Bis(2-amino­pyridine)(2,2′-bi­pyridine)­platinum(II) tetra­cyano­platinate(II) dihydrate

Sakai, K.; Mizota, M.; Akiyama, N.

doi:10.1107/S1600536803028332

Bis(2-aminopyridine)(2,2′-bipyridine)platinum(II) tetracyanoplatinate(II) dihydrate

In the title compound, [Pt(C₁₀H₈N₂)(C₅H₆N₂)₂][Pt(CN)₄]·2H₂O, cations and anions alternate along the a axis, giving a one-dimensional chain of the Magnus green salt type. The electrostatic interactions between the divalent cations and anions, together with the π–π stacking associations between the 2,2′-bipyridine moieties, contribute to the stabilization of the crystal packing. Two different Pt

Pt distances [5.2034 (6) and 4.5599 (6) Å] alternate along the one-dimensional stack.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803028332/ob6331sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536803028332/ob6331Isup2.hkl Contains datablock I

CCDC reference: 231829

checkCIF report

Key indicators

Single-crystal X-ray study
T = 296 K
Mean (C-C) = 0.018 Å
H-atom completeness 84%
R factor = 0.047
wR factor = 0.131
Data-to-parameter ratio = 14.3

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) .......         O1

Author Response: Hydrogen atoms of water molecules are generally hard to be located when a heavy atom is involved.

PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) .......         O2

Author Response: Hydrogen atoms of water molecules are generally hard to be located when a heavy atom is involved.


Alert level B
PLAT430_ALERT_2_B Short Inter D...A Contact  O1     ..  O2       =       2.77 Ang.
PLAT430_ALERT_2_B Short Inter D...A Contact  O1     ..  N8       =       2.81 Ang.

Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)...          ?
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         18
PLAT420_ALERT_2_C D-H Without Acceptor       N6     -   H6A    ...          ?
PLAT430_ALERT_2_C Short Inter D...A Contact  O2     ..  N9       =       2.90 Ang.

Alert level G
FORMU01_ALERT_2_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and the formula from the _atom_site* data.
            Atom count from _chemical_formula_sum:C24 H24 N10 O2 Pt2
            Atom count from the _atom_site data:  C24 H20 N10 O2 Pt2
CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected.
CELLZ01_ALERT_1_G WARNING: H atoms missing from atom site list. Is this intentional?
           From the CIF: _cell_formula_units_Z    2
           From the CIF: _chemical_formula_sum  C24 H24 N10 O2 Pt2
           TEST: Compare cell contents of formula and atom_site data

           atom    Z*formula  cif sites diff
           C         48.00     48.00    0.00
           H         48.00     40.00    8.00
           N         20.00     20.00    0.00
           O          4.00      4.00    0.00
           Pt         4.00      4.00    0.00

   2 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
   6 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

   5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   7 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: KENX (Sakai, 2002) and ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97, TEXSAN (Molecular Structure Corporation, 2001) and KENX.

Bis(2-aminopyridine)(2,2'-bipyridine)platinum(II) tetracyanoplatinate(II) dihydrate top

Crystal data top

[Pt(C₁₀H₈N₂)(C₅H₆N₂)₂][Pt(CN)₄]·2H₂O	Z = 2
M_r = 874.71	F(000) = 820
Triclinic, P1	? # Insert any comments here.
Hall symbol: -P 1	D_x = 2.121 Mg m⁻³
a = 7.2972 (5) Å	Mo Kα radiation, λ = 0.71073 Å
b = 12.7313 (8) Å	Cell parameters from 4752 reflections
c = 15.7612 (10) Å	θ = 2.4–25.4°
α = 98.266 (1)°	µ = 10.25 mm⁻¹
β = 98.963 (1)°	T = 296 K
γ = 105.187 (1)°	Needle, colorless
V = 1369.45 (15) Å³	0.32 × 0.07 × 0.07 mm

Data collection top

Bruker SMART APEX CCD-detector diffractometer	4918 independent reflections
Radiation source: fine-focus sealed tube	4030 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.082
Detector resolution: 8.366 pixels mm^-1	θ_max = 25.4°, θ_min = 2.4°
ω scans	h = −8→8
Absorption correction: gaussian (XPREP in SAINT; Bruker, 2001)	k = −15→15
T_min = 0.215, T_max = 0.604	l = −17→18
7239 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.047	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.131	H-atom parameters constrained
S = 1.10	w = 1/[σ²(F_o²) + (0.064P)² + 0.5602P] where P = (F_o² + 2F_c²)/3
4918 reflections	(Δ/σ)_max < 0.001
343 parameters	Δρ_max = 4.09 e Å⁻³
6 restraints	Δρ_min = −3.13 e Å⁻³

Special details top

Experimental. The first 50 frames were rescanned at the end of data collection to evaluate any possible decay phenomenon. Since it was judged to be negligible, no decay correction was applied to the data.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Mean-plane data from final SHELXL refinement run:-

Least-squares planes (x,y,z in crystal coordinates) and deviations from them (* indicates atom used to define plane)

7.0817 (0.0080) x - 1.0417 (0.0562) y - 5.3976 (0.0695) z = 2.9192 (0.0257)

* 0.0399 (0.0060) C21 * -0.0417 (0.0063) C22 * 0.0395 (0.0059) C23 * -0.0376 (0.0056) C24 0.0222 (0.0059) Pt2 - 3.2214 (0.0192) Pt1

Rms deviation of fitted atoms = 0.0397

7.0572 (0.0062) x - 0.6006 (0.0408) y - 0.9101 (0.0479) z = 0.9122 (0.0164)

Angle to previous plane (with approximate e.s.d.) = 17.38 (0.23)

* -0.0164 (0.0044) N1 * 0.0165 (0.0044) N2 * -0.0152 (0.0040) N3 * 0.0151 (0.0040) N5 - 0.0260 (0.0041) Pt1 3.4091 (0.0125) Pt2

Rms deviation of fitted atoms = 0.0158

- 1.9817 (0.0244) x + 12.2003 (0.0156) y - 6.4575 (0.0592) z = 1.8647 (0.0071)

Angle to previous plane (with approximate e.s.d.) = 83.94 (0.27)

* -0.0035 (0.0075) N5 * -0.0115 (0.0074) N6 * 0.0076 (0.0098) C16 * 0.0206 (0.0097) C17 * -0.0188 (0.0097) C18 * -0.0007 (0.0104) C19 * 0.0063 (0.0083) C20

Rms deviation of fitted atoms = 0.0121

- 2.4108 (0.0238) x + 5.3588 (0.0540) y + 13.1769 (0.0393) z = 4.4341 (0.0241)

Angle to previous plane (with approximate e.s.d.) = 80.91 (0.32)

* 0.0015 (0.0074) N3 * 0.0056 (0.0070) N4 * -0.0174 (0.0096) C11 * 0.0152 (0.0107) C12 * -0.0137 (0.0104) C13 * 0.0082 (0.0103) C14 * 0.0005 (0.0080) C15

Rms deviation of fitted atoms = 0.0108

7.0572 (0.0062) x - 0.6006 (0.0408) y - 0.9101 (0.0479) z = 0.9122 (0.0164)

Angle to previous plane (with approximate e.s.d.) = 82.86 (0.26)

* -0.0164 (0.0044) N1 * 0.0165 (0.0044) N2 * -0.0152 (0.0040) N3 * 0.0151 (0.0040) N5 - 0.0260 (0.0041) Pt1 3.4091 (0.0125) Pt2

Rms deviation of fitted atoms = 0.0158

7.0696 (0.0027) x - 0.2978 (0.0231) y - 2.0835 (0.0480) z = 0.5828 (0.0155)

Angle to previous plane (with approximate e.s.d.) = 4.35 (0.19)

* 0.0295 (0.0073) N1 * 0.0425 (0.0078) N2 * -0.0228 (0.0087) C1 * -0.0560 (0.0099) C2 * -0.0181 (0.0097) C3 * 0.0138 (0.0094) C4 * 0.0438 (0.0096) C5 * 0.0513 (0.0090) C6 * 0.0260 (0.0101) C7 * -0.0287 (0.0101) C8 * -0.0569 (0.0102) C9 * -0.0245 (0.0091) C10

Rms deviation of fitted atoms = 0.0374

7.1269 (0.0068) x - 0.6937 (0.0531) y - 2.2474 (0.0730) z = 0.4969 (0.0246)

Angle to previous plane (with approximate e.s.d.) = 1.99 (0.21)

* 0.0052 (0.0066) N1 * -0.0009 (0.0074) C1 * -0.0069 (0.0083) C2 * 0.0102 (0.0084) C3 * -0.0059 (0.0077) C4 * -0.0017 (0.0071) C5

Rms deviation of fitted atoms = 0.0060

6.9903 (0.0093) x + 0.1778 (0.0561) y - 1.9012 (0.0686) z = 0.8498 (0.0342)

Angle to previous plane (with approximate e.s.d.) = 4.35 (0.31)

* 0.0077 (0.0067) N2 * -0.0061 (0.0071) C6 * 0.0007 (0.0083) C7 * 0.0031 (0.0087) C8 * -0.0015 (0.0085) C9 * -0.0038 (0.0080) C10

Rms deviation of fitted atoms = 0.0045

7.0572 (0.0062) x - 0.6006 (0.0408) y - 0.9101 (0.0479) z = 0.9122 (0.0164)

Angle to previous plane (with approximate e.s.d.) = 4.71 (0.29)

* -0.0164 (0.0044) N1 * 0.0165 (0.0044) N2 * -0.0152 (0.0040) N3 * 0.0151 (0.0040) N5 - 0.0260 (0.0041) Pt1 3.4091 (0.0125) Pt2

Rms deviation of fitted atoms = 0.0158

7.1269 (0.0068) x - 0.6937 (0.0531) y - 2.2474 (0.0730) z = 0.4969 (0.0246)

Angle to previous plane (with approximate e.s.d.) = 5.02 (1/4)

* 0.0052 (0.0066) N1 * -0.0009 (0.0074) C1 * -0.0069 (0.0083) C2 * 0.0102 (0.0084) C3 * -0.0059 (0.0077) C4 * -0.0017 (0.0071) C5

Rms deviation of fitted atoms = 0.0060

- 1.9817 (0.0244) x + 12.2003 (0.0156) y - 6.4575 (0.0592) z = 1.8647 (0.0071)

Angle to previous plane (with approximate e.s.d.) = 84.95 (0.31)

* -0.0035 (0.0075) N5 * -0.0115 (0.0074) N6 * 0.0076 (0.0098) C16 * 0.0206 (0.0097) C17 * -0.0188 (0.0097) C18 * -0.0007 (0.0104) C19 * 0.0063 (0.0083) C20

Rms deviation of fitted atoms = 0.0121

7.0696 (0.0027) x - 0.2978 (0.0231) y - 2.0835 (0.0480) z = 0.5828 (0.0155)

Angle to previous plane (with approximate e.s.d.) = 86.41 (0.22)

Rms deviation of fitted atoms = 0.0374

- 2.4108 (0.0238) x + 5.3588 (0.0540) y + 13.1769 (0.0393) z = 4.4341 (0.0241)

Angle to previous plane (with approximate e.s.d.) = 79.69 (0.26)

* 0.0015 (0.0074) N3 * 0.0056 (0.0070) N4 * -0.0174 (0.0096) C11 * 0.0152 (0.0107) C12 * -0.0137 (0.0104) C13 * 0.0082 (0.0103) C14 * 0.0005 (0.0080) C15

Rms deviation of fitted atoms = 0.0108

6.9915 (0.0185) x + 0.1803 (0.0967) y - 1.9451 (0.1188) z = 0.8299 (0.0838)

Angle to previous plane (with approximate e.s.d.) = 81.36 (0.47)

* -0.0005 (0.0040) C7 * 0.0009 (0.0079) C8 * -0.0009 (0.0079) C9 * 0.0005 (0.0041) C10 3.5673 (0.0120) C7_$16 3.5659 (0.0139) C8_$16 3.5677 (0.0137) C9_$16 3.5663 (0.0119) C10_$16

Rms deviation of fitted atoms = 0.0007

7.1281 (0.0085) x - 0.7029 (0.0640) y - 2.2521 (0.0777) z = 0.4952 (0.0264)

Angle to previous plane (with approximate e.s.d.) = 4.34 (0.49)

* 0.0041 (0.0053) N1 * -0.0009 (0.0074) C1 * -0.0063 (0.0079) C2 * 0.0102 (0.0084) C3 * -0.0070 (0.0057) C4 3.4613 (0.0150) C21 3.4578 (0.0071) Pt2 3.8080 (0.0141) C22

Rms deviation of fitted atoms = 0.0065

7.1267 (0.0071) x - 0.6937 (0.0531) y - 2.2407 (0.0888) z = 0.4994 (0.0313)

Angle to previous plane (with approximate e.s.d.) = 0.06 (0.29)

* 0.0046 (0.0053) N1 * -0.0075 (0.0060) C2 * 0.0102 (0.0084) C3 * -0.0056 (0.0074) C4 * -0.0017 (0.0071) C5 - 3.6698 (0.0051) Pt2_$2 - 3.3177 (0.0153) C22_$2 - 3.6189 (0.0141) C23_$2

Rms deviation of fitted atoms = 0.0066

7.1290 (0.0053) x - 1.0638 (0.0466) y - 4.7226 (0.0515) z = 3.1801 (0.0198)

Angle to previous plane (with approximate e.s.d.) = 9.81 (0.23)

* -0.0050 (0.0046) Pt2 * -0.0044 (0.0096) C21 * 0.0030 (0.0061) N7 * 0.0172 (0.0099) C22 * -0.0107 (0.0062) N8 - 3.4660 (0.0103) N1 - 3.3323 (0.0133) C1 - 3.4115 (0.0133) C2 - 3.6213 (0.0129) C3 - 3.7867 (0.0115) C4 - 3.7014 (0.0115) C5

Rms deviation of fitted atoms = 0.0096

7.1269 (0.0068) x - 0.6937 (0.0531) y - 2.2474 (0.0730) z = 0.4969 (0.0246)

Angle to previous plane (with approximate e.s.d.) = 9.79 (0.22)

* 0.0052 (0.0066) N1 * -0.0009 (0.0074) C1 * -0.0069 (0.0083) C2 * 0.0102 (0.0084) C3 * -0.0059 (0.0077) C4 * -0.0017 (0.0071) C5 3.4575 (0.0069) Pt2 3.4623 (0.0146) C21 3.4711 (0.0163) N7 3.8088 (0.0137) C22 3.9798 (0.0169) N8

Rms deviation of fitted atoms = 0.0060

7.1290 (0.0053) x - 1.0638 (0.0466) y - 4.7226 (0.0515) z = 3.1801 (0.0198)

Angle to previous plane (with approximate e.s.d.) = 9.79 (0.22)

* -0.0050 (0.0046) Pt2 * -0.0044 (0.0096) C21 * 0.0030 (0.0061) N7 * 0.0172 (0.0099) C22 * -0.0107 (0.0062) N8 3.6631 (0.0085) N1_$3 3.7968 (0.0123) C1_$3 3.7175 (0.0148) C2_$3 3.5078 (0.0155) C3_$3 3.3423 (0.0130) C4_$3 3.4276 (0.0109) C5_$3

Rms deviation of fitted atoms = 0.0096

7.1269 (0.0068) x - 0.6937 (0.0531) y - 2.2474 (0.0730) z = 7.6238 (0.0227)

Angle to previous plane (with approximate e.s.d.) = 9.79 (0.22)

* 0.0052 (0.0066) N1_$3 * -0.0009 (0.0074) C1_$3 * -0.0069 (0.0083) C2_$3 * 0.0102 (0.0084) C3_$3 * -0.0059 (0.0077) C4_$3 * -0.0017 (0.0071) C5_$3 - 3.6694 (0.0044) Pt2 - 3.6646 (0.0175) C21 - 3.6558 (0.0197) N7 - 3.3181 (0.0149) C22 - 3.1471 (0.0189) N8

Rms deviation of fitted atoms = 0.0060

6.9915 (0.0185) x + 0.1803 (0.0969) y - 1.9451 (0.1188) z = 4.3967 (0.0865)

Angle to previous plane (with approximate e.s.d.) = 4.29 (0.47)

* 0.0005 (0.0040) C7_$16 * -0.0009 (0.0079) C8_$16 * 0.0009 (0.0079) C9_$16 * -0.0005 (0.0041) C10_$16 - 3.5673 (0.0120) C7 - 3.5659 (0.0138) C8 - 3.5677 (0.0136) C9 - 3.5663 (0.0119) C10

Rms deviation of fitted atoms = 0.0007

6.9915 (0.0185) x + 0.1803 (0.0967) y - 1.9451 (0.1188) z = 0.8299 (0.0838)

Angle to previous plane (with approximate e.s.d.) = 0.00 (2/3)

* -0.0005 (0.0040) C7 * 0.0009 (0.0079) C8 * -0.0009 (0.0079) C9 * 0.0005 (0.0041) C10 - 3.4242 (0.0235) C7_$17 - 3.4256 (0.0246) C8_$17 - 3.4238 (0.0242) C9_$17 - 3.4251 (0.0234) C10_$17

Rms deviation of fitted atoms = 0.0007

- 6.9915 (0.0185) x - 0.1803 (0.0969) y + 1.9451 (0.1188) z = 2.5947 (0.1036)

Angle to previous plane (with approximate e.s.d.) = 0.00 (2/3)

* -0.0005 (0.0040) C7_$17 * 0.0009 (0.0079) C8_$17 * -0.0009 (0.0079) C9_$17 * 0.0005 (0.0041) C10_$17 - 3.4242 (0.0235) C7 - 3.4256 (0.0246) C8 - 3.4238 (0.0242) C9 - 3.4251 (0.0235) C10

Rms deviation of fitted atoms = 0.0007

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pt1	0.18272 (5)	0.31570 (3)	0.23480 (2)	0.04305 (15)
Pt2	0.65850 (6)	0.08349 (3)	0.30291 (3)	0.05769 (16)
O1	0.2278 (14)	0.7275 (7)	0.3291 (6)	0.089 (3)
O2	0.8512 (15)	0.7097 (7)	0.2495 (7)	0.104 (3)
N1	0.1801 (11)	0.1840 (6)	0.2910 (5)	0.0441 (18)
N2	0.2108 (12)	0.3853 (6)	0.3602 (5)	0.0459 (19)
N3	0.1899 (13)	0.4556 (6)	0.1861 (5)	0.051 (2)
N4	0.5264 (15)	0.5195 (7)	0.2220 (7)	0.072 (3)
H4A	0.5286	0.4641	0.2470	0.087*
H4B	0.6331	0.5677	0.2209	0.087*
N5	0.1659 (14)	0.2381 (7)	0.1106 (6)	0.058 (2)
N6	−0.1594 (15)	0.1674 (9)	0.0782 (9)	0.090 (3)
H6A	−0.1591	0.1942	0.1316	0.108*
H6B	−0.2672	0.1317	0.0428	0.108*
N7	0.6731 (17)	0.3220 (8)	0.2696 (8)	0.077 (3)
N9	0.6581 (18)	−0.1526 (8)	0.3424 (8)	0.089 (3)
N10	0.467 (2)	−0.0311 (11)	0.1065 (8)	0.108 (5)
C1	0.1563 (16)	0.0809 (8)	0.2499 (7)	0.053 (3)
H1	0.1357	0.0666	0.1891	0.064*
C2	0.1605 (17)	−0.0049 (9)	0.2923 (9)	0.069 (3)
H2	0.1415	−0.0759	0.2611	0.082*
C3	0.1928 (17)	0.0156 (9)	0.3809 (8)	0.064 (3)
H3	0.2001	−0.0409	0.4116	0.077*
C4	0.2149 (16)	0.1217 (9)	0.4254 (8)	0.063 (3)
H4	0.2336	0.1363	0.4862	0.076*
C5	0.2093 (14)	0.2049 (8)	0.3802 (6)	0.049 (2)
C6	0.2265 (13)	0.3181 (8)	0.4188 (7)	0.047 (2)
C7	0.2504 (16)	0.3558 (9)	0.5065 (8)	0.063 (3)
H7	0.2627	0.3090	0.5458	0.076*
C8	0.2561 (18)	0.4655 (10)	0.5364 (7)	0.069 (3)
H8	0.2723	0.4923	0.5960	0.082*
C9	0.2374 (18)	0.5348 (9)	0.4767 (8)	0.067 (3)
H9	0.2404	0.6080	0.4955	0.080*
C10	0.2144 (16)	0.4915 (9)	0.3893 (7)	0.060 (3)
H10	0.2008	0.5367	0.3487	0.072*
C11	0.3589 (18)	0.5307 (8)	0.1850 (7)	0.057 (3)
C12	0.355 (2)	0.6252 (10)	0.1484 (9)	0.079 (4)
H12	0.4700	0.6796	0.1505	0.095*
C13	0.188 (3)	0.6360 (12)	0.1112 (9)	0.093 (5)
H13	0.1868	0.6960	0.0839	0.112*
C14	0.014 (2)	0.5603 (12)	0.1119 (8)	0.082 (4)
H14	−0.1030	0.5704	0.0878	0.098*
C15	0.0192 (19)	0.4716 (10)	0.1483 (7)	0.067 (3)
H15	−0.0972	0.4193	0.1478	0.080*
C16	0.0039 (19)	0.1811 (9)	0.0509 (8)	0.065 (3)
C17	0.010 (2)	0.1377 (10)	−0.0351 (8)	0.074 (4)
H17	−0.1035	0.1006	−0.0756	0.089*
C18	0.183 (2)	0.1501 (12)	−0.0583 (9)	0.084 (4)
H18	0.1871	0.1178	−0.1144	0.101*
C19	0.355 (2)	0.2104 (12)	−0.0002 (9)	0.089 (4)
H19	0.4740	0.2211	−0.0174	0.107*
C20	0.345 (2)	0.2524 (10)	0.0813 (8)	0.069 (3)
H20	0.4590	0.2927	0.1205	0.083*
C21	0.6674 (17)	0.2360 (11)	0.2818 (8)	0.063 (3)
C23	0.6596 (18)	−0.0664 (10)	0.3301 (9)	0.068 (3)
C24	0.541 (2)	0.0123 (11)	0.1742 (10)	0.081 (4)
C22	0.7531 (17)	0.1500 (9)	0.4260 (9)	0.060 (3)
N8	0.8046 (17)	0.1923 (8)	0.5001 (8)	0.079 (3)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.0500 (3)	0.0386 (2)	0.0424 (2)	0.01491 (16)	0.01062 (16)	0.00847 (16)
Pt2	0.0522 (3)	0.0573 (3)	0.0697 (3)	0.0203 (2)	0.0200 (2)	0.0156 (2)
O1	0.114 (7)	0.074 (5)	0.074 (6)	0.028 (5)	0.017 (6)	−0.001 (5)
O2	0.093 (7)	0.075 (6)	0.137 (9)	0.019 (5)	0.035 (7)	−0.010 (6)
N1	0.039 (4)	0.038 (4)	0.057 (5)	0.013 (3)	0.013 (4)	0.010 (4)
N2	0.054 (5)	0.048 (4)	0.036 (4)	0.019 (4)	0.011 (4)	0.003 (4)
N3	0.076 (6)	0.041 (4)	0.043 (5)	0.026 (4)	0.013 (4)	0.013 (4)
N4	0.078 (7)	0.058 (5)	0.090 (8)	0.026 (5)	0.023 (6)	0.028 (5)
N5	0.069 (6)	0.048 (5)	0.052 (5)	0.020 (4)	−0.010 (5)	0.007 (4)
N6	0.066 (7)	0.081 (7)	0.112 (10)	0.010 (6)	0.027 (7)	0.002 (7)
N7	0.095 (8)	0.062 (6)	0.076 (7)	0.026 (6)	0.006 (6)	0.027 (5)
N9	0.111 (9)	0.053 (6)	0.109 (9)	0.036 (6)	0.028 (8)	0.011 (6)
N10	0.116 (11)	0.125 (11)	0.054 (7)	0.000 (9)	0.007 (7)	0.000 (7)
C1	0.067 (7)	0.040 (5)	0.054 (6)	0.019 (5)	0.011 (5)	0.007 (5)
C2	0.074 (8)	0.046 (6)	0.094 (10)	0.020 (6)	0.029 (7)	0.020 (6)
C3	0.074 (8)	0.052 (6)	0.073 (8)	0.019 (6)	0.017 (6)	0.031 (6)
C4	0.075 (8)	0.066 (7)	0.069 (7)	0.031 (6)	0.031 (6)	0.035 (6)
C5	0.058 (6)	0.049 (5)	0.046 (6)	0.020 (5)	0.015 (5)	0.017 (5)
C6	0.043 (5)	0.049 (5)	0.050 (6)	0.010 (4)	0.013 (4)	0.010 (5)
C7	0.071 (8)	0.073 (7)	0.056 (7)	0.026 (6)	0.021 (6)	0.027 (6)
C8	0.078 (8)	0.082 (8)	0.039 (6)	0.020 (7)	0.014 (6)	−0.004 (6)
C9	0.093 (9)	0.049 (6)	0.062 (7)	0.027 (6)	0.031 (7)	−0.005 (5)
C10	0.072 (7)	0.062 (6)	0.055 (7)	0.030 (6)	0.018 (6)	0.017 (5)
C11	0.080 (8)	0.041 (5)	0.053 (6)	0.021 (5)	0.019 (6)	0.013 (5)
C12	0.106 (11)	0.057 (7)	0.080 (9)	0.023 (7)	0.019 (8)	0.033 (7)
C13	0.148 (15)	0.085 (10)	0.069 (9)	0.067 (11)	0.014 (10)	0.037 (8)
C14	0.104 (11)	0.099 (10)	0.060 (8)	0.064 (9)	0.004 (8)	0.019 (8)
C15	0.092 (9)	0.070 (7)	0.047 (6)	0.043 (7)	0.010 (6)	0.010 (6)
C16	0.078 (8)	0.057 (6)	0.068 (8)	0.025 (6)	0.020 (7)	0.021 (6)
C17	0.107 (11)	0.072 (7)	0.045 (6)	0.043 (7)	0.004 (7)	−0.005 (6)
C18	0.105 (12)	0.096 (10)	0.062 (8)	0.047 (9)	0.012 (8)	0.020 (8)
C19	0.086 (10)	0.104 (10)	0.086 (10)	0.031 (9)	0.040 (9)	0.017 (9)
C20	0.094 (9)	0.073 (7)	0.055 (7)	0.037 (7)	0.033 (7)	0.017 (6)
C21	0.060 (7)	0.081 (8)	0.059 (7)	0.033 (6)	0.008 (6)	0.022 (6)
C23	0.065 (7)	0.068 (7)	0.074 (8)	0.025 (6)	0.021 (6)	0.012 (6)
C24	0.071 (9)	0.077 (8)	0.087 (10)	0.005 (7)	0.025 (8)	0.010 (8)
C22	0.066 (6)	0.047 (5)	0.076 (7)	0.024 (4)	0.016 (5)	0.023 (5)
N8	0.104 (9)	0.054 (6)	0.077 (8)	0.019 (6)	0.015 (7)	0.012 (5)

Geometric parameters (Å, º) top

Pt1—N1	2.002 (7)	C8—C9	1.394 (16)
Pt1—N2	2.003 (8)	C9—C10	1.375 (15)
Pt1—N3	2.030 (7)	C11—C12	1.411 (14)
Pt1—N5	2.032 (9)	C12—C13	1.320 (19)
Pt2—C22	1.940 (13)	C13—C14	1.38 (2)
Pt2—C21	2.003 (12)	C14—C15	1.344 (16)
Pt2—C23	2.016 (13)	C16—C17	1.401 (17)
Pt2—C24	2.048 (16)	C17—C18	1.338 (19)
Pt1—Pt2	5.2034 (6)	C18—C19	1.396 (19)
Pt1—Pt2ⁱ	4.5599 (6)	C19—C20	1.340 (16)
Pt2—Pt1ⁱⁱ	4.5599 (6)	C22—N8	1.171 (15)
N1—C1	1.332 (12)	N4—H4A	0.8600
N1—C5	1.365 (12)	N4—H4B	0.8600
N2—C10	1.356 (12)	N6—H6A	0.8600
N2—C6	1.357 (12)	N6—H6B	0.8600
N3—C11	1.353 (14)	C1—H1	0.9300
N3—C15	1.373 (14)	C2—H2	0.9300
N4—C11	1.322 (14)	C3—H3	0.9300
N5—C16	1.348 (15)	C4—H4	0.9300
N5—C20	1.427 (15)	C7—H7	0.9300
N6—C16	1.307 (16)	C8—H8	0.9300
N7—C21	1.130 (14)	C9—H9	0.9300
N9—C23	1.139 (15)	C10—H10	0.9300
N10—C24	1.109 (17)	C12—H12	0.9300
C1—C2	1.365 (14)	C13—H13	0.9300
C2—C3	1.354 (17)	C14—H14	0.9300
C3—C4	1.386 (15)	C15—H15	0.9300
C4—C5	1.364 (13)	C17—H17	0.9300
C5—C6	1.447 (13)	C18—H18	0.9300
C6—C7	1.365 (15)	C19—H19	0.9300
C7—C8	1.396 (16)	C20—H20	0.9300

O1···O2ⁱ	2.774 (14)	O1···N9^iv	3.071 (16)
O1···N8ⁱⁱⁱ	2.807 (15)	O2···N9^iv	2.899 (14)

N1—Pt1—N2	80.0 (3)	C13—C12—C11	119.7 (13)
N1—Pt1—N3	176.1 (3)	C12—C13—C14	121.5 (12)
N2—Pt1—N3	96.2 (3)	C15—C14—C13	118.3 (13)
N1—Pt1—N5	96.6 (3)	C14—C15—N3	122.3 (13)
N2—Pt1—N5	175.9 (3)	N6—C16—N5	116.1 (12)
N3—Pt1—N5	87.2 (3)	N6—C16—C17	121.9 (14)
C22—Pt2—C21	87.1 (4)	N5—C16—C17	121.9 (12)
C22—Pt2—C23	90.1 (5)	C18—C17—C16	119.3 (14)
C21—Pt2—C23	177.0 (5)	C17—C18—C19	121.5 (14)
C22—Pt2—C24	176.4 (5)	C20—C19—C18	117.9 (14)
C21—Pt2—C24	92.7 (5)	C19—C20—N5	123.0 (13)
C23—Pt2—C24	90.2 (5)	N7—C21—Pt2	179.6 (13)
C1—N1—C5	118.2 (8)	N9—C23—Pt2	177.6 (13)
C1—N1—Pt1	126.4 (7)	N10—C24—Pt2	174.8 (14)
C5—N1—Pt1	115.4 (6)	N8—C22—Pt2	177.3 (11)
C10—N2—C6	119.3 (8)	N1—C1—H1	118.3
C10—N2—Pt1	125.2 (7)	C2—C1—H1	118.3
C6—N2—Pt1	115.5 (6)	C3—C2—H2	120.7
C11—N3—C15	118.6 (9)	C1—C2—H2	120.7
C11—N3—Pt1	121.9 (7)	C2—C3—H3	120.4
C15—N3—Pt1	119.3 (8)	C4—C3—H3	120.4
C16—N5—C20	116.3 (10)	C5—C4—H4	120.0
C16—N5—Pt1	127.3 (8)	C3—C4—H4	120.0
C20—N5—Pt1	116.3 (7)	C6—C7—H7	120.4
N1—C1—C2	123.5 (11)	C8—C7—H7	120.4
C3—C2—C1	118.6 (11)	C9—C8—H8	120.1
C2—C3—C4	119.2 (10)	C7—C8—H8	120.1
C5—C4—C3	120.1 (11)	C10—C9—H9	121.0
C4—C5—N1	120.4 (9)	C8—C9—H9	121.0
C4—C5—C6	125.3 (10)	N2—C10—H10	118.9
N1—C5—C6	114.3 (8)	C9—C10—H10	118.9
N2—C6—C7	121.5 (9)	C13—C12—H12	120.1
N2—C6—C5	114.7 (8)	C11—C12—H12	120.1
C7—C6—C5	123.9 (9)	C12—C13—H13	119.3
C6—C7—C8	119.2 (10)	C14—C13—H13	119.3
C9—C8—C7	119.8 (10)	C15—C14—H14	120.8
C11—N4—H4A	120.0	C13—C14—H14	120.8
C11—N4—H4B	120.0	C14—C15—H15	118.9
H4A—N4—H4B	120.0	N3—C15—H15	118.9
C16—N6—H6A	120.0	C18—C17—H17	120.3
C16—N6—H6B	120.0	C16—C17—H17	120.3
H6A—N6—H6B	120.0	C17—C18—H18	119.2
C10—C9—C8	118.0 (10)	C19—C18—H18	119.2
N2—C10—C9	122.3 (10)	C20—C19—H19	121.1
N4—C11—N3	120.6 (9)	C18—C19—H19	121.1
N4—C11—C12	119.8 (11)	C19—C20—H20	118.5
N3—C11—C12	119.4 (11)	N5—C20—H20	118.5

C5—N1—C1—C2	−0.3 (16)	C7—C8—C9—C10	−0.2 (19)
N7—N1—C1—C2	105.3 (11)	C6—N2—C10—C9	1.4 (16)
N1—C1—C2—C3	−0.8 (18)	C8—C9—C10—N2	−0.5 (18)
C1—C2—C3—C4	1.8 (18)	C15—N3—C11—N4	178.9 (10)
C2—C3—C4—C5	−1.8 (18)	C15—N3—C11—C12	2.5 (16)
C1—N1—C5—C4	0.4 (15)	N4—C11—C12—C13	179.7 (13)
N7—N1—C5—C4	−107.0 (9)	N3—C11—C12—C13	−4 (2)
C1—N1—C5—C6	−177.8 (9)	C11—C12—C13—C14	4 (2)
N7—N1—C5—C6	74.8 (8)	C12—C13—C14—C15	−3 (2)
C3—C4—C5—N1	0.6 (16)	C13—C14—C15—N3	1 (2)
C3—C4—C5—C6	178.7 (10)	C11—N3—C15—C14	−1.4 (17)
C10—N2—C6—C7	−1.6 (15)	C20—N5—C16—N6	179.5 (10)
C10—N2—C6—C5	176.5 (9)	C20—N5—C16—C17	0.3 (15)
N1—C5—C6—N2	0.0 (13)	N6—C16—C17—C18	−177.1 (12)
C4—C5—C6—N2	−178.1 (9)	N5—C16—C17—C18	2.0 (18)
N1—C5—C6—C7	178.0 (10)	C16—C17—C18—C19	−3 (2)
C4—C5—C6—C7	−0.1 (17)	C17—C18—C19—C20	2 (2)
N2—C6—C7—C8	0.9 (17)	C18—C19—C20—N5	0 (2)
C5—C6—C7—C8	−176.9 (10)	C16—N5—C20—C19	−1.3 (16)
C6—C7—C8—C9	0.0 (19)

Symmetry codes: (i) x−1, y, z; (ii) x+1, y, z; (iii) −x+1, −y+1, −z+1; (iv) x, y+1, z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N6—H6B···N10^v	0.86	2.53	3.316 (17)	153
N4—H4A···N7	0.86	2.36	3.121 (13)	147
N4—H4B···O2	0.86	2.01	2.835 (13)	161

Symmetry code: (v) −x, −y, −z.

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Bis(2-amino­pyridine)(2,2′-bi­pyridine)­platinum(II) tetra­cyano­platinate(II) dihydrate

Supporting information

Key indicators

checkCIF/PLATON results

Bis(2-aminopyridine)(2,2′-bipyridine)platinum(II) tetracyanoplatinate(II) dihydrate