Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806023117/om2026sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806023117/om2026Isup2.hkl |
CCDC reference: 614877
Data collection: COSMO/APEX2 (Bruker, 2004); cell refinement: SAINT (Bruker, 2004); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).
C21H25NO | F(000) = 664 |
Mr = 307.42 | Dx = 1.114 Mg m−3 |
Monoclinic, P21/n | Melting point: 362 K |
Hall symbol: -P 2yn | Mo Kα radiation, λ = 0.71073 Å |
a = 9.9291 (4) Å | Cell parameters from 87 reflections |
b = 18.5953 (6) Å | θ = 2.1–57.9° |
c = 10.4394 (4) Å | µ = 0.07 mm−1 |
β = 108.015 (2)° | T = 295 K |
V = 1832.98 (12) Å3 | Block, yellow |
Z = 4 | 0.26 × 0.24 × 0.15 mm |
Bruker APEX-II CCD area-detector diffractometer | Rint = 0.027 |
Graphite monochromator | θmax = 25.5°, θmin = 3° |
φ and ω scans | h = −12→12 |
16097 measured reflections | k = −14→22 |
3408 independent reflections | l = −12→12 |
2508 reflections with I > 2σ(I) |
Refinement on F2 | 0 restraints |
Least-squares matrix: full | H atoms treated by a mixture of independent and constrained refinement |
R[F2 > 2σ(F2)] = 0.048 | w = 1/[σ2(Fo2) + (0.0598P)2 + 0.2624P] where P = (Fo2 + 2Fc2)/3 |
wR(F2) = 0.144 | (Δ/σ)max = 0.001 |
S = 1.07 | Δρmax = 0.18 e Å−3 |
3408 reflections | Δρmin = −0.17 e Å−3 |
253 parameters |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. Least-squares planes (x,y,z in crystal coordinates) and deviations from them (* indicates atom used to define plane) 5.3268 (0.0067) x - 14.5879 (0.0085) y + 1.3560 (0.0088) z = 1.0192 (0.0051) * -0.0017 (0.0012) C1 * 0.0004 (0.0013) C2 * 0.0015 (0.0014) C3 * -0.0020 (0.0015) C4 * 0.0007 (0.0016) C5 * 0.0011 (0.0014) C6 Rms deviation of fitted atoms = 0.0014 6.0108 (0.0071) x - 14.4760 (0.0120) y - 3.6009 (0.0087) z = 2.1547 (0.0069) Angle to previous plane (with approximate e.s.d.) = 27.88 (0.09) * 0.2294 (0.0009) N1 * -0.2607 (0.0011) C14 * 0.0049 (0.0011) C13 * 0.2317 (0.0013) C1 * -0.2053 (0.0008) C6 Rms deviation of fitted atoms = 0.2080 5.5970 (0.0067) x + 15.2876 (0.0086) y - 2.6116 (0.0085) z = 6.1495 (0.0053) Angle to previous plane (with approximate e.s.d.) = 73.41 (0.05) * 0.0092 (0.0011) C7 * -0.0095 (0.0012) C8 * 0.0025 (0.0015) C9 * 0.0051 (0.0017) C10 * -0.0055 (0.0015) C11 * -0.0018 (0.0012) C12 Rms deviation of fitted atoms = 0.0063 5.3268 (0.0067) x - 14.5879 (0.0085) y + 1.3560 (0.0088) z = 1.0192 (0.0051) Angle to previous plane (with approximate e.s.d.) = 68.45 (0.05) * -0.0017 (0.0012) C1 * 0.0004 (0.0013) C2 * 0.0015 (0.0014) C3 * -0.0020 (0.0015) C4 * 0.0007 (0.0016) C5 * 0.0011 (0.0014) C6 Rms deviation of fitted atoms = 0.0014 6.8547 (0.0070) x - 13.4493 (0.0128) y - 2.0630 (0.0308) z = 2.6831 (0.0082) Angle to previous plane (with approximate e.s.d.) = 19.44 (0.15) * 0.0000 (0.0000) C1 * 0.0000 (0.0000) C13 * 0.0000 (0.0000) O1 Rms deviation of fitted atoms = 0.0000 6.7168 (0.0215) x - 13.6943 (0.0369) y - 2.2382 (0.0101) z = 2.5731 (0.0227) Angle to previous plane (with approximate e.s.d.) = 1.68 (0.31) * 0.0000 (0.0000) O1 * 0.0000 (0.0000) C13 * 0.0000 (0.0000) C14 Rms deviation of fitted atoms = 0.0000 9.0855 (0.0082) x - 6.7234 (0.0186) y - 4.7294 (0.0267) z = 5.6411 (0.0100) Angle to previous plane (with approximate e.s.d.) = 27.59 (0.23) * 0.0000 (0.0000) N1 * 0.0000 (0.0000) C14 * 0.0000 (0.0000) C15 Rms deviation of fitted atoms = 0.0000 5.4294 (0.0055) x - 14.4150 (0.0059) y + 1.3749 (0.0088) z = 1.0681 (0.0048) Angle to previous plane (with approximate e.s.d.) = 43.61 (0.10) * 0.0241 (0.0013) C1 * 0.0160 (0.0014) C2 * -0.0033 (0.0014) C3 * -0.0176 (0.0016) C4 * -0.0052 (0.0016) C5 * 0.0158 (0.0016) C6 * -0.0298 (0.0010) C13 Rms deviation of fitted atoms = 0.0182 5.5010 (0.0040) x + 15.3933 (0.0049) y - 2.6648 (0.0070) z = 6.0506 (0.0039) Angle to previous plane (with approximate e.s.d.) = 68.49 (0.03) * 0.0305 (0.0013) C7 * -0.0071 (0.0015) C8 * -0.0090 (0.0018) C9 * -0.0023 (0.0017) C10 * 0.0055 (0.0018) C11 * 0.0240 (0.0015) C12 * -0.0317 (0.0012) C16 * -0.0100 (0.0012) C19 Rms deviation of fitted atoms = 0.0186 5.7575 (0.0179) x + 14.6435 (0.0501) y - 3.9458 (0.0589) z = 5.9245 (0.0056) Angle to previous plane (with approximate e.s.d.) = 7.44 (0.34) * 0.0446 (0.0042) N1 * -0.0122 (0.0031) C7 * -0.0470 (0.0020) C8 * 0.1185 (0.0075) C19 * -0.1039 (0.0073) H19 Rms deviation of fitted atoms = 0.0764 6.1041 (0.0394) x + 14.6283 (0.0520) y - 2.5476 (0.0321) z = 6.4313 (0.0295) Angle to previous plane (with approximate e.s.d.) = 8.96 (0.54) * -0.0895 (0.0041) N1 * 0.0761 (0.0033) C7 * 0.0180 (0.0022) C12 * -0.1584 (0.0076) C16 * 0.1537 (0.0069) H16 Rms deviation of fitted atoms = 0.1121 3.6408 (0.0562) x + 10.8278 (0.1204) y - 8.3873 (0.0551) z = 3.2404 (0.0488) Angle to previous plane (with approximate e.s.d.) = 43.56 (0.54) * 0.0000 (0.0000) H6 * 0.0000 (0.0000) H16 * 0.0000 (0.0000) H19 0.2689 (0.0116) N1 Rms deviation of fitted atoms = 0.0000 |
x | y | z | Uiso*/Ueq | ||
C1 | 0.56434 (16) | 0.11813 (8) | −0.19561 (14) | 0.0511 (4) | |
C2 | 0.5313 (2) | 0.09365 (10) | −0.32760 (17) | 0.0633 (5) | |
C3 | 0.4192 (2) | 0.04776 (11) | −0.3804 (2) | 0.0743 (5) | |
C4 | 0.3378 (2) | 0.02542 (11) | −0.3035 (2) | 0.0767 (6) | |
C5 | 0.3686 (2) | 0.04856 (13) | −0.1734 (2) | 0.0831 (6) | |
C6 | 0.48157 (19) | 0.09486 (11) | −0.11884 (18) | 0.0693 (5) | |
C7 | 0.83502 (16) | 0.13476 (8) | 0.22014 (14) | 0.0503 (4) | |
C8 | 0.96145 (17) | 0.09514 (9) | 0.26640 (15) | 0.0589 (4) | |
C9 | 1.0303 (2) | 0.09418 (13) | 0.40382 (19) | 0.0793 (6) | |
C10 | 0.9765 (3) | 0.12916 (14) | 0.4921 (2) | 0.0894 (7) | |
C11 | 0.8514 (3) | 0.16644 (12) | 0.44635 (18) | 0.0794 (6) | |
C12 | 0.77725 (18) | 0.17041 (9) | 0.30926 (16) | 0.0602 (4) | |
C13 | 0.68192 (17) | 0.17072 (9) | −0.14777 (15) | 0.0564 (4) | |
C14 | 0.75702 (16) | 0.18324 (8) | 0.00103 (15) | 0.0502 (4) | |
C15 | 0.8287 (2) | 0.25414 (10) | 0.03802 (18) | 0.0723 (5) | |
H15A | 0.8796 | 0.2547 | 0.1326 | 0.109* | |
H15B | 0.7591 | 0.2918 | 0.0176 | 0.109* | |
H15C | 0.8937 | 0.2616 | −0.0124 | 0.109* | |
C16 | 0.6356 (2) | 0.20911 (10) | 0.2613 (2) | 0.0677 (5) | |
C17 | 0.6302 (3) | 0.27779 (13) | 0.3381 (3) | 0.1089 (8) | |
H17A | 0.6413 | 0.2664 | 0.4305 | 0.163* | |
H17B | 0.5406 | 0.3011 | 0.2988 | 0.163* | |
H17C | 0.7052 | 0.3093 | 0.3337 | 0.163* | |
C18 | 0.5157 (2) | 0.15936 (13) | 0.2666 (3) | 0.0904 (6) | |
H18A | 0.5172 | 0.1168 | 0.215 | 0.136* | |
H18B | 0.4267 | 0.1836 | 0.2296 | 0.136* | |
H18C | 0.5276 | 0.1463 | 0.3584 | 0.136* | |
C19 | 1.0233 (2) | 0.05618 (11) | 0.17015 (19) | 0.0697 (5) | |
C20 | 1.1397 (4) | 0.09917 (19) | 0.1450 (4) | 0.1522 (14) | |
H20A | 1.1031 | 0.1448 | 0.1065 | 0.228* | |
H20B | 1.1773 | 0.0736 | 0.0838 | 0.228* | |
H20C | 1.2134 | 0.1068 | 0.2285 | 0.228* | |
C21 | 1.0740 (4) | −0.01929 (15) | 0.2174 (3) | 0.1255 (10) | |
H21A | 1.1056 | −0.0428 | 0.15 | 0.188* | |
H21B | 0.9975 | −0.0462 | 0.232 | 0.188* | |
H21C | 1.1508 | −0.0165 | 0.3 | 0.188* | |
N1 | 0.75912 (12) | 0.13066 (7) | 0.07980 (12) | 0.0496 (3) | |
O1 | 0.72381 (16) | 0.20434 (9) | −0.22773 (13) | 0.0935 (5) | |
H2 | 0.589 (2) | 0.1088 (10) | −0.3782 (19) | 0.074 (6)* | |
H3 | 0.398 (2) | 0.0304 (11) | −0.472 (2) | 0.094 (7)* | |
H4 | 0.255 (2) | −0.0091 (13) | −0.343 (2) | 0.095 (6)* | |
H5 | 0.316 (2) | 0.0329 (12) | −0.118 (2) | 0.098 (7)* | |
H6 | 0.503 (2) | 0.1090 (9) | −0.0274 (19) | 0.074 (5)* | |
H9 | 1.118 (2) | 0.0656 (11) | 0.436 (2) | 0.088 (6)* | |
H10 | 1.024 (3) | 0.1304 (12) | 0.584 (2) | 0.107 (7)* | |
H11 | 0.809 (2) | 0.1909 (10) | 0.511 (2) | 0.082 (6)* | |
H16 | 0.6167 (19) | 0.2221 (10) | 0.1681 (19) | 0.074 (5)* | |
H19 | 0.946 (2) | 0.0494 (10) | 0.088 (2) | 0.075 (5)* |
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.0472 (8) | 0.0543 (9) | 0.0468 (8) | 0.0052 (7) | 0.0070 (6) | 0.0062 (6) |
C2 | 0.0596 (10) | 0.0722 (11) | 0.0555 (9) | 0.0065 (9) | 0.0139 (8) | 0.0010 (8) |
C3 | 0.0720 (12) | 0.0732 (12) | 0.0660 (11) | 0.0054 (10) | 0.0041 (10) | −0.0146 (10) |
C4 | 0.0661 (11) | 0.0663 (12) | 0.0813 (13) | −0.0082 (10) | −0.0010 (10) | 0.0010 (10) |
C5 | 0.0619 (11) | 0.1046 (16) | 0.0769 (13) | −0.0225 (11) | 0.0130 (10) | 0.0124 (12) |
C6 | 0.0576 (10) | 0.0929 (14) | 0.0544 (10) | −0.0142 (10) | 0.0127 (8) | 0.0008 (9) |
C7 | 0.0485 (8) | 0.0553 (9) | 0.0453 (8) | −0.0095 (7) | 0.0118 (6) | 0.0014 (6) |
C8 | 0.0498 (9) | 0.0716 (11) | 0.0516 (9) | −0.0049 (8) | 0.0102 (7) | 0.0066 (8) |
C9 | 0.0624 (12) | 0.1085 (16) | 0.0576 (10) | 0.0029 (11) | 0.0048 (9) | 0.0108 (11) |
C10 | 0.0873 (15) | 0.1228 (19) | 0.0463 (10) | −0.0015 (14) | 0.0031 (10) | 0.0016 (11) |
C11 | 0.0929 (15) | 0.0952 (15) | 0.0531 (10) | −0.0084 (12) | 0.0270 (10) | −0.0064 (10) |
C12 | 0.0650 (10) | 0.0630 (10) | 0.0543 (9) | −0.0086 (8) | 0.0210 (8) | −0.0003 (8) |
C13 | 0.0551 (9) | 0.0621 (10) | 0.0512 (8) | −0.0009 (8) | 0.0151 (7) | 0.0097 (7) |
C14 | 0.0461 (8) | 0.0545 (9) | 0.0509 (8) | −0.0033 (7) | 0.0160 (6) | 0.0017 (7) |
C15 | 0.0851 (13) | 0.0628 (11) | 0.0691 (11) | −0.0209 (10) | 0.0236 (9) | 0.0016 (9) |
C16 | 0.0764 (12) | 0.0676 (11) | 0.0673 (11) | 0.0048 (9) | 0.0339 (9) | 0.0019 (9) |
C17 | 0.132 (2) | 0.0755 (14) | 0.130 (2) | 0.0062 (14) | 0.0555 (17) | −0.0173 (14) |
C18 | 0.0723 (13) | 0.0877 (14) | 0.1193 (17) | 0.0016 (11) | 0.0414 (12) | 0.0031 (13) |
C19 | 0.0571 (10) | 0.0883 (13) | 0.0625 (11) | 0.0092 (10) | 0.0167 (9) | 0.0074 (10) |
C20 | 0.160 (3) | 0.150 (3) | 0.203 (3) | −0.037 (2) | 0.137 (3) | −0.026 (2) |
C21 | 0.162 (3) | 0.108 (2) | 0.1092 (19) | 0.0549 (19) | 0.0470 (19) | 0.0141 (15) |
N1 | 0.0446 (7) | 0.0551 (8) | 0.0464 (7) | −0.0036 (6) | 0.0101 (5) | 0.0019 (6) |
O1 | 0.1037 (11) | 0.1158 (11) | 0.0583 (7) | −0.0427 (9) | 0.0210 (7) | 0.0164 (7) |
C1—C6 | 1.383 (2) | C13—C14 | 1.519 (2) |
C1—C2 | 1.391 (2) | C14—N1 | 1.2735 (19) |
C1—C13 | 1.486 (2) | C14—C15 | 1.491 (2) |
C2—C3 | 1.375 (3) | C15—H15A | 0.96 |
C2—H2 | 0.93 (2) | C15—H15B | 0.96 |
C3—C4 | 1.368 (3) | C15—H15C | 0.96 |
C3—H3 | 0.97 (2) | C16—C17 | 1.518 (3) |
C4—C5 | 1.366 (3) | C16—C18 | 1.522 (3) |
C4—H4 | 1.02 (2) | C16—N1 | 2.943 (2) |
C5—C6 | 1.389 (3) | C16—H16 | 0.963 (19) |
C5—H5 | 0.93 (2) | C17—H17A | 0.96 |
C6—N1 | 2.967 (2) | C17—H17B | 0.96 |
C6—H6 | 0.949 (18) | C17—H17C | 0.96 |
C7—C12 | 1.401 (2) | C18—H18A | 0.96 |
C7—C8 | 1.406 (2) | C18—H18B | 0.96 |
C7—N1 | 1.4274 (18) | C18—H18C | 0.96 |
C8—C9 | 1.385 (2) | C19—C20 | 1.493 (3) |
C8—C19 | 1.514 (2) | C19—C21 | 1.521 (3) |
C9—C10 | 1.365 (3) | C19—N1 | 2.856 (2) |
C9—H9 | 0.99 (2) | C19—H19 | 0.97 (2) |
C10—C11 | 1.372 (3) | C20—H20A | 0.96 |
C10—H10 | 0.93 (2) | C20—H20B | 0.96 |
C11—C12 | 1.394 (2) | C20—H20C | 0.96 |
C11—H11 | 1.01 (2) | C21—H21A | 0.96 |
C12—C16 | 1.520 (3) | C21—H21B | 0.96 |
C13—O1 | 1.2147 (19) | C21—H21C | 0.96 |
C6—C1—C2 | 118.12 (16) | C16—C17—H17B | 109.5 |
C6—C1—C13 | 123.86 (14) | H17A—C17—H17B | 109.5 |
C2—C1—C13 | 117.95 (14) | C16—C17—H17C | 109.5 |
C3—C2—C1 | 120.95 (18) | H17A—C17—H17C | 109.5 |
C3—C2—H2 | 121.4 (12) | H17B—C17—H17C | 109.5 |
C1—C2—H2 | 117.6 (12) | C16—C18—H18A | 109.5 |
C4—C3—C2 | 120.31 (19) | C16—C18—H18B | 109.5 |
C4—C3—H3 | 119.4 (13) | H18A—C18—H18B | 109.5 |
C2—C3—H3 | 120.2 (13) | C16—C18—H18C | 109.5 |
C5—C4—C3 | 119.78 (19) | H18A—C18—H18C | 109.5 |
C5—C4—H4 | 120.1 (12) | H18B—C18—H18C | 109.5 |
C3—C4—H4 | 120.1 (11) | C20—C19—C8 | 110.80 (19) |
C4—C5—C6 | 120.5 (2) | C20—C19—C21 | 110.8 (2) |
C4—C5—H5 | 121.3 (14) | C8—C19—C21 | 112.81 (16) |
C6—C5—H5 | 118.3 (14) | C20—C19—N1 | 111.33 (19) |
C1—C6—C5 | 120.38 (18) | C8—C19—N1 | 57.83 (9) |
C1—C6—N1 | 75.21 (10) | C21—C19—N1 | 137.10 (17) |
C5—C6—N1 | 152.08 (15) | C20—C19—H19 | 111.2 (11) |
C1—C6—H6 | 120.6 (11) | C8—C19—H19 | 106.0 (11) |
C5—C6—H6 | 118.9 (11) | C21—C19—H19 | 105.1 (11) |
N1—C6—H6 | 50.6 (11) | N1—C19—H19 | 51.1 (11) |
C12—C7—C8 | 121.67 (14) | C19—C20—H20A | 109.5 |
C12—C7—N1 | 120.80 (14) | C19—C20—H20B | 109.5 |
C8—C7—N1 | 117.17 (13) | H20A—C20—H20B | 109.5 |
C9—C8—C7 | 117.70 (17) | C19—C20—H20C | 109.5 |
C9—C8—C19 | 120.61 (16) | H20A—C20—H20C | 109.5 |
C7—C8—C19 | 121.67 (14) | H20B—C20—H20C | 109.5 |
C10—C9—C8 | 121.5 (2) | C19—C21—H21A | 109.5 |
C10—C9—H9 | 120.9 (12) | C19—C21—H21B | 109.5 |
C8—C9—H9 | 117.6 (12) | H21A—C21—H21B | 109.5 |
C9—C10—C11 | 120.44 (18) | C19—C21—H21C | 109.5 |
C9—C10—H10 | 121.8 (15) | H21A—C21—H21C | 109.5 |
C11—C10—H10 | 117.7 (15) | H21B—C21—H21C | 109.5 |
C10—C11—C12 | 121.19 (19) | C14—N1—C7 | 121.32 (13) |
C10—C11—H11 | 121.2 (11) | C14—N1—H19 | 111.6 (4) |
C12—C11—H11 | 117.6 (11) | C7—N1—H19 | 80.7 (5) |
C11—C12—C7 | 117.49 (17) | C14—N1—H6 | 91.4 (4) |
C11—C12—C16 | 120.28 (16) | C7—N1—H6 | 128.0 (4) |
C7—C12—C16 | 122.16 (14) | H19—N1—H6 | 126.5 (6) |
O1—C13—C1 | 120.54 (14) | C14—N1—H16 | 79.7 (4) |
O1—C13—C14 | 117.38 (15) | C7—N1—H16 | 76.7 (4) |
C1—C13—C14 | 122.06 (13) | H19—N1—H16 | 157.4 (6) |
N1—C14—C15 | 126.89 (14) | H6—N1—H16 | 70.5 (6) |
N1—C14—C13 | 116.59 (14) | C14—N1—C19 | 114.55 (10) |
C15—C14—C13 | 116.38 (13) | C7—N1—C19 | 63.09 (8) |
C14—C15—H15A | 109.5 | H19—N1—C19 | 18.6 (5) |
C14—C15—H15B | 109.5 | H6—N1—C19 | 141.3 (4) |
H15A—C15—H15B | 109.5 | H16—N1—C19 | 139.2 (4) |
C14—C15—H15C | 109.5 | C14—N1—C16 | 96.22 (10) |
H15A—C15—H15C | 109.5 | C7—N1—C16 | 60.37 (9) |
H15B—C15—H15C | 109.5 | H19—N1—C16 | 140.3 (5) |
C17—C16—C12 | 113.87 (18) | H6—N1—C16 | 78.3 (4) |
C17—C16—C18 | 109.66 (18) | H16—N1—C16 | 18.5 (4) |
C12—C16—C18 | 110.76 (16) | C19—N1—C16 | 123.43 (7) |
C17—C16—N1 | 147.92 (15) | C14—N1—C6 | 83.96 (9) |
C12—C16—N1 | 56.63 (8) | C7—N1—C6 | 144.17 (9) |
C18—C16—N1 | 102.02 (12) | H19—N1—C6 | 115.3 (5) |
C17—C16—H16 | 107.2 (11) | H6—N1—C6 | 17.2 (4) |
C12—C16—H16 | 108.8 (11) | H16—N1—C6 | 84.5 (4) |
C18—C16—H16 | 106.2 (11) | C19—N1—C6 | 132.97 (7) |
N1—C16—H16 | 57.6 (11) | C16—N1—C6 | 94.54 (7) |
C16—C17—H17A | 109.5 | ||
C6—C1—C2—C3 | 0.2 (3) | C12—C7—N1—H16 | 10.8 (4) |
C13—C1—C2—C3 | −176.73 (16) | C8—C7—N1—H16 | −175.9 (4) |
C1—C2—C3—C4 | 0.1 (3) | C12—C7—N1—C19 | −176.45 (16) |
C2—C3—C4—C5 | −0.4 (3) | C8—C7—N1—C19 | −3.24 (11) |
C3—C4—C5—C6 | 0.3 (3) | C12—C7—N1—C16 | 1.42 (12) |
C2—C1—C6—C5 | −0.2 (3) | C8—C7—N1—C16 | 174.63 (16) |
C13—C1—C6—C5 | 176.46 (17) | C12—C7—N1—C6 | −49.4 (2) |
C2—C1—C6—N1 | 154.52 (15) | C8—C7—N1—C6 | 123.83 (17) |
C13—C1—C6—N1 | −28.77 (15) | C20—C19—N1—C14 | 15.5 (2) |
C4—C5—C6—C1 | 0.0 (3) | C8—C19—N1—C14 | 117.31 (14) |
C4—C5—C6—N1 | −118.3 (3) | C21—C19—N1—C14 | −152.9 (2) |
C12—C7—C8—C9 | −2.0 (2) | C20—C19—N1—C7 | −98.7 (2) |
N1—C7—C8—C9 | −175.11 (15) | C8—C19—N1—C7 | 3.16 (11) |
C12—C7—C8—C19 | 179.56 (15) | C21—C19—N1—C7 | 92.9 (2) |
N1—C7—C8—C19 | 6.4 (2) | C20—C19—N1—H19 | 100.6 (14) |
C7—C8—C9—C10 | 1.3 (3) | C8—C19—N1—H19 | −157.6 (14) |
C19—C8—C9—C10 | 179.8 (2) | C21—C19—N1—H19 | −67.9 (14) |
C8—C9—C10—C11 | 0.1 (4) | C20—C19—N1—H6 | 143.3 (7) |
C9—C10—C11—C12 | −0.8 (4) | C8—C19—N1—H6 | −114.9 (7) |
C10—C11—C12—C7 | 0.2 (3) | C21—C19—N1—H6 | −25.1 (7) |
C10—C11—C12—C16 | 177.2 (2) | C20—C19—N1—H16 | −87.8 (7) |
C8—C7—C12—C11 | 1.2 (2) | C8—C19—N1—H16 | 14.1 (7) |
N1—C7—C12—C11 | 174.14 (15) | C21—C19—N1—H16 | 103.8 (7) |
C8—C7—C12—C16 | −175.72 (15) | C20—C19—N1—C16 | −100.87 (18) |
N1—C7—C12—C16 | −2.8 (2) | C8—C19—N1—C16 | 0.94 (13) |
C6—C1—C13—O1 | −158.94 (18) | C21—C19—N1—C16 | 90.7 (2) |
C2—C1—C13—O1 | 17.8 (2) | C20—C19—N1—C6 | 121.01 (18) |
C6—C1—C13—C14 | 22.8 (2) | C8—C19—N1—C6 | −137.18 (12) |
C2—C1—C13—C14 | −160.47 (15) | C21—C19—N1—C6 | −47.4 (2) |
O1—C13—C14—N1 | −150.67 (17) | C17—C16—N1—C14 | −42.0 (3) |
C1—C13—C14—N1 | 27.6 (2) | C12—C16—N1—C14 | −124.01 (13) |
O1—C13—C14—C15 | 25.3 (2) | C18—C16—N1—C14 | 128.91 (15) |
C1—C13—C14—C15 | −156.36 (16) | C17—C16—N1—C7 | 80.7 (3) |
C11—C12—C16—C17 | 39.6 (2) | C12—C16—N1—C7 | −1.35 (11) |
C7—C12—C16—C17 | −143.48 (19) | C18—C16—N1—C7 | −108.43 (15) |
C11—C12—C16—C18 | −84.5 (2) | C17—C16—N1—H19 | 93.5 (8) |
C7—C12—C16—C18 | 92.4 (2) | C12—C16—N1—H19 | 11.4 (7) |
C11—C12—C16—N1 | −175.47 (19) | C18—C16—N1—H19 | −95.7 (7) |
C7—C12—C16—N1 | 1.41 (12) | C17—C16—N1—H6 | −132.1 (5) |
C9—C8—C19—C20 | −79.0 (3) | C12—C16—N1—H6 | 145.9 (4) |
C7—C8—C19—C20 | 99.4 (3) | C18—C16—N1—H6 | 38.8 (4) |
C9—C8—C19—C21 | 45.8 (3) | C17—C16—N1—H16 | −69.2 (13) |
C7—C8—C19—C21 | −135.8 (2) | C12—C16—N1—H16 | −151.2 (13) |
C9—C8—C19—N1 | 178.2 (2) | C18—C16—N1—H16 | 101.7 (13) |
C7—C8—C19—N1 | −3.37 (12) | C17—C16—N1—C19 | 83.0 (3) |
C15—C14—N1—C7 | 0.1 (2) | C12—C16—N1—C19 | 0.93 (13) |
C13—C14—N1—C7 | 175.62 (13) | C18—C16—N1—C19 | −106.16 (14) |
C15—C14—N1—H19 | −92.1 (5) | C17—C16—N1—C6 | −126.4 (3) |
C13—C14—N1—H19 | 83.4 (5) | C12—C16—N1—C6 | 151.59 (11) |
C15—C14—N1—H6 | 137.4 (4) | C18—C16—N1—C6 | 44.50 (14) |
C13—C14—N1—H6 | −47.1 (4) | C1—C6—N1—C14 | 38.99 (13) |
C15—C14—N1—H16 | 67.5 (4) | C5—C6—N1—C14 | 167.2 (3) |
C13—C14—N1—H16 | −116.9 (4) | C1—C6—N1—C7 | 177.29 (18) |
C15—C14—N1—C19 | −72.20 (19) | C5—C6—N1—C7 | −54.5 (4) |
C13—C14—N1—C19 | 103.35 (13) | C1—C6—N1—H19 | −72.1 (5) |
C15—C14—N1—C16 | 59.02 (18) | C5—C6—N1—H19 | 56.1 (6) |
C13—C14—N1—C16 | −125.43 (12) | C1—C6—N1—H6 | 154.0 (14) |
C15—C14—N1—C6 | 152.96 (17) | C5—C6—N1—H6 | −77.8 (14) |
C13—C14—N1—C6 | −31.50 (13) | C1—C6—N1—H16 | 119.2 (5) |
C12—C7—N1—C14 | 79.87 (19) | C5—C6—N1—H16 | −112.5 (6) |
C8—C7—N1—C14 | −106.92 (17) | C1—C6—N1—C19 | −79.20 (13) |
C12—C7—N1—H19 | −170.4 (5) | C5—C6—N1—C19 | 49.0 (4) |
C8—C7—N1—H19 | 2.8 (5) | C1—C6—N1—C16 | 134.78 (11) |
C12—C7—N1—H6 | −40.8 (6) | C5—C6—N1—C16 | −97.0 (3) |
C8—C7—N1—H6 | 132.4 (5) |
D—H···A | D—H | H···A | D···A | D—H···A |
C6—H6···N1 | 0.95 (2) | 2.47 (2) | 2.967 (2) | 112.3 (15) |
C16—H16···N1 | 0.96 (2) | 2.56 (2) | 2.943 (2) | 103.9 (13) |
C19—H19···N1 | 0.97 (2) | 2.37 (2) | 2.856 (2) | 110.3 (14) |