Tris­[μ-bis­(di­phenyl­phosphino)­methane-κ²P:P′]­di-μ₃-sulfanido-trisilver(I) hexa­fluoro­antimonate di­chloro­methane disolvate

The μ₃-SH dicapped trisilver compound [Ag₃(μ-dppm)₃(μ₃-SH)₂]SbF₆·2CH₂Cl₂ [dppm is bis­(di­phenyl­phosphino)­methane, C₂₅H₂₂P₂], formed by the reaction between [Ag₂(μ-dppm)₂(MeCN)₂](SbF₆)₂ and [Pd(phen)(tdt)] (phen is o-phenanthroline and tdt is toluene-3,4-­di­thiol­ate) through the disruption of C—S bonds, exhibits a trigonal bipyramid core, with two μ₃-SH ligands at the apices. The Ag atoms are located in tetrahedral environments with P₂S₂ donors.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.019 Å
• R factor = 0.080
• wR factor = 0.210
• Data-to-parameter ratio = 17.5

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level C:



PLAT_420  Alert C D-H Without Acceptor       S1     -   H6A               ?

PLAT_420  Alert C D-H Without Acceptor       S2     -   H6B               ?

PLAT_731  Alert C Bond    Calc   1.726(19), Rep    1.726(5) ....       3.80 su-Ratio
                     C4   -CL02    1.555   1.555

PLAT_731  Alert C Bond    Calc     1.72(2), Rep    1.720(5) ....       4.00 su-Ratio
                     C5   -CL03    1.555   1.555

PLAT_731  Alert C Bond    Calc     1.72(2), Rep    1.721(5) ....       4.00 su-Ratio
                     C5   -CL04    1.555   1.555


 0 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 5 Alert Level C = Please check

---

S1. Comment

There is considerable interest in designing novel metal complexes with mixed phosphorus- and sulfur-containing ligands owing to their unique optical and optoelectronic properties (Yam et al., 2000; Tang et al., 2002). It is well known that S²⁻ and SH⁻ as versatile coordination groups could exhibit various bonding modes to produce metal cluster complexes with diverse structural topologies (Kitagawa et al., 1990; Su et al., 1998). Here we reported the crystal structure of a trisilver complex, [Ag₃(µ-dppm)₃(µ₃-S)₂]SbF₆, (I), which resulted from the self-assembly between the metal components [Pd(phen)(tdt)] (phen is phenanthroline and tdt is 3,4-toluenedithiolate) and [Ag₂(µ₂-dppm)₂(MeCN)₄](SbF₆)₂ through the disruption of C—S of tdt.

A perspective drawing of the complex cation with the atomic numbering scheme is depicted in Fig. 1 and selected bonding parameters are presented in Table 1. The complex consists of the coordination [Ag₃(µ-dppm)₃(µ₃-S)₂]⁺ cation, an SbF₆⁻ anion and dichloromethane solvent molecules. The µ₃-SH dicapped trisilver complex exhibits a trigonal bipyramid coordination core, with two µ₃-SH ligands in the apices and the three Ag atoms in equatorial sites. The Ag atoms are located at distorted tetrahedral environments with a P₂S₂ chromophore. The Ag—Ag distances are in the range of 3.337 (1)–3.477 (1) Å, which are shorter than the sum of van der Waals radii for two Ag atoms, indicating a weak metal–metal contact that is operative in the complex. The Ag—S distances are in the range 2.661 (3)–2.825 (3) Å and the Ag—P bond distances are in the range 2.465 (2)–2.491 (3) Å, close to those found in other similar complexes of silver (Albano et al., 1999; Meyer et al., 1989; Lang et al., 1993; Henkel et al., 1988).

S2. Experimental

The title compound was isolated by the reaction between [Ag₂(µ₂-dppm)₂(MeCN)₄](SbF₆)₂ (Diez et al., 1987) and [Pd(phen)(tdt)] (Scott & Richard, 1996) in an equimolar ratio in dichloromethane under anaerobic condition for 12 h. Well shaped pale yellow crystals suitable for X-ray diffraction study were grown by slow diffusion of diethyl ether into a dichloromethane solution at room temperature.

S3. Refinement

All H atoms were included in calculated positions, with C—H distances of 0.93 (sp²) and 0.97 Å (sp³), and H–S distances of 1.20 Å. They were included in the refinement in riding motion approximation with U_iso = 1.2U_eq (1.5U_eq for sp³) of the carrier atom.

Computing details

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1994); data reduction: XPREP (Siemens, 1994); program(s) used to solve structure: SHELXTL (Siemens, 1994); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Figures

Fig. 1. A view of (I) with the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.

(I)

Crystal data

[Ag3(C25H22P2)3(HS)2]SbF6·2CH2Cl2	F(000) = 3880
Mr = 1948.45	Dx = 1.597 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 8192 reflections
a = 16.0813 (1) Å	θ = 1.3–25.0°
b = 18.0049 (2) Å	µ = 1.40 mm^−1
c = 28.1089 (3) Å	T = 293 K
β = 95.417 (1)°	Prism, pale yellow
V = 8102.36 (13) Å^3	0.72 × 0.60 × 0.46 mm
Z = 4

Data collection

Siemens SMART CCD diffractometer	14088 independent reflections
Radiation source: fine-focus sealed tube	10084 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.047
ω scans	θmax = 25.0°, θmin = 1.3°
Absorption correction: empirical (using intensity measurements) (SADABS; Sheldrick, 1996)	h = −10→19
Tmin = 0.354, Tmax = 0.525	k = −13→21
25151 measured reflections	l = −33→32

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.080	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.210	H-atom parameters constrained
S = 1.21	w = 1/[σ^2(Fo^2) + (0.0537P)^2 + 77.3298P] where P = (Fo^2 + 2Fc^2)/3
14088 reflections	(Δ/σ)max = 0.006
807 parameters	Δρmax = 1.50 e Å^−3
4 restraints	Δρmin = −1.23 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Sb	0.43562 (5)	0.77857 (6)	0.55439 (3)	0.0669 (3)
Ag1	0.85356 (5)	0.82543 (5)	0.75823 (3)	0.0451 (2)
Ag2	0.95905 (5)	0.82429 (5)	0.66155 (3)	0.0502 (2)
Ag3	1.06476 (5)	0.78051 (5)	0.77001 (3)	0.0504 (2)
S1	0.93674 (15)	0.70518 (14)	0.72450 (9)	0.0439 (6)
H6A	0.9205	0.6405	0.7192	0.053*
S2	0.98644 (16)	0.91081 (14)	0.73817 (9)	0.0459 (6)
H6B	1.0032	0.9754	0.7436	0.055*
P1	0.86185 (14)	0.82298 (15)	0.84624 (8)	0.0375 (5)
P2	0.72572 (15)	0.81252 (14)	0.70314 (8)	0.0378 (5)
P3	0.82164 (16)	0.83775 (16)	0.61517 (9)	0.0431 (6)
P4	1.09318 (15)	0.80107 (15)	0.62814 (9)	0.0399 (6)
P5	1.19248 (15)	0.77796 (15)	0.72685 (9)	0.0395 (6)
P6	1.04429 (15)	0.75885 (15)	0.85566 (9)	0.0398 (6)
C1	0.9362 (5)	0.7533 (6)	0.8724 (3)	0.041 (2)
H1A	0.9144	0.7045	0.8636	0.050*
H1B	0.9382	0.7572	0.9070	0.050*
C2	0.7399 (6)	0.7836 (5)	0.6414 (3)	0.039 (2)
H2A	0.7547	0.7314	0.6413	0.047*
H2B	0.6875	0.7896	0.6217	0.047*
C3	1.1890 (6)	0.8241 (6)	0.6673 (3)	0.043 (2)
H3A	1.1918	0.8775	0.6718	0.051*
H3B	1.2375	0.8091	0.6516	0.051*
C4	1.0629 (19)	1.0853 (8)	0.6681 (7)	0.234 (15)*
H4A	1.0891	1.0634	0.6972	0.281*
H4B	1.0042	1.0926	0.6723	0.281*
C5	1.1936 (11)	0.5080 (14)	0.4072 (7)	0.190 (11)*
H5A	1.2415	0.4844	0.4245	0.228*
H5B	1.2126	0.5542	0.3942	0.228*
C111	0.8910 (6)	0.9090 (6)	0.8772 (4)	0.048 (2)
C112	0.8949 (8)	0.9738 (7)	0.8509 (4)	0.064 (3)
H11B	0.8838	0.9723	0.8179	0.077*
C113	0.9155 (10)	1.0416 (8)	0.8735 (6)	0.090 (5)
H11E	0.9192	1.0846	0.8555	0.108*
C114	0.9304 (10)	1.0443 (9)	0.9230 (6)	0.091 (5)
H11D	0.9441	1.0891	0.9382	0.109*
C115	0.9250 (9)	0.9810 (8)	0.9491 (5)	0.075 (4)
H11C	0.9337	0.9829	0.9823	0.091*
C116	0.9065 (7)	0.9141 (7)	0.9268 (4)	0.062 (3)
H11A	0.9044	0.8713	0.9452	0.075*
C121	0.7649 (6)	0.7946 (6)	0.8712 (4)	0.045 (2)
C122	0.7619 (7)	0.7718 (7)	0.9189 (4)	0.060 (3)
H12A	0.8107	0.7701	0.9395	0.072*
C123	0.6869 (7)	0.7519 (8)	0.9353 (5)	0.074 (4)
H12D	0.6857	0.7364	0.9668	0.088*
C124	0.6142 (8)	0.7547 (9)	0.9060 (5)	0.081 (4)
H12E	0.5640	0.7413	0.9175	0.097*
C125	0.6157 (7)	0.7773 (8)	0.8597 (5)	0.073 (4)
H12C	0.5663	0.7793	0.8397	0.088*
C126	0.6903 (6)	0.7973 (7)	0.8425 (4)	0.058 (3)
H12B	0.6902	0.8129	0.8110	0.069*
C211	0.6545 (6)	0.8904 (5)	0.6991 (3)	0.040 (2)
C212	0.6682 (7)	0.9479 (7)	0.7316 (4)	0.061 (3)
H21B	0.7141	0.9453	0.7543	0.073*
C213	0.6155 (9)	1.0098 (7)	0.7314 (6)	0.080 (4)
H21D	0.6260	1.0476	0.7537	0.096*
C214	0.5482 (10)	1.0133 (8)	0.6978 (6)	0.085 (5)
H21C	0.5136	1.0548	0.6967	0.102*
C215	0.5312 (9)	0.9569 (9)	0.6659 (5)	0.085 (4)
H21E	0.4835	0.9586	0.6445	0.102*
C216	0.5856 (7)	0.8971 (7)	0.6658 (4)	0.066 (3)
H21A	0.5755	0.8603	0.6427	0.079*
C221	0.6650 (6)	0.7331 (5)	0.7222 (3)	0.038 (2)
C222	0.7083 (7)	0.6687 (6)	0.7358 (4)	0.054 (3)
H22B	0.7660	0.6667	0.7351	0.065*
C223	0.6661 (9)	0.6082 (7)	0.7503 (5)	0.077 (4)
H22D	0.6958	0.5653	0.7594	0.092*
C224	0.5822 (8)	0.6091 (8)	0.7518 (5)	0.073 (4)*
H22E	0.5549	0.5667	0.7611	0.088*
C225	0.5375 (8)	0.6714 (8)	0.7399 (6)	0.084 (4)
H22C	0.4802	0.6725	0.7420	0.100*
C226	0.5793 (7)	0.7342 (7)	0.7242 (5)	0.066 (3)
H22A	0.5491	0.7767	0.7152	0.079*
C311	0.8260 (7)	0.7952 (7)	0.5559 (4)	0.056 (3)
C312	0.8098 (8)	0.8336 (9)	0.5136 (4)	0.078 (4)
H31B	0.7885	0.8816	0.5133	0.093*
C313	0.8268 (10)	0.7972 (14)	0.4695 (4)	0.120 (8)
H31D	0.8151	0.8213	0.4404	0.144*
C314	0.8590 (14)	0.7298 (13)	0.4710 (9)	0.127 (7)*
H31F	0.8723	0.7083	0.4426	0.153*
C315	0.8737 (11)	0.6903 (11)	0.5123 (7)	0.111 (6)*
H31E	0.8941	0.6421	0.5120	0.133*
C316	0.8570 (9)	0.7246 (8)	0.5552 (5)	0.076 (4)
H31A	0.8674	0.6987	0.5838	0.091*
C321	0.7754 (7)	0.9291 (6)	0.6047 (4)	0.054 (3)
C322	0.8136 (9)	0.9905 (7)	0.6266 (5)	0.072 (4)
H32B	0.8640	0.9850	0.6454	0.086*
C323	0.7768 (12)	1.0617 (8)	0.6207 (6)	0.093 (5)
H32D	0.8020	1.1029	0.6359	0.112*
C324	0.7040 (11)	1.0688 (11)	0.5923 (6)	0.100 (5)*
H32E	0.6806	1.1158	0.5880	0.120*
C325	0.6638 (9)	1.0102 (9)	0.5701 (5)	0.088 (5)
H32A	0.6143	1.0172	0.5507	0.106*
C326	0.6983 (8)	0.9389 (8)	0.5769 (5)	0.074 (4)
H32C	0.6703	0.8979	0.5631	0.089*
C411	1.1048 (6)	0.8548 (6)	0.5741 (3)	0.045 (2)
C412	1.0348 (8)	0.8602 (9)	0.5416 (5)	0.082 (4)
H41C	0.9857	0.8366	0.5482	0.098*
C413	1.0365 (10)	0.9000 (9)	0.4995 (6)	0.088 (4)*
H41E	0.9890	0.9031	0.4780	0.106*
C414	1.1080 (10)	0.9346 (9)	0.4900 (5)	0.088 (4)
H41A	1.1089	0.9624	0.4622	0.105*
C415	1.1766 (10)	0.9291 (9)	0.5198 (5)	0.095 (5)
H41D	1.2256	0.9520	0.5124	0.114*
C416	1.1752 (8)	0.8891 (8)	0.5621 (4)	0.073 (4)
H41B	1.2237	0.8858	0.5828	0.088*
C421	1.1129 (6)	0.7062 (5)	0.6093 (4)	0.042 (2)
C422	1.0635 (8)	0.6485 (7)	0.6228 (5)	0.065 (3)
H42B	1.0196	0.6586	0.6410	0.077*
C423	1.0779 (10)	0.5767 (8)	0.6097 (6)	0.089 (4)
H42D	1.0433	0.5390	0.6188	0.106*
C424	1.1425 (10)	0.5599 (8)	0.5834 (5)	0.082 (4)
H42E	1.1528	0.5110	0.5751	0.098*
C425	1.1919 (9)	0.6160 (8)	0.5693 (6)	0.086 (4)
H42C	1.2359	0.6048	0.5513	0.103*
C426	1.1777 (8)	0.6894 (7)	0.5814 (5)	0.065 (3)
H42A	1.2111	0.7271	0.5710	0.078*
C511	1.2820 (6)	0.8242 (6)	0.7601 (4)	0.046 (2)
C512	1.3536 (7)	0.8471 (6)	0.7396 (4)	0.060 (3)
H51C	1.3567	0.8415	0.7070	0.072*
C513	1.4206 (7)	0.8783 (7)	0.7681 (6)	0.075 (4)
H51B	1.4691	0.8922	0.7548	0.090*
C514	1.4140 (9)	0.8883 (7)	0.8159 (5)	0.077 (4)
H51D	1.4584	0.9093	0.8349	0.093*
C515	1.3443 (9)	0.8684 (8)	0.8361 (5)	0.076 (4)*
H51E	1.3406	0.8760	0.8685	0.092*
C516	1.2786 (7)	0.8367 (6)	0.8080 (4)	0.056 (3)
H51A	1.2307	0.8234	0.8220	0.067*
C521	1.2316 (6)	0.6843 (6)	0.7174 (4)	0.046 (2)
C522	1.1877 (9)	0.6255 (7)	0.7346 (5)	0.071 (4)
H52B	1.1375	0.6340	0.7476	0.086*
C523	1.2197 (11)	0.5525 (10)	0.7322 (6)	0.100 (5)*
H52E	1.1908	0.5131	0.7444	0.120*
C524	1.2906 (10)	0.5395 (10)	0.7128 (6)	0.089 (4)*
H52D	1.3112	0.4912	0.7121	0.107*
C525	1.3336 (9)	0.5960 (9)	0.6938 (6)	0.087 (5)
H52C	1.3818	0.5860	0.6790	0.105*
C526	1.3042 (7)	0.6698 (7)	0.6967 (5)	0.070 (3)
H52A	1.3340	0.7087	0.6846	0.083*
C611	1.0875 (6)	0.6706 (6)	0.8791 (4)	0.049 (3)
C612	1.1532 (8)	0.6397 (7)	0.8590 (5)	0.073 (4)
H61A	1.1757	0.6644	0.8341	0.088*
C613	1.1876 (11)	0.5723 (10)	0.8747 (6)	0.103 (5)*
H61E	1.2330	0.5526	0.8609	0.123*
C614	1.1540 (9)	0.5353 (8)	0.9105 (6)	0.089 (5)
H61C	1.1762	0.4896	0.9207	0.107*
C615	1.0884 (9)	0.5642 (8)	0.9317 (5)	0.082 (4)
H61D	1.0656	0.5383	0.9560	0.099*
C616	1.0560 (8)	0.6323 (7)	0.9169 (5)	0.067 (3)
H61B	1.0128	0.6530	0.9322	0.081*
C621	1.0957 (6)	0.8292 (6)	0.8955 (3)	0.042 (2)
C622	1.1073 (7)	0.9003 (6)	0.8784 (4)	0.056 (3)
H62A	1.0889	0.9118	0.8469	0.068*
C623	1.1455 (9)	0.9537 (8)	0.9074 (5)	0.084 (4)
H62C	1.1529	1.0010	0.8953	0.101*
C624	1.1728 (9)	0.9386 (9)	0.9535 (5)	0.077 (4)*
H62E	1.1989	0.9753	0.9728	0.093*
C625	1.1621 (8)	0.8702 (9)	0.9713 (5)	0.083 (4)
H62D	1.1811	0.8604	1.0029	0.099*
C626	1.1227 (7)	0.8133 (7)	0.9432 (4)	0.061 (3)
H62B	1.1149	0.7664	0.9559	0.074*
F1	0.3936 (11)	0.6861 (8)	0.5616 (7)	0.222 (8)
Cl01	1.0705 (4)	1.0238 (4)	0.6219 (2)	0.151 (2)*
F2	0.4760 (12)	0.8702 (7)	0.5496 (6)	0.208 (7)
Cl02	1.1079 (3)	1.1709 (3)	0.6601 (2)	0.1267 (16)*
F3	0.4648 (8)	0.7500 (9)	0.4966 (4)	0.188 (7)
Cl03	1.1216 (8)	0.5280 (8)	0.4468 (5)	0.291 (6)*
F4	0.5366 (8)	0.7528 (10)	0.5827 (6)	0.218 (8)
Cl04	1.1579 (7)	0.4512 (7)	0.3603 (4)	0.260 (5)*
F5	0.3993 (9)	0.8078 (10)	0.6122 (4)	0.195 (7)
F6	0.3304 (10)	0.8001 (9)	0.5284 (6)	0.198 (6)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Sb	0.0529 (5)	0.0906 (7)	0.0572 (5)	−0.0049 (4)	0.0043 (4)	−0.0166 (4)
Ag1	0.0387 (4)	0.0583 (5)	0.0375 (4)	0.0006 (4)	−0.0017 (3)	−0.0018 (4)
Ag2	0.0355 (4)	0.0709 (6)	0.0443 (4)	0.0015 (4)	0.0038 (3)	−0.0004 (4)
Ag3	0.0385 (4)	0.0690 (6)	0.0440 (4)	0.0018 (4)	0.0051 (3)	0.0046 (4)
S1	0.0389 (13)	0.0388 (13)	0.0541 (15)	−0.0026 (11)	0.0048 (11)	−0.0023 (11)
S2	0.0483 (14)	0.0392 (14)	0.0503 (15)	−0.0030 (11)	0.0051 (11)	−0.0032 (11)
P1	0.0333 (12)	0.0438 (14)	0.0351 (12)	0.0032 (11)	0.0012 (10)	0.0017 (11)
P2	0.0354 (12)	0.0414 (14)	0.0357 (12)	−0.0013 (11)	−0.0016 (10)	0.0015 (10)
P3	0.0369 (13)	0.0532 (16)	0.0387 (13)	−0.0013 (12)	0.0009 (10)	0.0007 (12)
P4	0.0333 (12)	0.0500 (16)	0.0372 (13)	−0.0007 (11)	0.0067 (10)	0.0017 (11)
P5	0.0318 (12)	0.0466 (15)	0.0398 (13)	−0.0001 (11)	0.0023 (10)	0.0009 (11)
P6	0.0324 (12)	0.0495 (15)	0.0373 (13)	0.0030 (11)	0.0022 (10)	0.0024 (11)
C1	0.032 (5)	0.052 (6)	0.039 (5)	0.005 (4)	0.000 (4)	−0.001 (4)
C2	0.036 (5)	0.041 (5)	0.041 (5)	−0.008 (4)	0.005 (4)	−0.002 (4)
C3	0.039 (5)	0.047 (6)	0.044 (5)	−0.004 (5)	0.010 (4)	0.004 (5)
C111	0.040 (5)	0.058 (7)	0.045 (6)	0.003 (5)	0.000 (4)	−0.005 (5)
C112	0.079 (8)	0.059 (8)	0.053 (7)	−0.013 (6)	0.001 (6)	0.001 (6)
C113	0.118 (13)	0.055 (9)	0.097 (12)	−0.014 (8)	0.014 (10)	−0.003 (8)
C114	0.098 (11)	0.078 (11)	0.097 (12)	−0.013 (9)	0.007 (9)	−0.041 (9)
C115	0.089 (10)	0.080 (10)	0.056 (8)	−0.007 (8)	0.000 (7)	−0.028 (7)
C116	0.069 (8)	0.066 (8)	0.050 (7)	−0.003 (6)	−0.008 (6)	0.002 (6)
C121	0.046 (6)	0.043 (6)	0.047 (6)	−0.002 (5)	0.008 (4)	−0.004 (5)
C122	0.047 (6)	0.086 (9)	0.048 (6)	0.003 (6)	0.003 (5)	0.013 (6)
C123	0.053 (7)	0.105 (11)	0.065 (8)	−0.005 (7)	0.012 (6)	0.014 (7)
C124	0.044 (7)	0.117 (12)	0.084 (10)	−0.012 (7)	0.030 (7)	0.010 (9)
C125	0.033 (6)	0.112 (11)	0.075 (9)	0.003 (6)	0.003 (5)	0.006 (8)
C126	0.031 (5)	0.086 (9)	0.055 (6)	0.002 (5)	0.001 (5)	0.001 (6)
C211	0.035 (5)	0.046 (6)	0.039 (5)	0.004 (4)	0.004 (4)	−0.001 (4)
C212	0.049 (6)	0.060 (7)	0.073 (8)	−0.002 (6)	0.002 (6)	−0.003 (6)
C213	0.084 (10)	0.049 (8)	0.110 (12)	0.010 (7)	0.022 (9)	−0.025 (7)
C214	0.080 (10)	0.063 (9)	0.115 (13)	0.028 (8)	0.029 (9)	0.030 (9)
C215	0.076 (9)	0.097 (12)	0.080 (10)	0.042 (9)	−0.004 (7)	0.016 (9)
C216	0.061 (7)	0.079 (9)	0.057 (7)	0.024 (7)	−0.006 (6)	0.000 (6)
C221	0.038 (5)	0.035 (5)	0.041 (5)	−0.002 (4)	0.001 (4)	−0.009 (4)
C222	0.043 (6)	0.057 (7)	0.064 (7)	0.002 (5)	0.011 (5)	0.003 (6)
C223	0.077 (9)	0.051 (7)	0.108 (11)	0.003 (7)	0.035 (8)	0.012 (7)
C225	0.052 (7)	0.081 (10)	0.120 (12)	−0.021 (7)	0.016 (8)	0.004 (9)
C226	0.054 (7)	0.062 (8)	0.081 (9)	0.001 (6)	0.006 (6)	0.001 (7)
C311	0.044 (6)	0.075 (8)	0.049 (6)	−0.007 (6)	0.006 (5)	−0.001 (6)
C312	0.080 (9)	0.111 (11)	0.040 (6)	−0.009 (8)	−0.002 (6)	0.009 (7)
C313	0.096 (12)	0.23 (2)	0.029 (7)	−0.038 (14)	0.003 (7)	0.021 (10)
C316	0.094 (10)	0.076 (9)	0.059 (8)	0.001 (8)	0.019 (7)	−0.021 (7)
C321	0.054 (6)	0.057 (7)	0.052 (6)	−0.010 (5)	0.011 (5)	0.006 (5)
C322	0.089 (10)	0.064 (9)	0.064 (8)	−0.012 (7)	0.015 (7)	0.009 (6)
C323	0.150 (15)	0.045 (8)	0.089 (11)	−0.025 (9)	0.037 (10)	0.000 (7)
C325	0.062 (8)	0.113 (13)	0.090 (10)	0.027 (9)	0.014 (7)	0.042 (9)
C326	0.063 (8)	0.076 (9)	0.082 (9)	0.006 (7)	0.001 (7)	0.017 (7)
C411	0.047 (6)	0.045 (6)	0.043 (5)	−0.002 (5)	0.009 (4)	0.007 (5)
C412	0.067 (8)	0.114 (12)	0.062 (8)	−0.005 (8)	−0.002 (6)	0.041 (8)
C414	0.102 (11)	0.094 (11)	0.066 (9)	0.002 (9)	0.000 (8)	0.033 (8)
C415	0.097 (11)	0.121 (13)	0.067 (9)	−0.040 (10)	0.005 (8)	0.040 (9)
C416	0.068 (8)	0.093 (10)	0.058 (7)	−0.025 (7)	0.002 (6)	0.025 (7)
C421	0.030 (5)	0.043 (6)	0.051 (6)	0.007 (4)	−0.002 (4)	−0.003 (5)
C422	0.065 (8)	0.049 (7)	0.082 (9)	−0.003 (6)	0.017 (6)	−0.004 (6)
C423	0.091 (11)	0.064 (9)	0.114 (12)	−0.010 (8)	0.024 (9)	−0.001 (9)
C424	0.093 (11)	0.054 (8)	0.098 (11)	0.006 (8)	0.005 (9)	−0.016 (8)
C425	0.066 (8)	0.075 (10)	0.122 (13)	0.002 (8)	0.028 (8)	−0.019 (9)
C426	0.062 (7)	0.056 (8)	0.078 (8)	−0.002 (6)	0.016 (6)	−0.006 (6)
C511	0.042 (5)	0.043 (6)	0.054 (6)	0.002 (5)	−0.002 (4)	−0.001 (5)
C512	0.056 (7)	0.061 (7)	0.064 (7)	−0.009 (6)	0.014 (6)	−0.006 (6)
C513	0.036 (6)	0.073 (9)	0.115 (12)	−0.009 (6)	−0.001 (7)	−0.016 (8)
C514	0.076 (9)	0.061 (8)	0.087 (10)	0.003 (7)	−0.033 (8)	−0.021 (7)
C516	0.056 (7)	0.058 (7)	0.053 (7)	−0.008 (5)	−0.003 (5)	−0.002 (5)
C521	0.037 (5)	0.051 (6)	0.049 (6)	0.003 (5)	−0.008 (4)	−0.001 (5)
C522	0.079 (9)	0.053 (8)	0.085 (9)	−0.013 (7)	0.024 (7)	0.000 (7)
C525	0.067 (9)	0.093 (11)	0.102 (11)	0.020 (8)	0.004 (8)	−0.030 (9)
C526	0.054 (7)	0.058 (8)	0.097 (10)	0.007 (6)	0.007 (7)	−0.017 (7)
C611	0.042 (6)	0.042 (6)	0.060 (7)	0.009 (5)	−0.013 (5)	−0.002 (5)
C612	0.057 (7)	0.069 (8)	0.094 (10)	0.025 (7)	0.004 (7)	0.010 (7)
C614	0.070 (9)	0.064 (9)	0.125 (13)	0.026 (7)	−0.030 (9)	0.008 (9)
C615	0.079 (10)	0.078 (10)	0.087 (10)	0.004 (8)	−0.009 (8)	0.030 (8)
C616	0.059 (7)	0.071 (8)	0.073 (8)	0.019 (6)	0.010 (6)	0.019 (7)
C621	0.032 (5)	0.055 (6)	0.040 (5)	−0.004 (5)	0.005 (4)	−0.006 (5)
C622	0.063 (7)	0.059 (7)	0.047 (6)	−0.016 (6)	0.003 (5)	0.006 (5)
C623	0.095 (11)	0.063 (9)	0.096 (11)	−0.030 (8)	0.016 (9)	0.001 (8)
C625	0.068 (8)	0.120 (13)	0.056 (8)	−0.005 (8)	−0.016 (6)	−0.015 (8)
C626	0.059 (7)	0.078 (9)	0.045 (6)	−0.001 (6)	−0.005 (5)	−0.006 (6)
F1	0.230 (17)	0.152 (13)	0.29 (2)	−0.089 (12)	0.057 (15)	−0.010 (13)
F2	0.30 (2)	0.106 (9)	0.224 (16)	−0.068 (11)	0.075 (14)	−0.018 (10)
F3	0.164 (11)	0.303 (18)	0.107 (8)	−0.075 (11)	0.065 (8)	−0.117 (10)
F4	0.123 (10)	0.263 (17)	0.245 (17)	0.069 (11)	−0.096 (10)	−0.113 (14)
F5	0.182 (13)	0.30 (2)	0.107 (9)	−0.027 (12)	0.055 (9)	−0.078 (11)

Geometric parameters (Å, º)

Sb—F2	1.783 (12)	C224—H22E	0.9300
Sb—F4	1.801 (11)	C225—C226	1.407 (17)
Sb—F3	1.808 (9)	C225—H22C	0.9300
Sb—F1	1.815 (13)	C226—H22A	0.9300
Sb—F6	1.820 (17)	C311—C316	1.366 (18)
Sb—F5	1.853 (11)	C311—C312	1.379 (16)
Ag1—P2	2.465 (2)	C312—C313	1.45 (2)
Ag1—P1	2.465 (2)	C312—H31B	0.9300
Ag1—S2	2.734 (3)	C313—C314	1.32 (3)
Ag1—S1	2.760 (3)	C313—H31D	0.9300
Ag1—Ag2	3.3369 (11)	C314—C315	1.36 (3)
Ag2—P4	2.468 (2)	C314—H31F	0.9300
Ag2—P3	2.469 (3)	C315—C316	1.40 (2)
Ag2—S2	2.661 (3)	C315—H31E	0.9300
Ag2—S1	2.825 (3)	C316—H31A	0.9300
Ag3—P5	2.483 (3)	C321—C322	1.380 (17)
Ag3—P6	2.491 (3)	C321—C326	1.413 (16)
Ag3—S1	2.686 (3)	C322—C323	1.415 (19)
Ag3—S2	2.771 (3)	C322—H32B	0.9300
S1—H6A	1.2000	C323—C324	1.36 (2)
S2—H6B	1.2000	C323—H32D	0.9300
P1—C111	1.816 (11)	C324—C325	1.36 (2)
P1—C1	1.838 (9)	C324—H32E	0.9300
P1—C121	1.842 (10)	C325—C326	1.406 (19)
P2—C211	1.808 (10)	C325—H32A	0.9300
P2—C221	1.839 (10)	C326—H32C	0.9300
P2—C2	1.847 (9)	C411—C416	1.359 (15)
P3—C321	1.818 (12)	C411—C412	1.384 (16)
P3—C311	1.842 (12)	C412—C413	1.386 (19)
P3—C2	1.845 (9)	C412—H41C	0.9300
P4—C421	1.824 (10)	C413—C414	1.36 (2)
P4—C411	1.825 (10)	C413—H41E	0.9300
P4—C3	1.854 (10)	C414—C415	1.32 (2)
P5—C521	1.827 (11)	C414—H41A	0.9300
P5—C511	1.840 (10)	C415—C416	1.394 (17)
P5—C3	1.865 (9)	C415—H41D	0.9300
P6—C611	1.832 (10)	C416—H41B	0.9300
P6—C621	1.834 (10)	C421—C422	1.383 (15)
P6—C1	1.846 (9)	C421—C426	1.395 (15)
C1—H1A	0.9700	C422—C423	1.370 (18)
C1—H1B	0.9700	C422—H42B	0.9300
C2—H2A	0.9700	C423—C424	1.366 (19)
C2—H2B	0.9700	C423—H42D	0.9300
C3—H3A	0.9700	C424—C425	1.366 (19)
C3—H3B	0.9700	C424—H42E	0.9300
C4—Cl01	1.720 (5)	C425—C426	1.390 (18)
C4—Cl02	1.726 (5)	C425—H42C	0.9300
C4—H4A	0.9700	C426—H42A	0.9300
C4—H4B	0.9700	C511—C516	1.372 (15)
C5—Cl03	1.720 (5)	C511—C512	1.396 (15)
C5—Cl04	1.721 (5)	C512—C513	1.400 (16)
C5—H5A	0.9700	C512—H51C	0.9300
C5—H5B	0.9700	C513—C514	1.369 (19)
C111—C112	1.385 (15)	C513—H51B	0.9300
C111—C116	1.395 (15)	C514—C515	1.351 (19)
C112—C113	1.400 (18)	C514—H51D	0.9300
C112—H11B	0.9300	C515—C516	1.380 (17)
C113—C114	1.39 (2)	C515—H51E	0.9300
C113—H11E	0.9300	C516—H51A	0.9300
C114—C115	1.36 (2)	C521—C526	1.378 (16)
C114—H11D	0.9300	C521—C522	1.384 (15)
C115—C116	1.377 (17)	C522—C523	1.42 (2)
C115—H11C	0.9300	C522—H52B	0.9300
C116—H11A	0.9300	C523—C524	1.33 (2)
C121—C126	1.381 (14)	C523—H52E	0.9300
C121—C122	1.409 (14)	C524—C525	1.37 (2)
C122—C123	1.378 (16)	C524—H52D	0.9300
C122—H12A	0.9300	C525—C526	1.416 (18)
C123—C124	1.365 (18)	C525—H52C	0.9300
C123—H12D	0.9300	C526—H52A	0.9300
C124—C125	1.366 (18)	C611—C612	1.363 (16)
C124—H12E	0.9300	C611—C616	1.400 (16)
C125—C126	1.383 (15)	C612—C613	1.39 (2)
C125—H12C	0.9300	C612—H61A	0.9300
C126—H12B	0.9300	C613—C614	1.36 (2)
C211—C212	1.384 (15)	C613—H61E	0.9300
C211—C216	1.386 (14)	C614—C615	1.36 (2)
C212—C213	1.399 (17)	C614—H61C	0.9300
C212—H21B	0.9300	C615—C616	1.381 (18)
C213—C214	1.37 (2)	C615—H61D	0.9300
C213—H21D	0.9300	C616—H61B	0.9300
C214—C215	1.36 (2)	C621—C622	1.386 (15)
C214—H21C	0.9300	C621—C626	1.399 (14)
C215—C216	1.388 (17)	C622—C623	1.369 (17)
C215—H21E	0.9300	C622—H62A	0.9300
C216—H21A	0.9300	C623—C624	1.356 (19)
C221—C226	1.385 (15)	C623—H62C	0.9300
C221—C222	1.389 (14)	C624—C625	1.35 (2)
C222—C223	1.365 (16)	C624—H62E	0.9300
C222—H22B	0.9300	C625—C626	1.408 (17)
C223—C224	1.355 (18)	C625—H62D	0.9300
C223—H22D	0.9300	C626—H62B	0.9300
C224—C225	1.356 (19)
F2—Sb—F4	87.3 (9)	C214—C215—H21E	120.3
F2—Sb—F3	93.9 (7)	C216—C215—H21E	120.3
F4—Sb—F3	91.4 (7)	C211—C216—C215	121.9 (13)
F2—Sb—F1	177.8 (8)	C211—C216—H21A	119.0
F4—Sb—F1	92.5 (9)	C215—C216—H21A	119.0
F3—Sb—F1	88.3 (8)	C226—C221—C222	118.4 (10)
F2—Sb—F6	96.0 (8)	C226—C221—P2	124.0 (8)
F4—Sb—F6	176.1 (9)	C222—C221—P2	117.6 (7)
F3—Sb—F6	90.6 (7)	C223—C222—C221	119.9 (10)
F1—Sb—F6	84.2 (8)	C223—C222—H22B	120.1
F2—Sb—F5	87.2 (7)	C221—C222—H22B	120.1
F4—Sb—F5	91.8 (7)	C224—C223—C222	121.7 (13)
F3—Sb—F5	176.6 (6)	C224—C223—H22D	119.2
F1—Sb—F5	90.7 (8)	C222—C223—H22D	119.2
F6—Sb—F5	86.1 (7)	C223—C224—C225	120.5 (13)
P2—Ag1—P1	126.27 (8)	C223—C224—H22E	119.7
P2—Ag1—S2	123.04 (9)	C225—C224—H22E	119.7
P1—Ag1—S2	104.35 (8)	C224—C225—C226	119.0 (12)
P2—Ag1—S1	96.47 (8)	C224—C225—H22C	120.5
P1—Ag1—S1	110.40 (8)	C226—C225—H22C	120.5
S2—Ag1—S1	87.51 (8)	C221—C226—C225	120.6 (12)
P2—Ag1—Ag2	86.89 (6)	C221—C226—H22A	119.7
P1—Ag1—Ag2	146.48 (6)	C225—C226—H22A	119.7
S2—Ag1—Ag2	50.81 (6)	C316—C311—C312	119.6 (12)
S1—Ag1—Ag2	54.21 (6)	C316—C311—P3	116.4 (9)
P4—Ag2—P3	125.91 (9)	C312—C311—P3	123.4 (11)
P4—Ag2—S2	108.86 (9)	C311—C312—C313	118.4 (15)
P3—Ag2—S2	116.19 (9)	C311—C312—H31B	120.8
P4—Ag2—S1	106.08 (8)	C313—C312—H31B	120.8
P3—Ag2—S1	104.18 (9)	C314—C313—C312	119.5 (17)
S2—Ag2—S1	87.62 (8)	C314—C313—H31D	120.2
P4—Ag2—Ag1	147.21 (7)	C312—C313—H31D	120.2
P3—Ag2—Ag1	86.04 (6)	C313—C314—C315	123 (2)
S2—Ag2—Ag1	52.78 (6)	C313—C314—H31F	118.5
S1—Ag2—Ag1	52.42 (5)	C315—C314—H31F	118.5
P5—Ag3—P6	131.32 (9)	C314—C315—C316	118.1 (19)
P5—Ag3—S1	112.96 (9)	C314—C315—H31E	120.9
P6—Ag3—S1	102.47 (9)	C316—C315—H31E	120.9
P5—Ag3—S2	103.27 (9)	C311—C316—C315	121.3 (15)
P6—Ag3—S2	110.31 (9)	C311—C316—H31A	119.3
S1—Ag3—S2	88.23 (8)	C315—C316—H31A	119.3
Ag3—S1—Ag1	79.33 (7)	C322—C321—C326	118.5 (12)
Ag3—S1—Ag2	77.18 (7)	C322—C321—P3	119.6 (9)
Ag1—S1—Ag2	73.38 (7)	C326—C321—P3	121.7 (9)
Ag3—S1—H6A	134.2	C321—C322—C323	120.5 (14)
Ag1—S1—H6A	134.2	C321—C322—H32B	119.7
Ag2—S1—H6A	134.2	C323—C322—H32B	119.7
Ag2—S2—Ag1	76.40 (7)	C324—C323—C322	118.8 (15)
Ag2—S2—Ag3	78.54 (7)	C324—C323—H32D	120.6
Ag1—S2—Ag3	78.33 (7)	C322—C323—H32D	120.6
Ag2—S2—H6B	133.5	C325—C324—C323	122.9 (17)
Ag1—S2—H6B	133.5	C325—C324—H32E	118.5
Ag3—S2—H6B	133.5	C323—C324—H32E	118.5
C111—P1—C1	105.1 (5)	C324—C325—C326	118.8 (15)
C111—P1—C121	104.1 (5)	C324—C325—H32A	120.6
C1—P1—C121	101.6 (5)	C326—C325—H32A	120.6
C111—P1—Ag1	116.9 (4)	C325—C326—C321	120.2 (14)
C1—P1—Ag1	112.7 (3)	C325—C326—H32C	119.9
C121—P1—Ag1	114.8 (3)	C321—C326—H32C	119.9
C211—P2—C221	105.7 (4)	C416—C411—C412	116.7 (10)
C211—P2—C2	107.1 (4)	C416—C411—P4	126.9 (9)
C221—P2—C2	99.8 (4)	C412—C411—P4	116.4 (8)
C211—P2—Ag1	116.9 (3)	C411—C412—C413	121.2 (13)
C221—P2—Ag1	108.9 (3)	C411—C412—H41C	119.4
C2—P2—Ag1	116.6 (3)	C413—C412—H41C	119.4
C321—P3—C311	106.3 (5)	C414—C413—C412	119.5 (15)
C321—P3—C2	104.3 (5)	C414—C413—H41E	120.3
C311—P3—C2	103.4 (5)	C412—C413—H41E	120.3
C321—P3—Ag2	120.4 (4)	C415—C414—C413	120.8 (14)
C311—P3—Ag2	109.1 (4)	C415—C414—H41A	119.6
C2—P3—Ag2	111.9 (3)	C413—C414—H41A	119.6
C421—P4—C411	102.7 (5)	C414—C415—C416	120.0 (14)
C421—P4—C3	103.0 (4)	C414—C415—H41D	120.0
C411—P4—C3	103.3 (4)	C416—C415—H41D	120.0
C421—P4—Ag2	116.8 (3)	C411—C416—C415	121.8 (12)
C411—P4—Ag2	112.9 (3)	C411—C416—H41B	119.1
C3—P4—Ag2	116.3 (3)	C415—C416—H41B	119.1
C521—P5—C511	103.1 (4)	C422—C421—C426	118.0 (10)
C521—P5—C3	105.2 (5)	C422—C421—P4	120.3 (8)
C511—P5—C3	102.1 (5)	C426—C421—P4	121.7 (8)
C521—P5—Ag3	113.6 (4)	C423—C422—C421	121.4 (12)
C511—P5—Ag3	112.8 (3)	C423—C422—H42B	119.3
C3—P5—Ag3	118.3 (3)	C421—C422—H42B	119.3
C611—P6—C621	104.2 (5)	C424—C423—C422	120.7 (14)
C611—P6—C1	101.3 (5)	C424—C423—H42D	119.6
C621—P6—C1	105.2 (4)	C422—C423—H42D	119.6
C611—P6—Ag3	113.8 (4)	C423—C424—C425	119.1 (13)
C621—P6—Ag3	112.9 (3)	C423—C424—H42E	120.5
C1—P6—Ag3	118.0 (3)	C425—C424—H42E	120.5
P1—C1—P6	117.0 (5)	C424—C425—C426	121.3 (13)
P1—C1—H1A	108.1	C424—C425—H42C	119.3
P6—C1—H1A	108.1	C426—C425—H42C	119.3
P1—C1—H1B	108.1	C425—C426—C421	119.5 (12)
P6—C1—H1B	108.1	C425—C426—H42A	120.3
H1A—C1—H1B	107.3	C421—C426—H42A	120.3
P3—C2—P2	112.5 (5)	C516—C511—C512	117.8 (10)
P3—C2—H2A	109.1	C516—C511—P5	118.1 (8)
P2—C2—H2A	109.1	C512—C511—P5	124.1 (8)
P3—C2—H2B	109.1	C511—C512—C513	120.2 (12)
P2—C2—H2B	109.1	C511—C512—H51C	119.9
H2A—C2—H2B	107.8	C513—C512—H51C	119.9
P4—C3—P5	112.7 (5)	C514—C513—C512	119.1 (12)
P4—C3—H3A	109.0	C514—C513—H51B	120.4
P5—C3—H3A	109.0	C512—C513—H51B	120.4
P4—C3—H3B	109.0	C515—C514—C513	121.4 (12)
P5—C3—H3B	109.0	C515—C514—H51D	119.3
H3A—C3—H3B	107.8	C513—C514—H51D	119.3
Cl01—C4—Cl02	114.6 (7)	C514—C515—C516	119.4 (13)
Cl01—C4—H4A	108.6	C514—C515—H51E	120.3
Cl02—C4—H4A	108.6	C516—C515—H51E	120.3
Cl01—C4—H4B	108.6	C511—C516—C515	122.0 (12)
Cl02—C4—H4B	108.6	C511—C516—H51A	119.0
H4A—C4—H4B	107.6	C515—C516—H51A	119.0
Cl03—C5—Cl04	115.0 (11)	C526—C521—C522	118.8 (11)
Cl03—C5—H5A	108.5	C526—C521—P5	123.6 (9)
Cl04—C5—H5A	108.5	C522—C521—P5	117.5 (9)
Cl03—C5—H5B	108.5	C521—C522—C523	119.7 (13)
Cl04—C5—H5B	108.5	C521—C522—H52B	120.2
H5A—C5—H5B	107.5	C523—C522—H52B	120.2
C112—C111—C116	117.6 (11)	C524—C523—C522	120.8 (17)
C112—C111—P1	119.1 (8)	C524—C523—H52E	119.6
C116—C111—P1	123.2 (9)	C522—C523—H52E	119.6
C111—C112—C113	120.9 (12)	C523—C524—C525	121.0 (17)
C111—C112—H11B	119.6	C523—C524—H52D	119.5
C113—C112—H11B	119.6	C525—C524—H52D	119.5
C114—C113—C112	119.7 (14)	C524—C525—C526	119.4 (14)
C114—C113—H11E	120.2	C524—C525—H52C	120.3
C112—C113—H11E	120.2	C526—C525—H52C	120.3
C115—C114—C113	119.8 (13)	C521—C526—C525	120.3 (13)
C115—C114—H11D	120.1	C521—C526—H52A	119.9
C113—C114—H11D	120.1	C525—C526—H52A	119.9
C114—C115—C116	120.5 (12)	C612—C611—C616	117.6 (11)
C114—C115—H11C	119.8	C612—C611—P6	119.2 (10)
C116—C115—H11C	119.8	C616—C611—P6	123.2 (8)
C115—C116—C111	121.6 (12)	C611—C612—C613	121.7 (14)
C115—C116—H11A	119.2	C611—C612—H61A	119.1
C111—C116—H11A	119.2	C613—C612—H61A	119.1
C126—C121—C122	117.5 (10)	C614—C613—C612	119.3 (16)
C126—C121—P1	119.2 (8)	C614—C613—H61E	120.3
C122—C121—P1	123.3 (8)	C612—C613—H61E	120.3
C123—C122—C121	120.1 (11)	C613—C614—C615	120.9 (14)
C123—C122—H12A	119.9	C613—C614—H61C	119.5
C121—C122—H12A	119.9	C615—C614—H61C	119.5
C124—C123—C122	121.1 (12)	C614—C615—C616	119.5 (14)
C124—C123—H12D	119.5	C614—C615—H61D	120.3
C122—C123—H12D	119.5	C616—C615—H61D	120.3
C123—C124—C125	119.6 (11)	C615—C616—C611	120.9 (12)
C123—C124—H12E	120.2	C615—C616—H61B	119.6
C125—C124—H12E	120.2	C611—C616—H61B	119.6
C124—C125—C126	120.3 (11)	C622—C621—C626	118.8 (10)
C124—C125—H12C	119.9	C622—C621—P6	119.5 (8)
C126—C125—H12C	119.9	C626—C621—P6	121.7 (9)
C121—C126—C125	121.4 (11)	C623—C622—C621	120.6 (11)
C121—C126—H12B	119.3	C623—C622—H62A	119.7
C125—C126—H12B	119.3	C621—C622—H62A	119.7
C212—C211—C216	116.7 (10)	C624—C623—C622	121.0 (13)
C212—C211—P2	118.6 (8)	C624—C623—H62C	119.5
C216—C211—P2	124.8 (8)	C622—C623—H62C	119.5
C211—C212—C213	122.3 (12)	C625—C624—C623	119.8 (14)
C211—C212—H21B	118.8	C625—C624—H62E	120.1
C213—C212—H21B	118.8	C623—C624—H62E	120.1
C214—C213—C212	118.6 (13)	C624—C625—C626	121.6 (13)
C214—C213—H21D	120.7	C624—C625—H62D	119.2
C212—C213—H21D	120.7	C626—C625—H62D	119.2
C215—C214—C213	121.0 (13)	C621—C626—C625	118.2 (12)
C215—C214—H21C	119.5	C621—C626—H62B	120.9
C213—C214—H21C	119.5	C625—C626—H62B	120.9
C214—C215—C216	119.5 (13)