Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536801000782/om6003sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536801000782/om6003Isup2.hkl |
CCDC reference: 159742
The title compound was prepared in a three-necked flask containing sodium hydroxide (8 g, 200 mmol), triethylbenzylammonium chloride (0.25 g, 1 mmol) and water (25 ml). A solution of 9(10H)-acridone (5 mmol) in dichloromethane (125 ml) was added to 2-(9-anthryloxy)ethyl bromide (3 g, 10 mmol). At the end of the addition, the mixture was stirred and cooled in an ice water bath over 5 d. The solution was filtered and neutralized with aqueous hydrochloric acid (50 ml, 10%), sodium bicarbonate (50 ml, 5%) and water. The dichloromethane was removed on a rotary evaporator. The residue, recrystallized from ethyl ether and hexane (2/3), led to yellow crystals.
All H atoms were located by difference Fourier synthesis and refined with fixed individual displacement parameters [U(H) = 1.2Ueq(C)] using a riding model with aromatic C—H = 0.95 Å or methylene C—H = 0.99 Å.
Data collection: SMART (Siemens, 1995); cell refinement: SMART; data reduction: SAINT (Siemens, 1995); program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XP in SHELXTL-Plus (Sheldrick, 1991).
C29H21NO2 | Z = 4 |
Mr = 415.47 | F(000) = 872 |
Triclinic, P1 | Dx = 1.360 Mg m−3 |
a = 7.9833 (6) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 14.6168 (8) Å | Cell parameters from 512 reflections |
c = 18.744 (2) Å | θ = 1–20° |
α = 107.180 (5)° | µ = 0.09 mm−1 |
β = 96.514 (5)° | T = 173 K |
γ = 99.570 (5)° | Plate, yellow |
V = 2029.7 (3) Å3 | 0.51 × 0.38 × 0.14 mm |
Siemens CCD three-circle diffractometer | 7927 independent reflections |
Radiation source: fine-focus sealed tube | 4798 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.041 |
ω scans | θmax = 27.1°, θmin = 1.2° |
Absorption correction: empirical (using intensity measurements) (SADABS; Sheldrick, 1996) | h = −10→9 |
Tmin = 0.958, Tmax = 0.988 | k = −18→17 |
22246 measured reflections | l = −23→23 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.052 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.125 | H-atom parameters constrained |
S = 1.02 | w = 1/[σ2(Fo2) + (0.0533P)2 + 0.2959P] where P = (Fo2 + 2Fc2)/3 |
7927 reflections | (Δ/σ)max = 0.001 |
577 parameters | Δρmax = 0.25 e Å−3 |
0 restraints | Δρmin = −0.32 e Å−3 |
C29H21NO2 | γ = 99.570 (5)° |
Mr = 415.47 | V = 2029.7 (3) Å3 |
Triclinic, P1 | Z = 4 |
a = 7.9833 (6) Å | Mo Kα radiation |
b = 14.6168 (8) Å | µ = 0.09 mm−1 |
c = 18.744 (2) Å | T = 173 K |
α = 107.180 (5)° | 0.51 × 0.38 × 0.14 mm |
β = 96.514 (5)° |
Siemens CCD three-circle diffractometer | 7927 independent reflections |
Absorption correction: empirical (using intensity measurements) (SADABS; Sheldrick, 1996) | 4798 reflections with I > 2σ(I) |
Tmin = 0.958, Tmax = 0.988 | Rint = 0.041 |
22246 measured reflections |
R[F2 > 2σ(F2)] = 0.052 | 0 restraints |
wR(F2) = 0.125 | H-atom parameters constrained |
S = 1.02 | Δρmax = 0.25 e Å−3 |
7927 reflections | Δρmin = −0.32 e Å−3 |
577 parameters |
Experimental. ; |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
O1 | 0.27949 (17) | 0.27535 (10) | 0.18761 (8) | 0.0342 (4) | |
C1 | 0.3113 (3) | 0.21240 (15) | 0.22828 (12) | 0.0319 (5) | |
C2 | 0.3963 (3) | 0.25213 (17) | 0.30307 (12) | 0.0396 (6) | |
C3 | 0.4461 (3) | 0.3547 (2) | 0.34079 (14) | 0.0547 (7) | |
H3 | 0.4302 | 0.3993 | 0.3139 | 0.066* | |
C4 | 0.5177 (3) | 0.3889 (2) | 0.41644 (16) | 0.0753 (9) | |
H4 | 0.5502 | 0.4574 | 0.4423 | 0.090* | |
C5 | 0.5430 (4) | 0.3204 (3) | 0.45626 (16) | 0.0816 (11) | |
H5 | 0.5891 | 0.3445 | 0.5089 | 0.098* | |
C6 | 0.5032 (3) | 0.2241 (3) | 0.42092 (17) | 0.0725 (9) | |
H6 | 0.5264 | 0.1813 | 0.4485 | 0.087* | |
C7 | 0.4277 (3) | 0.1842 (2) | 0.34373 (13) | 0.0505 (7) | |
C8 | 0.3772 (3) | 0.0839 (2) | 0.30709 (16) | 0.0539 (7) | |
H8 | 0.4046 | 0.0402 | 0.3332 | 0.065* | |
C9 | 0.2886 (3) | 0.04634 (18) | 0.23394 (15) | 0.0467 (6) | |
C10 | 0.2281 (4) | −0.05682 (18) | 0.19613 (19) | 0.0592 (8) | |
H10 | 0.2563 | −0.1016 | 0.2210 | 0.071* | |
C11 | 0.1327 (4) | −0.0914 (2) | 0.12656 (19) | 0.0713 (9) | |
H11 | 0.0945 | −0.1601 | 0.1027 | 0.086* | |
C12 | 0.0890 (4) | −0.02647 (19) | 0.08880 (16) | 0.0609 (7) | |
H12 | 0.0179 | −0.0518 | 0.0402 | 0.073* | |
C13 | 0.1466 (3) | 0.07187 (16) | 0.12063 (13) | 0.0436 (6) | |
H13 | 0.1173 | 0.1143 | 0.0936 | 0.052* | |
C14 | 0.2503 (3) | 0.11209 (15) | 0.19383 (12) | 0.0349 (5) | |
C15 | 0.4121 (3) | 0.29040 (15) | 0.14411 (12) | 0.0343 (5) | |
H15A | 0.4285 | 0.2268 | 0.1113 | 0.041* | |
H15B | 0.5228 | 0.3261 | 0.1780 | 0.041* | |
C16 | 0.3518 (3) | 0.35028 (15) | 0.09647 (12) | 0.0335 (5) | |
H16A | 0.2381 | 0.3151 | 0.0651 | 0.040* | |
H16B | 0.3379 | 0.4139 | 0.1303 | 0.040* | |
N17 | 0.4748 (2) | 0.36787 (12) | 0.04693 (9) | 0.0308 (4) | |
C18 | 0.4563 (3) | 0.30264 (15) | −0.02586 (12) | 0.0319 (5) | |
C19 | 0.3378 (3) | 0.21200 (15) | −0.05010 (13) | 0.0393 (5) | |
H19 | 0.2696 | 0.1943 | −0.0160 | 0.047* | |
C20 | 0.3200 (3) | 0.14924 (16) | −0.12218 (14) | 0.0451 (6) | |
H20 | 0.2387 | 0.0888 | −0.1374 | 0.054* | |
C21 | 0.4183 (3) | 0.17188 (17) | −0.17388 (13) | 0.0463 (6) | |
H21 | 0.4045 | 0.1276 | −0.2238 | 0.056* | |
C22 | 0.5352 (3) | 0.25927 (16) | −0.15132 (12) | 0.0405 (6) | |
H22 | 0.6025 | 0.2755 | −0.1862 | 0.049* | |
C23 | 0.5575 (3) | 0.32535 (15) | −0.07771 (12) | 0.0322 (5) | |
C24 | 0.6830 (3) | 0.41800 (15) | −0.05659 (12) | 0.0323 (5) | |
O24 | 0.76190 (18) | 0.44363 (11) | −0.10304 (8) | 0.0407 (4) | |
C25 | 0.7112 (3) | 0.47748 (14) | 0.02314 (12) | 0.0302 (5) | |
C26 | 0.8428 (3) | 0.56241 (15) | 0.05064 (13) | 0.0360 (5) | |
H26 | 0.9126 | 0.5800 | 0.0170 | 0.043* | |
C27 | 0.8725 (3) | 0.62018 (16) | 0.12477 (13) | 0.0396 (6) | |
H27 | 0.9626 | 0.6770 | 0.1426 | 0.048* | |
C28 | 0.7690 (3) | 0.59479 (15) | 0.17389 (13) | 0.0394 (6) | |
H28 | 0.7882 | 0.6353 | 0.2253 | 0.047* | |
C29 | 0.6397 (3) | 0.51233 (15) | 0.14923 (12) | 0.0350 (5) | |
H29 | 0.5716 | 0.4960 | 0.1839 | 0.042* | |
C30 | 0.6069 (2) | 0.45158 (14) | 0.07310 (12) | 0.0294 (5) | |
O1A | −0.15790 (17) | 0.24023 (10) | 0.32763 (8) | 0.0367 (4) | |
C1A | −0.1203 (2) | 0.28802 (15) | 0.27553 (12) | 0.0300 (5) | |
C2A | −0.1767 (2) | 0.23783 (15) | 0.19863 (12) | 0.0319 (5) | |
C3A | −0.2762 (3) | 0.13987 (15) | 0.17098 (14) | 0.0406 (6) | |
H3A | −0.3021 | 0.1056 | 0.2056 | 0.049* | |
C4A | −0.3342 (3) | 0.09533 (17) | 0.09551 (15) | 0.0482 (6) | |
H4A | −0.4012 | 0.0304 | 0.0778 | 0.058* | |
C5A | −0.2955 (3) | 0.14501 (17) | 0.04309 (14) | 0.0472 (6) | |
H5A | −0.3373 | 0.1131 | −0.0095 | 0.057* | |
C6A | −0.1996 (3) | 0.23750 (16) | 0.06700 (12) | 0.0392 (5) | |
H6A | −0.1735 | 0.2690 | 0.0307 | 0.047* | |
C7A | −0.1373 (3) | 0.28827 (15) | 0.14520 (12) | 0.0318 (5) | |
C8A | −0.0415 (3) | 0.38433 (15) | 0.17134 (12) | 0.0315 (5) | |
H8A | −0.0122 | 0.4164 | 0.1357 | 0.038* | |
C9A | 0.0118 (3) | 0.43404 (14) | 0.24825 (12) | 0.0304 (5) | |
C10A | 0.1097 (3) | 0.53256 (15) | 0.27671 (13) | 0.0381 (5) | |
H10A | 0.1448 | 0.5651 | 0.2422 | 0.046* | |
C11A | 0.1530 (3) | 0.58013 (16) | 0.35221 (14) | 0.0454 (6) | |
H11A | 0.2192 | 0.6453 | 0.3700 | 0.054* | |
C12A | 0.1006 (3) | 0.53398 (17) | 0.40491 (13) | 0.0465 (6) | |
H12A | 0.1281 | 0.5693 | 0.4576 | 0.056* | |
C13A | 0.0118 (3) | 0.44002 (16) | 0.38108 (12) | 0.0379 (5) | |
H13A | −0.0213 | 0.4098 | 0.4173 | 0.045* | |
C14A | −0.0327 (3) | 0.38586 (14) | 0.30233 (11) | 0.0298 (5) | |
C15A | −0.0148 (3) | 0.20431 (15) | 0.35478 (12) | 0.0326 (5) | |
H15C | 0.0879 | 0.2582 | 0.3770 | 0.039* | |
H15D | 0.0146 | 0.1532 | 0.3130 | 0.039* | |
C16A | −0.0741 (3) | 0.16179 (15) | 0.41476 (12) | 0.0333 (5) | |
H16C | −0.1071 | 0.2133 | 0.4549 | 0.040* | |
H16D | −0.1771 | 0.1084 | 0.3915 | 0.040* | |
N17A | 0.0618 (2) | 0.12345 (12) | 0.44865 (9) | 0.0314 (4) | |
C18A | 0.1734 (3) | 0.18252 (15) | 0.51470 (12) | 0.0338 (5) | |
C19A | 0.1742 (3) | 0.28314 (16) | 0.54476 (13) | 0.0411 (6) | |
H19A | 0.0985 | 0.3117 | 0.5193 | 0.049* | |
C20A | 0.2833 (3) | 0.34004 (17) | 0.61039 (14) | 0.0482 (6) | |
H20A | 0.2814 | 0.4076 | 0.6300 | 0.058* | |
C21A | 0.3965 (3) | 0.30130 (19) | 0.64892 (14) | 0.0503 (6) | |
H21A | 0.4718 | 0.3417 | 0.6943 | 0.060* | |
C22A | 0.3976 (3) | 0.20368 (17) | 0.62034 (13) | 0.0417 (6) | |
H22A | 0.4745 | 0.1765 | 0.6465 | 0.050* | |
C23A | 0.2882 (3) | 0.14305 (15) | 0.55345 (12) | 0.0331 (5) | |
C24A | 0.2934 (3) | 0.03923 (16) | 0.52560 (12) | 0.0342 (5) | |
O24A | 0.38123 (18) | 0.00069 (11) | 0.56277 (8) | 0.0427 (4) | |
C25A | 0.1882 (3) | −0.01602 (15) | 0.45165 (11) | 0.0310 (5) | |
C26A | 0.1978 (3) | −0.11372 (16) | 0.41668 (13) | 0.0386 (6) | |
H26A | 0.2752 | −0.1424 | 0.4411 | 0.046* | |
C27A | 0.0980 (3) | −0.16869 (17) | 0.34812 (13) | 0.0424 (6) | |
H27A | 0.1066 | −0.2346 | 0.3250 | 0.051* | |
C28A | −0.0160 (3) | −0.12658 (16) | 0.31296 (13) | 0.0393 (5) | |
H28A | −0.0869 | −0.1647 | 0.2658 | 0.047* | |
C29A | −0.0283 (3) | −0.03147 (15) | 0.34483 (12) | 0.0341 (5) | |
H29A | −0.1060 | −0.0041 | 0.3193 | 0.041* | |
C30A | 0.0735 (3) | 0.02628 (15) | 0.41520 (12) | 0.0308 (5) |
U11 | U22 | U33 | U12 | U13 | U23 | |
O1 | 0.0328 (8) | 0.0444 (9) | 0.0411 (9) | 0.0177 (7) | 0.0165 (7) | 0.0283 (7) |
C1 | 0.0286 (11) | 0.0452 (13) | 0.0347 (13) | 0.0148 (10) | 0.0134 (10) | 0.0251 (11) |
C2 | 0.0286 (12) | 0.0621 (16) | 0.0352 (14) | 0.0119 (11) | 0.0135 (10) | 0.0217 (12) |
C3 | 0.0447 (15) | 0.0750 (19) | 0.0409 (16) | 0.0046 (13) | 0.0183 (12) | 0.0135 (14) |
C4 | 0.0505 (17) | 0.104 (2) | 0.0471 (18) | −0.0081 (16) | 0.0174 (15) | −0.0021 (18) |
C5 | 0.0412 (17) | 0.165 (4) | 0.0338 (17) | 0.001 (2) | 0.0089 (13) | 0.035 (2) |
C6 | 0.0354 (16) | 0.145 (3) | 0.0499 (19) | 0.0150 (18) | 0.0103 (14) | 0.052 (2) |
C7 | 0.0243 (12) | 0.109 (2) | 0.0376 (15) | 0.0203 (13) | 0.0144 (11) | 0.0461 (15) |
C8 | 0.0425 (15) | 0.079 (2) | 0.073 (2) | 0.0280 (14) | 0.0297 (14) | 0.0580 (17) |
C9 | 0.0387 (14) | 0.0642 (16) | 0.0619 (17) | 0.0234 (12) | 0.0301 (13) | 0.0424 (14) |
C10 | 0.0641 (18) | 0.0497 (17) | 0.099 (2) | 0.0313 (14) | 0.0547 (18) | 0.0510 (17) |
C11 | 0.083 (2) | 0.0499 (17) | 0.090 (2) | 0.0125 (16) | 0.048 (2) | 0.0235 (18) |
C12 | 0.0646 (18) | 0.0513 (17) | 0.0645 (19) | 0.0026 (14) | 0.0257 (15) | 0.0147 (15) |
C13 | 0.0428 (14) | 0.0463 (14) | 0.0468 (15) | 0.0077 (11) | 0.0166 (12) | 0.0204 (12) |
C14 | 0.0332 (12) | 0.0426 (13) | 0.0440 (14) | 0.0160 (10) | 0.0210 (11) | 0.0265 (11) |
C15 | 0.0331 (12) | 0.0429 (12) | 0.0400 (13) | 0.0140 (10) | 0.0153 (10) | 0.0264 (11) |
C16 | 0.0310 (12) | 0.0396 (12) | 0.0392 (13) | 0.0106 (10) | 0.0100 (10) | 0.0235 (11) |
N17 | 0.0310 (10) | 0.0361 (10) | 0.0329 (11) | 0.0096 (8) | 0.0080 (8) | 0.0202 (9) |
C18 | 0.0313 (12) | 0.0369 (12) | 0.0353 (13) | 0.0136 (10) | 0.0045 (10) | 0.0204 (11) |
C19 | 0.0382 (13) | 0.0404 (13) | 0.0435 (15) | 0.0081 (11) | 0.0052 (11) | 0.0206 (12) |
C20 | 0.0424 (14) | 0.0386 (13) | 0.0549 (17) | 0.0083 (11) | −0.0006 (12) | 0.0194 (13) |
C21 | 0.0475 (15) | 0.0478 (15) | 0.0411 (15) | 0.0148 (12) | 0.0024 (12) | 0.0096 (12) |
C22 | 0.0398 (13) | 0.0514 (14) | 0.0382 (14) | 0.0189 (12) | 0.0070 (11) | 0.0210 (12) |
C23 | 0.0309 (12) | 0.0403 (12) | 0.0349 (13) | 0.0165 (10) | 0.0064 (10) | 0.0208 (11) |
C24 | 0.0265 (11) | 0.0417 (13) | 0.0403 (14) | 0.0159 (10) | 0.0074 (10) | 0.0252 (11) |
O24 | 0.0379 (9) | 0.0537 (9) | 0.0437 (9) | 0.0147 (7) | 0.0165 (7) | 0.0291 (8) |
C25 | 0.0300 (11) | 0.0339 (11) | 0.0366 (13) | 0.0153 (9) | 0.0068 (10) | 0.0211 (10) |
C26 | 0.0297 (12) | 0.0395 (13) | 0.0481 (15) | 0.0119 (10) | 0.0089 (10) | 0.0248 (12) |
C27 | 0.0294 (12) | 0.0355 (12) | 0.0561 (16) | 0.0078 (10) | 0.0026 (11) | 0.0192 (12) |
C28 | 0.0404 (14) | 0.0383 (13) | 0.0407 (14) | 0.0162 (11) | 0.0028 (11) | 0.0116 (11) |
C29 | 0.0359 (13) | 0.0410 (13) | 0.0366 (13) | 0.0153 (10) | 0.0090 (10) | 0.0200 (11) |
C30 | 0.0265 (11) | 0.0335 (11) | 0.0362 (13) | 0.0132 (9) | 0.0031 (9) | 0.0203 (10) |
O1A | 0.0302 (8) | 0.0499 (9) | 0.0468 (9) | 0.0142 (7) | 0.0133 (7) | 0.0347 (8) |
C1A | 0.0261 (11) | 0.0389 (12) | 0.0381 (13) | 0.0136 (9) | 0.0115 (10) | 0.0258 (11) |
C2A | 0.0252 (11) | 0.0359 (12) | 0.0415 (14) | 0.0127 (9) | 0.0077 (10) | 0.0186 (11) |
C3A | 0.0313 (12) | 0.0378 (13) | 0.0562 (16) | 0.0100 (10) | 0.0030 (11) | 0.0202 (12) |
C4A | 0.0369 (14) | 0.0377 (13) | 0.0650 (18) | 0.0108 (11) | −0.0006 (13) | 0.0111 (13) |
C5A | 0.0404 (14) | 0.0542 (16) | 0.0425 (15) | 0.0188 (12) | 0.0004 (11) | 0.0064 (13) |
C6A | 0.0366 (13) | 0.0490 (14) | 0.0360 (14) | 0.0168 (11) | 0.0060 (11) | 0.0152 (12) |
C7A | 0.0283 (11) | 0.0398 (12) | 0.0345 (13) | 0.0178 (10) | 0.0078 (10) | 0.0161 (10) |
C8A | 0.0299 (11) | 0.0393 (12) | 0.0367 (13) | 0.0158 (10) | 0.0118 (10) | 0.0222 (11) |
C9A | 0.0296 (11) | 0.0345 (12) | 0.0367 (13) | 0.0138 (9) | 0.0091 (10) | 0.0206 (10) |
C10A | 0.0386 (13) | 0.0368 (12) | 0.0473 (15) | 0.0105 (10) | 0.0066 (11) | 0.0249 (12) |
C11A | 0.0454 (14) | 0.0370 (13) | 0.0514 (16) | 0.0073 (11) | −0.0015 (12) | 0.0152 (12) |
C12A | 0.0536 (16) | 0.0453 (14) | 0.0387 (15) | 0.0165 (12) | 0.0037 (12) | 0.0091 (12) |
C13A | 0.0412 (13) | 0.0473 (14) | 0.0337 (13) | 0.0174 (11) | 0.0092 (10) | 0.0205 (11) |
C14A | 0.0293 (11) | 0.0368 (12) | 0.0317 (12) | 0.0144 (9) | 0.0091 (9) | 0.0183 (10) |
C15A | 0.0298 (12) | 0.0396 (12) | 0.0417 (13) | 0.0150 (9) | 0.0118 (10) | 0.0264 (11) |
C16A | 0.0317 (12) | 0.0393 (12) | 0.0415 (13) | 0.0146 (10) | 0.0143 (10) | 0.0249 (11) |
N17A | 0.0324 (10) | 0.0355 (10) | 0.0363 (11) | 0.0121 (8) | 0.0103 (8) | 0.0221 (9) |
C18A | 0.0322 (12) | 0.0411 (13) | 0.0381 (13) | 0.0092 (10) | 0.0143 (10) | 0.0239 (11) |
C19A | 0.0429 (14) | 0.0424 (13) | 0.0460 (15) | 0.0129 (11) | 0.0149 (12) | 0.0213 (12) |
C20A | 0.0528 (16) | 0.0430 (14) | 0.0503 (16) | 0.0091 (12) | 0.0190 (13) | 0.0138 (13) |
C21A | 0.0450 (15) | 0.0593 (17) | 0.0430 (15) | 0.0029 (13) | 0.0103 (12) | 0.0146 (13) |
C22A | 0.0340 (13) | 0.0573 (16) | 0.0415 (14) | 0.0100 (11) | 0.0118 (11) | 0.0252 (13) |
C23A | 0.0295 (12) | 0.0437 (13) | 0.0344 (13) | 0.0075 (10) | 0.0134 (10) | 0.0221 (11) |
C24A | 0.0272 (11) | 0.0498 (14) | 0.0418 (14) | 0.0131 (10) | 0.0176 (10) | 0.0320 (12) |
O24A | 0.0364 (9) | 0.0580 (10) | 0.0503 (10) | 0.0164 (7) | 0.0106 (7) | 0.0373 (9) |
C25A | 0.0313 (12) | 0.0382 (12) | 0.0347 (13) | 0.0108 (9) | 0.0146 (10) | 0.0233 (10) |
C26A | 0.0419 (13) | 0.0445 (13) | 0.0467 (15) | 0.0183 (11) | 0.0204 (12) | 0.0306 (12) |
C27A | 0.0511 (15) | 0.0385 (13) | 0.0468 (15) | 0.0157 (11) | 0.0204 (12) | 0.0197 (12) |
C28A | 0.0409 (13) | 0.0423 (13) | 0.0406 (14) | 0.0092 (11) | 0.0137 (11) | 0.0192 (11) |
C29A | 0.0318 (12) | 0.0415 (13) | 0.0382 (13) | 0.0111 (10) | 0.0102 (10) | 0.0232 (11) |
C30A | 0.0303 (11) | 0.0367 (12) | 0.0354 (13) | 0.0094 (9) | 0.0152 (10) | 0.0217 (11) |
O1—C1 | 1.393 (2) | O1A—C1A | 1.390 (2) |
O1—C15 | 1.435 (2) | O1A—C15A | 1.437 (2) |
C1—C2 | 1.391 (3) | C1A—C2A | 1.392 (3) |
C1—C14 | 1.391 (3) | C1A—C14A | 1.397 (3) |
C2—C3 | 1.420 (3) | C2A—C3A | 1.428 (3) |
C2—C7 | 1.455 (3) | C2A—C7A | 1.441 (3) |
C3—C4 | 1.374 (3) | C3A—C4A | 1.359 (3) |
C3—H3 | 0.9500 | C3A—H3A | 0.9500 |
C4—C5 | 1.440 (4) | C4A—C5A | 1.416 (3) |
C4—H4 | 0.9500 | C4A—H4A | 0.9500 |
C5—C6 | 1.332 (4) | C5A—C6A | 1.354 (3) |
C5—H5 | 0.9500 | C5A—H5A | 0.9500 |
C6—C7 | 1.408 (4) | C6A—C7A | 1.420 (3) |
C6—H6 | 0.9500 | C6A—H6A | 0.9500 |
C7—C8 | 1.389 (4) | C7A—C8A | 1.396 (3) |
C8—C9 | 1.374 (3) | C8A—C9A | 1.388 (3) |
C8—H8 | 0.9500 | C8A—H8A | 0.9500 |
C9—C14 | 1.433 (3) | C9A—C10A | 1.430 (3) |
C9—C10 | 1.435 (3) | C9A—C14A | 1.439 (3) |
C10—C11 | 1.339 (4) | C10A—C11A | 1.354 (3) |
C10—H10 | 0.9500 | C10A—H10A | 0.9500 |
C11—C12 | 1.405 (4) | C11A—C12A | 1.414 (3) |
C11—H11 | 0.9500 | C11A—H11A | 0.9500 |
C12—C13 | 1.358 (3) | C12A—C13A | 1.353 (3) |
C12—H12 | 0.9500 | C12A—H12A | 0.9500 |
C13—C14 | 1.420 (3) | C13A—C14A | 1.424 (3) |
C13—H13 | 0.9500 | C13A—H13A | 0.9500 |
C15—C16 | 1.516 (3) | C15A—C16A | 1.520 (2) |
C15—H15A | 0.9900 | C15A—H15C | 0.9900 |
C15—H15B | 0.9900 | C15A—H15D | 0.9900 |
C16—N17 | 1.468 (2) | C16A—N17A | 1.466 (2) |
C16—H16A | 0.9900 | C16A—H16C | 0.9900 |
C16—H16B | 0.9900 | C16A—H16D | 0.9900 |
N17—C18 | 1.390 (3) | N17A—C18A | 1.391 (3) |
N17—C30 | 1.396 (2) | N17A—C30A | 1.397 (2) |
C18—C19 | 1.410 (3) | C18A—C23A | 1.405 (3) |
C18—C23 | 1.409 (3) | C18A—C19A | 1.410 (3) |
C19—C20 | 1.367 (3) | C19A—C20A | 1.369 (3) |
C19—H19 | 0.9500 | C19A—H19A | 0.9500 |
C20—C21 | 1.393 (3) | C20A—C21A | 1.386 (3) |
C20—H20 | 0.9500 | C20A—H20A | 0.9500 |
C21—C22 | 1.370 (3) | C21A—C22A | 1.370 (3) |
C21—H21 | 0.9500 | C21A—H21A | 0.9500 |
C22—C23 | 1.403 (3) | C22A—C23A | 1.399 (3) |
C22—H22 | 0.9500 | C22A—H22A | 0.9500 |
C23—C24 | 1.462 (3) | C23A—C24A | 1.461 (3) |
C24—O24 | 1.238 (2) | C24A—O24A | 1.244 (2) |
C24—C25 | 1.460 (3) | C24A—C25A | 1.459 (3) |
C25—C26 | 1.406 (3) | C25A—C26A | 1.403 (3) |
C25—C30 | 1.412 (3) | C25A—C30A | 1.409 (3) |
C26—C27 | 1.366 (3) | C26A—C27A | 1.370 (3) |
C26—H26 | 0.9500 | C26A—H26A | 0.9500 |
C27—C28 | 1.393 (3) | C27A—C28A | 1.390 (3) |
C27—H27 | 0.9500 | C27A—H27A | 0.9500 |
C28—C29 | 1.371 (3) | C28A—C29A | 1.366 (3) |
C28—H28 | 0.9500 | C28A—H28A | 0.9500 |
C29—C30 | 1.408 (3) | C29A—C30A | 1.408 (3) |
C29—H29 | 0.9500 | C29A—H29A | 0.9500 |
C1—O1—C15 | 111.77 (14) | C1A—O1A—C15A | 112.82 (14) |
C2—C1—C14 | 122.15 (19) | O1A—C1A—C2A | 118.88 (18) |
C2—C1—O1 | 118.91 (19) | O1A—C1A—C14A | 118.80 (19) |
C14—C1—O1 | 118.87 (19) | C2A—C1A—C14A | 122.28 (18) |
C1—C2—C3 | 122.6 (2) | C1A—C2A—C3A | 122.65 (19) |
C1—C2—C7 | 117.4 (2) | C1A—C2A—C7A | 118.34 (18) |
C3—C2—C7 | 119.9 (2) | C3A—C2A—C7A | 119.0 (2) |
C4—C3—C2 | 119.6 (3) | C4A—C3A—C2A | 120.5 (2) |
C4—C3—H3 | 120.2 | C4A—C3A—H3A | 119.8 |
C2—C3—H3 | 120.2 | C2A—C3A—H3A | 119.8 |
C3—C4—C5 | 119.6 (3) | C3A—C4A—C5A | 120.5 (2) |
C3—C4—H4 | 120.2 | C3A—C4A—H4A | 119.8 |
C5—C4—H4 | 120.2 | C5A—C4A—H4A | 119.8 |
C6—C5—C4 | 121.5 (3) | C6A—C5A—C4A | 120.8 (2) |
C6—C5—H5 | 119.3 | C6A—C5A—H5A | 119.6 |
C4—C5—H5 | 119.3 | C4A—C5A—H5A | 119.6 |
C5—C6—C7 | 121.7 (3) | C5A—C6A—C7A | 121.3 (2) |
C5—C6—H6 | 119.1 | C5A—C6A—H6A | 119.4 |
C7—C6—H6 | 119.1 | C7A—C6A—H6A | 119.4 |
C8—C7—C6 | 122.4 (3) | C8A—C7A—C6A | 122.34 (19) |
C8—C7—C2 | 120.0 (2) | C8A—C7A—C2A | 119.69 (19) |
C6—C7—C2 | 117.6 (3) | C6A—C7A—C2A | 117.97 (19) |
C9—C8—C7 | 121.6 (2) | C9A—C8A—C7A | 121.37 (18) |
C9—C8—H8 | 119.2 | C9A—C8A—H8A | 119.3 |
C7—C8—H8 | 119.2 | C7A—C8A—H8A | 119.3 |
C8—C9—C14 | 119.3 (2) | C8A—C9A—C10A | 122.62 (18) |
C8—C9—C10 | 122.6 (2) | C8A—C9A—C14A | 119.48 (18) |
C14—C9—C10 | 118.1 (2) | C10A—C9A—C14A | 117.9 (2) |
C11—C10—C9 | 121.5 (2) | C11A—C10A—C9A | 120.9 (2) |
C11—C10—H10 | 119.3 | C11A—C10A—H10A | 119.5 |
C9—C10—H10 | 119.3 | C9A—C10A—H10A | 119.5 |
C10—C11—C12 | 120.2 (3) | C10A—C11A—C12A | 120.8 (2) |
C10—C11—H11 | 119.9 | C10A—C11A—H11A | 119.6 |
C12—C11—H11 | 119.9 | C12A—C11A—H11A | 119.6 |
C13—C12—C11 | 121.1 (3) | C13A—C12A—C11A | 120.7 (2) |
C13—C12—H12 | 119.5 | C13A—C12A—H12A | 119.7 |
C11—C12—H12 | 119.5 | C11A—C12A—H12A | 119.7 |
C12—C13—C14 | 120.8 (2) | C12A—C13A—C14A | 120.7 (2) |
C12—C13—H13 | 119.6 | C12A—C13A—H13A | 119.6 |
C14—C13—H13 | 119.6 | C14A—C13A—H13A | 119.6 |
C1—C14—C13 | 122.41 (19) | C1A—C14A—C13A | 122.44 (18) |
C1—C14—C9 | 119.3 (2) | C1A—C14A—C9A | 118.67 (19) |
C13—C14—C9 | 118.2 (2) | C13A—C14A—C9A | 118.88 (19) |
O1—C15—C16 | 106.17 (16) | O1A—C15A—C16A | 105.49 (15) |
O1—C15—H15A | 110.5 | O1A—C15A—H15C | 110.6 |
C16—C15—H15A | 110.5 | C16A—C15A—H15C | 110.6 |
O1—C15—H15B | 110.5 | O1A—C15A—H15D | 110.6 |
C16—C15—H15B | 110.5 | C16A—C15A—H15D | 110.6 |
H15A—C15—H15B | 108.7 | H15C—C15A—H15D | 108.8 |
N17—C16—C15 | 111.50 (16) | N17A—C16A—C15A | 111.46 (16) |
N17—C16—H16A | 109.3 | N17A—C16A—H16C | 109.3 |
C15—C16—H16A | 109.3 | C15A—C16A—H16C | 109.3 |
N17—C16—H16B | 109.3 | N17A—C16A—H16D | 109.3 |
C15—C16—H16B | 109.3 | C15A—C16A—H16D | 109.3 |
H16A—C16—H16B | 108.0 | H16C—C16A—H16D | 108.0 |
C18—N17—C30 | 120.73 (17) | C18A—N17A—C30A | 120.73 (17) |
C18—N17—C16 | 119.92 (17) | C18A—N17A—C16A | 120.10 (17) |
C30—N17—C16 | 119.34 (17) | C30A—N17A—C16A | 119.13 (17) |
N17—C18—C19 | 121.51 (19) | N17A—C18A—C23A | 120.63 (19) |
N17—C18—C23 | 120.55 (18) | N17A—C18A—C19A | 121.17 (19) |
C19—C18—C23 | 117.9 (2) | C23A—C18A—C19A | 118.2 (2) |
C20—C19—C18 | 120.7 (2) | C20A—C19A—C18A | 120.5 (2) |
C20—C19—H19 | 119.7 | C20A—C19A—H19A | 119.8 |
C18—C19—H19 | 119.7 | C18A—C19A—H19A | 119.8 |
C19—C20—C21 | 121.6 (2) | C19A—C20A—C21A | 121.5 (2) |
C19—C20—H20 | 119.2 | C19A—C20A—H20A | 119.2 |
C21—C20—H20 | 119.2 | C21A—C20A—H20A | 119.2 |
C22—C21—C20 | 118.7 (2) | C22A—C21A—C20A | 118.7 (2) |
C22—C21—H21 | 120.6 | C22A—C21A—H21A | 120.6 |
C20—C21—H21 | 120.6 | C20A—C21A—H21A | 120.6 |
C21—C22—C23 | 121.4 (2) | C21A—C22A—C23A | 121.5 (2) |
C21—C22—H22 | 119.3 | C21A—C22A—H22A | 119.2 |
C23—C22—H22 | 119.3 | C23A—C22A—H22A | 119.2 |
C22—C23—C18 | 119.7 (2) | C22A—C23A—C18A | 119.6 (2) |
C22—C23—C24 | 119.25 (19) | C22A—C23A—C24A | 119.43 (19) |
C18—C23—C24 | 121.0 (2) | C18A—C23A—C24A | 121.0 (2) |
O24—C24—C25 | 122.28 (19) | O24A—C24A—C25A | 122.4 (2) |
O24—C24—C23 | 122.2 (2) | O24A—C24A—C23A | 122.1 (2) |
C25—C24—C23 | 115.52 (18) | C25A—C24A—C23A | 115.54 (18) |
C26—C25—C30 | 119.3 (2) | C26A—C25A—C30A | 119.1 (2) |
C26—C25—C24 | 119.67 (19) | C26A—C25A—C24A | 119.79 (19) |
C30—C25—C24 | 120.99 (19) | C30A—C25A—C24A | 121.10 (19) |
C27—C26—C25 | 121.4 (2) | C27A—C26A—C25A | 121.5 (2) |
C27—C26—H26 | 119.3 | C27A—C26A—H26A | 119.3 |
C25—C26—H26 | 119.3 | C25A—C26A—H26A | 119.3 |
C26—C27—C28 | 119.2 (2) | C26A—C27A—C28A | 119.0 (2) |
C26—C27—H27 | 120.4 | C26A—C27A—H27A | 120.5 |
C28—C27—H27 | 120.4 | C28A—C27A—H27A | 120.5 |
C29—C28—C27 | 121.1 (2) | C29A—C28A—C27A | 121.3 (2) |
C29—C28—H28 | 119.4 | C29A—C28A—H28A | 119.3 |
C27—C28—H28 | 119.4 | C27A—C28A—H28A | 119.3 |
C28—C29—C30 | 120.7 (2) | C28A—C29A—C30A | 120.5 (2) |
C28—C29—H29 | 119.7 | C28A—C29A—H29A | 119.7 |
C30—C29—H29 | 119.7 | C30A—C29A—H29A | 119.7 |
N17—C30—C29 | 121.39 (18) | N17A—C30A—C25A | 120.26 (19) |
N17—C30—C25 | 120.32 (19) | N17A—C30A—C29A | 121.17 (18) |
C29—C30—C25 | 118.29 (19) | C25A—C30A—C29A | 118.57 (19) |
C15—O1—C1—C2 | 94.4 (2) | C15A—O1A—C1A—C2A | 100.3 (2) |
C15—O1—C1—C14 | −88.5 (2) | C15A—O1A—C1A—C14A | −82.0 (2) |
C14—C1—C2—C3 | −174.52 (19) | O1A—C1A—C2A—C3A | 1.9 (3) |
O1—C1—C2—C3 | 2.5 (3) | C14A—C1A—C2A—C3A | −175.75 (19) |
C14—C1—C2—C7 | 3.1 (3) | O1A—C1A—C2A—C7A | 179.83 (17) |
O1—C1—C2—C7 | −179.86 (17) | C14A—C1A—C2A—C7A | 2.2 (3) |
C1—C2—C3—C4 | 175.0 (2) | C1A—C2A—C3A—C4A | 177.3 (2) |
C7—C2—C3—C4 | −2.6 (3) | C7A—C2A—C3A—C4A | −0.6 (3) |
C2—C3—C4—C5 | 0.7 (4) | C2A—C3A—C4A—C5A | 0.6 (3) |
C3—C4—C5—C6 | 2.0 (4) | C3A—C4A—C5A—C6A | 0.3 (3) |
C4—C5—C6—C7 | −2.8 (4) | C4A—C5A—C6A—C7A | −1.1 (3) |
C5—C6—C7—C8 | −176.6 (2) | C5A—C6A—C7A—C8A | −178.6 (2) |
C5—C6—C7—C2 | 0.8 (4) | C5A—C6A—C7A—C2A | 1.0 (3) |
C1—C2—C7—C8 | 1.6 (3) | C1A—C2A—C7A—C8A | 1.4 (3) |
C3—C2—C7—C8 | 179.3 (2) | C3A—C2A—C7A—C8A | 179.41 (19) |
C1—C2—C7—C6 | −175.8 (2) | C1A—C2A—C7A—C6A | −178.18 (18) |
C3—C2—C7—C6 | 1.8 (3) | C3A—C2A—C7A—C6A | −0.2 (3) |
C6—C7—C8—C9 | 173.5 (2) | C6A—C7A—C8A—C9A | 177.20 (19) |
C2—C7—C8—C9 | −3.8 (3) | C2A—C7A—C8A—C9A | −2.4 (3) |
C7—C8—C9—C14 | 1.3 (3) | C7A—C8A—C9A—C10A | −179.82 (19) |
C7—C8—C9—C10 | −177.0 (2) | C7A—C8A—C9A—C14A | −0.2 (3) |
C8—C9—C10—C11 | 175.7 (2) | C8A—C9A—C10A—C11A | 177.1 (2) |
C14—C9—C10—C11 | −2.6 (3) | C14A—C9A—C10A—C11A | −2.6 (3) |
C9—C10—C11—C12 | −0.2 (4) | C9A—C10A—C11A—C12A | −0.8 (3) |
C10—C11—C12—C13 | 2.2 (4) | C10A—C11A—C12A—C13A | 2.5 (3) |
C11—C12—C13—C14 | −1.3 (4) | C11A—C12A—C13A—C14A | −0.7 (3) |
C2—C1—C14—C13 | 172.7 (2) | O1A—C1A—C14A—C13A | −3.3 (3) |
O1—C1—C14—C13 | −4.4 (3) | C2A—C1A—C14A—C13A | 174.34 (19) |
C2—C1—C14—C9 | −5.6 (3) | O1A—C1A—C14A—C9A | 177.66 (17) |
O1—C1—C14—C9 | 177.34 (17) | C2A—C1A—C14A—C9A | −4.7 (3) |
C12—C13—C14—C1 | −179.9 (2) | C12A—C13A—C14A—C1A | 178.3 (2) |
C12—C13—C14—C9 | −1.6 (3) | C12A—C13A—C14A—C9A | −2.7 (3) |
C8—C9—C14—C1 | 3.4 (3) | C8A—C9A—C14A—C1A | 3.6 (3) |
C10—C9—C14—C1 | −178.26 (19) | C10A—C9A—C14A—C1A | −176.69 (18) |
C8—C9—C14—C13 | −175.0 (2) | C8A—C9A—C14A—C13A | −175.42 (19) |
C10—C9—C14—C13 | 3.4 (3) | C10A—C9A—C14A—C13A | 4.2 (3) |
C1—O1—C15—C16 | 173.84 (17) | C1A—O1A—C15A—C16A | 175.82 (17) |
O1—C15—C16—N17 | −178.01 (16) | O1A—C15A—C16A—N17A | −179.05 (16) |
C15—C16—N17—C18 | 90.9 (2) | C15A—C16A—N17A—C18A | 93.3 (2) |
C15—C16—N17—C30 | −90.6 (2) | C15A—C16A—N17A—C30A | −88.8 (2) |
C30—N17—C18—C19 | 172.05 (18) | C30A—N17A—C18A—C23A | −6.6 (3) |
C16—N17—C18—C19 | −9.5 (3) | C16A—N17A—C18A—C23A | 171.19 (17) |
C30—N17—C18—C23 | −7.5 (3) | C30A—N17A—C18A—C19A | 173.62 (17) |
C16—N17—C18—C23 | 170.94 (17) | C16A—N17A—C18A—C19A | −8.6 (3) |
N17—C18—C19—C20 | 179.25 (18) | N17A—C18A—C19A—C20A | 179.13 (19) |
C23—C18—C19—C20 | −1.2 (3) | C23A—C18A—C19A—C20A | −0.6 (3) |
C18—C19—C20—C21 | 0.5 (3) | C18A—C19A—C20A—C21A | 0.4 (3) |
C19—C20—C21—C22 | 0.0 (3) | C19A—C20A—C21A—C22A | −0.3 (3) |
C20—C21—C22—C23 | 0.2 (3) | C20A—C21A—C22A—C23A | 0.2 (3) |
C21—C22—C23—C18 | −1.0 (3) | C21A—C22A—C23A—C18A | −0.4 (3) |
C21—C22—C23—C24 | −179.55 (19) | C21A—C22A—C23A—C24A | −179.51 (19) |
N17—C18—C23—C22 | −179.01 (17) | N17A—C18A—C23A—C22A | −179.14 (17) |
C19—C18—C23—C22 | 1.4 (3) | C19A—C18A—C23A—C22A | 0.6 (3) |
N17—C18—C23—C24 | −0.5 (3) | N17A—C18A—C23A—C24A | −0.1 (3) |
C19—C18—C23—C24 | 179.97 (18) | C19A—C18A—C23A—C24A | 179.67 (18) |
C22—C23—C24—O24 | 5.4 (3) | C22A—C23A—C24A—O24A | 6.4 (3) |
C18—C23—C24—O24 | −173.20 (18) | C18A—C23A—C24A—O24A | −172.68 (18) |
C22—C23—C24—C25 | −173.70 (17) | C22A—C23A—C24A—C25A | −173.88 (17) |
C18—C23—C24—C25 | 7.7 (3) | C18A—C23A—C24A—C25A | 7.1 (3) |
O24—C24—C25—C26 | −6.0 (3) | O24A—C24A—C25A—C26A | −6.6 (3) |
C23—C24—C25—C26 | 173.01 (17) | C23A—C24A—C25A—C26A | 173.67 (17) |
O24—C24—C25—C30 | 173.30 (18) | O24A—C24A—C25A—C30A | 171.88 (18) |
C23—C24—C25—C30 | −7.6 (3) | C23A—C24A—C25A—C30A | −7.9 (3) |
C30—C25—C26—C27 | 0.3 (3) | C30A—C25A—C26A—C27A | −0.1 (3) |
C24—C25—C26—C27 | 179.66 (18) | C24A—C25A—C26A—C27A | 178.41 (18) |
C25—C26—C27—C28 | −0.6 (3) | C25A—C26A—C27A—C28A | −0.5 (3) |
C26—C27—C28—C29 | 0.8 (3) | C26A—C27A—C28A—C29A | 1.0 (3) |
C27—C28—C29—C30 | −0.8 (3) | C27A—C28A—C29A—C30A | −0.9 (3) |
C18—N17—C30—C29 | −172.57 (17) | C18A—N17A—C30A—C25A | 5.8 (3) |
C16—N17—C30—C29 | 9.0 (3) | C16A—N17A—C30A—C25A | −172.03 (16) |
C18—N17—C30—C25 | 7.6 (3) | C18A—N17A—C30A—C29A | −174.23 (17) |
C16—N17—C30—C25 | −170.86 (16) | C16A—N17A—C30A—C29A | 7.9 (3) |
C28—C29—C30—N17 | −179.40 (18) | C26A—C25A—C30A—N17A | −179.81 (17) |
C28—C29—C30—C25 | 0.4 (3) | C24A—C25A—C30A—N17A | 1.7 (3) |
C26—C25—C30—N17 | 179.63 (17) | C26A—C25A—C30A—C29A | 0.2 (3) |
C24—C25—C30—N17 | 0.3 (3) | C24A—C25A—C30A—C29A | −178.25 (17) |
C26—C25—C30—C29 | −0.2 (3) | C28A—C29A—C30A—N17A | −179.69 (17) |
C24—C25—C30—C29 | −179.56 (17) | C28A—C29A—C30A—C25A | 0.3 (3) |
Experimental details
Crystal data | |
Chemical formula | C29H21NO2 |
Mr | 415.47 |
Crystal system, space group | Triclinic, P1 |
Temperature (K) | 173 |
a, b, c (Å) | 7.9833 (6), 14.6168 (8), 18.744 (2) |
α, β, γ (°) | 107.180 (5), 96.514 (5), 99.570 (5) |
V (Å3) | 2029.7 (3) |
Z | 4 |
Radiation type | Mo Kα |
µ (mm−1) | 0.09 |
Crystal size (mm) | 0.51 × 0.38 × 0.14 |
Data collection | |
Diffractometer | Siemens CCD three-circle diffractometer |
Absorption correction | Empirical (using intensity measurements) (SADABS; Sheldrick, 1996) |
Tmin, Tmax | 0.958, 0.988 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 22246, 7927, 4798 |
Rint | 0.041 |
(sin θ/λ)max (Å−1) | 0.641 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.052, 0.125, 1.02 |
No. of reflections | 7927 |
No. of parameters | 577 |
H-atom treatment | H-atom parameters constrained |
Δρmax, Δρmin (e Å−3) | 0.25, −0.32 |
Computer programs: SMART (Siemens, 1995), SMART, SAINT (Siemens, 1995), SHELXS97 (Sheldrick, 1990), SHELXL97 (Sheldrick, 1997), XP in SHELXTL-Plus (Sheldrick, 1991).
O1—C1 | 1.393 (2) | O1A—C1A | 1.390 (2) |
O1—C15 | 1.435 (2) | O1A—C15A | 1.437 (2) |
C16—N17 | 1.468 (2) | C16A—N17A | 1.466 (2) |
N17—C18 | 1.390 (3) | N17A—C18A | 1.391 (3) |
N17—C30 | 1.396 (2) | N17A—C30A | 1.397 (2) |
C24—O24 | 1.238 (2) | C24A—O24A | 1.244 (2) |
C25—C24—C23 | 115.52 (18) | C25A—C24A—C23A | 115.54 (18) |
Acridone derivatives are well known for their biological properties (Blanchard et al., 1978). They have been reported to be anticancer active and to be applicable as antimicrobial and antiparasitic agents (Nishi et al., 1981). This kind of compound is prepared by condensation of 9(10H)-acridanone and alkylhalogenderivates using phase transfer catalysis. The X-ray structure analysis has been carried out to determine unambiguously the nature of the reaction product.
The title compound, (I), crystallizes with two molecules in the asymmetric unit, which are almost identical. A least-squares fit of all non-H atoms gives an r.m.s. deviation of 0.180 Å. Bond lengths and angles do not show unusual values. The angle between the acridone and the anthracene planes are 54.22 (3) and 54.04 (3)° for the two molecules in the asymmetric unit.