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The formal pseudo-octahedral coordination around the NiII atom in the title complex, [Ni(NO3)2(OPCy3)2], places the OPCy3 ligands (C18H33OP; Cy is cyclohexyl, C6H11) in an unusual, mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock slossno3

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 128525

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