metal-organic compounds
The CuII ion of the title complex, [Cu(NO3)(C14H24N4)]NO3.H2O, is five-coordinate and the geometry is distorted square pyramidal, with the four N atoms of the macrocyclic ligand equatorial and an O atom of the nitrato group axial. The tetradentate ligand adopts its most stable conformation, with two six-membered rings in chair forms and two five-membered rings in skew forms. The complex has the 3RS,11SR configuration for the two chiral N centers.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (SHELXL table format) |
CCDC reference: 130332