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The Co-S distances in the title compounds, [Co(C4H7N2O2)2(C9H13N)(C6H5S)] and [Co(C4H7N2O2)2(C9H13N)(C7H7OS)], are 2.2800 (8) and 2.2885 (15) Å, respectively. The electron-donating substituent on the para position of the arylthiolate lengthens the Co-S bond.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, 1, 2

fcf

Structure factor file (CIF format)
Contains datablock 1

fcf

Structure factor file (CIF format)
Contains datablock 2

CCDC references: 130208; 130209

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