Tetra­methyl­ammonium chloro­diphenylthio­cyanato­antimonate(III)

The crystal structure of the title compound, (C₄H₁₂N)[Sb(C₆H₅)₂Cl(NCS)], contains two cations and two anions in the asymmetric unit. The Sb atom exhibits a distorted pseudo-trigonal-bipyramidal coordination, with the phenyl groups and the lone pair of electrons in equatorial positions and N-bonded thio­cyanate and Cl^- ligands in axial positions.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.008 Å
• R factor = 0.039
• wR factor = 0.100
• Data-to-parameter ratio = 17.7

checkCIF/PLATON results

No syntax errors found



Alert level B
            Crystal system given = Triclinic
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        N1A
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C1A

Alert level C
PLAT022_ALERT_3_C Ratio Unique / Expected Reflections too Low ....       0.93
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT155_ALERT_4_C The Triclinic Unitcell is NOT Reduced ..........          ?
PLAT199_ALERT_1_C Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_C Check the Reported _diffrn_ambient_temperature .        293 K
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         N1
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C1
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         N2
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        N2A
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         32
            CL1A-SB2 -N1A -C1A   118.50  1.50   1.555   1.555   1.555   1.555

   0 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
  10 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   4 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: CAD-4 EXPRESS (Enraf–Nonius, 1994); cell refinement: CAD-4 EXPRESS; data reduction: XCAD4, PSI and EAC in CAD-4 EXPRESS; program(s) used to solve structure: SIR92 (Altomare et al., 1993); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

Tetramethylammonium chlorodiphenylthiocyanatoantimonate(III)

Crystal data

(C4H12N)[Sb(C6H5)2Cl(NCS)]	Z = 4
Mr = 443.65	F(000) = 888
Triclinic, P1	Dx = 1.507 Mg m^−3
Hall symbol: -P 1	Melting point: 144(1) K
a = 11.245 (2) Å	Mo Kα radiation, λ = 0.71073 Å
b = 12.354 (3) Å	Cell parameters from 25 reflections
c = 15.226 (3) Å	θ = 3.2–26°
α = 112.05 (2)°	µ = 1.65 mm^−1
β = 92.83 (3)°	T = 293 K
γ = 86.44 (3)°	Prism, white
V = 1955.9 (8) Å^3	0.36 × 0.32 × 0.26 mm

Data collection

Enraf–Nonius CAD-4 diffractometer	6983 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.030
Graphite monochromator	θmax = 26.0°, θmin = 3.2°
ω scans	h = −13→13
Absorption correction: empirical (using intensity measurements) via ψ scan (North et al., 1968)	k = −15→14
Tmin = 0.546, Tmax = 0.648	l = 0→18
7524 measured reflections	3 standard reflections every 180 min
7175 independent reflections	intensity decay: none

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.039	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.100	H-atom parameters constrained
S = 1.29	w = 1/[σ^2(Fo^2) + 3.4332P] where P = (Fo^2 + 2Fc^2)/3
7175 reflections	(Δ/σ)max = 0.010
405 parameters	Δρmax = 0.61 e Å^−3
0 restraints	Δρmin = −0.70 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Sb1	0.08155 (3)	0.57424 (3)	0.35023 (2)	0.05092 (10)
Cl1	0.26988 (12)	0.58217 (13)	0.45802 (9)	0.0685 (3)
S1	−0.30442 (12)	0.56372 (15)	0.17287 (11)	0.0748 (4)
N1	−0.0770 (4)	0.5370 (4)	0.2364 (4)	0.0740 (12)
C1	−0.1701 (4)	0.5488 (4)	0.2110 (3)	0.0521 (10)
C2	0.1964 (4)	0.5463 (4)	0.2345 (3)	0.0499 (10)
C3	0.1799 (5)	0.4596 (4)	0.1459 (3)	0.0601 (12)
H3	0.1157	0.4119	0.1349	0.072*
C4	0.2567 (6)	0.4427 (5)	0.0736 (4)	0.0703 (14)
H4	0.2450	0.3829	0.0150	0.084*
C5	0.3505 (5)	0.5143 (6)	0.0883 (4)	0.0754 (16)
H5	0.4024	0.5034	0.0397	0.090*
C6	0.3671 (5)	0.6023 (5)	0.1758 (4)	0.0708 (14)
H6	0.4302	0.6514	0.1860	0.085*
C7	0.2912 (4)	0.6179 (4)	0.2474 (4)	0.0600 (12)
H7	0.3035	0.6776	0.3060	0.072*
C8	0.0672 (4)	0.3949 (4)	0.3321 (3)	0.0488 (10)
C9	−0.0296 (4)	0.3646 (5)	0.3688 (4)	0.0612 (12)
H9	−0.0860	0.4224	0.4010	0.073*
C10	−0.0444 (5)	0.2507 (5)	0.3589 (4)	0.0713 (14)
H10	−0.1099	0.2322	0.3847	0.086*
C11	0.0376 (6)	0.1651 (5)	0.3110 (4)	0.0737 (15)
H11	0.0274	0.0878	0.3032	0.088*
C12	0.1357 (5)	0.1934 (5)	0.2742 (4)	0.0673 (13)
H12	0.1917	0.1352	0.2420	0.081*
C13	0.1508 (4)	0.3073 (4)	0.2850 (3)	0.0550 (11)
H13	0.2175	0.3259	0.2606	0.066*
Sb2	0.62169 (3)	−0.10731 (3)	0.13780 (2)	0.05222 (10)
Cl1A	0.79191 (11)	−0.09915 (12)	0.03022 (9)	0.0637 (3)
S1A	0.27174 (16)	−0.05862 (16)	0.34197 (14)	0.0905 (5)
N1A	0.4802 (5)	−0.0836 (5)	0.2534 (4)	0.0900 (16)
C1A	0.3965 (4)	−0.0727 (4)	0.2884 (3)	0.0512 (10)
C2A	0.7536 (4)	−0.0925 (4)	0.2476 (3)	0.0547 (11)
C3A	0.7404 (6)	−0.0186 (5)	0.3402 (4)	0.0741 (15)
H3A	0.6724	0.0305	0.3579	0.089*
C4A	0.8304 (7)	−0.0174 (7)	0.4083 (4)	0.092 (2)
H4A	0.8221	0.0334	0.4710	0.110*
C5A	0.9299 (7)	−0.0907 (6)	0.3827 (5)	0.0875 (19)
H5A	0.9882	−0.0904	0.4282	0.105*
C6A	0.9436 (6)	−0.1636 (6)	0.2912 (5)	0.0803 (17)
H6A	1.0118	−0.2123	0.2738	0.096*
C7A	0.8564 (5)	−0.1653 (4)	0.2246 (4)	0.0627 (12)
H7A	0.8661	−0.2166	0.1622	0.075*
C8A	0.5831 (4)	0.0757 (4)	0.1698 (3)	0.0481 (9)
C9A	0.4769 (4)	0.1090 (4)	0.1345 (4)	0.0601 (12)
H9A	0.4249	0.0522	0.0984	0.072*
C10A	0.4472 (5)	0.2261 (5)	0.1523 (4)	0.0655 (13)
H10A	0.3759	0.2473	0.1280	0.079*
C11A	0.5230 (5)	0.3098 (5)	0.2055 (4)	0.0663 (13)
H11A	0.5026	0.3882	0.2181	0.080*
C12A	0.6293 (5)	0.2789 (4)	0.2405 (4)	0.0661 (13)
H12A	0.6807	0.3363	0.2765	0.079*
C13A	0.6595 (4)	0.1624 (4)	0.2221 (3)	0.0560 (11)
H13A	0.7320	0.1418	0.2450	0.067*
N2	0.1508 (3)	0.7913 (3)	0.0114 (3)	0.0521 (9)
C14	0.1185 (5)	0.9045 (5)	0.0880 (4)	0.0682 (14)
H14A	0.0333	0.9154	0.0909	0.082*
H14B	0.1507	0.9670	0.0750	0.082*
H14C	0.1508	0.9044	0.1475	0.082*
C15	0.1066 (6)	0.6933 (5)	0.0331 (5)	0.0776 (16)
H15A	0.0213	0.7011	0.0365	0.093*
H15B	0.1406	0.6953	0.0927	0.093*
H15C	0.1293	0.6203	−0.0160	0.093*
C16	0.0959 (5)	0.7899 (5)	−0.0806 (4)	0.0703 (14)
H16A	0.1189	0.7178	−0.1306	0.084*
H16B	0.1231	0.8543	−0.0937	0.084*
H16C	0.0107	0.7966	−0.0764	0.084*
C17	0.2833 (5)	0.7767 (6)	0.0028 (4)	0.0793 (16)
H17A	0.3196	0.7811	0.0623	0.095*
H17B	0.3115	0.8376	−0.0145	0.095*
H17C	0.3038	0.7020	−0.0452	0.095*
N2A	0.6149 (4)	0.7093 (3)	0.4756 (3)	0.0543 (9)
C14A	0.7463 (5)	0.7181 (6)	0.4804 (4)	0.0799 (16)
H14D	0.7832	0.6585	0.5002	0.096*
H14E	0.7668	0.7936	0.5252	0.096*
H14F	0.7739	0.7079	0.4190	0.096*
C15A	0.5830 (5)	0.5900 (5)	0.4099 (4)	0.0703 (14)
H15D	0.4979	0.5848	0.4065	0.084*
H15E	0.6189	0.5329	0.4330	0.084*
H15F	0.6115	0.5755	0.3479	0.084*
C16A	0.5716 (6)	0.7285 (6)	0.5717 (4)	0.0808 (17)
H16D	0.4865	0.7241	0.5688	0.097*
H16E	0.5931	0.8043	0.6154	0.097*
H16F	0.6075	0.6695	0.5927	0.097*
C17A	0.5573 (7)	0.7968 (6)	0.4399 (6)	0.105 (2)
H17D	0.5866	0.7838	0.3784	0.126*
H17E	0.5754	0.8741	0.4828	0.126*
H17F	0.4725	0.7893	0.4354	0.126*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Sb1	0.04983 (17)	0.04558 (17)	0.05355 (18)	0.00586 (12)	0.00097 (13)	0.01548 (13)
Cl1	0.0593 (7)	0.0877 (9)	0.0616 (7)	−0.0102 (6)	−0.0101 (6)	0.0318 (7)
S1	0.0544 (7)	0.1031 (11)	0.0689 (8)	−0.0083 (7)	−0.0100 (6)	0.0351 (8)
N1	0.062 (3)	0.067 (3)	0.087 (3)	0.009 (2)	−0.012 (2)	0.026 (2)
C1	0.061 (3)	0.051 (2)	0.041 (2)	−0.004 (2)	0.003 (2)	0.0136 (19)
C2	0.053 (2)	0.046 (2)	0.053 (2)	0.0004 (19)	−0.0026 (19)	0.0217 (19)
C3	0.073 (3)	0.054 (3)	0.054 (3)	−0.009 (2)	0.000 (2)	0.021 (2)
C4	0.093 (4)	0.064 (3)	0.055 (3)	−0.003 (3)	0.006 (3)	0.023 (2)
C5	0.077 (4)	0.090 (4)	0.074 (4)	0.011 (3)	0.020 (3)	0.047 (3)
C6	0.058 (3)	0.082 (4)	0.088 (4)	−0.011 (3)	−0.003 (3)	0.049 (3)
C7	0.063 (3)	0.060 (3)	0.063 (3)	−0.012 (2)	−0.011 (2)	0.029 (2)
C8	0.046 (2)	0.051 (2)	0.048 (2)	−0.0032 (18)	0.0000 (18)	0.0178 (19)
C9	0.051 (3)	0.066 (3)	0.064 (3)	−0.003 (2)	0.007 (2)	0.021 (2)
C10	0.075 (4)	0.074 (4)	0.069 (3)	−0.024 (3)	−0.001 (3)	0.030 (3)
C11	0.101 (4)	0.054 (3)	0.068 (3)	−0.025 (3)	−0.010 (3)	0.023 (3)
C12	0.081 (4)	0.054 (3)	0.063 (3)	0.000 (3)	0.001 (3)	0.018 (2)
C13	0.057 (3)	0.053 (3)	0.055 (3)	0.000 (2)	0.005 (2)	0.021 (2)
Sb2	0.04662 (17)	0.04741 (17)	0.06072 (19)	−0.00935 (12)	−0.00460 (13)	0.01767 (14)
Cl1A	0.0581 (7)	0.0707 (8)	0.0639 (7)	0.0028 (6)	0.0075 (5)	0.0272 (6)
S1A	0.0833 (11)	0.0826 (10)	0.1068 (13)	0.0086 (8)	0.0412 (10)	0.0340 (9)
N1A	0.082 (4)	0.092 (4)	0.108 (4)	−0.020 (3)	0.013 (3)	0.047 (3)
C1A	0.058 (3)	0.046 (2)	0.049 (2)	0.000 (2)	−0.001 (2)	0.0176 (19)
C2A	0.061 (3)	0.054 (3)	0.057 (3)	−0.014 (2)	−0.006 (2)	0.028 (2)
C3A	0.078 (4)	0.082 (4)	0.064 (3)	−0.012 (3)	0.006 (3)	0.027 (3)
C4A	0.115 (6)	0.111 (5)	0.051 (3)	−0.036 (5)	−0.011 (3)	0.028 (3)
C5A	0.094 (5)	0.098 (5)	0.087 (5)	−0.022 (4)	−0.028 (4)	0.054 (4)
C6A	0.084 (4)	0.074 (4)	0.094 (5)	−0.010 (3)	−0.018 (3)	0.046 (4)
C7A	0.070 (3)	0.053 (3)	0.070 (3)	−0.004 (2)	−0.012 (3)	0.030 (2)
C8A	0.045 (2)	0.049 (2)	0.048 (2)	−0.0009 (18)	0.0022 (18)	0.0166 (19)
C9A	0.054 (3)	0.062 (3)	0.060 (3)	−0.001 (2)	−0.004 (2)	0.018 (2)
C10A	0.055 (3)	0.071 (3)	0.067 (3)	0.018 (2)	0.005 (2)	0.025 (3)
C11A	0.077 (3)	0.055 (3)	0.063 (3)	0.015 (3)	0.013 (3)	0.019 (2)
C12A	0.079 (4)	0.044 (3)	0.065 (3)	−0.007 (2)	−0.002 (3)	0.009 (2)
C13A	0.049 (2)	0.059 (3)	0.059 (3)	−0.001 (2)	−0.004 (2)	0.022 (2)
N2	0.051 (2)	0.051 (2)	0.050 (2)	−0.0028 (16)	0.0004 (16)	0.0144 (17)
C14	0.082 (4)	0.060 (3)	0.052 (3)	−0.001 (3)	0.002 (2)	0.009 (2)
C15	0.088 (4)	0.064 (3)	0.087 (4)	−0.008 (3)	0.017 (3)	0.032 (3)
C16	0.079 (4)	0.075 (3)	0.052 (3)	−0.011 (3)	−0.012 (2)	0.019 (3)
C17	0.056 (3)	0.104 (5)	0.082 (4)	−0.002 (3)	0.004 (3)	0.039 (4)
N2A	0.059 (2)	0.057 (2)	0.049 (2)	−0.0038 (18)	−0.0023 (17)	0.0216 (18)
C14A	0.062 (3)	0.098 (4)	0.078 (4)	−0.014 (3)	0.000 (3)	0.031 (3)
C15A	0.081 (4)	0.066 (3)	0.060 (3)	−0.014 (3)	0.002 (3)	0.017 (3)
C16A	0.083 (4)	0.088 (4)	0.060 (3)	0.001 (3)	0.012 (3)	0.014 (3)
C17A	0.127 (6)	0.083 (4)	0.115 (6)	−0.001 (4)	−0.035 (5)	0.054 (4)

Geometric parameters (Å, º)

Sb1—C8	2.143 (4)	C7A—H7A	0.9300
Sb1—C2	2.145 (5)	C8A—C13A	1.387 (6)
Sb1—N1	2.365 (5)	C8A—C9A	1.388 (6)
Sb1—Cl1	2.5981 (15)	C9A—C10A	1.390 (7)
S1—C1	1.617 (5)	C9A—H9A	0.9300
N1—C1	1.117 (6)	C10A—C11A	1.366 (8)
C2—C3	1.385 (6)	C10A—H10A	0.9300
C2—C7	1.387 (6)	C11A—C12A	1.376 (8)
C3—C4	1.377 (7)	C11A—H11A	0.9300
C3—H3	0.9300	C12A—C13A	1.383 (7)
C4—C5	1.375 (8)	C12A—H12A	0.9300
C4—H4	0.9300	C13A—H13A	0.9300
C5—C6	1.380 (8)	N2—C14	1.484 (6)
C5—H5	0.9300	N2—C15	1.486 (6)
C6—C7	1.368 (7)	N2—C16	1.497 (6)
C6—H6	0.9300	N2—C17	1.496 (6)
C7—H7	0.9300	C14—H14A	0.9600
C8—C9	1.381 (6)	C14—H14B	0.9600
C8—C13	1.387 (6)	C14—H14C	0.9600
C9—C10	1.378 (7)	C15—H15A	0.9600
C9—H9	0.9300	C15—H15B	0.9600
C10—C11	1.367 (8)	C15—H15C	0.9600
C10—H10	0.9300	C16—H16A	0.9600
C11—C12	1.383 (8)	C16—H16B	0.9600
C11—H11	0.9300	C16—H16C	0.9600
C12—C13	1.375 (7)	C17—H17A	0.9600
C12—H12	0.9300	C17—H17B	0.9600
C13—H13	0.9300	C17—H17C	0.9600
Sb2—C2A	2.143 (5)	N2A—C17A	1.485 (7)
Sb2—C8A	2.147 (4)	N2A—C14A	1.484 (7)
Sb2—N1A	2.355 (6)	N2A—C15A	1.491 (6)
Sb2—Cl1A	2.6105 (15)	N2A—C16A	1.493 (7)
S1A—C1A	1.625 (5)	C14A—H14D	0.9600
N1A—C1A	1.080 (7)	C14A—H14E	0.9600
C2A—C3A	1.371 (7)	C14A—H14F	0.9600
C2A—C7A	1.393 (7)	C15A—H15D	0.9600
C3A—C4A	1.410 (9)	C15A—H15E	0.9600
C3A—H3A	0.9300	C15A—H15F	0.9600
C4A—C5A	1.370 (10)	C16A—H16D	0.9600
C4A—H4A	0.9300	C16A—H16E	0.9600
C5A—C6A	1.355 (9)	C16A—H16F	0.9600
C5A—H5A	0.9300	C17A—H17D	0.9600
C6A—C7A	1.371 (7)	C17A—H17E	0.9600
C6A—H6A	0.9300	C17A—H17F	0.9600
C8—Sb1—C2	97.84 (17)	C8A—C9A—H9A	119.6
C8—Sb1—N1	84.25 (17)	C10A—C9A—H9A	119.6
C2—Sb1—N1	86.19 (17)	C11A—C10A—C9A	119.8 (5)
C8—Sb1—Cl1	88.83 (12)	C11A—C10A—H10A	120.1
C2—Sb1—Cl1	88.66 (12)	C9A—C10A—H10A	120.1
N1—Sb1—Cl1	170.74 (12)	C10A—C11A—C12A	120.4 (5)
C1—N1—Sb1	154.6 (4)	C10A—C11A—H11A	119.8
N1—C1—S1	179.1 (5)	C12A—C11A—H11A	119.8
C3—C2—C7	117.6 (5)	C11A—C12A—C13A	119.8 (5)
C3—C2—Sb1	122.9 (4)	C11A—C12A—H12A	120.1
C7—C2—Sb1	119.5 (4)	C13A—C12A—H12A	120.1
C4—C3—C2	121.4 (5)	C12A—C13A—C8A	120.9 (5)
C4—C3—H3	119.3	C12A—C13A—H13A	119.5
C2—C3—H3	119.3	C8A—C13A—H13A	119.5
C5—C4—C3	119.9 (5)	C14—N2—C15	110.0 (4)
C5—C4—H4	120.0	C14—N2—C16	109.3 (4)
C3—C4—H4	120.0	C15—N2—C16	109.6 (4)
C4—C5—C6	119.4 (5)	C14—N2—C17	109.8 (4)
C4—C5—H5	120.3	C15—N2—C17	109.4 (4)
C6—C5—H5	120.3	C16—N2—C17	108.8 (4)
C7—C6—C5	120.3 (5)	N2—C14—H14A	109.5
C7—C6—H6	119.9	N2—C14—H14B	109.5
C5—C6—H6	119.9	H14A—C14—H14B	109.5
C6—C7—C2	121.3 (5)	N2—C14—H14C	109.5
C6—C7—H7	119.3	H14A—C14—H14C	109.5
C2—C7—H7	119.3	H14B—C14—H14C	109.5
C9—C8—C13	118.3 (4)	N2—C15—H15A	109.5
C9—C8—Sb1	118.7 (3)	N2—C15—H15B	109.5
C13—C8—Sb1	123.1 (3)	H15A—C15—H15B	109.5
C10—C9—C8	121.5 (5)	N2—C15—H15C	109.5
C10—C9—H9	119.3	H15A—C15—H15C	109.5
C8—C9—H9	119.3	H15B—C15—H15C	109.5
C11—C10—C9	119.6 (5)	N2—C16—H16A	109.5
C11—C10—H10	120.2	N2—C16—H16B	109.5
C9—C10—H10	120.2	H16A—C16—H16B	109.5
C10—C11—C12	119.9 (5)	N2—C16—H16C	109.5
C10—C11—H11	120.1	H16A—C16—H16C	109.5
C12—C11—H11	120.1	H16B—C16—H16C	109.5
C13—C12—C11	120.3 (5)	N2—C17—H17A	109.5
C13—C12—H12	119.8	N2—C17—H17B	109.5
C11—C12—H12	119.8	H17A—C17—H17B	109.5
C12—C13—C8	120.4 (5)	N2—C17—H17C	109.5
C12—C13—H13	119.8	H17A—C17—H17C	109.5
C8—C13—H13	119.8	H17B—C17—H17C	109.5
C2A—Sb2—C8A	98.31 (17)	C17A—N2A—C14A	109.9 (5)
C2A—Sb2—N1A	86.1 (2)	C17A—N2A—C15A	108.9 (4)
C8A—Sb2—N1A	84.23 (18)	C14A—N2A—C15A	109.7 (4)
C2A—Sb2—Cl1A	88.35 (13)	C17A—N2A—C16A	110.5 (5)
C8A—Sb2—Cl1A	88.41 (12)	C14A—N2A—C16A	109.5 (4)
N1A—Sb2—Cl1A	170.06 (14)	C15A—N2A—C16A	108.3 (4)
C1A—N1A—Sb2	162.1 (5)	N2A—C14A—H14D	109.5
N1A—C1A—S1A	178.8 (5)	N2A—C14A—H14E	109.5
C3A—C2A—C7A	118.2 (5)	H14D—C14A—H14E	109.5
C3A—C2A—Sb2	123.5 (4)	N2A—C14A—H14F	109.5
C7A—C2A—Sb2	118.2 (4)	H14D—C14A—H14F	109.5
C2A—C3A—C4A	119.6 (6)	H14E—C14A—H14F	109.5
C2A—C3A—H3A	120.2	N2A—C15A—H15D	109.5
C4A—C3A—H3A	120.2	N2A—C15A—H15E	109.5
C5A—C4A—C3A	120.4 (6)	H15D—C15A—H15E	109.5
C5A—C4A—H4A	119.8	N2A—C15A—H15F	109.5
C3A—C4A—H4A	119.8	H15D—C15A—H15F	109.5
C6A—C5A—C4A	120.2 (6)	H15E—C15A—H15F	109.5
C6A—C5A—H5A	119.9	N2A—C16A—H16D	109.5
C4A—C5A—H5A	119.9	N2A—C16A—H16E	109.5
C5A—C6A—C7A	119.7 (6)	H16D—C16A—H16E	109.5
C5A—C6A—H6A	120.1	N2A—C16A—H16F	109.5
C7A—C6A—H6A	120.1	H16D—C16A—H16F	109.5
C6A—C7A—C2A	121.9 (6)	H16E—C16A—H16F	109.5
C6A—C7A—H7A	119.1	N2A—C17A—H17D	109.5
C2A—C7A—H7A	119.1	N2A—C17A—H17E	109.5
C13A—C8A—C9A	118.1 (4)	H17D—C17A—H17E	109.5
C13A—C8A—Sb2	123.7 (3)	N2A—C17A—H17F	109.5
C9A—C8A—Sb2	118.2 (3)	H17D—C17A—H17F	109.5
C8A—C9A—C10A	120.9 (5)	H17E—C17A—H17F	109.5
C2—Sb1—N1—C1	−146.0 (11)	C8A—Sb2—N1A—C1A	76.0 (16)
C8—Sb1—C2—C3	43.7 (4)	Cl1A—Sb2—N1A—C1A	118.5 (15)
N1—Sb1—C2—C3	−39.9 (4)	C8A—Sb2—C2A—C3A	46.3 (4)
Cl1—Sb1—C2—C3	132.3 (4)	N1A—Sb2—C2A—C3A	−37.3 (4)
C8—Sb1—C2—C7	−136.8 (4)	Cl1A—Sb2—C2A—C3A	134.4 (4)
N1—Sb1—C2—C7	139.5 (4)	C8A—Sb2—C2A—C7A	−136.4 (4)
Cl1—Sb1—C2—C7	−48.2 (4)	N1A—Sb2—C2A—C7A	140.0 (4)
C7—C2—C3—C4	1.8 (7)	Cl1A—Sb2—C2A—C7A	−48.2 (4)
Sb1—C2—C3—C4	−178.8 (4)	C7A—C2A—C3A—C4A	0.6 (8)
C2—C3—C4—C5	−1.4 (8)	Sb2—C2A—C3A—C4A	178.0 (4)
C3—C4—C5—C6	0.3 (9)	C2A—C3A—C4A—C5A	−0.8 (9)
C4—C5—C6—C7	0.4 (9)	C3A—C4A—C5A—C6A	1.1 (10)
C5—C6—C7—C2	0.0 (8)	C4A—C5A—C6A—C7A	−1.1 (10)
C3—C2—C7—C6	−1.1 (7)	C5A—C6A—C7A—C2A	1.0 (9)
Sb1—C2—C7—C6	179.4 (4)	C3A—C2A—C7A—C6A	−0.7 (8)
C2—Sb1—C8—C9	−157.6 (4)	Sb2—C2A—C7A—C6A	−178.2 (4)
N1—Sb1—C8—C9	−72.3 (4)	C2A—Sb2—C8A—C13A	20.5 (4)
Cl1—Sb1—C8—C9	113.9 (4)	N1A—Sb2—C8A—C13A	105.7 (4)
C2—Sb1—C8—C13	22.4 (4)	Cl1A—Sb2—C8A—C13A	−67.6 (4)
N1—Sb1—C8—C13	107.7 (4)	C2A—Sb2—C8A—C9A	−161.0 (4)
Cl1—Sb1—C8—C13	−66.1 (4)	N1A—Sb2—C8A—C9A	−75.8 (4)
C13—C8—C9—C10	−0.5 (7)	Cl1A—Sb2—C8A—C9A	110.9 (4)
Sb1—C8—C9—C10	179.5 (4)	C13A—C8A—C9A—C10A	−1.0 (7)
C8—C9—C10—C11	−0.6 (8)	Sb2—C8A—C9A—C10A	−179.6 (4)
C9—C10—C11—C12	1.0 (9)	C8A—C9A—C10A—C11A	−0.2 (8)
C10—C11—C12—C13	−0.4 (8)	C9A—C10A—C11A—C12A	0.9 (8)
C11—C12—C13—C8	−0.7 (8)	C10A—C11A—C12A—C13A	−0.3 (8)
C9—C8—C13—C12	1.1 (7)	C11A—C12A—C13A—C8A	−1.0 (8)
Sb1—C8—C13—C12	−178.9 (4)	C9A—C8A—C13A—C12A	1.6 (7)
C2A—Sb2—N1A—C1A	174.8 (17)	Sb2—C8A—C13A—C12A	−179.9 (4)