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In the title compound, [Al(CH3CN)6][TeCl5]3. CH3CN, the polymeric anions form infinite helical chains from apex-sharing distorted octahedral TeCl6 units. These anionic chains are stabilized by [Al(CH3CN)6]3+ counterions.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, TeClAlAce

fcf

Structure factor file (CIF format)
Contains datablock ww

CCDC reference: 129041

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