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The title compound, [Pd(C11H6O3)(C10H8N2)]·0.5H2O, contains two monoclear PdII complexes and one water molecule in the asymmetric unit. The Pd atom of each complex has a similar distorted cis-square-planar coordination geometry and is bonded to two N atoms from 2,2′-bi­pyridine ligand, and one carboxyl­ate O and one naphthol O atom from the 3-oxido­naphthalene-2-carboxyl­ate ligand. There are intermolecular π–π interactions, together with hydrogen bonds involving the solvent water mol­ecule.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804030983/ob6443sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804030983/ob6443Isup2.hkl
Contains datablock I

CCDC reference: 262221

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.006 Å
  • R factor = 0.031
  • wR factor = 0.044
  • Data-to-parameter ratio = 15.9

checkCIF/PLATON results

No syntax errors found



Alert level C GOODF01_ALERT_2_C The least squares goodness of fit parameter lies outside the range 0.80 <> 2.00 Goodness of fit given = 0.658 PLAT026_ALERT_3_C Ratio Observed / Unique Reflections too Low .... 43 Perc. PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 0.50 Ratio PLAT230_ALERT_2_C Hirshfeld Test Diff for N12 - C126 .. 5.16 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Pd2 - O21 .. 5.82 su
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 7 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: RAPID-AUTO (Rigaku, 2003); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2004) and CRYSTALS (Watkin et al., 1996); program(s) used to solve structure: SIR97 (Altomare et al., 1999) and DIRDIF99 (Beurskens et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: CrystalStructure.

(2,2'-Bipyridine-κ2N,N')(3-oxidonaphthalene-2-carboxylato- κ2O:O')palladium(II) hemihydrate top
Crystal data top
[Pd(C11H6O3)(C10H8N2)]·0.5H2OF(000) = 1832
Mr = 457.77Dx = 1.759 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -p_2ybcCell parameters from 16615 reflections
a = 21.399 (8) Åθ = 3.2–27.4°
b = 7.504 (5) ŵ = 1.10 mm1
c = 24.891 (16) ÅT = 293 K
β = 120.15 (4)°Needle, brown
V = 3456 (4) Å30.40 × 0.05 × 0.05 mm
Z = 8
Data collection top
Rigaku R-AXIS RAPID
diffractometer
7876 independent reflections
Radiation source: fine-focus sealed tube3381 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.082
Detector resolution: 10.00 pixels mm-1θmax = 27.5°, θmin = 3.2°
ω scansh = 2725
Absorption correction: multi-scan
(ABSCOR; Higashi, 1995)
k = 98
Tmin = 0.798, Tmax = 0.946l = 3224
33195 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.031Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.044H-atom parameters constrained
S = 0.66 w = 1/[σ2(Fo2) + (0.0133P)2]
where P = (Fo2 + 2Fc2)/3
7876 reflections(Δ/σ)max = 0.001
496 parametersΔρmax = 0.41 e Å3
0 restraintsΔρmin = 0.39 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Pd10.342408 (15)0.51498 (3)0.058170 (12)0.03859 (8)
O110.24980 (11)0.6192 (2)0.03708 (9)0.0439 (6)
O120.38312 (11)0.5371 (3)0.14887 (9)0.0470 (6)
O130.38866 (13)0.6201 (3)0.23506 (10)0.0578 (7)
N110.43242 (15)0.4025 (3)0.06688 (13)0.0399 (7)
N120.31083 (15)0.4788 (3)0.03107 (11)0.0372 (7)
C110.16148 (18)0.7433 (4)0.05316 (15)0.0366 (9)
H110.13120.74440.01030.044*
C120.23152 (19)0.6783 (4)0.07768 (15)0.0331 (8)
C130.27804 (18)0.6792 (4)0.14359 (15)0.0326 (8)
C1310.35390 (19)0.6080 (4)0.17787 (16)0.0402 (9)
C140.25107 (19)0.7465 (4)0.17976 (14)0.0385 (9)
H140.28150.74790.22260.046*
C150.1551 (2)0.8836 (4)0.19340 (16)0.0454 (9)
H150.18570.88800.23620.054*
C160.0869 (2)0.9454 (4)0.16865 (17)0.0502 (10)
H160.07130.99420.19420.060*
C170.0399 (2)0.9358 (4)0.10446 (18)0.0533 (10)
H170.00750.97520.08760.064*
C180.0632 (2)0.8684 (4)0.06600 (16)0.0453 (10)
H180.03140.86320.02340.054*
C190.13490 (19)0.8070 (4)0.09073 (16)0.0335 (8)
C1100.18115 (19)0.8121 (4)0.15571 (16)0.0344 (8)
C1120.4279 (2)0.3555 (4)0.01287 (16)0.0377 (9)
C1130.4851 (2)0.2711 (4)0.01262 (17)0.0545 (11)
H1130.48120.23590.02480.065*
C1140.5478 (2)0.2390 (5)0.06763 (19)0.0603 (11)
H1140.58680.18350.06790.072*
C1150.5517 (2)0.2907 (4)0.12226 (18)0.0584 (11)
H1150.59380.27170.16000.070*
C1160.4930 (2)0.3704 (4)0.12082 (17)0.0493 (10)
H1160.49550.40260.15790.059*
C1220.35953 (19)0.3989 (4)0.04291 (16)0.0368 (9)
C1230.3427 (2)0.3644 (4)0.10270 (17)0.0504 (10)
H1230.37650.31070.11050.060*
C1240.2758 (2)0.4094 (4)0.15096 (16)0.0537 (11)
H1240.26400.38640.19170.064*
C1250.22642 (19)0.4886 (4)0.13890 (15)0.0533 (10)
H1250.18060.51860.17110.064*
C1260.24628 (19)0.5228 (4)0.07796 (15)0.0475 (9)
H1260.21340.57840.06940.057*
Pd20.246831 (15)0.42615 (3)0.484602 (12)0.04301 (8)
O210.15507 (12)0.3548 (3)0.41288 (10)0.0538 (7)
O220.28647 (12)0.5278 (3)0.43456 (10)0.0520 (6)
O230.29069 (12)0.5895 (3)0.35049 (10)0.0619 (7)
N210.33689 (15)0.4789 (3)0.56539 (12)0.0436 (7)
N220.21717 (17)0.3310 (3)0.54345 (13)0.0395 (7)
C210.06943 (19)0.3178 (4)0.30951 (16)0.0400 (9)
H210.04190.25560.32270.048*
C220.13639 (19)0.3804 (4)0.35372 (16)0.0395 (9)
C230.18038 (18)0.4672 (4)0.33316 (15)0.0364 (8)
C2310.25644 (19)0.5323 (4)0.37458 (17)0.0455 (9)
C240.15184 (18)0.4908 (4)0.27013 (15)0.0382 (8)
H240.18050.54680.25690.046*
C250.05253 (19)0.4698 (4)0.16092 (15)0.0421 (9)
H250.07920.53400.14740.050*
C260.0134 (2)0.4120 (4)0.11887 (16)0.0476 (10)
H260.03190.43600.07690.057*
C270.0549 (2)0.3146 (4)0.13852 (17)0.0490 (10)
H270.10030.27190.10930.059*
C280.02842 (19)0.2829 (4)0.20021 (16)0.0435 (9)
H280.05650.22020.21260.052*
C290.04110 (19)0.3437 (4)0.24592 (16)0.0355 (9)
C2100.08308 (18)0.4366 (4)0.22508 (15)0.0331 (8)
C2120.3354 (2)0.4264 (4)0.61655 (17)0.0438 (9)
C2130.3954 (2)0.4500 (5)0.67481 (17)0.0610 (11)
H2130.39450.41160.70990.073*
C2140.4566 (2)0.5305 (5)0.68092 (18)0.0689 (12)
H2140.49700.54750.72000.083*
C2150.4567 (2)0.5847 (5)0.6286 (2)0.0656 (12)
H2150.49720.63980.63150.079*
C2160.3962 (2)0.5566 (4)0.57143 (17)0.0492 (10)
H2160.39660.59300.53590.059*
C2220.2672 (2)0.3459 (4)0.60443 (18)0.0419 (10)
C2230.2530 (2)0.2888 (4)0.64987 (17)0.0549 (11)
H2230.28790.29810.69170.066*
C2240.1858 (2)0.2175 (4)0.63195 (19)0.0582 (12)
H2240.17470.18020.66190.070*
C2250.1354 (2)0.2017 (4)0.57014 (19)0.0565 (11)
H2250.09020.15310.55770.068*
C2260.1528 (2)0.2591 (4)0.52629 (16)0.0497 (10)
H2260.11910.24720.48430.060*
O10.35634 (14)0.3695 (3)0.29959 (11)0.0805 (9)
H10.36710.44990.27640.097*
H20.33100.44520.31210.097*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pd10.03391 (18)0.04380 (16)0.03828 (17)0.00217 (14)0.01830 (14)0.00346 (13)
O110.0356 (16)0.0649 (15)0.0320 (15)0.0154 (12)0.0176 (13)0.0025 (11)
O120.0391 (16)0.0645 (16)0.0363 (14)0.0063 (13)0.0180 (13)0.0034 (12)
O130.0397 (18)0.0975 (19)0.0296 (15)0.0113 (14)0.0126 (14)0.0086 (13)
N110.0292 (19)0.0444 (17)0.0383 (18)0.0028 (15)0.0111 (16)0.0040 (15)
N120.0301 (18)0.0454 (17)0.0333 (17)0.0028 (15)0.0140 (15)0.0065 (14)
C110.031 (3)0.038 (2)0.032 (2)0.0017 (18)0.010 (2)0.0024 (16)
C120.033 (3)0.034 (2)0.035 (2)0.0030 (17)0.018 (2)0.0032 (16)
C130.029 (2)0.036 (2)0.031 (2)0.0039 (17)0.013 (2)0.0045 (16)
C1310.027 (2)0.051 (2)0.038 (2)0.0055 (18)0.013 (2)0.0109 (19)
C140.040 (3)0.046 (2)0.029 (2)0.0079 (19)0.016 (2)0.0011 (17)
C150.048 (3)0.048 (2)0.040 (2)0.0041 (19)0.022 (2)0.0026 (17)
C160.051 (3)0.053 (2)0.053 (3)0.001 (2)0.031 (2)0.005 (2)
C170.049 (3)0.047 (2)0.071 (3)0.009 (2)0.036 (3)0.006 (2)
C180.041 (3)0.046 (2)0.044 (2)0.0050 (19)0.018 (2)0.0046 (17)
C190.030 (3)0.031 (2)0.039 (2)0.0012 (16)0.017 (2)0.0021 (16)
C1100.032 (3)0.037 (2)0.038 (2)0.0039 (17)0.020 (2)0.0022 (17)
C1120.037 (3)0.036 (2)0.044 (2)0.0026 (18)0.023 (2)0.0045 (17)
C1130.050 (3)0.061 (3)0.058 (3)0.008 (2)0.030 (3)0.001 (2)
C1140.045 (3)0.067 (3)0.075 (3)0.014 (2)0.034 (3)0.013 (2)
C1150.033 (3)0.069 (3)0.060 (3)0.009 (2)0.013 (2)0.014 (2)
C1160.045 (3)0.056 (3)0.048 (3)0.003 (2)0.024 (2)0.0072 (19)
C1220.031 (2)0.036 (2)0.045 (2)0.0006 (18)0.021 (2)0.0027 (18)
C1230.048 (3)0.060 (3)0.048 (3)0.008 (2)0.027 (2)0.001 (2)
C1240.070 (3)0.057 (2)0.039 (2)0.006 (2)0.031 (3)0.001 (2)
C1250.047 (3)0.068 (3)0.036 (2)0.011 (2)0.015 (2)0.005 (2)
C1260.050 (3)0.050 (2)0.044 (2)0.010 (2)0.024 (2)0.0062 (19)
Pd20.0364 (2)0.04919 (17)0.04085 (17)0.00142 (15)0.01744 (16)0.00062 (14)
O210.0404 (18)0.0854 (18)0.0285 (15)0.0227 (13)0.0119 (14)0.0003 (12)
O220.0402 (16)0.0681 (17)0.0468 (16)0.0155 (13)0.0212 (14)0.0034 (13)
O230.0371 (17)0.0952 (19)0.0596 (18)0.0230 (14)0.0290 (15)0.0024 (14)
N210.035 (2)0.0440 (17)0.0474 (19)0.0038 (16)0.0175 (16)0.0120 (15)
N220.038 (2)0.0418 (18)0.039 (2)0.0075 (15)0.0194 (18)0.0019 (14)
C210.032 (3)0.046 (2)0.045 (2)0.0046 (18)0.021 (2)0.0023 (18)
C220.029 (2)0.047 (2)0.038 (2)0.0023 (18)0.014 (2)0.0026 (18)
C230.032 (2)0.036 (2)0.044 (2)0.0008 (17)0.021 (2)0.0022 (17)
C2310.037 (3)0.049 (2)0.051 (3)0.0009 (19)0.023 (2)0.000 (2)
C240.039 (2)0.038 (2)0.047 (2)0.0006 (18)0.029 (2)0.0009 (18)
C250.046 (3)0.042 (2)0.042 (2)0.0003 (19)0.025 (2)0.0005 (18)
C260.045 (3)0.056 (2)0.041 (2)0.000 (2)0.021 (2)0.0019 (19)
C270.038 (3)0.050 (2)0.049 (3)0.0021 (19)0.014 (2)0.0095 (19)
C280.037 (3)0.045 (2)0.052 (3)0.0017 (19)0.024 (2)0.0004 (19)
C290.033 (3)0.031 (2)0.042 (2)0.0006 (16)0.019 (2)0.0013 (16)
C2100.030 (2)0.0316 (19)0.039 (2)0.0015 (17)0.019 (2)0.0016 (16)
C2120.039 (3)0.048 (2)0.036 (2)0.016 (2)0.013 (2)0.0011 (19)
C2130.055 (3)0.070 (3)0.045 (3)0.018 (2)0.016 (3)0.001 (2)
C2140.047 (3)0.084 (3)0.050 (3)0.017 (3)0.005 (2)0.013 (2)
C2150.035 (3)0.076 (3)0.067 (3)0.004 (2)0.011 (3)0.015 (3)
C2160.045 (3)0.048 (2)0.052 (3)0.007 (2)0.022 (2)0.0024 (19)
C2220.044 (3)0.040 (2)0.038 (3)0.0163 (19)0.018 (2)0.0011 (18)
C2230.062 (4)0.058 (3)0.041 (3)0.016 (2)0.023 (3)0.002 (2)
C2240.078 (4)0.050 (3)0.064 (3)0.011 (2)0.048 (3)0.008 (2)
C2250.056 (3)0.055 (3)0.065 (3)0.005 (2)0.035 (3)0.006 (2)
C2260.044 (3)0.052 (2)0.049 (3)0.005 (2)0.020 (2)0.0038 (19)
O10.096 (3)0.0889 (19)0.077 (2)0.0067 (16)0.059 (2)0.0100 (14)
Geometric parameters (Å, º) top
Pd1—O111.942 (2)Pd2—O221.978 (2)
Pd1—O121.977 (2)Pd2—N221.998 (3)
Pd1—N121.989 (3)Pd2—N212.005 (3)
Pd1—N112.012 (3)O21—C221.332 (3)
O11—C121.330 (3)O22—C2311.296 (4)
O12—C1311.284 (3)O23—C2311.234 (3)
O13—C1311.235 (4)N21—C2161.334 (4)
N11—C1161.339 (4)N21—C2121.349 (4)
N11—C1121.346 (4)N22—C2261.333 (4)
N12—C1261.326 (4)N22—C2221.353 (4)
N12—C1221.357 (3)C21—C221.379 (4)
C11—C121.392 (4)C21—C291.395 (4)
C11—C191.400 (4)C21—H210.9300
C11—H110.9300C22—C231.434 (4)
C12—C131.429 (4)C23—C241.380 (4)
C13—C141.386 (4)C23—C2311.505 (4)
C13—C1311.502 (4)C24—C2101.389 (4)
C14—C1101.393 (4)C24—H240.9300
C14—H140.9300C25—C261.339 (4)
C15—C161.349 (4)C25—C2101.411 (4)
C15—C1101.416 (4)C25—H250.9300
C15—H150.9300C26—C271.412 (4)
C16—C171.398 (4)C26—H260.9300
C16—H160.9300C27—C281.364 (4)
C17—C181.378 (4)C27—H270.9300
C17—H170.9300C28—C291.420 (4)
C18—C191.412 (4)C28—H280.9300
C18—H180.9300C29—C2101.425 (4)
C19—C1101.410 (4)C212—C2131.383 (4)
C112—C1131.380 (4)C212—C2221.463 (5)
C112—C1221.461 (4)C213—C2141.379 (5)
C113—C1141.374 (5)C213—H2130.9300
C113—H1130.9300C214—C2151.366 (4)
C114—C1151.375 (4)C214—H2140.9300
C114—H1140.9300C215—C2161.377 (4)
C115—C1161.375 (4)C215—H2150.9300
C115—H1150.9300C216—H2160.9300
C116—H1160.9300C222—C2231.379 (4)
C122—C1231.369 (4)C223—C2241.382 (5)
C123—C1241.371 (4)C223—H2230.9300
C123—H1230.9300C224—C2251.370 (5)
C124—C1251.371 (4)C224—H2240.9300
C124—H1240.9300C225—C2261.388 (4)
C125—C1261.378 (4)C225—H2250.9300
C125—H1250.9300C226—H2260.9300
C126—H1260.9300O1—H10.94
Pd2—O211.951 (2)O1—H20.94
O11—Pd1—O1294.56 (9)O21—Pd2—N2291.62 (12)
O11—Pd1—N1291.42 (11)O22—Pd2—N22173.65 (11)
O12—Pd1—N12173.99 (10)O21—Pd2—N21171.95 (10)
O11—Pd1—N11171.81 (10)O22—Pd2—N2193.17 (11)
O12—Pd1—N1193.62 (11)N22—Pd2—N2180.48 (13)
N12—Pd1—N1180.39 (12)C22—O21—Pd2125.2 (2)
C12—O11—Pd1125.4 (2)C231—O22—Pd2127.9 (2)
C131—O12—Pd1128.1 (2)C216—N21—C212119.6 (3)
C116—N11—C112120.1 (3)C216—N21—Pd2125.4 (2)
C116—N11—Pd1125.2 (2)C212—N21—Pd2115.0 (2)
C112—N11—Pd1114.7 (2)C226—N22—C222120.1 (3)
C126—N12—C122119.5 (3)C226—N22—Pd2124.5 (3)
C126—N12—Pd1124.6 (2)C222—N22—Pd2115.4 (3)
C122—N12—Pd1115.8 (2)C22—C21—C29122.9 (3)
C12—C11—C19122.4 (3)C22—C21—H21118.6
C12—C11—H11118.8C29—C21—H21118.6
C19—C11—H11118.8O21—C22—C21116.6 (3)
O11—C12—C11116.5 (3)O21—C22—C23125.0 (3)
O11—C12—C13124.9 (3)C21—C22—C23118.4 (3)
C11—C12—C13118.5 (3)C24—C23—C22118.0 (3)
C14—C13—C12118.0 (3)C24—C23—C231116.5 (3)
C14—C13—C131116.4 (3)C22—C23—C231125.5 (3)
C12—C13—C131125.5 (3)O23—C231—O22119.8 (3)
O13—C131—O12119.8 (3)O23—C231—C23118.8 (3)
O13—C131—C13118.8 (3)O22—C231—C23121.4 (3)
O12—C131—C13121.4 (3)C23—C24—C210124.4 (3)
C13—C14—C110123.9 (3)C23—C24—H24117.8
C13—C14—H14118.1C210—C24—H24117.8
C110—C14—H14118.1C26—C25—C210122.3 (3)
C16—C15—C110121.5 (3)C26—C25—H25118.8
C16—C15—H15119.2C210—C25—H25118.8
C110—C15—H15119.2C25—C26—C27119.7 (3)
C15—C16—C17119.8 (3)C25—C26—H26120.1
C15—C16—H16120.1C27—C26—H26120.1
C17—C16—H16120.1C28—C27—C26120.1 (3)
C18—C17—C16120.6 (3)C28—C27—H27119.9
C18—C17—H17119.7C26—C27—H27119.9
C16—C17—H17119.7C27—C28—C29121.4 (3)
C17—C18—C19120.6 (3)C27—C28—H28119.3
C17—C18—H18119.7C29—C28—H28119.3
C19—C18—H18119.7C21—C29—C28123.2 (3)
C11—C19—C110119.2 (3)C21—C29—C210119.1 (3)
C11—C19—C18122.5 (3)C28—C29—C210117.7 (3)
C110—C19—C18118.3 (3)C24—C210—C25124.2 (3)
C14—C110—C19117.8 (3)C24—C210—C29117.1 (3)
C14—C110—C15123.0 (3)C25—C210—C29118.7 (3)
C19—C110—C15119.1 (3)N21—C212—C213120.1 (4)
N11—C112—C113120.4 (3)N21—C212—C222114.9 (3)
N11—C112—C122115.2 (3)C213—C212—C222125.0 (4)
C113—C112—C122124.4 (3)C214—C213—C212120.1 (4)
C114—C113—C112120.0 (3)C214—C213—H213119.9
C114—C113—H113120.0C212—C213—H213119.9
C112—C113—H113120.0C215—C214—C213118.8 (4)
C113—C114—C115118.7 (4)C215—C214—H214120.6
C113—C114—H114120.6C213—C214—H214120.6
C115—C114—H114120.6C214—C215—C216119.2 (4)
C116—C115—C114119.7 (4)C214—C215—H215120.4
C116—C115—H115120.2C216—C215—H215120.4
C114—C115—H115120.2N21—C216—C215122.1 (3)
N11—C116—C115121.1 (3)N21—C216—H216118.9
N11—C116—H116119.5C215—C216—H216118.9
C115—C116—H116119.5N22—C222—C223121.2 (4)
N12—C122—C123120.6 (3)N22—C222—C212114.2 (3)
N12—C122—C112113.8 (3)C223—C222—C212124.5 (4)
C123—C122—C112125.6 (3)C222—C223—C224118.6 (4)
C122—C123—C124119.6 (3)C222—C223—H223120.7
C122—C123—H123120.2C224—C223—H223120.7
C124—C123—H123120.2C225—C224—C223120.0 (4)
C123—C124—C125119.7 (3)C225—C224—H224120.0
C123—C124—H124120.1C223—C224—H224120.0
C125—C124—H124120.1C224—C225—C226119.0 (4)
C124—C125—C126118.4 (3)C224—C225—H225120.5
C124—C125—H125120.8C226—C225—H225120.5
C126—C125—H125120.8N22—C226—C225121.1 (4)
N12—C126—C125122.1 (3)N22—C226—H226119.5
N12—C126—H126119.0C225—C226—H226119.5
C125—C126—H126119.0H1—O1—H2100.1
O21—Pd2—O2294.73 (10)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1—H1···O130.941.842.777 (3)176
O1—H2···O230.941.912.844 (3)171
 

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