metal-organic compounds
The title complex, [Co(N3)3(C10H8N2)(C5H5N)], adopts fac-octahedral coordination geometry. All the azido ligands are terminally coordinated with an average Co-N-N angle of 125 Å. The pyridine ligand is least strongly coordinated to CoIII and forms the longest Co-N bond [1.992 (2) Å]. The bipyridine rings lie in the equatorial plane are nearly perpendicular to the pyridine ring.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129893