Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806020307/ob2021sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806020307/ob2021Isup2.hkl |
CCDC reference: 613784
Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.
[Pd(C5H5)(C15H17N)Cl(C18H15P)] | Dx = 1.458 Mg m−3 |
Mr = 736.36 | Melting point: 473 K |
Orthorhombic, Pbca | Mo Kα radiation, λ = 0.71073 Å |
a = 16.878 (4) Å | Cell parameters from 7937 reflections |
b = 16.488 (4) Å | θ = 2.4–25.2° |
c = 24.107 (5) Å | µ = 1.12 mm−1 |
V = 6709 (2) Å3 | T = 273 K |
Z = 8 | Block, red |
F(000) = 3008 | 0.32 × 0.26 × 0.20 mm |
Bruker APEX-II CCD area-detector diffractometer | 5924 independent reflections |
Radiation source: fine-focus sealed tube | 4851 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.033 |
φ and ω scans | θmax = 25.0°, θmin = 1.9° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −18→20 |
Tmin = 0.701, Tmax = 0.801 | k = −19→19 |
34744 measured reflections | l = −28→26 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.024 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.061 | H-atom parameters constrained |
S = 1.02 | w = 1/[σ2(Fo2) + (0.0234P)2 + 4.0356P] where P = (Fo2 + 2Fc2)/3 |
5924 reflections | (Δ/σ)max = 0.002 |
390 parameters | Δρmax = 0.56 e Å−3 |
0 restraints | Δρmin = −0.27 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Pd1 | 0.040130 (10) | 0.365692 (10) | 0.131283 (7) | 0.03085 (6) | |
Fe1 | −0.13785 (2) | 0.27337 (2) | 0.182364 (15) | 0.03979 (10) | |
Cl1 | 0.18116 (4) | 0.38755 (4) | 0.13648 (3) | 0.05063 (17) | |
P3 | 0.06451 (4) | 0.29193 (4) | 0.05488 (2) | 0.03282 (14) | |
N1 | 0.01546 (12) | 0.45591 (12) | 0.19604 (8) | 0.0407 (5) | |
C1 | −0.07741 (14) | 0.35451 (13) | 0.13295 (9) | 0.0331 (5) | |
C2 | −0.14072 (13) | 0.31649 (14) | 0.10334 (10) | 0.0363 (5) | |
H2 | −0.1350 | 0.2838 | 0.0696 | 0.044* | |
C3 | −0.21351 (14) | 0.33378 (16) | 0.13098 (11) | 0.0438 (6) | |
H3 | −0.2662 | 0.3153 | 0.1195 | 0.053* | |
C4 | −0.19630 (15) | 0.38172 (16) | 0.17808 (11) | 0.0461 (6) | |
H4 | −0.2349 | 0.4022 | 0.2050 | 0.055* | |
C5 | −0.11338 (14) | 0.39496 (15) | 0.17933 (10) | 0.0392 (6) | |
C6 | −0.05718 (19) | 0.1909 (2) | 0.21015 (16) | 0.0699 (10) | |
H6 | −0.0004 | 0.1909 | 0.2016 | 0.084* | |
C7 | −0.1171 (2) | 0.15159 (18) | 0.17878 (15) | 0.0701 (9) | |
H7 | −0.1093 | 0.1193 | 0.1451 | 0.084* | |
C8 | −0.1888 (2) | 0.1660 (2) | 0.20545 (15) | 0.0696 (10) | |
H8 | −0.2407 | 0.1463 | 0.1933 | 0.084* | |
C9 | −0.1745 (2) | 0.2142 (2) | 0.25239 (14) | 0.0726 (10) | |
H9 | −0.2144 | 0.2335 | 0.2788 | 0.087* | |
C10 | −0.0926 (2) | 0.2296 (2) | 0.25486 (14) | 0.0682 (9) | |
H10 | −0.0653 | 0.2614 | 0.2834 | 0.082* | |
C11 | −0.06532 (15) | 0.44078 (17) | 0.22107 (11) | 0.0478 (7) | |
H11 | −0.0576 | 0.4047 | 0.2529 | 0.057* | |
C12 | −0.1079 (2) | 0.5166 (2) | 0.24258 (17) | 0.0930 (13) | |
H12A | −0.1249 | 0.5491 | 0.2117 | 0.139* | |
H12B | −0.0724 | 0.5475 | 0.2654 | 0.139* | |
H12C | −0.1532 | 0.5007 | 0.2641 | 0.139* | |
C13 | 0.0169 (2) | 0.53123 (16) | 0.16153 (13) | 0.0615 (8) | |
H13A | 0.0098 | 0.5777 | 0.1850 | 0.092* | |
H13B | −0.0250 | 0.5291 | 0.1347 | 0.092* | |
H13C | 0.0670 | 0.5352 | 0.1428 | 0.092* | |
C14 | 0.07627 (17) | 0.46622 (17) | 0.24109 (11) | 0.0515 (7) | |
H14A | 0.0653 | 0.5161 | 0.2610 | 0.062* | |
H14B | 0.1282 | 0.4714 | 0.2242 | 0.062* | |
C15 | 0.07808 (16) | 0.3969 (2) | 0.28199 (11) | 0.0533 (7) | |
C16 | 0.10812 (16) | 0.3221 (2) | 0.26784 (13) | 0.0572 (8) | |
H16 | 0.1302 | 0.3144 | 0.2329 | 0.069* | |
C17 | 0.1058 (2) | 0.2583 (3) | 0.30488 (17) | 0.0822 (11) | |
H17 | 0.1263 | 0.2081 | 0.2947 | 0.099* | |
C18 | 0.0737 (3) | 0.2686 (4) | 0.3562 (2) | 0.1098 (19) | |
H18 | 0.0716 | 0.2251 | 0.3808 | 0.132* | |
C19 | 0.0449 (3) | 0.3412 (4) | 0.37151 (16) | 0.113 (2) | |
H19 | 0.0232 | 0.3478 | 0.4067 | 0.135* | |
C20 | 0.0474 (2) | 0.4066 (3) | 0.33497 (13) | 0.0848 (12) | |
H20 | 0.0284 | 0.4570 | 0.3461 | 0.102* | |
C21 | −0.01631 (15) | 0.25493 (16) | 0.01082 (10) | 0.0428 (6) | |
C22 | −0.05089 (16) | 0.3048 (2) | −0.02862 (11) | 0.0560 (8) | |
H22 | −0.0306 | 0.3565 | −0.0345 | 0.067* | |
C23 | −0.11518 (19) | 0.2786 (3) | −0.05932 (14) | 0.0829 (12) | |
H23 | −0.1381 | 0.3129 | −0.0854 | 0.100* | |
C24 | −0.1448 (2) | 0.2031 (3) | −0.05150 (18) | 0.0963 (15) | |
H24 | −0.1880 | 0.1859 | −0.0723 | 0.116* | |
C25 | −0.1119 (2) | 0.1525 (3) | −0.01347 (19) | 0.0862 (12) | |
H25 | −0.1323 | 0.1005 | −0.0087 | 0.103* | |
C26 | −0.04725 (17) | 0.1781 (2) | 0.01864 (13) | 0.0630 (8) | |
H26 | −0.0253 | 0.1436 | 0.0450 | 0.076* | |
C27 | 0.11964 (13) | 0.35605 (14) | 0.00667 (9) | 0.0342 (5) | |
C28 | 0.17898 (16) | 0.32781 (17) | −0.02744 (11) | 0.0482 (7) | |
H28 | 0.1953 | 0.2741 | −0.0247 | 0.058* | |
C29 | 0.21466 (18) | 0.3787 (2) | −0.06576 (12) | 0.0623 (8) | |
H29 | 0.2546 | 0.3588 | −0.0886 | 0.075* | |
C30 | 0.19161 (19) | 0.4577 (2) | −0.07014 (12) | 0.0615 (8) | |
H30 | 0.2150 | 0.4913 | −0.0964 | 0.074* | |
C31 | 0.13420 (19) | 0.48736 (18) | −0.03590 (13) | 0.0628 (8) | |
H31 | 0.1188 | 0.5414 | −0.0386 | 0.075* | |
C32 | 0.09875 (17) | 0.43724 (16) | 0.00292 (11) | 0.0516 (7) | |
H32 | 0.0605 | 0.4582 | 0.0267 | 0.062* | |
C33 | 0.12382 (15) | 0.20074 (14) | 0.06601 (11) | 0.0407 (6) | |
C34 | 0.15348 (17) | 0.18310 (17) | 0.11800 (12) | 0.0522 (7) | |
H34 | 0.1435 | 0.2177 | 0.1477 | 0.063* | |
C35 | 0.1983 (2) | 0.1136 (2) | 0.12574 (16) | 0.0756 (10) | |
H35 | 0.2180 | 0.1017 | 0.1608 | 0.091* | |
C36 | 0.2138 (2) | 0.0625 (2) | 0.0830 (2) | 0.0867 (12) | |
H36 | 0.2440 | 0.0161 | 0.0889 | 0.104* | |
C37 | 0.1850 (2) | 0.07941 (19) | 0.03126 (17) | 0.0787 (10) | |
H37 | 0.1962 | 0.0448 | 0.0018 | 0.094* | |
C38 | 0.13925 (18) | 0.14782 (16) | 0.02249 (13) | 0.0564 (7) | |
H38 | 0.1188 | 0.1584 | −0.0126 | 0.068* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Pd1 | 0.03111 (10) | 0.03127 (10) | 0.03018 (10) | −0.00508 (7) | 0.00287 (8) | −0.00002 (7) |
Fe1 | 0.03381 (19) | 0.0448 (2) | 0.0408 (2) | −0.00401 (16) | −0.00166 (15) | 0.01337 (16) |
Cl1 | 0.0364 (3) | 0.0665 (4) | 0.0489 (4) | −0.0164 (3) | 0.0059 (3) | −0.0045 (3) |
P3 | 0.0345 (3) | 0.0323 (3) | 0.0316 (3) | −0.0002 (3) | 0.0019 (3) | 0.0001 (2) |
N1 | 0.0437 (12) | 0.0370 (12) | 0.0414 (12) | −0.0041 (9) | 0.0031 (9) | −0.0077 (9) |
C1 | 0.0337 (12) | 0.0315 (13) | 0.0341 (12) | −0.0008 (10) | 0.0001 (10) | 0.0055 (10) |
C2 | 0.0355 (13) | 0.0376 (14) | 0.0358 (13) | −0.0016 (11) | −0.0033 (11) | 0.0075 (11) |
C3 | 0.0318 (13) | 0.0497 (15) | 0.0498 (16) | 0.0007 (11) | −0.0050 (12) | 0.0114 (13) |
C4 | 0.0351 (14) | 0.0525 (17) | 0.0507 (16) | 0.0088 (12) | 0.0071 (12) | 0.0059 (13) |
C5 | 0.0380 (14) | 0.0396 (14) | 0.0401 (14) | 0.0051 (11) | 0.0051 (11) | 0.0025 (11) |
C6 | 0.0509 (19) | 0.062 (2) | 0.097 (3) | 0.0033 (16) | −0.0105 (19) | 0.044 (2) |
C7 | 0.091 (3) | 0.0443 (18) | 0.075 (2) | 0.0031 (17) | −0.011 (2) | 0.0211 (16) |
C8 | 0.064 (2) | 0.066 (2) | 0.079 (2) | −0.0235 (17) | −0.0186 (18) | 0.0361 (19) |
C9 | 0.071 (2) | 0.090 (3) | 0.057 (2) | −0.0136 (19) | 0.0078 (17) | 0.0381 (19) |
C10 | 0.071 (2) | 0.074 (2) | 0.060 (2) | −0.0168 (18) | −0.0227 (17) | 0.0310 (18) |
C11 | 0.0430 (15) | 0.0521 (16) | 0.0484 (16) | −0.0018 (13) | 0.0082 (12) | −0.0128 (13) |
C12 | 0.070 (2) | 0.093 (3) | 0.116 (3) | 0.010 (2) | 0.011 (2) | −0.062 (2) |
C13 | 0.082 (2) | 0.0330 (15) | 0.070 (2) | −0.0044 (15) | −0.0014 (17) | −0.0008 (14) |
C14 | 0.0512 (16) | 0.0547 (17) | 0.0486 (16) | −0.0111 (14) | 0.0002 (13) | −0.0199 (13) |
C15 | 0.0396 (15) | 0.087 (2) | 0.0338 (15) | −0.0148 (15) | −0.0029 (12) | −0.0023 (14) |
C16 | 0.0458 (17) | 0.074 (2) | 0.0515 (18) | −0.0087 (15) | −0.0068 (14) | 0.0113 (16) |
C17 | 0.057 (2) | 0.099 (3) | 0.090 (3) | −0.0154 (19) | −0.0267 (19) | 0.037 (2) |
C18 | 0.063 (3) | 0.188 (6) | 0.079 (3) | −0.035 (3) | −0.026 (2) | 0.070 (4) |
C19 | 0.073 (3) | 0.228 (7) | 0.037 (2) | −0.028 (4) | −0.0037 (19) | 0.027 (3) |
C20 | 0.070 (2) | 0.141 (4) | 0.0440 (19) | −0.007 (2) | −0.0009 (17) | −0.012 (2) |
C21 | 0.0382 (14) | 0.0493 (16) | 0.0408 (14) | −0.0025 (12) | 0.0033 (11) | −0.0139 (12) |
C22 | 0.0426 (16) | 0.078 (2) | 0.0474 (17) | 0.0060 (15) | −0.0037 (13) | −0.0073 (15) |
C23 | 0.0474 (19) | 0.143 (4) | 0.058 (2) | 0.006 (2) | −0.0128 (16) | −0.019 (2) |
C24 | 0.051 (2) | 0.152 (4) | 0.086 (3) | −0.016 (3) | −0.008 (2) | −0.050 (3) |
C25 | 0.063 (2) | 0.091 (3) | 0.105 (3) | −0.031 (2) | 0.014 (2) | −0.047 (2) |
C26 | 0.0554 (18) | 0.064 (2) | 0.070 (2) | −0.0152 (16) | 0.0082 (16) | −0.0195 (16) |
C27 | 0.0349 (13) | 0.0382 (14) | 0.0296 (12) | −0.0005 (10) | −0.0023 (10) | 0.0022 (10) |
C28 | 0.0512 (16) | 0.0468 (16) | 0.0466 (16) | 0.0028 (13) | 0.0096 (13) | 0.0027 (13) |
C29 | 0.0583 (19) | 0.082 (2) | 0.0471 (17) | −0.0045 (16) | 0.0177 (14) | 0.0049 (16) |
C30 | 0.069 (2) | 0.073 (2) | 0.0421 (16) | −0.0195 (17) | −0.0001 (15) | 0.0215 (15) |
C31 | 0.080 (2) | 0.0457 (17) | 0.063 (2) | −0.0016 (16) | −0.0001 (17) | 0.0217 (15) |
C32 | 0.0594 (17) | 0.0435 (16) | 0.0518 (17) | 0.0090 (13) | 0.0098 (14) | 0.0093 (13) |
C33 | 0.0430 (14) | 0.0308 (13) | 0.0482 (16) | −0.0017 (11) | 0.0031 (12) | 0.0041 (11) |
C34 | 0.0565 (17) | 0.0488 (17) | 0.0512 (17) | −0.0016 (14) | −0.0006 (14) | 0.0147 (13) |
C35 | 0.072 (2) | 0.062 (2) | 0.093 (3) | 0.0059 (18) | −0.015 (2) | 0.037 (2) |
C36 | 0.077 (3) | 0.0426 (19) | 0.140 (4) | 0.0185 (18) | −0.003 (2) | 0.020 (2) |
C37 | 0.088 (3) | 0.0431 (19) | 0.105 (3) | 0.0166 (18) | 0.007 (2) | −0.0101 (19) |
C38 | 0.0671 (19) | 0.0387 (16) | 0.0635 (19) | 0.0063 (14) | 0.0022 (15) | −0.0046 (14) |
Pd1—C1 | 1.993 (2) | C14—C15 | 1.510 (4) |
Pd1—N1 | 2.1962 (19) | C14—H14A | 0.9700 |
Pd1—P3 | 2.2452 (7) | C14—H14B | 0.9700 |
Pd1—Cl1 | 2.4107 (8) | C15—C16 | 1.376 (4) |
Fe1—C2 | 2.034 (2) | C15—C20 | 1.388 (4) |
Fe1—C6 | 2.038 (3) | C16—C17 | 1.380 (4) |
Fe1—C10 | 2.039 (3) | C16—H16 | 0.9300 |
Fe1—C3 | 2.039 (2) | C17—C18 | 1.362 (6) |
Fe1—C7 | 2.040 (3) | C17—H17 | 0.9300 |
Fe1—C4 | 2.043 (3) | C18—C19 | 1.344 (7) |
Fe1—C8 | 2.045 (3) | C18—H18 | 0.9300 |
Fe1—C9 | 2.045 (3) | C19—C20 | 1.393 (7) |
Fe1—C5 | 2.048 (3) | C19—H19 | 0.9300 |
Fe1—C1 | 2.061 (2) | C20—H20 | 0.9300 |
P3—C27 | 1.826 (2) | C21—C26 | 1.383 (4) |
P3—C33 | 1.826 (2) | C21—C22 | 1.386 (4) |
P3—C21 | 1.833 (3) | C22—C23 | 1.383 (4) |
N1—C13 | 1.495 (3) | C22—H22 | 0.9300 |
N1—C14 | 1.504 (3) | C23—C24 | 1.354 (6) |
N1—C11 | 1.512 (3) | C23—H23 | 0.9300 |
C1—C2 | 1.430 (3) | C24—C25 | 1.359 (6) |
C1—C5 | 1.437 (3) | C24—H24 | 0.9300 |
C2—C3 | 1.426 (3) | C25—C26 | 1.403 (5) |
C2—H2 | 0.9800 | C25—H25 | 0.9300 |
C3—C4 | 1.414 (4) | C26—H26 | 0.9300 |
C3—H3 | 0.9800 | C27—C28 | 1.377 (3) |
C4—C5 | 1.417 (3) | C27—C32 | 1.387 (3) |
C4—H4 | 0.9800 | C28—C29 | 1.385 (4) |
C5—C11 | 1.497 (4) | C28—H28 | 0.9300 |
C6—C10 | 1.389 (5) | C29—C30 | 1.364 (4) |
C6—C7 | 1.420 (5) | C29—H29 | 0.9300 |
C6—H6 | 0.9800 | C30—C31 | 1.363 (4) |
C7—C8 | 1.391 (5) | C30—H30 | 0.9300 |
C7—H7 | 0.9800 | C31—C32 | 1.385 (4) |
C8—C9 | 1.404 (5) | C31—H31 | 0.9300 |
C8—H8 | 0.9800 | C32—H32 | 0.9300 |
C9—C10 | 1.407 (5) | C33—C34 | 1.381 (4) |
C9—H9 | 0.9800 | C33—C38 | 1.389 (4) |
C10—H10 | 0.9800 | C34—C35 | 1.386 (4) |
C11—C12 | 1.533 (4) | C34—H34 | 0.9300 |
C11—H11 | 0.9800 | C35—C36 | 1.356 (5) |
C12—H12A | 0.9600 | C35—H35 | 0.9300 |
C12—H12B | 0.9600 | C36—C37 | 1.368 (5) |
C12—H12C | 0.9600 | C36—H36 | 0.9300 |
C13—H13A | 0.9600 | C37—C38 | 1.383 (4) |
C13—H13B | 0.9600 | C37—H37 | 0.9300 |
C13—H13C | 0.9600 | C38—H38 | 0.9300 |
C1—Pd1—N1 | 81.93 (8) | Fe1—C8—H8 | 125.7 |
C1—Pd1—P3 | 98.56 (7) | C8—C9—C10 | 107.8 (3) |
N1—Pd1—P3 | 169.99 (6) | C8—C9—Fe1 | 69.92 (17) |
C1—Pd1—Cl1 | 174.71 (7) | C10—C9—Fe1 | 69.61 (17) |
N1—Pd1—Cl1 | 92.81 (6) | C8—C9—H9 | 126.1 |
P3—Pd1—Cl1 | 86.71 (2) | C10—C9—H9 | 126.1 |
C2—Fe1—C6 | 123.85 (13) | Fe1—C9—H9 | 126.1 |
C2—Fe1—C10 | 159.29 (12) | C6—C10—C9 | 107.9 (3) |
C6—Fe1—C10 | 39.83 (13) | C6—C10—Fe1 | 70.04 (17) |
C2—Fe1—C3 | 41.00 (9) | C9—C10—Fe1 | 70.10 (17) |
C6—Fe1—C3 | 160.78 (14) | C6—C10—H10 | 126.0 |
C10—Fe1—C3 | 158.13 (14) | C9—C10—H10 | 126.0 |
C2—Fe1—C7 | 107.97 (12) | Fe1—C10—H10 | 126.0 |
C6—Fe1—C7 | 40.74 (13) | C5—C11—N1 | 107.69 (19) |
C10—Fe1—C7 | 67.92 (14) | C5—C11—C12 | 112.6 (2) |
C3—Fe1—C7 | 124.23 (13) | N1—C11—C12 | 115.0 (2) |
C2—Fe1—C4 | 68.63 (10) | C5—C11—H11 | 107.0 |
C6—Fe1—C4 | 157.33 (14) | N1—C11—H11 | 107.0 |
C10—Fe1—C4 | 122.22 (14) | C12—C11—H11 | 107.0 |
C3—Fe1—C4 | 40.52 (10) | C11—C12—H12A | 109.5 |
C7—Fe1—C4 | 160.26 (13) | C11—C12—H12B | 109.5 |
C2—Fe1—C8 | 123.19 (12) | H12A—C12—H12B | 109.5 |
C6—Fe1—C8 | 67.29 (13) | C11—C12—H12C | 109.5 |
C10—Fe1—C8 | 67.55 (13) | H12A—C12—H12C | 109.5 |
C3—Fe1—C8 | 108.95 (12) | H12B—C12—H12C | 109.5 |
C7—Fe1—C8 | 39.82 (13) | N1—C13—H13A | 109.5 |
C4—Fe1—C8 | 124.56 (13) | N1—C13—H13B | 109.5 |
C2—Fe1—C9 | 158.82 (12) | H13A—C13—H13B | 109.5 |
C6—Fe1—C9 | 67.22 (14) | N1—C13—H13C | 109.5 |
C10—Fe1—C9 | 40.30 (13) | H13A—C13—H13C | 109.5 |
C3—Fe1—C9 | 123.00 (12) | H13B—C13—H13C | 109.5 |
C7—Fe1—C9 | 67.53 (15) | N1—C14—C15 | 113.6 (2) |
C4—Fe1—C9 | 108.20 (13) | N1—C14—H14A | 108.9 |
C8—Fe1—C9 | 40.14 (13) | C15—C14—H14A | 108.9 |
C2—Fe1—C5 | 68.24 (10) | N1—C14—H14B | 108.9 |
C6—Fe1—C5 | 122.03 (12) | C15—C14—H14B | 108.9 |
C10—Fe1—C5 | 107.53 (12) | H14A—C14—H14B | 107.7 |
C3—Fe1—C5 | 68.06 (10) | C16—C15—C20 | 118.0 (3) |
C7—Fe1—C5 | 158.02 (13) | C16—C15—C14 | 121.6 (2) |
C4—Fe1—C5 | 40.51 (10) | C20—C15—C14 | 120.4 (3) |
C8—Fe1—C5 | 160.32 (13) | C15—C16—C17 | 120.8 (3) |
C9—Fe1—C5 | 123.85 (13) | C15—C16—H16 | 119.6 |
C2—Fe1—C1 | 40.86 (9) | C17—C16—H16 | 119.6 |
C6—Fe1—C1 | 107.00 (11) | C18—C17—C16 | 120.3 (4) |
C10—Fe1—C1 | 122.65 (11) | C18—C17—H17 | 119.8 |
C3—Fe1—C1 | 69.01 (10) | C16—C17—H17 | 119.8 |
C7—Fe1—C1 | 121.97 (13) | C19—C18—C17 | 120.2 (4) |
C4—Fe1—C1 | 69.04 (10) | C19—C18—H18 | 119.9 |
C8—Fe1—C1 | 157.99 (13) | C17—C18—H18 | 119.9 |
C9—Fe1—C1 | 159.40 (13) | C18—C19—C20 | 120.4 (4) |
C5—Fe1—C1 | 40.92 (9) | C18—C19—H19 | 119.8 |
C27—P3—C33 | 106.91 (11) | C20—C19—H19 | 119.8 |
C27—P3—C21 | 101.71 (11) | C15—C20—C19 | 120.2 (4) |
C33—P3—C21 | 102.65 (12) | C15—C20—H20 | 119.9 |
C27—P3—Pd1 | 107.57 (8) | C19—C20—H20 | 119.9 |
C33—P3—Pd1 | 115.22 (9) | C26—C21—C22 | 118.5 (3) |
C21—P3—Pd1 | 121.28 (8) | C26—C21—P3 | 120.4 (2) |
C13—N1—C14 | 107.3 (2) | C22—C21—P3 | 120.9 (2) |
C13—N1—C11 | 112.0 (2) | C23—C22—C21 | 120.8 (3) |
C14—N1—C11 | 110.24 (19) | C23—C22—H22 | 119.6 |
C13—N1—Pd1 | 99.44 (15) | C21—C22—H22 | 119.6 |
C14—N1—Pd1 | 117.42 (16) | C24—C23—C22 | 120.2 (4) |
C11—N1—Pd1 | 110.05 (14) | C24—C23—H23 | 119.9 |
C2—C1—C5 | 106.0 (2) | C22—C23—H23 | 119.9 |
C2—C1—Pd1 | 140.76 (18) | C23—C24—C25 | 120.5 (4) |
C5—C1—Pd1 | 113.17 (16) | C23—C24—H24 | 119.8 |
C2—C1—Fe1 | 68.53 (13) | C25—C24—H24 | 119.8 |
C5—C1—Fe1 | 69.05 (13) | C24—C25—C26 | 120.3 (4) |
Pd1—C1—Fe1 | 124.36 (11) | C24—C25—H25 | 119.8 |
C3—C2—C1 | 108.8 (2) | C26—C25—H25 | 119.8 |
C3—C2—Fe1 | 69.69 (14) | C21—C26—C25 | 119.6 (4) |
C1—C2—Fe1 | 70.60 (13) | C21—C26—H26 | 120.2 |
C3—C2—H2 | 125.6 | C25—C26—H26 | 120.2 |
C1—C2—H2 | 125.6 | C28—C27—C32 | 118.2 (2) |
Fe1—C2—H2 | 125.6 | C28—C27—P3 | 123.70 (19) |
C4—C3—C2 | 108.1 (2) | C32—C27—P3 | 118.08 (18) |
C4—C3—Fe1 | 69.91 (14) | C27—C28—C29 | 120.6 (3) |
C2—C3—Fe1 | 69.31 (13) | C27—C28—H28 | 119.7 |
C4—C3—H3 | 126.0 | C29—C28—H28 | 119.7 |
C2—C3—H3 | 126.0 | C30—C29—C28 | 120.4 (3) |
Fe1—C3—H3 | 126.0 | C30—C29—H29 | 119.8 |
C3—C4—C5 | 107.8 (2) | C28—C29—H29 | 119.8 |
C3—C4—Fe1 | 69.57 (15) | C31—C30—C29 | 119.9 (3) |
C5—C4—Fe1 | 69.93 (14) | C31—C30—H30 | 120.1 |
C3—C4—H4 | 126.1 | C29—C30—H30 | 120.1 |
C5—C4—H4 | 126.1 | C30—C31—C32 | 120.2 (3) |
Fe1—C4—H4 | 126.1 | C30—C31—H31 | 119.9 |
C4—C5—C1 | 109.2 (2) | C32—C31—H31 | 119.9 |
C4—C5—C11 | 128.9 (2) | C31—C32—C27 | 120.7 (3) |
C1—C5—C11 | 121.9 (2) | C31—C32—H32 | 119.7 |
C4—C5—Fe1 | 69.56 (15) | C27—C32—H32 | 119.7 |
C1—C5—Fe1 | 70.03 (13) | C34—C33—C38 | 119.0 (2) |
C11—C5—Fe1 | 125.39 (18) | C34—C33—P3 | 120.4 (2) |
C10—C6—C7 | 108.5 (3) | C38—C33—P3 | 120.6 (2) |
C10—C6—Fe1 | 70.13 (18) | C33—C34—C35 | 119.6 (3) |
C7—C6—Fe1 | 69.72 (17) | C33—C34—H34 | 120.2 |
C10—C6—H6 | 125.8 | C35—C34—H34 | 120.2 |
C7—C6—H6 | 125.8 | C36—C35—C34 | 121.1 (3) |
Fe1—C6—H6 | 125.8 | C36—C35—H35 | 119.4 |
C8—C7—C6 | 107.2 (3) | C34—C35—H35 | 119.4 |
C8—C7—Fe1 | 70.28 (19) | C35—C36—C37 | 119.8 (3) |
C6—C7—Fe1 | 69.54 (18) | C35—C36—H36 | 120.1 |
C8—C7—H7 | 126.4 | C37—C36—H36 | 120.1 |
C6—C7—H7 | 126.4 | C36—C37—C38 | 120.3 (3) |
Fe1—C7—H7 | 126.4 | C36—C37—H37 | 119.9 |
C7—C8—C9 | 108.7 (3) | C38—C37—H37 | 119.9 |
C7—C8—Fe1 | 69.90 (17) | C37—C38—C33 | 120.1 (3) |
C9—C8—Fe1 | 69.94 (17) | C37—C38—H38 | 120.0 |
C7—C8—H8 | 125.7 | C33—C38—H38 | 120.0 |
C9—C8—H8 | 125.7 | ||
C1—Pd1—P3—C27 | 124.12 (10) | C1—Fe1—C6—C10 | 120.94 (19) |
N1—Pd1—P3—C27 | 32.0 (3) | C2—Fe1—C6—C7 | −77.9 (2) |
Cl1—Pd1—P3—C27 | −55.49 (8) | C10—Fe1—C6—C7 | 119.5 (3) |
C1—Pd1—P3—C33 | −116.79 (11) | C3—Fe1—C6—C7 | −44.7 (4) |
N1—Pd1—P3—C33 | 151.1 (3) | C4—Fe1—C6—C7 | 164.2 (3) |
Cl1—Pd1—P3—C33 | 63.61 (9) | C8—Fe1—C6—C7 | 37.8 (2) |
C1—Pd1—P3—C21 | 7.92 (12) | C9—Fe1—C6—C7 | 81.5 (2) |
N1—Pd1—P3—C21 | −84.2 (3) | C5—Fe1—C6—C7 | −161.76 (19) |
Cl1—Pd1—P3—C21 | −171.68 (11) | C1—Fe1—C6—C7 | −119.6 (2) |
C1—Pd1—N1—C13 | −97.51 (17) | C10—C6—C7—C8 | −0.9 (3) |
P3—Pd1—N1—C13 | −4.0 (4) | Fe1—C6—C7—C8 | −60.5 (2) |
Cl1—Pd1—N1—C13 | 83.02 (16) | C10—C6—C7—Fe1 | 59.6 (2) |
C1—Pd1—N1—C14 | 147.34 (18) | C2—Fe1—C7—C8 | −120.6 (2) |
P3—Pd1—N1—C14 | −119.1 (3) | C6—Fe1—C7—C8 | 118.0 (3) |
Cl1—Pd1—N1—C14 | −32.13 (17) | C10—Fe1—C7—C8 | 81.0 (2) |
C1—Pd1—N1—C11 | 20.17 (17) | C3—Fe1—C7—C8 | −78.3 (2) |
P3—Pd1—N1—C11 | 113.7 (3) | C4—Fe1—C7—C8 | −44.0 (5) |
Cl1—Pd1—N1—C11 | −159.30 (16) | C9—Fe1—C7—C8 | 37.27 (19) |
N1—Pd1—C1—C2 | 171.2 (3) | C5—Fe1—C7—C8 | 163.1 (3) |
P3—Pd1—C1—C2 | 1.3 (3) | C1—Fe1—C7—C8 | −163.35 (18) |
Cl1—Pd1—C1—C2 | 176.9 (5) | C2—Fe1—C7—C6 | 121.4 (2) |
N1—Pd1—C1—C5 | −11.28 (16) | C10—Fe1—C7—C6 | −37.0 (2) |
P3—Pd1—C1—C5 | 178.82 (15) | C3—Fe1—C7—C6 | 163.75 (19) |
Cl1—Pd1—C1—C5 | −5.5 (8) | C4—Fe1—C7—C6 | −161.9 (3) |
N1—Pd1—C1—Fe1 | −91.00 (14) | C8—Fe1—C7—C6 | −118.0 (3) |
P3—Pd1—C1—Fe1 | 99.10 (12) | C9—Fe1—C7—C6 | −80.7 (2) |
Cl1—Pd1—C1—Fe1 | −85.2 (7) | C5—Fe1—C7—C6 | 45.2 (4) |
C6—Fe1—C1—C2 | 122.47 (18) | C1—Fe1—C7—C6 | 78.7 (2) |
C10—Fe1—C1—C2 | 163.20 (18) | C6—C7—C8—C9 | 0.6 (3) |
C3—Fe1—C1—C2 | −37.63 (14) | Fe1—C7—C8—C9 | −59.4 (2) |
C7—Fe1—C1—C2 | 80.46 (18) | C6—C7—C8—Fe1 | 60.0 (2) |
C4—Fe1—C1—C2 | −81.16 (15) | C2—Fe1—C8—C7 | 77.9 (2) |
C8—Fe1—C1—C2 | 51.2 (3) | C6—Fe1—C8—C7 | −38.7 (2) |
C9—Fe1—C1—C2 | −167.2 (3) | C10—Fe1—C8—C7 | −82.0 (2) |
C5—Fe1—C1—C2 | −117.9 (2) | C3—Fe1—C8—C7 | 121.1 (2) |
C2—Fe1—C1—C5 | 117.9 (2) | C4—Fe1—C8—C7 | 163.45 (19) |
C6—Fe1—C1—C5 | −119.60 (17) | C9—Fe1—C8—C7 | −119.8 (3) |
C10—Fe1—C1—C5 | −78.9 (2) | C5—Fe1—C8—C7 | −161.2 (3) |
C3—Fe1—C1—C5 | 80.31 (15) | C1—Fe1—C8—C7 | 40.4 (4) |
C7—Fe1—C1—C5 | −161.61 (16) | C2—Fe1—C8—C9 | −162.30 (19) |
C4—Fe1—C1—C5 | 36.77 (14) | C6—Fe1—C8—C9 | 81.1 (2) |
C8—Fe1—C1—C5 | 169.1 (3) | C10—Fe1—C8—C9 | 37.8 (2) |
C9—Fe1—C1—C5 | −49.3 (4) | C3—Fe1—C8—C9 | −119.1 (2) |
C2—Fe1—C1—Pd1 | −137.7 (2) | C7—Fe1—C8—C9 | 119.8 (3) |
C6—Fe1—C1—Pd1 | −15.20 (19) | C4—Fe1—C8—C9 | −76.8 (2) |
C10—Fe1—C1—Pd1 | 25.5 (2) | C5—Fe1—C8—C9 | −41.4 (4) |
C3—Fe1—C1—Pd1 | −175.29 (17) | C1—Fe1—C8—C9 | 160.2 (3) |
C7—Fe1—C1—Pd1 | −57.20 (19) | C7—C8—C9—C10 | −0.2 (3) |
C4—Fe1—C1—Pd1 | 141.17 (17) | Fe1—C8—C9—C10 | −59.5 (2) |
C8—Fe1—C1—Pd1 | −86.5 (3) | C7—C8—C9—Fe1 | 59.4 (2) |
C9—Fe1—C1—Pd1 | 55.1 (4) | C2—Fe1—C9—C8 | 44.8 (5) |
C5—Fe1—C1—Pd1 | 104.40 (19) | C6—Fe1—C9—C8 | −81.3 (2) |
C5—C1—C2—C3 | 0.3 (3) | C10—Fe1—C9—C8 | −118.9 (3) |
Pd1—C1—C2—C3 | 177.9 (2) | C3—Fe1—C9—C8 | 80.2 (2) |
Fe1—C1—C2—C3 | 59.41 (17) | C7—Fe1—C9—C8 | −37.0 (2) |
C5—C1—C2—Fe1 | −59.15 (15) | C4—Fe1—C9—C8 | 122.4 (2) |
Pd1—C1—C2—Fe1 | 118.5 (2) | C5—Fe1—C9—C8 | 164.44 (18) |
C6—Fe1—C2—C3 | 164.03 (17) | C1—Fe1—C9—C8 | −158.8 (3) |
C10—Fe1—C2—C3 | −163.2 (3) | C2—Fe1—C9—C10 | 163.6 (3) |
C7—Fe1—C2—C3 | 121.90 (18) | C6—Fe1—C9—C10 | 37.6 (2) |
C4—Fe1—C2—C3 | −37.43 (15) | C3—Fe1—C9—C10 | −160.9 (2) |
C8—Fe1—C2—C3 | 80.7 (2) | C7—Fe1—C9—C10 | 81.9 (2) |
C9—Fe1—C2—C3 | 47.9 (4) | C4—Fe1—C9—C10 | −118.7 (2) |
C5—Fe1—C2—C3 | −81.14 (16) | C8—Fe1—C9—C10 | 118.9 (3) |
C1—Fe1—C2—C3 | −119.7 (2) | C5—Fe1—C9—C10 | −76.7 (3) |
C6—Fe1—C2—C1 | −76.28 (19) | C1—Fe1—C9—C10 | −40.0 (5) |
C10—Fe1—C2—C1 | −43.5 (4) | C7—C6—C10—C9 | 0.8 (3) |
C3—Fe1—C2—C1 | 119.7 (2) | Fe1—C6—C10—C9 | 60.1 (2) |
C7—Fe1—C2—C1 | −118.42 (17) | C7—C6—C10—Fe1 | −59.4 (2) |
C4—Fe1—C2—C1 | 82.26 (15) | C8—C9—C10—C6 | −0.4 (3) |
C8—Fe1—C2—C1 | −159.58 (17) | Fe1—C9—C10—C6 | −60.1 (2) |
C9—Fe1—C2—C1 | 167.6 (3) | C8—C9—C10—Fe1 | 59.7 (2) |
C5—Fe1—C2—C1 | 38.54 (13) | C2—Fe1—C10—C6 | −44.6 (4) |
C1—C2—C3—C4 | −0.6 (3) | C3—Fe1—C10—C6 | 166.0 (3) |
Fe1—C2—C3—C4 | 59.38 (17) | C7—Fe1—C10—C6 | 37.8 (2) |
C1—C2—C3—Fe1 | −59.97 (16) | C4—Fe1—C10—C6 | −161.30 (18) |
C2—Fe1—C3—C4 | −119.4 (2) | C8—Fe1—C10—C6 | 81.0 (2) |
C6—Fe1—C3—C4 | −163.3 (3) | C9—Fe1—C10—C6 | 118.6 (3) |
C10—Fe1—C3—C4 | 44.6 (4) | C5—Fe1—C10—C6 | −119.31 (19) |
C7—Fe1—C3—C4 | 162.96 (17) | C1—Fe1—C10—C6 | −76.9 (2) |
C8—Fe1—C3—C4 | 121.43 (18) | C2—Fe1—C10—C9 | −163.3 (3) |
C9—Fe1—C3—C4 | 79.2 (2) | C6—Fe1—C10—C9 | −118.6 (3) |
C5—Fe1—C3—C4 | −37.79 (14) | C3—Fe1—C10—C9 | 47.4 (4) |
C1—Fe1—C3—C4 | −81.91 (15) | C7—Fe1—C10—C9 | −80.8 (2) |
C6—Fe1—C3—C2 | −43.9 (4) | C4—Fe1—C10—C9 | 80.1 (2) |
C10—Fe1—C3—C2 | 164.0 (3) | C8—Fe1—C10—C9 | −37.7 (2) |
C7—Fe1—C3—C2 | −77.6 (2) | C5—Fe1—C10—C9 | 122.1 (2) |
C4—Fe1—C3—C2 | 119.4 (2) | C1—Fe1—C10—C9 | 164.4 (2) |
C8—Fe1—C3—C2 | −119.16 (18) | C4—C5—C11—N1 | −165.2 (2) |
C9—Fe1—C3—C2 | −161.36 (18) | C1—C5—C11—N1 | 16.5 (3) |
C5—Fe1—C3—C2 | 81.61 (15) | Fe1—C5—C11—N1 | 103.5 (2) |
C1—Fe1—C3—C2 | 37.50 (14) | C4—C5—C11—C12 | −37.3 (4) |
C2—C3—C4—C5 | 0.7 (3) | C1—C5—C11—C12 | 144.4 (3) |
Fe1—C3—C4—C5 | 59.70 (18) | Fe1—C5—C11—C12 | −128.6 (3) |
C2—C3—C4—Fe1 | −59.00 (17) | C13—N1—C11—C5 | 86.1 (3) |
C2—Fe1—C4—C3 | 37.86 (14) | C14—N1—C11—C5 | −154.5 (2) |
C6—Fe1—C4—C3 | 165.8 (3) | Pd1—N1—C11—C5 | −23.5 (2) |
C10—Fe1—C4—C3 | −161.97 (16) | C13—N1—C11—C12 | −40.4 (3) |
C7—Fe1—C4—C3 | −45.8 (4) | C14—N1—C11—C12 | 79.0 (3) |
C8—Fe1—C4—C3 | −78.5 (2) | Pd1—N1—C11—C12 | −150.0 (2) |
C9—Fe1—C4—C3 | −119.86 (17) | C13—N1—C14—C15 | 176.2 (2) |
C5—Fe1—C4—C3 | 119.0 (2) | C11—N1—C14—C15 | 54.0 (3) |
C1—Fe1—C4—C3 | 81.83 (15) | Pd1—N1—C14—C15 | −73.1 (3) |
C2—Fe1—C4—C5 | −81.09 (15) | N1—C14—C15—C16 | 72.2 (3) |
C6—Fe1—C4—C5 | 46.9 (4) | N1—C14—C15—C20 | −106.2 (3) |
C10—Fe1—C4—C5 | 79.08 (19) | C20—C15—C16—C17 | 1.6 (4) |
C3—Fe1—C4—C5 | −119.0 (2) | C14—C15—C16—C17 | −176.9 (3) |
C7—Fe1—C4—C5 | −164.8 (3) | C15—C16—C17—C18 | 0.0 (5) |
C8—Fe1—C4—C5 | 162.54 (17) | C16—C17—C18—C19 | −0.9 (6) |
C9—Fe1—C4—C5 | 121.19 (17) | C17—C18—C19—C20 | 0.2 (7) |
C1—Fe1—C4—C5 | −37.12 (14) | C16—C15—C20—C19 | −2.3 (5) |
C3—C4—C5—C1 | −0.5 (3) | C14—C15—C20—C19 | 176.2 (3) |
Fe1—C4—C5—C1 | 58.93 (17) | C18—C19—C20—C15 | 1.4 (6) |
C3—C4—C5—C11 | −179.0 (3) | C27—P3—C21—C26 | 146.8 (2) |
Fe1—C4—C5—C11 | −119.6 (3) | C33—P3—C21—C26 | 36.3 (2) |
C3—C4—C5—Fe1 | −59.47 (18) | Pd1—P3—C21—C26 | −94.0 (2) |
C2—C1—C5—C4 | 0.2 (3) | C27—P3—C21—C22 | −37.2 (2) |
Pd1—C1—C5—C4 | −178.21 (16) | C33—P3—C21—C22 | −147.7 (2) |
Fe1—C1—C5—C4 | −58.65 (17) | Pd1—P3—C21—C22 | 82.0 (2) |
C2—C1—C5—C11 | 178.8 (2) | C26—C21—C22—C23 | 0.3 (4) |
Pd1—C1—C5—C11 | 0.4 (3) | P3—C21—C22—C23 | −175.8 (2) |
Fe1—C1—C5—C11 | 120.0 (2) | C21—C22—C23—C24 | −0.6 (5) |
C2—C1—C5—Fe1 | 58.82 (15) | C22—C23—C24—C25 | 0.1 (6) |
Pd1—C1—C5—Fe1 | −119.57 (13) | C23—C24—C25—C26 | 0.7 (6) |
C2—Fe1—C5—C4 | 82.14 (16) | C22—C21—C26—C25 | 0.5 (4) |
C6—Fe1—C5—C4 | −160.62 (19) | P3—C21—C26—C25 | 176.6 (2) |
C10—Fe1—C5—C4 | −119.41 (18) | C24—C25—C26—C21 | −1.0 (5) |
C3—Fe1—C5—C4 | 37.80 (15) | C33—P3—C27—C28 | 19.4 (2) |
C7—Fe1—C5—C4 | 166.3 (3) | C21—P3—C27—C28 | −87.9 (2) |
C8—Fe1—C5—C4 | −47.2 (4) | Pd1—P3—C27—C28 | 143.7 (2) |
C9—Fe1—C5—C4 | −78.1 (2) | C33—P3—C27—C32 | −162.8 (2) |
C1—Fe1—C5—C4 | 120.6 (2) | C21—P3—C27—C32 | 89.9 (2) |
C2—Fe1—C5—C1 | −38.49 (13) | Pd1—P3—C27—C32 | −38.5 (2) |
C6—Fe1—C5—C1 | 78.75 (19) | C32—C27—C28—C29 | −2.3 (4) |
C10—Fe1—C5—C1 | 119.96 (17) | P3—C27—C28—C29 | 175.5 (2) |
C3—Fe1—C5—C1 | −82.83 (15) | C27—C28—C29—C30 | 0.2 (4) |
C7—Fe1—C5—C1 | 45.7 (4) | C28—C29—C30—C31 | 1.3 (5) |
C4—Fe1—C5—C1 | −120.6 (2) | C29—C30—C31—C32 | −0.6 (5) |
C8—Fe1—C5—C1 | −167.8 (3) | C30—C31—C32—C27 | −1.5 (5) |
C9—Fe1—C5—C1 | 161.26 (16) | C28—C27—C32—C31 | 2.9 (4) |
C2—Fe1—C5—C11 | −154.0 (2) | P3—C27—C32—C31 | −175.0 (2) |
C6—Fe1—C5—C11 | −36.8 (3) | C27—P3—C33—C34 | 116.5 (2) |
C10—Fe1—C5—C11 | 4.4 (2) | C21—P3—C33—C34 | −136.9 (2) |
C3—Fe1—C5—C11 | 161.6 (2) | Pd1—P3—C33—C34 | −3.0 (2) |
C7—Fe1—C5—C11 | −69.9 (4) | C27—P3—C33—C38 | −64.0 (2) |
C4—Fe1—C5—C11 | 123.8 (3) | C21—P3—C33—C38 | 42.6 (2) |
C8—Fe1—C5—C11 | 76.6 (4) | Pd1—P3—C33—C38 | 176.50 (19) |
C9—Fe1—C5—C11 | 45.7 (3) | C38—C33—C34—C35 | 0.4 (4) |
C1—Fe1—C5—C11 | −115.6 (3) | P3—C33—C34—C35 | 179.9 (2) |
C2—Fe1—C6—C10 | 162.60 (17) | C33—C34—C35—C36 | 0.3 (5) |
C3—Fe1—C6—C10 | −164.2 (3) | C34—C35—C36—C37 | 0.0 (6) |
C7—Fe1—C6—C10 | −119.5 (3) | C35—C36—C37—C38 | −0.8 (6) |
C4—Fe1—C6—C10 | 44.7 (4) | C36—C37—C38—C33 | 1.5 (5) |
C8—Fe1—C6—C10 | −81.7 (2) | C34—C33—C38—C37 | −1.2 (4) |
C9—Fe1—C6—C10 | −38.0 (2) | P3—C33—C38—C37 | 179.3 (2) |
C5—Fe1—C6—C10 | 78.7 (2) |