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Three compounds, [(C2H5)4N]2[HgCl4], [(C2H5)4N]2[CdCl4] and [(C2H5)4N]2[ZnCl4], have been investigated by means of single-crystal X-ray diffraction. They are isomorphous at room temperature. The structures of the three crystals are comprised of discrete [(C2H5)4N]+ cations and [MCl4]2- anions, which both present dynamic orientational disorder. The major structural difference between these compounds is seen in the size of the slightly distorted [MCl4]2- tetrahedra.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, M=Hg, M=Cd, M=Zn

fcf

Structure factor file (CIF format)
Contains datablock (M=Hg)

fcf

Structure factor file (CIF format)
Contains datablock (M=Cd)

fcf

Structure factor file (CIF format)
Contains datablock (M=Zn)

CCDC references: 128153; 128154; 128155

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