Empirical Lewis acid strengths for 135 cations bonded to oxygen

Gagné, O.C.; Hawthorne, F.C.

doi:10.1107/S2052520617010988

Acta Crystallographica Section B
Acta Crystallographica
Section B STRUCTURAL SCIENCE, CRYSTAL ENGINEERING AND MATERIALS

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Acta Cryst. (2017). B73, 956-961
https://doi.org/10.1107/S2052520617010988

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Empirical Lewis acid strengths for 135 cations bonded to oxygen

O. C. Gagné and F. C. Hawthorne

New and updated Lewis acid strengths are listed for 135 cations bonded to oxygen for use with published Lewis base strengths. A strong correlation between Lewis acid strength and ionization energy is shown, and correlation with electronegativity is confirmed.

Keywords: Lewis acidity; valence-matching principle; bond valence; ionization energy; electronegativity.

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