3) | C25—P1—C13—C14 | 4.0 (7) |
S1—Pd1—P1—C13 | −166.4 (3) | C19—P1—C13—C14 | 119.6 (7) |
P1—Pd1—S1—C1 | −70.3 (2) | Pd1—P1—C13—C14 | −115.8 (6) |
S1i—Pd1—S1—C1 | 107.6 (2) | C25—P1—C13—C18 | −174.1 (5) |
P1—Pd1—S1—Pd1i | −177.88 (6) | C19—P1—C13—C18 | −58.5 (6) |
S1i—Pd1—S1—Pd1i | 0.0 | Pd1—P1—C13—C18 | 66.1 (5) |
P1—Pd1—S2—C7 | 154.5 (2) | C18—C13—C14—F14 | 179.1 (6) |
S1i—Pd1—S2—C7 | −23.5 (2) | P1—C13—C14—F14 | 1.0 (10) |
Pd1—S1—C1—C2 | 125.7 (4) | C18—C13—C14—C15 | 0.5 (10) |
Pd1i—S1—C1—C2 | −131.3 (4) | P1—C13—C14—C15 | −177.6 (6) |
Pd1—S1—C1—C6 | −57.4 (5) | F14—C14—C15—C16 | −178.8 (7) |
Pd1i—S1—C1—C6 | 45.7 (5) | C13—C14—C15—C16 | −0.1 (12) |
C6—C1—C2—F2 | 175.3 (5) | F14—C14—C15—F15 | 2.4 (11) |
S1—C1—C2—F2 | −7.5 (7) | C13—C14—C15—F15 | −179.0 (7) |
C6—C1—C2—C3 | −3.6 (8) | F15—C15—C16—C17 | 179.4 (7) |
S1—C1—C2—C3 | 173.5 (5) | C14—C15—C16—C17 | 0.6 (13) |
F2—C2—C3—F3 | 6.0 (10) | F15—C15—C16—F16 | −1.8 (13) |
C1—C2—C3—F3 | −175.0 (6) | C14—C15—C16—F16 | 179.4 (7) |
F2—C2—C3—C4 | −176.8 (7) | C15—C16—C17—F17 | −178.6 (7) |
C1—C2—C3—C4 | 2.2 (10) | F16—C16—C17—F17 | 2.7 (12) |
F3—C3—C4—F4 | −3.0 (12) | C15—C16—C17—C18 | −1.4 (13) |
C2—C3—C4—F4 | 179.8 (6) | F16—C16—C17—C18 | 179.8 (7) |
F3—C3—C4—C5 | −179.5 (7) | C14—C13—C18—F18 | 179.5 (6) |
C2—C3—C4—C5 | 3.3 (12) | P1—C13—C18—F18 | −2.2 (8) |
F4—C4—C5—F5 | −1.3 (12) | C14—C13—C18—C17 | −1.4 (10) |
C3—C4—C5—F5 | 175.3 (7) | P1—C13—C18—C17 | 176.9 (5) |
F4—C4—C5—C6 | 176.5 (6) | F17—C17—C18—F18 | −1.8 (10) |
C3—C4—C5—C6 | −7.0 (12) | C16—C17—C18—F18 | −179.0 (7) |
F5—C5—C6—F6 | −0.1 (9) | F17—C17—C18—C13 | 179.1 (6) |
C4—C5—C6—F6 | −177.9 (6) | C16—C17—C18—C13 | 1.9 (11) |
F5—C5—C6—C1 | −176.8 (6) | C25—P1—C19—C24 | −130.6 (7) |
C4—C5—C6—C1 | 5.4 (10) | C13—P1—C19—C24 | 116.6 (7) |
C2—C1—C6—F6 | −176.8 (5) | Pd1—P1—C19—C24 | −10.3 (8) |
S1—C1—C6—F6 | 6.1 (8) | C25—P1—C19—C20 | 52.5 (7) |
C2—C1—C6—C5 | −0.2 (9) | C13—P1—C19—C20 | −60.4 (7) |
S1—C1—C6—C5 | −177.2 (5) | Pd1—P1—C19—C20 | 172.7 (5) |
Pd1—S2—C7—C12 | 122.6 (4) | C24—C19—C20—C21 | 1.7 (14) |
Pd1—S2—C7—C8 | −61.5 (5) | P1—C19—C20—C21 | 178.6 (8) |
C12—C7—C8—F8 | 179.7 (5) | C19—C20—C21—C22 | −0.6 (18) |
S2—C7—C8—F8 | 3.5 (7) | C20—C21—C22—C23 | −2 (2) |
C12—C7—C8—C9 | −0.9 (8) | C21—C22—C23—C24 | 3 (2) |
S2—C7—C8—C9 | −177.1 (4) | C20—C19—C24—C23 | −0.5 (15) |
F8—C8—C9—F9 | 0.3 (8) | P1—C19—C24—C23 | −177.4 (8) |
C7—C8—C9—F9 | −179.1 (5) | C22—C23—C24—C19 | −1.6 (18) |
F8—C8—C9—C10 | −179.9 (6) | C19—P1—C25—C30 | 167.1 (5) |
C7—C8—C9—C10 | 0.7 (9) | C13—P1—C25—C30 | −83.7 (6) |
F9—C9—C10—F10 | −0.1 (9) | Pd1—P1—C25—C30 | 42.6 (6) |
C8—C9—C10—F10 | −179.9 (5) | C19—P1—C25—C26 | −11.1 (7) |
F9—C9—C10—C11 | −179.9 (5) | C13—P1—C25—C26 | 98.2 (6) |
C8—C9—C10—C11 | 0.4 (10) | Pd1—P1—C25—C26 | −135.5 (6) |
F10—C10—C11—F11 | 0.3 (9) | C30—C25—C26—C27 | 4.4 (13) |
C9—C10—C11—F11 | −180.0 (6) | P1—C25—C26—C27 | −177.5 (9) |
F10—C10—C11—C12 | 179.2 (5) | C25—C26—C27—C28 | −5 (2) |
C9—C10—C11—C12 | −1.1 (9) | C26—C27—C28—C29 | 3 (3) |
F11—C11—C12—F12 | 0.8 (8) | C27—C28—C29—C30 | 0 (2) |
C10—C11—C12—F12 | −178.1 (5) | C26—C25—C30—C29 | −1.2 (11) |
F11—C11—C12—C7 | 179.7 (5) | P1—C25—C30—C29 | −179.5 (6) |
C10—C11—C12—C7 | 0.8 (9) | C28—C29—C30—C25 | −1.1 (14) |
Symmetry code: (i) −x+1/2, −y+3/2, −z. |