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In the title compound, [Co4(C5HN2O4)4(C10H8N2)4]·16H2O, each 1-imidazole-4,5-dicarboxyl­ate trianion μ-bridges two Co(2,2′-bipyridine) units into a centrosymmetric tetra­nuclear mol­ecule. The two symmetry-independent Co atoms show a cis-octa­hedral coordination.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806040451/ob3024sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806040451/ob3024Isup2.hkl
Contains datablock I

CCDC reference: 293658

Key indicators

  • Single-crystal X-ray study
  • T = 295 K
  • Mean [sigma](C-C) = 0.008 Å
  • R factor = 0.054
  • wR factor = 0.169
  • Data-to-parameter ratio = 16.4

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT220_ALERT_2_B Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.62 Ratio PLAT415_ALERT_2_B Short Inter D-H..H-X H5 .. H3W1 .. 1.98 Ang. PLAT415_ALERT_2_B Short Inter D-H..H-X H5 .. H3W2 .. 2.02 Ang. PLAT420_ALERT_2_B D-H Without Acceptor O2W - H2W1 ... ? PLAT420_ALERT_2_B D-H Without Acceptor O3W - H3W1 ... ? PLAT420_ALERT_2_B D-H Without Acceptor O3W - H3W2 ... ? PLAT420_ALERT_2_B D-H Without Acceptor O4W - H4W1 ... ? PLAT420_ALERT_2_B D-H Without Acceptor O4W - H4W2 ... ?
Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT142_ALERT_4_C su on b - Axis Small or Missing (x 100000) ..... 10 Ang. PLAT143_ALERT_4_C su on c - Axis Small or Missing (x 100000) ..... 10 Ang. PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent ..... ? PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.64 Ratio PLAT230_ALERT_2_C Hirshfeld Test Diff for C12 - C13 .. 6.44 su PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C12 PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 8 PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 16 PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 4 H2 O PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 8 H2 O PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 9 H2 O
0 ALERT level A = In general: serious problem 8 ALERT level B = Potentially serious problem 12 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 10 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 6 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: SHELXL97.

Tetrakis[(2,2'-bipyridine-N,N')-µ2-(1H-imidazole- 4,5-dicarboxylato-N,O: N',O')cobalt(III)] hexadecahydrate top
Crystal data top
[Co4(C10H8N2)4(C5HN2O4)4](H2O)16Z = 1
Mr = 1761.02F(000) = 904
Triclinic, P1Dx = 1.591 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 11.7238 (2) ÅCell parameters from 7235 reflections
b = 13.5350 (1) Åθ = 1.7–27.5°
c = 13.6101 (1) ŵ = 0.99 mm1
α = 65.066 (2)°T = 295 K
β = 72.973 (2)°Prism, pink
γ = 73.131 (1)°0.30 × 0.24 × 0.16 mm
V = 1837.58 (4) Å3
Data collection top
Rigaku RAXIS-RAPID IP
diffractometer
8260 independent reflections
Radiation source: fine-focus sealed tube5161 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.042
ω scanθmax = 27.5°, θmin = 1.7°
Absorption correction: multi-scan
ABSCOR (Higashi, 1995)
h = 1415
Tmin = 0.760, Tmax = 0.858k = 1716
17172 measured reflectionsl = 1717
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.054Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.169H-atom parameters constrained
S = 0.96 w = 1/[σ2(Fo2) + (0.1042P)2]
where P = (Fo2 + 2Fc2)/3
8260 reflections(Δ/σ)max = 0.001
505 parametersΔρmax = 0.88 e Å3
64 restraintsΔρmin = 0.52 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Co10.63674 (5)0.16138 (4)0.65465 (4)0.03434 (17)
Co20.29860 (5)0.51697 (4)0.81241 (4)0.02874 (16)
O10.7709 (3)0.2116 (3)0.6600 (3)0.0471 (7)
O20.8186 (3)0.3446 (4)0.6877 (4)0.0797 (13)
O30.4363 (3)0.5449 (2)0.8376 (2)0.0392 (7)
O40.6379 (3)0.5112 (4)0.8003 (4)0.0926 (16)
O50.1981 (3)0.6357 (2)0.8578 (2)0.0379 (6)
O60.1329 (3)0.8183 (2)0.7981 (3)0.0528 (9)
O70.1423 (3)0.9854 (2)0.5445 (3)0.0562 (9)
O80.2531 (3)0.9519 (2)0.3940 (2)0.0460 (7)
O1W1.0706 (4)0.3174 (5)0.5841 (4)0.1142 (17)
H1W10.99400.34270.58140.137*
H1W21.10660.32500.51700.137*
O2W1.0162 (5)0.2017 (4)0.4818 (5)0.131 (2)
H2W10.95920.23110.44380.158*
H2W21.05890.14680.46240.158*
O3W1.1878 (4)0.2177 (5)0.7760 (5)0.1206 (19)
H3W11.25360.20980.72850.145*
H3W21.18550.27760.78520.145*
O4W0.2852 (6)0.4171 (6)0.4838 (5)0.174 (3)
H4W10.29610.45600.51740.208*
H4W20.33010.44080.41850.208*
O5W0.0294 (6)1.0212 (6)0.7420 (7)0.238 (4)
H5W10.00130.95320.74800.286*
H5W20.08751.04150.70650.286*
O6W0.0352 (10)1.0728 (13)0.8796 (8)0.400 (9)
H6W10.03511.11520.81060.480*
H6W20.10521.07160.88970.480*
O7W0.1557 (13)1.1541 (8)0.9952 (7)0.293 (6)
H7W10.15351.22110.94810.352*
H7W20.15471.15531.05750.352*
O8W0.3717 (7)1.2996 (5)1.0310 (5)0.159 (3)
H8W10.38411.32421.08400.191*
H8W20.39631.35650.97690.191*
N10.5399 (3)0.2796 (3)0.7016 (3)0.0307 (7)
N20.4155 (3)0.4064 (2)0.7643 (2)0.0282 (7)
N30.6305 (4)0.0521 (3)0.8029 (3)0.0522 (10)
N40.5016 (3)0.1063 (3)0.6562 (3)0.0413 (8)
N50.3193 (3)0.6311 (3)0.6689 (3)0.0325 (7)
N60.3436 (3)0.7489 (3)0.4978 (3)0.0318 (7)
N70.2576 (3)0.4154 (3)0.9624 (3)0.0330 (7)
N80.1567 (3)0.4858 (3)0.7949 (3)0.0336 (7)
C10.7429 (4)0.2985 (4)0.6864 (4)0.0472 (11)
C20.6095 (4)0.3346 (3)0.7184 (3)0.0368 (9)
C30.5320 (3)0.4122 (3)0.7588 (3)0.0353 (9)
C40.5418 (4)0.4950 (4)0.7991 (4)0.0452 (11)
C50.4236 (3)0.3257 (3)0.7286 (3)0.0276 (8)
H50.35750.30460.72340.033*
C60.7016 (6)0.0338 (5)0.8721 (4)0.0735 (17)
H60.75350.08250.85260.088*
C70.7004 (7)0.0539 (6)0.9705 (5)0.098 (3)
H70.75210.06651.01670.118*
C80.6220 (8)0.1221 (5)0.9991 (5)0.100 (3)
H80.61830.18091.06690.120*
C90.5468 (7)0.1062 (4)0.9293 (5)0.090 (2)
H90.49420.15390.94770.108*
C100.5546 (5)0.0164 (4)0.8317 (4)0.0621 (15)
C110.4782 (5)0.0150 (4)0.7484 (4)0.0597 (14)
C120.3865 (7)0.0380 (5)0.7563 (6)0.091 (2)
H120.36860.09980.81880.109*
C130.3249 (7)0.0003 (6)0.6739 (7)0.090 (2)
H130.26600.03580.67850.107*
C140.3495 (6)0.0919 (5)0.5843 (6)0.0758 (18)
H140.30600.12030.52780.091*
C150.4389 (5)0.1426 (4)0.5774 (5)0.0569 (13)
H150.45600.20470.51490.068*
C160.1881 (4)0.7344 (3)0.7801 (3)0.0374 (9)
C170.2521 (3)0.7325 (3)0.6690 (3)0.0311 (8)
C180.2665 (3)0.8054 (3)0.5620 (3)0.0316 (8)
C190.2150 (4)0.9230 (3)0.5002 (4)0.0395 (9)
C200.3734 (4)0.6442 (3)0.5637 (3)0.0316 (8)
H200.42450.58810.54040.038*
C210.3172 (4)0.3875 (4)1.0439 (4)0.0434 (10)
H210.38610.41641.02880.052*
C220.2775 (5)0.3157 (4)1.1510 (4)0.0550 (13)
H220.31930.29711.20680.066*
C230.1764 (5)0.2733 (4)1.1726 (4)0.0612 (14)
H230.14970.22421.24300.073*
C240.1138 (4)0.3040 (4)1.0886 (4)0.0501 (12)
H240.04480.27591.10190.060*
C250.1557 (4)0.3765 (3)0.9853 (3)0.0351 (9)
C260.0955 (4)0.4193 (3)0.8906 (3)0.0363 (9)
C270.0155 (4)0.3998 (4)0.8938 (4)0.0518 (12)
H270.05770.35620.96000.062*
C280.0637 (4)0.4442 (4)0.8001 (5)0.0561 (13)
H280.13790.43100.80160.067*
C290.0007 (4)0.5083 (4)0.7046 (4)0.0557 (13)
H290.02950.53870.63980.067*
C300.1092 (4)0.5284 (4)0.7032 (4)0.0437 (10)
H300.15120.57260.63720.052*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.0360 (3)0.0309 (3)0.0261 (3)0.0021 (2)0.0021 (2)0.0066 (2)
Co20.0299 (3)0.0299 (3)0.0244 (3)0.0099 (2)0.0008 (2)0.0094 (2)
O10.0332 (16)0.0578 (18)0.051 (2)0.0049 (14)0.0117 (14)0.0275 (15)
O20.0324 (18)0.118 (3)0.122 (4)0.011 (2)0.006 (2)0.082 (3)
O30.0386 (16)0.0447 (16)0.0408 (17)0.0136 (13)0.0032 (13)0.0212 (13)
O40.038 (2)0.141 (4)0.160 (5)0.022 (2)0.008 (2)0.117 (4)
O50.0440 (17)0.0361 (14)0.0282 (15)0.0114 (13)0.0069 (12)0.0137 (12)
O60.066 (2)0.0349 (15)0.0453 (19)0.0055 (15)0.0101 (16)0.0200 (14)
O70.065 (2)0.0395 (16)0.0445 (19)0.0079 (16)0.0008 (17)0.0166 (14)
O80.0512 (19)0.0329 (14)0.0355 (17)0.0046 (13)0.0010 (14)0.0085 (12)
O1W0.079 (3)0.143 (4)0.120 (4)0.018 (3)0.001 (3)0.062 (3)
O2W0.136 (4)0.070 (3)0.177 (5)0.003 (3)0.068 (4)0.026 (3)
O3W0.091 (3)0.137 (4)0.169 (5)0.011 (3)0.028 (3)0.095 (4)
O4W0.137 (5)0.160 (5)0.163 (6)0.030 (4)0.030 (5)0.002 (4)
O5W0.170 (6)0.239 (7)0.161 (6)0.113 (5)0.009 (5)0.054 (5)
O6W0.370 (12)0.411 (12)0.391 (12)0.062 (9)0.063 (9)0.139 (9)
O7W0.322 (10)0.292 (9)0.303 (10)0.114 (8)0.009 (8)0.143 (8)
O8W0.238 (7)0.115 (4)0.150 (5)0.044 (4)0.105 (5)0.023 (4)
N10.0318 (17)0.0333 (16)0.0248 (16)0.0069 (14)0.0040 (13)0.0093 (13)
N20.0269 (16)0.0296 (15)0.0257 (16)0.0079 (13)0.0024 (13)0.0083 (13)
N30.059 (3)0.041 (2)0.032 (2)0.0058 (19)0.0005 (19)0.0062 (16)
N40.045 (2)0.0341 (17)0.037 (2)0.0116 (16)0.0050 (17)0.0125 (15)
N50.0309 (17)0.0329 (16)0.0291 (18)0.0092 (14)0.0041 (14)0.0117 (14)
N60.0314 (17)0.0301 (16)0.0288 (17)0.0041 (14)0.0001 (14)0.0109 (13)
N70.0360 (18)0.0335 (17)0.0279 (17)0.0083 (14)0.0002 (14)0.0126 (13)
N80.0293 (17)0.0349 (17)0.0337 (18)0.0059 (14)0.0020 (14)0.0129 (14)
C10.029 (2)0.068 (3)0.048 (3)0.001 (2)0.0082 (19)0.030 (2)
C20.031 (2)0.048 (2)0.032 (2)0.0075 (19)0.0051 (17)0.0158 (18)
C30.029 (2)0.045 (2)0.035 (2)0.0076 (18)0.0059 (17)0.0180 (18)
C40.037 (2)0.058 (3)0.052 (3)0.011 (2)0.007 (2)0.032 (2)
C50.0296 (19)0.0282 (18)0.0205 (18)0.0056 (16)0.0029 (15)0.0060 (14)
C60.073 (4)0.078 (4)0.038 (3)0.017 (3)0.015 (3)0.009 (3)
C70.099 (6)0.097 (5)0.045 (4)0.032 (4)0.014 (4)0.009 (4)
C80.136 (7)0.058 (4)0.033 (3)0.035 (4)0.004 (4)0.004 (3)
C90.128 (6)0.035 (3)0.052 (4)0.003 (3)0.019 (4)0.000 (3)
C100.081 (4)0.034 (2)0.039 (3)0.002 (2)0.014 (3)0.009 (2)
C110.072 (3)0.037 (2)0.058 (3)0.024 (2)0.021 (3)0.020 (2)
C120.111 (6)0.060 (4)0.090 (5)0.055 (4)0.038 (4)0.030 (4)
C130.093 (5)0.099 (5)0.101 (6)0.061 (4)0.006 (4)0.048 (5)
C140.072 (4)0.090 (4)0.086 (5)0.042 (3)0.001 (3)0.044 (4)
C150.056 (3)0.061 (3)0.057 (3)0.021 (3)0.003 (3)0.025 (3)
C160.035 (2)0.038 (2)0.036 (2)0.0136 (18)0.0049 (17)0.0140 (18)
C170.0280 (19)0.0294 (18)0.031 (2)0.0075 (16)0.0017 (16)0.0107 (16)
C180.031 (2)0.0290 (18)0.028 (2)0.0061 (16)0.0003 (16)0.0081 (15)
C190.042 (2)0.035 (2)0.036 (2)0.0059 (19)0.0001 (19)0.0134 (18)
C200.035 (2)0.0263 (18)0.029 (2)0.0060 (16)0.0017 (16)0.0112 (15)
C210.052 (3)0.044 (2)0.035 (2)0.010 (2)0.012 (2)0.0133 (19)
C220.075 (4)0.054 (3)0.032 (2)0.013 (3)0.016 (2)0.008 (2)
C230.085 (4)0.054 (3)0.032 (3)0.026 (3)0.007 (3)0.008 (2)
C240.049 (3)0.055 (3)0.037 (3)0.021 (2)0.005 (2)0.009 (2)
C250.034 (2)0.037 (2)0.032 (2)0.0100 (18)0.0033 (17)0.0154 (17)
C260.033 (2)0.043 (2)0.034 (2)0.0120 (18)0.0034 (17)0.0191 (18)
C270.038 (2)0.066 (3)0.057 (3)0.026 (2)0.011 (2)0.031 (2)
C280.039 (3)0.075 (3)0.069 (4)0.013 (2)0.011 (2)0.039 (3)
C290.051 (3)0.068 (3)0.054 (3)0.009 (3)0.023 (2)0.021 (3)
C300.044 (3)0.049 (2)0.038 (2)0.011 (2)0.015 (2)0.0102 (19)
Geometric parameters (Å, º) top
Co1—O11.915 (3)N6—C181.366 (5)
Co1—O8i1.914 (3)N6—Co1i1.895 (3)
Co1—N11.908 (3)N7—C211.344 (5)
Co1—N31.930 (4)N7—C251.346 (5)
Co1—N41.929 (4)N8—C301.347 (5)
Co1—N6i1.895 (3)N8—C261.364 (5)
Co2—O31.911 (3)C1—C21.487 (6)
Co2—O51.914 (3)C2—C31.367 (6)
Co2—N21.912 (3)C3—C41.484 (6)
Co2—N51.912 (3)C5—H50.9300
Co2—N71.932 (3)C6—C71.365 (8)
Co2—N81.931 (3)C6—H60.9300
O1—C11.298 (5)C7—C81.352 (11)
O2—C11.232 (5)C7—H70.9300
O3—C41.302 (5)C8—C91.391 (11)
O4—C41.214 (5)C8—H80.9300
O5—C161.307 (5)C9—C101.372 (7)
O6—C161.218 (5)C9—H90.9300
O7—C191.231 (5)C10—C111.495 (8)
O8—C191.299 (5)C11—C121.412 (8)
O8—Co1i1.914 (3)C12—C131.347 (10)
O1W—H1W10.87C12—H120.9300
O1W—H1W20.86C13—C141.354 (9)
O2W—H2W10.86C13—H130.9300
O2W—H2W20.86C14—C151.373 (7)
O3W—H3W10.86C14—H140.9300
O3W—H3W20.86C15—H150.9300
O4W—H4W10.88C16—C171.485 (5)
O4W—H4W20.87C17—C181.366 (5)
O5W—H5W10.86C18—C191.488 (5)
O5W—H5W20.86C20—H200.9300
O6W—H6W10.87C21—C221.399 (6)
O6W—H6W20.87C21—H210.9300
O7W—H7W10.87C22—C231.368 (7)
O7W—H7W20.86C22—H220.9300
O8W—H8W10.88C23—C241.390 (7)
O8W—H8W20.86C23—H230.9300
N1—C51.337 (5)C24—C251.376 (5)
N1—C21.371 (5)C24—H240.9300
N2—C51.341 (5)C25—C261.471 (6)
N2—C31.370 (5)C26—C271.386 (6)
N3—C101.332 (7)C27—C281.373 (7)
N3—C61.337 (7)C27—H270.9300
N4—C151.319 (6)C28—C291.367 (7)
N4—C111.366 (6)C28—H280.9300
N5—C201.343 (5)C29—C301.369 (6)
N5—C171.370 (5)C29—H290.9300
N6—C201.326 (5)C30—H300.9300
O1—Co1—O8i90.3 (1)N1—C5—N2110.7 (3)
O1—Co1—N184.4 (1)N1—C5—H5124.6
O1—Co1—N393.2 (2)N2—C5—H5124.6
O1—Co1—N4177.4 (2)N3—C6—C7122.1 (7)
O1—Co1—N6i88.0 (1)N3—C6—H6118.9
O8i—Co1—N1174.6 (1)C7—C6—H6118.9
O8i—Co1—N386.9 (1)C8—C7—C6118.2 (7)
O8i—Co1—N489.7 (1)C8—C7—H7120.9
O8i—Co1—N6i84.7 (1)C6—C7—H7120.9
N1—Co1—N394.1 (2)C7—C8—C9121.5 (6)
N1—Co1—N495.6 (1)C7—C8—H8119.3
N1—Co1—N6i94.4 (1)C9—C8—H8119.3
N3—Co1—N484.3 (2)C10—C9—C8116.4 (7)
N3—Co1—N6i171.5 (2)C10—C9—H9121.8
N4—Co1—N6i94.6 (1)C8—C9—H9121.8
O3—Co2—O589.3 (1)N3—C10—C9122.8 (6)
O3—Co2—N284.1 (1)N3—C10—C11113.6 (4)
O3—Co2—N588.9 (1)C9—C10—C11123.6 (6)
O3—Co2—N793.9 (1)N4—C11—C12118.5 (6)
O3—Co2—N8177.2 (1)N4—C11—C10114.2 (4)
O5—Co2—N2173.0 (1)C12—C11—C10127.3 (5)
O5—Co2—N584.2 (1)C13—C12—C11120.5 (6)
O5—Co2—N788.5 (1)C13—C12—H12119.8
O5—Co2—N889.8 (1)C11—C12—H12119.8
N2—Co2—N593.4 (1)C12—C13—C14119.4 (6)
N2—Co2—N794.3 (1)C12—C13—H13120.3
N2—Co2—N896.9 (1)C14—C13—H13120.3
N5—Co2—N7172.1 (1)C13—C14—C15119.6 (6)
N5—Co2—N893.7 (1)C13—C14—H14120.2
N7—Co2—N883.4 (1)C15—C14—H14120.2
C1—O1—Co1115.7 (3)N4—C15—C14122.3 (5)
C4—O3—Co2115.7 (2)N4—C15—H15118.8
C16—O5—Co2116.0 (3)C14—C15—H15118.8
C19—O8—Co1i115.5 (3)O6—C16—O5123.0 (4)
H1W1—O1W—H1W2104.9O6—C16—C17124.3 (4)
H2W1—O2W—H2W2105.3O5—C16—C17112.7 (3)
H3W1—O3W—H3W2105.5C18—C17—N5107.3 (3)
H4W1—O4W—H4W2103.3C18—C17—C16138.1 (4)
H5W1—O5W—H5W2105.3N5—C17—C16114.6 (3)
H6W1—O6W—H6W2104.5)C17—C18—N6107.7 (3)
H7W1—O7W—H7W2105.7C17—C18—C19137.1 (4)
H8W1—O8W—H8W2104.8N6—C18—C19115.0 (3)
C5—N1—C2107.1 (3)O7—C19—O8123.6 (4)
C5—N1—Co1140.9 (3)O7—C19—C18123.8 (4)
C2—N1—Co1111.9 (3)O8—C19—C18112.7 (3)
C5—N2—C3106.7 (3)N6—C20—N5110.2 (3)
C5—N2—Co2141.4 (3)N6—C20—H20124.9
C3—N2—Co2111.9 (2)N5—C20—H20124.9
C10—N3—C6119.0 (5)N7—C21—C22121.1 (4)
C10—N3—Co1114.4 (4)N7—C21—H21119.4
C6—N3—Co1126.3 (4)C22—C21—H21119.4
C15—N4—C11119.7 (4)C23—C22—C21119.2 (5)
C15—N4—Co1127.4 (3)C23—C22—H22120.4
C11—N4—Co1112.8 (4)C21—C22—H22120.4
C20—N5—C17107.2 (3)C22—C23—C24119.5 (4)
C20—N5—Co2140.4 (3)C22—C23—H23120.3
C17—N5—Co2112.2 (2)C24—C23—H23120.3
C20—N6—C18107.6 (3)C25—C24—C23118.9 (4)
C20—N6—Co1i140.1 (3)C25—C24—H24120.6
C18—N6—Co1i112.1 (2)C23—C24—H24120.6
C21—N7—C25119.3 (3)N7—C25—C24122.0 (4)
C21—N7—Co2125.7 (3)N7—C25—C26113.6 (3)
C25—N7—Co2114.8 (3)C24—C25—C26124.4 (4)
C30—N8—C26118.6 (3)N8—C26—C27120.4 (4)
C30—N8—Co2127.5 (3)N8—C26—C25114.1 (3)
C26—N8—Co2113.7 (3)C27—C26—C25125.4 (4)
O2—C1—O1123.7 (4)C28—C27—C26120.6 (4)
O2—C1—C2123.5 (4)C28—C27—H27119.7
O1—C1—C2112.8 (4)C26—C27—H27119.7
C3—C2—N1107.5 (3)C29—C28—C27117.9 (4)
C3—C2—C1137.8 (4)C29—C28—H28121.1
N1—C2—C1114.7 (4)C27—C28—H28121.1
C2—C3—N2108.0 (3)C28—C29—C30120.8 (5)
C2—C3—C4137.2 (4)C28—C29—H29119.6
N2—C3—C4114.7 (4)C30—C29—H29119.6
O4—C4—O3123.6 (4)N8—C30—C29121.7 (4)
O4—C4—C3123.6 (4)N8—C30—H30119.2
O3—C4—C3112.7 (3)C29—C30—H30119.2
N1—Co1—O1—C12.3 (3)N2—C3—C4—O4180.0 (5)
O8i—Co1—O1—C1177.1 (3)C2—C3—C4—O3175.1 (5)
N3—Co1—O1—C196.1 (3)N2—C3—C4—O32.8 (6)
N5—Co2—O3—C484.0 (3)C2—N1—C5—N21.3 (4)
N2—Co2—O3—C49.5 (3)Co1—N1—C5—N2175.1 (3)
O5—Co2—O3—C4168.2 (3)C3—N2—C5—N10.4 (4)
N7—Co2—O3—C4103.4 (3)Co2—N2—C5—N1176.7 (3)
O3—Co2—O5—C1688.3 (3)C10—N3—C6—C71.2 (8)
N5—Co2—O5—C160.7 (3)Co1—N3—C6—C7172.0 (5)
N8—Co2—O5—C1694.4 (3)N3—C6—C7—C81.8 (10)
N7—Co2—O5—C16177.8 (3)C6—C7—C8—C92.0 (10)
N6i—Co1—N1—C594.1 (4)C7—C8—C9—C101.5 (10)
O1—Co1—N1—C5178.4 (4)C6—N3—C10—C90.7 (8)
N4—Co1—N1—C51.1 (4)Co1—N3—C10—C9173.3 (4)
N3—Co1—N1—C585.7 (4)C6—N3—C10—C11178.5 (4)
N6i—Co1—N1—C289.6 (3)Co1—N3—C10—C117.5 (5)
O1—Co1—N1—C22.1 (3)C8—C9—C10—N30.9 (8)
N4—Co1—N1—C2175.3 (3)C8—C9—C10—C11178.2 (5)
N3—Co1—N1—C290.7 (3)C15—N4—C11—C120.1 (7)
O3—Co2—N2—C5176.5 (4)Co1—N4—C11—C12175.8 (4)
N5—Co2—N2—C595.0 (4)C15—N4—C11—C10179.4 (4)
N8—Co2—N2—C50.9 (4)Co1—N4—C11—C104.9 (5)
N7—Co2—N2—C583.0 (4)N3—C10—C11—N41.7 (6)
O3—Co2—N2—C37.4 (3)C9—C10—C11—N4179.1 (5)
N5—Co2—N2—C381.2 (3)N3—C10—C11—C12177.5 (5)
N8—Co2—N2—C3175.3 (3)C9—C10—C11—C121.7 (9)
N7—Co2—N2—C3100.8 (3)N4—C11—C12—C130.8 (9)
N1—Co1—N3—C10103.5 (3)C10—C11—C12—C13179.9 (6)
O8i—Co1—N3—C1081.8 (3)C11—C12—C13—C141.6 (11)
O1—Co1—N3—C10171.9 (3)C12—C13—C14—C151.8 (11)
N4—Co1—N3—C108.2 (3)C11—N4—C15—C140.3 (8)
N1—Co1—N3—C683.1 (4)Co1—N4—C15—C14175.3 (4)
O8i—Co1—N3—C691.7 (4)C13—C14—C15—N41.1 (9)
O1—Co1—N3—C61.5 (4)Co2—O5—C16—O6175.7 (3)
N4—Co1—N3—C6178.3 (4)Co2—O5—C16—C173.8 (4)
N6i—Co1—N4—C1510.9 (4)C20—N5—C17—C180.6 (4)
N1—Co1—N4—C1584.0 (4)Co2—N5—C17—C18175.6 (2)
O8i—Co1—N4—C1595.5 (4)C20—N5—C17—C16178.3 (3)
N3—Co1—N4—C15177.6 (4)Co2—N5—C17—C165.5 (4)
N6i—Co1—N4—C11164.5 (3)O6—C16—C17—C185.1 (8)
N1—Co1—N4—C11100.6 (3)O5—C16—C17—C18175.5 (4)
O8i—Co1—N4—C1179.8 (3)O6—C16—C17—N5173.3 (4)
N3—Co1—N4—C117.1 (3)O5—C16—C17—N56.1 (5)
O3—Co2—N5—C2093.4 (4)N5—C17—C18—N61.0 (4)
N2—Co2—N5—C209.4 (4)C16—C17—C18—N6177.5 (4)
O5—Co2—N5—C20177.2 (4)N5—C17—C18—C19173.7 (4)
N8—Co2—N5—C2087.8 (4)C16—C17—C18—C197.8 (9)
O3—Co2—N5—C1792.2 (3)C20—N6—C18—C171.0 (4)
N2—Co2—N5—C17176.2 (3)Co1i—N6—C18—C17176.2 (3)
O5—Co2—N5—C172.8 (3)C20—N6—C18—C19175.0 (3)
N8—Co2—N5—C1786.6 (3)Co1i—N6—C18—C190.1 (4)
O3—Co2—N7—C211.0 (4)Co1i—O8—C19—O7178.6 (4)
N2—Co2—N7—C2185.3 (3)Co1i—O8—C19—C180.1 (5)
O5—Co2—N7—C2188.2 (3)C17—C18—C19—O74.0 (8)
N8—Co2—N7—C21178.2 (4)N6—C18—C19—O7178.5 (4)
O3—Co2—N7—C25176.8 (3)C17—C18—C19—O8174.5 (4)
N2—Co2—N7—C2598.9 (3)N6—C18—C19—O80.0 (5)
O5—Co2—N7—C2587.6 (3)C18—N6—C20—N50.6 (4)
N8—Co2—N7—C252.4 (3)Co1i—N6—C20—N5173.6 (3)
N5—Co2—N8—C306.3 (4)C17—N5—C20—N60.0 (4)
N2—Co2—N8—C3087.6 (4)Co2—N5—C20—N6174.5 (3)
O5—Co2—N8—C3090.4 (4)C25—N7—C21—C222.3 (6)
N7—Co2—N8—C30178.9 (4)Co2—N7—C21—C22177.8 (3)
N5—Co2—N8—C26168.3 (3)N7—C21—C22—C230.2 (7)
N2—Co2—N8—C2697.8 (3)C21—C22—C23—C241.3 (8)
O5—Co2—N8—C2684.2 (3)C22—C23—C24—C250.1 (8)
N7—Co2—N8—C264.3 (3)C21—N7—C25—C243.6 (6)
Co1—O1—C1—O2175.9 (4)Co2—N7—C25—C24179.6 (3)
Co1—O1—C1—C25.7 (5)C21—N7—C25—C26176.2 (4)
C5—N1—C2—C31.7 (4)Co2—N7—C25—C260.2 (4)
Co1—N1—C2—C3175.9 (3)C23—C24—C25—N72.4 (7)
C5—N1—C2—C1176.8 (3)C23—C24—C25—C26177.4 (4)
Co1—N1—C2—C15.6 (4)C30—N8—C26—C272.4 (6)
O2—C1—C2—C33.7 (9)Co2—N8—C26—C27172.7 (3)
O1—C1—C2—C3174.7 (5)C30—N8—C26—C25179.5 (4)
O2—C1—C2—N1174.1 (5)Co2—N8—C26—C255.3 (4)
O1—C1—C2—N17.5 (6)N7—C25—C26—N83.4 (5)
N1—C2—C3—N21.4 (5)C24—C25—C26—N8176.8 (4)
C1—C2—C3—N2176.5 (5)N7—C25—C26—C27174.5 (4)
N1—C2—C3—C4176.6 (5)C24—C25—C26—C275.3 (7)
C1—C2—C3—C45.5 (10)N8—C26—C27—C282.0 (7)
C5—N2—C3—C20.6 (4)C25—C26—C27—C28179.8 (4)
Co2—N2—C3—C2176.8 (3)C26—C27—C28—C290.4 (7)
C5—N2—C3—C4177.9 (3)C27—C28—C29—C300.7 (8)
Co2—N2—C3—C44.6 (4)C26—N8—C30—C291.3 (6)
Co2—O3—C4—O4173.7 (5)Co2—N8—C30—C29173.1 (4)
Co2—O3—C4—C39.1 (5)C28—C29—C30—N80.3 (8)
C2—C3—C4—O42.1 (9)
Symmetry code: (i) x+1, y+1, z+1.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1w—H1w1···O20.872.142.867 (6)141
O1w—H1w2···O2w0.862.482.781 (8)102
O2w—H2w2···O7ii0.862.082.758 (5)135
O5w—H5w1···O60.862.032.792 (7)147
O5w—H5w2···O1iii0.862.372.996 (6)129
O6w—H6w1···O5w0.872.242.61 (2)105
O6w—H6w2···O3wiii0.872.212.70 (1)115
O7w—H7w2···O6iv0.862.243.084 (9)170
O8w—H8w1···O3iv0.882.293.108 (7)156
O8w—H8w2···O4iii0.862.453.236 (8)153
Symmetry codes: (ii) x+1, y1, z; (iii) x1, y+1, z; (iv) x, y+2, z+2.
 

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