Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804017076/ob6384sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804017076/ob6384Isup2.hkl |
CCDC reference: 240269
Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 1997); software used to prepare material for publication: SHELXTL.
[Cu2(C2N3)Cl2(C6H15N3)2]ClO4 | F(000) = 1272 |
Mr = 621.90 | Dx = 1.718 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
a = 17.882 (6) Å | Cell parameters from 864 reflections |
b = 7.494 (3) Å | θ = 2.3–26.0° |
c = 18.596 (6) Å | µ = 2.14 mm−1 |
β = 105.200 (5)° | T = 293 K |
V = 2404.9 (14) Å3 | Block, blue |
Z = 4 | 0.24 × 0.18 × 0.12 mm |
Bruker SMART CCD area-detector diffractometer | 4901 independent reflections |
Radiation source: fine-focus sealed tube | 3372 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.047 |
φ and ω scans | θmax = 26.4°, θmin = 1.4° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −22→22 |
Tmin = 0.592, Tmax = 0.773 | k = −6→9 |
13116 measured reflections | l = −23→23 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.043 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.103 | H-atom parameters constrained |
S = 1.05 | w = 1/[σ2(Fo2) + (0.0444P)2 + 0.6189P] where P = (Fo2 + 2Fc2)/3 |
4901 reflections | (Δ/σ)max = 0.001 |
289 parameters | Δρmax = 0.59 e Å−3 |
0 restraints | Δρmin = −0.42 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Cu1 | 0.10325 (3) | 0.05726 (6) | 0.16789 (3) | 0.02783 (14) | |
Cu2 | 0.11208 (3) | 0.02841 (6) | 0.57760 (3) | 0.03258 (15) | |
Cl1 | 0.16795 (6) | −0.15756 (13) | 0.12035 (6) | 0.0430 (3) | |
Cl2 | 0.05043 (7) | −0.16675 (13) | 0.63700 (6) | 0.0456 (3) | |
N1 | 0.0867 (2) | 0.2035 (4) | 0.07432 (18) | 0.0403 (9) | |
H1C | 0.0920 | 0.1303 | 0.0369 | 0.048* | |
N2 | 0.18742 (19) | 0.2817 (5) | 0.21444 (19) | 0.0434 (9) | |
H2C | 0.2292 | 0.2424 | 0.2502 | 0.052* | |
N3 | 0.0252 (2) | 0.2383 (4) | 0.1905 (2) | 0.0444 (9) | |
H3C | −0.0116 | 0.1771 | 0.2061 | 0.053* | |
N4 | 0.0966 (2) | −0.0888 (5) | 0.25400 (19) | 0.0439 (9) | |
N5 | 0.0802 (3) | −0.2480 (5) | 0.36396 (19) | 0.0595 (12) | |
N6 | 0.0946 (3) | −0.1195 (5) | 0.4866 (2) | 0.0563 (11) | |
N7 | 0.2367 (2) | 0.0611 (5) | 0.5891 (2) | 0.0455 (9) | |
H7A | 0.2592 | −0.0480 | 0.5898 | 0.055* | |
N8 | 0.10725 (19) | 0.2689 (4) | 0.51709 (17) | 0.0354 (8) | |
H8A | 0.0710 | 0.2590 | 0.4726 | 0.042* | |
N9 | 0.13557 (18) | 0.1933 (4) | 0.66602 (17) | 0.0318 (8) | |
H9C | 0.1027 | 0.1665 | 0.6945 | 0.038* | |
C1 | 0.1404 (3) | 0.3531 (7) | 0.0793 (3) | 0.0590 (14) | |
H1A | 0.1137 | 0.4637 | 0.0836 | 0.071* | |
H1B | 0.1576 | 0.3587 | 0.0341 | 0.071* | |
C2 | 0.2086 (3) | 0.3345 (6) | 0.1444 (3) | 0.0542 (13) | |
H2A | 0.2363 | 0.4471 | 0.1528 | 0.065* | |
H2B | 0.2433 | 0.2454 | 0.1333 | 0.065* | |
C3 | 0.1449 (3) | 0.4216 (6) | 0.2425 (3) | 0.0602 (14) | |
H3A | 0.1336 | 0.5192 | 0.2070 | 0.072* | |
H3B | 0.1769 | 0.4676 | 0.2892 | 0.072* | |
C4 | 0.0707 (3) | 0.3511 (6) | 0.2543 (3) | 0.0718 (18) | |
H4A | 0.0388 | 0.4509 | 0.2615 | 0.086* | |
H4B | 0.0824 | 0.2802 | 0.2996 | 0.086* | |
C5 | −0.0129 (3) | 0.3377 (7) | 0.1229 (3) | 0.0676 (16) | |
H5A | −0.0685 | 0.3374 | 0.1167 | 0.081* | |
H5B | 0.0047 | 0.4606 | 0.1281 | 0.081* | |
C6 | 0.0037 (3) | 0.2610 (7) | 0.0576 (3) | 0.0670 (16) | |
H6A | −0.0067 | 0.3483 | 0.0177 | 0.080* | |
H6B | −0.0298 | 0.1590 | 0.0411 | 0.080* | |
C7 | 0.0887 (2) | −0.1562 (5) | 0.3066 (2) | 0.0362 (10) | |
C8 | 0.0891 (3) | −0.1714 (5) | 0.4280 (2) | 0.0422 (11) | |
C9 | 0.2407 (3) | 0.1576 (7) | 0.5218 (3) | 0.0671 (15) | |
H9A | 0.2301 | 0.0752 | 0.4801 | 0.081* | |
H9B | 0.2928 | 0.2033 | 0.5285 | 0.081* | |
C10 | 0.1841 (3) | 0.3103 (6) | 0.5037 (3) | 0.0590 (14) | |
H10A | 0.2063 | 0.4126 | 0.5337 | 0.071* | |
H10B | 0.1766 | 0.3427 | 0.4518 | 0.071* | |
C11 | 0.0817 (3) | 0.4029 (5) | 0.5639 (2) | 0.0434 (11) | |
H11A | 0.0267 | 0.3888 | 0.5587 | 0.052* | |
H11B | 0.0901 | 0.5215 | 0.5466 | 0.052* | |
C12 | 0.1248 (3) | 0.3851 (5) | 0.6446 (2) | 0.0426 (11) | |
H12A | 0.1750 | 0.4425 | 0.6532 | 0.051* | |
H12B | 0.0960 | 0.4442 | 0.6752 | 0.051* | |
C13 | 0.2149 (2) | 0.1471 (6) | 0.7088 (2) | 0.0457 (11) | |
H13A | 0.2151 | 0.0285 | 0.7297 | 0.055* | |
H13B | 0.2320 | 0.2306 | 0.7497 | 0.055* | |
C14 | 0.2697 (2) | 0.1526 (7) | 0.6604 (3) | 0.0530 (13) | |
H14A | 0.2807 | 0.2758 | 0.6509 | 0.064* | |
H14B | 0.3180 | 0.0957 | 0.6860 | 0.064* | |
Cl3 | 0.11492 (7) | 0.16551 (15) | 0.86812 (6) | 0.0464 (3) | |
O1 | 0.1127 (2) | 0.0088 (5) | 0.8242 (2) | 0.0823 (13) | |
O2 | 0.1875 (2) | 0.1836 (6) | 0.9195 (3) | 0.1106 (16) | |
O3 | 0.1022 (2) | 0.3147 (5) | 0.8182 (2) | 0.0885 (13) | |
O4 | 0.0531 (2) | 0.1623 (5) | 0.9046 (2) | 0.0832 (12) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Cu1 | 0.0360 (3) | 0.0239 (2) | 0.0245 (3) | 0.0019 (2) | 0.0097 (2) | 0.0007 (2) |
Cu2 | 0.0497 (3) | 0.0250 (3) | 0.0255 (3) | −0.0065 (2) | 0.0143 (2) | −0.0030 (2) |
Cl1 | 0.0570 (7) | 0.0353 (5) | 0.0397 (6) | 0.0129 (5) | 0.0179 (5) | −0.0022 (5) |
Cl2 | 0.0650 (8) | 0.0331 (6) | 0.0456 (6) | −0.0131 (5) | 0.0269 (6) | −0.0022 (5) |
N1 | 0.065 (3) | 0.0283 (18) | 0.0262 (18) | 0.0004 (17) | 0.0100 (18) | 0.0020 (15) |
N2 | 0.035 (2) | 0.043 (2) | 0.044 (2) | 0.0059 (16) | −0.0035 (17) | −0.0127 (18) |
N3 | 0.043 (2) | 0.0335 (19) | 0.065 (3) | 0.0012 (17) | 0.0290 (19) | −0.0003 (19) |
N4 | 0.065 (3) | 0.041 (2) | 0.032 (2) | 0.0029 (18) | 0.0216 (19) | 0.0035 (17) |
N5 | 0.124 (4) | 0.036 (2) | 0.032 (2) | −0.020 (2) | 0.042 (2) | −0.0077 (18) |
N6 | 0.106 (3) | 0.037 (2) | 0.031 (2) | −0.016 (2) | 0.027 (2) | −0.0068 (18) |
N7 | 0.044 (2) | 0.045 (2) | 0.053 (2) | 0.0155 (18) | 0.0235 (19) | 0.0044 (19) |
N8 | 0.044 (2) | 0.0357 (18) | 0.0232 (17) | −0.0053 (16) | 0.0033 (15) | 0.0026 (15) |
N9 | 0.041 (2) | 0.0287 (17) | 0.0284 (18) | −0.0045 (15) | 0.0147 (16) | −0.0020 (15) |
C1 | 0.084 (4) | 0.053 (3) | 0.046 (3) | −0.026 (3) | 0.027 (3) | −0.005 (2) |
C2 | 0.041 (3) | 0.052 (3) | 0.074 (4) | −0.006 (2) | 0.023 (3) | 0.018 (3) |
C3 | 0.066 (3) | 0.056 (3) | 0.055 (3) | −0.009 (3) | 0.011 (3) | −0.023 (3) |
C4 | 0.127 (5) | 0.038 (3) | 0.081 (4) | −0.027 (3) | 0.081 (4) | −0.030 (3) |
C5 | 0.042 (3) | 0.050 (3) | 0.111 (5) | 0.013 (2) | 0.019 (3) | 0.017 (3) |
C6 | 0.065 (4) | 0.055 (3) | 0.064 (4) | 0.019 (3) | −0.013 (3) | 0.008 (3) |
C7 | 0.046 (3) | 0.032 (2) | 0.034 (2) | −0.0010 (19) | 0.016 (2) | −0.008 (2) |
C8 | 0.069 (3) | 0.028 (2) | 0.035 (3) | −0.013 (2) | 0.023 (2) | 0.002 (2) |
C9 | 0.063 (4) | 0.082 (4) | 0.071 (4) | 0.004 (3) | 0.044 (3) | 0.004 (3) |
C10 | 0.068 (4) | 0.059 (3) | 0.059 (3) | −0.012 (3) | 0.033 (3) | 0.014 (3) |
C11 | 0.050 (3) | 0.028 (2) | 0.047 (3) | 0.003 (2) | 0.002 (2) | 0.003 (2) |
C12 | 0.056 (3) | 0.031 (2) | 0.039 (3) | 0.006 (2) | 0.008 (2) | −0.0028 (19) |
C13 | 0.053 (3) | 0.040 (2) | 0.036 (3) | 0.006 (2) | −0.003 (2) | 0.001 (2) |
C14 | 0.033 (3) | 0.063 (3) | 0.057 (3) | 0.004 (2) | 0.001 (2) | −0.001 (3) |
Cl3 | 0.0579 (7) | 0.0411 (6) | 0.0420 (6) | −0.0080 (5) | 0.0165 (6) | −0.0056 (5) |
O1 | 0.083 (3) | 0.057 (2) | 0.118 (4) | −0.016 (2) | 0.045 (3) | −0.038 (2) |
O2 | 0.083 (3) | 0.106 (4) | 0.113 (4) | −0.021 (3) | −0.028 (3) | −0.003 (3) |
O3 | 0.124 (4) | 0.064 (3) | 0.095 (3) | 0.020 (2) | 0.061 (3) | 0.028 (2) |
O4 | 0.103 (3) | 0.099 (3) | 0.064 (2) | −0.021 (2) | 0.051 (2) | −0.011 (2) |
Cu1—N4 | 1.969 (4) | C1—H1A | 0.9700 |
Cu1—N1 | 2.011 (3) | C1—H1B | 0.9700 |
Cu1—N3 | 2.068 (3) | C2—H2A | 0.9700 |
Cu1—N2 | 2.272 (3) | C2—H2B | 0.9700 |
Cu1—Cl1 | 2.2909 (12) | C3—C4 | 1.496 (6) |
Cu2—N6 | 1.979 (4) | C3—H3A | 0.9700 |
Cu2—N9 | 2.011 (3) | C3—H3B | 0.9700 |
Cu2—N8 | 2.114 (3) | C4—H4A | 0.9700 |
Cu2—N7 | 2.196 (4) | C4—H4B | 0.9700 |
Cu2—Cl2 | 2.2833 (12) | C5—C6 | 1.442 (7) |
N1—C1 | 1.463 (5) | C5—H5A | 0.9700 |
N1—C6 | 1.497 (6) | C5—H5B | 0.9700 |
N1—H1C | 0.9100 | C6—H6A | 0.9700 |
N2—C3 | 1.469 (5) | C6—H6B | 0.9700 |
N2—C2 | 1.501 (5) | C9—C10 | 1.506 (7) |
N2—H2C | 0.9100 | C9—H9A | 0.9700 |
N3—C5 | 1.467 (6) | C9—H9B | 0.9700 |
N3—C4 | 1.510 (6) | C10—H10A | 0.9700 |
N3—H3C | 0.9100 | C10—H10B | 0.9700 |
N4—C7 | 1.142 (5) | C11—C12 | 1.502 (6) |
N5—C8 | 1.295 (5) | C11—H11A | 0.9700 |
N5—C7 | 1.311 (5) | C11—H11B | 0.9700 |
N6—C8 | 1.135 (5) | C12—H12A | 0.9700 |
N7—C9 | 1.463 (6) | C12—H12B | 0.9700 |
N7—C14 | 1.470 (5) | C13—C14 | 1.495 (6) |
N7—H7A | 0.9100 | C13—H13A | 0.9700 |
N8—C11 | 1.477 (5) | C13—H13B | 0.9700 |
N8—C10 | 1.493 (5) | C14—H14A | 0.9700 |
N8—H8A | 0.9100 | C14—H14B | 0.9700 |
N9—C13 | 1.474 (5) | Cl3—O2 | 1.402 (4) |
N9—C12 | 1.490 (5) | Cl3—O1 | 1.425 (4) |
N9—H9C | 0.9100 | Cl3—O3 | 1.433 (4) |
C1—C2 | 1.483 (6) | Cl3—O4 | 1.441 (4) |
N4—Cu1—N1 | 168.44 (15) | H2A—C2—H2B | 107.8 |
N4—Cu1—N3 | 90.63 (14) | N2—C3—C4 | 111.2 (4) |
N1—Cu1—N3 | 82.20 (14) | N2—C3—H3A | 109.4 |
N4—Cu1—N2 | 106.10 (14) | C4—C3—H3A | 109.4 |
N1—Cu1—N2 | 81.89 (13) | N2—C3—H3B | 109.4 |
N3—Cu1—N2 | 81.48 (13) | C4—C3—H3B | 109.4 |
N4—Cu1—Cl1 | 93.88 (11) | H3A—C3—H3B | 108.0 |
N1—Cu1—Cl1 | 91.37 (10) | C3—C4—N3 | 113.4 (4) |
N3—Cu1—Cl1 | 167.41 (11) | C3—C4—H4A | 108.9 |
N2—Cu1—Cl1 | 108.43 (9) | N3—C4—H4A | 108.9 |
N6—Cu2—N9 | 174.88 (14) | C3—C4—H4B | 108.9 |
N6—Cu2—N8 | 92.69 (14) | N3—C4—H4B | 108.9 |
N9—Cu2—N8 | 83.21 (12) | H4A—C4—H4B | 107.7 |
N6—Cu2—N7 | 94.31 (16) | C6—C5—N3 | 111.6 (4) |
N9—Cu2—N7 | 82.09 (13) | C6—C5—H5A | 109.3 |
N8—Cu2—N7 | 81.71 (13) | N3—C5—H5A | 109.3 |
N6—Cu2—Cl2 | 93.84 (11) | C6—C5—H5B | 109.3 |
N9—Cu2—Cl2 | 91.26 (9) | N3—C5—H5B | 109.3 |
N8—Cu2—Cl2 | 147.77 (10) | H5A—C5—H5B | 108.0 |
N7—Cu2—Cl2 | 129.09 (10) | C5—C6—N1 | 110.5 (4) |
C1—N1—C6 | 113.0 (4) | C5—C6—H6A | 109.5 |
C1—N1—Cu1 | 114.6 (3) | N1—C6—H6A | 109.5 |
C6—N1—Cu1 | 104.5 (3) | C5—C6—H6B | 109.5 |
C1—N1—H1C | 108.2 | N1—C6—H6B | 109.5 |
C6—N1—H1C | 108.2 | H6A—C6—H6B | 108.1 |
Cu1—N1—H1C | 108.2 | N4—C7—N5 | 174.6 (4) |
C3—N2—C2 | 113.1 (4) | N6—C8—N5 | 173.3 (4) |
C3—N2—Cu1 | 108.1 (3) | N7—C9—C10 | 112.7 (4) |
C2—N2—Cu1 | 99.1 (2) | N7—C9—H9A | 109.0 |
C3—N2—H2C | 112.0 | C10—C9—H9A | 109.0 |
C2—N2—H2C | 112.0 | N7—C9—H9B | 109.0 |
Cu1—N2—H2C | 112.0 | C10—C9—H9B | 109.0 |
C5—N3—C4 | 115.1 (4) | H9A—C9—H9B | 107.8 |
C5—N3—Cu1 | 110.2 (3) | N8—C10—C9 | 113.5 (4) |
C4—N3—Cu1 | 105.9 (3) | N8—C10—H10A | 108.9 |
C5—N3—H3C | 108.5 | C9—C10—H10A | 108.9 |
C4—N3—H3C | 108.5 | N8—C10—H10B | 108.9 |
Cu1—N3—H3C | 108.5 | C9—C10—H10B | 108.9 |
C7—N4—Cu1 | 171.9 (3) | H10A—C10—H10B | 107.7 |
C8—N5—C7 | 120.2 (4) | N8—C11—C12 | 111.8 (3) |
C8—N6—Cu2 | 165.1 (3) | N8—C11—H11A | 109.3 |
C9—N7—C14 | 116.2 (4) | C12—C11—H11A | 109.3 |
C9—N7—Cu2 | 104.3 (3) | N8—C11—H11B | 109.3 |
C14—N7—Cu2 | 107.3 (2) | C12—C11—H11B | 109.3 |
C9—N7—H7A | 109.6 | H11A—C11—H11B | 107.9 |
C14—N7—H7A | 109.6 | N9—C12—C11 | 110.5 (3) |
Cu2—N7—H7A | 109.6 | N9—C12—H12A | 109.6 |
C11—N8—C10 | 113.4 (3) | C11—C12—H12A | 109.6 |
C11—N8—Cu2 | 104.0 (2) | N9—C12—H12B | 109.6 |
C10—N8—Cu2 | 110.8 (3) | C11—C12—H12B | 109.6 |
C11—N8—H8A | 109.5 | H12A—C12—H12B | 108.1 |
C10—N8—H8A | 109.5 | N9—C13—C14 | 111.0 (3) |
Cu2—N8—H8A | 109.5 | N9—C13—H13A | 109.4 |
C13—N9—C12 | 114.2 (3) | C14—C13—H13A | 109.4 |
C13—N9—Cu2 | 105.2 (2) | N9—C13—H13B | 109.4 |
C12—N9—Cu2 | 112.9 (2) | C14—C13—H13B | 109.4 |
C13—N9—H9C | 108.1 | H13A—C13—H13B | 108.0 |
C12—N9—H9C | 108.1 | N7—C14—C13 | 111.0 (4) |
Cu2—N9—H9C | 108.1 | N7—C14—H14A | 109.4 |
N1—C1—C2 | 111.5 (4) | C13—C14—H14A | 109.4 |
N1—C1—H1A | 109.3 | N7—C14—H14B | 109.4 |
C2—C1—H1A | 109.3 | C13—C14—H14B | 109.4 |
N1—C1—H1B | 109.3 | H14A—C14—H14B | 108.0 |
C2—C1—H1B | 109.3 | O2—Cl3—O1 | 110.6 (3) |
H1A—C1—H1B | 108.0 | O2—Cl3—O3 | 109.1 (3) |
C1—C2—N2 | 113.1 (4) | O1—Cl3—O3 | 107.2 (2) |
C1—C2—H2A | 109.0 | O2—Cl3—O4 | 111.6 (3) |
N2—C2—H2A | 109.0 | O1—Cl3—O4 | 110.3 (2) |
C1—C2—H2B | 109.0 | O3—Cl3—O4 | 107.8 (2) |
N2—C2—H2B | 109.0 | ||
N4—Cu1—N1—C1 | 142.6 (6) | N9—Cu2—N8—C10 | 92.9 (3) |
N3—Cu1—N1—C1 | 90.5 (3) | N7—Cu2—N8—C10 | 9.9 (3) |
N2—Cu1—N1—C1 | 8.1 (3) | Cl2—Cu2—N8—C10 | 174.4 (2) |
Cl1—Cu1—N1—C1 | −100.4 (3) | N6—Cu2—N9—C13 | −78.8 (18) |
N4—Cu1—N1—C6 | 18.4 (8) | N8—Cu2—N9—C13 | −115.8 (3) |
N3—Cu1—N1—C6 | −33.7 (3) | N7—Cu2—N9—C13 | −33.3 (2) |
N2—Cu1—N1—C6 | −116.2 (3) | Cl2—Cu2—N9—C13 | 96.0 (2) |
Cl1—Cu1—N1—C6 | 135.4 (3) | N6—Cu2—N9—C12 | 46.3 (19) |
N4—Cu1—N2—C3 | −82.1 (3) | N8—Cu2—N9—C12 | 9.3 (3) |
N1—Cu1—N2—C3 | 89.4 (3) | N7—Cu2—N9—C12 | 91.8 (3) |
N3—Cu1—N2—C3 | 6.1 (3) | Cl2—Cu2—N9—C12 | −138.9 (3) |
Cl1—Cu1—N2—C3 | 178.1 (3) | C6—N1—C1—C2 | 135.6 (4) |
N4—Cu1—N2—C2 | 159.9 (2) | Cu1—N1—C1—C2 | 16.0 (5) |
N1—Cu1—N2—C2 | −28.6 (2) | N1—C1—C2—N2 | −45.4 (6) |
N3—Cu1—N2—C2 | −111.9 (3) | C3—N2—C2—C1 | −67.6 (5) |
Cl1—Cu1—N2—C2 | 60.1 (2) | Cu1—N2—C2—C1 | 46.6 (4) |
N4—Cu1—N3—C5 | −156.7 (3) | C2—N2—C3—C4 | 126.8 (4) |
N1—Cu1—N3—C5 | 14.2 (3) | Cu1—N2—C3—C4 | 18.2 (5) |
N2—Cu1—N3—C5 | 97.1 (3) | N2—C3—C4—N3 | −45.5 (6) |
Cl1—Cu1—N3—C5 | −45.7 (6) | C5—N3—C4—C3 | −72.9 (6) |
N4—Cu1—N3—C4 | 78.3 (3) | Cu1—N3—C4—C3 | 49.0 (5) |
N1—Cu1—N3—C4 | −110.8 (3) | C4—N3—C5—C6 | 130.0 (4) |
N2—Cu1—N3—C4 | −27.9 (3) | Cu1—N3—C5—C6 | 10.4 (5) |
Cl1—Cu1—N3—C4 | −170.7 (4) | N3—C5—C6—N1 | −40.2 (6) |
N1—Cu1—N4—C7 | −67 (3) | C1—N1—C6—C5 | −75.2 (5) |
N3—Cu1—N4—C7 | −15 (3) | Cu1—N1—C6—C5 | 50.0 (5) |
N2—Cu1—N4—C7 | 66 (3) | Cu1—N4—C7—N5 | 159 (4) |
Cl1—Cu1—N4—C7 | 176 (3) | C8—N5—C7—N4 | 164 (5) |
N9—Cu2—N6—C8 | −19 (3) | Cu2—N6—C8—N5 | −178 (100) |
N8—Cu2—N6—C8 | 17.4 (17) | C7—N5—C8—N6 | 174 (5) |
N7—Cu2—N6—C8 | −64.5 (17) | C14—N7—C9—C10 | −73.4 (5) |
Cl2—Cu2—N6—C8 | 165.8 (17) | Cu2—N7—C9—C10 | 44.5 (5) |
N6—Cu2—N7—C9 | 62.8 (3) | C11—N8—C10—C9 | 128.2 (4) |
N9—Cu2—N7—C9 | −113.5 (3) | Cu2—N8—C10—C9 | 11.6 (5) |
N8—Cu2—N7—C9 | −29.3 (3) | N7—C9—C10—N8 | −39.5 (6) |
Cl2—Cu2—N7—C9 | 161.3 (2) | C10—N8—C11—C12 | −75.4 (4) |
N6—Cu2—N7—C14 | −173.3 (3) | Cu2—N8—C11—C12 | 45.1 (4) |
N9—Cu2—N7—C14 | 10.3 (3) | C13—N9—C12—C11 | 133.2 (4) |
N8—Cu2—N7—C14 | 94.6 (3) | Cu2—N9—C12—C11 | 13.1 (4) |
Cl2—Cu2—N7—C14 | −74.8 (3) | N8—C11—C12—N9 | −40.0 (5) |
N6—Cu2—N8—C11 | 153.8 (3) | C12—N9—C13—C14 | −71.2 (5) |
N9—Cu2—N8—C11 | −29.3 (2) | Cu2—N9—C13—C14 | 53.2 (4) |
N7—Cu2—N8—C11 | −112.3 (3) | C9—N7—C14—C13 | 131.7 (4) |
Cl2—Cu2—N8—C11 | 52.2 (3) | Cu2—N7—C14—C13 | 15.5 (4) |
N6—Cu2—N8—C10 | −84.0 (3) | N9—C13—C14—N7 | −45.9 (5) |